CN107502044A - A kind of water-based UV ink of shelf-stable and preparation method thereof - Google Patents
A kind of water-based UV ink of shelf-stable and preparation method thereof Download PDFInfo
- Publication number
- CN107502044A CN107502044A CN201710939359.9A CN201710939359A CN107502044A CN 107502044 A CN107502044 A CN 107502044A CN 201710939359 A CN201710939359 A CN 201710939359A CN 107502044 A CN107502044 A CN 107502044A
- Authority
- CN
- China
- Prior art keywords
- water
- ink
- shelf
- stable
- light trigger
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/101—Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The present invention relates to printing technology, discloses a kind of water-based UV ink of shelf-stable, comprises the following raw materials by weight percent：Silylation modified acroleic acid resin 20 30%；Water-based UV monomers 10 15%；Color stuffing 10 15%；Absolute ethyl alcohol 10 15%；Oxystearin 3 4%；Auxiliary agent 1 3%；Light trigger 3 5%；Deionized water adds to 100%.Ink smell is small, and excitant is small, and good mechanical properties, adhesive force is excellent, and chemical resistance is good, and smooth in appearance is bright and clean after solidification.Performance is reached in use and environmental protection ambilateral takes into account.The a variety of mode of printings of adaptation of the water-based ink of the present invention, can be applied to the printing of the packagings such as food, medicine.
Description
Technical field
The present invention relates to printing technology, and in particular to a kind of water-based UV ink of shelf-stable and preparation method thereof.
Background technology
Water-based ink (Water-based ink) is referred to as ink, and it is mainly by water-soluble resin, organic pigment, molten
Agent and related auxiliaries form through abrasive machining.Water-based ink is especially suitable for cigarette, wine, food, beverage, medicine, Er Tongwan
The sanitary conditions such as tool require strict Packaging Printing Product.Due to making dissolving carrier with water, water-based ink has significant environmental protection
Safety feature：It is safe and nontoxic harmless, non-ignitable not quick-fried, produced almost without VOC, be that country is sent out energetically in recent years
The ink kind of exhibition.
However, different from traditional oil-soluble ink, there are many problems in water-based ink in storage, and placement in the near future can
Phenomena such as being layered.
The content of the invention
The technical problems to be solved by the invention are to provide a kind of water-based UV ink of shelf-stable.
The technical problems to be solved by the invention are achieved by the following technical programs：
A kind of water-based UV ink of shelf-stable, the water-based ink include the raw material of following percentage by weight：
Silylation modified acroleic acid resin 20-30%；
Water-based UV monomers 10-15%；
Color stuffing 10-15%；
Absolute ethyl alcohol 10-15%；
Oxystearin 3-4%；
Auxiliary agent 1-3%；
Light trigger 3-5%；
Deionized water adds to 100%.
Other organic solvents, such as ethyl acetate can also be needed to add according to actual production.
Further, described water-based UV monomers include ethoxyquin trimethylolpropane trimethacrylate, polyethyleneglycol
Any one in methacrylate, methoxy poly (ethylene glycol) mono acrylic ester.Such monomer has low VOC, wide gloss model
Enclose, preferable chemical resistance.
Further, described color stuffing is that particle diameter is 40-50nm.It is preferred that this size filler, avoids consolidating ink
Film after change produces the harmful effects such as bubble.
Further, described light trigger be 1- [4- (2- hydroxy ethoxies)-phenylene] -2- hydroxyls -2 ' and/or 2 ' -
Dimethyl ethyl ketone.
Further, described auxiliary agent is the combination of aqueous levelling agent, water-based coupling agent, aqueous defoamer.
A kind of preparation method of the described water-based UV ink of shelf-stable：
According to designed formula, each raw material is weighed by proportioning, by silylation modified acroleic acid resin, color stuffing, hydroxy stearate
Smart, water-based UV monomers, auxiliary agent, absolute ethyl alcohol and deionized water, which are added in agitator, carries out preliminary stirring 30min, then by oil
Ink is transferred in high-performance ball mill and ground 2 hours（Ball milling speed is 700-900r/min）, finally transfer in agitator
Light trigger is added, finished product is obtained after being sufficiently stirred 30min.
