CN107446669A - 防锈乳化油 - Google Patents

防锈乳化油 Download PDF

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CN107446669A
CN107446669A CN201710614613.8A CN201710614613A CN107446669A CN 107446669 A CN107446669 A CN 107446669A CN 201710614613 A CN201710614613 A CN 201710614613A CN 107446669 A CN107446669 A CN 107446669A
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emulsified oil
anticorrosive emulsified
minutes
anticorrosive
dosage
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陶洪南
范本新
张月亮
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Jiangsu Jetta Oil Co Ltd
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Jiangsu Jetta Oil Co Ltd
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Abstract

本发明涉及一种防锈乳化油包括以下质量百分比的组分：基础油60%～75%，硼酸3%～5%，氢氧化钠0.3%～0.8%，三乙醇胺1%～4%，乳化剂4%～6%，二壬基萘磺酸钡8%～15%，环烷酸锌1%～3%，十二烯基丁二酸1%～5%，乙醇3%～5%。本发明的防锈乳化油防锈性好，稳定性佳。

Description

防锈乳化油
技术领域
本发明涉及一种防锈乳化油及其制备方法，属于润滑油技术领域。
背景技术
在机械加工生产过程中，由防锈乳化油配制的乳化液可以减轻刀具与加工件之间的摩擦，增加润滑性，及时带走由于摩擦而产生的热量，加工后的工件具有防锈性。有利于提高生产率，可有效减少刀具磨损，延长刀具使用寿命，改善工件精度及光洁度，与普通的石油溶剂相比在性能上具有无可比拟的优势。
防锈乳化油适合多种CNC加工中心、组合机床等车削、磨削、拉削及攻丝等加工，可满足各类钢材（特别是磨具钢）、合金钢、不锈钢、铸铁等材料的切削加工，尤其对不锈钢等难加工效果更为显著。适用于黑色金属及铜、铝、铸铁等有色金属和黑色金属的车、钻、锯、磨、攻丝加工工序。
防锈乳化油是高品质的机械加工不可缺少的介质，在机械加工领域取代石油溶剂是大势所趋，近年来我国制造业飞速发展，机械加工行业产能不断增加，对于防锈乳化油的需求量是巨大的。
目前市场上现有的防锈乳化油存在易腐败变质，防锈周期较短，会导致工件光洁度不高，刀具损耗严重等诸多问题。
发明内容
本发明要解决的技术问题是提供一种防锈性好，稳定性佳的防锈乳化油，以及该防锈乳化油的制备方法。
本发明为解决上述技术问题提出的一种技术方案是：一种防锈乳化油，包括以下质量百分比的组分：基础油60%～75%，硼酸3%～5%，氢氧化钠0.3%～0.8%，三乙醇胺1%～4%，乳化剂4%～6%，二壬基萘磺酸钡8%～15%，环烷酸锌1%～3%，十二烯基丁二酸1%～5%，乙醇3%～5%。
所述三乙醇胺的用量是2.5%～3.5%。
所述十二烯基丁二酸的用量是2%～4%。
所述二壬基萘磺酸钡的用量是10%～12%。
所述基础油的用量是66%～69%。
所述基础油是N10号机械油。
所述乳化剂是非离子表面活性剂。
所述非离子表面活性剂是OP-10和Span-80中的一种或两种。
所述非离子表面活性剂是OP-10和Span-80，且OP-10和Span-80的用量质量比为1:1～1.5。
