WO2016008372A1 - Bridged-type waterproof coating material, and production method and use therefor - Google Patents

Bridged-type waterproof coating material, and production method and use therefor Download PDF

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Publication number
WO2016008372A1
WO2016008372A1 PCT/CN2015/083497 CN2015083497W WO2016008372A1 WO 2016008372 A1 WO2016008372 A1 WO 2016008372A1 CN 2015083497 W CN2015083497 W CN 2015083497W WO 2016008372 A1 WO2016008372 A1 WO 2016008372A1
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Prior art keywords
bridge
agent
waterproof
waterproof coating
type waterproof
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PCT/CN2015/083497
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French (fr)
Chinese (zh)
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卢桂才
朱方伍
伍盛江
郭文雄
陈立斌
周为为
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广西金雨伞防水装饰有限公司
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Publication of WO2016008372A1 publication Critical patent/WO2016008372A1/en

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D195/00Coating compositions based on bituminous materials, e.g. asphalt, tar, pitch
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D109/00Coating compositions based on homopolymers or copolymers of conjugated diene hydrocarbons
    • C09D109/06Copolymers with styrene
    • C09D109/08Latex
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D111/00Coating compositions based on homopolymers or copolymers of chloroprene
    • C09D111/02Latex
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D153/00Coating compositions based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
    • C09D153/02Vinyl aromatic monomers and conjugated dienes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D193/00Coating compositions based on natural resins; Coating compositions based on derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives

Definitions

  • the invention relates to a waterproof coating, which is a waterproof coating capable of chemically reacting with cement concrete to produce chemical cross-linking, and a production method and application thereof.
  • the water-based rubber waterproof coating is a water-repellent coating material which is mainly composed of a polymer material as a film-forming material, an emulsifier, water and some additives, and then processed through a special process. It has excellent high elasticity, excellent high and low temperature properties and water resistance.
  • the rubber waterproof coating has excellent performance, and the disadvantage is that the price is relatively expensive.
  • Asphalt is a kind of organic cementing material which is waterproof, moisture-proof, anti-corrosive and low-cost. However, asphalt is easy to flow at high temperature, brittle and crack at low temperature, and asphalt is solid at normal temperature, which is inconvenient to construct. Therefore, people make emulsified asphalt or emulsified modified asphalt. And other products to use.
  • Emulsified asphalt is a liquid asphalt that produces oil-in-water or water-in-oil under the action of certain processes, and is often used for waterproofing of bridges, roads and buildings.
  • Emulsified modified asphalt is a waterproofing coating made of rubber modified asphalt, emulsifier, water, solvent and some additives. It has better performance than emulsified asphalt.
  • the waterproofing mechanism of the above waterproof coating is to apply a waterproof coating on the surface of the civil structure. After the solvent of the coating is volatilized, a hydrophobic organic coating is formed on the surface of the civil structure, thereby waterproofing.
  • the adhesion between the waterproof layer and the base surface is based on the physical adsorption force, the bonding strength between the waterproof layer and the base surface is relatively low, and the peeling is easily caused by the thermal expansion and contraction of the base surface, thereby destructing the waterproof layer and causing flaws. Water, water leakage, loss of water resistance.
  • Lu Guicai (Guangxi Jinyu Umbrella Waterproof Decoration Co., Ltd.) and others can chemically react with the cement concrete base surface to produce a strong Chemically bonded waterproof bridging agent, made of modified asphalt waterproofing material with excellent performance, such as Chinese patent: application (patent) number: CN200910114456.X, name: chemical cross-linking with concrete and physical co-bonding Waterproof membrane; public (announcement) number: CN101694114A application (patent): Guangxi Jinyu Umbrella Waterproof Decoration Co., Ltd., discloses a waterproof membrane which can be chemically crosslinked and physically bonded to cement concrete.
  • the waterproof glue used is a waterproof bridging agent which can be chemically cross-linked with cement concrete in the modified asphalt, and the waterproof bridging agent is polymethylethoxysilane or sodium polynaphthalene sulfonate. salt. Since the reactive groups contained in these waterproof bridging agents can chemically crosslink with cement concrete, the modified asphalt rubber has strong adhesion to the base surface and is irreversible, so the waterproof performance is extremely outstanding. It can be constructed in a humid environment, construction is very simple, and construction efficiency is very high.
  • the object of the present invention is to disclose a bridge-type waterproof coating, which is a rubber asphalt-based waterproof coating capable of chemically reacting with a concrete base surface to produce chemical cross-linking, and the waterproof layer formed by the coating is adhered to the cement concrete base surface.
  • the knot strength is high, the water resistance is significantly improved, and the waterproofing is more durable and reliable.
  • Bridge-type waterproof coating the composition of which includes the following parts by weight:
  • the rubber latex is any one of natural rubber latex, styrene butadiene rubber latex, neoprene latex, SBS rubber latex or polyacrylate or a combination thereof.
  • the rubber latex described above is available on the market and can be produced by the manufacturer.
  • the production method is as follows: the rubber is dissolved in an organic solvent, and water, an emulsifier, a thickener, a filler, and the like are added, and a uniform emulsion is obtained by a conventional stirring method such as vigorous stirring or a grinding action of a colloid mill.
  • a conventional stirring method such as vigorous stirring or a grinding action of a colloid mill.
  • it is also necessary to add functional additives such as anti-aging agents and leveling agents.
  • the emulsified asphalt is a petroleum asphalt, an emulsifier, a coating auxiliary agent (a thickener, a leveling agent, a drier, a defoaming agent, an anti-skinning agent, etc.) and a water treated by a high-speed emulsifier to obtain a solid content of 40. ⁇ 70% asphalt emulsion is available on the market and can be produced by itself. Petroleum asphalt is generally selected from models 50 to 130.
  • the emulsified asphalt is a cationic emulsified asphalt, a nonionic emulsified asphalt or an anionic emulsified asphalt.
  • the cationic emulsified asphalt comprises an emulsified asphalt prepared by using a cationic emulsifier such as an alkyl polyamine, an amine oxide, a quaternary ammonium salt, an amidoamine, an imidazoline or a lignan;
  • a cationic emulsifier such as an alkyl polyamine, an amine oxide, a quaternary ammonium salt, an amidoamine, an imidazoline or a lignan
  • the non-ionic emulsified asphalt includes an emulsified asphalt prepared from a nonionic emulsifier such as an ether group, an ester group, an amide or a heterocyclic milk;
  • the anionic emulsified asphalt includes an emulsified asphalt prepared from a carboxylate type, a sulfonate type, and a sulfate type anionic emulsifier.
  • anionic emulsifiers react with cationic emulsifiers to react and lose emulsification. They are generally nonionic and cationic or nonionic and anionic.
  • Cationic emulsifiers such as octadecyltrimethylammonium chloride, cetyltrimethylammonium chloride, cetyltributylammonium chloride, etc., have strong emulsification effect on asphalt, preferably cationic emulsification
  • the agent is an asphalt emulsifier.
  • Some special products also need to add functional additives such as anti-aging agents, leveling agents and reinforcing agents. In order to reduce the production cost, a certain amount of filler such as limestone powder, kaolin, bentonite or the like may be added without deteriorating the performance of the product.
  • the concrete is chemically cross-linked, and a waterproof bridge is built.
  • the coating and the cement are tightly integrated into one body.
  • the relevant parts have a chemical bond function, which acts as an irreversible bond after solidification.
  • the asphalt and the rubber combine to solidify the coating. After that, the asphalt adhesion is maintained, and the rubber has excellent elasticity and weather resistance.
  • the coating is a water-based environmentally friendly coating with convenient construction and excellent social and economic benefits.
  • Such materials may be silane waterproof bridging agents, bimetallic waterproof bridging agents, lignin waterproof bridging agents, tin waterproof bridging agents, zirconium waterproof bridging agents, phosphate ester waterproofing bridging agents or rare earth waterproof bridging agents. Any one of them or a combination thereof.
