CN107471780B - Automatically cleaning anticorrosion self-adhesive modified asphalt waterproof rolling material - Google Patents
Automatically cleaning anticorrosion self-adhesive modified asphalt waterproof rolling material Download PDFInfo
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- CN107471780B CN107471780B CN201610408002.3A CN201610408002A CN107471780B CN 107471780 B CN107471780 B CN 107471780B CN 201610408002 A CN201610408002 A CN 201610408002A CN 107471780 B CN107471780 B CN 107471780B
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B11/00—Layered products comprising a layer of bituminous or tarry substances
- B32B11/04—Layered products comprising a layer of bituminous or tarry substances comprising such bituminous or tarry substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B11/046—Layered products comprising a layer of bituminous or tarry substances comprising such bituminous or tarry substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/28—Layered products comprising a layer of synthetic resin comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42
- B32B27/283—Layered products comprising a layer of synthetic resin comprising synthetic resins not wholly covered by any one of the sub-groups B32B27/30 - B32B27/42 comprising polysiloxanes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/38—Layered products comprising a layer of synthetic resin comprising epoxy resins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B33/00—Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2250/00—Layers arrangement
- B32B2250/05—5 or more layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/714—Inert, i.e. inert to chemical degradation, corrosion
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/714—Inert, i.e. inert to chemical degradation, corrosion
- B32B2307/7145—Rot proof, resistant to bacteria, mildew, mould, fungi
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/73—Hydrophobic
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/754—Self-cleaning
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Abstract
The present invention relates to a kind of automatically cleaning anticorrosion self-adhesive modified asphalt waterproof rolling materials, belong to construction waterproofing engineering technical field.The automatically cleaning anticorrosion self-adhesive modified asphalt waterproof rolling material; including tire base; the upper and lower surface of tire base is impregnated with the SBS self-adhered modified bitumen adhesive bed of material and the lower SBS self-adhered modified bitumen adhesive bed of material respectively; the top of the upper SBS self-adhered modified bitumen adhesive bed of material is successively covered with corrosion-resistant coating and super-hydrophobic automatic cleaning layer, and the outside of the lower SBS self-adhered modified bitumen adhesive bed of material is covered with protective layer.The present invention solve waterproof strength existing for existing waterproof roll is low, service life is short, there are environmental pollution, the problems such as Corrosion Protection is poor, construction is dangerous, with excellent self-cleaning property, waterproofness and anticorrosive property, the intensity and waterproof performance of waterproof layer are high, and the growth of bacterium, long service life can be effectively prevent.
Description
Technical field
The present invention relates to a kind of automatically cleaning anticorrosion self-adhesive modified asphalt waterproof rolling materials, belong to construction waterproofing engineering technology neck
Domain.
Background technique
With the development of economy with the progress in epoch, requirement of the modern society to construction material is higher and higher, original to build
Build the demand that material has been unable to meet era development.Many buildings are all to reduce service life because of the erosion of water.With
Requirement of the people to building service life it is higher and higher, requirement of the people to waterproof material quality is also increasingly paid attention to.Mesh
Before, domestic elastomer modified asphalt waterproof roll is still main product, especially exposed in roofing in use, its superior resistance to height
Warm nature can be that other materials is difficult to replace, however, elastomer modified asphalt waterproof roll is applied applying man-hour requirement and carry out hot melt
Work, blowtorch baking when open fire presence can generate great fire hazard, and in baking process the burning of surface PE film and
Partially modified asphalt size causes seriously to pollute since heat resolve can generate dioxin, hydrocarbons etc., to environment.
Self-adhesive coiled material be it is a kind of can room temperature construction, do not need the waterproof material of hot melt application, it is deep at present by market blueness
It looks at, rate of rise is far more than elastomer modified asphalt waterproof roll, and the waterproof of common self-adhesive modified asphalt waterproof rolling material
Layer limited strength, and bacterium easy to breed is used for a long time, and service life is low, Corrosion Protection is undesirable.
Summary of the invention
The object of the present invention is to provide a kind of automatically cleaning anticorrosion self-adhesive modified asphalt waterproof rolling materials, solve existing waterproof
Waterproof strength existing for coiled material is low, service life is short, there are environmental pollution, the problems such as Corrosion Protection is poor, construction is dangerous, tool
There are excellent self-cleaning property, waterproofness and anticorrosive property.