本发明为解决上述技术问题提出的一种技术方案是：上述防锈乳化油的制备方法是将基础油加入反应釜中，然后加入硼酸和氢氧化钠，升温至90℃～95℃，保温搅拌20分钟～30分钟，再加入三乙醇胺，保温搅拌2小时～3小时，待液体透明后加入乳化剂，搅拌20分钟～30分钟，温度控制在80℃～85℃加入二壬基萘磺酸钡、环烷酸锌、十二烯基丁二酸，继续搅拌，混合均匀后，降温至60℃以下，加入乙醇，搅拌20分钟～30分钟即可得到成品。
本发明具有积极的效果：本发明的防锈乳化油由N10号机械油、硼酸、三乙醇胺、OP-10、Span-80、二壬基萘磺酸钡、环烷酸锌、十二烯基丁二酸等混合而成。其采用硼酸取代传统的油酸，采用二壬基萘磺酸钡代替石油磺酸钡和石油磺酸钠，硼酸与氢氧化钠反应生成硼酸钠，硼酸与三乙醇胺反应生成三乙醇胺硼酸酯，具有极好的乳化和防锈效果，可以降低乳化液对pH值的依赖性，OP-10和Span-80共同使用乳化效率高，Span-80、二壬基萘磺酸钡、环烷酸锌、十二烯基丁二酸、三乙醇胺硼酸酯协同作用，使得产品的防锈性得到了很大的提升，防锈时间是同类产品的1.5～2倍。该产品通过对基础油与乳化剂和防锈剂的合理配合及工艺的研究，使其具有优良的冷却性、防锈性、润滑性，还具有良好的清洗性。使用时，防锈乳化油加入水中搅拌成白色乳化液即可，磨削加工一般使用浓度为5%配制乳化液，切削加工使用浓度一般为8～10%。配制的乳化液稳定性极佳，在使用中不会产生泡沫、浑浊、分层、析油等问题。可广泛地应用于机械加工的车床、刨床、磨床上，更广泛地应用于轴承生产的金属加工工艺上，作为冷却、防锈、润滑之用。
具体实施方式
实施例1
本实施例的防锈乳化油的制备方法是将680kg的N10号机械油加入反应釜中，然后加入40kg的硼酸和5kg的氢氧化钠，升温至90℃，保温搅拌30分钟，再加入25kg的三乙醇胺，保温搅拌2小时，待液体透明后加入25kg的乳化剂OP-10和25kg的乳化剂Span-80，搅拌30分钟，温度控制在85℃加入110kg的二壬基萘磺酸钡、20kg的环烷酸锌、30kg的十二烯基丁二酸，继续搅拌，混合均匀后，降温至60℃以下，加入40kg的乙醇，搅拌30分钟即可得到防锈乳化油。
实施例2
本实施例的防锈乳化油的制备方法是将670kg的N10号机械油加入反应釜中，然后加入35kg的硼酸和6kg的氢氧化钠，升温至90℃，保温搅拌30分钟，再加入29kg的三乙醇胺，保温搅拌2小时，待液体透明后加入20kg的乳化剂OP-10和30kg的乳化剂Span-80，搅拌30分钟，温度控制在85℃加入115kg的二壬基萘磺酸钡、25kg的环烷酸锌、25kg的十二烯基丁二酸，继续搅拌，混合均匀后，降温至60℃以下，加入45kg的乙醇，搅拌30分钟即可得到防锈乳化油。
实施例3
本实施例的防锈乳化油的制备方法是将690kg的N10号机械油加入反应釜中，然后加入41kg的硼酸和4kg的氢氧化钠，升温至90℃，保温搅拌30分钟，再加入25kg的三乙醇胺，保温搅拌2小时，待液体透明后加入25kg的乳化剂OP-10和25kg的乳化剂Span-80，搅拌30分钟，温度控制在85℃加入105kg的二壬基萘磺酸钡、15kg的环烷酸锌、35kg的十二烯基丁二酸，继续搅拌，混合均匀后，降温至60℃以下，加入35kg的乙醇，搅拌30分钟即可得到防锈乳化油。
实施例1至3的防锈乳化油检测主要的技术指标，如表1所示。
表1 防锈乳化油技术指标数据表
从表1中可以看出，本发明的防锈乳化油pH稳定在8.8左右，腐蚀试验符合标准，乳液安定性和消泡性优异。防锈性突出，标准要求叠片8小时，单片48小时。
本发明所用化学试剂均为外购，浓度为化学纯。
显然，上述实施例仅仅是为清楚地说明本发明所作的举例，而并非是对本发明的实施方式的限定。对于所属领域的普通技术人员来说，在上述说明的基础上还可以做出其它不同形式的变化或变动。这里无需也无法对所有的实施方式予以穷举。而这些属于本发明的精神所引伸出的显而易见的变化或变动仍处于本发明的保护范围之中。

Claims (10)

