CN107455384A - A kind of pesticide synergistic composition containing phenthoate dimephenthoate cidial - Google Patents
A kind of pesticide synergistic composition containing phenthoate dimephenthoate cidial Download PDFInfo
- Publication number
- CN107455384A CN107455384A CN201710899949.3A CN201710899949A CN107455384A CN 107455384 A CN107455384 A CN 107455384A CN 201710899949 A CN201710899949 A CN 201710899949A CN 107455384 A CN107455384 A CN 107455384A
- Authority
- CN
- China
- Prior art keywords
- diacloden
- dimephenthoate cidial
- phenthoate dimephenthoate
- composition pesticide
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
- A01N57/14—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing aromatic radicals
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N51/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds having the sequences of atoms O—N—S, X—O—S, N—N—S, O—N—N or O-halogen, regardless of the number of bonds each atom has and with no atom of these sequences forming part of a heterocyclic ring
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention relates to a kind of composition pesticide, its active component contains phenthoate dimephenthoate cidial and Diacloden, and the weight ratio of the phenthoate dimephenthoate cidial and Diacloden is 5:1 to 12:1.It is used for the purposes for preventing and treating agricultural pests the invention further relates to the composition pesticide.
Description
Technical field
The invention belongs to technical field of pesticide combination, and in particular to a kind of pesticide synergistic group containing phenthoate dimephenthoate cidial and Diacloden
Compound and its application for preventing and treating crop pest.
Background technology
Phenthoate dimephenthoate cidial (phenthoate), molecular formula：C12H17O4PS2, chemical name：O, O- dimethyl-S- (α-ethyoxyl
Carbonyl benzyl) phosphorodithioate, its mechanism of action is the acetylcholinesterase in suppression insect bodies.Phenthoate dimephenthoate cidial is a kind of high
Effect, broad spectrum activity organophosphor desinsection, ovicidal, acaricide, have and tag and stomach poison function, no systemic action.In addition, also there is residual effect
The characteristics of phase is long, quick-acting is strong, to crop safety.Available for preventing and treating rice, cotton, vegetables, citrus, fruit tree, tealeaves, oil plant etc.
The various pests such as the pink rice borer of crop, striped rice borer, yellow rice borer, leafhopper, plant hopper.Suitable for crops such as rice, cotton, fruit tree, vegetables.
Diacloden, English common name：Thiamethoxam, chemical name：3- (the chloro- 1,3- thiazoles -5- ylmethyls of 2-) -5-
Methyl isophthalic acid, 3,5- oxadiazines -4- bases fork (nitro) amine, is white crystal.Diacloden is that a kind of second generation of brand new is saline and alkaline
Class high-efficient low toxicity insecticide, there is stomach toxicity to insect, tag, Inner suctions effect, have the characteristics that work fast, lasting period are long.
Diacloden can effectively prevent and treat Lepidoptera, coleopteran pest, such as various aphids, leafhopper, aleyrodid, plant hopper, thrips, scale insect, yellow bar
Flea beetle etc., especially there is special efficacy to aphid, plant hopper etc., available for rice, tea tree, flowers, potato, vegetables, cotton, fruit tree etc.
Crop.
Use of the single dose in cultural control, often in the presence of many defects, long-term a large amount of single uses, it can make unavoidably
Plant insects produce resistance to medicament, cause preventive effect to reduce, dosage increases, cost is high, pollutes environment etc..And different activities into
Divide and compounded, can effectively overcome disadvantage mentioned above.Meanwhile utilize synergistic effect caused by two kinds of active components mixture, Ke Yiti
High preventive effect, the dosage for reducing active ingredient, the generation saved drug cost, delay pest resistance to insecticide, reduction environmental pollution, are comprehensive
Close the important means of pest control.
In recent years, harm of the small chinch bug of cotton to cotton is more serious, and long-term medication causes the resistance to the action of a drug of small chinch bug bright
Aobvious increase, lacks the medicament to its effective preventing and treating on the market at present.
The content of the invention
The problem of being difficult to preventing and treating for the small chinch bug of cotton, the present inventor passes through substantial amounts of screening test, it is proposed that phenthoate dimephenthoate cidial
With the pesticide complex composition of Diacloden, the complex composition can effectively prevent and treat the small chinch bug of cotton, solve asking agriculturally
Topic.