  • the bimetallic waterproof bridging agent is an aluminum zirconate waterproof bridging agent;
  • the lignin waterproof bridging agent is a lignin macromolecular organic mixture produced by the paper industry, and the lignin molecule contains a plurality of hydroxyl groups.
  • the tin waterproof crosslinking agent is tin tetrachloride, trioctyltin chloride or dioctyltin dichloride;
  • the zirconium water-proof bridging agent is tetra-n-butyl zirconate, tetrapentyl zirconate or tetraoctyl zirconate;
  • the phosphate cross-linking agent is di-n-butyl methyl phosphate, two positive Butylethyl phosphate, dioctylmethyl phosphate or dioctylethyl phosphate;
  • the rare earth water-repellent bridging agent is obtained by reacting an organic acid with a rare earth oxide in a molar ratio of about 1:1.
  • the product is usually a rare earth lauric acid compound or a rare earth stearic acid compound.
  • the silane-based water-repellent bridging agent described above is any one of an alkenylsiloxane, an aminosiloxane, a chloroalkylsiloxane, a methacryloxysiloxane or an epoxysiloxane. Or their compositions.
  • the alkenylsiloxane is vinyltrichlorosilane, vinyltrimethoxysilane, vinyltriethoxysilane, vinyltris( ⁇ -methoxyethoxy)silane, vinyltriacetic acid Silyl, tri-tert-butoxyvinylsilane, vinyltri-tert-butylperoxysilane, allyltrimethoxysilane or allyltriethoxysilane;
  • the aminosilicone is aniline methyltrimethoxysilane, aniline methyltriethoxysilane, N-(4-aminobutyl)aminomethyltriethoxysilane, ⁇ -aminopropyltrimethoxy Silane, (3-aminopropyl)triethoxysilane, N-methyl-3-aminopropyltrimethoxysilane, N-phenyl-3-aminopropyltrimethoxysilane, ⁇ -( ⁇ -aminoethyl)aminopropyltrimethoxysilane, ⁇ -( ⁇ -aminoethyl)aminopropylmethyldimethoxysilane, ⁇ -diethylenetriaminopropyltrimethoxysilane, 3-aminobenzene Trimethoxysilane, 2-(4-N-benzylethylenediamine)ethyltrimethoxysilane or N,N-bis(2-
  • the chloroalkylsiloxane is ⁇ -chloropropyltrichlorosilane, ⁇ -chloropropyltrimethoxysilane, ⁇ -chloropropyltriethoxysilane or 2-(4-chlorinated benzyl)B. Trimethoxysilane.
  • the methacryloxysiloxane is ⁇ -methacryloxypropyltrichlorosilane, ⁇ -methacryloxypropyltrimethoxysilane, ⁇ -methacryloxypropyl three ( ⁇ -methoxyethoxy)silane or ⁇ -methacryloxypropyltris(trimethylsiloxy)silane.
  • the epoxy siloxane is 3-(2,3 epoxypropoxy)propyltrimethoxy, ⁇ -(3,4-epoxycyclohexyl) Ethyltrimethoxysilane, ⁇ -(3,4-epoxycyclohexyl)ethyltriethoxysilane or ⁇ -(3,4-epoxycyclohexyl)ethylmethyldiethoxysilane.
  • the mechanism for reacting one end of the olefin-based silane with aluminate cement, sulphoaluminate cement or aluminosilicate cement is also the same.
  • the bridging agent of the present invention does not cause damage to the steel bars in the coupling compound of the hydroxyl group, the ether bond and the silica in the cement gel.
  • the waterproof bridging agent molecule of the invention contains a plurality of reactive functional groups, and when the waterproof bridging agent in the product contacts the base surface, the reactive groups in the molecule rapidly react with the base surface to form a chemical bond. Produces strong adhesion, while other functional groups in the molecule extend in the rubber-asphalt composite layer through steric hindrance and intermolecular forces. At the same time, the combination of asphalt and rubber keeps the asphalt sticky after curing. It also has the excellent elasticity and weather resistance of rubber.
  • the coating is a water-based environmentally friendly coating with convenient construction and excellent social and economic benefits.
  • %s described in the following examples are all % by weight, and the parts are parts by weight.
  • neoprene latex with a solid content of 50% 30 parts was taken, and 20 parts of neoprene-modified emulsified asphalt with a solid content of 50% and 1 part of vinyltrichlorosilane were added under normal temperature stirring to obtain a bridge-type waterproof coating.
  • the soap of trimethylammonium chloride is emulsified by emulsified colloid mill.
  • the coating production method is to mix and stir natural rubber latex, emulsified asphalt and tri-tert-butoxyvinylsilane at 50-60 ° C. Bridge-type waterproof coating.
  • styrene-butadiene rubber latex with a solid content of 50% 60 parts of styrene-butadiene rubber latex with a solid content of 50%, 30 parts of emulsified asphalt, and 5 parts of 3-(2,3 epoxypropoxy)propyltrimethoxy; wherein the emulsified asphalt uses 1 ton of 100-pure petroleum asphalt and 1 ton of soap containing 10 kg of octadecyltrimethylammonium chloride is emulsified by emulsified colloid mill.
  • the coating production method is natural rubber latex, emulsified asphalt, 3-(2, at 50-60 °C. 3 epoxy propylene oxide) propyl trimethoxy mixture, stirring evenly, to obtain a bridge-type waterproof coating.
  • neoprene latex with a solid content of 50% 30 parts was taken, and 20 parts of neoprene-modified emulsified asphalt with a solid content of 50% and 1 part of vinyltrichlorosilane were added under normal temperature stirring to obtain a bridge-type waterproof coating.
  • the neoprene-modified emulsified asphalt having a solid content of 50% is 96 parts of No.
  • neoprene latex with a solid content of 50% 20 parts of chloroprene-modified emulsified asphalt with a solid content of 50% and 0.6 parts of aluminum zirconate waterproof bridge agent were added under normal temperature stirring, and the mixture was evenly stirred to obtain a bridge. Joint waterproof coating.
  • the construction process is as follows: After testing with special instruments, the bond strength with cement concrete is >0.9MPa, the heat resistance is 80°C without slip, the tensile strength is >0.7MPa, and the performance is excellent. After three years of rainy season test, no Leakage and cracking phenomenon, while another building in the next-door community uses ordinary asphalt as a waterproof coating for treatment. There are cracks at several pipe joints on the floor, and it is seepage when it rains.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
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  • Wood Science & Technology (AREA)
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Abstract

A waterproof coating material, comprising the following raw materials in the following parts by weight: a rubber latex 20-60, an emulsified asphalt 20-60, and a waterproof bridging agent 0.2-4. The waterproof bridging agent may be any one of a silane-type waterproof bridging agent, a bimetallic waterproof bridging agent, a lignin waterproof bridging agent, a tin waterproof bridging agent, a zirconium waterproof bridging agent, an organophosphate waterproof bridging agent or a rare earth waterproof bridging agent or a combination thereof.

Description

桥联式防水涂料及其生产方法和应用Bridge type waterproof coating and production method and application thereof 技术领域Technical field
本发明涉及一种防水涂料,是一种能够与水泥混凝土发生化学反应,产生化学交联的防水涂料及其生产方法和应用。The invention relates to a waterproof coating, which is a waterproof coating capable of chemically reacting with cement concrete to produce chemical cross-linking, and a production method and application thereof.
