CN105295142A - Reaction type compound waterproof sealing cream containing sulfydryl bridging agent and preparation method of reaction type compound waterproof sealing cream - Google Patents
Reaction type compound waterproof sealing cream containing sulfydryl bridging agent and preparation method of reaction type compound waterproof sealing cream Download PDFInfo
- Publication number
- CN105295142A CN105295142A CN201410330357.6A CN201410330357A CN105295142A CN 105295142 A CN105295142 A CN 105295142A CN 201410330357 A CN201410330357 A CN 201410330357A CN 105295142 A CN105295142 A CN 105295142A
- Authority
- CN
- China
- Prior art keywords
- thickening material
- bridging agent
- sealing compound
- rubber latex
- emulsified bitumen
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Abstract
The invention aims to provide a reaction type compound waterproof sealing cream containing a sulfydryl bridging agent and a preparation method of the reaction type compound waterproof sealing cream. The waterproof sealing cream comprises synthetic rubber latex, emulsified asphalt and the bridging agent. The bridging agent is added into the formula system, through the adoption of the bridging agent, asphalt and rubber in the waterproof sealing cream and uncured cement or concrete can form the chemical crosslinking and physical mortise and tenon synergic bonding function, the sealing cream and the cement can be tightly combined together, related parts have the chemical bond function, an irreversible bonding function is achieved after curing, and the waterproof sealing cream can wriggle to permeate into capillary pores of the cement gel and concrete in the cement setting process, so as to play a tightly combined, firm and irreversible flesh-blood connecting bonding role.
Description
Technical field
The present invention relates to a kind of water-tight field, particularly relate to a kind of response type composite water-proof sealing compound containing sulfydryl bridging agent and preparation method thereof.
Background technology
At present, differ greatly at PPR or the PVC supplying drainage at building kitchen and toilet passing through floors position and the linear expansivity of concrete floor, under normal temperature, concrete is 1*10
-5/ DEG C, PPR or PVC are (6 ~ 7) * 10
-5/ DEG C, after seasonal cold and hot freeze-thaw cycle several times, supplying drainage and concrete floor junction are easy to occur gap, therefore, during the construction of building kitchen and toilet water supply and sewerage pipeline, when passing through floors position PPR or the construction of PVC supplying drainage, need to carry out water-tight process.Existing water-tight treatment technology has following several modes:
Modifying asphalt encapsulation process, adopt modifying asphalt to build after hot melt under optimal temperature, complicated operation during this construction technology, temperature controls with coating process very crucial.First, when hot-melt asphalt, temperature control is just right, if temperature is too high, pitch mobility is excessively good, and pitch can be made cannot to adhere to on PPR or PVC, cannot realize sealing, and when temperature is more than 100 DEG C, easily damage; If temperature is too low, pitch and PPR or PVC and concrete adhesion property all can not reach requirement.Second is that when constructing, gimmick wants exactissima diligentia, coating is very even, often to carry out for several times above coating repeatedly, this is because modifying asphalt and PPR or PVC and concrete adhesiving effect not ideal enough, only have and made up by gimmick of constructing.
The process of asphalt mixture sealing compound, what utilize unfilled bitumen, fibre object and solvent is mixed with into sealing compound, and sealing cream becomes the character of viscous liquid state under having normal temperature, and the envelope that can be directly used in cement and pipeline junction is coated with, such as U.S. Henry company
the roof leakage maintenance product of plate.Such sealing compound, but such sealing compound has used the organic solvent of low volatility as solvent, and time of drying is slow, often needs the time of fortnight more than could drying, and when basal plane humidity, because cannot adhere to basal plane, and can not construct; And because main component is pitch and fibre object composition, after drying, sealing ply does not have elasticity, and intensity is poor, inadequate durable.
Polyurethane sealant, take urethane as main component, can directly use at normal temperatures, shortcoming be with PPR or PVC and concrete adhesiving effect not ideal enough, and cannot to construct when basal plane is moist.
