CN103333555A - Waterproof coating capable of chemical crosslinking and physical mortise and tenon with cement - Google Patents
Waterproof coating capable of chemical crosslinking and physical mortise and tenon with cement Download PDFInfo
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- CN103333555A CN103333555A CN2013102768124A CN201310276812A CN103333555A CN 103333555 A CN103333555 A CN 103333555A CN 2013102768124 A CN2013102768124 A CN 2013102768124A CN 201310276812 A CN201310276812 A CN 201310276812A CN 103333555 A CN103333555 A CN 103333555A
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- chemically crosslinked
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- 239000004568 cement Substances 0.000 title claims abstract description 31
- 238000000576 coating method Methods 0.000 title abstract description 12
- 239000011248 coating agent Substances 0.000 title abstract description 11
- 238000010382 chemical cross-linking Methods 0.000 title abstract 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 22
- 239000010426 asphalt Substances 0.000 claims abstract description 16
- 239000000945 filler Substances 0.000 claims abstract description 7
- 229920006174 synthetic rubber latex Polymers 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 4
- 239000003973 paint Substances 0.000 claims description 37
- -1 titanic acid ester Chemical class 0.000 claims description 19
- 229920000126 latex Polymers 0.000 claims description 18
- 230000001804 emulsifying effect Effects 0.000 claims description 14
- 239000003795 chemical substances by application Substances 0.000 claims description 13
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 12
- 239000000203 mixture Substances 0.000 claims description 10
- 229920001084 poly(chloroprene) Polymers 0.000 claims description 10
- 229920003048 styrene butadiene rubber Polymers 0.000 claims description 10
- 239000007822 coupling agent Substances 0.000 claims description 8
- 239000004816 latex Substances 0.000 claims description 8
- 239000007787 solid Substances 0.000 claims description 8
- 239000000839 emulsion Substances 0.000 claims description 7
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 6
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 6
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 6
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 6
- 239000006185 dispersion Substances 0.000 claims description 6
- 229920000058 polyacrylate Polymers 0.000 claims description 6
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 claims description 6
- UXFQFBNBSPQBJW-UHFFFAOYSA-N 2-amino-2-methylpropane-1,3-diol Chemical compound OCC(N)(C)CO UXFQFBNBSPQBJW-UHFFFAOYSA-N 0.000 claims description 5
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 5
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 5
- WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 claims description 4
- 239000005995 Aluminium silicate Substances 0.000 claims description 4
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims description 4
- 108010010803 Gelatin Proteins 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 4
- 235000012211 aluminium silicate Nutrition 0.000 claims description 4
- 239000001110 calcium chloride Substances 0.000 claims description 4
- 229910001628 calcium chloride Inorganic materials 0.000 claims description 4
- 229920000159 gelatin Polymers 0.000 claims description 4
- 239000008273 gelatin Substances 0.000 claims description 4
- 235000019322 gelatine Nutrition 0.000 claims description 4
- 235000011852 gelatine desserts Nutrition 0.000 claims description 4
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 4
- 229910052760 oxygen Inorganic materials 0.000 claims description 4
- 239000001301 oxygen Substances 0.000 claims description 4
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 claims description 4
- ALVYUZIFSCKIFP-UHFFFAOYSA-N triethoxy(2-methylpropyl)silane Chemical compound CCO[Si](CC(C)C)(OCC)OCC ALVYUZIFSCKIFP-UHFFFAOYSA-N 0.000 claims description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 3
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 3
- 125000004423 acyloxy group Chemical group 0.000 claims description 3
- 239000006229 carbon black Substances 0.000 claims description 3
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 3
- 235000011187 glycerol Nutrition 0.000 claims description 3
- 150000004002 naphthaldehydes Chemical class 0.000 claims description 3
- 229920002401 polyacrylamide Polymers 0.000 claims description 3
