CN107549167A - A kind of production method of triazolone - Google Patents
A kind of production method of triazolone Download PDFInfo
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- CN107549167A CN107549167A CN201710748628.3A CN201710748628A CN107549167A CN 107549167 A CN107549167 A CN 107549167A CN 201710748628 A CN201710748628 A CN 201710748628A CN 107549167 A CN107549167 A CN 107549167A
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Abstract
The invention discloses a kind of production method of triazolone, comprise the following steps, prepare triadimefon pesticide production raw material：10~25 parts of triazolone, 5~16 parts of organic solvent, 5~10 parts of emulsifying agent, 3~9 parts of antifreeze, 6~15 parts of primary surfactant, 3~5 parts of cosurfactant, anti- 3~5 parts of auxiliary agent of drift, 3~5 parts of bleeding agent, 0.5~1 part of dispersant, remaining is deionized water, triazolone and organic solvent are put into agitator and dissolved by heating, rotating speed is that 20~50r/S adds emulsifying agent and dispersant while stirring, obtain mixing liquid A, after well mixed, improve temperature, deionized water is added in mixing liquid B, primary surfactant and cosurfactant, it is sufficiently stirred 30~60min, obtain mixing liquid C, mixing liquid C is put into refrigerating chamber and refrigerated, packed after refrigeration, obtain product.The inventive method is unique, and positive effect, method is ingenious, is adapted to promote.
Description
Technical field
The present invention relates to triazolone technical field, more particularly to a kind of production method of triazolone.
Background technology
Triazolone is a kind of efficient, low toxicity, low-residual, the triazole bactericidal agent that the lasting period is long, absorbability is strong.By plant
After each several part absorbs, it can be conducted in plant.Have to rust and powdery mildew and prevent, root out, treating etc. to act on.To a variety of works
The disease of thing such as Helminthosporium carbonum, wheat class moire disease, wheat leaf blight, pineapple black rot, maize head smut etc. is effective.It is right
Fish and birds are safer.It is harmless to honeybee and natural enemy.The bactericidal mechanism principle of triazolone is extremely complex, mainly suppresses thalline
The biosynthesis of ergosterol, thus suppress or disturb the development of thalline attachment spore and haustorium, the growth of mycelia and the shape of spore
Into.The activity in live body is very strong to some germs for triazolone, but in vitro poor effect.It is strong to the activity comparison spore of mycelia.Three
Oxazolone can be now mixed current with many bactericide, Insecticides (tech) ＆ Herbicides (tech) etc..
The permeability of existing triazolone is poor, it is impossible to which the inside for going deep into plant is sterilized, and existing triazolone
Dispersiveness is poor, easily produces precipitation, so as to influence the performance of this product, therefore, the present invention proposes a kind of production of triazolone
Method, for solving the deficiencies in the prior art.
The content of the invention
The invention aims to solve shortcoming present in prior art, and a kind of producer of the triazolone proposed
Method.
To achieve these goals, present invention employs following technical scheme：
A kind of production method of triazolone, comprises the following steps,
S1, prepare triadimefon pesticide production raw material：10~25 parts of triazolone, 5~16 parts of organic solvent, 5~10 parts of emulsifying agent,
3~9 parts of antifreeze, 6~15 parts of primary surfactant, 3~5 parts of cosurfactant, anti-3~5 parts of auxiliary agent of drift, bleeding agent 3~5
Part, 0.5~1 part of dispersant, remaining be deionized water；
S2, triazolone and organic solvent are put into agitator and dissolved by heating, temperature control treats that triazolone is complete at 50 DEG C~65 DEG C
After fully dissolved, then to open agitator and be stirred, rotating speed is that 20~50r/S adds emulsifying agent and dispersant while stirring,
Obtain mixing liquid A；
S3, the mixing liquid A in S2 is well mixed, after being well mixed, improves temperature, by temperature control at 65 DEG C~75 DEG C,
Rotating speed is improved, rotating speed is 60~100r/S, adds bleeding agent and anti-drift auxiliary agent, stirs, obtain mixing liquid B；
S4, deionized water, primary surfactant and cosurfactant will be added in the mixing liquid B in S3, be sufficiently stirred 30
~60min, obtain mixing liquid C；
S5, mixing liquid C is put into refrigerating chamber and refrigerated, is packed after refrigeration, obtains product.