Silicone sealant, with water glass and the material such as organosilicon, silicone structure polymkeric substance for main component, with PPR or PVC and concrete adhesiving effect better, but its poor stability, can not be lasting under solar radiation or dampness, easily come off, intensity is also poor, can not meet construction requirement.
Polyacrylic resin sealing compound take crylic acid resin as main component, and its preparation technology's more complicated, needs the modification carrying out high request, be prepared into water-borne acrylic resin, be then prepared into emulsion.Polyacrylic resin sealing compound can be constructed on moisture substrate, but itself and PPR or PVC and concrete adhesiving effect poor.
In sum, also there is many deficiencies in encapsulation process technology when PPR or the PVC supplying drainage of prior art at passing through floors position is constructed, and is badly in need of finding a kind of preparation technology simple, easy construction, water-tight performance is good, and intensity is high, long-lived new waterproof sealing prod.
Summary of the invention
The present invention aims to provide a kind of response type composite water-proof sealing compound containing sulfydryl bridging agent and preparation method thereof, and this waterproof sealing cream preparation technology is simple, and easy construction, water-tight performance is good, and intensity is high, durable in use.
Waterproof sealing cream of the present invention is prepared from by the raw material comprising following parts by weight:
Described bridging agent is hydrosulphonyl silane, and the carboxyl of one end in pitch of hydrosulphonyl silane is combined, and the acid group that the other end produces after hydrated cementitious is combined, and erects the waterproof bridge of a water-proof material;
Its general formula is as follows:
Wherein,
X is Cl ,-OC
nh
2n+1or CH
3;
N is the natural numerical value between 1-10.
Described synthetic rubber latex and the mixed total solid content of emulsified bitumen are 20%-80%.
Described synthetic rubber latex is the mixture of any one or more in styrene butadiene rubber latex, carboxylic styrene-butadiene rubber latex, Neoprene latex, SBS rubber latex, polyacrylate(s).
Described emulsified bitumen is cationic emulsified bitumen, non ionic emulsified bitumen or anionic emulsified bitumen.
Described emulsified bitumen is one or more the mixture in SBS modified emulsifying asphalt, carboxylic styrene-butadiene rubber latex, styrene-butadiene rubber(SBR) modified emulsifying asphalt or chloroprene rubber modified emulsifying asphalt.
The rubber that buildings waterproof field adopts, the form mostly being mixture exists, and therefore, above-mentioned rubber latex any ratio can carry out mixing utilization.
The petroleum pitch that buildings waterproof field adopts, the form mostly being mixture exists, and therefore, above-mentioned various petroleum pitch emulsion any ratio can carry out mixing utilization.
Described bridging agent is all consistent with concrete reaction mechanism, and between each bridging agent, its chemical property is also similar, therefore can any ratio used in combination.
Described thickening material is the mixture of the one or more than one in ether of cellulose and derivative thereof, alkali swelling type thickening material, polyurethane thickener, the non-polyurethane thickener of hydrophobically modified, inorganic thickening agent, solvay-type organometallic compound class thickening material, polyacrylamide, sodium polyacrylate, Xylo-Mucine, sodium alginate.
Described ether of cellulose and derivative thereof comprise Natvosol, methyl hydroxyethylcellulose, Type 3U, methylhydroxypropylcellulose, methylcellulose gum, hydrophobically modified Mierocrystalline cellulose, xanthan gum, guar gum.
Described alkali swelling type thickening material comprises non-association type polyacrylic acid saline and alkaline swelling type emulsion, the saline and alkaline swelling type emulsion of association type polyacrylic acid.
Described polyurethane thickener and the non-polyurethane thickener of hydrophobically modified comprise anionic associative polyurethane thickening material, cationic associative polyurethane thickening material, non-ionic type associative polyurethane thickening material, hydrophobically modified amino thickening material, hydrophobically modified polyethers thickening material, hydrophobically modified polyurea thickener.