- 239000011734 sodium Substances 0.000 claims description 3
- 229910052708 sodium Inorganic materials 0.000 claims description 3
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 claims description 3
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims description 3
- 229920002554 vinyl polymer Polymers 0.000 claims description 3
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 2
- 239000003995 emulsifying agent Substances 0.000 claims description 2
- 239000011301 petroleum pitch Substances 0.000 claims description 2
- 239000004408 titanium dioxide Substances 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 12
- 229920001971 elastomer Polymers 0.000 abstract description 10
- 239000005060 rubber Substances 0.000 abstract description 10
- 238000001179 sorption measurement Methods 0.000 abstract description 7
- 239000000126 substance Substances 0.000 abstract description 7
- 238000006243 chemical reaction Methods 0.000 abstract description 4
- 229920003051 synthetic elastomer Polymers 0.000 abstract description 3
- 239000005061 synthetic rubber Substances 0.000 abstract description 3
- 230000007613 environmental effect Effects 0.000 abstract description 2
- 239000013538 functional additive Substances 0.000 abstract 2
- 150000002605 large molecules Chemical class 0.000 abstract 2
- 229920002521 macromolecule Polymers 0.000 abstract 2
- 239000000853 adhesive Substances 0.000 abstract 1
- 230000001070 adhesive effect Effects 0.000 abstract 1
- 230000001808 coupling effect Effects 0.000 abstract 1
- 239000002270 dispersing agent Substances 0.000 abstract 1
- 238000003756 stirring Methods 0.000 description 39
- 238000005303 weighing Methods 0.000 description 8
- 239000004567 concrete Substances 0.000 description 7
- 229920001296 polysiloxane Polymers 0.000 description 6
- 230000001680 brushing effect Effects 0.000 description 5
- 238000010276 construction Methods 0.000 description 5
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 235000015424 sodium Nutrition 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 2
- 235000010216 calcium carbonate Nutrition 0.000 description 2
- 235000019241 carbon black Nutrition 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 230000008878 coupling Effects 0.000 description 2
- 238000010168 coupling process Methods 0.000 description 2
- 238000005859 coupling reaction Methods 0.000 description 2
- 239000010408 film Substances 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- 239000011440 grout Substances 0.000 description 2
- 230000036555 skin type Effects 0.000 description 2
- 235000010215 titanium dioxide Nutrition 0.000 description 2
- 235000019738 Limestone Nutrition 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 239000004902 Softening Agent Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 229920003086 cellulose ether Polymers 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical class [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 238000005204 segregation Methods 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- YUYCVXFAYWRXLS-UHFFFAOYSA-N trimethoxysilane Chemical compound CO[SiH](OC)OC YUYCVXFAYWRXLS-UHFFFAOYSA-N 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention provides a waterproof coating capable of chemical crosslinking and physical mortise and tenon with cement. The waterproof coating is characterized by comprising the following raw materials by weight: 20-50 parts of a synthetic rubber latex, 20-50 parts of emulsified asphalt, 0.5-2 parts of a functional additive and 0.5-2 parts of a dispersant, 20-40 parts of a filler and 10-25 parts of water. The principle is that through coupling effect of the functional additive, part of the molecules in the synthetic rubber and most molecules in the asphalt couple into large molecules with reaction activity; when the large molecules contact with a base plane, the non-reactive molecule segments of the rubber and asphalt and the base plane form physical adsorption, and the molecular segments with reaction activity conduct react with the base plane to form chemical bond effect, so as to generate strong adhesive force; and after bonding, the coating is hardly influenced by environmental factors. Therefore, the waterproof coating provided by the invention has excellent waterproof performance.
Description
Technical field
The present invention relates to a kind of waterproof paint, particularly can be with cement and concrete generation chemical reaction and the coating that bonds.