背景技术Background technique
水性橡胶防水涂料是以高分子聚合材料为主要成膜物质,添加乳化剂、水和一些助剂,然后经过特殊工艺加工而成的具有防水功能的涂料。其具有优良的高弹性、优异的高低温性能和防水性能。橡胶防水涂料性能优异,缺点是价格比较贵。沥青是一种防水防潮、防腐、价格低廉的有机胶凝材料,但沥青高温易流淌,低温易脆裂,且常温下沥青为固体,施工不方便,因而人们制成乳化沥青或乳化改性沥青等产品来使用。乳化沥青是沥青和乳化剂在一定工艺作用下,生成水包油或油包水的液态沥青,常用于桥梁、公路和建筑物等结构的防水。乳化改性沥青是橡胶改性沥青、乳化剂、水、溶剂和一些助剂经过特殊工艺加工而成的具有防水功能的涂料,其性能优于乳化沥青。上述防水涂料防水的机理是通过在土建结构表面涂刷防水涂料,待涂料的溶剂挥发后,土建结构表面形成一层憎水的有机涂层,从而起到防水作用。由于防水层与基面的粘结力是靠物理吸附力,因而防水层与基面的粘结强度比较低,易受到基面的热胀冷缩作用而产生剥离,进而破坏防水层,导致窜水、漏水,失去防水作用。The water-based rubber waterproof coating is a water-repellent coating material which is mainly composed of a polymer material as a film-forming material, an emulsifier, water and some additives, and then processed through a special process. It has excellent high elasticity, excellent high and low temperature properties and water resistance. The rubber waterproof coating has excellent performance, and the disadvantage is that the price is relatively expensive. Asphalt is a kind of organic cementing material which is waterproof, moisture-proof, anti-corrosive and low-cost. However, asphalt is easy to flow at high temperature, brittle and crack at low temperature, and asphalt is solid at normal temperature, which is inconvenient to construct. Therefore, people make emulsified asphalt or emulsified modified asphalt. And other products to use. Emulsified asphalt is a liquid asphalt that produces oil-in-water or water-in-oil under the action of certain processes, and is often used for waterproofing of bridges, roads and buildings. Emulsified modified asphalt is a waterproofing coating made of rubber modified asphalt, emulsifier, water, solvent and some additives. It has better performance than emulsified asphalt. The waterproofing mechanism of the above waterproof coating is to apply a waterproof coating on the surface of the civil structure. After the solvent of the coating is volatilized, a hydrophobic organic coating is formed on the surface of the civil structure, thereby waterproofing. Since the adhesion between the waterproof layer and the base surface is based on the physical adsorption force, the bonding strength between the waterproof layer and the base surface is relatively low, and the peeling is easily caused by the thermal expansion and contraction of the base surface, thereby destructing the waterproof layer and causing flaws. Water, water leakage, loss of water resistance.
针对目前防水材料的防水层与基面的粘结作用只能靠较弱的物理吸附作用,卢桂才(广西金雨伞防水装饰有限公司)等人通过加入能够与水泥混凝土基面发生化学反应,产生强大化学结合力的防水桥联剂,制成了性能优异的改性沥青防水材料,如中国专利:申请(专利)号:CN200910114456.X,名称:与混凝土进行化学交联和物理卯榫协同粘结的防水卷材;公开(公告)号:CN101694114A申请(专利权)人:广西金雨伞防水装饰有限公司,公开了一种能够与水泥混凝土发生化学交联和物理卯榫协同粘结的防水卷材,其使用的防水胶是在改性沥青中加入能够与水泥混凝土发生化学交联反应的防水桥联剂,所述的防水桥联剂是聚甲基乙氧基硅烷或聚萘甲醛磺酸钠盐。由于这些防水桥联剂含有的活性基团可以与水泥混凝土发生化学交联反应,因而改性沥青胶与基面的粘接力强,并且是不可逆的,所以防水性能极其突出。其可在潮湿环境下施工,施工非常简便,施工效率非常高。The bonding effect between the waterproof layer and the base surface of the current waterproof material can only rely on weak physical adsorption. Lu Guicai (Guangxi Jinyu Umbrella Waterproof Decoration Co., Ltd.) and others can chemically react with the cement concrete base surface to produce a strong Chemically bonded waterproof bridging agent, made of modified asphalt waterproofing material with excellent performance, such as Chinese patent: application (patent) number: CN200910114456.X, name: chemical cross-linking with concrete and physical co-bonding Waterproof membrane; public (announcement) number: CN101694114A application (patent): Guangxi Jinyu Umbrella Waterproof Decoration Co., Ltd., discloses a waterproof membrane which can be chemically crosslinked and physically bonded to cement concrete. The waterproof glue used is a waterproof bridging agent which can be chemically cross-linked with cement concrete in the modified asphalt, and the waterproof bridging agent is polymethylethoxysilane or sodium polynaphthalene sulfonate. salt. Since the reactive groups contained in these waterproof bridging agents can chemically crosslink with cement concrete, the modified asphalt rubber has strong adhesion to the base surface and is irreversible, so the waterproof performance is extremely outstanding. It can be constructed in a humid environment, construction is very simple, and construction efficiency is very high.
但市场上未见有能够与水泥混凝土基面发生化学反应的防水涂料出售。 However, there are no waterproof coatings on the market that can react chemically with the cement concrete base.
发明内容Summary of the invention
本发明的目的是公开一种桥联式防水涂料,是一种能够与混凝土基面发生化学反应,产生化学交联的橡胶沥青基防水涂料,该涂料形成的防水层与水泥混凝土基面的粘结强度大、耐水性能得到显著提高,防水更持久可靠。The object of the present invention is to disclose a bridge-type waterproof coating, which is a rubber asphalt-based waterproof coating capable of chemically reacting with a concrete base surface to produce chemical cross-linking, and the waterproof layer formed by the coating is adhered to the cement concrete base surface. The knot strength is high, the water resistance is significantly improved, and the waterproofing is more durable and reliable.
本发明的技术方案是:The technical solution of the present invention is:
桥联式防水涂料,其组成包括以下重量份数的原料:Bridge-type waterproof coating, the composition of which includes the following parts by weight:
橡胶胶乳     20~60;Rubber latex 20~60;
乳化沥青     20~60;Emulsified asphalt 20~60;
防水桥联剂   0.2~4;Waterproof bridging agent 0.2~4;
所述的橡胶胶乳为天然橡胶胶乳、丁苯橡胶胶乳、氯丁橡胶胶乳、SBS橡胶胶乳或聚丙烯酸酯类中的任一种或它们的组合物。以上所述的橡胶胶乳市面上有售,厂家也可以自己生产。其生产方法是:橡胶用有机溶剂溶解,加入水、乳化剂、增稠剂、填料等,通过强力搅拌或胶体磨的研磨作用等常规加工方法,得到均匀的乳状液。有特殊需求的,还需要加入抗老化剂、流平剂等功能性助剂。The rubber latex is any one of natural rubber latex, styrene butadiene rubber latex, neoprene latex, SBS rubber latex or polyacrylate or a combination thereof. The rubber latex described above is available on the market and can be produced by the manufacturer. The production method is as follows: the rubber is dissolved in an organic solvent, and water, an emulsifier, a thickener, a filler, and the like are added, and a uniform emulsion is obtained by a conventional stirring method such as vigorous stirring or a grinding action of a colloid mill. For special needs, it is also necessary to add functional additives such as anti-aging agents and leveling agents.
所述的乳化沥青是石油沥青、乳化剂、涂料助剂(增稠剂、流平剂、催干剂、消泡剂、抗结皮剂等)和水经高速乳化机处理得到固含量为40~70%的沥青乳液,市面上有售,也可以自己生产。石油沥青一般选择50~130号的型号。The emulsified asphalt is a petroleum asphalt, an emulsifier, a coating auxiliary agent (a thickener, a leveling agent, a drier, a defoaming agent, an anti-skinning agent, etc.) and a water treated by a high-speed emulsifier to obtain a solid content of 40. ~70% asphalt emulsion is available on the market and can be produced by itself. Petroleum asphalt is generally selected from models 50 to 130.
所述的乳化沥青为阳离子乳化沥青、非离子乳化沥青或者阴离子乳化沥青。The emulsified asphalt is a cationic emulsified asphalt, a nonionic emulsified asphalt or an anionic emulsified asphalt.