One aspect of the present invention is related to a kind of composition pesticide, and its active component contains phenthoate dimephenthoate cidial and Diacloden.Preferably, institute
The active component for stating composition pesticide is only made up of phenthoate dimephenthoate cidial and Diacloden.
In a kind of preferred embodiment of the present invention, wherein, the weight ratio of the phenthoate dimephenthoate cidial and Diacloden is 5:1 to
12:1, preferably 7:1 to 9:1, more preferably 7:1.
In a kind of preferred embodiment of the present invention, wherein, the composition is further comprising agriculturally acceptable
Carrier and/or auxiliary agent, it is prepared into agriculturally available formulation.
Preferably, the formulation is the weight hundred of missible oil, suspending agent, wettable powder or aqueous emulsion, wherein active ingredient
It is 6%-70%, preferably 10-50% to divide content.Used carrier and/or auxiliary agent including but not limited to solvent, cosolvent, emulsifying agent,
Dispersant, wetting agent, adhesive, disintegrant, thickener, antifreezing agent, cyst material, defoamer, preservative, stabilizer, pH are adjusted
Save agent, filler and/or carrier etc..
In one embodiment of the invention, composition pesticide of the present invention is prepared into missible oil, its formula group
As (weight percentage)：Phenthoate dimephenthoate cidial 0.5-50%, Diacloden 0.1-30%, emulsifying agent 1-20%, wetting agent 1-20% are molten
Agent complements to 100%.
Preparation method is：Active ingredient and various auxiliary agents are added in solvent, agitated to make each composition fully dissolve, system
Obtain missible oil.
In one embodiment of the invention, the composition pesticide of the present invention is prepared into suspending agent, it is formulated composition
For (weight percentage)：Phenthoate dimephenthoate cidial 0.5-50%, Diacloden 0.1-30%, dispersant 2-25%, wetting agent 1-20%, thickening
Agent 0.1-10%, antifreezing agent 0.5-10%, defoamer 0.1-4%, water complement to 100%.
Preparation method is：Active ingredient and various auxiliary agents are mixed with water, disperseed through high speed shear, sand mill is sanded
Afterwards, high dispersive, stable suspension system are formed, suspending agent is made.
In one embodiment of the invention, the composition pesticide of the present invention is prepared into wettable powder, it is formulated
Form as (weight percentage)：Phenthoate dimephenthoate cidial 0.5-50%, Diacloden 0.1-30%, dispersant 2-20%, wetting agent 2-20%,
Solid carrier complements to 100%.
Preparation method is：Each component is mixed, ground, crushing, wettable powder is made.
In one embodiment of the invention, the composition pesticide of the present invention is prepared into aqueous emulsion, it is formulated composition
For (weight percentage)：Phenthoate dimephenthoate cidial 0.5-50%, Diacloden 0.1-30%, solvent 1-30%, emulsifying agent 2-20%, dispersant
2-20%, thickener 1-10%, defoamer 0.5-10%, antifreezing agent 0.1-10%, stabilizer 0-5%, water complement to 100%.
Preparation method is：The dissolving of active ingredient solvent is prepared into oil phase, it is equal that other each components are added to the water into stirring
It is even to be prepared into aqueous phase, oil phase is then added into aqueous phase while stirring, stirred, aqueous emulsion is made.
In embodiment of the present invention, wherein,
The solvent can be selected from dimethylformamide, ethanol, ether, chloroform, acetone, toluene, dimethylbenzene, cyclohexanone,
One or more in dimethyl sulfoxide (DMSO), petroleum ether, hexamethylene, cyclohexanol, ethyl acetate, mineral oil.
The emulsifying agent can be selected from thermally coupled distillation columns, castor oil polyoxyethylene ether, polyoxyethylene nonyl phenyl
It is vinethene, lauryl sodium sulfate, neopelex, calcium dodecyl benzene sulfonate, Polyoxyethylene fatty acid amides fatty acid ester, wooden
Plain sulfonate, naphthalenesulfonate formaldehyde condensation compound, benzyl dimethyl phenol polyoxyethyl ether, styryl phenyl APEO, fat
Fat alcohol APEO, polyoxyethylene alkyl ether, Polyoxyethylene Sorbitol Fatty Acid Esters, sorbitan monostearate, dehydration
One or more in sorbitol monostearate APEO, sorbitan fatty acid ester APEO.