Background technology
The waterproof paint brushing is on building surface, and the chemical reaction of component forms thin film at building surface after the volatilization of solvent or moisture or in two kinds of coating, and the protection building surface completely cuts off with water, thereby plays waterproof, dampproof effect.The water resistance of waterproof paint is relevant with cohesiveness, extensibility, elastoplasticity, splitting resistance, impermeability and the weathering resistance of the film of its formation.The cohesive strength of film and basal plane is an important indicator of check waterproof paint water resistance, and cohesive force is strong, good water-proof effect.At present, conventional waterproof coating on the market mainly relies on physical adsorption and basal plane bonding, and this cohesive force is smaller, is subjected to the influence of external environment factor easily and disappears.For example be subjected to expanding with heat and contract with cold of hydraulic pressure effect, soda acid salt corrosion, basal plane etc. and do the time spent, waterproof layer easily separates with basal plane, the situation of scurrying water, leaking occurs.Application of paints is in smooth interface, as plastics tubing, ceramic tile glaze etc., because the cohesive force of waterproof layer and smooth surface is little, and easier coming off and cause the phenomenon of scurrying water, leaking.
Summary of the invention
The objective of the invention is to develop a kind of waterproof paint, its molecule can with cement and the effect of concrete surface generation chemical bonding, by physical adsorption and chemical bonding effect, improved the cohesive force of waterproof layer and basal plane, waterproof layer and basal plane form the waterproof construction of skin-type, have strengthened the water resistance of coating.
Technical scheme of the present invention is:
With the waterproof paint of cement generation chemically crosslinked and physics mortise and tenon, comprise the raw material of following parts by weight:
Synthetic rubber latex 20～50; Emulsified bitumen 20～50; Functional aid 0.5～2; Dispersion agent 0.5～2; Filler 20～40; Water 10～25;
Described synthetic rubber latex solid content is the composition of any or they in 40～60% styrene butadiene rubber latex, chloroprene rubber latex, SBS rubber latex or the polyacrylate(s);
To be petroleum pitch, emulsifying agent and water through high-speed emulsifying machine handle described emulsified bitumen that to obtain solid content be that 40～70% emulsion or solid content are any in 40～60% SBS modified emulsifying asphalt, styrene-butadiene rubber(SBR) modified emulsifying asphalt or the chloroprene rubber modified emulsifying asphalt.
Described functional aid is the coupling agent with hydroxyl, vinyl, amino or carboxyl isoreactivity group.
Described functional aid is to have vinyl, hydroxyl, the coupling agent of amino or carboxyl isoreactivity group, hydroxyl is particularly arranged, the polysiloxane coupling agent of amino or carboxyl-reactive functional group, poly-naphthaldehyde sulfonate sodium or their mixture, polysiloxane coupling agent comprises: the hydroxyl alkyl polysiloxane, the carboxyl polysiloxane, the derivative of dimethyl siloxane or cyclohexyl methyl siloxanes, as poly-methyl ethoxy silane, the fatty amide alkyl silane, two kinds of amino third Trimethoxy silane of carboxyl polysiloxane or 3-or they, two or more mixtures, the active group that produces after their hydrolysis can play synergistic effect (the Chemical Bonding and Physical Crosslinking Synergism of chemically crosslinked-physics mortise and tenon with cement or concrete, be called for short CPS) additive (Chinese patent of inventor's application: application (patent) number: CN200910114456.X, title: carry out the waterproof roll of chemically crosslinked and the collaborative bonding of physics mortise and tenon with concrete; Open (bulletin) number: CN101694114A applies for (patent right) people: Guangxi Jiyusan Waterproof Decoration Co., Ltd. address: WangZhou Road, Nanning City, Guangxi Zhuang Autonomous nationality District 267-1 contriver: Lu Guicai; Wu Shengjiang; Zhu Fangwu; Guo Wenxiong) disclose wherein two kinds: poly-methyl ethoxy silane and poly-naphthaldehyde sulfonate sodium.Through overtesting, we find except these two kinds of compounds, coupling agent with hydroxyl, amino or carboxyl, particularly the polysiloxane coupling agent of responding property functional group all has or partly has and can carry out chemically crosslinked and the collaborative cohesive action of physics mortise and tenon with cement and concrete, as isobutyl-triethoxyl silane, 3-aminopropyl triethoxysilane, distearyl acyl-oxygen sec.-propyl aluminic acid ester, sec.-propyl three (dioctylphyrophosphoric acid acyloxy) titanic acid ester.
