CN107449757A - 高灵敏度及稳定度的光纤消逝场氢浓度传感器及制备方法 - Google Patents
高灵敏度及稳定度的光纤消逝场氢浓度传感器及制备方法 Download PDFInfo
- Publication number
- CN107449757A CN107449757A CN201710781626.4A CN201710781626A CN107449757A CN 107449757 A CN107449757 A CN 107449757A CN 201710781626 A CN201710781626 A CN 201710781626A CN 107449757 A CN107449757 A CN 107449757A
- Authority
- CN
- China
- Prior art keywords
- fiber
- film
- thickness
- fibre
- optical fiber
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000835 fiber Substances 0.000 title claims abstract description 154
- 239000001257 hydrogen Substances 0.000 title claims abstract description 96
- 229910052739 hydrogen Inorganic materials 0.000 title claims abstract description 96
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 title claims abstract description 54
- 238000002360 preparation method Methods 0.000 title claims abstract description 23
- 230000035945 sensitivity Effects 0.000 title claims abstract description 23
- 239000010408 film Substances 0.000 claims abstract description 127
- 239000013307 optical fiber Substances 0.000 claims abstract description 64
- 239000011347 resin Substances 0.000 claims abstract description 46
- 229920005989 resin Polymers 0.000 claims abstract description 46
- 150000002431 hydrogen Chemical class 0.000 claims abstract description 43
- 229920001690 polydopamine Polymers 0.000 claims abstract description 36
- 239000004810 polytetrafluoroethylene Substances 0.000 claims abstract description 36
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims abstract description 36
- 230000003287 optical effect Effects 0.000 claims abstract description 34
- 238000005253 cladding Methods 0.000 claims abstract description 32
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 29
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims abstract description 16
- VYFYYTLLBUKUHU-UHFFFAOYSA-N dopamine Chemical compound NCCC1=CC=C(O)C(O)=C1 VYFYYTLLBUKUHU-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000010409 thin film Substances 0.000 claims abstract description 10
- 229960003638 dopamine Drugs 0.000 claims abstract description 8
- 239000000203 mixture Substances 0.000 claims abstract description 6
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical group [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 59
- 229910052763 palladium Inorganic materials 0.000 claims description 27
- 238000005260 corrosion Methods 0.000 claims description 22
- 239000000463 material Substances 0.000 claims description 22
- 230000007797 corrosion Effects 0.000 claims description 21
- -1 polyethylene Polymers 0.000 claims description 16
- 239000011248 coating agent Substances 0.000 claims description 15
- 238000000576 coating method Methods 0.000 claims description 15
- 230000002209 hydrophobic effect Effects 0.000 claims description 10
- 239000007788 liquid Substances 0.000 claims description 10
- 238000000926 separation method Methods 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 7
- 239000002105 nanoparticle Substances 0.000 claims description 7
- MUJIDPITZJWBSW-UHFFFAOYSA-N palladium(2+) Chemical compound [Pd+2] MUJIDPITZJWBSW-UHFFFAOYSA-N 0.000 claims description 7
- 239000012528 membrane Substances 0.000 claims description 6
- PIBWKRNGBLPSSY-UHFFFAOYSA-L palladium(II) chloride Chemical compound Cl[Pd]Cl PIBWKRNGBLPSSY-UHFFFAOYSA-L 0.000 claims description 6
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims description 5
- 239000008103 glucose Substances 0.000 claims description 5
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 3
- 239000004698 Polyethylene Substances 0.000 claims description 3
- 238000007605 air drying Methods 0.000 claims description 3
- 239000003638 chemical reducing agent Substances 0.000 claims description 3
- 239000007888 film coating Substances 0.000 claims description 3
