CN103304862B - With the waterproof sealing cream of cement generation chemically crosslinked and physics mortise and tenon - Google Patents
With the waterproof sealing cream of cement generation chemically crosslinked and physics mortise and tenon Download PDFInfo
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- CN103304862B CN103304862B CN201310276909.5A CN201310276909A CN103304862B CN 103304862 B CN103304862 B CN 103304862B CN 201310276909 A CN201310276909 A CN 201310276909A CN 103304862 B CN103304862 B CN 103304862B
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- 238000007789 sealing Methods 0.000 title claims abstract description 48
- 239000006071 cream Substances 0.000 title claims abstract description 39
- 239000004568 cement Substances 0.000 title claims abstract description 35
- 239000010426 asphalt Substances 0.000 claims abstract description 19
- 239000000463 material Substances 0.000 claims abstract description 17
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000000203 mixture Substances 0.000 claims abstract description 15
- 229920006174 synthetic rubber latex Polymers 0.000 claims abstract description 9
- 239000004902 Softening Agent Substances 0.000 claims abstract description 8
- 230000008719 thickening Effects 0.000 claims abstract description 8
- 239000000945 filler Substances 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 5
- MOVRNJGDXREIBM-UHFFFAOYSA-N aid-1 Chemical compound O=C1NC(=O)C(C)=CN1C1OC(COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)COP(O)(=O)OC2C(OC(C2)N2C(NC(=O)C(C)=C2)=O)COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)COP(O)(=O)OC2C(OC(C2)N2C(NC(=O)C(C)=C2)=O)COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)COP(O)(=O)OC2C(OC(C2)N2C(NC(=O)C(C)=C2)=O)COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)COP(O)(=O)OC2C(OC(C2)N2C3=C(C(NC(N)=N3)=O)N=C2)CO)C(O)C1 MOVRNJGDXREIBM-UHFFFAOYSA-N 0.000 claims abstract description 3
- 229920000126 latex Polymers 0.000 claims description 21
- 230000001804 emulsifying effect Effects 0.000 claims description 17
- -1 titanic acid ester Chemical class 0.000 claims description 16
- 238000000034 method Methods 0.000 claims description 12
- 229920001084 poly(chloroprene) Polymers 0.000 claims description 12
- 229920003048 styrene butadiene rubber Polymers 0.000 claims description 12
- 239000004816 latex Substances 0.000 claims description 10
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 9
- 239000007787 solid Substances 0.000 claims description 9
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 8
- 239000000839 emulsion Substances 0.000 claims description 7
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims description 6
- 230000008569 process Effects 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- TVWTZAGVNBPXHU-FOCLMDBBSA-N dioctyl (e)-but-2-enedioate Chemical compound CCCCCCCCOC(=O)\C=C\C(=O)OCCCCCCCC TVWTZAGVNBPXHU-FOCLMDBBSA-N 0.000 claims description 5
- WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 claims description 4
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 claims description 4
- 239000002253 acid Substances 0.000 claims description 4
- 125000004423 acyloxy group Chemical group 0.000 claims description 4
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 claims description 4
- JBSLOWBPDRZSMB-FPLPWBNLSA-N dibutyl (z)-but-2-enedioate Chemical compound CCCCOC(=O)\C=C/C(=O)OCCCC JBSLOWBPDRZSMB-FPLPWBNLSA-N 0.000 claims description 4
- 229910052760 oxygen Inorganic materials 0.000 claims description 4
- 239000001301 oxygen Substances 0.000 claims description 4
- 229920002401 polyacrylamide Polymers 0.000 claims description 4
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 claims description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 3
- 239000006229 carbon black Substances 0.000 claims description 3
- 239000004927 clay Substances 0.000 claims description 3
- JBSLOWBPDRZSMB-BQYQJAHWSA-N dibutyl (e)-but-2-enedioate Chemical compound CCCCOC(=O)\C=C\C(=O)OCCCC JBSLOWBPDRZSMB-BQYQJAHWSA-N 0.000 claims description 3
- 235000011187 glycerol Nutrition 0.000 claims description 3
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 claims description 3
- 229920000058 polyacrylate Polymers 0.000 claims description 3
- 235000010413 sodium alginate Nutrition 0.000 claims description 3
- 239000000661 sodium alginate Substances 0.000 claims description 3
- 229940005550 sodium alginate Drugs 0.000 claims description 3
- ALVYUZIFSCKIFP-UHFFFAOYSA-N triethoxy(2-methylpropyl)silane Chemical compound CCO[Si](CC(C)C)(OCC)OCC ALVYUZIFSCKIFP-UHFFFAOYSA-N 0.000 claims description 3
- 239000005083 Zinc sulfide Substances 0.000 claims description 2
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 2