Automatically cleaning anticorrosion self-adhesive modified asphalt waterproof rolling material of the present invention, including tire base, tire base up and down
Surface is impregnated with the SBS self-adhered modified bitumen adhesive bed of material and the lower SBS self-adhered modified bitumen adhesive bed of material respectively, and upper SBS is from adhered modification
The top of the asphalt adhesive bed of material is successively covered with corrosion-resistant coating and super-hydrophobic automatic cleaning layer, the lower SBS self-adhered modified bitumen adhesive bed of material it is outer
Portion is covered with protective layer.
Wherein:
The upper SBS self-adhered modified bitumen adhesive bed of material and the lower SBS self-adhered modified bitumen adhesive bed of material are by following parts by weight
Several raw materials are made:
The tire base is made of polyester blank or glass fiber blank.
The tire base with a thickness of 5-8mm;The thickness of super-hydrophobic automatic cleaning layer is 3-5mm;The thickness of corrosion-resistant coating
For 3-5mm;The thickness of the upper SBS self-adhered modified bitumen adhesive bed of material and the lower SBS self-adhered modified bitumen adhesive bed of material is 3-5mm;Protection
Layer with a thickness of 2-3mm.
The super-hydrophobic automatic cleaning layer is super-hydrophobic polypropylene film.
The corrosion-resistant coating is epoxy resin corrosion-resistant coating.
The tackifying resin is prepared from the following raw materials in parts by weight:
10-30 parts of coumarone indene resin
10-30 parts of terpene resin
Nine resin of carbon is 10-30 parts.
The protective layer is antiseize silicone oil isolation film.
The upper SBS self-adhered modified bitumen adhesive bed of material and the lower SBS self-adhered modified bitumen adhesive bed of material are by following preparation side
Method is made: first I type waterproof roll pitch heated, then aromatic naphtha and vinyl bis-stearamides are added thereto, stirring
Then cooling after uniformly is added SBS and is heated up, stirred, then proceedes to that tackifying resin is added and shoddy is stirred, finally
Nanometer calcium carbonate is added to be stirred, can be obtained.
Wherein, preferred technical solution is as follows:
(1) I type waterproof roll pitch is heated to 190-200 DEG C;Aromatic naphtha and vinyl bis-stearamides stirring is added
180-190 DEG C is cooled to after uniformly;190-200 DEG C is warming up to after SBS is added;
(2) it is added after SBS is heated up and stirs 1.5h;0.5h is stirred after tackifying resin and shoddy is added;It is eventually adding
Nanometer calcium carbonate stirs 0.5h.
Wettability is an important feature of the surface of solids, it is considered that, 150 ° of contact angle > in the surface of solids of water
When, which is in super-hydrophobic state.It was verified that super hydrophobic surface not only has a self-cleaning function, but also have anticorrosion,
The functions such as waterproof, antifog, anti-pollution.Therefore, it is with a wide range of applications.
Beneficial effects of the present invention are as follows:
Automatically cleaning anticorrosion self-adhesive modified asphalt waterproof rolling material of the invention has excellent self-cleaning property, waterproofness and prevents
Corrosivity, the intensity and waterproof performance of waterproof layer are high, and can effectively prevent the growth of bacterium, long service life.
Detailed description of the invention
Fig. 1 is structural schematic diagram of the invention.
In figure: 1, super-hydrophobic automatic cleaning layer;2, corrosion-resistant coating;3, the upper SBS self-adhered modified bitumen adhesive bed of material;4, tire base;
5, the lower SBS self-adhered modified bitumen adhesive bed of material;6, protective layer.
Specific embodiment
The present invention is described further with reference to embodiments.
Embodiment 1
As shown in Figure 1, automatically cleaning anticorrosion self-adhesive modified asphalt waterproof rolling material, including tire base 4, tire base 4 up and down
Surface is impregnated with the SBS self-adhered modified bitumen adhesive bed of material 3 and the lower SBS self-adhered modified bitumen adhesive bed of material 5 respectively, and upper SBS self-adhesion changes
The top of the property asphalt adhesive bed of material 3 is successively covered with corrosion-resistant coating 2 and super-hydrophobic automatic cleaning layer 1, the lower SBS self-adhered modified bitumen adhesive bed of material
5 outside is covered with protective layer 6.