阳离子乳化沥青包括烷基多胺类、氧化胺类、季铵盐类、酰胺基胺类、咪唑啉类、木脂素类等等阳离子乳化剂制备的乳化沥青;The cationic emulsified asphalt comprises an emulsified asphalt prepared by using a cationic emulsifier such as an alkyl polyamine, an amine oxide, a quaternary ammonium salt, an amidoamine, an imidazoline or a lignan;
非离子乳化沥青包括醚基类、酯基类、酰胺类和杂环类乳等非离子乳化剂制备的乳化沥青;The non-ionic emulsified asphalt includes an emulsified asphalt prepared from a nonionic emulsifier such as an ether group, an ester group, an amide or a heterocyclic milk;
阴离子乳化沥青包括羧酸盐型、磺酸盐型及硫酸盐型阴离子乳化剂制备的乳化沥青。The anionic emulsified asphalt includes an emulsified asphalt prepared from a carboxylate type, a sulfonate type, and a sulfate type anionic emulsifier.
特别需要注意的是大多数阴离子乳化剂与阳离子乳化剂混合会发生反应,失去乳化作用,一般都是非离子与阳离子复配或是非离子与阴离子复配。阳离子乳化剂,如十八烷基三甲基氯化铵、十六烷基三甲基氯化铵、十六烷基三丁基氯化铵等对沥青有很强的乳化作用,优选阳离子乳化剂为沥青乳化剂。一些特殊的产品还需要加入抗老化剂、流平剂、补强剂等功能性助剂。为了降低生产成本,在不降低产品性能的情况下,可加入一定量的填料,如石灰石粉、高岭土、膨润土等。It is important to note that most anionic emulsifiers react with cationic emulsifiers to react and lose emulsification. They are generally nonionic and cationic or nonionic and anionic. Cationic emulsifiers, such as octadecyltrimethylammonium chloride, cetyltrimethylammonium chloride, cetyltributylammonium chloride, etc., have strong emulsification effect on asphalt, preferably cationic emulsification The agent is an asphalt emulsifier. Some special products also need to add functional additives such as anti-aging agents, leveling agents and reinforcing agents. In order to reduce the production cost, a certain amount of filler such as limestone powder, kaolin, bentonite or the like may be added without deteriorating the performance of the product.
所述的防水桥联剂一端能够与橡胶和沥青材料中的不饱和C=C双键、羧基-COOH、羟基-OH等基团反应连接起来,另一端和水泥水化过程中产生的羟基或酸根结合形成化学键,与 混凝土进行化学交联反应,架起一座防水桥梁,将涂层和水泥紧密地联结为一体,相关部位存在化学键作用,固化后起到不可逆的粘结作用,同时,沥青与橡胶结合使涂层固化后即保持沥青粘附性又兼有橡胶优异的弹性、耐候等性能。该涂料是水性环保涂料,施工便捷,具有优异的社会及经济效益。The one end of the waterproof bridging agent can be reacted with the unsaturated C=C double bond, carboxyl-COOH, hydroxyl-OH and the like in the rubber and asphalt materials, and the other end and the hydroxyl group generated during the hydration of the cement or Acid radicals form chemical bonds, and The concrete is chemically cross-linked, and a waterproof bridge is built. The coating and the cement are tightly integrated into one body. The relevant parts have a chemical bond function, which acts as an irreversible bond after solidification. At the same time, the asphalt and the rubber combine to solidify the coating. After that, the asphalt adhesion is maintained, and the rubber has excellent elasticity and weather resistance. The coating is a water-based environmentally friendly coating with convenient construction and excellent social and economic benefits.
这类物质可以为硅烷类防水桥联剂,双金属防水桥联剂、木质素防水桥联剂、锡防水桥联剂、锆防水桥联剂、磷酸酯防水桥联剂或稀土防水桥联剂中的任一种或它们的组合物。所述的双金属防水桥联剂为铝锆酸酯防水桥联剂;所述的木质素防水桥联剂是造纸工业副产的木质素类大分子有机混合物,木质素分子中含有多个羟基、羧基、甲氧基等活性基团,它们可以与水泥混凝土中的硅酸盐发生化学反应;所述的锡防水桥联剂是四氯化锡、氯化三辛基锡或二氯化二辛基锡;所述的锆防水桥联剂是四正丁基锆酸酯、四戊基锆酸酯或四辛基锆酸酯;所述的磷酸酯防水桥联剂是二正丁基甲基磷酸酯、二正丁基乙基磷酸酯、二辛基甲基磷酸酯或二辛基乙基磷酸酯;所述的稀土防水桥联剂是有机酸与稀土氧化物按照摩尔比约1:1的比例反应得到的产物,常用的有月桂酸稀土化合物或硬脂酸稀土化合物。稀土具有很强的螯合性能,与水泥中的硅酸盐化合物形成非常牢固的化学螯合键。Such materials may be silane waterproof bridging agents, bimetallic waterproof bridging agents, lignin waterproof bridging agents, tin waterproof bridging agents, zirconium waterproof bridging agents, phosphate ester waterproofing bridging agents or rare earth waterproof bridging agents. Any one of them or a combination thereof. The bimetallic waterproof bridging agent is an aluminum zirconate waterproof bridging agent; the lignin waterproof bridging agent is a lignin macromolecular organic mixture produced by the paper industry, and the lignin molecule contains a plurality of hydroxyl groups. a reactive group such as a carboxyl group or a methoxy group, which can be chemically reacted with a silicate in cement concrete; the tin waterproof crosslinking agent is tin tetrachloride, trioctyltin chloride or dioctyltin dichloride; The zirconium water-proof bridging agent is tetra-n-butyl zirconate, tetrapentyl zirconate or tetraoctyl zirconate; the phosphate cross-linking agent is di-n-butyl methyl phosphate, two positive Butylethyl phosphate, dioctylmethyl phosphate or dioctylethyl phosphate; the rare earth water-repellent bridging agent is obtained by reacting an organic acid with a rare earth oxide in a molar ratio of about 1:1. The product is usually a rare earth lauric acid compound or a rare earth stearic acid compound. Rare earths have strong chelating properties and form very strong chemical chelating bonds with silicate compounds in cement.
以上所述的硅烷类防水桥联剂为链烯基硅氧烷、氨基硅氧烷、氯烃基硅氧烷、甲基丙烯酰氧基硅氧烷或环氧基硅氧烷中的任一种或它们的组合物。The silane-based water-repellent bridging agent described above is any one of an alkenylsiloxane, an aminosiloxane, a chloroalkylsiloxane, a methacryloxysiloxane or an epoxysiloxane. Or their compositions.
所述的链烯基硅氧烷是乙烯基三氯硅烷、乙烯基三甲氧基硅烷、乙烯基三乙氧基硅烷、乙烯基三(β—甲氧基乙氧基)硅烷、乙烯基三乙酸基硅烷、三叔丁氧基乙烯基硅烷、乙烯基三叔丁基过氧硅烷、烯丙基三甲氧基硅烷或烯丙基三乙氧基硅烷;The alkenylsiloxane is vinyltrichlorosilane, vinyltrimethoxysilane, vinyltriethoxysilane, vinyltris(β-methoxyethoxy)silane, vinyltriacetic acid Silyl, tri-tert-butoxyvinylsilane, vinyltri-tert-butylperoxysilane, allyltrimethoxysilane or allyltriethoxysilane;
所述的氨基硅氧烷是苯胺甲基三甲氧基硅烷、苯胺甲基三乙氧基硅烷、N-(4-氨基丁基)氨基甲基三乙氧基硅烷、γ-氨基丙基三甲氧基硅烷、(3-氨基丙基)三乙氧基硅烷、N-甲基-3-氨丙基三甲氧基硅烷、N-苯基-3-氨基丙基三甲氧基硅烷、γ-(β-氨乙基)氨丙基三甲氧基硅烷、γ-(β-氨乙基)氨丙基甲基二甲氧基硅烷、γ-二乙烯三氨基丙基三甲氧基硅烷、3-氨基苯基三甲氧基硅烷、2-(4-N-苄基乙二胺基)乙基三甲氧基硅烷或N,N-二(2-羟乙基)-3-氨丙基三乙氧基硅烷。The aminosilicone is aniline methyltrimethoxysilane, aniline methyltriethoxysilane, N-(4-aminobutyl)aminomethyltriethoxysilane, γ-aminopropyltrimethoxy Silane, (3-aminopropyl)triethoxysilane, N-methyl-3-aminopropyltrimethoxysilane, N-phenyl-3-aminopropyltrimethoxysilane, γ-(β -aminoethyl)aminopropyltrimethoxysilane, γ-(β-aminoethyl)aminopropylmethyldimethoxysilane, γ-diethylenetriaminopropyltrimethoxysilane, 3-aminobenzene Trimethoxysilane, 2-(4-N-benzylethylenediamine)ethyltrimethoxysilane or N,N-bis(2-hydroxyethyl)-3-aminopropyltriethoxysilane .
