TW379157B - Round-shaped-board-type coloring grinding wheel for cutting purposes and the manufacturing method - Google Patents

Round-shaped-board-type coloring grinding wheel for cutting purposes and the manufacturing method Download PDF

Info

Publication number
TW379157B
TW379157B TW87121859A TW87121859A TW379157B TW 379157 B TW379157 B TW 379157B TW 87121859 A TW87121859 A TW 87121859A TW 87121859 A TW87121859 A TW 87121859A TW 379157 B TW379157 B TW 379157B
Authority
TW
Taiwan
Prior art keywords
grinding wheel
cutting
disc
shaped
raw
Prior art date
Application number
TW87121859A
Other languages
Chinese (zh)
Inventor
Tsuneo Katsuyama
Original Assignee
Kanto
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kanto filed Critical Kanto
Application granted granted Critical
Publication of TW379157B publication Critical patent/TW379157B/en

Links

Landscapes

  • Polishing Bodies And Polishing Tools (AREA)

Abstract

Provided is a kind of manufacturing method making abrasive particles be scattered in the phenol-resin substrate, forming the round-shaped-coloring grinding wheel for cutting. Including the manufacturing method: a raw grinding wheel preparing process in which under the forming temperature of 60 DEG C~70 DEG C, semi-hot forming the abrasive raw material having colorant into a round shape and a thermal hardening process by heating the raw grinding wheel during the period of 8~10 hours from 135 DEG C~145 DEG C to 155 DEG C~165 DEG C and keeping it at 155 DEG C~165 DEG C for the last 2~4 hours, to allow the phenol-resin be hardened. The abrasive particles contain 0.6~1.0 wt.% of magnesium oxide. The round-shaped-board-type coloring grinding wheel for cutting purposes made by this method would, because of its capability of immediate determination for the different hardness or granule codes, not only improve the operation efficiency, but also make the inventory much easier.

Description

五、發明說明(1) 本發明係有關於一種切斷用圓板型著色砂輪及其製造 方法。此切斷用圓板型著色砂輪可用來切斷由金屬、混凝 土(concrete)等所製成的工(w〇rk)材。 切斷用圓板型砂輪設置在切斷機中,藉由回轉來切斷 由金屬、混凝土等所製成的工材。且,被廣泛的使用於建 設業、造船業、土木業以及電力相關製程等領域中。 此種切斷用圓板型砂輪對應於工材種類、要求切斷面 的粗度等’必須分別使用不同的硬度和粒度番號。其重點 在於當硬度或粒度番號不同時,切斷用圓板型砂輪若可因 應狀況而迅速判別的話,可改善作業效率。又,如果切斷 用圓板型砂輪’依據直徑可以色彩分別的話,因為在被磨 耗的情況下,磨耗前的直徑容易分辨,因此容易判斷磨耗 減少量。 在這情況下’將硬度或粒度番號、直徑在砂輪表面上 印字’或將表示硬度或粒度番號的標記(1 abe 1 )貼在砂輪 表面上的話,隨著使用會使標記剝落’或使印字漸薄,因 此並不容易迅速判別砂輪或判斷磨耗減少量。 為此’製造了已著色之切斷用圓板型砂輪,以根據色 彩進行砂輪的判別。著色砂輪是使磨粒分散在酚(phenol) 系樹脂的基質(matrix)中而構成。加入顏料調製而成的原 磨料,在脫濕、整粒後,在成形溫度為4〇〜50。C下,半熱 (semi hot)成形為圓板狀的生砂輪。此生砂輪在1 7〇 ° C〜190 ° C下處理6〜7個小時,藉由使樹脂硬化後而製造出 切斷用圓板型砂輪。5. Description of the invention (1) The present invention relates to a disc-shaped colored grinding wheel for cutting and a manufacturing method thereof. The disc-shaped colored grinding wheel for cutting can be used to cut a work material made of metal, concrete, or the like. The disc-shaped grinding wheel for cutting is installed in a cutting machine, and cuts a work material made of metal, concrete, or the like by turning. Moreover, it is widely used in the fields of construction, shipbuilding, civil engineering, and power-related processes. This type of cutting disc-shaped grinding wheel must have a different hardness and particle size number corresponding to the type of work material and the required thickness of the cutting surface. The main point is that when the hardness or particle size is different, the disc-shaped grinding wheel for cutting can improve the work efficiency if it can be quickly judged according to the situation. Further, if the disc-shaped grinding wheel for cutting is different in color depending on the diameter, the diameter before abrasion is easily distinguished in the case of abrasion, so it is easy to judge the reduction in abrasion. In this case, if the hardness or particle size number and diameter are printed on the surface of the grinding wheel or the mark (1 abe 1) indicating the hardness or particle size number is affixed to the surface of the grinding wheel, the mark will peel off with use 'or It makes the printing thinner, so it is not easy to quickly judge the grinding wheel or the reduction of wear. To this end, a colored disc-shaped grinding wheel was manufactured to discriminate the grinding wheel based on the color. The colored grinding wheel is configured by dispersing abrasive particles in a matrix of a phenol resin. The raw abrasive prepared by adding pigment is dehydrated and granulated, and the forming temperature is 40-50. Below C, a semi-hot (green) wheel is formed into a circular plate. This green grinding wheel is processed at 170 ° C. to 190 ° C. for 6 to 7 hours, and the resin is hardened to produce a cutting disc type grinding wheel.