Wherein:
Tire base 4 is made of polyester blank.
Super-hydrophobic automatic cleaning layer 1 is super-hydrophobic polypropylene film.
Corrosion-resistant coating 2 is epoxy resin corrosion-resistant coating.
Tire base 4 with a thickness of 5mm, the thickness of super-hydrophobic automatic cleaning layer 1 is 3mm, corrosion-resistant coating 2 with a thickness of 3mm, on
The thickness of the SBS self-adhered modified bitumen adhesive bed of material 3 and the lower SBS self-adhered modified bitumen adhesive bed of material 5 is 3mm, and the thickness of protective layer 6 is equal
For 2mm.
The upper SBS self-adhered modified bitumen adhesive bed of material 3 and the lower SBS self-adhered modified bitumen adhesive bed of material 5 are by following parts by weight
Raw material is made:
Wherein, tackifying resin is prepared from the following raw materials in parts by weight:
15 parts of coumarone indene resin
15 parts of terpene resin
Nine resin of carbon is 15 parts.
The preparation method is as follows:
I type waterproof roll pitch is first heated to 190-200 DEG C, then aromatic naphtha and vinyl stearic bicine diester are added thereto
Amine is cooled to 180-190 DEG C after mixing evenly, and SBS is then added and is warming up to 190-200 DEG C, controls temperature, stirs 1.5h, so
After continuously add tackifying resin and shoddy stirring 0.5h, be eventually adding nanometer calcium carbonate stirring 0.5h, obtain SBS self-adhesion and change
The property asphalt adhesive bed of material or the lower SBS self-adhered modified bitumen adhesive bed of material.
The testing result of automatically cleaning anticorrosion self-adhesive modified asphalt waterproof rolling material in the present embodiment is shown in Table 1.
Embodiment 2
Automatically cleaning anticorrosion self-adhesive modified asphalt waterproof rolling material such as embodiment 1 described in the present embodiment, the difference is that tire
Base 4 with a thickness of 6mm, the thickness of super-hydrophobic automatic cleaning layer 1 is 4mm, corrosion-resistant coating 2 with a thickness of 4mm, upper SBS self-adhesion changes
The thickness of the property asphalt adhesive bed of material 3 and the lower SBS self-adhered modified bitumen adhesive bed of material 5 is 4mm, and the thickness of protective layer 6 is 2mm.
The testing result of automatically cleaning anticorrosion self-adhesive modified asphalt waterproof rolling material in the present embodiment is shown in Table 1.
Embodiment 3
Automatically cleaning anticorrosion self-adhesive modified asphalt waterproof rolling material such as embodiment 1 described in the present embodiment, the difference is that tire
Base 4 with a thickness of 6mm, the thickness of super-hydrophobic automatic cleaning layer 1 is 5mm, corrosion-resistant coating 2 with a thickness of 4mm, upper SBS self-adhesion changes
The thickness of the property asphalt adhesive bed of material 3 and the lower SBS self-adhered modified bitumen adhesive bed of material 5 is 4mm, and the thickness of protective layer 6 is 2mm.
The testing result of automatically cleaning anticorrosion self-adhesive modified asphalt waterproof rolling material in the present embodiment is shown in Table 1.
Embodiment 4
Automatically cleaning anticorrosion self-adhesive modified asphalt waterproof rolling material such as embodiment 1 described in the present embodiment, the difference is that tire
Base 4 with a thickness of 7mm, the thickness of super-hydrophobic automatic cleaning layer 1 is 5mm, corrosion-resistant coating 2 with a thickness of 5mm, upper SBS self-adhesion changes
The thickness of the property asphalt adhesive bed of material 3 and the lower SBS self-adhered modified bitumen adhesive bed of material 5 is 5mm, and the thickness of protective layer 6 is 3mm.
The testing result of automatically cleaning anticorrosion self-adhesive modified asphalt waterproof rolling material in the present embodiment is shown in Table 1.
