CN107520771A - A kind of preparation method of antidamping resin wheel - Google Patents

A kind of preparation method of antidamping resin wheel Download PDF

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Publication number
CN107520771A
CN107520771A CN201710810331.5A CN201710810331A CN107520771A CN 107520771 A CN107520771 A CN 107520771A CN 201710810331 A CN201710810331 A CN 201710810331A CN 107520771 A CN107520771 A CN 107520771A
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CN
China
Prior art keywords
mass parts
resin
hours
fused alumina
white fused
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710810331.5A
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Chinese (zh)
Inventor
尹增虎
于泓
郑国铎
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Zhuhai Taida Grinding Wheel Co Ltd
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Zhuhai Taida Grinding Wheel Co Ltd
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Priority to CN201710810331.5A priority Critical patent/CN107520771A/en
Publication of CN107520771A publication Critical patent/CN107520771A/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24DTOOLS FOR GRINDING, BUFFING OR SHARPENING
    • B24D18/00Manufacture of grinding tools or other grinding devices, e.g. wheels, not otherwise provided for
    • B24D18/0009Manufacture of grinding tools or other grinding devices, e.g. wheels, not otherwise provided for using moulds or presses
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24DTOOLS FOR GRINDING, BUFFING OR SHARPENING
    • B24D3/00Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents
    • B24D3/02Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent
    • B24D3/20Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent and being essentially organic
    • B24D3/28Resins or natural or synthetic macromolecular compounds
    • B24D3/285Reaction products obtained from aldehydes or ketones
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24DTOOLS FOR GRINDING, BUFFING OR SHARPENING
    • B24D3/00Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents
    • B24D3/34Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents characterised by additives enhancing special physical properties, e.g. wear resistance, electric conductivity, self-cleaning properties
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B24GRINDING; POLISHING
    • B24DTOOLS FOR GRINDING, BUFFING OR SHARPENING
    • B24D3/00Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents
    • B24D3/34Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents characterised by additives enhancing special physical properties, e.g. wear resistance, electric conductivity, self-cleaning properties
    • B24D3/342Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents characterised by additives enhancing special physical properties, e.g. wear resistance, electric conductivity, self-cleaning properties incorporated in the bonding agent
    • B24D3/344Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents characterised by additives enhancing special physical properties, e.g. wear resistance, electric conductivity, self-cleaning properties incorporated in the bonding agent the bonding agent being organic

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Polishing Bodies And Polishing Tools (AREA)

Abstract

The present invention provides a kind of preparation method of antidamping resin wheel, includes the liquid phenolic resin of 0.5 1.0 mass parts silane couplers, 8 12 mass parts, 50 80 mass parts 46# plating clothing white fused alumina, 20 40 mass parts 54# plating clothing white fused alumina, the carbon black of 0.5 1.0 mass parts, the potassium fluoroaluminate of 8 12 mass parts, the calcium sulfate crystal whiskers of 35 mass parts, the modified phenolic resin cosmetics of 18 23 mass parts;The present invention is by using plating clothing white fused alumina abrasive material, the abrasive surface has one layer of high temperature coating, the coating is favorably improved resin and abrasive material interface binding intensity, there is energy and inanimate matter material, chemically combined reactive group and the reactive group combined with organic matter materials chemistry in silane coupled agent molecule, it is bonded in inorganic formed with organic interface, promote interface fusion, strengthen performance;Secondly, phenol-formaldehyde resin modified employed in this method in phenolic resin its molecular structure compared to oxidizable group be free of, and free phenol content is low in this method, so as to effectively slow down harden after resin performance degradation.