- 238000009501 film coating Methods 0.000 claims description 3
- 229920000573 polyethylene Polymers 0.000 claims description 3
- 238000001552 radio frequency sputter deposition Methods 0.000 claims description 3
- 239000008096 xylene Substances 0.000 claims description 3
- 230000001235 sensitizing effect Effects 0.000 claims 1
- 230000004044 response Effects 0.000 abstract description 8
- 230000008859 change Effects 0.000 abstract description 7
- 239000007789 gas Substances 0.000 abstract description 4
- 238000003780 insertion Methods 0.000 abstract description 2
- 230000037431 insertion Effects 0.000 abstract description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- 230000005540 biological transmission Effects 0.000 description 8
- 239000012153 distilled water Substances 0.000 description 8
- 230000008034 disappearance Effects 0.000 description 7
- 239000003518 caustics Substances 0.000 description 6
- 230000001419 dependent effect Effects 0.000 description 6
- 230000009467 reduction Effects 0.000 description 6
- 239000013308 plastic optical fiber Substances 0.000 description 5
- KFSLWBXXFJQRDL-UHFFFAOYSA-N Peracetic acid Chemical compound CC(=O)OO KFSLWBXXFJQRDL-UHFFFAOYSA-N 0.000 description 4
- 238000011010 flushing procedure Methods 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 238000005259 measurement Methods 0.000 description 4
- 239000004033 plastic Substances 0.000 description 4
- 229920003023 plastic Polymers 0.000 description 4
- 238000000280 densification Methods 0.000 description 3
- 238000001514 detection method Methods 0.000 description 3
- 239000004065 semiconductor Substances 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 230000003197 catalytic effect Effects 0.000 description 2
- 238000006555 catalytic reaction Methods 0.000 description 2
- 238000010276 construction Methods 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000004880 explosion Methods 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 150000002500 ions Chemical class 0.000 description 2
- 239000007791 liquid phase Substances 0.000 description 2
- 238000002715 modification method Methods 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 2
- 238000001179 sorption measurement Methods 0.000 description 2
- 238000005728 strengthening Methods 0.000 description 2
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical class NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- ZZVUWRFHKOJYTH-UHFFFAOYSA-N diphenhydramine Chemical compound C=1C=CC=CC=1C(OCCN(C)C)C1=CC=CC=C1 ZZVUWRFHKOJYTH-UHFFFAOYSA-N 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000010892 electric spark Methods 0.000 description 1
- 238000004146 energy storage Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 1
- 230000035800 maturation Effects 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- JKQOBWVOAYFWKG-UHFFFAOYSA-N molybdenum trioxide Chemical compound O=[Mo](=O)=O JKQOBWVOAYFWKG-UHFFFAOYSA-N 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- KKCBUQHMOMHUOY-UHFFFAOYSA-N sodium oxide Chemical compound [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
- 229910001948 sodium oxide Inorganic materials 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/17—Systems in which incident light is modified in accordance with the properties of the material investigated
- G01N21/41—Refractivity; Phase-affecting properties, e.g. optical path length
Landscapes
- Physics & Mathematics (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- General Physics & Mathematics (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Investigating Or Analysing Materials By Optical Means (AREA)
- Investigating Or Analysing Materials By The Use Of Chemical Reactions (AREA)
Abstract
Description