The present invention has the advantages that：
Ink of the present invention is arranged in pairs or groups using silylation modified acroleic acid resin and Oxystearin, the hydroxyl on Oxystearin
Base can form stable cross-linked network with silylation, while avoid the generation of pin hole after film forming.In addition, due to the drop of surface tension
Low, it can also promote layer of ink sprawling on low critical surface tension base material, increase and the contact area of air, so that dry
Dry speed further improves.So that printing process saves the time, energy consumption is reduced, simplifies technique, while the properties of ink are good
It is good, it is environment-protecting and non-poisonous.
Embodiment
With reference to embodiment, the present invention will be described in detail, and embodiment is only the preferred embodiment of the present invention,
It is not limitation of the invention.
Raw material used in embodiment 1-3 is conventional commercial product.
The preparation method of the water-based UV ink of shelf-stable described in embodiment 1-3：
According to designed formula, each raw material is weighed by proportioning, by silylation modified acroleic acid resin, color stuffing, hydroxy stearate
Smart, water-based UV monomers, auxiliary agent, absolute ethyl alcohol and deionized water, which are added in agitator, carries out preliminary stirring 30min, then by oil
Ink is transferred in high-performance ball mill and ground 2 hours（Ball milling speed is 700-900r/min）, finally transfer in agitator
Light trigger is added, finished product is obtained after being sufficiently stirred 30min.
Embodiment 1
A kind of water-based UV ink of shelf-stable, is made up of following weight percent composition：
Silylation modified acroleic acid resin 20%；
Ethoxyquin trimethylolpropane trimethacrylate 15%
Diameter 40nm titanium dioxides 10%；
Absolute ethyl alcohol 10%；
Oxystearin 3%；
Aqueous levelling agent 0.5%, water-based coupling agent 0.5%, aqueous defoamer 1%；
1- [4- (2- hydroxy ethoxies)-phenylene] -2- hydroxyls -2 ' 3%；
Deionized water adds to 100%.
Embodiment 2
A kind of water-based UV ink of shelf-stable, is made up of following weight percent composition：
Silylation modified acroleic acid resin 30%；
Polyethylene glycol monomethacrylate 10%
Diameter 50nm silicon powders 15%；
Absolute ethyl alcohol 15%；
Oxystearin 4%；
Aqueous levelling agent 1%, water-based coupling agent 1%, aqueous defoamer 1%；
2 '-dimethyl ethyl ketone 5%；
Deionized water adds to 100%.
Embodiment 3
A kind of water-based UV ink of shelf-stable, is made up of following weight percent composition：
Silylation modified acroleic acid resin 23%；
Ethoxyquin trimethylolpropane trimethacrylate 11%
Diameter 45nm calcium carbonate 13%；
Absolute ethyl alcohol 13%；
Oxystearin 3.6%；
Aqueous levelling agent 0.3%, water-based coupling agent 0.3%, aqueous defoamer 0.4%；
1- [4- (2- hydroxy ethoxies)-phenylene] -2- hydroxyls -2 ' 2%, 2 '-dimethyl ethyl ketone 2%；
Deionized water adds to 100%.
In order to further illustrate the water-based UV ink of shelf-stable disclosed in this invention, the present invention is also to embodiment 1,2,3
Ink has carried out corresponding test after solidification, and test event is as follows：
Acid resistance：10%NaOH solution soaks 5h.
Alkali resistance：10% sulfuric acid solution soaks 5h.
Heat resistance：By GB/T 1735-2009 standard testings.
Electrolyte-resistant：14d salt spray tests.
Curing rate is tested：The time required to ink sample is fully cured under 4.5KW 365nm ultraviolet lamps.
Film forming character：Observe the appearance of ink film forming.
Stability：Take the water-based UV ink of 20mL shelf-stable to make sample, be put into a 1500rpm rotating speeds in centrifuge and centrifuge
5min, observe whether there is layering and sediment after centrifugation.