The dispersant can be selected from naphthalenesulfonate formaldehyde condensation compound, naphthalene sulfonic acid-formaldehyde condensation product sodium salt, lignin sulfonic acid
Salt, Polyoxyethylene Sorbitan acid esters, polyoxyethylene glyceryl mono fatty acid ester, p-hydroxyphenyl sodium lignin sulfonate, fat
Fat alcohol APEO, aliphatic alcohol polyoxyvinethene phosphate, NPE, glycerine fatty acid APEO,
One kind or more in polyoxyethylene alkylaryl ether, polyoxyethylene lanolin alcohol, alkylolamides and polyoxyethylene alkyl amine etc.
Kind.
The wetting agent can be selected from oleoyl methyl sodium taurocholate, polyoxyethylene lauryl ether carboxylic acid sodium, dodecyl
Benzene sulfonic acid calcium, lauryl sodium sulfate, isooctanol Disodium sulfosuccinate, sodium N-lauroyl sarcosinate, N- lauroyl paddy ammonia
Sour sodium, trisiloxanes APEO, castor oil polyoxyethylene ether, AEO, sorbitan aliphatic ester etc.
In one or more.
The thickener can be selected from aluminium-magnesium silicate, sodium alginate, sodium carboxymethylcellulose, Arabic gum, polyvinyl alcohol,
One or more in xanthans, gelatin, polyvinyl acetate.
The defoamer can be selected from the one or more in n- octanol, phosphoric acid isobutyl ester, butylphosphoric acid ester, silicone.
The antifreezing agent can be selected from the one or more in ethylene glycol, propane diols, glycerine.
The stabilizer can be selected from N- soybean oleyl trimethylene diamine, triphenyl phosphite, epoxychloropropane, butyl
One or more in glycidol ether etc..
The carrier can be selected from attapulgite, kaolin, white carbon, bentonite, sepiolite, diatomite, montmorillonite, light
One or more in matter calcium carbonate, talcum powder, clay.
Another aspect of the present invention is related to the purposes that described composition pesticide is used to prevent and treat agricultural pests.Wherein, the agriculture
The small chinch bug of the preferred cotton of industry insect.
The present invention is more serious for harm of the small chinch bug of cotton to cotton, and long-term medication causes the resistance to the action of a drug of small chinch bug
Obvious increase, lacks the prior art of the medicament to its effective preventing and treating, cotton can effectively be prevented and treated by having filtered out on the market at present
The composition pesticide of small chinch bug, proved by indoor and field test, in the present invention after the reasonable compounding of two kinds of insecticides, tool
There is obvious synergistic effect.
Embodiment
With reference to embodiment and application, the present invention is further illustrated, and the percentage in embodiment is weight hundred
Divide ratio, but the invention is not limited in this.
Unless otherwise indicated, percentage described in following embodiments is weight percentage.
First, indoor bioassay
For trying insect：The small chinch bug of cotton
Reagent agent：Phenthoate dimephenthoate cidial, Diacloden, had respectively by Jiangsu Tenglong Biological Pharmaceutical Co., Ltd. and Zhejiang grass science and technology
Limit company provides
Experimental design：
The cotton tender tip of collection is cleaned, dried, is then immersed in each concentration gradient decoction of the different ratio prepared
5s is soaked, naturally dry is taken out, is put into insect box, then connects for examination nymph, is raised under the conditions of 25 DEG C.Often handle 4 times
Repeat, often repeat test worm 10 used, while set blank control.Death toll is checked after 72 hours, and calculates the death rate and correction
The death rate.
Corrected mortality is converted into probit value (y), concentration for the treatment of (mg/L) is converted into logarithmic form, tries to achieve toxicity regression
Equation simultaneously calculates LC50Value.Then, co-toxicity coefficient CTC is calculated according to Sun Yun Liubang's formula.Wherein, CTC ＜ 80 are antagonism,
80≤CTC≤120 are summation action, and CTC ＞ 120 are synergistic effect.Calculation formula it is following (using phenthoate dimephenthoate cidial as standard agent, its
100) toxicity index is：
TI × P of M theoretical toxicity index (TTI)=phenthoate dimephenthoate cidialPhenthoate dimephenthoate cidialTI × P of+DiaclodenDiacloden
In formula：
M is the mixture of different ratio
PPhenthoate dimephenthoate cidialFor phenthoate dimephenthoate cidial shared ratio in the composition
PDiaclodenFor Diacloden shared ratio in the composition
As a result it is described in table 1 below.