Described dispersion agent is a kind of in polyacrylamide, cellulose ethers, sodium polyacrylate, gelatin or the polyoxyethylene or their composition.
Described filler is any one or more mixture of white carbon black, titanium dioxide, kaolin, barium sulfate, talcum powder, light calcium carbonate or water-ground limestone.
The waterproof paint of of the present invention and cement generation chemically crosslinked and physics mortise and tenon also comprises the antifreezing agent of 0～0.5 parts by weight, and described antifreezing agent is glycerine, ethylene glycol, 1, the mixture of any one or more of ammediol or calcium chloride.
Principle of the present invention is to be raw material with synthetic rubber latex and modified rubber emulsified bitumen, add functional aid, make synthetic rubber molecule, the asphaltene molecule macromole that coupling becomes to have reactive behavior with the functional aid molecule, when this macromole contacts with basal plane, rubber molecule and asphaltene molecule section and basal plane form physical adsorption, and macromole and the adsorption of basal plane generation chemical bonding with reactive behavior, produce chemical action power, therefore the cohesive force of the waterproof layer that forms and basal plane just strengthens greatly, is difficult to by extraneous such environmental effects.Waterproof paint of the present invention is water-borne coatings, in order to make the layering of the stable difficult segregation of product, also needs to add dispersion agent, filler, antifreezing agent etc.
Above-mentioned preparation method with waterproof paint cement generation chemically crosslinked and physics mortise and tenon is:
(1) normal temperature is respectively put into a jar to two kinds of emulsions, stirs earlier;
(2) synthetic rubber latex stirs and adds the modified rubber emulsified bitumen down, add functional aid after adding the modified rubber emulsified bitumen, add softening agent, stir, add filler at last, dispersion agent is according to the environment for use needs interpolation antifreezing agent of product, stir, namely obtain the waterproof paint with cement generation chemically crosslinked and physics mortise and tenon.
The positively effect that the present invention produces: by the coupled action of functional aid, the macromole that makes synthetic rubber molecule and asphaltene molecule coupling become to have reactive behavior, when this macromole contacts with basal plane, rubber molecule and asphaltene molecule section and basal plane form physical adsorption, and macromole and the effect of basal plane generation chemical bonding with reactive behavior, and the cohesiveness of coating rete, extensibility, elastoplasticity, splitting resistance are very outstanding, waterproof layer and basal plane have formed the waterproof construction of skin-type, good water-proof effect like this.
Embodiment
Embodiment 1
(1) in two jars, takes by weighing 40 parts of neoprene latex latex rubbers and 20 parts of SBS modified emulsifying asphalts respectively, stir;
(2) stirring joins 20 parts of SBS modified emulsifying asphalts in 40 parts of neoprene latex latex rubbers down, add 1 part of isobutyl-triethoxyl silane then, stir, add 30 parts of white carbon blacks, 0.5 part Xylo-Mucine, 0.1 part ethylene glycol and 10 parts of water stir, and obtain the waterproof paint with cement generation chemically crosslinked and physics mortise and tenon
Embodiment 2
(1) in two jars, takes by weighing 50 parts of styrene butadiene rubber latexes and 20 parts of styrene-butadiene rubber(SBR) modified emulsifying asphalts respectively, stir;
(2) 50 parts of styrene butadiene rubber latexes stir and add 25 parts of styrene-butadiene rubber(SBR) modified emulsifying asphalts down, add 1.5 parts of 3-aminopropyl triethoxysilanes then, stir, add 25 parts of light calcium carbonates at last, 0.4 part glycerine, 12 parts of water, 0.75 part of sodium polyacrylate, stir, obtain the waterproof paint with cement generation chemically crosslinked and physics mortise and tenon.