所述的氯烃基硅氧烷是γ-氯丙基三氯硅烷、γ-氯丙基三甲氧基硅烷、γ-氯丙基三乙氧基硅烷或2-(4-氯化苄基)乙基三甲氧基硅烷。The chloroalkylsiloxane is γ-chloropropyltrichlorosilane, γ-chloropropyltrimethoxysilane, γ-chloropropyltriethoxysilane or 2-(4-chlorinated benzyl)B. Trimethoxysilane.
所述的甲基丙烯酰氧基硅氧烷是γ-甲基丙烯酰氧丙基三氯硅烷、γ-甲基丙烯酰氧丙基三甲氧基硅烷、γ-甲基丙烯酰氧丙基三(β—甲氧基乙氧基)硅烷或γ-甲基丙烯酰氧丙基三(三甲基硅氧烷基)硅烷。The methacryloxysiloxane is γ-methacryloxypropyltrichlorosilane, γ-methacryloxypropyltrimethoxysilane, γ-methacryloxypropyl three (β-methoxyethoxy)silane or γ-methacryloxypropyltris(trimethylsiloxy)silane.
所述的环氧基硅氧烷是3—(2,3环氧丙氧)丙基三甲氧基、β—(3,4环氧基环己基) 乙基三甲氧基硅烷、β-(3,4环氧基环己基)乙基三乙氧基硅烷或β-(3,4环氧基环己基)乙基甲基二乙氧基硅烷。The epoxy siloxane is 3-(2,3 epoxypropoxy)propyltrimethoxy, β-(3,4-epoxycyclohexyl) Ethyltrimethoxysilane, β-(3,4-epoxycyclohexyl)ethyltriethoxysilane or β-(3,4-epoxycyclohexyl)ethylmethyldiethoxysilane.
以下是反应机理:The following is the reaction mechanism:
1、以硅烷类防水桥联剂中的烯烃基类硅烷为例,当烯烃基类硅烷的一端与沥青混合的时候,以烯烃基乙烯基硅烷为例,它们能够发生如下的化学反应:1. Taking the olefin-based silane in the silane-based water-repellent bridging agent as an example, when one end of the olefin-based silane is mixed with the asphalt, taking the olefin-based vinyl silane as an example, they can undergo the following chemical reaction:
Figure PCTCN2015083497-appb-000001
Figure PCTCN2015083497-appb-000001
2、以硅酸盐水泥为例,烯烃基类硅烷的一端与与混凝土的作用机理如下:2. Taking Portland cement as an example, the mechanism of action of one end of olefin-based silane and concrete is as follows:
①常温下水泥发生水化反应生成水化硅酸钙(C-S-H凝胶)和Ca(OH)2,CSH凝胶中存在Si-OH基团,反应式:3CaO·SiO2+nH2O=xCa·SiO2·yH2O+(3-x)Ca(OH)21 The hydration reaction of cement at normal temperature produces hydrated calcium silicate (CSH gel) and Ca(OH) 2 , and there are Si-OH groups in the CSH gel. The reaction formula: 3CaO·SiO 2 +nH2O=xCa·SiO 2 · yH 2 O+(3-x)Ca(OH) 2 ;
②胶层中的活性基团遇水水解:2 The reactive groups in the adhesive layer are hydrolyzed by water:
Figure PCTCN2015083497-appb-000002
Figure PCTCN2015083497-appb-000002
③水解生成Si-OH基团与CSH凝胶中Si-OH基团反应生成醚键,使水化硅酸钙凝胶与卷材表面生成化学键(与CSH形成醚键)反应如下:3 Hydrolysis to form Si-OH groups and react with Si-OH groups in CSH gel to form ether bonds, so that the hydrated calcium silicate gel reacts with the surface of the coil to form a chemical bond (forming an ether bond with CSH) as follows:
Figure PCTCN2015083497-appb-000003
Figure PCTCN2015083497-appb-000003
所述的烯烃基类硅烷的一端与铝酸水泥、硫铝酸水泥或铁铝酸水泥反应的机理也是一样的。The mechanism for reacting one end of the olefin-based silane with aluminate cement, sulphoaluminate cement or aluminosilicate cement is also the same.
本发明的桥联剂在与水泥凝胶中的羟基、醚键与二氧化硅的偶联化合物,不会造成对钢筋的损害。The bridging agent of the present invention does not cause damage to the steel bars in the coupling compound of the hydroxyl group, the ether bond and the silica in the cement gel.
本发明产生的积极效果:本发明的防水桥联剂分子中含有多个活性官能团,产品中防水桥联剂与基面接触时,分子中活性基团迅速与基面发生化学反应产生化学键合作用,产生强大的粘合力,而分子中其他功能基团伸展于橡胶与沥青复合层中通过空间位阻以及分子间作用力紧密结合,同时,沥青与橡胶结合使涂层固化后即保持沥青粘附性又兼有橡胶优异的弹性、耐候等性能。该涂料是水性环保涂料,施工便捷,具有优异的社会及经济效益。The positive effect produced by the invention: the waterproof bridging agent molecule of the invention contains a plurality of reactive functional groups, and when the waterproof bridging agent in the product contacts the base surface, the reactive groups in the molecule rapidly react with the base surface to form a chemical bond. Produces strong adhesion, while other functional groups in the molecule extend in the rubber-asphalt composite layer through steric hindrance and intermolecular forces. At the same time, the combination of asphalt and rubber keeps the asphalt sticky after curing. It also has the excellent elasticity and weather resistance of rubber. The coating is a water-based environmentally friendly coating with convenient construction and excellent social and economic benefits.
具体实施方式detailed description
以下实施例所述的%均为重量%,份数均为重量份The %s described in the following examples are all % by weight, and the parts are parts by weight.
实施例1Example 1
取固含量为42%的丁苯橡胶胶乳20份,常温搅拌下加入乳化沥青20份和0.6份N-苯基-3-氨基丙基三甲氧基硅烷,搅拌均匀,得到桥联式防水涂料。20 parts of styrene-butadiene rubber latex having a solid content of 42% was taken, and 20 parts of emulsified asphalt and 0.6 parts of N-phenyl-3-aminopropyltrimethoxysilane were added under stirring at room temperature, and the mixture was uniformly stirred to obtain a bridge-type waterproof coating.
实施例2Example 2
取固含量为50%的氯丁橡胶胶乳30份,常温搅拌下加入固含量为50%的氯丁橡胶改性乳化沥青20份;乙烯基三氯硅烷1份,得到桥联式防水涂料。30 parts of neoprene latex with a solid content of 50% was taken, and 20 parts of neoprene-modified emulsified asphalt with a solid content of 50% and 1 part of vinyltrichlorosilane were added under normal temperature stirring to obtain a bridge-type waterproof coating.