Preferably, emulsifying agent be selected from NPE, neopelex, calcium dodecyl benzene sulfonate,
One or more in polyoxethylene octylphenyl phenol ether
Preferably, one or more of the described organic solvent in methanol, acetone, ethanol, dimethylbenzene.
Preferably, the triadimefon pesticide production raw material in the step S1：10~25 parts of triazolone, organic solvent 5~
16 parts, 5~10 parts of emulsifying agent, 3~9 parts of antifreeze, 6~15 parts of primary surfactant, 3~5 parts of cosurfactant, it is anti-drift help
3~5 parts of agent, 3~5 parts of bleeding agent, 0.5~1 part of dispersant, remaining be deionized water.
Preferably, described primary surfactant is NPE, AEO, polyoxyethylene
At least one of sorbitol anhydride mono fatty acid ester, glyceryl monooleate, glycerin monostearate and sldium lauryl sulfate, tristearin
The composition of at least one of sour calcium, calcium dodecyl benzene sulfonate.
Preferably, described cosurfactant is at least n-butanol, n-amyl alcohol, isoamyl alcohol, ethanol, ethyl acetate, sweet
One kind in oil.
Preferably, the bleeding agent is hypertonic azone or JFC.
In the present invention, the mixing liquid A in S2 is well mixed, and after being well mixed, temperature is improved, by temperature control at 65 DEG C
~75 DEG C, rotating speed is improved, rotating speed be 60~100r/S, addition bleeding agent and anti-drift auxiliary agent, is stirred, and bleeding agent can be with
Strengthen the permeability of this product, this product can be made to stretch into the inside of plant, bactericidal effect is obvious, in the mixing liquid B in S3
Deionized water, primary surfactant and cosurfactant are added, is sufficiently stirred 30~60min, so in processing, solution mixes
Close more uniformly, holding more persistently, the inventive method is unique, and positive effect, method is ingenious, is adapted to promote.
Embodiment
The technical scheme in the embodiment of the present invention will be clearly and completely described below, it is clear that described implementation
Example only part of the embodiment of the present invention, rather than whole embodiments.
Embodiment one
A kind of production method of triazolone, comprises the following steps,
S1, prepare triadimefon pesticide production raw material：12 parts of triazolone, 6 parts of organic solvent, 6 parts of emulsifying agent, 4 parts of antifreeze, master
8 parts of surfactant, 3 parts of cosurfactant, it is anti-drift 3 parts of auxiliary agent, 3 parts of bleeding agent, 0.6 part of dispersant, remaining be deionization
Water；
S2, triazolone and organic solvent are put into agitator and dissolved by heating, temperature control treats that triazolone is completely dissolved at 55 DEG C
Afterwards, then open agitator and be stirred, rotating speed is that 25r/S adds emulsifying agent and dispersant while stirring, obtains mixed liquor
Body A；
S3, the mixing liquid A in S2 is well mixed, after being well mixed, improves temperature, by temperature control at 67 DEG C, improved and turn
Speed, rotating speed 70r/S, bleeding agent and anti-drift auxiliary agent are added, stirs, obtains mixing liquid B；
S4, deionized water, primary surfactant and cosurfactant will be added in the mixing liquid B in S3, be sufficiently stirred
40min, obtain mixing liquid C；
S5, mixing liquid C is put into refrigerating chamber and refrigerated, is packed after refrigeration, obtains product.