Toxicity test of the phenthoate dimephenthoate cidial of table 1 with Diacloden different ratio to the small chinch bug of cotton
Phenthoate dimephenthoate cidial is tested the small chinch bug Toxicity Determination of cotton with Diacloden and compounding and found, when phenthoate dimephenthoate cidial and thiophene worm
Piperazine proportioning is 5:1 to 12:Co-toxicity coefficient is all higher than 120 when 1, indicates obvious synergistic effect, when the two proportioning is 7:1 to 9:
When 1, synergistic effect substantially protrudes；Especially when the ratio of phenthoate dimephenthoate cidial and Diacloden is 7:When 1, co-toxicity coefficient is maximum, synergistic effect
It is the most obvious.It can be seen that phenthoate dimephenthoate cidial：Diacloden is 5:1 to 12:There is synergistic function to the small chinch bug of cotton between 1.
2nd, example of formulations
Embodiment 1
Phenthoate dimephenthoate cidial 10%, Diacloden 2%, neopelex 6%, trisiloxanes APEO 4%, dimethyl
Formamide complements to 100%.
Preparation method is：Each component is added in dimethyl formyl, it is agitated each composition is fully dissolved, missible oil is made.
Embodiment 2
Phenthoate dimephenthoate cidial 12%, Diacloden 1%, AEO 5%, N- sodium lauroyl glutamates 4%, dimethyl
Formamide complements to 100%.
Preparation method is：Each component is added in dimethyl formyl, it is agitated each composition is fully dissolved, missible oil is made.
Embodiment 3
Phenthoate dimephenthoate cidial 28%, Diacloden 4%, p-hydroxyphenyl sodium lignin sulfonate 9%, castor oil polyoxyethylene ether 6%, poly- second
Enol 4%, ethylene glycol 4%, n- octanol 0.5%, water complements to 100%.
Preparation method is：Phenthoate dimephenthoate cidial, Diacloden and other components are mixed with water, disperseed through high speed shear, sand mill
After sand milling, high dispersive, stable suspension system are formed, suspending agent is made.
Embodiment 4
Phenthoate dimephenthoate cidial 18%, Diacloden 2%, polyoxyethylene lanolin alcohol 6%, calcium dodecyl benzene sulfonate 7%, carboxymethyl are fine
Plain sodium 5% is tieed up, ethylene glycol 5%, phosphoric acid isobutyl ester 0.5%, water complements to 100%.
Preparation method is：Phenthoate dimephenthoate cidial, Diacloden and other components are mixed with water, disperseed through high speed shear, sand mill
After sand milling, high dispersive, stable suspension system are formed, suspending agent is made.
Embodiment 5
Phenthoate dimephenthoate cidial 35%, Diacloden 7%, naphthalene sulfonic acid-formaldehyde condensation product sodium salt 6%, AEO 5%, swelling
Soil complements to 100%.
Preparation method is：Each component is mixed, ground, crushing, wettable powder is made.
Embodiment 6
Phenthoate dimephenthoate cidial 27%, Diacloden 3%, glycerine fatty acid APEO 4%, N- sodium lauroyl glutamates 7% are recessed
Convex rod soil complements to 100%.
Preparation method is：Each component is mixed, ground, crushing, wettable powder is made.
Embodiment 7
Phenthoate dimephenthoate cidial 14%, Diacloden 2%, dimethylformamide 18%, sodium lignin sulfonate 7%, naphthalenesulfonateformaldehyde formaldehyde condensation
Thing sodium 3%, polyvinyl alcohol 4%, butylphosphoric acid ester 0.5%, glycerine 5%, water complements to 100%.
Preparation method is：Phenthoate dimephenthoate cidial, the dissolving of Diacloden dimethylformamide are prepared into oil phase, other each components are added
Enter to stir in water and be prepared into aqueous phase, oil phase is then added into aqueous phase while stirring, stirred, aqueous emulsion is made.