Described inorganic thickening agent comprises wilkinite, attapulgite, aerosil.
Described bridging agent comprises mercaptopropyl trimethoxysilane, mercaptopropyltriethoxysilane.
Described waterproof sealing cream, its production method comprises the following steps: synthetic rubber latex, emulsified bitumen, bridging agent are injected in still, after stirring, added by thickening material in still, mixing and stirring.
Bridging agent is added in formula system of the present invention, this composition serves vital effect for lift-off seal lotion system to concrete bonding force, be one of core technology in the present invention, contriver have passed through a large amount of screening experiments and determines these bridging agent compositions.Its principle is as follows: the sulfydryl in bridging agent is in reactor blending process, because temperature reaches reaction conditions, meeting and pitch and rubber generation crosslinking reaction, form crosslinked network connection architecture, more firmly firm with the connection of pitch and rubber; Simultaneously because concrete has building stones and the blended solidification of cement to form, generate hydrated calcium silicate (C-S-H gel) and calcium hydroxide after hydrated cementitious, surface is containing a large amount of active Si-OH groups and electronegatively contain oxygen mineral compound.The sealing compound bridging of cement and asphalt rubber composition, just by this bridging agent, gets up, forms firmly water-tight system, thus obtain the waterproof effect surmounting existing any waterproof sealing cream by the present invention.
Its reaction mechanism is as follows:
1, react with pitch and rubber
Wherein
represent the compound containing carboxyl in pitch and rubber.
2, react with concrete
1. water at normal temperature mud generation hydration reaction generates hydrated calcium silicate (C-S-H gel) and Ca (OH)
2, there is Si-OH group in CSH gel, reaction formula: 3CaOSiO
2+ nH
2o=xCaSiO
2yH
2o+ (3-x) Ca (OH)
2
2. the active group in glue-line meets water hydrolysis:
3. hydrolysis generates Si-OH radical reaction in Si-OH group and CSH gel and generates ehter bond, makes hydrated calcium silicate gel and coiled material surface generate chemical bond and secure bond.React as follows:
The mechanism that one end and aluminic acid cement, sulphur aluminic acid cement or the iron aluminic acid cement of described hydrosulphonyl silane react also is the same.The carboxyl of one end in pitch of described hydrosulphonyl silane is combined, and the acid group that the other end produces after hydrated cementitious is combined.The acid group produced after described hydrated cementitious is silicate, aluminate, sulphur aluminate or iron aluminate.That is, above-described hydrosulphonyl silane tar cement waterproof bridging agent, the sulfydryl of structural formula one end of this bridging agent can couple together with the carboxyl of pitch, form good chemical affinity, and the other end of silane is in the concrete adding water and cement, produce the chemical bond of aquation, carry out with concrete that chemically crosslinked and physics mortise and tenon are collaborative to bond, pitch and cement are closely coupled as one, there is chemical bond in region of interest, irreversible cohesive action is played after solidification, waterproof sealing cream can be made, its oil-proofness and flexible resistance are given prominence to, and it is nontoxic, safety and environmental protection, pollution-free, at cement, can wriggle in the process of concrete setting and penetrate in cement gel and concrete pore, reach and combine closely, firmly, irreversible as closely linked as flesh and blood bond effect.Want to take away or peel off waterproof layer, be difficult to accomplish.
Hydrosulphonyl silane bridging agent of the present invention, at the coupling compound with the hydroxyl in cement gel, ehter bond and silicon-dioxide, can not cause the infringement to reinforcing bar.
The present invention has used the bridging agent that simultaneously can react with pitch, rubber and concrete, and traditional product compared by the waterproof sealing cream made, and has better Concrete Bond Strength and peel strength.
