CN107415024B - A kind of preparation process of white pottery ceramic handiwork - Google Patents
A kind of preparation process of white pottery ceramic handiwork Download PDFInfo
- Publication number
- CN107415024B CN107415024B CN201710654548.1A CN201710654548A CN107415024B CN 107415024 B CN107415024 B CN 107415024B CN 201710654548 A CN201710654548 A CN 201710654548A CN 107415024 B CN107415024 B CN 107415024B
- Authority
- CN
- China
- Prior art keywords
- mud
- weight
- parts
- pottery
- glaze
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B1/00—Producing shaped prefabricated articles from the material
- B28B1/02—Producing shaped prefabricated articles from the material by turning or jiggering in moulds or moulding surfaces on rotatable supports
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B11/00—Apparatus or processes for treating or working the shaped or preshaped articles
- B28B11/04—Apparatus or processes for treating or working the shaped or preshaped articles for coating or applying engobing layers
- B28B11/044—Apparatus or processes for treating or working the shaped or preshaped articles for coating or applying engobing layers with glaze or engobe or enamel or varnish
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B11/00—Apparatus or processes for treating or working the shaped or preshaped articles
- B28B11/08—Apparatus or processes for treating or working the shaped or preshaped articles for reshaping the surface, e.g. smoothing, roughening, corrugating, making screw-threads
- B28B11/0818—Apparatus or processes for treating or working the shaped or preshaped articles for reshaping the surface, e.g. smoothing, roughening, corrugating, making screw-threads for roughening, profiling, corrugating
- B28B11/0827—Apparatus or processes for treating or working the shaped or preshaped articles for reshaping the surface, e.g. smoothing, roughening, corrugating, making screw-threads for roughening, profiling, corrugating for corrugating, profiling or the like of plates such as asbestos cement sheets
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B11/00—Apparatus or processes for treating or working the shaped or preshaped articles
- B28B11/08—Apparatus or processes for treating or working the shaped or preshaped articles for reshaping the surface, e.g. smoothing, roughening, corrugating, making screw-threads
- B28B11/0818—Apparatus or processes for treating or working the shaped or preshaped articles for reshaping the surface, e.g. smoothing, roughening, corrugating, making screw-threads for roughening, profiling, corrugating
- B28B11/0836—Apparatus or processes for treating or working the shaped or preshaped articles for reshaping the surface, e.g. smoothing, roughening, corrugating, making screw-threads for roughening, profiling, corrugating for pottery articles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B28—WORKING CEMENT, CLAY, OR STONE
- B28B—SHAPING CLAY OR OTHER CERAMIC COMPOSITIONS; SHAPING SLAG; SHAPING MIXTURES CONTAINING CEMENTITIOUS MATERIAL, e.g. PLASTER
- B28B11/00—Apparatus or processes for treating or working the shaped or preshaped articles
- B28B11/24—Apparatus or processes for treating or working the shaped or preshaped articles for curing, setting or hardening
- B28B11/243—Setting, e.g. drying, dehydrating or firing ceramic articles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44C—PRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
- B44C1/00—Processes, not specifically provided for elsewhere, for producing decorative surface effects
- B44C1/24—Pressing or stamping ornamental designs on surfaces
Landscapes
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Mechanical Engineering (AREA)
- Structural Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Road Signs Or Road Markings (AREA)
- Finishing Walls (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention relates to a kind of preparation process of white pottery ceramic handiwork, the production of white pottery ceramic handiwork includes the following steps: S1 pottery mud process: mud raw material processed being removed impurity, is uniformly mixed so as to obtain pottery mud, pottery mud is divided, pillared pile mud is piled up；S2 throwing process: the pile mud in S1 is put into traffic cycle, and porcelain mud is pulled into porcelain billet with hand and throwing tool by rotary turnplate；S3 copper sheet process: the white film and copper-nickel alloy plate are made according to layout design；S4 pulls out print process: black is added in pulling out print magma and pulls out print powder, is uniformly mixed to get black and pulls out red ink paste used for seals material, pull out to printing area according to layout design stamping color；S5 biscuiting process: by 3~5h of green compact biscuiting；S6 is fired by glaze process: will carry out 1~1.5h of glaze firing after green body glazing obtained in S5 biscuiting process.The present invention has the advantages that pure color, high mechanical strength, shock resistance are good.