实施例3Example 3
取固含量为60%的SBS橡胶胶乳40份,常温搅拌下加入固含量为60%的乳化沥青60份和1份γ-氯丙基三乙氧基硅烷,搅拌均匀,得到桥联式防水涂料。40 parts of SBS rubber latex with a solid content of 60%, 60 parts of emulsified asphalt with 60% solid content and 1 part of γ-chloropropyltriethoxysilane were added under normal temperature stirring, and evenly stirred to obtain bridge-type waterproof coating. .
实施例4Example 4
取固含量为55%的聚丙烯酸甲酯乳液50份,常温搅拌下加入固含量为55%的乳化沥青50份和2份γ-甲基丙烯酰氧丙基三(三甲基硅氧烷基)硅烷,搅拌均匀,得到桥联式防水涂料。50 parts of polymethyl acrylate emulsion with a solid content of 55%, 50 parts of emulsified asphalt with a solid content of 55% and 2 parts of γ-methacryloxypropyltris(trimethylsiloxane) were added under normal temperature stirring. The silane is stirred evenly to obtain a bridge-type waterproof coating.
实施例5Example 5
取固含量为55%的聚丙烯酸丁酯45份,50-60℃搅拌下加入固含量为55%的乳化沥青35份和3份β-(3,4环氧基环己基)乙基甲基二乙氧基硅烷,5份SBS搅拌均匀,得到桥联式防水涂料。45 parts of polybutyl acrylate with a solid content of 55%, 35 parts of emulsified asphalt with a solid content of 55% and 3 parts of β-(3,4 epoxycyclohexyl)ethylmethyl group with 50-60 ° C stirring. Diethoxysilane, 5 parts of SBS was stirred evenly to obtain a bridge-type waterproof coating.
实施例6Example 6
取固含量为50%的聚甲基丙烯酸甲酯乳液55份,常温搅拌下加入固含量为55%的乳化沥青45份、1份烯丙基三甲氧基硅烷和3份N-(4-氨基丁基)氨基甲基三乙氧基硅烷,搅拌均 匀,得到桥联式防水涂料。55 parts of polymethyl methacrylate emulsion with a solid content of 50%, 45 parts of emulsified asphalt with a solid content of 55%, 1 part of allyltrimethoxysilane and 3 parts of N-(4-amino group) were added under normal temperature stirring. Butyl) aminomethyltriethoxysilane, stirring Evenly, get a bridge-type waterproof coating.
实施例7Example 7
取固含量为50%的天然橡胶胶乳25份,乳化沥青33份,三叔丁氧基乙烯基硅烷3份;其中乳化沥青采用1吨100号的石油沥青和1吨含有20公斤十八烷基三甲基氯化铵的皂液经乳化胶体磨混合乳化而成,涂料生产方法是在50-60℃下将天然橡胶胶乳、乳化沥青、三叔丁氧基乙烯基硅烷混合并搅拌均匀,得到桥联式防水涂料。25 parts of natural rubber latex with a solid content of 50%, 33 parts of emulsified asphalt and 3 parts of tri-tert-butoxyvinylsilane; wherein the emulsified asphalt uses 1 ton of 100-pure petroleum pitch and 1 ton of 20 kg of octadecyl The soap of trimethylammonium chloride is emulsified by emulsified colloid mill. The coating production method is to mix and stir natural rubber latex, emulsified asphalt and tri-tert-butoxyvinylsilane at 50-60 ° C. Bridge-type waterproof coating.
实施例8Example 8
取固含量为50%的丁苯橡胶胶乳60份,乳化沥青30份,3-(2,3环氧丙氧)丙基三甲氧基5份;其中乳化沥青采用1吨100号的石油沥青和1吨含有10公斤十八烷基三甲基氯化铵的皂液经乳化胶体磨混合乳化而成,涂料生产方法是在50-60℃下将天然橡胶胶乳、乳化沥青、3-(2,3环氧丙氧)丙基三甲氧基混合,搅拌均匀,得到桥联式防水涂料。60 parts of styrene-butadiene rubber latex with a solid content of 50%, 30 parts of emulsified asphalt, and 5 parts of 3-(2,3 epoxypropoxy)propyltrimethoxy; wherein the emulsified asphalt uses 1 ton of 100-pure petroleum asphalt and 1 ton of soap containing 10 kg of octadecyltrimethylammonium chloride is emulsified by emulsified colloid mill. The coating production method is natural rubber latex, emulsified asphalt, 3-(2, at 50-60 °C. 3 epoxy propylene oxide) propyl trimethoxy mixture, stirring evenly, to obtain a bridge-type waterproof coating.
实施例9Example 9
取固含量为50%的氯丁橡胶胶乳30份,常温搅拌下加入固含量为50%的氯丁橡胶改性乳化沥青20份;乙烯基三氯硅烷1份,得到桥联式防水涂料。所述的固含量为50%的氯丁橡胶改性乳化沥青是96份90号石油沥青加入4份氯丁橡胶,在180-220℃的温度下改性3h,降温至160-170℃,再与100份含10份十六烷基三丁基氯化铵的70-80℃的皂液经乳化胶体磨混合乳化而成。30 parts of neoprene latex with a solid content of 50% was taken, and 20 parts of neoprene-modified emulsified asphalt with a solid content of 50% and 1 part of vinyltrichlorosilane were added under normal temperature stirring to obtain a bridge-type waterproof coating. The neoprene-modified emulsified asphalt having a solid content of 50% is 96 parts of No. 90 petroleum pitch added with 4 parts of chloroprene rubber, modified at a temperature of 180-220 ° C for 3 hours, and cooled to 160-170 ° C, and then It was prepared by emulsifying and mixing 100 parts of a soap solution containing 10 parts of cetyltributylammonium chloride at 70-80 ° C by an emulsified colloid mill.
实施例10Example 10
取固含量为50%的聚甲基丙烯酸甲酯乳液55份,常温搅拌下加入固含量为55%的乳化沥青45份、3份三叔丁氧基乙烯基硅烷,搅拌均匀,得到桥联式防水涂料。55 parts of polymethyl methacrylate emulsion with a solid content of 50%, 45 parts of emulsified asphalt with a solid content of 55% and 3 parts of tri-tert-butoxyvinylsilane were stirred at room temperature, and stirred uniformly to obtain a bridged type. Waterproof coating.
实施例11Example 11
取固含量为42%的丁苯橡胶胶乳20份,常温搅拌下加入固含量为50%的丁苯橡胶改性乳化沥青30份和0.2份月桂酸稀土化合物,搅拌均匀,得到桥联式防水涂料。20 parts of styrene-butadiene rubber latex with a solid content of 42%, 30 parts of styrene-butadiene rubber modified emulsified asphalt with a solid content of 50% and 0.2 parts of rare earth lauric acid compound were added under normal temperature stirring, and evenly stirred to obtain a bridge-type waterproof coating. .
实施例12Example 12
取固含量为50%的氯丁橡胶胶乳30份,常温搅拌下加入固含量为50%的氯丁橡胶改性乳化沥青20份和0.6份铝锆酸酯防水桥联剂,搅拌均匀,得到桥联式防水涂料。30 parts of neoprene latex with a solid content of 50%, 20 parts of chloroprene-modified emulsified asphalt with a solid content of 50% and 0.6 parts of aluminum zirconate waterproof bridge agent were added under normal temperature stirring, and the mixture was evenly stirred to obtain a bridge. Joint waterproof coating.
实施例13Example 13
取固含量为60%的SBS橡胶胶乳40份,常温搅拌下加入固含量为60%的乳化沥青60份和1份氯化三辛基锡,搅拌均匀,得到桥联式防水涂料。40 parts of SBS rubber latex with a solid content of 60% was taken, 60 parts of emulsified asphalt with a solid content of 60% and 1 part of trioctyltin chloride were added under normal temperature stirring, and the mixture was uniformly stirred to obtain a bridge-type waterproof coating.
实施例14Example 14
取固含量为55%的聚丙烯酸甲酯乳液50份,常温搅拌下加入固含量为55%的乳化沥青 50份和2份四正丁基锆酸酯,搅拌均匀,得到桥联式防水涂料。50 parts of polymethyl acrylate emulsion with a solid content of 55%, and added emulsified asphalt with a solid content of 55% under normal temperature stirring 50 parts and 2 parts of tetra-n-butyl zirconate were stirred uniformly to obtain a bridge-type waterproof coating.