Relatively large thickening material is adopted in formula system of the present invention, the main purpose of utilization thickening material is the viscosity in order to increase emulsified bitumen and rubber waterproof sealing compound system, make emulsified bitumen and rubber waterproof sealing compound can be used in pipe root, wall and do not occur the phenomenons such as downslide, sagging, realize the good sealing of PPR or PVC supplying drainage and concrete floor junction.
Embodiment
Embodiment 1
Described synthetic rubber latex is Neoprene latex;
Described emulsified bitumen is SBS modified rubber emulsified bitumen;
Described bridging agent is mercaptopropyl trimethoxysilane.
Described thickening material is ether of cellulose and derivative thereof, is specially methylhydroxypropylcellulose;
Described synthetic rubber latex and the mixed total solid content of emulsified bitumen are 60%;
Synthetic rubber latex, emulsified bitumen, bridging agent are injected in still, after stirring, thickening material is added in still, mixing and stirring.
Embodiment 2
Described synthetic rubber latex is styrene butadiene rubber latex;
Described emulsified bitumen is neoprene latex modified emulsifying asphalt;
Described bridging agent is mercaptopropyltriethoxysilane;
Described thickening material is polyurethane thickener, is specially cationic associative polyurethane thickening material;
Described synthetic rubber latex and the mixed total solid content of emulsified bitumen are 20%;
Synthetic rubber latex, emulsified bitumen, bridging agent are injected in still, after stirring, thickening material is added in still, mixing and stirring.
Embodiment 3
Described synthetic rubber latex is SBS rubber latex;
Described emulsified bitumen is chloroprene rubber modified emulsifying asphalt;
Described bridging agent is mercaptopropyl trimethoxysilane;
Described thickening material is alkali swelling type thickening material, is specially the saline and alkaline swelling type emulsion of non-association type polyacrylic acid;
Described synthetic rubber latex and the mixed total solid content of emulsified bitumen are 20%;
Synthetic rubber latex, emulsified bitumen, bridging agent are injected in still, after stirring, thickening material is added in still, mixing and stirring.
Embodiment 4
Described synthetic rubber latex is the mixture of styrene butadiene rubber latex, Neoprene latex;
Described emulsified bitumen is the mixture of SBS modified emulsifying asphalt and styrene-butadiene rubber(SBR) modified emulsifying asphalt;
Described bridging agent is mercaptopropyltriethoxysilane;
Described thickening material is ether of cellulose and derivative thereof, is specially Natvosol;
Described synthetic rubber latex and the mixed total solid content of emulsified bitumen are 30%;
Synthetic rubber latex, emulsified bitumen, bridging agent are injected in still, after stirring, thickening material is added in still, mixing and stirring.
Embodiment 5
Described synthetic rubber latex polyacrylic ester latex;
Described emulsified bitumen is APP modified emulsifying asphalt;
Described bridging agent is the mixture of mercaptopropyl trimethoxysilane, mercaptopropyltriethoxysilane;
Described thickening material is ether of cellulose and derivative thereof, is specially the mixture of Type 3U and guar gum.
Described synthetic rubber latex and the mixed total solid content of emulsified bitumen are 40%;
Synthetic rubber latex, emulsified bitumen, bridging agent are injected in still, after stirring, thickening material is added in still, mixing and stirring.
Embodiment 6
Described synthetic rubber latex is SBS rubber latex;
Described emulsified bitumen is isoprene-isobutylene rubber modifying asphalt latex;
Described bridging agent is the mixture of mercaptopropyl trimethoxysilane, mercaptopropyltriethoxysilane;
Described thickening material is alkali swelling type thickening material, is specially the mixture of non-association type polyacrylic acid saline and alkaline swelling type emulsion and the saline and alkaline swelling type emulsion of association type polyacrylic acid;
Described synthetic rubber latex and the mixed total solid content of emulsified bitumen are 50%;
Synthetic rubber latex, emulsified bitumen, bridging agent are injected in still, after stirring, thickening material is added in still, mixing and stirring.