五、發明說明(2) 然而, 進行燒成, 又,相反地 不鮮明,且 觸不良,而 且,由於刀 輪彎曲的問 有鑑於 圓板型著色 輪具有足夠 亦即, 而形成的切 提供一 色砂輪 砂輪強 溫下進 得太大 研磨面 良,切 ’本發 製造方 、耐久 一種使 型著色 圓板型 ~ 7 0 0 C 成形為 從 135。 時保持 製程。 法,藉 形溫度 氧化鐵 ,提供 為了使色彩鮮明,而在低溫下 物性及其耐久性變差的問題。 行燒成的話’不只出現的色彩 ’使得在切斷時,其刀刃的接 脫離而使切斷困難的問題。並 入時不平順,而產生圓板型砂 明的目 法,其 性、銳 磨粒分 砂輪的 著色砂 下,將 圓板狀 C 〜145 在 155。 上述原 習知的著 如此產生 ’若在高 硬度也變 產生因為 刃接觸不 題。 上述狀況 砂輪及其 的強韌性 本發明為 斷用圓板 種切斷用 括·在成形溫度為6 0 磨粒的原磨料,半熱 輪在8〜1 0個小時中, C ’且在最後2〜4小 系樹脂硬化的熱硬化 的氧化鎂。 本發明的製造方 110〜120° C,可將成 含有0. 2〜0. 6重量%的 又,根據本發明 用圓板型著色砂輪。 的在於提供一種切斷用 中切斷用圓板型著色砂 利度以及適當的硬度。 散在盼系樹脂的基質中 製造方法。 輪的製造方法,其包 含有顏料、樹脂原料及 生砂輪之製程;使生砂 。C上昇至155。(M65 c,而使該酚 磨料含有〇,6〜1. 〇重量% 由將半熱成形基盤維持在 控制在60,。c。又,原磨料 疋合乎理想的。 一種藉由上述方法製造的切斷V. Description of the invention (2) However, firing is performed, and the opposite is not clear and the touch is poor, and because the cutter wheel is bent, the disc-shaped coloring wheel has enough, that is, the cut provides a one-color grinding wheel. The grinding wheel advances too much under strong temperature, and the grinding surface is good. It is cut by the manufacturer and durable. It is a type of colored disc plate ~ 7 0 0 C. The shape is from 135. Keep the process. In order to make the color vivid, the physical properties and the durability are deteriorated at low temperature. In the case of firing, "not only the color that appears" causes a problem that the cutting edge is detached during cutting, making cutting difficult. The incorporation was not smooth, which resulted in a disc-shaped sand. The sharp, abrasive grains were divided into colored wheels of the wheel, and the disc-shaped C ~ 145 was set at 155. The above-mentioned original conventional works are thus produced, 'If it is also high in hardness, it will be produced because the blade contact is not a problem. The above conditions of the grinding wheel and its toughness. The present invention is a cutting disc for cutting. It is a raw abrasive with a forming temperature of 60 grit. The semi-heated wheel is in the range of 8 to 10 hours. 2 to 4 small series of resin hardened magnesium oxide. The manufacturer of the present invention is 110 to 120 ° C, and can be made to contain 0.2 to 0.6% by weight. In addition, according to the present invention, a disc-shaped colored grinding wheel is used. The purpose is to provide a disc-shaped colored sand for cutting and an appropriate hardness. Manufactured in a matrix of a hope resin. A method for manufacturing a wheel, which includes a process for producing pigments, resin raw materials, and a green grinding wheel; C rose to 155. (M65 c, so that the phenolic abrasive contains 0.6 to 1.0% by weight. The semi-thermoformed base plate is controlled to be controlled at 60 ° C. Moreover, the original abrasive is ideal. A method manufactured by the above method Cut off

第5頁 '發明說明(3) 並且,根據本發明,提供硬度5〜20%、強知 切斷用圓板型著色砂輪。 〜4mm的 圖式之簡單說明: 第1圖顯示半熱成形裝置之概要之示意剖面圖. 第2圖顯示生砂輪燒成方法之示意剖面圖;以及 第3圖顯示切斷用圓板型著色砂輪的燒成 子的曲線圖。 來件的一例 最佳之實施例的說明 v切斷用圓板型著色砂輪是使磨粒在酚系樹脂的基質 分散而構成。本發明之切斷用圓板型著色砂輪經二 溫度為60〜70。C下,將含有顏料、樹脂、磨粒等以及/ 〇. 6〜1. 〇重量%的氧化鎂的原磨料,半熱成形為圓板狀生紗 輪之製程,以及藉由使上述生砂輪在8〜丨〇個小時中 ν 135° C〜145。° C上昇至155。C〜165。C,且在最後2〜4小時 保持在155 C〜1 65。C,以使酚系樹脂硬化的熱硬化製程 而被製造。 原磨料除了含有顏料、樹脂原料、磨粒以外,也含 〇. 6 ~ 1. 0重量%的氧化鎂。 因為藉由添加氧化鎂以改善砂輪的硬度,且進而可增 進銳利度。又,與著色劑(c〇1〇rant) 一起添加的話,也有 使色彩更鮮胃明的效果。設定為〇 6〜丨.〇重量%的原因為:若 未滿0. 6重量%的言舌,财久性會下降;#過^ 〇重量%的場 合,硬度變大,如此不僅使銳利度變差,同時會妨礙樹脂 的硬化反應。又,氧化鎂的含量為0.7〜0.9重量%是較佳Page 5 'Explanation of the invention (3) Furthermore, according to the present invention, a disc-shaped colored grinding wheel with a hardness of 5 to 20% and a strong cutting is provided. A brief explanation of the drawings of ~ 4mm: Figure 1 shows a schematic cross-sectional view of the outline of a semi-thermoforming device. Figure 2 shows a schematic cross-sectional view of the firing method of a green grinding wheel; and Figure 3 shows a disc-shaped coloring for cutting Graph of sintered wheels of a grinding wheel. An example of the incoming part Description of the best embodiment v The disc-shaped colored grinding wheel for cutting is formed by dispersing abrasive particles in a matrix of a phenol resin. The cutting disc-shaped colored grinding wheel according to the present invention has a temperature of 60 to 70 after passing through the second stage. Under C, a process of semi-hot forming a raw green yarn wheel including pigment, resin, abrasive grains, etc. and 0.6 to 1.0% by weight of magnesium oxide, and by making the green grinding wheel Ν 135 ° C ~ 145 in 8 ~ 丨 0 hours. ° C rises to 155. C ~ 165. C and kept at 155 C ~ 1 65 for the last 2 to 4 hours. C is manufactured by a thermosetting process for hardening a phenol resin. In addition to the pigment, resin raw materials, and abrasive grains, the original abrasive also contains 0.6 to 1.0% by weight of magnesium oxide. Because by adding magnesium oxide to improve the hardness of the grinding wheel, and further increase the sharpness. In addition, when added together with a coloring agent (c0〇rant), it has the effect of making the color more vivid. The reason for setting it to 〇6 ~ 丨 .〇wt% is: if the speech is less than 0.6wt%, the long-term performance will decrease; in the case of # over ^ 〇〇wt%, the hardness becomes large, which not only makes the sharpness Deterioration and at the same time hinder the hardening reaction of the resin. The content of magnesium oxide is preferably 0.7 to 0.9% by weight.

第6頁 五、發明說明(4) 地。 對磨粒而言,可使用紹氧粉(alundum、Al2〇3、96重量 %)、白鋁氧粉(white alundum、Al2〇3、98 重量%)、燒結磨 料(Al2〇3、99 重量%)、綠色破(green carbon、Si2〇)等。 樹脂原料可使用盼和甲經(formaldehyde)。 顏料可根據目的,使用不同的色彩。紅色(J IS Η : 3- 5R/V : 3_5、C : ho)的場合可使用Fe2 03 (氧化鐵紅),黃色 (JIS H : 4_5YR/V : 6_7、C : 12_14)的場合可使用Fe20 · H20(黃 氧化鐵),綠色(JIS H :5—6G/V :2_3、C的場合可使用 C〇0 · nZnO( cobalt green、鈷綠),藍色(JIS H : 3_6B/V : 4- 6、C : 6_10)的場合可使用 Na6A16(Si04)6 · 2Na304 (群青),白 色(JISH:白色、N: 8 5_9 5、C : 3_5)的場合可使用τ i 〇2 (氧 化鈦)是較佳地《又,原磨料含有〇. 2〜〇. 6重量%的顏料是 較佳地。 在原磨料中,除了上述之外,也可因應所需而添加充 填劑、助硬化劑等。具體而言,充填劑可使用具有使硬度 增加的功能之著色劑(c〇1〇rant、Na3A1Fe) ’而助硬化劑可 使用有助於砂輪全體的硬度安定化之石鹽是較佳 曰關0於本發明’在原磨料中’氧化鐵的含量為0. 2〜0. 6 Π疋僅較可佳辦地:上述除了使色彩更鮮明而可改善色彩感 輪的熱傳導性,同時也兼有在切斷時, ^ : ^擦熱排除的效果。含量為G·2〜G.6重量% ' 、/ 〇 · 2重量%時,不能充分得到上述效果,而Page 6 5. Description of Invention (4) Land. For the abrasive grains, it is possible to use alumina powder (alundum, Al203, 96% by weight), white aluminum powder (white alundum, Al203, 98% by weight), and sintered abrasive (Al203, 99% by weight). ), Green carbon (green carbon, Si2〇) and so on. As the resin raw material, formaldehyde can be used. Pigments can be used in different colors depending on the purpose. Fe2 03 (iron oxide red) can be used for red (J IS Η: 3- 5R / V: 3_5, C: ho), and Fe20 can be used for yellow (JIS H: 4_5YR / V: 6_7, C: 12_14). · H20 (yellow iron oxide), green (JIS H: 5-6G / V: 2_3, C can be used in the case of C. · nZnO (cobalt green, cobalt green), blue (JIS H: 3_6B / V: 4) -6, C: 6_10) can use Na6A16 (Si04) 6 · 2Na304 (ultramarine), white (JISH: white, N: 8 5_9 5, C: 3_5) can use τ i 〇2 (titanium oxide) It is preferable that the original abrasive contains 0.2 to 0.6% by weight of a pigment. In addition to the foregoing, a filler, a hardener, and the like may be added to the original abrasive in addition to the above. Specifically, as the filler, a coloring agent (c0 rant, Na3A1Fe) having a function of increasing hardness can be used, and a hardening agent can be a stone salt that can help stabilize the hardness of the entire grinding wheel. The content of iron oxide in the present invention 'in the original abrasive' is 0.2 to 0.6. Π 疋 is only better than the above: in addition to making the color more vivid, the thermal conductivity of the color wheel can be improved, At the same time, it also has the effect of ^: ^ rubbing heat removal at the time of cutting. When the content is G · 2 ~ G.6% by weight ', / 〇 · 2% by weight, the above effects cannot be fully obtained, and

第7頁 五、發明說明(5) 在超過0.6重量%的場合,其成本(cost)變高。 由上述混合而得的混合物,在脫濕、整粒後,形成原 磨料(g r a i η,細粒)。 例如,脫濕是在5 〇〜6 ORh、約2 0。C等的低濕、常溫環 境下放置4小時來進行。又’整粒可使脫濕過的混合物放 在20〜40篩孔(mesh)的篩來進行。整粒是藉由將未吸著在 磨粒上而殘餘的遊離成份除去,可防止砂輪變脆的重要製 程。 藉由把原磨料放在60〜70° C成形溫度下,半熱成形為 圓板狀,而可得到生砂輪。 半熱成形可利用如第1圖所示的裝置來進行。首先, 藉由將壓機(press)接面部5保溫,同時加熱基盤4至 110〜120° C,使得基盤上面部11的溫度為60~70。c,以調 整成形溫度。其次,在圓板型砂輪用模型3中,均一地投 入一半容量的原磨料,以得到下部層8。其次,在下部層8 的上面全部敷上玻璃混合物(glass cross)製的補強材6, 其上再投入殘餘的一半容量的原磨料後,最上面以滚子 (rol ler)弄平。最後,壓機2以18〇公斤加壓3~4秒,即得 到生砂輪。 右成形溫度為6〇~7〇。c的話’因為比習知方法高2〇。 C ’使砂輪密度加大,而可增進強韌性及财久性。 藉由使生砂輪在8〜10個小時内從140。C上昇至155。 ’同時在上述8〜10個小時中的最後2〜4小時保持 1 6 5 ° C,使樹脂熱硬化,而可得到切斷用圓板 0165 在155Page 7 V. Description of the invention (5) When it exceeds 0.6% by weight, its cost becomes high. The mixture obtained by the above mixing is dehumidified and granulated to form a raw abrasive (g r a i η, fine particles). For example, dehumidification is at 50 to 6 ORh, about 20. C and so on for 4 hours under low humidity and room temperature. The granulation can be carried out by placing the dehumidified mixture on a 20 to 40 mesh sieve. Sizing is an important process that prevents the wheels from becoming brittle by removing the remaining free components that are not adsorbed on the abrasive particles. A green grinding wheel can be obtained by forming the raw abrasive at a forming temperature of 60 to 70 ° C and semi-hot forming into a disc shape. The semi-thermoforming can be performed using the apparatus shown in FIG. Firstly, the heat is applied to the surface 5 of the press to heat the substrate 4 to 110 to 120 ° C, so that the temperature of the upper surface 11 of the substrate is 60 to 70. c to adjust the forming temperature. Next, in the model 3 for a disc-shaped grinding wheel, a half-capacity raw abrasive was uniformly injected to obtain a lower layer 8. Next, the upper surface of the lower layer 8 is entirely covered with a reinforcing material 6 made of glass cross, and the remaining half capacity of the original abrasive is put thereon, and then the top surface is flattened with a roller (rol ler). Finally, the press 2 was pressurized at 180 kg for 3 to 4 seconds to obtain a green grinding wheel. The right forming temperature is 60 to 70. The word c is 20% higher than the conventional method. C 'increases the density of the grinding wheel, and can improve its toughness and financial properties. By making the green grinding wheel from 140 in 8 to 10 hours. C rose to 155. ’At the same time, the resin is thermally hardened by holding at 16 5 ° C for the last 2 to 4 hours of the above 8 to 10 hours. 0165 at 155

第8頁 五、發明說明(6) ------- 型著色砂輪。 生一衫輪以積層的狀態進行熱處理。具體而言,例如第 圖斤Λ母8片平行夾板13(厚度為0.6〜〇.7mm)之間配置7 f生j輪Η為一組(Set),其中平行夾板13和生砂輪14是 父互β又置。具有安定厚板12介入在每組間的2〇組積層放入 燒成,中’以進行減理。χ,以可均句地進行熱處理的 觀點來看’平行夾板13利用熱傳導性優良的鐵製物品是較 為了使樹脂硬化,上述熱處理首先進行生砂輪的水去 除及樹脂的融解。關於水去除,例如,在1〇〇。c下1〇小 時。關於樹脂的融解,例如,在丨3〇。c下進行7小時。、 又,生砂輪的水去除、樹脂的融解及樹脂的硬化可在 燒成爐中連續地進行。 熱處理的樹脂硬化溫度從135。c〜145。c至155。 C〜165° C的原因為··在超過165。〇的高溫下,因為會 面過早硬化’而造成如第3圖所示的反應氣孔的生成不 良’同時使銳利度變差。又,添加氧化鎮的話,會使 的硬度有過度變大的傾向。#而,藉由在上述溫度 進行硬化,可去除氧化鎂對於硬度的影響。並且,在古^ 下進行樹脂硬化的話’著色砂輪的色彩鮮明度會差_ :/皿 而不容易得到鮮明的色彩。另—方面,在未滿135。C的、、i 度下,樹脂的硬化反應不足,使砂輪的硬度及強韌性不 足。又,熱處理的樹脂硬化溫度從14〇。c開始上昇至“οPage 8 V. Description of the invention (6) ------- Type colored wheel. The raw shirt wheel is heat-treated in a laminated state. Specifically, for example, in the figure, 7 parallel plywood plates 13 (thickness 0.6 to 0.7 mm) are arranged between 7 f j j wheels Η as a set, wherein the parallel plywood plate 13 and the green grinding wheel 14 are the Mutual β is set again. The 20 thick layers with the stable thick plate 12 intervened between each group were put into firing, middle 'for reduction. χ, from the viewpoint that heat treatment can be performed uniformly. The parallel plywood 13 uses iron articles having excellent thermal conductivity rather than hardening the resin. The above heat treatment first removes water from the raw grindstone and melts the resin. Regarding water removal, for example, at 100. 10 hours under c. Regarding the melting of the resin, for example, it is 30 °. Under c for 7 hours. In addition, water removal from the green grinding wheel, melting of the resin, and hardening of the resin can be continuously performed in a firing furnace. The heat-treated resin has a curing temperature from 135. c ~ 145. c to 155. The reason for C to 165 ° C. is in excess of 165. At a high temperature of 〇, the premature hardening of the meeting causes the poor formation of the reaction pores as shown in Fig. 3 and deteriorates the sharpness. In addition, the addition of an oxidation ball tends to increase the hardness excessively. #In addition, the effect of magnesium oxide on hardness can be removed by hardening at the above temperature. In addition, if the resin hardening is performed under the old age, the color sharpness of the 'coloring wheel' will be inferior _: / dish, and it is not easy to obtain a bright color. On the other hand, under 135. At the degrees of C and I, the resin's hardening reaction is insufficient, making the hardness and toughness of the grinding wheel insufficient. In addition, the heat-treated resin has a curing temperature from 14 °. c begins to rise to "ο

五、發明說明(7) 熱處理的樹脂硬化時問母中&。^ 2〜“、時保持⑽二間個小 習知低’ 4 了得到足夠的強韌’、因J :為硬化溫度比 久性差的妙私.,,、去仟到足夠的強韌性,而產生脆且耐 不自b期望i :二又,即使熱硬化進行超過1 0小時的話,也 不此功望其強韌性能夠比上述增大。 ,鮮^述方法製造的切斷用圓板型著色砂輪,因為附 因應不同硬度或粒度番號的砂輪狀況而 =斷二:可改善作業效率,同時使庫存管理變得容 會造成磨罐。並且,因為具有適當的硬=使=二 良好以良好,同時在切斷時,砂輪不產生Π 施例m 細祝明使用的實施例,但本發明並不限於此實 (實施例1) 产及L造ί色Γ刀斷用圓板型著色妙輪,,量其密度、硬 度及強韌性,進行切斷試驗。 崎 ❼輪的製造如以下方式進行。 首先’在1001配合器中’投入80公斤 卜 鐵(氧化鐵紅)0.4公斤、含水酚(昭和高分子t如、軋化 BRL-219)4公斤。在25 士5。c下混合3分鐘。 ' 約含有20重量%的水分的液狀酚。首先,,3水酚為 粒充分地潤濕,而使樹脂原料的磨粒均一且」^大酚使磨 添加2〜5重量%的含水酚是較佳地。這是::地渗透。 乂 u芍未滿2重量%的V. Description of the invention (7) When heat-treated resin hardens, ask & ^ 2 ~ ", when keeping the two small knowledge low '4 I get enough toughness", because J: for the mystery of the hardening temperature is worse than long-lasting. ,,, to go to enough strength and toughness, and It is brittle and resistant to failure. I: Second, even if heat curing is performed for more than 10 hours, the strength and toughness can be increased than the above. The cutting disc type manufactured by the method described above Colored wheels, because of the different conditions of different hardness or grain size of the wheel = broken two: can improve operating efficiency, while making inventory management capacity can cause grinding cans. And because of the appropriate hardness = make = two good to Good, at the same time, when cutting, the grinding wheel does not produce Π Example m The detailed examples are used, but the present invention is not limited to this example (Example 1) Production and production of L color Γ knife disc coloring A wonderful wheel, measure its density, hardness, and toughness, and carry out a cutting test. The manufacturing of the rugged wheel is performed as follows. First, put 80 kg of iron (red iron oxide) 0.4 kg and water in the 1001 adapter. Phenol (showa polymer tru, rolled BRL-219) 4 kg. At 25 ± 5. c. Mix for 3 minutes. 'Liquid phenol containing about 20% by weight of water. First, the phenol in water is sufficiently wetted to make the abrasive grains of the resin raw material uniform and the phenol is added to the mill by 2 ~ 5% by weight of aqueous phenol is preferred. This is :: Earth infiltration.乂 u 芍 less than 2% by weight

第10頁Page 10

硬度變得過 話,砂輪的強韌性變差;超過5重量%的場合 大,且銳利度變差。 其次,混合上述得到的混合物、酚(昭和高分子社 製、BRP_511)3公斤、環氧(ep〇xy)化酚(昭和高分子社 製、BRP-808 ) 7公斤、著色劑4公斤、氧化鎂〇. 8公斤以及 石鹽0. 8公jt。投入1501配合器中,在25 ±5。c下混合5分 鐘又,環氧化酚系樹脂是在酚系樹脂中導入環氧基而 成。藉由架橋的形成,具有改善砂輪強韌性的效果。酚及 環氧化酚的添加量分別為2〜5重量%及6〜1〇重量%是較佳 地,是因為未滿上述值的話,砂輪的強韌性會變差,而 在超過上述值的場合中,硬度變得過大,且銳利度變差。 又,著色劑的添加量為3〜7重量%是較佳地,這是因為未滿 3重量%的話,無法得到適當的硬度,而在超過7重量%的場 合中,硬度變得過大,且銳利度變差。又石鹽的添加量 為〇. 6〜1. 0重量%是較佳地,這是因為未滿〇· 6重量%的話, 砂輪的耐久性變差,而在超過丨.〇重量%的場合中,硬度變 得過大,不僅銳利度變差’同時妨礙樹脂的硬化反應。 其次’上述混合物在濕度50〜6 0Rh、溫度約2〇。c的條 件下’放置約4小時’以進行脫濕後,將其放在2〇〜40篩孔 的篩來進行整粒,以得到原磨料(細粒)。 其次,藉由把原磨料(細粒)放在60〜70。C成形溫度 下,半熱成形為圓板狀,即可得到生砂輪。 半熱成形可利用如第1圖所示的裝置來進行。首先, 藉由使壓機接面部5保溫在50〜60。C,同時加熱基盤4至If the hardness becomes too high, the toughness of the grinding wheel becomes worse; if it exceeds 5% by weight, the sharpness becomes worse. Next, 3 kg of phenol (manufactured by Showa Polymer Co., Ltd., BRP_511), 3 kg of epoxy (epoxy) phenol (BRP-808, manufactured by Showa Polymer Co., Ltd.), 4 kg of colorant, and oxidation were mixed. Magnesium 0.8 kg and stone salt 0.8 male jt. Put it into the 1501 coupler at 25 ± 5. The mixture was mixed for 5 minutes under c. The epoxidized phenol-based resin was prepared by introducing an epoxy group into the phenol-based resin. The formation of bridges has the effect of improving the toughness of the grinding wheel. The addition amounts of phenol and epoxidized phenol are preferably 2 to 5% by weight and 6 to 10% by weight, respectively. If the value is less than the above value, the strength and toughness of the grinding wheel will be deteriorated, and when it exceeds the value In the middle, the hardness becomes too large and the sharpness becomes worse. In addition, the addition amount of the colorant is preferably 3 to 7% by weight, because if it is less than 3% by weight, proper hardness cannot be obtained, and when it exceeds 7% by weight, the hardness becomes too large, and Sharpness becomes worse. The addition amount of the stone salt is preferably from 0.6 to 1.0% by weight, because if the content is less than 0.6% by weight, the durability of the grinding wheel is deteriorated, and when the amount exceeds 丨 0.0% by weight However, the hardness becomes too large, and not only the sharpness becomes worse, but also the hardening reaction of the resin is hindered. Next, the above-mentioned mixture is at a humidity of 50 to 60 Rh and a temperature of about 20 °. After being left to stand for about 4 hours under the condition of c for dehumidification, it was placed on a sieve with a sieve of 20 to 40 to perform granulation to obtain the original abrasive (fine particles). Next, put the original abrasive (fine particles) at 60 ~ 70. At C forming temperature, semi-hot forming into a disc shape can obtain a green grinding wheel. The semi-thermoforming can be performed using the apparatus shown in FIG. First, the press-contacting portion 5 is kept at 50 to 60 by pressing. C, while heating the substrate 4 to

第11頁 發明說明(9) 110〜120 ° C,使得基盤上面部u的溫度為6〇〜7〇。c。其 次’在圓板型砂輪用模型3中,均一地投入一半容量的原 磨料(細粒),以形成下部層8。其次,在下部層8的上面全 部敷上玻璃混合物製的補強材6 (安全器材社製、#43〇〇、 厚度0.8mm、直徑40 0mm、色彩R#3〇5),其上再投入殘餘— 半容量的原磨料(細粒)後’最上面以滾子弄平。最後,' 機2以180公斤加壓3〜4秒,即得到生砂輪。又,成形裝置工 的圓板型砂輪用模型3,是利用具有直徑3〇5mm、深度 的模槽(cavity)9,且為氮化鋼所製的物品。又,基盤4使 用直後500min的45C製的物品。壓機2使用接面部5的曲率為 5 0 0mmR的物品。 最後’對生砂輪施加熱處理,使樹脂硬化,以得到直 徑4 0 5mm、突緣(flange )徑5 0mm '厚度3. 〇_的切斷用圓. 型著色砂輪。 吸 如第2圖所示’每8片平行夾板13(厚度為0 7mm、直後 420mni、45C製)之間配置7片生砂輪14為一組,jl中平行化 間夾板1 3和生砂輪1 4是交互設置。安定厚板丨2介入在每組 間的20組積層’在燒成爐中進行熱處理。熱處理如第3圖 所示,藉由在8個小時内從140。C上昇至160。c,且在最 後的2小時保持在1 6 0 ° C下進行。 又’上述熱處理首先進行生砂輪的水去除及樹脂的融 解。水去除是在25 ° C、濕度40RH下4小時。樹脂的融解是 藉由在70° C下,180公斤的加壓處理1分鐘來進行。 疋 由以下方法測量得到的切斷用圓板型著色砂輪之密Page 11 Description of the invention (9) 110 ~ 120 ° C, so that the temperature of the upper part u of the base plate is 60 ~ 70. c. Secondly, in the model 3 for a disc-shaped grinding wheel, a half-capacity raw abrasive (fine grain) is uniformly charged to form a lower layer 8. Next, all of the lower layer 8 is covered with a reinforcing material 6 (manufactured by Safety Equipment Co., Ltd., # 43〇〇, thickness 0.8mm, diameter 40mm, color R # 305), and the remaining material is put on it. — After half capacity of the raw abrasive (fine grain), the top surface is smoothed with a roller. Finally, the machine 2 is pressurized with 180 kg for 3 to 4 seconds, and a green grinding wheel is obtained. In addition, the model 3 for a disc-type grinding wheel of a forming apparatus is an article made of nitrided steel using a cavity 9 having a diameter of 305 mm and a depth. For the base plate 4, a 45C-made article was used for 500 minutes. The press 2 uses an article having a curvature of 500 mmR at the joint 5. Finally, a heat treatment is applied to the green grinding wheel to harden the resin to obtain a cutting-shaped colored grinding wheel having a diameter of 405 mm and a flange diameter of 50 mm and a thickness of 3.0 mm. As shown in Figure 2, 'Eight 8 parallel plywood plates 13 (thickness of 0 7mm, straight 420mni, 45C) are arranged with a group of 7 green grinding wheels 14 as a set, and the parallelizing plate 13 and the green grinding wheel 1 in jl 4 is the interactive setting. Stabilizing slabs 2 were interposed between 20 groups of laminations' and heat-treated in a firing furnace. As shown in Figure 3, the heat treatment was performed from 140 to 8 hours. C rose to 160. c, and maintained at 160 ° C for the last 2 hours. In addition, the above-mentioned heat treatment first removes water from the green grinding wheel and melts the resin. Water was removed for 4 hours at 25 ° C and 40RH. Melting of the resin was carried out by applying a pressure of 180 kg for 1 minute at 70 ° C.密 The density of the disc-shaped colored wheel for cutting measured by the following method

五、發明說明(10) 度、硬度及強韌性。又,以下列方法進行切斷試驗。 (密度(g/cm3)的測量方法) 測量砂輪重量W和外部體積V,再由W / V的式子算出。 (硬度(% )的測量方·、去j 測置切斷X 65mni X 60mm L型角(angle)鋼材 時’被試驗砂輪的直徑的減耗%值,決定其硬度。 (強韌性(mm)的測量方法) 將20 0_ X 5〇mm X 3mm的試驗片砂輪一端固定在機台 (t ab 1 e)端’測量在距離固定點1 〇 〇 mm的自由端上,加上5 公斤應力時的歪量(撓量),以決定其強韌性。強韌性在 2 m m以上為強杨",1 m m〜2 m m之間為11普通11 ,未滿1 _為"脆 弱”。 (切斷試驗的方法) 利用所得的砂輪切斷65mm X 65mm X 60mm L型角鋼材 10次’量測其切斷速度。切斷機械是使用由爪“扣^社 製的產品。 (耐久性的試驗方法) 利用所得的砂輪重覆地切斷標準鋼材至其突緣邊緣, 依據用盡砂輪時的切斷次數來判斷。亦即,切斷次數在’ 次以上的為”優良”,切斷次數在16〜24次之間為,,普通n, 切斷次數不滿1 6次為”不良”。 表1所示,切斷試 密度、硬度及強韌性的測試結果如 驗的結果如表2所示。 (比較例1)5. Description of the invention (10) Degree, hardness and toughness. In addition, the cutting test was performed by the following method. (Measurement method of density (g / cm3)) The weight W of the grinding wheel and the external volume V are measured, and then calculated by the formula of W / V. (Measurement method of hardness (%). When j is cut, X 65mni X 60mm L-shaped angle steel is cut, and the value of% reduction in the diameter of the wheel to be tested determines its hardness. (Strength and toughness (mm) Measurement method) Fix one end of the test piece grinding wheel of 20 0 X X 50mm X 3mm to the end of the machine table (t ab 1 e). Measure at the free end 100mm away from the fixed point and add 5 kg of stress. Distortion (deflection) to determine its strength and toughness. Strength and toughness above 2 mm is strong ", between 1 mm and 2 mm is 11 ordinary 11, and less than 1 _ is " fragile " (cut off) Test method) Cut the 65mm X 65mm X 60mm L-shaped angle steel 10 times with the obtained grinding wheel to measure the cutting speed. The cutting machine uses a product made by the "claw" company. (Durability test method ) Use the obtained grinding wheel to repeatedly cut the standard steel to the edge of its flange, and judge based on the number of cuts when the wheel is exhausted. That is, the number of cuts is "excellent" and the number of cuts is between Between 16 and 24 times, normal n, and the number of cuts less than 16 times are "bad". As shown in Table 1, cut and test density The test results of hardness, hardness, and toughness are shown in Table 2. (Comparative Example 1)