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 2
- RISLXYINQFKFRL-UHFFFAOYSA-N dibutyl nonanedioate Chemical compound CCCCOC(=O)CCCCCCCC(=O)OCCCC RISLXYINQFKFRL-UHFFFAOYSA-N 0.000 claims description 2
- 239000003995 emulsifying agent Substances 0.000 claims description 2
- 239000011301 petroleum pitch Substances 0.000 claims description 2
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 claims description 2
- 239000004408 titanium dioxide Substances 0.000 claims description 2
- 229910052984 zinc sulfide Inorganic materials 0.000 claims description 2
- DRDVZXDWVBGGMH-UHFFFAOYSA-N zinc;sulfide Chemical compound [S-2].[Zn+2] DRDVZXDWVBGGMH-UHFFFAOYSA-N 0.000 claims description 2
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims 1
- 229920002472 Starch Polymers 0.000 claims 1
- 239000001110 calcium chloride Substances 0.000 claims 1
- 229910001628 calcium chloride Inorganic materials 0.000 claims 1
- 150000002170 ethers Chemical class 0.000 claims 1
- 239000008107 starch Substances 0.000 claims 1
- 235000019698 starch Nutrition 0.000 claims 1
- 229920001971 elastomer Polymers 0.000 abstract description 11
- 239000005060 rubber Substances 0.000 abstract description 11
- 239000000126 substance Substances 0.000 abstract description 8
- 230000000694 effects Effects 0.000 abstract description 7
- 230000009471 action Effects 0.000 abstract description 5
- 229920003051 synthetic elastomer Polymers 0.000 abstract description 5
- 239000005061 synthetic rubber Substances 0.000 abstract description 5
- 230000008878 coupling Effects 0.000 abstract description 3
- 238000010168 coupling process Methods 0.000 abstract description 3
- 238000005859 coupling reaction Methods 0.000 abstract description 3
- 230000007613 environmental effect Effects 0.000 abstract description 3
- 238000004375 physisorption Methods 0.000 abstract description 3
- 238000003756 stirring Methods 0.000 description 38
- 239000004567 concrete Substances 0.000 description 16
- 238000010276 construction Methods 0.000 description 15
- 150000001875 compounds Chemical class 0.000 description 9
- 229920003023 plastic Polymers 0.000 description 9
- 239000004033 plastic Substances 0.000 description 9
- 239000003566 sealing material Substances 0.000 description 6
- 239000002585 base Substances 0.000 description 5
- 229920001296 polysiloxane Polymers 0.000 description 5
- 238000002360 preparation method Methods 0.000 description 5
- 238000001179 sorption measurement Methods 0.000 description 5
- 229920002319 Poly(methyl acrylate) Polymers 0.000 description 4
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 4
- 239000007822 coupling agent Substances 0.000 description 4
- 239000003960 organic solvent Substances 0.000 description 4
- 235000010216 calcium carbonate Nutrition 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
- 239000004588 polyurethane sealant Substances 0.000 description 3
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 3
- 239000004590 silicone sealant Substances 0.000 description 3
- 235000010215 titanium dioxide Nutrition 0.000 description 3
- 108010010803 Gelatin Proteins 0.000 description 2
- 235000019738 Limestone Nutrition 0.000 description 2
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 2
- 230000001680 brushing effect Effects 0.000 description 2
- 235000019241 carbon black Nutrition 0.000 description 2
- 230000005465 channeling Effects 0.000 description 2
- TVWTZAGVNBPXHU-NXVVXOECSA-N dioctyl (z)-but-2-enedioate Chemical class CCCCCCCCOC(=O)\C=C/C(=O)OCCCCCCCC TVWTZAGVNBPXHU-NXVVXOECSA-N 0.000 description 2
- 238000005538 encapsulation Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 229920000159 gelatin Polymers 0.000 description 2
- 239000008273 gelatin Substances 0.000 description 2
- 235000019322 gelatine Nutrition 0.000 description 2
- 235000011852 gelatine desserts Nutrition 0.000 description 2
- 239000011440 grout Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000007769 metal material Substances 0.000 description 2
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical class [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 2
- 239000005077 polysulfide Substances 0.000 description 2
- 229920001021 polysulfide Polymers 0.000 description 2
- 150000008117 polysulfides Polymers 0.000 description 2
- 229910000077 silane Inorganic materials 0.000 description 2
- 230000036555 skin type Effects 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- UXFQFBNBSPQBJW-UHFFFAOYSA-N 2-amino-2-methylpropane-1,3-diol Chemical compound OCC(N)(C)CO UXFQFBNBSPQBJW-UHFFFAOYSA-N 0.000 description 1
- 239000004925 Acrylic resin Substances 0.000 description 1