Claims (5)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201710781626.4A CN107449757B (zh) | 2017-09-02 | 2017-09-02 | 高灵敏度及稳定度的光纤消逝场氢浓度传感器及制备方法 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201710781626.4A CN107449757B (zh) | 2017-09-02 | 2017-09-02 | 高灵敏度及稳定度的光纤消逝场氢浓度传感器及制备方法 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN107449757A true CN107449757A (zh) | 2017-12-08 |
CN107449757B CN107449757B (zh) | 2020-01-14 |
Family
ID=60494672
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201710781626.4A Active CN107449757B (zh) | 2017-09-02 | 2017-09-02 | 高灵敏度及稳定度的光纤消逝场氢浓度传感器及制备方法 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN107449757B (zh) |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108844921A (zh) * | 2018-09-12 | 2018-11-20 | 中国计量大学 | 基于mz干涉倾斜光纤光栅测量变压器中氢气的传感器 |
CN109342363A (zh) * | 2018-10-18 | 2019-02-15 | 西安电子科技大学 | 一种基于微纳光纤环的折射率传感器及其封装方法 |
CN109632659A (zh) * | 2019-01-04 | 2019-04-16 | 京东方科技集团股份有限公司 | 一种检测仪及检测方法 |
CN109813664A (zh) * | 2019-01-10 | 2019-05-28 | 上海理工大学 | 一种裸露纤芯的全光纤倏逝波传感器 |
CN110031418A (zh) * | 2019-05-17 | 2019-07-19 | 河南工业大学 | 一种微光纤光栅ph3浓度传感器及其制备方法 |
CN110220868A (zh) * | 2019-07-26 | 2019-09-10 | 中国计量大学 | 一种可同时测量氢气和甲烷的pcf-spr结构传感器 |
CN113075165A (zh) * | 2021-03-18 | 2021-07-06 | 重庆理工大学 | 一种u形湿敏光纤传感器及制作方法 |
CN114112911A (zh) * | 2021-11-29 | 2022-03-01 | 中国地质调查局水文地质环境地质调查中心 | 一种用于在线检测的红外光纤倏逝波传感器及制备方法 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2009154216A1 (ja) * | 2008-06-20 | 2009-12-23 | 国立大学法人横浜国立大学 | 分布型光ファイバ水素センサ、多点観測用の分布型光ファイバ水素センサ、水素感応膜及びその製造方法 |
CN102192930A (zh) * | 2010-01-20 | 2011-09-21 | 通用汽车环球科技运作有限责任公司 | 氢传感器组件 |
JP2014059300A (ja) * | 2012-08-24 | 2014-04-03 | Soka Univ | 水素センサ、および、それを用いた検出装置 |
CN104792715A (zh) * | 2015-05-04 | 2015-07-22 | 华北电力大学 | 用于检测变压器油中氢气的光纤布喇格光栅氢气传感器 |
CN105044040A (zh) * | 2015-07-06 | 2015-11-11 | 四川智立方博导科技有限责任公司 | 一种高灵敏度的氢气光纤传感器 |
-
2017
- 2017-09-02 CN CN201710781626.4A patent/CN107449757B/zh active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2009154216A1 (ja) * | 2008-06-20 | 2009-12-23 | 国立大学法人横浜国立大学 | 分布型光ファイバ水素センサ、多点観測用の分布型光ファイバ水素センサ、水素感応膜及びその製造方法 |
CN102192930A (zh) * | 2010-01-20 | 2011-09-21 | 通用汽车环球科技运作有限责任公司 | 氢传感器组件 |
JP2014059300A (ja) * | 2012-08-24 | 2014-04-03 | Soka Univ | 水素センサ、および、それを用いた検出装置 |
CN104792715A (zh) * | 2015-05-04 | 2015-07-22 | 华北电力大学 | 用于检测变压器油中氢气的光纤布喇格光栅氢气传感器 |
CN105044040A (zh) * | 2015-07-06 | 2015-11-11 | 四川智立方博导科技有限责任公司 | 一种高灵敏度的氢气光纤传感器 |
Non-Patent Citations (1)
Title |
---|
S. SEKIMOTO ET AL.: "A fiber-optic evanescent-wave hydrogen gas sensor using palladium-supported tungsten oxide", 《SENSORS AND ACTUATORS B》 * |
Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108844921A (zh) * | 2018-09-12 | 2018-11-20 | 中国计量大学 | 基于mz干涉倾斜光纤光栅测量变压器中氢气的传感器 |
CN108844921B (zh) * | 2018-09-12 | 2024-02-06 | 中国计量大学 | 基于mz干涉倾斜光纤光栅测量变压器中氢气的传感器 |
CN109342363A (zh) * | 2018-10-18 | 2019-02-15 | 西安电子科技大学 | 一种基于微纳光纤环的折射率传感器及其封装方法 |
CN109632659A (zh) * | 2019-01-04 | 2019-04-16 | 京东方科技集团股份有限公司 | 一种检测仪及检测方法 |
CN109632659B (zh) * | 2019-01-04 | 2022-07-05 | 京东方科技集团股份有限公司 | 一种检测仪及检测方法 |
CN109813664A (zh) * | 2019-01-10 | 2019-05-28 | 上海理工大学 | 一种裸露纤芯的全光纤倏逝波传感器 |
CN110031418A (zh) * | 2019-05-17 | 2019-07-19 | 河南工业大学 | 一种微光纤光栅ph3浓度传感器及其制备方法 |
CN110220868A (zh) * | 2019-07-26 | 2019-09-10 | 中国计量大学 | 一种可同时测量氢气和甲烷的pcf-spr结构传感器 |
CN110220868B (zh) * | 2019-07-26 | 2023-06-20 | 中国计量大学 | 一种可同时测量氢气和甲烷的pcf-spr结构传感器 |
CN113075165A (zh) * | 2021-03-18 | 2021-07-06 | 重庆理工大学 | 一种u形湿敏光纤传感器及制作方法 |
CN113075165B (zh) * | 2021-03-18 | 2022-10-18 | 重庆理工大学 | 一种u形湿敏光纤传感器及制作方法 |
CN114112911A (zh) * | 2021-11-29 | 2022-03-01 | 中国地质调查局水文地质环境地质调查中心 | 一种用于在线检测的红外光纤倏逝波传感器及制备方法 |
Also Published As
Publication number | Publication date |
---|---|
CN107449757B (zh) | 2020-01-14 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN107449757A (zh) | 高灵敏度及稳定度的光纤消逝场氢浓度传感器及制备方法 | |
Lokman et al. | Optical fiber relative humidity sensor based on inline Mach–Zehnder interferometer with ZnO nanowires coating | |
Luna-Moreno et al. | Optical fiber hydrogen sensor based on core diameter mismatch and annealed Pd–Au thin films | |
CN107607218A (zh) | 温度和浓度同时测量的fbg氢气传感器及其制备方法 | |
US20040264901A1 (en) | Moisture sensor based on evanescent wave light scattering by porous sol-gel silica coating | |
US7720321B2 (en) | Fiber optic sensor and method for making | |
CN103852428A (zh) | 一种基于多模纤芯和光纤光栅的湿度传感器及其制备方法 | |
CN207540970U (zh) | 一种基于氧化石墨烯镀层光纤的湿度传感器 | |
Bian et al. | A novel optical fiber Mach–Zehnder interferometer based on the calcium alginate hydrogel film for humidity sensing | |
Li et al. | A fiber-optic formic acid gas sensor based on molybdenum disulfide nanosheets and chitosan works at room temperature | |
CN109142271B (zh) | 一种结合蜘蛛包卵丝的光纤湿度传感器及其制作方法 | |
Xia et al. | Polyelectrolyte/graphene oxide nano-film integrated fiber-optic sensors for high-sensitive and rapid-response humidity measurement | |
Moslan et al. | Real-time fluid flow movement identification in porous media for reservoir monitoring application using polycarbonate optical fibre Bragg grating sensor | |
CN207379920U (zh) | 一种基于氧化锌纳米棒的光纤湿度传感器 | |
CN203216865U (zh) | 输电线路绝缘子污秽监测器件 | |
CN108387494B (zh) | 一种基于空芯Bragg光纤的PM2.5浓度检测装置 | |
Johari et al. | Formaldehyde sensing using tapered U-shape plastic optical fiber coated with zinc oxide nanorods | |
CN101551356A (zh) | 一种固定化乙酰胆碱酯酶电化学生物传感器的制备 | |
Okazaki et al. | A reusable fiber optic sensor for the real-time sensing of CaCO 3 scale formation in geothermal water | |
Sui et al. | Optical fiber relative humidity sensor based on Fabry-Perot interferometer coated with sodium-p-styrenesulfonate/allyamine hydrochloride films | |
CN209432699U (zh) | 一种新型硝酸盐检测传感器探头 | |
CN206132611U (zh) | 基于氧化石墨烯的酒精浓度光纤传感器 | |
CN109142277B (zh) | 一种结合蜘蛛包卵丝的光纤湿度传感器及制作方法 | |
CN206594059U (zh) | 一种基于细芯光纤修饰pva/cnt的迈克尔逊干涉仪的湿度传感器 | |
Roslan et al. | Relative Humidity Sensor based on Tapered Plastic Optical Fibre with Full-and Spiral-Patterned Agarose Gel Coating |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
TA01 | Transfer of patent application right | ||
TA01 | Transfer of patent application right |
Effective date of registration: 20191219 Address after: 402760 No. 123 Jianshan Road, Bishan District, Chongqing Applicant after: CHONGQING WANTAI ELECTRIC POWER TECHNOLOGY Co.,Ltd. Address before: 402700 Bi Xing Avenue, Bi Quan street, Bishan County, Chongqing City, No. 8 Applicant before: CHONGQING HUANGJUESHU OPTOELECTRONICS TECHNOLOGY CO.,LTD. |
|
GR01 | Patent grant | ||
GR01 | Patent grant | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: Optical fiber evanescent field hydrogen concentration sensor with high sensitivity and stability and its preparation method Effective date of registration: 20210713 Granted publication date: 20200114 Pledgee: China Minsheng Banking Corp Chongqing branch Pledgor: CHONGQING WANTAI ELECTRIC POWER TECHNOLOGY Co.,Ltd. Registration number: Y2021500000031 |
|
PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
PC01 | Cancellation of the registration of the contract for pledge of patent right |
Date of cancellation: 20230612 Granted publication date: 20200114 Pledgee: China Minsheng Banking Corp Chongqing branch Pledgor: CHONGQING WANTAI ELECTRIC POWER TECHNOLOGY Co.,Ltd. Registration number: Y2021500000031 |
|
PE01 | Entry into force of the registration of the contract for pledge of patent right | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: High sensitivity and stability optical fiber evanescent field hydrogen concentration sensor and preparation method Effective date of registration: 20231017 Granted publication date: 20200114 Pledgee: China Minsheng Banking Corp Chongqing branch Pledgor: CHONGQING WANTAI ELECTRIC POWER TECHNOLOGY Co.,Ltd. Registration number: Y2023980061382 |