Embodiment 5
Automatically cleaning anticorrosion self-adhesive modified asphalt waterproof rolling material such as embodiment 1 described in the present embodiment, the difference is that tire
Base 4 with a thickness of 8mm, the thickness of super-hydrophobic automatic cleaning layer 1 is 5mm, corrosion-resistant coating 2 with a thickness of 5mm, upper SBS self-adhesion changes
The thickness of the property asphalt adhesive bed of material 3 and the lower SBS self-adhered modified bitumen adhesive bed of material 5 is 5mm, and the thickness of protective layer 6 is 3mm.
The testing result of automatically cleaning anticorrosion self-adhesive modified asphalt waterproof rolling material in the present embodiment is shown in Table 1.
Comparative example 1
The anticorrosion self-adhesive modified asphalt waterproof rolling material of this comparative example such as embodiment 1, the difference is that in coiled material not
Super-hydrophobic automatic cleaning layer, and tire base with a thickness of 5mm, corrosion-resistant coating with a thickness of 3mm, upper SBS self-adhered modified bitumen adhesive material
The thickness of layer and the lower SBS self-adhered modified bitumen adhesive bed of material is 3mm;The thickness of protective layer is 2mm.
The testing result of anticorrosion self-adhesive modified asphalt waterproof rolling material in this comparative example is shown in Table 1.
Comparative example 2
The anticorrosion self-adhesive modified asphalt waterproof rolling material of this comparative example such as embodiment 1, the difference is that upper SBS self-adhesion changes
The property asphalt adhesive bed of material and the lower SBS self-adhered modified bitumen adhesive bed of material are prepared from the following raw materials in parts by weight and are made:
Wherein, tackifying resin is prepared from the following raw materials in parts by weight:
15 parts of coumarone indene resin
15 parts of terpene resin
Nine resin of carbon is 15 parts.
The preparation method is as follows:
I type waterproof roll pitch is first heated to 190-200 DEG C, then aromatic naphtha is added thereto, is cooled down after mixing evenly
To 180-190 DEG C, SBS is then added and is warming up to 190-200 DEG C, controls temperature, stirs 1.5h, then proceedes to that tackifying resin is added
With shoddy stir 0.5h, be eventually adding nanometer calcium carbonate stirring 0.5h, obtain the SBS self-adhered modified bitumen adhesive bed of material or under
The SBS self-adhered modified bitumen adhesive bed of material.
The testing result of anticorrosion self-adhesive modified asphalt waterproof rolling material in this comparative example is shown in Table 1.
By the data in table 1 it can be seen that automatically cleaning anticorrosion self-adhesive modified asphalt waterproof rolling material of the invention, contact angle
150 ° are all larger than, there is excellent self-cleaning property and waterproofness, and the heat resistance of the coiled material and low temperature flexibility are good, peel strength
It is high.To sum up described, automatically cleaning anticorrosion self-adhesive modified asphalt waterproof rolling material of the invention not only maintains the excellent of self-adhesive coiled material
Performance, and it is provided with automatically cleaning and etch-proof performance, it can be effectively prevent the growth of bacterium, prolonged the service life.
1 detection performance index of table
Claims (9)
1. a kind of automatically cleaning anticorrosion self-adhesive modified asphalt waterproof rolling material, including tire base (4), it is characterised in that: tire base (4)
Upper and lower surface be impregnated with the SBS self-adhered modified bitumen adhesive bed of material (3) and the lower SBS self-adhered modified bitumen adhesive bed of material (5) respectively, on
The top of the SBS self-adhered modified bitumen adhesive bed of material (3) is successively covered with corrosion-resistant coating (2) and super-hydrophobic automatic cleaning layer (1), and lower SBS is certainly
The outside of the adhered modification asphalt adhesive bed of material (5) is covered with protective layer (6);
The upper SBS self-adhered modified bitumen adhesive bed of material (3) and the lower SBS self-adhered modified bitumen adhesive bed of material (5) are by following parts by weight
Several raw materials are made:
The super-hydrophobic automatic cleaning layer (1) is super-hydrophobic polypropylene film.
2. automatically cleaning anticorrosion self-adhesive modified asphalt waterproof rolling material according to claim 1, it is characterised in that: tire base
(4) it is made of polyester blank or glass fiber blank.
3. automatically cleaning anticorrosion self-adhesive modified asphalt waterproof rolling material according to claim 1, it is characterised in that: tire base
(4) with a thickness of 5-8mm;The thickness of super-hydrophobic automatic cleaning layer (1) is 3-5mm;Corrosion-resistant coating (2) with a thickness of 3-5mm;On
The SBS self-adhered modified bitumen adhesive bed of material (3) and the thickness of the lower SBS self-adhered modified bitumen adhesive bed of material (5) are 3-5mm;Protective layer (6)
Thickness be 2-3mm.
4. automatically cleaning anticorrosion self-adhesive modified asphalt waterproof rolling material according to claim 1, it is characterised in that: corrosion-resistant coating
It (2) is epoxy resin corrosion-resistant coating.
5. automatically cleaning anticorrosion self-adhesive modified asphalt waterproof rolling material according to claim 1, it is characterised in that: tackifying resin
It is prepared from the following raw materials in parts by weight:
10-30 parts of coumarone indene resin
10-30 parts of terpene resin
10-30 parts of nine resin of carbon.
6. automatically cleaning anticorrosion self-adhesive modified asphalt waterproof rolling material according to claim 1, it is characterised in that: protective layer
It (6) is antiseize silicone oil isolation film.
7. automatically cleaning anticorrosion self-adhesive modified asphalt waterproof rolling material according to claim 1, it is characterised in that: upper SBS is certainly
The adhered modification asphalt adhesive bed of material (3) and the lower SBS self-adhered modified bitumen adhesive bed of material (5) the preparation method is as follows:
First I type waterproof roll pitch is heated, then aromatic naphtha and vinyl bis-stearamides are added thereto, is stirred evenly
After cool down, SBS is then added and heated up, stirred, then proceedes to tackifying resin and shoddy is added and is stirred, is eventually adding
Nanometer calcium carbonate is stirred, and obtains automatically cleaning anticorrosion self-adhesive modified asphalt waterproof rolling material.
8. automatically cleaning anticorrosion self-adhesive modified asphalt waterproof rolling material according to claim 7, it is characterised in that: prevent I type
Water coiled material pitch is heated to 190-200 DEG C;Aromatic naphtha is added and vinyl bis-stearamides are cooled to 180-190 after mixing evenly
℃;180-190 DEG C is warming up to after SBS is added.
9. automatically cleaning anticorrosion self-adhesive modified asphalt waterproof rolling material according to claim 7, it is characterised in that: SBS is added
1.5h is stirred after being heated up;0.5h is stirred after tackifying resin and shoddy is added;0.5h is stirred after adding nanometer calcium carbonate.
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CN201610408002.3A CN107471780B (en) | 2016-06-07 | 2016-06-07 | Automatically cleaning anticorrosion self-adhesive modified asphalt waterproof rolling material |
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Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN203391410U (en) * | 2013-07-24 | 2014-01-15 | 唐山德生防水股份有限公司 | Self-cleaning flame-retardant waterproof roll material for color steel roof |
CN104742432A (en) * | 2014-08-19 | 2015-07-01 | 吴华林 | Anti-corrosion self-adhered polymer modified asphalt waterproofing roll |
CN105273687A (en) * | 2015-11-25 | 2016-01-27 | 广东台实实业有限公司 | Self-adhered waterproof rubber compound, self-adhered waterproof roll and preparation method |
-
2016
- 2016-06-07 CN CN201610408002.3A patent/CN107471780B/en active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN203391410U (en) * | 2013-07-24 | 2014-01-15 | 唐山德生防水股份有限公司 | Self-cleaning flame-retardant waterproof roll material for color steel roof |
CN104742432A (en) * | 2014-08-19 | 2015-07-01 | 吴华林 | Anti-corrosion self-adhered polymer modified asphalt waterproofing roll |
CN105273687A (en) * | 2015-11-25 | 2016-01-27 | 广东台实实业有限公司 | Self-adhered waterproof rubber compound, self-adhered waterproof roll and preparation method |
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