Embodiment 7
Described synthetic rubber latex is polyacrylic ester latex;
Described emulsified bitumen is SBR modified emulsifying asphalt;
Described bridging agent is the mixture of mercaptopropyl trimethoxysilane, mercaptopropyltriethoxysilane.
Described thickening material is polyurethane thickener, is specially non-ionic type associative polyurethane thickening material, the amino thickening material of hydrophobically modified;
Described synthetic rubber latex and the mixed total solid content of emulsified bitumen are 60%;
Synthetic rubber latex, emulsified bitumen, bridging agent are injected in still, after stirring, thickening material is added in still, mixing and stirring.
Embodiment 8
Described synthetic rubber latex is the mixture of Neoprene latex and SBS rubber latex;
Described emulsified bitumen be APP modified emulsifying asphalt and mixture;
Described bridging agent is the mixture of mercaptopropyl trimethoxysilane, mercaptopropyltriethoxysilane;
Described thickening material is hydrophobically modified polyethers thickening material;
Described synthetic rubber latex and the mixed total solid content of emulsified bitumen are 70%;
Synthetic rubber latex, emulsified bitumen, bridging agent are injected in still, after stirring, thickening material is added in still, mixing and stirring.
Embodiment 9
Described synthetic rubber latex is the mixture of SBS rubber latex or polyacrylic ester latex;
Described emulsified bitumen is chloroprene rubber modified emulsifying asphalt;
Described bridging agent is the mixture of mercaptopropyl trimethoxysilane, mercaptopropyltriethoxysilane;
Described thickening material is solvay-type organometallic compound class thickening material;
Described synthetic rubber latex and the mixed total solid content of emulsified bitumen are 80%;
Synthetic rubber latex, emulsified bitumen, bridging agent are injected in still, after stirring, thickening material is added in still, mixing and stirring.
Embodiment 10
Described synthetic rubber latex is styrene butadiene rubber latex;
Described emulsified bitumen is SBS modified emulsifying asphalt;
Described bridging agent is mercaptopropyl trimethoxysilane;
Described thickening material is sodium polyacrylate;
Described synthetic rubber latex and the mixed total solid content of emulsified bitumen are 65%;
Synthetic rubber latex, emulsified bitumen, bridging agent are injected in still, after stirring, thickening material is added in still, mixing and stirring.
Embodiment 11
Described synthetic rubber latex is carboxylic styrene-butadiene rubber latex;
Described emulsified bitumen is SBS modified emulsifying asphalt;
Described bridging agent is the mixture of described mercaptopropyl trimethoxysilane, mercaptopropyltriethoxysilane.
Plant acid type monoalkoxy class titanic acid ester;
Described thickening material is gaseous silicon oxide;
Described synthetic rubber latex and the mixed total solid content of emulsified bitumen are 75%;
Synthetic rubber latex, emulsified bitumen, bridging agent are injected in still, after stirring, thickening material is added in still, mixing and stirring.
Embodiment 12
The present invention introduces the bridging agent containing two kinds of different chemical active groups, wherein a kind of group can with cement basal plane generation chemically crosslinked effect, another group can be combined with pitch and rubber and form fine and close spacial framework, the synergy of final physical mortise and tenon and chemically crosslinked, water-proof material is enable to be closely integrated into Unified Global with cement or concrete surface, effectively overcome traditional diadactic structure bonding insecure, cold and heat succeed each other, under drying and watering cycle condition easily and the defect peeled off of basal plane, the water resistance of water-proof material is significantly improved.Meanwhile, waterproof sealing cream of the present invention is water-based, therefore can construct at the basal plane of humidity, convenient to use.