Embodiment 8
Phenthoate dimephenthoate cidial 12%, Diacloden 1%, dimethylformamide 15%, NPE 6%, polyoxyethylene sheep
Hair lipidol 5%, polyvinyl alcohol 5%, silicone 0.5%, glycerine 5%, water complements to 100%.
Preparation method is：Phenthoate dimephenthoate cidial, the dissolving of Diacloden dimethylformamide are prepared into oil phase, other each components are added
Enter to stir in water and be prepared into aqueous phase, oil phase is then added into aqueous phase while stirring, stirred, aqueous emulsion is made.
3rd, field test
The small chinch bug of cotton occurs serious and carries out field efficacy examination as experimental plot, delimitation cell than more uniform cotton field
Test, respectively handle random alignment, often handle 3 repetitions, separately set blank control.Before treatment, to insect population base before each cell progress medicine
Number investigation, then with hand sprayer routine dispenser, carry out preventive effect investigation within 7 days after medicine, investigation uses five point sampling.Under
State formula and calculate Rectifying efficacies, as a result see the table below 2：
The field test results of table 2
| Medicament | Active component dosage (gram/acre) | Preventive effect (%) |
| Embodiment 1 | 12 | 84.2 |
| Embodiment 3 | 14 | 93.7 |
| Embodiment 6 | 20 | 92.1 |
| Embodiment 8 | 26 | 87.5 |
| 75% Diacloden wettable powder | 6 | 68.2 |
| 50% phenthoate dimephenthoate cidial missible oil | 30 | 59.6 |
Above-mentioned field test results can be seen that compared to the Diacloden wettable powder of single dose 75%, 50% phenthoate dimephenthoate cidial breast
Oil, in the case where effective dose reduces, preventive effect still substantially increases preparation of the invention, and the wherein increase of embodiment 3,6 is more bright
It is aobvious, it is especially more prominent with embodiment 3.That is, through field test, composition of the invention has to the small chinch bug of field cotton
There is obvious synergistic effect.
The present invention is described by specific embodiment.Those skilled in the art can use for reference the interior of the present invention
Accommodate when links such as feed change, process conditions to realize corresponding other purposes, its correlation changes all without departing from the present invention
Content, all similar replacements and change are it will become apparent to those skilled in the art that be considered as being included in
Within the scope of the present invention.
Claims (8)
- A kind of 1. composition pesticide, it is characterised in that active ingredient contains phenthoate dimephenthoate cidial and Diacloden in the composition pesticide, its The weight ratio of middle phenthoate dimephenthoate cidial and Diacloden is 1:12 to 12:1.
- 2. composition pesticide according to claim 1, it is characterised in that the weight ratio of the phenthoate dimephenthoate cidial and Diacloden is 5: 1 to 12:1.
- 3. composition pesticide according to claim 1 or 2, it is characterised in that the composition is further comprising agriculturally Acceptable carrier and/or auxiliary agent, it is prepared into agriculturally available formulation.
- 4. composition pesticide according to claim 3, it is characterised in that the formulation is missible oil, suspending agent, wettable powder Agent or aqueous emulsion.
- 5. the composition pesticide according to claim 3 or 4, it is characterised in that the weight percentage of the active ingredient For 6%-70%.
- 6. composition pesticide according to claim 5, it is characterised in that the weight percentage of the active ingredient is preferred 10-50%.
- 7. the composition pesticide described in claim any one of 1-6 is used for the purposes for preventing and treating agricultural pests.