第13頁 五、發明說明(11) 製造黑色的切斷用圓板型著色砂輪’測量其密度、硬 度及強勃性,且進行切斷试驗。 砂輪的製造如以下方式進行。 首先,在1 0 01配合器中,投入1 0 0公斤的鋁氧粉、碳 (carbon)0.3公斤、含水酚4·5公斤。在25±5° C下混合3 分鐘。 其次,混合上述得到的混合物、紛1 3. 5公斤、著色劑 〇. 7公斤、硫化鐵3公斤以及石鹽3公斤。投入1501配合器 中,在25 ±5 ° C下混合5分鐘。 上述混合物以與實施例1相同的方法進行脫濕、整 粒,以得到原磨料。 上述原磨料以與實施例1相同的方法得到生砂輪。然 :90在Γ度臭條件中’壓機接面部約為4〇。C,&盤溫度約 最,'盤上面部的溫度(成形溫度)為80〜9〇。C。 Φ ^ 1 藉由對生砂輪施加與實施例1相同的熱處理, 使樹脂硬化,w ^ m ^ a 件到直徑400mm、厚度3. 0mm的切斷用圓板 昇至190。Γ ,、、、而,熱處理是在6個小時内,從17〇。C上 L下進行。 融解。水^述熱處理首先進行生砂輪的水之去除及樹脂的 是在70。c除是在25。C、濕度4〇RH下4小時。樹脂的融解 ,、,也’以180公斤加壓處理1分鐘來進行。 以*與實# γ 荖甶別、II 、 到1相同的方法’測量得到的切斷用圓板型 百巴々> 輪之密麻 的方 又、硬度及強韌性。又,以與實施例1相同 友進行切斷試驗。Page 13 V. Description of the invention (11) A black disc-shaped colored grinding wheel for cutting is manufactured to measure its density, hardness and toughness, and a cutting test is performed. The manufacturing of a grinding wheel is performed as follows. First, 100 kg of aluminum oxide powder, 0.3 kg of carbon, and 4.5 kg of water-containing phenol were put into a 1001 coupler. Mix at 25 ± 5 ° C for 3 minutes. Next, the above-obtained mixture, 1.35 kg, 0.7 kg of colorant, 3 kg of iron sulfide, and 3 kg of stone salt were mixed. Put in 1501 blender and mix for 5 minutes at 25 ± 5 ° C. The above mixture was dehumidified and granulated in the same manner as in Example 1 to obtain a raw abrasive. The raw abrasive was obtained in the same manner as in Example 1 to obtain a green grinding wheel. However, 90% of the press's face in the Γ degree odor condition is about 40%. C, the temperature of the disk is about 50 ° C, and the temperature (forming temperature) of the upper surface of the disk is 80 to 90. C. Φ ^ 1 The resin was hardened by applying the same heat treatment as in Example 1 to the green grinding wheel, and the w ^ m ^ a piece was cut to a diameter of 400 mm and a cutting disk having a thickness of 3.0 mm to 190. Γ ,,,, and, the heat treatment is within 6 hours, from 170. C up L down. melt. The water treatment described above first removes water and resin from the raw grinding wheel at 70 ° C. c division is at 25. C, 4 hours at 40 RH. Melting of the resin was also performed under a pressure of 180 kg for 1 minute. The cutting disc type Hundred Barb 々 of the cut-off type obtained by the same method as that of the real # γ 荖 甶 荖 甶, II, to 1 was measured for hardness, toughness and toughness. The same test as in Example 1 was performed.

第14頁 五、發明說明(12) 密度、硬度及強韌性的測試結果如表1所示,切斷試 驗的結果如表2所示。 (比較例2) 以與比較例1同樣的方法,製造黑色的切斷用圓板型 著色砂輪。又,以與實施例1相同的方法,測量其密度、 硬度及強韌性。又,以與實施例1相同的方法進行切斷試 驗。 密度、硬度及強韌性的測試結果如表1所示,切斷試驗 的結果如表2所示。 [表1] 實施例1 it較例1 比較例2 密度 2.5 2.3 2.3 (g/cm3) 硬度 良好 良好 良好 (°/〇) 強韌性 強韌 脆弱 脆弱 (mm) 色彩 红色 黑色 黑色 [表2] 實施例1 比較例1 比較例2 切斷速度 18 23 21 (秒) 耐久性 普通 普通 不良 由表1和表2,可知實施例的切斷用圓板型著色砂輪, 在強韋刃性、切斷速度等方面,均比比較例的切斷用圓板型 著色砂輪優越。又,在耐久性方面,至少與比較例的切斷Page 14 V. Description of the invention (12) The test results of density, hardness, and toughness are shown in Table 1, and the results of the cut-off test are shown in Table 2. (Comparative Example 2) In the same manner as in Comparative Example 1, a black disc-shaped colored grinding wheel for cutting was manufactured. The density, hardness, and toughness were measured in the same manner as in Example 1. The cutting test was performed in the same manner as in Example 1. The test results of density, hardness, and toughness are shown in Table 1, and the results of the cutting test are shown in Table 2. [Table 1] Example 1 it Comparative Example 1 Comparative Example 2 Density 2.5 2.3 2.3 (g / cm3) Good hardness Good Good (° / 〇) Toughness Toughness Fragile (mm) Color Red Black Black [Table 2] Implementation Example 1 Comparative example 1 Comparative example 2 Cutting speed 18 23 21 (seconds) Durability General and common defects From Table 1 and Table 2, it can be seen that the cutting disc-shaped colored grinding wheel of the example has a strong cutting edge and cuts. In terms of speed, etc., they are superior to the cutting disc-shaped colored wheel for the comparative example. In terms of durability, it is at least cut off from the comparative example.

第15頁 五、發明說明(13) 用圓板型著色砂輪同等級。在硬度方面,與比較例的切斷 用圓板型著色砂輪同等級。 由本發明方法製造的切斷用圓板型著色砂輪,因為可 因應硬度或粒度番號不同的砂輪狀況,迅速地判斷,因此 不僅可改善作業效率,同時使庫存管理變得容易。又,切 斷用圓板型砂輪依據直徑可以色彩分別的話,因為在被磨 耗的場合中,磨耗前的直徑容易分辨,因此容易判斷磨耗 減少量。又,因為具有足夠的強韌性、耐久性,在使用 中,不會造成磨粒崩落。並且,具有適當的硬度,刀刃接 觸良好,銳利度也良好,同時砂輪不產生彎曲。又,因為 密度相當地高,不需要分別表示工材的硬度。Page 15 V. Description of the invention (13) Use disc-shaped colored grinding wheels of the same grade. In terms of hardness, it was the same grade as the disc-shaped colored wheel for cutting of the comparative example. The disc-shaped colored grinding wheel for cutting manufactured by the method of the present invention can be quickly judged according to the condition of the grinding wheel with different hardness or grain size. Therefore, not only the work efficiency can be improved, but also inventory management can be facilitated. In addition, if the disc-shaped grinding wheel for cutting can be different in color according to the diameter, in the case of abrasion, the diameter before abrasion is easy to distinguish, so it is easy to judge the reduction in abrasion. In addition, because it has sufficient toughness and durability, it will not cause abrasive particles to fall during use. In addition, it has appropriate hardness, good blade contact and good sharpness, and the grinding wheel does not bend. In addition, since the density is relatively high, it is not necessary to separately indicate the hardness of the work material.