Shelf characteric is tested：The water-based UV ink normal temperature of uncured shelf-stable is stored for lower 250 days.
Test result such as table one：
| Test event | Embodiment 1 | Embodiment 2 | Embodiment 3 |
| Acid resistance | Character is unchanged | Character is unchanged | Character is unchanged |
| Alkali resistance | Character is unchanged | Character is unchanged | Character is unchanged |
| Heat resistance | Character is unchanged | Character is unchanged | Character is unchanged |
| Electrolyte-resistant | Character is unchanged | Character is unchanged | Character is unchanged |
| Curing rate（s） | 33 | 45 | 30 |
| Film forming shape | Film bubble-free is pin-free glossy | Film bubble-free is pin-free glossy | Film bubble-free is pin-free glossy |
| Stability | Character is unchanged | Character is unchanged | Character is unchanged |
| Shelf characteric is tested | Character is unchanged | Character is unchanged | Character is unchanged |
Claims (6)
1. a kind of water-based UV ink of shelf-stable, it is characterised in that the water-based ink includes the raw material of following percentage by weight：
Silylation modified acroleic acid resin 20-30%；
Water-based UV monomers 10-15%；
Color stuffing 10-15%；
Absolute ethyl alcohol 10-15%；
Oxystearin 3-4%；
Auxiliary agent 1-3%；
Light trigger 3-5%；
Deionized water adds to 100%.
2. the water-based UV ink of shelf-stable according to claim 1, it is characterised in that described water-based UV monomers include ethoxy
Change in trimethylolpropane trimethacrylate, polyethylene glycol monomethacrylate, methoxy poly (ethylene glycol) mono acrylic ester
Any one.
3. the water-based UV ink of shelf-stable according to claim 1, it is characterised in that described color stuffing is that particle diameter is
40-50nm。
4. the water-based UV ink of shelf-stable according to claim 1, it is characterised in that described light trigger is 1- [4- (2-
Hydroxy ethoxy)-phenylene] -2- hydroxyl -2 ' and/or 2 '-dimethyl ethyl ketones.
5. the water-based UV ink of shelf-stable according to claim 1, it is characterised in that described auxiliary agent be aqueous levelling agent,
The combination of water-based coupling agent, aqueous defoamer.
A kind of 6. preparation method of the water-based UV ink of shelf-stable described in claim 1-5 any one, it is characterised in that：
According to designed formula, each raw material is weighed by proportioning, by silylation modified acroleic acid resin, color stuffing, hydroxy stearate
Smart, water-based UV monomers, auxiliary agent, absolute ethyl alcohol and deionized water, which are added in agitator, carries out preliminary stirring 30min, then by oil
Ink is transferred in high-performance ball mill and ground 2 hours（Ball milling speed is 700-900r/min）, finally transfer in agitator
Light trigger is added, finished product is obtained after being sufficiently stirred 30min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710939359.9A CN107502044A (en) | 2017-10-11 | 2017-10-11 | A kind of water-based UV ink of shelf-stable and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710939359.9A CN107502044A (en) | 2017-10-11 | 2017-10-11 | A kind of water-based UV ink of shelf-stable and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107502044A true CN107502044A (en) | 2017-12-22 |
Family
ID=60701423
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710939359.9A Pending CN107502044A (en) | 2017-10-11 | 2017-10-11 | A kind of water-based UV ink of shelf-stable and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107502044A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107629542A (en) * | 2017-10-11 | 2018-01-26 | 至远彩色印刷工业（惠州）有限公司 | A kind of high-performance water-based UV ink and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002038065A (en) * | 2000-07-25 | 2002-02-06 | Printing Bureau Ministry Of Finance | Resin composition for intaglio printing ink, ink composition made by using it and printed matter obtained therefrom |
| CN102241914A (en) * | 2011-05-26 | 2011-11-16 | 西安理工大学 | Water-based UV (ultraviolet) ink and preparation method thereof |
| CN105504972A (en) * | 2016-02-23 | 2016-04-20 | 谭海林 | Waterborne UV cured ceramic printing ink and preparation method thereof |
| CN106118173A (en) * | 2016-07-28 | 2016-11-16 | 上海维凯光电新材料有限公司 | Hydrophilic antifogging coating composition of photo-thermal dual curable and preparation method thereof |
-
2017
- 2017-10-11 CN CN201710939359.9A patent/CN107502044A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002038065A (en) * | 2000-07-25 | 2002-02-06 | Printing Bureau Ministry Of Finance | Resin composition for intaglio printing ink, ink composition made by using it and printed matter obtained therefrom |
| CN102241914A (en) * | 2011-05-26 | 2011-11-16 | 西安理工大学 | Water-based UV (ultraviolet) ink and preparation method thereof |
| CN105504972A (en) * | 2016-02-23 | 2016-04-20 | 谭海林 | Waterborne UV cured ceramic printing ink and preparation method thereof |
| CN106118173A (en) * | 2016-07-28 | 2016-11-16 | 上海维凯光电新材料有限公司 | Hydrophilic antifogging coating composition of photo-thermal dual curable and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 丁浩: "《塑料工业使用手册》", 31 May 1995, 化学工业出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107629542A (en) * | 2017-10-11 | 2018-01-26 | 至远彩色印刷工业（惠州）有限公司 | A kind of high-performance water-based UV ink and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103614026B (en) | Aqueous woodenware matte clean finishing coat and its preparation method | |
| CN106497222A (en) | A kind of full water-based plastic flexographic ink and preparation method thereof | |
| CN111423765A (en) | Preparation process of environment-friendly water-based ink | |
| CN100588691C (en) | Coating for UV cured plastic and use | |
| WO2016197260A1 (en) | Aqueous plastic gravure printing surface printing/composite ink, binder and preparation methods therefor | |
| CN107245299A (en) | A kind of aqueous light diffusion coating and its production and use | |
| CN106675269A (en) | Waterborne archaized art paint and preparation method thereof | |
| CN104817887A (en) | Water-based printing ink for printing PET (polyethylene terephthalate) films and method for manufacturing water-based printing ink | |
| CN105925189A (en) | Nano microsphere scratching-resisting and high-covering matte gloss oil | |
| CN105440931B (en) | Ultraviolet light solidifies hydrophilic aluminum foil paint composition | |
| CN110424189A (en) | A kind of quick-fried pearl type tipping paper and preparation method thereof with laser effect | |
| JP6117457B1 (en) | Resist ink for low temperature baking | |
| CN102286229B (en) | Environment-friendly aqueous aluminum foil ink and preparation method thereof | |
| CN107502044A (en) | A kind of water-based UV ink of shelf-stable and preparation method thereof | |
| CN102807814B (en) | Nano silica-modified recoatable ultraviolet (UV) varnish used on plastic and preparation method for varnish | |
| CN104774501A (en) | Polyvinyl alcohol fiber-doped polyacrylic acid type environmental-protection water-based ink | |
| CN102702859A (en) | Mirror face plastic printing ink for OPS (oriented polystyrene) thermoshrinkable film and preparation method thereof | |
| CN110205868B (en) | Anti-drop and anti-adhesion gloss oil for aluminized tipping paper and preparation method thereof | |
| CN104263076B (en) | Laughable red pair of PE ink of environment-friendly type and preparation method thereof | |
| CN104231503B (en) | A kind of water soluble resin composite | |
| CN116554727A (en) | Environment-friendly water-based ink and preparation method thereof | |
| CN107793828B (en) | Nanometer color-adjustable environment-friendly printing ink and preparation method thereof | |
| CN107629542A (en) | A kind of high-performance water-based UV ink and preparation method thereof | |
| CN106590174B (en) | Degradable gravure UV anti-counterfeiting ink and application thereof to gold and silver card paper | |
| CN104497811A (en) | Alkali-washable UV (ultraviolet) paint for mobile phone glass screens and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20171222 |
|
| RJ01 | Rejection of invention patent application after publication |