Embodiment 3
(1) in two jars, takes by weighing 30 parts of SBS rubber latexs and 30 parts of modified rubber emulsified bitumens respectively, stir;
(2) 30 parts of SBS rubber latexs stir and add 30 parts of modified rubber emulsified bitumens down, add 2 parts of distearyl acyl-oxygen sec.-propyl aluminic acid esters then, stir, add 30 parts of water-ground limestones at last, 1 part of gelatin, 20 parts of water and 0.5 part of calcium chloride stir, and obtain the waterproof paint with cement generation chemically crosslinked and physics mortise and tenon.
Embodiment 4
(1) in two jars, takes by weighing 42 parts of butyl polyacrylate emulsions and 30 parts of modified rubber emulsified bitumens respectively, stir;
(2) 42 parts of butyl polyacrylate emulsions stir down and add 24 parts of modified rubber emulsified bitumens, add 1.6 parts of sec.-propyls three (dioctylphyrophosphoric acid acyloxy) titanic acid ester then, stir, add the feed liquid that step (1) obtains, stir, add 0.3 part 1, ammediol, add 30 parts of kaolin at last, 0.8 part polyoxyethylene, 18 parts of water and 0.3 part 1, ammediol, stir, obtain the waterproof paint with cement generation chemically crosslinked and physics mortise and tenon.
Embodiment 5
(1) in two jars, takes by weighing 20 parts of neoprene latex latex rubbers and 50 parts of emulsified bitumens respectively, stir;
(2) 50 parts of emulsified bitumens stir and add 20 parts of neoprene latex latex rubbers down, add 0.5 part of isobutyl-triethoxyl silane then, stir, 0.1 part antifreezing agent ethylene glycol, add 30 parts of kaolin at last, 1 part of Xylo-Mucine, 15 parts of water, stir, obtain the waterproof paint with cement generation chemically crosslinked and physics mortise and tenon.
Embodiment 6
(1) in two jars, takes by weighing 25 parts of styrene butadiene rubber latexes and 40 parts of emulsified bitumens respectively, stir;
(2) 25 parts of styrene butadiene rubber latexes stir and add 40 parts of emulsified bitumens down, add 1 part of distearyl acyl-oxygen sec.-propyl aluminic acid ester then, stir, add 35 parts of talcum powder, 1.5 parts of sodium polyacrylates and 20 parts of water at last, stir, obtain the waterproof paint with cement generation chemically crosslinked and physics mortise and tenon.
Embodiment 7
(1) in two jars, takes by weighing 30 parts of SBS rubber latexs and 30 parts of emulsified bitumens respectively, stir in 25 parts of water;
(2) 30 parts of SBS rubber latexs stir and add 30 parts of emulsified bitumens down, add 2 parts of 3-aminopropyl triethoxysilanes then, stir, add 0.3 part of calcium chloride and 0.2 part 1, ammediol adds 2 parts of gelatin and 25 parts of water, stir, add 40 parts of barium sulfate at last, stir, obtain the waterproof paint with cement generation chemically crosslinked and physics mortise and tenon.
Embodiment 8
(1) in two jars, take by weighing 24 parts of butyl polyacrylate emulsions and 36 parts of chloroprene rubber modified emulsifying asphalts respectively, in stir;
(2) 24 parts of butyl polyacrylate emulsions stir and add 36 parts of chloroprene rubber modified emulsifying asphalts down, add 1.6 parts of poly-naphthaldehyde sulfonate sodiums then, stir, add 1.4 parts of polyacrylamides and 18 parts of water, stir, add 32 parts of titanium dioxides at last, stir, obtain the waterproof paint with cement generation chemically crosslinked and physics mortise and tenon.
According to JC/T 408-2005 standard the waterproof paint with cement generation chemically crosslinked and physics mortise and tenon of the present invention is carried out the detection of each index, the result is as shown in table 1:
The detected result of table 1 waterproof paint with cement generation chemically crosslinked and physics mortise and tenon of the present invention
| Project | Solid content/% | Thermal stability/℃ | Watertightness | Cohesive strength/Mpa | The time do time/h | Low-temperature tenderness (standard conditions)/℃ | Extension at break degree/% |
| Embodiment 1 | 55.2 | 115 | 0.3MPa 30min is waterproof | 0.58 | 15 | -25 | 1000 |
| Embodiment 2 | 56.5 | 118 | 0.3MPa 30min is waterproof | 0.61 | 13 | -25 | 1060 |
| Embodiment 3 | 47.7 | 90 | 0.3MPa 30min is waterproof | 0.42 | 20 | -20 | 800 |
| Embodiment 4 | 57.3 | 122 | 0.3MPa 30min is waterproof | 0.66 | 12 | -30 | 1200 |
| Embodiment 5 | 57.1 | 85 | 0.3MPa 30min is waterproof | 0.38 | 15 | -15 | 650 |
| Embodiment 6 | 56.8 | 90 | 0.3MPa 30min is waterproof | 0.45 | 13 | -20 | 780 |
| Embodiment 7 | 57.3 | 105 | 0.3MPa 30min is waterproof | 0.46 | 20 | -20 | 920 |
| Embodiment 8 | 57.5 | 100 | 0.3MPa 30min is waterproof | 0.52 | 12 | -20 | 860 |
Table 2 performance with the waterproof paint of cement generation chemically crosslinked and physics mortise and tenon and fast-selling on the market waterproof paint of the present invention relatively
| Project | Execution conditions | Watertightness | Cohesive strength/Mpa with basal plane | Extension at break degree/% |
| The waterproof paint of of the present invention and cement generation chemically crosslinked and physics mortise and tenon | But construct under the wet environment, basal plane needn't clean | 0.3MPa 30min is waterproof | 0.5～0.7 | 1000～1200 |
| Polyurethane water-proof paint | Basal plane must be dry, and cleaning | 0.3MPa 30min is waterproof | 0.3～0.5 | 600～800 |
| 208-Wet Patch of U.S. Henry company | Basal plane must be dry, and cleaning | 0.10MPa 30min is waterproof | 0.35～0.45 | 10-30 |
| The JS waterproof paint | But construct under the wet environment, basal plane needn't clean | 0.2MPa 30min is waterproof | 0.3～0.4 | 80～120 |
As seen from Table 1 and Table 2, the waterproof paint of of the present invention and cement generation chemically crosslinked and physics mortise and tenon since with basal plane generation chemisorption power, cohesive strength is stronger than the waterproof paint that has only physical adsorption, the waterproof layer of formation can be waterproof under high hydraulic pressure.The waterproof layer extension at break degree height that waterproof paint of the present invention and cement generation chemically crosslinked and physics mortise and tenon forms, low temperature flexibility is good, even basal plane ruptures, waterproof layer also is not easy to be damaged, and still keeps good watertightness, the water resistance excellence.
The working procedure of the waterproof paint of of the present invention and cement generation chemically crosslinked and physics mortise and tenon is as follows:
(1) base treatment: solid smooth, the no floating dust of basal plane, no greasy dirt.Dry basal plane water in advance wetting effect is better, or at the basal plane lean concrete grout of filming, just can when treating the lean concrete grout initial set.Pipe root limit or drain gully etc. will be smeared into circular arc with the basic unit seam crossing, and arc radius is preferably 5cm.
(2) brushing waterproof paint: sealing compound evenly is applied in node positions such as crack, pipe root, gutter, eaves gutter, negative and positive angle with hairbrush or slurry cutter, generally brushes 2-3 all over finishing, gauge control is at 1.5～2.5mm; Wide 10cm is smeared at pipe root node circumference place, and the pipe root is smeared high 5cm, but reinforcement tire sills such as brushing process paving grid cloth, non-woven fabrics are made enhancement process, and brushing should adopt the method for scumbling multipass to carry out;
(3) maintenance: the construction back guarantees to ventilate, drying, and solidified in general 2-3 days fully the brushing back, stuffy or wet environment, and then can prolong set time.