1.一种防锈乳化油，其特征在于,包括以下质量百分比的组分：基础油60%～75%，硼酸3%～5%，氢氧化钠0.3%～0.8%，三乙醇胺1%～4%，乳化剂4%～6%，二壬基萘磺酸钡8%～15%，环烷酸锌1%～3%，十二烯基丁二酸1%～5%，乙醇3%～5%。
2.根据权利要求1所述的防锈乳化油，其特征在于：所述三乙醇胺的用量是2.5%～3.5%。
3.根据权利要求1所述的防锈乳化油，其特征在于：所述十二烯基丁二酸的用量是2%～4%。
4.根据权利要求1所述的防锈乳化油，其特征在于：所述二壬基萘磺酸钡的用量是10%～12%。
5.根据权利要求1所述的防锈乳化油，其特征在于：所述基础油的用量是66%～69%。
6.根据权利要求5所述的防锈乳化油，其特征在于：所述基础油是N10号机械油。
7.根据权利要求1至6中任一项所述的防锈乳化油，其特征在于：所述乳化剂是非离子表面活性剂。
8.根据权利要求7所述的防锈乳化油，其特征在于：所述非离子表面活性剂是OP-10和Span-80中的一种或两种。
9.根据权利要求8所述的防锈乳化油，其特征在于：所述非离子表面活性剂是OP-10和Span-80，且OP-10和Span-80的用量质量比为1:1～1.5。
10.一种如权利要求1所述的防锈乳化油的制备方法，其特征在于：将基础油加入反应釜中，然后加入硼酸和氢氧化钠，升温至90℃～95℃，保温搅拌20分钟～30分钟，再加入三乙醇胺，保温搅拌2小时～3小时，待液体透明后加入乳化剂，搅拌20分钟～30分钟，温度控制在80℃～85℃加入二壬基萘磺酸钡、环烷酸锌、十二烯基丁二酸，继续搅拌，混合均匀后，降温至60℃以下，加入乙醇，搅拌20分钟～30分钟即可得到成品。
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108441279A (zh) * 2018-04-11 2018-08-24 江苏捷达油品有限公司 一种双组分的高润滑性防锈乳化油及其制备方法和应用
CN111269744A (zh) * 2020-02-18 2020-06-12 山东技师学院 一种防水防潮铝轧机专用乳化油及其制备方法
CN112481009A (zh) * 2020-11-11 2021-03-12 河南平高电气股份有限公司 一种铜铝铁材加工用微乳化切削液及其制备方法

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102041150A (zh) * 2011-01-14 2011-05-04 上海锦海特种润滑油厂 防锈乳化油及其制备方法
CN102206531A (zh) * 2010-03-31 2011-10-05 比亚迪股份有限公司 一种防锈油及其制备方法
CN104164283A (zh) * 2014-08-19 2014-11-26 清华大学 微乳金属切削液
CN105154201A (zh) * 2015-09-14 2015-12-16 宁波市蓝润能源科技有限公司 一种半合成乳化切削液、及其稀释液的生产工艺
CN105733785A (zh) * 2016-04-19 2016-07-06 天津市金海利油脂有限公司 一种含硼酸酯的带钢冷轧乳化油及其制备方法

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102206531A (zh) * 2010-03-31 2011-10-05 比亚迪股份有限公司 一种防锈油及其制备方法
CN102041150A (zh) * 2011-01-14 2011-05-04 上海锦海特种润滑油厂 防锈乳化油及其制备方法
CN104164283A (zh) * 2014-08-19 2014-11-26 清华大学 微乳金属切削液
CN105154201A (zh) * 2015-09-14 2015-12-16 宁波市蓝润能源科技有限公司 一种半合成乳化切削液、及其稀释液的生产工艺
CN105733785A (zh) * 2016-04-19 2016-07-06 天津市金海利油脂有限公司 一种含硼酸酯的带钢冷轧乳化油及其制备方法

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
谢明师等: "《机械制造工艺材料技术手册 中》", 31 December 1993, 机械工业出版社 *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108441279A (zh) * 2018-04-11 2018-08-24 江苏捷达油品有限公司 一种双组分的高润滑性防锈乳化油及其制备方法和应用
CN108441279B (zh) * 2018-04-11 2020-11-17 江苏捷达油品有限公司 一种双组分的高润滑性防锈乳化油及其制备方法和应用
CN111269744A (zh) * 2020-02-18 2020-06-12 山东技师学院 一种防水防潮铝轧机专用乳化油及其制备方法
CN112481009A (zh) * 2020-11-11 2021-03-12 河南平高电气股份有限公司 一种铜铝铁材加工用微乳化切削液及其制备方法

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