实施例15Example 15
取固含量为55%的聚丙烯酸丁酯45份,常温搅拌下加入固含量为55%的乳化沥青35份和3份二正丁基乙基磷酸酯,搅拌均匀,得到桥联式防水涂料。45 parts of polybutyl acrylate having a solid content of 55% was taken, and 35 parts of emulsified asphalt having a solid content of 55% and 3 parts of di-n-butylethyl phosphate were added under stirring at room temperature, and the mixture was uniformly stirred to obtain a bridge-type waterproof coating.
实施例16Example 16
取固含量为50%的聚甲基丙烯酸甲酯乳液55份,常温搅拌下加入固含量为55%的乳化沥青45份和4份木质素防水桥联剂,搅拌均匀后加入2份凹凸棒土,混合均匀,得到桥联式防水涂料。Take 55 parts of polymethyl methacrylate emulsion with 50% solid content, add 45 parts of emulsified asphalt with 55% solid content and 4 parts of lignin waterproof bridge agent under normal temperature stirring. Stir well and add 2 parts of attapulgite , evenly mixed, to obtain a bridge-type waterproof coating.
实施例17Example 17
取固含量为50%的聚甲基丙烯酸甲酯乳液55份,常温搅拌下加入固含量为55%的乳化沥青45份、1份二辛基乙基磷酸酯和3份木质素防水桥联剂,搅拌均匀,得到桥联式防水涂料。55 parts of polymethyl methacrylate emulsion with a solid content of 50%, 45 parts of emulsified asphalt with a solid content of 55%, 1 part of dioctylethyl phosphate and 3 parts of lignin waterproof bridged agent under normal temperature stirring Stir well and obtain a bridge-type waterproof coating.
对比实施例Comparative example
取固含量为50%的聚甲基丙烯酸甲酯乳液55份,常温搅拌下加入固含量为55%的乳化沥青45份,搅拌均匀后加入2份凹凸棒土,混合均匀,得到普通防水涂料。55 parts of polymethyl methacrylate emulsion with a solid content of 50% was taken, and 45 parts of emulsified asphalt with a solid content of 55% was added under normal temperature stirring. After stirring, 2 parts of attapulgite was added and uniformly mixed to obtain an ordinary waterproof coating.
试验:取上述实施例得到的防水涂料涂刷在水泥混凝土表面上,使实干后的防水层厚度为1~2mm,按照JC/T 408-2005《水乳性沥青基防水涂料》检测方法对上述形成的防水层进行主要性能测试,结果如下表1所示: Test: Take the waterproof coating obtained in the above example and apply it on the surface of cement concrete, so that the thickness of the waterproof layer after drying is 1-2 mm, according to the test method of JC/T 408-2005 "Water-based asphalt-based waterproof coating" The resulting waterproof layer was tested for major performance and the results are shown in Table 1 below:
Figure PCTCN2015083497-appb-000004
Figure PCTCN2015083497-appb-000004
应用实施例Application example
广西南宁市某大型楼盘,2012年7月,由于采用多管道通水,卫生间,楼顶顶板,均有通水PVC管道,采用本发明的桥联式防水涂料进行处理。其施工过程如下:经过了专用仪器的测试,与水泥混凝土粘结强度>0.9MPa,耐热性80℃无下滑,拉伸强度>0.7MPa,性能优良,经过3年的雨季考验,没有发现有渗漏和裂纹现象,而隔壁小区的另一大楼,采用普通沥青作为防水涂料进行处理,楼面有几个管道接口处出现龟裂现象,下雨即渗水。 A large-scale real estate in Nanning, Guangxi, in July 2012, due to the use of multi-pipe water, toilets, roof tops, all through the water PVC pipe, using the bridge-type waterproof coating of the invention for processing. The construction process is as follows: After testing with special instruments, the bond strength with cement concrete is >0.9MPa, the heat resistance is 80°C without slip, the tensile strength is >0.7MPa, and the performance is excellent. After three years of rainy season test, no Leakage and cracking phenomenon, while another building in the next-door community uses ordinary asphalt as a waterproof coating for treatment. There are cracks at several pipe joints on the floor, and it is seepage when it rains.

Claims (15)

  1. 桥联式防水涂料,其特征在于,包括以下重量份数的原料:A bridge-type waterproof coating characterized by comprising the following parts by weight:
    橡胶胶乳   20~60;Rubber latex 20~60;
    乳化沥青   20~60;Emulsified asphalt 20~60;
    防水桥联剂  0.2~4。Waterproof bridging agent 0.2~4.
  2. 如权利要求1所述的桥联式防水涂料,其特征在于,所述的橡胶胶乳为天然橡胶胶乳、丁苯橡胶胶乳、氯丁橡胶胶乳、SBS橡胶胶乳或聚丙烯酸酯类中的任一种或它们的组合物。The bridge type waterproof coating according to claim 1, wherein the rubber latex is any one of natural rubber latex, styrene butadiene rubber latex, neoprene latex, SBS rubber latex or polyacrylate. Or their compositions.
  3. 如权利要求1所述的桥联式防水涂料,其特征在于,所述的乳化沥青是沥青、乳化剂、涂料助剂和水经乳化机处理得到乳液;所述的乳化沥青选用阳离子乳化沥青、阴离子乳化沥青、非离子乳化沥青。The bridge type waterproof coating according to claim 1, wherein the emulsified asphalt is an asphalt, an emulsifier, a coating auxiliary agent and water treated by an emulsifier to obtain an emulsion; and the emulsified asphalt is selected from a cationic emulsified asphalt. Anionic emulsified asphalt, non-ionic emulsified asphalt.
  4. 如权利要求3所述的桥联式防水涂料,其特征在于,所述的涂料助剂是抗老化剂、流平剂、补强剂和填料。The bridge type waterproof coating according to claim 3, wherein the coating aid is an anti-aging agent, a leveling agent, a reinforcing agent, and a filler.
  5. 如权利要求1所述的桥联式防水涂料,其特征在于,所述的防水桥联剂为硅烷类防水桥联剂,双金属防水桥联剂、木质素防水桥联剂、锡防水桥联剂、锆防水桥联剂、磷酸酯防水桥联剂或稀土防水桥联剂中的任一种或它们的组合物,所述的防水桥联剂一端与沥青的C=C双键、羧基-COOH、羟基-OH基团结合,另一端与水泥水化后产生的的羟基或酸根结合,与混凝土进行化学交联反应,架起一座防水桥梁,固化后起到不可逆的粘结作用,沥青与橡胶胶乳结合使涂层固化后即保持沥青粘附性又兼有橡胶优异的弹性、耐候性能。The bridge type waterproof coating according to claim 1, wherein the waterproof bridge agent is a silane type waterproof bridge agent, a bimetal waterproof bridge agent, a lignin waterproof bridge agent, and a tin waterproof bridge. Any one or a combination of a zirconium water-repellent bridging agent, a phosphate ester waterproofing bridging agent or a rare earth water-repellent bridging agent, wherein the water-repellent bridging agent has a C=C double bond and a carboxyl group at one end of the asphalt. The COOH and hydroxy-OH groups are combined, and the other end is combined with the hydroxyl or acid group produced by the hydration of the cement. The chemical cross-linking reaction with the concrete is carried out to build a waterproof bridge, which acts as an irreversible bonding after solidification. Asphalt and The rubber latex combines to maintain the asphalt adhesion after the coating is cured, and has the excellent elasticity and weather resistance of the rubber.
  6. 如权利要求5所述的桥联式防水涂料,其特征在于,所述的硅烷类防水桥联剂为链烯基硅氧烷、氨基硅氧烷、氯烃基硅氧烷、甲基丙烯酰氧基硅氧烷或环氧基硅氧烷中的任一种或它们的组合物。The bridge type waterproof coating according to claim 5, wherein the silane type waterproof crosslinking agent is an alkenylsiloxane, an aminosiloxane, a chloroalkylsiloxane, or a methacryloyloxy group. Any one of a siloxane or an epoxy siloxane or a combination thereof.
  7. 如权利要求6所述的桥联式防水涂料,其特征在于,所述的链烯基硅氧烷是乙烯基三氯硅烷、乙烯基三甲氧基硅烷、乙烯基三乙氧基硅烷、乙烯基三(β—甲氧基乙氧基)硅烷、乙烯基三乙酸基硅烷、三叔丁氧基乙烯基硅烷、乙烯基三叔丁基过氧硅烷、烯丙基三甲氧基硅烷或烯丙基三乙氧基硅烷;The bridge type waterproof coating according to claim 6, wherein said alkenylsiloxane is vinyltrichlorosilane, vinyltrimethoxysilane, vinyltriethoxysilane, vinyl Tris(β-methoxyethoxy)silane, vinyltriacetoxysilane, tri-tert-butoxyvinylsilane, vinyltri-tert-butylperoxysilane, allyltrimethoxysilane or allyl Triethoxysilane;
    所述的氨基硅氧烷是苯胺甲基三甲氧基硅烷、苯胺甲基三乙氧基硅烷、N-(4-氨基丁基)氨基甲基三乙氧基硅烷、γ-氨基丙基三甲氧基硅烷、(3-氨基丙基)三乙氧基硅烷、N-甲基-3-氨丙基三甲氧基硅烷、N-苯基-3-氨基丙基三甲氧基硅烷、γ-(β-氨乙基)氨丙基三甲氧基硅烷、γ-(β-氨乙基)氨丙基甲基二甲氧基硅烷、γ-二乙烯三氨基丙基三甲氧基硅烷、3-氨基苯基三甲氧基硅烷、2-(4-N-苄基乙二胺基)乙基三甲氧基硅烷或N,N-二(2-羟乙基)-3-氨丙基三乙氧基硅烷;The aminosilicone is aniline methyltrimethoxysilane, aniline methyltriethoxysilane, N-(4-aminobutyl)aminomethyltriethoxysilane, γ-aminopropyltrimethoxy Silane, (3-aminopropyl)triethoxysilane, N-methyl-3-aminopropyltrimethoxysilane, N-phenyl-3-aminopropyltrimethoxysilane, γ-(β -aminoethyl)aminopropyltrimethoxysilane, γ-(β-aminoethyl)aminopropylmethyldimethoxysilane, γ-diethylenetriaminopropyltrimethoxysilane, 3-aminobenzene Trimethoxysilane, 2-(4-N-benzylethylenediamine)ethyltrimethoxysilane or N,N-bis(2-hydroxyethyl)-3-aminopropyltriethoxysilane ;
    所述的氯烃基硅氧烷是γ-氯丙基三氯硅烷、γ-氯丙基三甲氧基硅烷、γ-氯丙基三乙 氧基硅烷或2-(4-氯化苄基)乙基三甲氧基硅烷;The chloroalkylsiloxane is γ-chloropropyltrichlorosilane, γ-chloropropyltrimethoxysilane, γ-chloropropyltriethyl Oxysilane or 2-(4-chlorobenzyl)ethyltrimethoxysilane;
    所述的甲基丙烯酰氧基硅氧烷是γ-甲基丙烯酰氧丙基三氯硅烷、γ-甲基丙烯酰氧丙基三甲氧基硅烷、γ-甲基丙烯酰氧丙基三(β—甲氧基乙氧基)硅烷或γ-甲基丙烯酰氧丙基三(三甲基硅氧烷基)硅烷;The methacryloxysiloxane is γ-methacryloxypropyltrichlorosilane, γ-methacryloxypropyltrimethoxysilane, γ-methacryloxypropyl three (β-methoxyethoxy)silane or γ-methacryloxypropyltris(trimethylsiloxy)silane;
    所述的环氧基硅氧烷是3—(2,3环氧丙氧)丙基三甲氧基、β—(3,4环氧基环己基)乙基三甲氧基硅烷、β-(3,4环氧基环己基)乙基三乙氧基硅烷或β-(3,4环氧基环己基)乙基甲基二乙氧基硅烷。The epoxy siloxane is 3-(2,3 epoxypropoxy)propyltrimethoxy, β-(3,4-epoxycyclohexyl)ethyltrimethoxysilane, β-(3) , 4-epoxycyclohexyl)ethyltriethoxysilane or β-(3,4-epoxycyclohexyl)ethylmethyldiethoxysilane.
  8. 如权利要求5所述的桥联式防水涂料,其特征在于,所述的双金属防水桥联剂为铝锆酸酯防水桥联剂。The bridge type waterproof coating according to claim 5, wherein the bimetallic waterproof bridge agent is an aluminum zirconate waterproof bridge agent.
  9. 如权利要求5所述的桥联式防水涂料,其特征在于,所述的木质素防水桥联剂是造纸工业副产的木质素类大分子有机混合物。The bridge-type waterproof coating according to claim 5, wherein the lignin waterproofing bridge agent is a lignin-based macromolecular organic mixture produced by the paper industry.
  10. 如权利要求5所述的桥联式防水涂料,其特征在于,所述的锡防水桥联剂是四氯化锡、氯化三辛基锡或二氯化二辛基锡。The bridge type waterproof coating according to claim 5, wherein the tin waterproof bridge agent is tin tetrachloride, trioctyltin chloride or dioctyltin dichloride.
  11. 如权利要求5所述的桥联式防水涂料,其特征在于,所述的锆防水桥联剂是四正丁基锆酸酯、四戊基锆酸酯或四辛基锆酸酯。The bridge-type water repellent coating according to claim 5, wherein the zirconium water-repellent bridging agent is tetra-n-butyl zirconate, tetrapentyl zirconate or tetraoctyl zirconate.
  12. 如权利要求5所述的桥联式防水涂料,其特征在于,所述的磷酸酯防水桥联剂是二正丁基甲基磷酸酯、二正丁基乙基磷酸酯、二辛基甲基磷酸酯或二辛基乙基磷酸酯。The bridge type waterproof coating according to claim 5, wherein said phosphate waterproof bridge agent is di-n-butyl methyl phosphate, di-n-butyl ethyl phosphate, dioctyl methyl phosphate Or dioctylethyl phosphate.
  13. 如权利要求5所述的桥联式防水涂料,其特征在于,所述的稀土防水桥联剂是月桂酸稀土化合物或硬脂酸稀土化合物。The bridge type waterproof coating according to claim 5, wherein the rare earth waterproofing bridge agent is a rare earth lauric acid compound or a rare earth stearic acid compound.
  14. 如权利要求1所述的桥联式防水涂料,其特征在于,其生产方法包括以下步骤:将乳化沥青和防水桥联剂在常温下搅拌1~3h,使之充分熔融混合,得到混合物A;再启动乳化机,将混合物A与橡胶胶乳水溶液混合,同时加入至乳化机,将沥青混合物乳化,搅拌均匀,得到桥联式防水涂料产品。The bridge type waterproof coating according to claim 1, wherein the production method comprises the following steps: stirring the emulsified asphalt and the water-repellent bridging agent at room temperature for 1 to 3 hours, and fully melt-mixing to obtain a mixture A; The emulsifier is restarted, the mixture A is mixed with the rubber latex aqueous solution, and simultaneously added to the emulsifier, the asphalt mixture is emulsified, and the mixture is uniformly stirred to obtain a bridge-type waterproof coating product.
  15. 如权利要求1所述的桥联式防水涂料,在作为混凝土基面或基面连接处、水管边与混凝土之间的防水涂料方面的用途。 The bridge type waterproof coating according to claim 1, which is used as a waterproof coating between a concrete base surface or a base joint, a water pipe edge and concrete.
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