Description

A kind of preparation method of antidamping resin wheel
Technical field
The present invention relates to a kind of grinding tool technical field, especially a kind of preparation method of antidamping resin wheel.
Background technology
Emery wheel is the main tool of grinding, and it is the porous body being made up of abrasive material and bonding agent.Wherein abrasive material, binding agent It is three underlying dimensions of emery wheel with hole, with the difference of abrasive material, bonding agent and emery wheel manufacturing process etc., grinding wheel characteristics Possible difference is very big, has important influence to the precision, roughness and production efficiency of grinding, therefore, it is necessary to according to tool Concrete conditions in the establishment of a specific crime selects suitable emery wheel.
Resin wheel is the emery wheel that bonding agent is resin, with grinding force is small, grinding temperature is low, self-sharpening is good, grinding effect The advantages that rate is high, it is widely used in the grinding of the hard brittle materials such as hard alloy, ceramics, glass.
But the binding agent in resin wheel is high-molecular organic material, its product during long-time is deposited, easily by Influence to environment produces aging, and cohesive strength declines, and causes grinding wheel performance to decay, while resinoid bond and mill in emery wheel There is organic and inorganic combination interface in material, cleannes, moisture content and itself grain shape of abrasive surface can all reduce interface Bond properties, and its performance degradation reduces by more than 20%.
The content of the invention
In view of the shortcomings of the prior art, the present invention provides a kind of preparation method of antidamping resin wheel.
The technical scheme is that:A kind of preparation method of antidamping resin wheel, comprises the following steps:
S1 0.5-1.0 mass parts silane coupler), is taken, the phenolic resin that 8-12 mass parts viscosity is 800-1200mpa.s Liquid is added in batch mixing pot A, and is uniformly mixed standby, and it is firm in vain then to add the plating clothing that 50-80 mass parts granularities is 46# Beautiful and 20-40 mass parts granularity is 54# plating clothing white fused alumina, is stirred the charcoal of addition 0.5-1.0 mass parts after 3-5min It is black, it is stirred 15-18min;
S2 the potassium fluoroaluminate, 3-5 mass parts calcium sulfate crystal whiskers, 18-23 matter that 8-12 mass parts fineness is 200-300 mesh), are taken Amount part fineness is added in mixing kettle B for the modified phenolic resin cosmetics of 200-300 mesh and is well mixed;
S3), by step S1) batch mixing in mixing kettle A is added to step S2) in mixing kettle B, and be uniformly mixed;
S4), by step S3) in batch mixing pour into the mould for having laid glass screen cloth, then shakeout by scraper plate whole mixed Close material, place into upper strata screen cloth and packing ring, add after die cap will mould be sent into it is compressing in press, obtain thickness for 1.3 ± 0.1mm emery wheel base substrate;
S5 it), will be separated between the every two panels of compressing emery wheel base substrate with Teflon cloth, use flat pattern between every 5 base substrates Aluminium sheet separates, be put into after spring pressurization temperature be dried in 60 DEG C of resistance-type batch-type furnace 3-4h then solidification temperature from 80 DEG C are gradually heating under conditions of 190 DEG C, solidify 15-25h;
Wherein, 1-2 hours are incubated after solidification temperature is raised to 100 DEG C by 80 DEG C, wherein, the heating-up time is 2 hours;
Solidification temperature is incubated 1.5-2.5 hours after being warming up to 120 DEG C by 100 DEG C, wherein, the heating-up time is 2.5 hours;
Solidification temperature is incubated 7-10 hours after being warming up to 190 DEG C by 120 DEG C, wherein, 5 hours heating-up times, so as to obtain Density is 2.34g/cm3Resin wheel.
In above-mentioned technical proposal, step S4), the briquetting pressure is 5-7Mpa, forming temperature is 40-60 DEG C, during compacting Between be the 6-8 seconds.
Further, described glass screen cloth is the enhancement layer of emery wheel, and its specification is 13 mesh, 104mmx17mm, 130g.
Beneficial effects of the present invention are:This method has a floor height temperature by using plating clothing white fused alumina abrasive material, the abrasive surface Coating, the coating are favorably improved resin and abrasive material interface binding intensity, and having in silane coupled agent molecule can be with inorganic material Expect (such as glass, silica sand, metal) chemically combined reactive group and chemically combined with organic material (synthetic resin etc.) Reactive group, it is bonded in inorganic formed with organic interface, promotes interface fusion, strengthen performance;Secondly, employed in this method Phenol-formaldehyde resin modified can cause compared to oxidizable group is free of in phenolic resin its molecular structure after being hardened due to emery wheel Molecular resin cracks, and reduces intensity, middle reaches are low from phenol content in this way for institute, less than 0.5%, so as to effectively slow down hardening The performance degradation of resin afterwards.
Embodiment
The embodiment of the present invention is described further below:
Embodiment 1
A kind of preparation method of antidamping resin wheel, comprises the following steps:
S1 0.5 mass parts silane coupler), is taken, the liquid phenolic resin that 8 mass parts viscosity are 800mpa.s is added to batch mixing In pot A, and it is uniformly mixed standby, then adding plating clothing white fused alumina, 40 mass parts granularities that 60 mass parts granularities are 46# is 54# plating clothing white fused alumina, the carbon black that 0.5 mass parts are added after 5min is stirred, is stirred 16min;
S2), to take 8 mass parts fineness be the potassium fluoroaluminate of 200 mesh, 3 mass parts calcium sulfate crystal whiskers, 18 mass parts fineness are The modified phenolic resin cosmetics of 200 mesh is added in mixing kettle B and is well mixed;
