CN107500544A - A kind of red glaze of an ancient unit of weight and preparation method thereof - Google Patents

A kind of red glaze of an ancient unit of weight and preparation method thereof Download PDF

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Publication number
CN107500544A
CN107500544A CN201710915756.2A CN201710915756A CN107500544A CN 107500544 A CN107500544 A CN 107500544A CN 201710915756 A CN201710915756 A CN 201710915756A CN 107500544 A CN107500544 A CN 107500544A
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Prior art keywords
parts
weight
glaze
ancient unit
preparation
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CN201710915756.2A
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Chinese (zh)
Inventor
王建伟
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Yuzhou City Longshan Jun Porcelain Culture Co Ltd
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Yuzhou City Longshan Jun Porcelain Culture Co Ltd
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Priority to CN201710915756.2A priority Critical patent/CN107500544A/en
Publication of CN107500544A publication Critical patent/CN107500544A/en
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    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
    • C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B33/00—Clay-wares
    • C04B33/32—Burning methods
    • C04B33/34—Burning methods combined with glazing
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/5022—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81—Coating or impregnation
    • C04B41/85—Coating or impregnation with inorganic materials
    • C04B41/86—Glazes; Cold glazes

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Dispersion Chemistry (AREA)
  • Glass Compositions (AREA)

Abstract

The invention provides a kind of red glaze of an ancient unit of weight, it is prepared by the raw material of following parts by weight：68 parts of this medicine, 40 46 parts of melilite, 7 13 parts of quartz, 10 16 parts of calcite, 8 12 parts of kaolin, 23 parts of block tin, 34 parts of Copper Ores, 0.75 1.25 parts of iron ore, 68 parts of talcum, 2.5 3.5 parts of bone ash.The present invention is compared with prior art, any chemical substance is not added with formula, color development is carried out using a variety of chromonic materials contained in ore, make color development more natural, and pass through scientific and reasonable raw material proportioning and control burning process, the red glaze jade texture of an ancient unit of weight and opaque prepared are strong, high yield rate, up to more than 89%.