Product performance
Can be there is chemically crosslinked effect again owing to can produce physics mortise and tenon with basal plane in product, be therefore the performance innovative point of this product with the adhesive effect of basal plane excellence.Comparative test result is in table 1:
Table 1
Embodiment 13
After part bridging agent adds sealing compound system, concrete waterproof parameter comparison, the results are shown in Table 2:
Table 2
Under equal addition prerequisite, basically identical to material and cement basal plane cohesive strength, shows that the bridging agent added also has same effect in bonding.And at performance of watertightness, low-temperature performance, anti-channeling water aspect of performance increases, especially low temperature flexibility and anti-channeling water sex expression more outstanding.Through experimental verification, the water-fast persistence of material after adding new bridging agent, can be improved.Because after adding New function auxiliary agent, become after sealing compound is shaping and solid there is elastic sealing ply, and sealing ply inside is rubbery state, can effective the entering or permeate of block water molecule, and there is hydrophobicity performance, therefore more excellent at waterproof and anti-channeling water aspect of performance.After adding new bridging agent, sealing compound is shaping based on rubbery state, and rubber originally has superiority in low-temperature performance aspect, so the low-temperature performance of sealing compound improves.
Claims (12)
1. a response type composite water-proof sealing compound, is characterized in that being, is to be prepared from by the raw material comprising following parts by weight:
Described bridging agent is hydrosulphonyl silane, and the carboxyl of one end in pitch of hydrosulphonyl silane is combined, and the acid group that the other end produces after hydrated cementitious is combined, and erects the waterproof bridge of a water-proof material;
Its general formula is as follows:
Wherein,
X is Cl ,-OC
nh
2n+1or CH
3;
N is the natural numerical value between 1-10.
2. response type composite water-proof sealing compound according to claim 1, is characterized in that: described synthetic rubber latex and the mixed total solid content of emulsified bitumen are 20%-80%.
3. response type composite water-proof sealing compound according to claim 1, is characterized in that: described synthetic rubber latex is the mixture of any one or more in styrene butadiene rubber latex, carboxylic styrene-butadiene rubber latex, Neoprene latex, SBS rubber latex, polyacrylate(s).
4. response type composite water-proof sealing compound according to claim 1, is characterized in that: described emulsified bitumen is cationic emulsified bitumen, non ionic emulsified bitumen or anionic emulsified bitumen.
5. response type composite water-proof sealing compound according to claim 1, is characterized in that: described emulsified bitumen is one or more the mixture in SBS modified emulsifying asphalt, styrene-butadiene rubber(SBR) modified emulsifying asphalt or chloroprene rubber modified emulsifying asphalt.
6. response type composite water-proof sealing compound according to claim 1, is characterized in that: described thickening material is the mixture of the one or more than one in ether of cellulose and derivative thereof, alkali swelling type thickening material, polyurethane thickener, the non-polyurethane thickener of hydrophobically modified, inorganic thickening agent, solvay-type organometallic compound class thickening material, polyacrylamide, sodium polyacrylate, Xylo-Mucine, sodium alginate.
7. response type composite water-proof sealing compound according to claim 6, is characterized in that: described ether of cellulose and derivative thereof comprise Natvosol, methyl hydroxyethylcellulose, Type 3U, methylhydroxypropylcellulose, methylcellulose gum, hydrophobically modified Mierocrystalline cellulose, xanthan gum, guar gum.
8. response type composite water-proof sealing compound according to claim 6, is characterized in that: described alkali swelling type thickening material comprises non-association type polyacrylic acid saline and alkaline swelling type emulsion, the saline and alkaline swelling type emulsion of association type polyacrylic acid.
9. response type composite water-proof sealing compound according to claim 6, is characterized in that: described polyurethane thickener and the non-polyurethane thickener of hydrophobically modified comprise anionic associative polyurethane thickening material, cationic associative polyurethane thickening material, non-ionic type associative polyurethane thickening material, hydrophobically modified amino thickening material, hydrophobically modified polyethers thickening material, hydrophobically modified polyurea thickener.
10. response type composite water-proof sealing compound according to claim 6, is characterized in that: described inorganic thickening agent comprises wilkinite, attapulgite, aerosil.