S3), by step S1) batch mixing in mixing kettle A is added to step S2) in mixing kettle B, and be uniformly mixed;
S4), by step S3) in batch mixing pour into the mould for having laid glass screen cloth, then shakeout by scraper plate whole mixed Close material, place into upper strata screen cloth and packing ring, add after die cap by mould be sent into press pressure be 5Mpa, forming temperature be 40 DEG C Compressing, the press time is the 6-8 seconds, obtains the emery wheel base substrate that thickness is 1.3 ± 0.1mm;
S5 it), will be separated between the every two panels of compressing emery wheel base substrate with Teflon cloth, use flat pattern between every 5 base substrates Aluminium sheet separates, and it is 4h to be dried in 60 DEG C of resistance-type batch-type furnace and then in solidification temperature from 80 that temperature is put into after spring pressurization DEG C it is gradually heating under conditions of 190 DEG C, solidifies 19h;
Wherein, 1 hour is incubated after solidification temperature is raised to 100 DEG C by 80 DEG C, wherein, the heating-up time is 2 hours;
Solidification temperature is incubated 1.5 hours after being warming up to 120 DEG C by 100 DEG C, wherein, the heating-up time is 2.5 hours;
Solidification temperature is incubated 7 hours after being warming up to 190 DEG C by 120 DEG C, wherein, 5 hours heating-up times, so as to obtain density For 2.34g/cm3Resin wheel.
Embodiment 2
A kind of preparation method of antidamping resin wheel, comprises the following steps:
S1 0.7 mass parts silane coupler, 10 mass parts viscosity), is taken to be added to for 1000mpa.s liquid phenolic resin mixed Expect in pot A, and be uniformly mixed standby, it is 46# plating clothing white fused alumina, 30 mass parts granularities then to add 70 mass parts granularities For 54# plating clothing white fused alumina, the carbon black that 0.8 mass parts are added after 5min is stirred, is stirred 18min;
S2), to take 10 mass parts fineness be the potassium fluoroaluminate of 200 mesh, 4 mass parts calcium sulfate crystal whiskers, 20 mass parts fineness are The modified phenolic resin cosmetics of 200 mesh is added in mixing kettle B and is well mixed;
S3), by step S1) batch mixing in mixing kettle A is added to step S2) in mixing kettle B, and be uniformly mixed;
S4), by step S3) in batch mixing pour into the mould for having laid glass screen cloth, then shakeout by scraper plate whole mixed Close material, place into upper strata screen cloth and packing ring, add after die cap by mould be sent into press pressure be 6Mpa, forming temperature be 50 DEG C Compressing, the press time is the 6-8 seconds, obtains the emery wheel base substrate that thickness is 1.3 ± 0.1mm;
S5 it), will be separated between the every two panels of compressing emery wheel base substrate with Teflon cloth, use flat pattern between every 5 base substrates Aluminium sheet separates, be put into after spring pressurization temperature be dried in 60 DEG C of resistance-type batch-type furnace 3-4h then solidification temperature from 80 DEG C are gradually heating under conditions of 190 DEG C, solidify 21h;
Wherein, 1.5 hours are incubated after solidification temperature is raised to 100 DEG C by 80 DEG C, wherein, the heating-up time is 2 hours;
Solidification temperature is incubated 2 hours after being warming up to 120 DEG C by 100 DEG C, wherein, the heating-up time is 2.5 hours;
Solidification temperature is incubated 8 hours after being warming up to 190 DEG C by 120 DEG C, wherein, 5 hours heating-up times, so as to obtain density For 2.34g/cm3Resin wheel.
Embodiment 3
A kind of preparation method of antidamping resin wheel, comprises the following steps:
S1 1 mass parts silane coupler), is taken, the liquid phenolic resin that 12 mass parts viscosity are 1200mpa.s is added to batch mixing In pot A, and it is uniformly mixed standby, then adding plating clothing white fused alumina, 20 mass parts granularities that 50 mass parts granularities are 46# is 54# plating clothing white fused alumina, the carbon black that 1 mass parts are added after 5min is stirred, is stirred 18min;
S2), to take 12 mass parts fineness be the potassium fluoroaluminate of 200 mesh, 5 mass parts calcium sulfate crystal whiskers, 23 mass parts fineness are The modified phenolic resin cosmetics of 200 mesh is added in mixing kettle B and is well mixed;
S3), by step S1) batch mixing in mixing kettle A is added to step S2) in mixing kettle B, and be uniformly mixed;
S4), by step S3) in batch mixing pour into the mould for having laid glass screen cloth, then shakeout by scraper plate whole mixed Close material, place into upper strata screen cloth and packing ring, add after die cap by mould be sent into press pressure be 7Mpa, forming temperature be 60 DEG C Compressing, the press time is the 6-8 seconds, obtains the emery wheel base substrate that thickness is 1.3 ± 0.1mm;
S5 it), will be separated between the every two panels of compressing emery wheel base substrate with Teflon cloth, use flat pattern between every 5 base substrates Aluminium sheet separates, be put into after spring pressurization temperature be dried in 60 DEG C of resistance-type batch-type furnace 3-4h then solidification temperature from 80 DEG C are gradually heating under conditions of 190 DEG C, solidify 23h;
Wherein, 2 hours are incubated after solidification temperature is raised to 100 DEG C by 80 DEG C, wherein, the heating-up time is 2 hours;
Solidification temperature is incubated 2.5 hours after being warming up to 120 DEG C by 100 DEG C, wherein, the heating-up time is 2.5 hours;
Solidification temperature is incubated 9 hours after being warming up to 190 DEG C by 120 DEG C, wherein, 5 hours heating-up times, so as to obtain density For 2.34g/cm3Resin wheel.
Merely illustrating the principles of the invention described in above-described embodiment and specification and most preferred embodiment, this is not being departed from On the premise of spirit and scope, various changes and modifications of the present invention are possible, and these changes and improvements both fall within requirement and protected In the scope of the invention of shield.

Claims (2)

1. a kind of preparation method of antidamping resin wheel, it is characterised in that comprise the following steps:
S1 0.5-1.0 mass parts silane coupler), is taken, the liquid phenolic resin that 8-12 mass parts viscosity is 800-1200mpa.s adds Enter into batch mixing pot A, and be uniformly mixed it is standby, then add plating clothing white fused alumina that 50-80 mass parts granularities is 46#, with And the plating clothing white fused alumina that 20-40 mass parts granularity is 54#, the carbon black of addition 0.5-1.0 mass parts after 3-5min is stirred, is stirred Mix mixing 15-18min;
S2 the potassium fluoroaluminate, 3-5 mass parts calcium sulfate crystal whiskers, 18-23 mass parts that 8-12 mass parts fineness is 200-300 mesh), are taken Fineness is added in mixing kettle B for the modified phenolic resin cosmetics of 200-300 mesh and is well mixed;
S3), by step S1) batch mixing in mixing kettle A is added to step S2) in mixing kettle B, and be uniformly mixed;
S4), by step S3) in batch mixing pour into the mould for having laid glass screen cloth, whole compound is then shakeout by scraper plate, Upper strata screen cloth and packing ring are placed into, adds after die cap and mould is sent into compressing in press, it is 1.3 ± 0.1mm's to obtain thickness Emery wheel base substrate;
S5 it), will be separated between the every two panels of compressing emery wheel base substrate with Teflon cloth, flat pattern aluminium sheet used between every 5 base substrates Separate, be put into after spring pressurization in the resistance-type batch-type furnace that temperature is 60 DEG C and dry 3-4h and then in solidification temperature from 80 DEG C It is gradually heating under conditions of 190 DEG C, solidifies 15-25h;
Wherein, 1-2 hours are incubated after solidification temperature is raised to 100 DEG C by 80 DEG C, wherein, the heating-up time is 2 hours;
Solidification temperature is incubated 1.5-2.5 hours after being warming up to 120 DEG C by 100 DEG C, wherein, the heating-up time is 2.5 hours;
Solidification temperature is incubated 7-10 hours after being warming up to 190 DEG C by 120 DEG C, wherein, 5 hours heating-up times, so as to obtain density For 2.34g/cm3Resin wheel.
A kind of 2. preparation method of antidamping resin wheel according to claim 1, it is characterised in that:Step S4), it is described Briquetting pressure is 5-7Mpa, forming temperature is 40-60 DEG C, and the press time is the 6-8 seconds.
CN201710810331.5A 2017-09-11 2017-09-11 A kind of preparation method of antidamping resin wheel Pending CN107520771A (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108890542A (en) * 2018-05-30 2018-11-27 安徽佑开科技有限公司 A kind of anti-attenuation resin wheel formula
CN110340814A (en) * 2019-07-02 2019-10-18 惠州市淀金研磨科技有限公司 A kind of preparation method of grinding wheel
CN110450061A (en) * 2019-07-15 2019-11-15 郑州磨料磨具磨削研究所有限公司 Surface modifying method, the resinoid bonded grinding tool of a kind of modified abrasion resistant material and wear-resistant material
CN110509195A (en) * 2019-07-15 2019-11-29 郑州磨料磨具磨削研究所有限公司 A kind of resin abrasive tools and preparation method thereof
CN111168589A (en) * 2020-01-09 2020-05-19 石家庄福澈研磨科技有限公司 Cutting and grinding dual-purpose grinding wheel and preparation method thereof
CN111761514A (en) * 2020-07-02 2020-10-13 长沙理工大学 Method for monitoring wear state of ordered microgroove multilayer abrasive grinding wheel based on radiation signals

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CN102039561A (en) * 2010-10-15 2011-05-04 江苏省新型复合研磨材料及制品工程技术研究中心 Abrasive material special for high-accuracy PCB and manufacturing method thereof
CN104002250A (en) * 2014-06-10 2014-08-27 湖南大学 Preparing method of ceramic bonding agent CBN (Cubic Boron Nitride) grinding wheel with precisely adjustable and controllable hardness attenuation value
CN104144876A (en) * 2011-12-29 2014-11-12 史密斯国际有限公司 Thermally stable polycrystalline ultrahard material reinforced with fibrous materials
CN104875128A (en) * 2015-05-25 2015-09-02 东莞市金利威磨料磨具有限公司 Formula and machining method of cutting piece for titanium alloy
US20160184971A1 (en) * 2014-12-31 2016-06-30 Saint-Gobain Abrasives, Inc. Colored abrasive articles and method of making colored abrasive articles
CN105818006A (en) * 2016-04-06 2016-08-03 青岛金世博磨具有限公司 High-strength and low-loss resin cutting piece and preparing method thereof

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CN101695827A (en) * 2009-10-15 2010-04-21 江苏耐尔坚砂轮有限公司 Large-diameter high-speed cutting and high-speed heavy load grinding resin wheel
CN102039561A (en) * 2010-10-15 2011-05-04 江苏省新型复合研磨材料及制品工程技术研究中心 Abrasive material special for high-accuracy PCB and manufacturing method thereof
CN104144876A (en) * 2011-12-29 2014-11-12 史密斯国际有限公司 Thermally stable polycrystalline ultrahard material reinforced with fibrous materials
CN104002250A (en) * 2014-06-10 2014-08-27 湖南大学 Preparing method of ceramic bonding agent CBN (Cubic Boron Nitride) grinding wheel with precisely adjustable and controllable hardness attenuation value
US20160184971A1 (en) * 2014-12-31 2016-06-30 Saint-Gobain Abrasives, Inc. Colored abrasive articles and method of making colored abrasive articles
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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108890542A (en) * 2018-05-30 2018-11-27 安徽佑开科技有限公司 A kind of anti-attenuation resin wheel formula
CN110340814A (en) * 2019-07-02 2019-10-18 惠州市淀金研磨科技有限公司 A kind of preparation method of grinding wheel
CN110450061A (en) * 2019-07-15 2019-11-15 郑州磨料磨具磨削研究所有限公司 Surface modifying method, the resinoid bonded grinding tool of a kind of modified abrasion resistant material and wear-resistant material
CN110509195A (en) * 2019-07-15 2019-11-29 郑州磨料磨具磨削研究所有限公司 A kind of resin abrasive tools and preparation method thereof
CN110509195B (en) * 2019-07-15 2020-12-01 郑州磨料磨具磨削研究所有限公司 Resin grinding tool and preparation method thereof
CN111168589A (en) * 2020-01-09 2020-05-19 石家庄福澈研磨科技有限公司 Cutting and grinding dual-purpose grinding wheel and preparation method thereof
CN111761514A (en) * 2020-07-02 2020-10-13 长沙理工大学 Method for monitoring wear state of ordered microgroove multilayer abrasive grinding wheel based on radiation signals
CN111761514B (en) * 2020-07-02 2022-02-01 长沙理工大学 Method for monitoring wear state of ordered microgroove multilayer abrasive grinding wheel based on radiation signals

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