Description

A kind of red glaze of an ancient unit of weight and preparation method thereof
Technical field
The present invention relates to a kind of glaze, and in particular to a kind of red glaze of an ancient unit of weight and preparation method thereof.
Background technology
Pottery rough flambe has a long history, and is still considered as rarity by ceramic fan so far.Its glaze layer is mainly presented Different degrees of is red or red inner purplish blue, and glossiness is excellent, and enamel is good, and it is not the beautiful texture for surpassing jade to have.The red glaze conduct of an ancient unit of weight One kind in rough flambe, its appearance uniform moisten, and entire body is pure bright-coloured red, have certain mobility and do not take off mouth, glaze Face is furnished with fine and closely woven crackle, bright and clean bright.But the manufacture difficulty of the red glaze of an ancient unit of weight is high, yield rate is relatively low.
The content of the invention
It is an object of the invention to overcome the deficiencies of the prior art and provide a kind of color development nature, jade texture and opaque By force, the red glaze of an ancient unit of weight of high yield rate.
To achieve these goals, the technical solution adopted by the present invention is as follows：
A kind of red glaze of an ancient unit of weight, is prepared by the raw material of following parts by weight：This medicine 6-8 parts, melilite 40-46 parts, quartzy 7-13 parts, Calcite 10-16 parts, kaolin 8-12 parts, block tin 2-3 parts, Copper Ores 3-4 parts, iron ore 0.75-1.25 parts, talcum 6-8 parts, Bone ash 2.5-3.5 parts.
The red glaze of above-mentioned an ancient unit of weight, wherein, it is prepared by the raw material of following parts by weight：7 parts of this medicine, 43 parts of melilite, 10 parts of quartz, 13 parts of calcite, 10 parts of kaolin, 2.5 parts of block tin, 3.5 parts of Copper Ores, 1 part of iron ore, 7 parts of talcum, bone ash 3 Part.
The preparation method of the red glaze of above-mentioned an ancient unit of weight, comprises the following steps：
（1）The preparation of glaze slip；
（2）Glazing；
（3）Burn till, 1280-1300 DEG C of firing temperature.
The preparation method of the red glaze of above-mentioned an ancient unit of weight, wherein, step（3）In firing process specifically comprise the following steps：1. oxygen Change the flame stage：Base substrate after glazing is put into kiln, is fired under oxidizing atmosphere, temperature is ramped up 980-1020 in 3-5h ℃；2. the reducing flame stage：Under reducing atmosphere, temperature is made to be ramped up 1280-1300 DEG C in 6-8h；3. cooling stage：It is natural Room temperature is cooled to, is made.
Beneficial effect in the present invention is：
1st, in the present invention, scientific and reasonable this medicine of allotment, melilite, quartz, calcite, kaolin, talcum, bone ash are passed through Content, and then to control the content of potassium, sodium, calcium, silicon, the shortcomings of glaze paint prepared is without sliver, smoking, sagging.
2nd, the red glaze of an ancient unit of weight in the present invention is mainly used as photoghraphic coupler using the ferro element in glaze and copper, in sintering procedure and also Former initial temperature is strict controlled in 980-1020 DEG C, can so make under reducing atmosphere, Fe2O3With FeO, Fe2O3、Fe3O4Three Kind form is present, but with Fe2O3Based on colour generation, reduction initial temperature control has suppressed Fe at 980-1020 DEG C2+Colour generation, make Glaze paint shows red, and in cooling procedure, FeO is easily oxidized to Fe2O3, Cu can be also protected to a certain extent2O's Colour generation, an ancient unit of weight red for making to burn out more are stablized.
3rd, the raw material used in the present invention is mineral matter, is not added with any chemical substance, makes the red glaze color development of an ancient unit of weight more natural.
The present invention is not added with any chemical substance compared with prior art, in formula, utilizes a variety of hairs contained in ore Color substance carries out color development, makes color development more natural, and by scientific and reasonable raw material proportioning and control burning process, prepares The red glaze jade texture of an ancient unit of weight and opaque are strong, high yield rate, up to more than 89%.
Embodiment
Embodiment 1
A kind of red glaze of an ancient unit of weight, is prepared by the raw material of following parts by weight：This medicine 6-8 parts, melilite 40-46 parts, quartzy 7-13 parts, Calcite 10-16 parts, kaolin 8-12 parts, block tin 2-3 parts, Copper Ores 3-4 parts, iron ore 0.75-1.25 parts, talcum 6-8 parts, Bone ash 2.5-3.5 parts.
The preparation method of the above-mentioned red glaze of an ancient unit of weight, comprises the following steps：
（1）The preparation of glaze slip：1. the kaolin of above-mentioned parts by weight, talcum is taken to calcine 20-30min at 920-980 DEG C；2. it will forge Kaolin, talcum and above-mentioned other raw material mixing, ball milling, sievings after burning, that is, obtain the glaze slip that mass concentration is 54-56%；
（2）Glazing：Base substrate is immersed into step（1）In take out for a moment in obtained glaze slip, be again dipped into a moment, take out, utilize base The water imbibition of body, makes glaze slip uniformly be attached to billet surface；
（3）Burn till, 1280-1300 DEG C of firing temperature.
Firing process specifically comprises the following steps：
1. the oxidizing flame stage：Base substrate after glazing is put into kiln, is fired under oxidizing atmosphere, temperature is ramped up in 3-5h 980-1020℃；
2. the reducing flame stage：Under reducing atmosphere, temperature is made to be ramped up 1280-1300 DEG C in 6-8h from 980-1020 DEG C；
3. cooling stage：Room temperature is naturally cooled to, is made.
Using this medicine, melilite, quartz, calcite, kaolin, talcum, bone ash as main component in the present invention, wherein, this Medicine is a kind of natural feldspar of Yuzhou, and its main component is SiO2, also containing a small amount of Fe elements；Contain in melilite Potassium, sodium, there is cosolvent effect, firing time can be shortened, increase the light transmittance of pottery, improve the knot between base substrate and glaze layer With joint efforts；The content of quartz is silica, it is possible to increase the melting temperature and viscosity of glaze, reduces the coefficient of expansion of glaze, improves glaze Mechanical strength, hardness, wearability and chemical resistance, and quartz can be by more lyotrope CaO, Na2O、K2O、 MgO melting generation transparence quartz glass, makes glaze paint bright, improves the glossiness of pottery；Calcite is also known as calcium stone, mainly Play the effect of solvent, by increasing capacitance it is possible to increase hardness, abrasion resistance and the corrosion resistance of glaze, reduce the melting temperature of glaze, increase glaze colours Glossiness and transparency, preventing and treating glaze paint cracking and accumulation；Kaolin adds Al2O3Content, improve the suspension of glaze Property；In block tin in addition to containing Sn elements, also containing a small amount of Pb elements, Sn elements are a kind of opacifiers and assistant toner, and Pb is first Also a kind of assistant toner of element, can make an ancient unit of weight red color color development more preferable；Copper Ores are main colouring agents, typically by Cu, Fe, Tri- kinds of element compositions of S, burn till, Fe under reducing atmosphere2+、Fe3+、Cu+、Cu2+It is main colour generation ion；Iron ore be containing Iron simple substance or iron compound are capable of the mineral aggregate of economic utilization, it is every containing can the ore of ferro element of economic utilization be called Iron ore, the species of iron ore is a lot, mainly has magnetic iron ore for ironmaking（Fe3O4）, bloodstone（Fe2O3）And siderite （FeCO3）Etc. a kind of colouring agent for being the present invention；Bone ash mainly contains calcium phosphate, is a kind of cosolvent, can reduce chun glaze Melting temperature and the coefficient of expansion, increase the opaque of chun glaze；The chemical formula of talcum is 3MgO4SiO2·H2O, it is at high temperature A kind of activating agent, the hardness, abrasion resistance and opaque of glaze paint can be improved, prevent the cracking of glaze paint.
Embodiment 2
A kind of red glaze of an ancient unit of weight, is prepared by the raw material of following parts by weight：7 parts of this medicine, 43 parts of melilite, quartzy 10 parts, calcite 13 parts, 10 parts of kaolin, 2.5 parts of block tin, 3.5 parts of Copper Ores, 1 part of iron ore, 7 parts of talcum, 3 parts of bone ash.
The preparation method of the above-mentioned red glaze of an ancient unit of weight, comprises the following steps：
（1）The preparation of glaze slip：1. the kaolin of above-mentioned parts by weight, talcum is taken to calcine 25min at 950 DEG C；2. after calcining Kaolin, talcum and above-mentioned other raw material mixing, ball milling, sievings, that is, obtain the glaze slip that mass concentration is 55%；
（2）Glazing：Base substrate is immersed into step（1）In take out for a moment in obtained glaze slip, be again dipped into a moment, take out, utilize base The water imbibition of body, makes glaze slip uniformly be attached to billet surface.
（3）Burn till, 1290 DEG C of firing temperature.
Firing process specifically comprises the following steps：
1. the oxidizing flame stage：Base substrate after glazing is put into kiln, is fired under oxidizing atmosphere, temperature is ramped up in 4h 1000℃；
2. the reducing flame stage：Under reducing atmosphere, temperature is made to be ramped up 1290 DEG C in 7h from 1000 DEG C；
3. cooling stage：Room temperature is naturally cooled to, is made.
The present invention is not added with any chemical substance compared with prior art, in formula, utilizes a variety of hairs contained in ore Color substance carries out color development, makes color development more natural, and by scientific and reasonable raw material proportioning and control burning process, prepares The red glaze jade texture of an ancient unit of weight and opaque are strong, high yield rate, up to more than 90%.
Embodiment 3
A kind of red glaze of an ancient unit of weight, is prepared by the raw material of following parts by weight：7.5 parts of this medicine, 42 parts of melilite, quartz 11 parts, Fang Xie 14 parts of stone, 10 parts of kaolin, 2.5 parts of block tin, 3.6 parts of Copper Ores, 1.1 parts of iron ore, 7 parts of talcum, 3 parts of bone ash.
The preparation method of the above-mentioned red glaze of an ancient unit of weight, comprises the following steps：
（1）The preparation of glaze slip：1. the kaolin of above-mentioned parts by weight, talcum is taken to calcine 27min at 940 DEG C；2. after calcining Kaolin, talcum and above-mentioned other raw material mixing, ball milling, sievings, that is, obtain the glaze slip that mass concentration is 56%；
（2）Glazing：Base substrate is immersed into step（1）In take out for a moment in obtained glaze slip, be again dipped into a moment, take out, utilize base The water imbibition of body, makes glaze slip uniformly be attached to billet surface.
（3）Burn till, 1300 DEG C of firing temperature.
Firing process specifically comprises the following steps：
1. the oxidizing flame stage：Base substrate after glazing is put into kiln, is fired under oxidizing atmosphere, temperature is ramped up in 4.5h 990℃；
2. the reducing flame stage：Under reducing atmosphere, temperature is made to be ramped up 1300 DEG C in 7.5h from 990 DEG C；
3. cooling stage：Room temperature is naturally cooled to, is made.
The present invention is not added with any chemical substance compared with prior art, in formula, utilizes a variety of hairs contained in ore Color substance carries out color development, makes color development more natural, and by scientific and reasonable raw material proportioning and control burning process, prepares The red glaze jade texture of an ancient unit of weight and opaque are strong, high yield rate, up to more than 89%.
Comparative example 1
A kind of red glaze of an ancient unit of weight, is prepared by the raw material of following parts by weight：7 parts of this medicine, 43 parts of melilite, quartzy 10 parts, calcite 13 parts, 10 parts of kaolin, 2.5 parts of block tin, 3.5 parts of Copper Ores, 1 part of iron ore, 7 parts of talcum, 3 parts of bone ash.
The preparation method of the above-mentioned red glaze of an ancient unit of weight, comprises the following steps：
（1）The preparation of glaze slip：1. the kaolin of above-mentioned parts by weight, talcum is taken to calcine 25min at 950 DEG C；2. after calcining Kaolin, talcum and above-mentioned other raw material mixing, ball milling, sievings, that is, obtain the glaze slip that mass concentration is 55%；
（2）Glazing：Base substrate is immersed into step（1）In take out for a moment in obtained glaze slip, be again dipped into a moment, take out, utilize base The water imbibition of body, makes glaze slip uniformly be attached to billet surface.
（3）Burn till, 1290 DEG C of firing temperature.
Firing process specifically comprises the following steps：
1. the oxidizing flame stage：Base substrate after glazing is put into kiln, is fired under oxidizing atmosphere, temperature is ramped up in 4h 950℃；
2. the reducing flame stage：Under reducing atmosphere, temperature is made to be ramped up 1290 DEG C in 7h from 950 DEG C；
3. cooling stage：Room temperature is naturally cooled to, is made.
The glaze formula of this comparative example is with embodiment 2, and compared with embodiment 2, initial reduction temperature changes specific preparation method Be changed into 950 DEG C, the glaze glaze colours burnt out for blueness or violet tint, yield rate 85%.
The formula for the red glaze of an ancient unit of weight that 4-25 of the embodiment of the present invention is provided is shown in Table 1-3.
Table 1
Table 2
Table 3

