CN107531603B - 在氧分压低于1bar下催化生成甲酸和再生在其中使用的催化剂的方法 - Google Patents

在氧分压低于1bar下催化生成甲酸和再生在其中使用的催化剂的方法 Download PDF

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CN107531603B
CN107531603B CN201680018226.1A CN201680018226A CN107531603B CN 107531603 B CN107531603 B CN 107531603B CN 201680018226 A CN201680018226 A CN 201680018226A CN 107531603 B CN107531603 B CN 107531603B
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liquid solution
oxygen
partial pressure
oxygen partial
vessel
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Chinese (zh)
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CN107531603A (zh
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赫尔曼·沃尔夫·杰巴赫
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Oxfa GmbH
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Oxfa GmbH
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    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
    • C07C51/235—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups of —CHO groups or primary alcohol groups
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/23—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of oxygen-containing groups to carboxyl groups
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/14—Phosphorus; Compounds thereof
    • B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J27/195—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium with vanadium, niobium or tantalum
    • B01J27/198—Vanadium
    • B01J27/199—Vanadium with chromium, molybdenum, tungsten or polonium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • B01J27/28—Regeneration or reactivation
    • B01J27/285—Regeneration or reactivation of catalysts comprising compounds of phosphorus
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C53/00—Saturated compounds having only one carboxyl group bound to an acyclic carbon atom or hydrogen
    • C07C53/02—Formic acid
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
CN201680018226.1A 2015-01-26 2016-01-22 在氧分压低于1bar下催化生成甲酸和再生在其中使用的催化剂的方法 Active CN107531603B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
EP15152518.5A EP3048092B1 (de) 2015-01-26 2015-01-26 Verfahren zur katalytischen Erzeugung von Ameisensäure bei einem Sauerstoffpartialdruck unter 1 bar und Regeneration des dabei eingesetzten Katalysators
EP15152518.5 2015-01-26
PCT/EP2016/051348 WO2016120169A1 (de) 2015-01-26 2016-01-22 Verfahren zur katalytischen erzeugung von ameisensäure bei einem sauerstoffpartialdruck unter 1 bar und regeneration des dabei eingesetzten katalysators

Publications (2)

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CN107531603A CN107531603A (zh) 2018-01-02
CN107531603B true CN107531603B (zh) 2020-10-23

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CN201680018226.1A Active CN107531603B (zh) 2015-01-26 2016-01-22 在氧分压低于1bar下催化生成甲酸和再生在其中使用的催化剂的方法

Country Status (8)

Country Link
US (1) US10035748B2 (de)
EP (2) EP3048092B1 (de)
JP (1) JP6653335B2 (de)
KR (1) KR20170108051A (de)
CN (1) CN107531603B (de)
DK (2) DK3048092T3 (de)
ES (1) ES2747927T3 (de)
WO (1) WO2016120169A1 (de)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3854778A1 (de) 2020-01-27 2021-07-28 Friedrich-Alexander-Universität Erlangen-Nürnberg Verfahren zur katalytischen erzeugung eines alkylformiats
EP4431487A1 (de) 2023-03-17 2024-09-18 OxFA GmbH Verfahren zur gewinnung einer alkansäure

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5695606A (en) * 1992-08-28 1997-12-09 The United States Of America As Represented By The Secretary Of Agriculture Oxidative delignification of wood or wood pulp by transition metal-substituted polyoxometalates
JP2008273915A (ja) * 2007-05-07 2008-11-13 Tohoku Univ バイオマスの湿式酸化によるギ酸の製造方法
CN103209950A (zh) * 2010-09-17 2013-07-17 Jbach有限公司 催化生产甲酸的方法

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CH655673B (de) 1982-03-30 1986-05-15
US10179757B2 (en) 2014-11-18 2019-01-15 Jbach Gmbh Process for obtaining a formate from a reaction mixture

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5695606A (en) * 1992-08-28 1997-12-09 The United States Of America As Represented By The Secretary Of Agriculture Oxidative delignification of wood or wood pulp by transition metal-substituted polyoxometalates
JP2008273915A (ja) * 2007-05-07 2008-11-13 Tohoku Univ バイオマスの湿式酸化によるギ酸の製造方法
CN103209950A (zh) * 2010-09-17 2013-07-17 Jbach有限公司 催化生产甲酸的方法

Also Published As

Publication number Publication date
JP2018504278A (ja) 2018-02-15
EP3048092A1 (de) 2016-07-27
US20180022678A1 (en) 2018-01-25
CN107531603A (zh) 2018-01-02
WO2016120169A1 (de) 2016-08-04
EP3250544B1 (de) 2019-07-03
DK3250544T3 (da) 2019-10-14
DK3048092T3 (da) 2017-07-31
ES2747927T3 (es) 2020-03-12
JP6653335B2 (ja) 2020-02-26
US10035748B2 (en) 2018-07-31
KR20170108051A (ko) 2017-09-26
EP3250544A1 (de) 2017-12-06
EP3048092B1 (de) 2017-04-12

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