- XMSXQFUHVRWGNA-UHFFFAOYSA-N Decamethylcyclopentasiloxane Chemical compound C[Si]1(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O[Si](C)(C)O1 XMSXQFUHVRWGNA-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 239000003183 carcinogenic agent Substances 0.000 description 1
- 125000003636 chemical group Chemical group 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 229940086555 cyclomethicone Drugs 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 230000009429 distress Effects 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 125000002768 hydroxyalkyl group Chemical group 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 230000002427 irreversible effect Effects 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000004643 material aging Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 238000007591 painting process Methods 0.000 description 1
- VHUCVIFTAJKQRR-UHFFFAOYSA-N propan-1-amine trimethoxysilane Chemical compound CO[SiH](OC)OC.C(CC)N VHUCVIFTAJKQRR-UHFFFAOYSA-N 0.000 description 1
- 230000008439 repair process Effects 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Abstract
The invention provides a kind of with cement generation chemically crosslinked with the waterproof sealing cream of physics mortise and tenon, it is characterized in that the raw material composition comprising following parts by weight: synthetic rubber latex 40 ~ 60; Modified rubber emulsified bitumen 20 ~ 30; Functional aid 1 ~ 2; Filler 10 ~ 30; Softening agent 0.5 ~ 5; Thickening material 1 ~ 3; Water 2 ~ 5.Its principle is the coupled action by functional aid, synthetic rubber is made to become to have the macromole of reactive behavior with the moieties coupling in pitch, when this macromole contacts with basal plane, the nonreactive activity of rubber and pitch divides subsegment and basal plane to form physisorption, and there is reactive behavior point subsegment and basal plane react and form chemical bonding effect, produce powerful bounding force, bondd rear being difficult to by the such environmental effects in the external world, and therefore waterproof sealing cream of the present invention has very excellent water resistance.
Description
Technical field
The present invention relates to a kind of waterproof sealing cream, particularly can with the sealing compound of cement or concrete surface generation chemisorption power.
Background technology
Waterproof sealing cream is the one in water-proof material, the filling of the seam areas such as the structural joint, construction joint, plate seam, door and window seam and each category node that be that design upper is had a mind to arrange, produce in construction, sealing material.Waterproof sealing cream normal with other water-proof materials as waterproof roll, waterproof paint conbined usage, make buildings reach the waterproof effect of excellence.Waterproof sealing cream mainly contains polyurethane sealant, silicone sealant, polyacrylic resin sealing compound, polysulfide sealing compound, synthetic rubber base sealing compound, modifying asphalt sealing compound etc.Polyurethane sealant, silicone sealant and polysulfide sealing compound production cost are high, are seldom applied to large-area engineering, and they cannot be constructed in wet condition, and construction cost is higher.The materials such as synthetic rubber base sealing compound, modifying asphalt sealing adopt organic solvent as solvent, and time of drying is long, and rate of drying is slow, the volatilization of organic solvent can cause environmental pollution, and when basal plane humidity, because cannot adhere to basal plane, and cannot construct.Above-mentioned sealing material and the cohesive force of basal plane mainly pass through physisorption, therefore cohesive force is smaller and have bonding reversibility, expanded with heat and contract with cold for a long time, the erosion of hydraulic pressure, acid-alkali salt, the outside environmental elements such as material aging and the impact of material oneself factor, water-proof material can lose with basal plane and bonds and occur hollowing and obscission, causes channeling water, leaks.
Summary of the invention
The object of the invention is to develop a kind of waterproof sealing cream, its molecule can with cement or the effect of concrete surface generation chemical bonding, by physical adsorption and chemical bonding effect, improve the cohesive force of water-proof material and basal plane, waterproof layer and basal plane form the waterproof construction of skin-type, the phenomenon of greatly reduce channeling water, leaking, and waterproof sealing cream of the present invention can be constructed under moisture substrate environment, easy construction, efficiency are high.
Principle of the present invention is for raw material with synthetic rubber latex and modified rubber emulsified bitumen, add functional aid, by the coupled action of functional aid, synthetic rubber molecule is made to become to have the macromole of reactive behavior with asphaltene molecule coupling, when this macromole contacts with cement or concrete surface, rubber molecule and asphaltene molecule section and basal plane form physical adsorption, and there is macromole and the adsorption of basal plane generation chemical bonding of reactive behavior, produce very strong chemical interactions, therefore the cohesive force of water-proof material and cement or concrete surface just strengthens greatly, be difficult to be arrived by the such environmental effects in the external world.Waterproof sealing cream of the present invention is water-based, therefore can construct at the basal plane of humidity, in order to make the stable layering of not easily emanating of product, also needs to add thickening material, softening agent, filler etc.
Detailed technology scheme of the present invention is:
With the waterproof sealing cream of cement generation chemically crosslinked and physics mortise and tenon, comprise the raw material composition of following parts by weight:
Synthetic rubber latex 40 ~ 60; Modified rubber emulsified bitumen 20 ~ 30;
Functional aid 1 ~ 2; Thickening material 1 ~ 3;
Filler 10 ~ 30; Softening agent 0.5 ~ 5;
Water 2 ~ 5;
Considering that winter north weather is colder, for not affecting product construction in the winter time and storage, also adding the antifreezing agent of 0.5 ~ 2 parts by weight, described antifreezing agent is the composition of any one or they in ethylene glycol, 1,3-PD or glycerine.
Described modified rubber emulsified bitumen to be solid content be 50 ± 2% SBS modified emulsifying asphalt, styrene-butadiene rubber(SBR) modified emulsifying asphalt, chloroprene rubber modified emulsifying drop.
Described synthetic rubber latex solid content be 50 ± 2% styrene butadiene rubber latex, Neoprene latex, a kind of in SBS rubber latex or polyacrylate(s) or their composition;
Described functional aid has vinyl, hydroxyl, the coupling agent of amino or carboxyl, particularly there is hydroxyl, the polysiloxane coupling agent of amino or carboxyl-reactive functional group, poly-naphthalene formaldehyde sulfonate salt or their mixture, polysiloxane coupling agent comprises: hydroxyl alkyl polysiloxane, carboxyl polysiloxane, the derivative of dimethyl siloxane or cyclomethicone, as poly-methylethoxy base silane, fatty amide alkyl silane, carboxyl polysiloxane or 3-aminopropan Trimethoxy silane or they two kinds, two or more mixtures, the active group produced after their hydrolysis can play synergistic effect (the Chemical Bonding and Physical Crosslinking Synergism of chemically crosslinked-physics mortise and tenon with cement or concrete, be called for short CPS) additive (the present inventor application Chinese patent: Application Number (patent): CN200910114456.X, title: carry out the waterproof roll that bonding worked in coordination with by chemically crosslinked and physics mortise and tenon with concrete, open (bulletin) number: CN101694114A applies for (patent right) people: Guangxi Jiyusan Waterproof Decoration Co., Ltd. address: WangZhou Road, Nanning City, Guangxi Zhuang Autonomous nationality District 267-1 contriver: Lu Guicai, Wu Shengjiang, Zhu Fangwu, Guo Wenxiong) disclose two kinds wherein: poly-methylethoxy base silane and poly-naphthalene formaldehyde sulfonate salt.Through overtesting, we find except these two kinds of compounds, there is the coupling agent of hydroxyl, amino or carboxyl, particularly isobutyl triethoxy silane, 3-aminopropyl triethoxysilane, distearyl acyl-oxygen sec.-propyl Aluminate, sec.-propyl three (dioctylphyrophosphoric acid acyloxy) titanic acid ester all have and can carry out chemically crosslinked with cement and concrete and cohesive action worked in coordination with by physics mortise and tenon.
Described synthetic rubber latex solid content be 40 ~ 60% styrene butadiene rubber latex, Neoprene latex, any one or they in SBS rubber latex or polyacrylate(s) composition;
Described emulsified bitumen is petroleum pitch, emulsifying agent and water through high-speed emulsifying machine process obtain solid content be 40 ~ 70% emulsion or solid content be 40 ~ 60% SBS modified emulsifying asphalt, any one in styrene-butadiene rubber(SBR) modified emulsifying asphalt or chloroprene rubber modified emulsifying asphalt.
Described thickening material is a kind of in wilkinite, polyacrylamide, sodium polyacrylate, Xylo-Mucine, sodium alginate or association type urethane or their composition.
Described filler is a kind of in white carbon black, titanium dioxide, barium sulfate, potter's clay, zinc sulfide white, light calcium carbonate or water-ground limestone or their composition.
Described softening agent is any one or more mixture in dibutyl fumarate, dioctyl fumarate, dibutyl maleinate, dioctyl maleate or dibutyl azelate.
Above-mentioned with cement generation chemically crosslinked and the preparation method of the waterproof sealing cream of physics mortise and tenon be:
(1) normal temperature respectively puts into a tank two kinds of emulsions, first stirs;
(2) synthetic rubber latex adds modified rubber emulsified bitumen under stirring, functional aid is added after adding modified rubber emulsified bitumen, add softening agent, stir, finally add filler, thickening material, need to add antifreezing agent according to the environment for use of product, stir, namely obtain the waterproof sealing cream with cement generation chemically crosslinked and physics mortise and tenon.
The positively effect that the present invention produces: by the coupled action of functional aid, synthetic rubber molecule is made to become to have greatly the molecule of reactive behavior with asphaltene molecule coupling, when this macromole contacts with basal plane, rubber molecule and asphaltene molecule section and basal plane form physical adsorption, and there is the molecule of reactive behavior and the bonding action of basal plane generation chemical bond, produce very strong adsorption, therefore the cohesive force of waterproof sealing cream and basal plane is very strong, is not easy the impact being subject to extraneous factor; Add synthetic rubber latex and softening agent, overcome the shortcoming that conventional sealing material unit elongation is low, easy to crack, improve the snappiness of material, cohesiveness, material unit elongation is high, and tear resistance is strong.Waterproof sealing cream of the present invention is water-based, can construct on moisture substrate, easy construction.
Embodiment
Embodiment 1
With the preparation method of the waterproof sealing cream of cement generation chemically crosslinked and physics mortise and tenon:
(1) in two tanks, take 40 parts of neoprene latex latex rubbers and 20 parts of SBS modified emulsifying asphalts respectively, stir;
(2) under stirring, 20 parts of SBS modified emulsifying asphalts are joined in 40 parts of neoprene latex latex rubbers, then 1 part of isobutyl triethoxy silane is added, add 0.5 part of dibutyl fumarate, stir, add 30 parts of water-ground limestones, stir, finally add 1 part of association type urethane, thickening is carried out in stirring, obtains the waterproof sealing cream with cement generation chemically crosslinked and physics mortise and tenon.
Embodiment 2
With the preparation method of the waterproof sealing cream of cement generation chemically crosslinked and physics mortise and tenon:
(1) in two tanks, take 50 parts of styrene butadiene rubber latexes and 25 parts of styrene-butadiene rubber(SBR) modified emulsifying asphalts respectively, stir;
(2) under stirring, 25 parts of styrene-butadiene rubber(SBR) modified emulsifying asphalts are added in 50 parts of styrene butadiene rubber latexes, then 1.5 parts of 3-aminopropyl triethoxysilanes are added, add 2 parts of dioctyl maleates, stir, add 20 parts of light calcium carbonates again, stir, finally add 2 parts of wilkinites and 0.5 part of ethylene glycol, stir, obtain the waterproof sealing cream with cement generation chemically crosslinked and physics mortise and tenon.
Embodiment 3
With the preparation method of the waterproof sealing cream of cement generation chemically crosslinked and physics mortise and tenon:
(1) in two tanks, take 60 parts of SBS rubber latexs and 30 parts of chloroprene rubber modified emulsifying asphalts respectively, stir;
(2) under stirring, 30 parts of chloroprene rubber modified emulsifying asphalts are added in 60 parts of SBS rubber latexs, then 2 parts of distearyl acyl-oxygen sec.-propyl Aluminates are added, add 5 parts of dibutyl maleinates, stir, add 10 parts of white carbon blacks and 1 part of 1,3-PD, 2 parts of gelatin, stir, obtain the waterproof sealing cream with cement generation chemically crosslinked and physics mortise and tenon.
Embodiment 4
With the preparation method of the waterproof sealing cream of cement generation chemically crosslinked and physics mortise and tenon:
(1) in two tanks, take 52 parts of polymethyl acrylate emulsions and 26 parts of modified rubber emulsified bitumens respectively, stir;
(2) under stirring, 52 parts of polymethyl acrylate emulsions are added in 26 parts of modified rubber emulsified bitumens, then 1.4 parts of sec.-propyls three (dioctylphyrophosphoric acid acyloxy) titanic acid ester is added, add 3 parts of dibutyl azelates, stir, add 18 parts of heavy titanium dioxides, 1 part 1, ammediol and 1 part of glycerine, 1.5 parts of sodium polyacrylates, stir, and obtain the waterproof sealing cream with cement generation chemically crosslinked and physics mortise and tenon.
Embodiment 5
With the method for making of the waterproof sealing cream of cement generation chemically crosslinked and physics mortise and tenon:
(1) in two tanks, take 30 parts of neoprene latex latex rubbers and 40 parts of emulsified bitumens respectively, stir;
(2) under stirring, 30 parts of neoprene latex latex rubbers are added 40 parts of emulsified bitumens, then 1 portion of poly-naphthalene formaldehyde sulfonate salt is added, add 1 part of dioctyl fumarate, stir, add 30 parts of water-ground limestones, 0.5 part of polyacrylamide, 0.5 part of sodium alginate, stir, obtain the waterproof sealing cream with cement generation chemically crosslinked and physics mortise and tenon.
Embodiment 6
With the method for making of the waterproof sealing cream of cement generation chemically crosslinked and physics mortise and tenon:
(1) in two tanks, take 25 parts of styrene butadiene rubber latexes and 50 parts of emulsified bitumens respectively, stir;
(2) under stirring, 25 parts of styrene butadiene rubber latexes are added 50 parts of emulsified bitumens, then 2.5 parts of 3-aminopropyl triethoxysilanes are added, add 2 parts of dioctyl maleates, stir, add 25 parts of light calcium carbonates, 0.5 part of polyacrylamide, 2 parts of wilkinites, 8 parts of water, stir, and obtain the waterproof sealing cream with cement generation chemically crosslinked and physics mortise and tenon
Embodiment 7
With the method for making of the waterproof sealing cream of cement generation chemically crosslinked and physics mortise and tenon:
(1) in two tanks, take 20 parts of SBS rubber latexs and 60 parts of emulsified bitumens respectively, stir;
(2) under stirring, 20 parts of SBS rubber latexs are added 60 parts of emulsified bitumens, then 4 parts of distearyl acyl-oxygen sec.-propyl Aluminates are added, add 3 parts of dibutyl maleinates, stir, add 20 parts of potter's clay, 2 parts of association type urethane, 2 parts of gelatin, 6 parts of water, stir, and obtain the waterproof sealing cream with cement generation chemically crosslinked and physics mortise and tenon
Embodiment 8
With the method for making of the waterproof sealing cream of cement generation chemically crosslinked and physics mortise and tenon:
(1) in two tanks, take 22 parts of polymethyl acrylate emulsions and 48 parts of emulsified bitumens respectively, stir;
(2) under stirring, 22 parts of polymethyl acrylate emulsions are added in 48 parts of emulsified bitumens, then 2.4 parts of sec.-propyls three (dioctylphyrophosphoric acid acyloxy) titanic acid ester is added, add 3 parts of dibutyl azelates, stir, add 18 parts of heavy titanium dioxides, 2 parts of wilkinites, 0.5 part of Xylo-Mucine, 5 parts of water, stir, and obtain the waterproof sealing cream with cement generation chemically crosslinked and physics mortise and tenon.
According to the detection method of GB/T 13477.1 ~ 13477.20--2002 " construction sealing materials testing method " the inside to of the present invention with cement generation chemically crosslinked and the main performance index of the waterproof sealing cream of physics mortise and tenon test, result is as shown in table 1 below:
| Project | Elongation at break/% | Elongation at break/% after immersion | Elastic restoration ratio/% | Volumetric shrinkage/% | With cement concrete cohesive strength/MPa |
| Embodiment 1 | 385 | 330 | 86 | 17 | 0.60 |
| Embodiment 2 | 373 | 314 | 88 | 18 | 0.58 |
| Embodiment 3 | 250 | 220 | 73 | 20 | 0.51 |
| Embodiment 4 | 405 | 383 | 92 | 15 | 0.68 |
| Embodiment 5 | 315 | 289 | 82 | 18 | 0.55 |
| Embodiment 6 | 303 | 271 | 74 | 20 | 0.51 |
| Embodiment 7 | 278 | 252 | 71 | 24 | 0.46 |
| Embodiment 8 | 265 | 233 | 70 | 21 | 0.41 |
Find out from the data of table 1, of the present invention with cement generation chemically crosslinked and the waterproof sealing cream main performance index of physics mortise and tenon meet 12.5E type technical requirement in JC/T881-2001 " concrete construction seam seal gum " completely.
The Performance comparision of table 2 product of the present invention and sealing material fast-selling on the market
| Project | Execution conditions | With the cohesive strength/Mpa of concrete surface | Extension at break degree/% | Practicality |
| Product of the present invention | Can construct under wet environment, basal plane need not clean | 0.5～0.7 | 300～400 | Cost is low, non-volatility organic solvent, bonds well with the smooth surface such as plastics tubing, metallic conduit object, is suitable for wide |
| Polyurethane sealant | Basal plane must be dry, and clean | 0.3～0.5 | 200～300 | Moderate cost, raw materials for production are volatile carcinogenic substance, bond poor, easily peel off with the smooth surface such as plastics tubing, metallic conduit object |
| 208-Wet Patch of Henry company of the U.S. | Basal plane must be dry, and clean | 0.3～0.4 | 10～30 | Moderate cost, containing volatile organic solvent, bond poor with the smooth surface such as plastics tubing, metallic conduit object, easily peel off, do not have toughness, tack time is of a specified duration |
| Silicone sealant | Can construct under wet environment, basal plane need not clean | 0.3～0.4 | 100～150 | Cost is high, and the organic acid produced in solidification process can corrode basal plane, bonds poor, easily peel off with the smooth surface such as plastics tubing, metallic conduit object, |
To have cohesive strength high for product of the present invention and sealing material on the market as seen from Table 2, easy construction, cost is low, the advantages such as applied range, particularly be applied between plastic conduit and plastic conduit, between plastic conduit and concrete, between metallic substance, node between metallic substance and plastics or concrete, the sealing in gap, this have benefited from product of the present invention except with various material contacting surface generation physisorption power except, active chemical group in product of the present invention can with contact surface generation chemisorption power, thus it is large to produce intensity, stable, irreversible chemical bonding, greatly increase the cohesive strength with basal plane, the waterproof construction of skin-type is defined with basal plane, water resistance is very outstanding.
Of the present invention with cement generation chemically crosslinked with the constructional method of the waterproof sealing cream of physics mortise and tenon:
(1) base treatment: basal plane solid smooth, without floating dust, without greasy dirt.Dry basal plane water in advance wetting effect is better, or at basal plane film lean concrete grout, just can when lean concrete grout initial set.Pipe root limit or drain gully etc. will smear into circular arc with basic unit seam crossing, and arc radius is preferably 5cm.
(2) brush seals cream: with hairbrush or slurry cutter by sealing compound uniform application in crack, Guan Gen, gutter, eaves gutter, the position of joints such as negative and positive angle, the general 2-3 that brushes is all over completing, and gauge control is at 1.5 ~ 2.5mm;
Wide 10cm is smeared at pipe root node circumference place, and pipe root smears high 5cm, and painting process paving grid cloth, non-woven fabrics etc. can be strengthened tire sill and make enhancement process, and brushing should adopt the method for scumbling multipass to carry out.
(3) maintenance: ensure ventilation, drying after construction, strengthen finished product protection, generally solidifies completely for 2-3 days after brushing, stuffy or wet environment, set time then can extend.
(4) subsequent construction: when doing subsequent construction on water-tight layer, must carry out after coating is solidified completely.
Of the present invention with cement generation chemically crosslinked with the scope of application of the waterproof sealing cream of physics mortise and tenon: all types of plastic, metal tube root limit, water fall the encapsulation process of the node such as mouth and concrete structure lap-joint and the encapsulation process of the position of joints such as distress in concrete, seam, construction joint, movement joint; Be applicable to indoor, roofing modular repair mending-leakage.
Claims (2)
1., with the waterproof sealing cream of cement generation chemically crosslinked and physics mortise and tenon, it is characterized in that, comprise the raw material of following parts by weight:
Synthetic rubber latex 20 ~ 60;
Emulsified bitumen 20 ~ 60;
Functional aid 1 ~ 4;
Thickening material 1 ~ 3;
Filler 10 ~ 30;
Softening agent 0.5 ~ 5;
Water 2 ~ 10;
Described synthetic rubber latex solid content be 40 ~ 60% styrene butadiene rubber latex, Neoprene latex, any one or they in SBS rubber latex or polyacrylate(s) composition;
Described emulsified bitumen is petroleum pitch, emulsifying agent and water through high-speed emulsifying machine process obtain solid content be 40 ~ 70% emulsion or solid content be 40 ~ 60% SBS modified emulsifying asphalt, any one in styrene-butadiene rubber(SBR) modified emulsifying asphalt or chloroprene rubber modified emulsifying asphalt;
Described functional aid is any one in isobutyl triethoxy silane, 3-aminopropyl triethoxysilane, distearyl acyl-oxygen sec.-propyl Aluminate, sec.-propyl three (dioctylphyrophosphoric acid acyloxy) titanic acid ester or poly-naphthalene formaldehyde sulfonate salt;
Described thickening material is a kind of in wilkinite, polyacrylamide, sodium polyacrylate, Xylo-Mucine, starch ethers, sodium alginate or association type urethane or their composition;
Described filler is the mixture of any one or more in white carbon black, titanium dioxide, barium sulfate, potter's clay, zinc sulfide white, light calcium carbonate or water-ground limestone;
Described softening agent is any one or more mixture in dibutyl fumarate, dioctyl fumarate, dibutyl maleinate, dioctyl maleate or dibutyl azelate.
2. according to claim 1 with cement generation chemically crosslinked with the waterproof sealing cream of physics mortise and tenon, it is characterized in that, also comprise the antifreezing agent of 0 ~ 0.5 parts by weight, described antifreezing agent is the mixture of any one or more of glycerine, ethylene glycol, 1,3-PD or calcium chloride.
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101694114A (en) * | 2009-10-09 | 2010-04-14 | 广西金雨伞防水装饰有限公司 | Waterproof roll capable of carrying out chemical bonding and physical crosslinking synergism with concrete |
| CN102911638A (en) * | 2012-11-10 | 2013-02-06 | 广西金雨伞防水装饰有限公司 | Reaction bonding type node sealant and preparation method thereof |
| CN102936439A (en) * | 2012-11-27 | 2013-02-20 | 湖北工业大学 | Water-emulsified chloroprene rubber modified asphalt waterproof paint and preparation method thereof |
| CN102964929A (en) * | 2012-11-30 | 2013-03-13 | 山东北方创信防水技术有限公司 | Spraying rapid-hardening rubber asphalt water proofing material for drinking water pond |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6706787B1 (en) * | 2000-12-05 | 2004-03-16 | Flex Products, Inc. | Method for preparing asphalt/polymer emulsion-rubber paving composition |
-
2013
- 2013-07-03 CN CN201310276909.5A patent/CN103304862B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101694114A (en) * | 2009-10-09 | 2010-04-14 | 广西金雨伞防水装饰有限公司 | Waterproof roll capable of carrying out chemical bonding and physical crosslinking synergism with concrete |
| CN102911638A (en) * | 2012-11-10 | 2013-02-06 | 广西金雨伞防水装饰有限公司 | Reaction bonding type node sealant and preparation method thereof |
| CN102936439A (en) * | 2012-11-27 | 2013-02-20 | 湖北工业大学 | Water-emulsified chloroprene rubber modified asphalt waterproof paint and preparation method thereof |
| CN102964929A (en) * | 2012-11-30 | 2013-03-13 | 山东北方创信防水技术有限公司 | Spraying rapid-hardening rubber asphalt water proofing material for drinking water pond |
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Address after: 530216 scientific research building, Xiniu science and Technology Park, No. 68, team 4, naluopo, Sitang community, Santang Town, Xingning District, Nanning City, Guangxi Zhuang Autonomous Region Patentee after: Xiniupi Waterproof Technology Co.,Ltd. Address before: 530002 Donggouling Landscape Road, Xingning District, Nanning City, Guangxi Zhuang Autonomous Region, Lin18 Sunshine Green City, 1 Building, 1 Unit 4 Patentee before: Xiniupi Waterproof Technology Co.,Ltd. |
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