- 8. purposes according to claim 7, it is characterised in that the small chinch bug of the preferred cotton of agricultural pests.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710899949.3A CN107455384B (en) | 2017-09-28 | 2017-09-28 | A kind of pesticide synergistic composition containing phenthoate dimephenthoate cidial |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710899949.3A CN107455384B (en) | 2017-09-28 | 2017-09-28 | A kind of pesticide synergistic composition containing phenthoate dimephenthoate cidial |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN107455384A true CN107455384A (en) | 2017-12-12 |
| CN107455384B CN107455384B (en) | 2018-08-17 |
Family
ID=60553157
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710899949.3A Active CN107455384B (en) | 2017-09-28 | 2017-09-28 | A kind of pesticide synergistic composition containing phenthoate dimephenthoate cidial |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107455384B (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1921759A (en) * | 2004-02-24 | 2007-02-28 | 住化武田农药株式会社 | Insecticide composition |
| CN101326913A (en) * | 2008-05-14 | 2008-12-24 | 青岛瀚生生物科技股份有限公司 | Compositional composition containing Fipronil and benzoyl urea pesticide compound |
| CN102037990A (en) * | 2010-12-30 | 2011-05-04 | 江苏腾龙生物药业有限公司 | Pesticide composition containing phenthoate and buprofezin |
| CN102217644A (en) * | 2011-03-25 | 2011-10-19 | 陕西汤普森生物科技有限公司 | Synergistic pesticide composition containing Sulfoxaflor |
-
2017
- 2017-09-28 CN CN201710899949.3A patent/CN107455384B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1921759A (en) * | 2004-02-24 | 2007-02-28 | 住化武田农药株式会社 | Insecticide composition |
| CN101326913A (en) * | 2008-05-14 | 2008-12-24 | 青岛瀚生生物科技股份有限公司 | Compositional composition containing Fipronil and benzoyl urea pesticide compound |
| CN102037990A (en) * | 2010-12-30 | 2011-05-04 | 江苏腾龙生物药业有限公司 | Pesticide composition containing phenthoate and buprofezin |
| CN102217644A (en) * | 2011-03-25 | 2011-10-19 | 陕西汤普森生物科技有限公司 | Synergistic pesticide composition containing Sulfoxaflor |
Non-Patent Citations (1)
| Title |
|---|
| 张帅，等: "杀虫剂对长江中下游地区水稻害虫田间防效", 《农药》 * |
Also Published As
| Publication number | Publication date |
|---|---|
| CN107455384B (en) | 2018-08-17 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103283764A (en) | Cyantraniliprole containing insecticidal composition | |
| CN105901005A (en) | Weeding composition containing pyraclonil | |
| CN101263823A (en) | Indoxacarb and emamectin benzoate-chlorfenapyr pesticidal composition | |
| CN106689145A (en) | Weeding composition containing pyroxasulfone and amide herbicides | |
| CN101703054A (en) | Insecticidal composite of Cyantraniliprole and methylamino abamectin benzoate | |
| CN104115845B (en) | A kind of high-efficient pesticide composition containing fluorobenzene insect amide | |
| CN103155929B (en) | Binary pesticide composition and application thereof | |
| CN102210321A (en) | Pesticide composite containing etoxazole | |
| CN102084862B (en) | Insecticidal composition containing ethiprole | |
| CN103004867B (en) | Insecticidal composition with synergism | |
| CN103070183B (en) | High-efficiency and low-toxicity composite bird repellent containing thiram and dimethyl phthalate | |
| CN108013045A (en) | A kind of agricultural insecticide composition containing fluorine pyrrole furanone and Tolfenpyrad | |
| CN102273476B (en) | Pesticide composition containing bispyribac-sodium | |
| CN102228056A (en) | Pesticide composition containing sulfur-fluorine oxime ether and part of organophosphorus pesticides | |
| CN107455384B (en) | A kind of pesticide synergistic composition containing phenthoate dimephenthoate cidial | |
| CN104396961A (en) | Suspending agent comprising spirodiclofen | |
| CN104855399B (en) | A kind of Pesticidal combination containing butene-fipronil and fluorobenzene insect amide | |
| CN107306947A (en) | A kind of agricultural synergist and pyraclostrobin, the mixture of Prochloraz compound mixture and its preparation and application | |
| CN103518773B (en) | Insecticidal composition with synergism | |
| CN103250713B (en) | Synergistic pesticide composition for killing gall midge insects | |
| WO2021019574A1 (en) | Synergistic pesticidal composition | |
| CN102669152B (en) | A kind of Pesticidal combination containing Tefluthrin | |
| CN104351238A (en) | Pesticide composition containing picoxystrobin and pyrethroids, preparation and application thereof | |
| CN103503896A (en) | Insecticide composition having synergistic effect | |
| CN103478135A (en) | Insect disinfestation composition containing dicyclanil and diacylhydrazine |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |