CN107475843B - A kind of processing technology of cotton fiber and metal wire mixed yarn - Google Patents
A kind of processing technology of cotton fiber and metal wire mixed yarn Download PDFInfo
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- CN107475843B CN107475843B CN201710853712.1A CN201710853712A CN107475843B CN 107475843 B CN107475843 B CN 107475843B CN 201710853712 A CN201710853712 A CN 201710853712A CN 107475843 B CN107475843 B CN 107475843B
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- cotton fiber
- wire
- mixed yarn
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- metal wire
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- 229920000742 Cotton Polymers 0.000 title claims abstract description 64
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 29
- 239000002184 metal Substances 0.000 title claims abstract description 29
- 238000005516 engineering process Methods 0.000 title claims abstract description 20
- 238000002360 preparation method Methods 0.000 claims abstract description 26
- 238000001035 drying Methods 0.000 claims abstract description 20
- 238000000034 method Methods 0.000 claims abstract description 13
- 238000007493 shaping process Methods 0.000 claims abstract description 13
- 230000008569 process Effects 0.000 claims abstract description 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 47
- 238000011282 treatment Methods 0.000 claims description 29
- 235000019441 ethanol Nutrition 0.000 claims description 24
- 239000010935 stainless steel Substances 0.000 claims description 24
- 229910001220 stainless steel Inorganic materials 0.000 claims description 24
- 229910000831 Steel Inorganic materials 0.000 claims description 18
- 239000010959 steel Substances 0.000 claims description 18
- 229910045601 alloy Inorganic materials 0.000 claims description 16
- 239000000956 alloy Substances 0.000 claims description 16
- 238000000498 ball milling Methods 0.000 claims description 16
- 239000007788 liquid Substances 0.000 claims description 16
- 239000000463 material Substances 0.000 claims description 16
- 239000000203 mixture Substances 0.000 claims description 15
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 12
- 238000000227 grinding Methods 0.000 claims description 9
- 239000002994 raw material Substances 0.000 claims description 9
- 238000005245 sintering Methods 0.000 claims description 9
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 8
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 8
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 8
- 235000021355 Stearic acid Nutrition 0.000 claims description 8
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 8
- 238000007664 blowing Methods 0.000 claims description 8
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 8
- 239000000839 emulsion Substances 0.000 claims description 8
- 239000004519 grease Substances 0.000 claims description 8
- 239000012535 impurity Substances 0.000 claims description 8
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 claims description 8
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 claims description 8
- 239000004576 sand Substances 0.000 claims description 8
- 229920002545 silicone oil Polymers 0.000 claims description 8
- 239000008117 stearic acid Substances 0.000 claims description 8
- 238000004804 winding Methods 0.000 claims description 8
- 238000005491 wire drawing Methods 0.000 claims description 8
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims description 7
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims description 7
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims description 7
- 238000010792 warming Methods 0.000 claims description 7
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 claims description 5
- 229910001928 zirconium oxide Inorganic materials 0.000 claims description 5
- 238000004513 sizing Methods 0.000 claims description 2
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 4
- 239000004744 fabric Substances 0.000 abstract description 3
- 239000002932 luster Substances 0.000 abstract description 2
- 230000000052 comparative effect Effects 0.000 description 5
- 235000016068 Berberis vulgaris Nutrition 0.000 description 3
- 241000335053 Beta vulgaris Species 0.000 description 3
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 3
- 239000003513 alkali Substances 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 3
- 230000008859 change Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- 230000005855 radiation Effects 0.000 description 2
- FFRBMBIXVSCUFS-UHFFFAOYSA-N 2,4-dinitro-1-naphthol Chemical compound C1=CC=C2C(O)=C([N+]([O-])=O)C=C([N+]([O-])=O)C2=C1 FFRBMBIXVSCUFS-UHFFFAOYSA-N 0.000 description 1
- 241000193830 Bacillus <bacterium> Species 0.000 description 1
- 241000588724 Escherichia coli Species 0.000 description 1
- 235000009754 Vitis X bourquina Nutrition 0.000 description 1
- 235000012333 Vitis X labruscana Nutrition 0.000 description 1
- 235000014787 Vitis vinifera Nutrition 0.000 description 1
- 240000006365 Vitis vinifera Species 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000003899 bactericide agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 230000005670 electromagnetic radiation Effects 0.000 description 1
- 238000010828 elution Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- -1 polyethylene pyrrole Polymers 0.000 description 1
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 238000009987 spinning Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
- D02G3/04—Blended or other yarns or threads containing components made from different materials
-
- B22F1/0003—
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
- B22F3/12—Both compacting and sintering
- B22F3/14—Both compacting and sintering simultaneously
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/02—Yarns or threads characterised by the material or by the materials from which they are made
- D02G3/12—Threads containing metallic filaments or strips
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/44—Yarns or threads characterised by the purpose for which they are designed
- D02G3/441—Yarns or threads with antistatic, conductive or radiation-shielding properties
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/44—Yarns or threads characterised by the purpose for which they are designed
- D02G3/449—Yarns or threads with antibacterial properties
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/188—Monocarboxylic acids; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/46—Compounds containing quaternary nitrogen atoms
- D06M13/463—Compounds containing quaternary nitrogen atoms derived from monoamines
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/356—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of other unsaturated compounds containing nitrogen, sulfur, silicon or phosphorus atoms
- D06M15/3562—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of other unsaturated compounds containing nitrogen, sulfur, silicon or phosphorus atoms containing nitrogen
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/50—Modified hand or grip properties; Softening compositions
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2201/00—Cellulose-based fibres, e.g. vegetable fibres
- D10B2201/01—Natural vegetable fibres
- D10B2201/02—Cotton
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Microbiology (AREA)
- Manufacturing & Machinery (AREA)
- Artificial Filaments (AREA)
- Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
Abstract
The invention discloses the processing technologys of a kind of cotton fiber and metal wire mixed yarn, are related to scribbled technical field.The processing technology of cotton fiber and metal wire mixed yarn of the invention, comprising the following steps: (1) prepared by wire;(2) preparation of cotton fiber;(3) blended;(4) soften drying and shaping.The simple process is controllable, and without harsh high-temperature and high-pressure conditions, the scribbled of preparation has beautiful metallic luster, and anti-electromagnetic-radiation, antistatic, excellent antibacterial performance, comfortable ventilating;Softening drying and shaping has improved the color fastness of cotton fiber, pliability, alleviates the harsh feeling of fabric, high resilience and strength.
Description
Technical field:
The present invention relates to scribbled technical fields, and in particular to a kind of processing work of cotton fiber and metal wire mixed yarn
Skill.
Background technique:
Metal is pumped into filament using special process by metal wire mixed yarn, fineness can with it is various in textile raw material
The fineness of fiber compares favourably, and flexibility is fine, but spinnability is poor, and wire and cotton, animal origin, chemical fibre class raw material are spun one
It rises, like a metal mesh, metal itself has a reflection function to electromagnetic wave, in this way the fabric that is made into of the yarn made of wire
It is just provided with the function of anti-electromagnetic radiation, and there is gas permeability and warmth retention property possessed by cotton, animal origin, dress is relaxed
It is suitable, it is without side-effects to human body.
Current metal wire mixed spinning Wiring technology needs the process conditions of high temperature and pressure to can be only achieved production effect mostly, raw
Produce at high cost, and yarn evenness is uneven, and pilling fluffing resistant performance is poor, needs further to be studied.
Summary of the invention:
Technical problem to be solved by the present invention lies in providing the processing technology of a kind of cotton fiber and metal wire mixed yarn,
So that scribbled has good anti-electromagnetic radiation, antistatic, wear-resisting, corrosion resistance, and simple process is controllable.
The following technical solution is employed for the technical problems to be solved by the invention to realize:
A kind of processing technology of cotton fiber and metal wire mixed yarn, comprising the following steps:
(1) prepared by wire: stainless steel comminuted steel shot precomminution to 100~200 mesh being added in planetary type ball-milling tank, is added
The mill ball having a size of 20~30mm, heating is added according to 40~50:1 of ratio of grinding media to material in the ethyl alcohol of 5~10 times of stainless steel comminuted steel shot quality
To 35~45 DEG C, ball milling 12~16 hours under the revolving speed of 400~600r/min;After being cooled to room temperature, by copper powder, zinc powder,
Cobalt powder, nickel powder, graphite powder are added in ball grinder according to mass ratio 3:1:1:1:0.2, in room temperature, the revolving speed of 200~300r/min
Lower grinding obtains mixture in 20~22 hours;Ethanol rinse mixture 3~5 times, removing ethyl alcohol is concentrated under reduced pressure and obtains siccative;Siccative
Alloy is obtained in 1300~1500 DEG C of hot pressed sinterings;Alloy obtains wire using single wire drawing;
(2) preparation of cotton fiber: the cotton of function admirable is selected successively to carry out blowing, combing, in combing process, under comb
Cotton fiber is made in 35~38% short flannel and impurity;
(3) blended: cotton fiber prepared by the wire of step (1) preparation, step (2) is according to mass ratio 1:20~30
It carries out blended, successively carries out three draftings, rove, spun yarn, automatic winding, Cheng Bao, obtain scribbled;
(4) soften drying and shaping: scribbled being put into soft treatment liquid and carries out sofening treatment, is placed into dryer
Drying and processing is finally putting into forming machine and carries out shaping processing.
Preferably, step (1) ball grinder is identical as the material of mill ball, is stainless steel, zirconium oxide or agate.
Preferably, the drafting gauge of the cotton fiber and wire is 46~52mm, and when three draftings ensures that temperature is greater than
25 DEG C, humidity is greater than 70%.
Preferably, the coarse sand, spun yarn operate according to the intensity requirement of mixed yarn, and periodically wipe grease.
Preferably, the soft treatment liquid includes the raw material of following parts by weight: 40~60 parts of polyaminoester emulsion, polyethylene pyrrole
10~20 parts of pyrrolidone, 3~8 parts of silicone oil, 2~6 parts of stearic acid, 1~3 part of empgen BB.
Preferably, step (4) drying is 2~3 hours dry for 130~150 DEG C.
Preferably, the temperature of the sizing is 160~180 DEG C, and the movement speed of forming machine is 25~30m/min.
The beneficial effects of the present invention are: the processing technology of 1, cotton fiber of the invention and metal wire mixed yarn, simply may be used
Control, without harsh high-temperature and high-pressure conditions, the scribbled of preparation has beautiful metallic luster, and anti-electromagnetic-radiation, anti-
Electrostatic, excellent antibacterial performance, comfortable ventilating.
2, in wire preparation of the invention, using stainless steel comminuted steel shot as main component, it joined raising toughness, corrosion-resistant
Property, the copper powder of intensity, zinc powder, cobalt powder, nickel powder, graphite powder, hot pressed sintering, after monofilament drawing, obtained wire mechanical performance
Excellent, machinability is strong.
3, softening drying and shaping of the invention has improved color fastness, the pliability of cotton fiber, has alleviated fabric
Harsh feeling, high resilience and strength.
4, soft treatment liquid of the invention is point with the good polyaminoester emulsion of safe and reliable, good mechanical performance, compatibility
Granular media system, is added the polyvinylpyrrolidone of excellent bonding, moisture absorption, coherency, and it is soft to stablize polishing for antibacterial, corrosion resistant silicone oil
The stearic acid and wide-spectrum bactericide empgen BB of change, substantially increase arrangement softening performance.
Specific embodiment:
In order to be easy to understand the technical means, the creative features, the aims and the efficiencies achieved by the present invention, tie below
Specific embodiment is closed, the present invention is further explained.
Embodiment 1
A kind of processing technology of cotton fiber and metal wire mixed yarn, comprising the following steps:
(1) prepared by wire: stainless steel comminuted steel shot precomminution to 100~200 mesh being added in planetary type ball-milling tank, is added
The ethyl alcohol of 6 times of stainless steel comminuted steel shot quality is added the mill ball having a size of 20~30mm according to ratio of grinding media to material 42:1, is warming up to 40 DEG C,
Ball milling 15 hours under the revolving speed of 480r/min;After being cooled to room temperature, by copper powder, zinc powder, cobalt powder, nickel powder, graphite powder according to
Mass ratio 3:1:1:1:0.2 is added in ball grinder, room temperature, 250r/min revolving speed under grind 20 hours and obtain mixture;Second
Alcohol elutes mixture 3 times, and removing ethyl alcohol is concentrated under reduced pressure and obtains siccative;Siccative obtains alloy in 1365 DEG C of hot pressed sinterings;Alloy is adopted
Wire is obtained with single wire drawing.Wherein, ball grinder is identical as the material of mill ball, is stainless steel.
(2) preparation of cotton fiber: the cotton of function admirable is selected successively to carry out blowing, combing, in combing process, under comb
Cotton fiber is made in 35~38% short flannel and impurity.
(3) blended: the cotton fiber of the wire of step (1) preparation, step (2) preparation is carried out according to mass ratio 1:26
It is blended, three draftings, rove, spun yarn, automatic winding, Cheng Bao are successively carried out, scribbled is obtained.Wherein, cotton fiber and metal
The drafting gauge of silk is 50mm, and when three draftings ensures that temperature is greater than 25 DEG C, and humidity is greater than 70%;Coarse sand, spun yarn are according to blended
The intensity requirement of yarn operates, and periodically wipes grease.
(4) soften drying and shaping: scribbled being put into soft treatment liquid and carries out sofening treatment, is placed into dryer
138 DEG C drying 2.5 hours, be finally putting into forming machine in 172 DEG C of setting treatments.Wherein, soft treatment liquid includes as follows
The raw material of parts by weight: 50 parts of polyaminoester emulsion, 16 parts of polyvinylpyrrolidone, 6 parts of silicone oil, 3 parts of stearic acid, dodecyl beet
1 part of alkali.The movement speed of forming machine is 28m/min.
Embodiment 2
A kind of processing technology of cotton fiber and metal wire mixed yarn, comprising the following steps:
(1) prepared by wire: stainless steel comminuted steel shot precomminution to 100~200 mesh being added in planetary type ball-milling tank, is added
The ethyl alcohol of 8 times of stainless steel comminuted steel shot quality is added the mill ball having a size of 20~30mm according to ratio of grinding media to material 46:1, is warming up to 42 DEG C,
Ball milling 14 hours under the revolving speed of 500r/min;After being cooled to room temperature, by copper powder, zinc powder, cobalt powder, nickel powder, graphite powder according to
Mass ratio 3:1:1:1:0.2 is added in ball grinder, room temperature, 300r/min revolving speed under grind 21 hours and obtain mixture;Second
Alcohol elutes mixture 5 times, and removing ethyl alcohol is concentrated under reduced pressure and obtains siccative;Siccative obtains alloy in 1400 DEG C of hot pressed sinterings;Alloy is adopted
Wire is obtained with single wire drawing.Wherein, ball grinder is identical as the material of mill ball, is zirconium oxide.
(2) preparation of cotton fiber: the cotton of function admirable is selected successively to carry out blowing, combing, in combing process, under comb
Cotton fiber is made in 35~38% short flannel and impurity.
(3) blended: cotton fiber prepared by the wire of step (1) preparation, step (2) is according to mass ratio 1:20~30
It carries out blended, successively carries out three draftings, rove, spun yarn, automatic winding, Cheng Bao, obtain scribbled.Wherein, cotton fiber with
The drafting gauge of wire is 47mm, and when three draftings ensures that temperature is greater than 25 DEG C, and humidity is greater than 70%;Coarse sand, spun yarn according to
The intensity requirement of mixed yarn operates, and periodically wipes grease.
(4) soften drying and shaping: scribbled being put into soft treatment liquid and carries out sofening treatment, is placed into dryer
145 DEG C drying 2.2 hours, be finally putting into forming machine in 172 DEG C of setting treatments.Wherein, soft treatment liquid includes as follows
The raw material of parts by weight: 58 parts of polyaminoester emulsion, 18 parts of polyvinylpyrrolidone, 5 parts of silicone oil, 4 parts of stearic acid, dodecyl beet
2 parts of alkali.The movement speed of forming machine is 30m/min.
Embodiment 3
A kind of processing technology of cotton fiber and metal wire mixed yarn, comprising the following steps:
(1) prepared by wire: stainless steel comminuted steel shot precomminution to 100~200 mesh being added in planetary type ball-milling tank, is added
The ethyl alcohol of 6 times of stainless steel comminuted steel shot quality is added the mill ball having a size of 20~30mm according to ratio of grinding media to material 50:1, is warming up to 45 DEG C,
Ball milling 15 hours under the revolving speed of 600r/min;After being cooled to room temperature, by copper powder, zinc powder, cobalt powder, nickel powder, graphite powder according to
Mass ratio 3:1:1:1:0.2 is added in ball grinder, room temperature, 300r/min revolving speed under grind 20 hours and obtain mixture;Second
Alcohol elutes mixture 4 times, and removing ethyl alcohol is concentrated under reduced pressure and obtains siccative;Siccative obtains alloy in 1450 DEG C of hot pressed sinterings;Alloy is adopted
Wire is obtained with single wire drawing.Wherein, ball grinder is identical as the material of mill ball, is stainless steel, zirconium oxide or agate.
(2) preparation of cotton fiber: the cotton of function admirable is selected successively to carry out blowing, combing, in combing process, under comb
Cotton fiber is made in 35~38% short flannel and impurity.
(3) blended: cotton fiber prepared by the wire of step (1) preparation, step (2) is according to mass ratio 1:20~30
It carries out blended, successively carries out three draftings, rove, spun yarn, automatic winding, Cheng Bao, obtain scribbled.Wherein, cotton fiber with
The drafting gauge of wire is 46~52mm, and when three draftings ensures that temperature is greater than 25 DEG C, and humidity is greater than 70%;Coarse sand, spun yarn
It is operated according to the intensity requirement of mixed yarn, and periodically wipes grease.
(4) soften drying and shaping: scribbled being put into soft treatment liquid and carries out sofening treatment, is placed into dryer
150 DEG C drying 2 hours, be finally putting into forming machine in 180 DEG C of setting treatments.Wherein, soft treatment liquid includes following weight
Measure the raw material of part: 60 parts of polyaminoester emulsion, 20 parts of polyvinylpyrrolidone, 7 parts of silicone oil, 5 parts of stearic acid, empgen BB
3 parts.The movement speed of forming machine is 30m/min.
Embodiment 4
A kind of processing technology of cotton fiber and metal wire mixed yarn, comprising the following steps:
(1) prepared by wire: stainless steel comminuted steel shot precomminution to 100~200 mesh being added in planetary type ball-milling tank, is added
The ethyl alcohol of 10 times of stainless steel comminuted steel shot quality is added the mill ball having a size of 25mm according to ratio of grinding media to material 50:1, is warming up to 42 DEG C, In
Ball milling 14 hours under the revolving speed of 600r/min;After being cooled to room temperature, by copper powder, zinc powder, cobalt powder, nickel powder, graphite powder according to matter
Amount is added in ball grinder than 3:1:1:1:0.2, room temperature, 300r/min revolving speed under grind 21 hours and obtain mixture;Ethyl alcohol
Elution mixture 5 times is concentrated under reduced pressure removing ethyl alcohol and obtains siccative;Siccative obtains alloy in 1500 DEG C of hot pressed sinterings;Alloy uses
Single wire drawing obtains wire.Wherein, ball grinder is identical as the material of mill ball, is stainless steel, zirconium oxide or agate.
(2) preparation of cotton fiber: the cotton of function admirable is selected successively to carry out blowing, combing, in combing process, under comb
Cotton fiber is made in 35~38% short flannel and impurity.
(3) blended: the cotton fiber of the wire of step (1) preparation, step (2) preparation is carried out according to mass ratio 1:20
It is blended, three draftings, rove, spun yarn, automatic winding, Cheng Bao are successively carried out, scribbled is obtained.Wherein, cotton fiber and metal
The drafting gauge of silk is 52mm, and when three draftings ensures that temperature is greater than 25 DEG C, and humidity is greater than 70%;Coarse sand, spun yarn are according to blended
The intensity requirement of yarn operates, and periodically wipes grease.
(4) soften drying and shaping: scribbled being put into soft treatment liquid and carries out sofening treatment, is placed into dryer
150 DEG C drying 2 hours, be finally putting into forming machine in 180 DEG C of setting treatments.Wherein, soft treatment liquid includes following weight
Measure the raw material of part: 60 parts of polyaminoester emulsion, 20 parts of polyvinylpyrrolidone, 6 parts of silicone oil, 5 parts of stearic acid, empgen BB
3 parts.The movement speed of forming machine is 26m/min.
Comparative example 1
A kind of processing technology of cotton fiber and metal wire mixed yarn, comprising the following steps:
(1) prepared by wire: stainless steel comminuted steel shot precomminution to 100~200 mesh being added in planetary type ball-milling tank, is added
The ethyl alcohol of 6 times of stainless steel comminuted steel shot quality is added the mill ball having a size of 20~30mm according to ratio of grinding media to material 42:1, is warming up to 40 DEG C,
Ball milling 15 hours under the revolving speed of 480r/min;Ethanol rinse mixture 3 times, removing ethyl alcohol is concentrated under reduced pressure and obtains siccative;Siccative
Alloy is obtained in 1365 DEG C of hot pressed sinterings;Alloy obtains wire using single wire drawing.Wherein, the material of ball grinder and mill ball
Matter is identical, is stainless steel.
(2) preparation of cotton fiber: the cotton of function admirable is selected successively to carry out blowing, combing, in combing process, under comb
Cotton fiber is made in 35~38% short flannel and impurity.
(3) blended: the cotton fiber of the wire of step (1) preparation, step (2) preparation is carried out according to mass ratio 1:26
It is blended, three draftings, rove, spun yarn, automatic winding, Cheng Bao are successively carried out, scribbled is obtained.Wherein, cotton fiber and metal
The drafting gauge of silk is 50mm, and when three draftings ensures that temperature is greater than 25 DEG C, and humidity is greater than 70%;Coarse sand, spun yarn are according to blended
The intensity requirement of yarn operates, and periodically wipes grease.
(4) soften drying and shaping: scribbled being put into soft treatment liquid and carries out sofening treatment, is placed into dryer
138 DEG C drying 2.5 hours, be finally putting into forming machine in 172 DEG C of setting treatments.Wherein, soft treatment liquid includes as follows
The raw material of parts by weight: 50 parts of polyaminoester emulsion, 16 parts of polyvinylpyrrolidone, 6 parts of silicone oil, 3 parts of stearic acid, dodecyl beet
1 part of alkali.The movement speed of forming machine is 28m/min.
Comparative example 2
A kind of processing technology of cotton fiber and metal wire mixed yarn, comprising the following steps:
(1) prepared by wire: stainless steel comminuted steel shot precomminution to 100~200 mesh being added in planetary type ball-milling tank, is added
The ethyl alcohol of 6 times of stainless steel comminuted steel shot quality is added the mill ball having a size of 20~30mm according to ratio of grinding media to material 42:1, is warming up to 40 DEG C,
Ball milling 15 hours under the revolving speed of 480r/min;After being cooled to room temperature, by copper powder, zinc powder, cobalt powder, nickel powder, graphite powder according to
Mass ratio 3:1:1:1:0.2 is added in ball grinder, room temperature, 250r/min revolving speed under grind 20 hours and obtain mixture;Second
Alcohol elutes mixture 3 times, and removing ethyl alcohol is concentrated under reduced pressure and obtains siccative;Siccative obtains alloy in 1365 DEG C of hot pressed sinterings;Alloy is adopted
Wire is obtained with single wire drawing.Wherein, ball grinder is identical as the material of mill ball, is stainless steel.
(2) preparation of cotton fiber: the cotton of function admirable is selected successively to carry out blowing, combing, in combing process, under comb
Cotton fiber is made in 35~38% short flannel and impurity.
(3) blended: the cotton fiber of the wire of step (1) preparation, step (2) preparation is carried out according to mass ratio 1:26
It is blended, three draftings, rove, spun yarn, automatic winding, Cheng Bao are successively carried out, scribbled is obtained.Wherein, cotton fiber and metal
The drafting gauge of silk is 50mm, and when three draftings ensures that temperature is greater than 25 DEG C, and humidity is greater than 70%;Coarse sand, spun yarn are according to blended
The intensity requirement of yarn operates, and periodically wipes grease.
(4) drying and shaping: being put into 138 DEG C drying 2.5 hours in dryer for scribbled, be finally putting into forming machine in
172 DEG C of setting treatments.
Performance test: to the scribbled of above-described embodiment, comparative example preparation, the shielding rate under 1500MHz has been carried out
Test, the test to golden yellow grape bacillus, Escherichia coli bacteriostasis rate, the test of elongation at break, tensile strength, concrete outcome
It see the table below:
As can be seen from the above table, scribbled prepared by the processing technology of cotton fiber of the invention and metal wire mixed yarn
With excellent ELECTROMAGNETIC RADIATION SHIELDING rate, bacteriostasis rate, breaking strength, tensile strength, can be seen that from comparative example 1, comparative example 2
Metal powder additive in stainless steel powder substantially improves mechanical property, and soft treatment liquid also improves the synthesis of scribbled
Performance.
The above shows and describes the basic principles and main features of the present invention and the advantages of the present invention.The technology of the industry
Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and the above embodiments and description only describe this
The principle of invention, without departing from the spirit and scope of the present invention, various changes and improvements may be made to the invention, these changes
Change and improvement all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appended claims and its
Equivalent thereof.
Claims (4)
1. the processing technology of a kind of cotton fiber and metal wire mixed yarn, it is characterised in that: the following steps are included:
(1) prepared by wire: stainless steel comminuted steel shot precomminution to 100~200 mesh being added in planetary type ball-milling tank, is added stainless
The ethyl alcohol of 5~10 times of steel comminuted steel shot quality is added the mill ball having a size of 20~30mm according to 40~50:1 of ratio of grinding media to material, is warming up to 35
~45 DEG C, ball milling 12~16 hours under the revolving speed of 400~600r/min;After being cooled to room temperature, by copper powder, zinc powder, cobalt powder,
Nickel powder, graphite powder according to mass ratio 3:1:1:1:0.2 be added ball grinder in, room temperature, 200~300r/min revolving speed under grind
Obtain mixture within 20~22 hours;Ethanol rinse mixture 3~5 times, removing ethyl alcohol is concentrated under reduced pressure and obtains siccative;Siccative is in 1300
~1500 DEG C of hot pressed sinterings obtain alloy;Alloy obtains wire using single wire drawing;
(2) preparation of cotton fiber: selecting the cotton of function admirable successively to carry out blowing, combing, in combing process, comb lower 35~
Cotton fiber is made in 38% short flannel and impurity;
(3) blended: the cotton fiber of the wire of step (1) preparation, step (2) preparation is carried out according to mass ratio 1:20~30
It is blended, three draftings, rove, spun yarn, automatic winding, Cheng Bao are successively carried out, scribbled is obtained;
(4) soften drying and shaping: scribbled being put into soft treatment liquid and carries out sofening treatment, places into dryer and dries
Processing, is finally putting into forming machine and carries out shaping processing;
The soft treatment liquid includes the raw material of following parts by weight: 40~60 parts of polyaminoester emulsion, polyvinylpyrrolidone 10~
20 parts, 3~8 parts of silicone oil, 2~6 parts of stearic acid, 1~3 part of empgen BB;
Step (4) drying is 2~3 hours dry for 130~150 DEG C;
The temperature of the sizing is 160~180 DEG C, and the movement speed of forming machine is 25~30m/min.
2. the processing technology of cotton fiber according to claim 1 and metal wire mixed yarn, it is characterised in that: the step
(1) ball grinder is identical as the material of mill ball, is stainless steel, zirconium oxide or agate.
3. the processing technology of cotton fiber according to claim 1 and metal wire mixed yarn, it is characterised in that: the cotton is fine
Dimension and the drafting gauge of wire are 46~52mm, and when three draftings ensures that temperature is greater than 25 DEG C, and humidity is greater than 70%.
4. the processing technology of cotton fiber according to claim 1 and metal wire mixed yarn, it is characterised in that: described thick
Sand, spun yarn operate according to the intensity requirement of mixed yarn, and periodically wipe grease.
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CN109652883B (en) * | 2019-01-23 | 2021-06-08 | 江南大学 | Production method of cotton and stainless steel hybrid yarn for electromagnetic shielding |
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JPH07157934A (en) * | 1993-12-08 | 1995-06-20 | Toyobo Co Ltd | Special spun yarn and its production |
ITBS20040008A1 (en) * | 2004-01-20 | 2004-04-20 | Aldo Ribezzo | APPARATUS AND METHOD FOR THE REALIZATION OF A MANUFACTURE INCLUDING AT LEAST A PORTION IN METALLIC WIRE AND MANUFACTURE OBTAINABLE THROUGH THIS METHOD |
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CN102704110A (en) * | 2012-05-29 | 2012-10-03 | 山东来利来毛纺有限公司 | Textile made of metal wire blended yarns |
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