11. response type composite water-proof sealing compounds according to claim 1, is characterized in that:
Described bridging agent comprises mercaptopropyl trimethoxysilane, mercaptopropyltriethoxysilane.
12. according to the response type composite water-proof sealing compound of claim 1-10 described in any one, it is characterized in that, its production method comprises the following steps: inject in still, after stirring by synthetic rubber latex, emulsified bitumen, bridging agent, thickening material is added in still, mixing and stirring.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410330357.6A CN105295142A (en) | 2014-07-12 | 2014-07-12 | Reaction type compound waterproof sealing cream containing sulfydryl bridging agent and preparation method of reaction type compound waterproof sealing cream |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410330357.6A CN105295142A (en) | 2014-07-12 | 2014-07-12 | Reaction type compound waterproof sealing cream containing sulfydryl bridging agent and preparation method of reaction type compound waterproof sealing cream |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN105295142A true CN105295142A (en) | 2016-02-03 |
Family
ID=55193031
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410330357.6A Pending CN105295142A (en) | 2014-07-12 | 2014-07-12 | Reaction type compound waterproof sealing cream containing sulfydryl bridging agent and preparation method of reaction type compound waterproof sealing cream |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN105295142A (en) |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1477174A (en) * | 2002-08-21 | 2004-02-25 | 上海挪亚环境资源开发有限公司 | Water-proofing roll material using paper-making waste mud as filling agent |
| CN1649965A (en) * | 2002-04-24 | 2005-08-03 | 旭化成化学株式会社 | Asphalt composition |
| CN101426749A (en) * | 2006-04-21 | 2009-05-06 | 路博润高级材料公司 | Elastomeric emulsion polymers for masonry coatings |
| CN102911638A (en) * | 2012-11-10 | 2013-02-06 | 广西金雨伞防水装饰有限公司 | Reaction bonding type node sealant and preparation method thereof |
| CN103160234A (en) * | 2013-04-09 | 2013-06-19 | 南京大学 | High-performance thermosetting epoxy resin adhesive for roads and bridges and preparation method thereof |
| CN103304862A (en) * | 2013-07-03 | 2013-09-18 | 广西金雨伞防水科技有限公司 | Waterproof sealing paste producing chemical crosslinking and physical mortising with cement |
| CN103468142A (en) * | 2013-08-16 | 2013-12-25 | 安徽快来防水防腐有限公司 | Solvent type petroleum asphalt waterproof coating |
| CN103897398A (en) * | 2014-03-27 | 2014-07-02 | 中科院广州化学有限公司南雄材料生产基地 | Silica sol reinforced water-based organic silicone elastomer as well as preparation method and application thereof |
-
2014
- 2014-07-12 CN CN201410330357.6A patent/CN105295142A/en active Pending
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1649965A (en) * | 2002-04-24 | 2005-08-03 | 旭化成化学株式会社 | Asphalt composition |
| CN1477174A (en) * | 2002-08-21 | 2004-02-25 | 上海挪亚环境资源开发有限公司 | Water-proofing roll material using paper-making waste mud as filling agent |
| CN101426749A (en) * | 2006-04-21 | 2009-05-06 | 路博润高级材料公司 | Elastomeric emulsion polymers for masonry coatings |
| CN102911638A (en) * | 2012-11-10 | 2013-02-06 | 广西金雨伞防水装饰有限公司 | Reaction bonding type node sealant and preparation method thereof |
| CN103160234A (en) * | 2013-04-09 | 2013-06-19 | 南京大学 | High-performance thermosetting epoxy resin adhesive for roads and bridges and preparation method thereof |
| CN103304862A (en) * | 2013-07-03 | 2013-09-18 | 广西金雨伞防水科技有限公司 | Waterproof sealing paste producing chemical crosslinking and physical mortising with cement |
| CN103468142A (en) * | 2013-08-16 | 2013-12-25 | 安徽快来防水防腐有限公司 | Solvent type petroleum asphalt waterproof coating |
| CN103897398A (en) * | 2014-03-27 | 2014-07-02 | 中科院广州化学有限公司南雄材料生产基地 | Silica sol reinforced water-based organic silicone elastomer as well as preparation method and application thereof |
Non-Patent Citations (1)
| Title |
|---|
| 李永河 主编: "《橡胶硫化技术》", 31 May 2012, 黄河水利出版社 * |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN105238292A (en) | Reactive type modified emulsified asphalt and rubber waterproof sealant, and preparation method therefor | |
| CN105315915A (en) | Reaction type modified emulsified rubber-asphalt waterproof sealing paste and preparation method thereof | |
| CN105315526A (en) | Reaction type composite waterproof sealing paste containing isocyanate bridging agent and preparation method thereof | |
| CN105315961A (en) | Reaction type modified emulsified asphalt waterproof sealing paste and preparation method thereof | |
| CN105237839A (en) | Reactive composite waterproof sealant containing methacryloyloxy bridging agent and preparation method for reactive composite waterproof sealant | |
| CN105273661A (en) | Reactive composite waterproof sealant containing epoxyalkyl bridging agent and preparation method thereof | |
| CN105273260A (en) | Reactive composite waterproof sealant containing alkylene bridging agent and preparation method thereof | |
| CN105238301A (en) | Reactive composite waterproof sealant containing methylacryloyloxy bridging agent and preparation method for reactive composite waterproof sealant | |
| CN105273652A (en) | Isocyanate bridging agent-containing reactive asphalt waterproofing sealant and preparation method thereof | |
| CN105237806A (en) | Reactive asphalt waterproof sealant containing alkenyl bridging agent and preparation method for reactive asphalt waterproof sealant | |
| CN105315921A (en) | Reaction type composite waterproof sealing paste containing mercapto bridging agent and preparation method thereof | |
| CN105237840A (en) | Reactive rubber waterproof sealant containing isocyanate bridging agent and preparation method for reactive rubber waterproof sealant | |
| CN105238293A (en) | Reactive composite waterproof sealant containing ammonia sulfhydryl bridging agent and preparation method for composite waterproof sealant | |
| CN105295142A (en) | Reaction type compound waterproof sealing cream containing sulfydryl bridging agent and preparation method of reaction type compound waterproof sealing cream | |
| CN105295775A (en) | Reaction-type composite water-proof sealant containing epoxy alkyl bridging agent, and preparation method for sealant | |
| CN105295767A (en) | Reaction type modified emulsified rubber waterproof sealant and preparation method thereof | |
| CN105273235A (en) | Mercapto bridging agent-containing reactive asphalt waterproofing sealant and preparation method thereof | |
| CN105273685A (en) | Methacryloxy bridging agent-containing reactive asphalt waterproofing sealant and preparation method thereof | |
| CN105273686A (en) | Epoxyalkyl bridging agent-containing reactive asphalt waterproofing sealant and preparation method thereof | |
| CN105273261A (en) | Alkylene bridging agent-containing reactive composite waterproofing sealant and preparation method thereof | |
| CN105273662A (en) | Mercapto bridging agent-containing reactive rubber waterproofing sealant and preparation method thereof | |
| CN105295768A (en) | Reaction type rubber waterproof sealing cream containing methylacryloyl oxy bridging agent and preparation method of reaction type rubber waterproof sealing cream | |
| CN105273259A (en) | Reactive composite waterproof sealant containing isocyanate bridging agent and preparation method thereof | |
| CN105238294A (en) | Reactive rubber waterproof sealant containing epoxy sulfhydryl bridging agent and preparation method for reactive rubber waterproof sealant | |
| CN105295769A (en) | Reaction type rubber waterproof sealing cream containing alkylene bridging agent and preparation method of reaction type rubber waterproof sealing cream |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20160203 |