Claims (4)

1. a kind of red glaze of an ancient unit of weight, it is characterised in that be prepared by the raw material of following parts by weight：This medicine 6-8 parts, melilite 40-46 Part, quartzy 7-13 parts, calcite 10-16 parts, kaolin 8-12 parts, block tin 2-3 parts, Copper Ores 3-4 parts, iron ore 0.75- 1.25 parts, talcum 6-8 parts, bone ash 2.5-3.5 parts.
2. the red glaze of an ancient unit of weight as claimed in claim 1, it is characterised in that it is prepared by the raw material of following parts by weight：This medicine 7 Part, 43 parts of melilite, quartz 10 parts, 13 parts of calcite, 10 parts of kaolin, 2.5 parts of block tin, 3.5 parts of Copper Ores, 1 part of iron ore, 7 parts of talcum, 3 parts of bone ash.
3. the preparation method of the red glaze of an ancient unit of weight as described in claim any one of 1-2, it is characterised in that comprise the following steps：
（1）The preparation of glaze slip；
（2）Glazing；
（3）Burn till, 1280-1300 DEG C of firing temperature.
4. the preparation method of the red glaze of an ancient unit of weight as claimed in claim 3, it is characterised in that step（3）In firing process specifically include Following steps：1. the oxidizing flame stage：Base substrate after glazing is put into kiln, is fired under oxidizing atmosphere, makes temperature equal in 3-5h It is ramped up 980-1020 DEG C；2. the reducing flame stage：Under reducing atmosphere, temperature is made to be ramped up 1280-1300 DEG C in 6-8h；③ Cooling stage：Room temperature is naturally cooled to, is made.
CN201710915756.2A 2017-09-30 2017-09-30 A kind of red glaze of an ancient unit of weight and preparation method thereof Withdrawn CN107500544A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108585506A (en) * 2018-07-30 2018-09-28 赵红刚 A kind of red chun glaze and preparation method thereof
CN109052951A (en) * 2018-09-30 2018-12-21 张丹丹 A kind of photochromic pottery glaze and preparation method thereof
CN112299716A (en) * 2020-12-01 2021-02-02 禹州市神器钧窑有限公司 Jun porcelain copper red glaze and preparation method thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108585506A (en) * 2018-07-30 2018-09-28 赵红刚 A kind of red chun glaze and preparation method thereof
CN109052951A (en) * 2018-09-30 2018-12-21 张丹丹 A kind of photochromic pottery glaze and preparation method thereof
CN109052951B (en) * 2018-09-30 2021-01-15 张丹丹 Photochromic jun porcelain glaze and preparation method thereof
CN112299716A (en) * 2020-12-01 2021-02-02 禹州市神器钧窑有限公司 Jun porcelain copper red glaze and preparation method thereof

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