(4) follow-up construction: when the water-tight layer is done follow-up construction, must after coating is solidified fully, carry out.
Claims (5)
1. with the waterproof paint of cement generation chemically crosslinked and physics mortise and tenon, it is characterized in that, comprise the raw material of following parts by weight:
Synthetic rubber latex 20～50; Emulsified bitumen 20～50; Functional aid 0.5～2; Dispersion agent 0.5～2; Filler 20～40; Water 10～25;
Described synthetic rubber latex solid content is the composition of any or they in 40～60% styrene butadiene rubber latex, chloroprene rubber latex, SBS rubber latex or the polyacrylate(s);
To be petroleum pitch, emulsifying agent and water through high-speed emulsifying machine handle described emulsified bitumen that to obtain solid content be that 40～70% emulsion or solid content are any in 40～60% SBS modified emulsifying asphalt, styrene-butadiene rubber(SBR) modified emulsifying asphalt or the chloroprene rubber modified emulsifying asphalt;
Described functional aid is the coupling agent with hydroxyl, vinyl, amino or carboxyl active group.
2. the waterproof paint of according to claim 1 and cement generation chemically crosslinked and physics mortise and tenon, it is characterized in that, the antifreezing agent that also comprises 0～0.5 parts by weight, described antifreezing agent are glycerine, ethylene glycol, 1, the mixture of any one or more of ammediol or calcium chloride.
3. the waterproof paint of according to claim 1 and cement generation chemically crosslinked and physics mortise and tenon, it is characterized in that described coupling agent is any in isobutyl-triethoxyl silane, 3-aminopropyl triethoxysilane, distearyl acyl-oxygen sec.-propyl aluminic acid ester, sec.-propyl three (dioctylphyrophosphoric acid acyloxy) titanic acid ester or the poly-naphthaldehyde sulfonate sodium.
4. the waterproof paint of according to claim 1 and cement generation chemically crosslinked and physics mortise and tenon, it is characterized in that described dispersion agent is any one or more the mixture in polyacrylamide, Xylo-Mucine, sodium polyacrylate, gelatin or the polyoxyethylene.
5. the waterproof paint of according to claim 1 and cement generation chemically crosslinked and physics mortise and tenon, it is characterized in that described filler is any one or more mixture of white carbon black, titanium dioxide, kaolin, barium sulfate, talcum powder, light calcium carbonate or water-ground limestone.
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Denomination of invention: Waterproof coating capable of chemical crosslinking and physical mortise and tenon with cement Effective date of registration: 20170914 Granted publication date: 20160113 Pledgee: Nanning Xingning Changjiang village bank Limited by Share Ltd Pledgor: Guangxi Golden Umbrella Waterproofing Co.,Ltd. Registration number: 2017450000007 |
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Change date: 20190228 Registration number: 2017450000007 Pledgor after: Xiniupi Waterproof Technology Co., Ltd. Pledgor before: Guangxi Golden Umbrella Waterproofing Co.,Ltd. |
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Date of cancellation: 20190311 Granted publication date: 20160113 Pledgee: Nanning Xingning Changjiang village bank Limited by Share Ltd Pledgor: Xiniupi Waterproof Technology Co., Ltd. Registration number: 2017450000007 |
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Address after: 530216 scientific research building, Xiniu science and Technology Park, No. 68, team 4, naluopo, Sitang community, Santang Town, Xingning District, Nanning City, Guangxi Zhuang Autonomous Region Patentee after: Xiniupi Waterproof Technology Co.,Ltd. Address before: 530002 Donggouling Landscape Road, Xingning District, Nanning City, Guangxi Zhuang Autonomous Region, Lin18 Sunshine Green City, 1 Building, 1 Unit 4 Patentee before: Xiniupi Waterproof Technology Co.,Ltd. |
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