Embodiment two
A kind of production method of triazolone, comprises the following steps,
S1, prepare triadimefon pesticide production raw material：15 parts of triazolone, 8 parts of organic solvent, 8 parts of emulsifying agent, 5 parts of antifreeze, master
8 parts of surfactant, 4 parts of cosurfactant, it is anti-drift 4 parts of auxiliary agent, 4 parts of bleeding agent, 0.8 part of dispersant, remaining be deionization
Water；
S2, triazolone and organic solvent are put into agitator and dissolved by heating, temperature control treats that triazolone is completely dissolved at 60 DEG C
Afterwards, then open agitator and be stirred, rotating speed is that 30r/S adds emulsifying agent and dispersant while stirring, obtains mixed liquor
Body A；
S3, the mixing liquid A in S2 is well mixed, after being well mixed, improves temperature, by temperature control at 70 DEG C, improved and turn
Speed, rotating speed 80r/S, bleeding agent and anti-drift auxiliary agent are added, stirs, obtains mixing liquid B；
S4, deionized water, primary surfactant and cosurfactant will be added in the mixing liquid B in S3, be sufficiently stirred
45min, obtain mixing liquid C；
S5, mixing liquid C is put into refrigerating chamber and refrigerated, is packed after refrigeration, obtains product.
Embodiment three
A kind of production method of triazolone, comprises the following steps,
S1, prepare triadimefon pesticide production raw material：16 parts of triazolone, 9 parts of organic solvent, 7 parts of emulsifying agent, 7 parts of antifreeze, master
8 parts of surfactant, 5 parts of cosurfactant, it is anti-drift 5 parts of auxiliary agent, 4 parts of bleeding agent, 0.8 part of dispersant, remaining be deionization
Water；
S2, triazolone and organic solvent are put into agitator and dissolved by heating, temperature control treats that triazolone is completely dissolved at 60 DEG C
Afterwards, then open agitator and be stirred, rotating speed is that 45r/S adds emulsifying agent and dispersant while stirring, obtains mixed liquor
Body A；
S3, the mixing liquid A in S2 is well mixed, after being well mixed, improves temperature, by temperature control at 70 DEG C, improved and turn
Speed, rotating speed 85r/S, bleeding agent and anti-drift auxiliary agent are added, stirs, obtains mixing liquid B；
S4, deionized water, primary surfactant and cosurfactant will be added in the mixing liquid B in S3, be sufficiently stirred
45min, obtain mixing liquid C；
S5, mixing liquid C is put into refrigerating chamber and refrigerated, is packed after refrigeration, obtains product.
Example IV
A kind of production method of triazolone, comprises the following steps,
S1, prepare triadimefon pesticide production raw material：22 parts of triazolone, 14 parts of organic solvent, 9 parts of emulsifying agent, 8 parts of antifreeze,
12 parts of primary surfactant, 4 parts of cosurfactant, it is anti-drift 4 parts of auxiliary agent, 5 parts of bleeding agent, 1 part of dispersant, remaining be deionization
Water；
S2, triazolone and organic solvent are put into agitator and dissolved by heating, temperature control treats that triazolone is completely dissolved at 65 DEG C
Afterwards, then open agitator and be stirred, rotating speed is that 50r/S adds emulsifying agent and dispersant while stirring, obtains mixed liquor
Body A；
S3, the mixing liquid A in S2 is well mixed, after being well mixed, improves temperature, by temperature control at 74 DEG C, improved and turn
Speed, rotating speed 85r/S, bleeding agent and anti-drift auxiliary agent are added, stirs, obtains mixing liquid B；
S4, deionized water, primary surfactant and cosurfactant will be added in the mixing liquid B in S3, be sufficiently stirred
600min, obtain mixing liquid C；
S5, mixing liquid C is put into refrigerating chamber and refrigerated, is packed after refrigeration, obtains product.
The penetrating power of the triazolone prepared is tested in the embodiment of the present invention one~tetra- respectively, and tests market is sold three
Oxazolone compares, and draws following parameter：
| Penetrating power（Milligram/cm3） | |
| Embodiment one | 15 |
| Embodiment two | 20 |
| Embodiment three | 24 |
| Example IV | 20 |
| Control group | 10 |
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto, it is any
Those familiar with the art the invention discloses technical scope in, technique according to the invention scheme and its invention
Design is subject to equivalent substitution or change, should all be included within the scope of the present invention.