第16頁Page 16

Claims (1)

S7^i57 六、申請專利範圍 ' 〜------ 1.—種切斷用圓板型著色砂輪 盼系樹脂的基質中分散,該切斷法,使磨粒在 方法包括: 辦用圓板型者色砂輪的製造 生砂輪製程,在成形溫度為6η〜7ί1〇Γ_ Α 的原磨料,半熱成形為圓心為6以0及70 C下,將含有顏料 〇145熱=程,使生砂輪在8〜10個小時中,從135。 155。C 。汁至155 C〜165。C,且在最後2〜4小時保持在 155 c~165 c,而使該酚系樹脂硬化; 隹 其特徵在於: 該原磨料含有〇. n 0重量%的氧化鎂。 輪的2制11專利範圍第1項所述之切斷用圓板型著色砂 #忐,其中藉由將半熱成形基盤維持在11 〇〜12 〇 C,而將成形溫度控制在60〜70。c。 砂輪3的Ϊ I ; Ϊ利Ϊ圍第1或2項所述之切斷用圓板型著色 W ',”中該原磨料含有〇.2~〇. 6重量%的氧化 鐵。 藉由如申請專利範圍 藉由如申請專利範圍 藉由如申請專利範圍 其特徵在於:其硬度 4. 一種切斷用圓板型著色砂輪 第1項所述之方法所製造者。 5. 一種切斷用圓板型著色砂輪 第2項所述之方法所製造者。 6. 一種切斷用圓板型著色砂輪 第3項所述之方法所製造者。 7·,種切斷用圓板型著色砂 為5〜20%,強韌性為卜4_。S7 ^ i57 6. Scope of patent application '~ ------ 1.—A kind of cutting disc-shaped colored grinding wheel type resin is dispersed in the matrix. This cutting method makes the abrasive particles in the method including: The raw plate grinding wheel manufacturing process of the disc type color wheel is made of raw abrasives with a forming temperature of 6η ~ 7ί1〇Γ_ Α, semi-hot-formed to a circle center of 6, 0 and 70 C, and contains pigments 145 heat = pass, so that Green grinding wheel from 135 in 8 to 10 hours. 155. C. Juice to 155 C ~ 165. C, and maintained at 155 c to 165 c for the last 2 to 4 hours to harden the phenol-based resin; 隹 It is characterized in that: the raw abrasive contains 0.000% by weight of magnesium oxide. The disc type colored sand # 忐 for cutting according to item 1 of the patent scope of 2 to 11 of the wheel, wherein the forming temperature is controlled to 60 to 70 by maintaining the semi-thermoformed base plate at 110 to 120 ° C. . c. ΪI of the grinding wheel 3; The cutting disc type coloring W ', as described in item 1 or 2 of ΪLiΪ, in which the raw abrasive contains 0.2 to 0.6% by weight of iron oxide. The scope of the patent application is based on the scope of the patent application. It is characterized by: its hardness 4. It is manufactured by the method described in item 1 of a disc-shaped colored grinding wheel for cutting. 5. A circle for cutting Plate type colored grinding wheel manufactured by the method described in item 2. 6. A cutting plate type colored grinding wheel manufactured by the method described in item 3. 7. ·, a kind of cutting plate type colored sand is 5 ~ 20%, strength and toughness is 4_. $ Π頁$ Π pages
TW87121859A 1998-12-25 1998-12-30 Round-shaped-board-type coloring grinding wheel for cutting purposes and the manufacturing method TW379157B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP10371559A JP2000190230A (en) 1998-12-25 1998-12-25 Disk type colored grinding wheel for cutting and its manufacture

Publications (1)

Publication Number Publication Date
TW379157B true TW379157B (en) 2000-01-11

Family

ID=18498919

Family Applications (1)

Application Number Title Priority Date Filing Date
TW87121859A TW379157B (en) 1998-12-25 1998-12-30 Round-shaped-board-type coloring grinding wheel for cutting purposes and the manufacturing method

Country Status (2)

Country Link
JP (1) JP2000190230A (en)
TW (1) TW379157B (en)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6846223B2 (en) * 2000-12-09 2005-01-25 Saint-Gobain Abrasives Technology Company Abrasive wheels with workpiece vision feature
PT2174751E (en) * 2008-10-10 2014-08-06 Ct For Abrasives & Refractories Res & Dev Carrd Gmbh Abrasive grain agglomerates, method for their manufacture and their application
JP2014108480A (en) * 2012-11-30 2014-06-12 Noritake Co Ltd End surface polishing tool for sheet glass
CN105856080A (en) * 2016-04-01 2016-08-17 青岛四砂泰益超硬研磨股份有限公司 Medical grinding wheel for grinding insulin needles and manufacturing method thereof
EP3558588A4 (en) * 2016-12-22 2020-08-19 3M Innovative Properties Company Resin bonded-abrasive article having multiple colors

Also Published As

Publication number Publication date
JP2000190230A (en) 2000-07-11

Similar Documents

Publication Publication Date Title
US4800685A (en) Alumina bonded abrasive for cast iron
DE10392510B4 (en) Method of grinding rolls
EP0789641B1 (en) Improved abrasive articles and method for preparing them
KR101226420B1 (en) Abrasive Grain Based on Melted Spherical Corundum
CN105252427B (en) A kind of hard grinding wheel with and preparation method thereof
TW201024035A (en) Reinforced bonded abrasive tools
US4913708A (en) Grinding wheel
CN102343558A (en) Resin abrasive cutting wheel and manufacturing method thereof
CN102343560A (en) Resin grinding wheel and manufacturing method thereof
CN102762341A (en) Bonded abrasive wheel
CN105729316A (en) Artificial stone grinding plate and preparation method thereof
US5834569A (en) Grinding wheel for flat glass beveling
TW379157B (en) Round-shaped-board-type coloring grinding wheel for cutting purposes and the manufacturing method
CN107234553B (en) A kind of elastic grinding disk and preparation method thereof
US5139539A (en) Alumina bonded abrasive for cast iron
US4883501A (en) Alumina bonded abrasive for cast iron
CN111571462B (en) Grindstone and method for producing grindstone
US4988370A (en) Alumina bonded abrasive for cast iron
JP2003191170A (en) Abrasive cutting wheel and its manufacturing method
CN107081688A (en) The multiple grinding piece and its manufacture method of a kind of high-strength high-performance
CN105666350A (en) Artificial stone chamfering wheel and manufacturing method thereof
CN108161782A (en) A kind of preparation method of modified silicon nitride water proof type resin wheel
CN109227421A (en) A kind of wear-resisting grinding wheel and preparation method thereof
US5139536A (en) Alumina bonded abrasive for cast iron
USRE19318E (en) Abrasive article

Legal Events

Date Code Title Description
GD4A Issue of patent certificate for granted invention patent
MM4A Annulment or lapse of patent due to non-payment of fees