Claims (7)
- A kind of 1. production method of triazolone, it is characterised in that comprise the following steps,S1, prepare triadimefon pesticide production raw material：10~25 parts of triazolone, 5~16 parts of organic solvent, 5~10 parts of emulsifying agent, 3~9 parts of antifreeze, 6~15 parts of primary surfactant, 3~5 parts of cosurfactant, anti-3~5 parts of auxiliary agent of drift, bleeding agent 3~5 Part, 0.5~1 part of dispersant, remaining be deionized water；S2, triazolone and organic solvent are put into agitator and dissolved by heating, temperature control treats that triazolone is complete at 50 DEG C~65 DEG C After fully dissolved, then to open agitator and be stirred, rotating speed is that 20~50r/S adds emulsifying agent and dispersant while stirring, Obtain mixing liquid A；S3, the mixing liquid A in S2 is well mixed, after being well mixed, improves temperature, by temperature control at 65 DEG C~75 DEG C, Rotating speed is improved, rotating speed is 60~100r/S, adds bleeding agent and anti-drift auxiliary agent, stirs, obtain mixing liquid B；S4, deionized water, primary surfactant and cosurfactant will be added in the mixing liquid B in S3, be sufficiently stirred 30 ~60min, obtain mixing liquid C；S5, mixing liquid C is put into refrigerating chamber and refrigerated, is packed after refrigeration, obtains product.
- 2. the production method of a kind of triazolone according to claim 1, it is characterised in that emulsifying agent is selected from polyoxyethylene nonyl phenyl One or more in vinethene, neopelex, calcium dodecyl benzene sulfonate, polyoxethylene octylphenyl phenol ether.
- 3. the production method of a kind of triazolone according to claim 1, it is characterised in that described organic solvent is selected from first One or more in alcohol, acetone, ethanol, dimethylbenzene.
- A kind of 4. production method of triazolone according to claim 1, it is characterised in that the triazolone in the step S1 Pesticide producing raw material：10~25 parts of triazolone, 5~16 parts of organic solvent, 5~10 parts of emulsifying agent, 3~9 parts of antifreeze, main table 6~15 parts of face activating agent, 3~5 parts of cosurfactant, anti-3~5 parts of auxiliary agent of drift, 3~5 parts of bleeding agent, dispersant 0.5~1 Part, remaining be deionized water.
- 5. the production method of a kind of triazolone according to claim 1, it is characterised in that described primary surfactant is NPE, AEO, polyoxyethylene sorbitol acid anhydride mono fatty acid ester, glyceryl monooleate, list At least one of tristerin and at least one of sldium lauryl sulfate, calcium stearate, calcium dodecyl benzene sulfonate Composition.
- 6. the production method of a kind of triazolone according to claim 1, it is characterised in that described cosurfactant is extremely It is one kind in n-butanol, n-amyl alcohol, isoamyl alcohol, ethanol, ethyl acetate, glycerine less.
- 7. the production method of a kind of triazolone according to claim 1, it is characterised in that the bleeding agent is hypertonic azone Or JFC.
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| CN201710748628.3A CN107549167A (en) | 2017-08-28 | 2017-08-28 | A kind of production method of triazolone |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111304174A (en) * | 2020-04-16 | 2020-06-19 | 江南大学 | Triazolone monoclonal antibody hybridoma cell strain B11S and application thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101642094A (en) * | 2008-08-08 | 2010-02-10 | 郑州轻工业学院 | Triadimefon pesticide microemulsion and preparation method thereof |
-
2017
- 2017-08-28 CN CN201710748628.3A patent/CN107549167A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101642094A (en) * | 2008-08-08 | 2010-02-10 | 郑州轻工业学院 | Triadimefon pesticide microemulsion and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 张强 等: "环保型水乳剂专用乳化剂的研制", 《世界农药》 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111304174A (en) * | 2020-04-16 | 2020-06-19 | 江南大学 | Triazolone monoclonal antibody hybridoma cell strain B11S and application thereof |
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Application publication date: 20180109 |