Description
Technical field
The present invention relates to ceramic technology fields, and in particular to a kind of preparation process of white pottery ceramic handiwork.
Background technique
Ceramics are the general names of pottery and porcelain.Chinese just send out early in about B.C. 8000-2000 (Neolithic Age)
Pottery is illustrated.Ceramic material is oxide, nitride, boride and carbide etc. mostly.Common ceramic material has clay, oxygen
Change aluminium, kaolin etc..Primary raw material for it is the silicate mineral for taking from nature, thus with glass, cement, ward off
The industry such as porcelain, refractory material belong to the scope of " silicate industry ".The general hardness of ceramic material is higher, but plasticity is poor.
In addition to also being played an important role in the use of feeder, decoration in scientific, technology development.Ceramic raw material is that the earth is original
Vast resources clay take by quenching.And the property of clay has toughness, room temperature chance water is plastic, and micro- do can carve, absolutely dry to grind；
Water can be filled at pottery by burning to 700 DEG C；It burns to 1230 DEG C of then porcelain, can not absorb water completely and corrosion-and high-temp-resistant.Its usage it
Elasticity still has the application of various intention in culture today science and technology.Modern humans life in, all kinds of craftworks increasingly by
The welcome of people, especially ceramics, exquisite in workmanship, remarkably true to life, elegant style.
China's white glaze porcelain is sprouted in the Northern and Southern Dynasties, has been arrived the Sui Dynasty, has been had evolved to the stage of ripeness.More there is new hair to the Tang Dynasty
Exhibition.Porcelain firing temperature reaches 1200 DEG C, and the whiteness of porcelain has also reached 70% or more, close to the standard of modern times senior fine porcelain.This
One development for becoming underglaze colour and overglaze color porcelain lays the foundation.Ceramic whiteware is the low porcelain billet of iron-content, is imposed pure transparent
Glaze is fired.
Ceramic technique is superior, has good reputation in existing pottery area.In existing ceramic process,
Although ceramics exquisite appearance, ornamental value is high, and color purity and shock resistance are poor.
Summary of the invention
It is an object of the invention to overcome the deficiencies of the prior art and provide a kind of preparation process of white pottery ceramic handiwork, solutions
It has determined the process difficulties of white pottery porcelain and the problem of pottery shock resistance difference.
The purpose of the present invention is achieved through the following technical solutions:
A kind of preparation process of white pottery ceramic handiwork, includes the following steps:
S1 pottery mud process: removing impurity for mud raw material processed, be uniformly mixed so as to obtain pottery mud, and pottery mud is divided into different size of mud
Group, piles up pillared pile mud for walk.Kaolin is the optimum feed stock of fire porcelain, and kaolin is a kind of nonmetallic minerals, is
A kind of clay and clay rock based on kaolinite race clay mineral, because white and fine and smooth, also known as white clouds soil, matter are pure
Kaolin has the physicochemical properties such as good plasticity and fire resistance in pure white fine and smooth, soft earthy.First of work of porcelain making
Sequence: mud is washed in a pan, china clay is exactly washed in a pan into available porcelain mud.The porcelain mud washed in a pan can not use immediately, be separated ceramic skill
Art product come, and pile is used in order to store with throwing at column.
S2 throwing process: the pile mud in S1 is put into traffic cycle, by rotary turnplate, with hand and throwing tool, by porcelain
Mud pulls into porcelain billet；Throwing is the blank production of molding initial period and implements.It is that the pug that will be prepared is placed on base vehicle
On, the blank with certain shapes and size is made with forming method processed is taken turns.
S3 copper sheet process: the white film and copper-nickel alloy plate are made according to layout design；Corresponding lines is made on ceramic body,
It needs very finely, to avoid the aesthetic feeling of error due ceramics during lines production.
S4 pulls out print process: black is added in pulling out print magma and pulls out print powder, is uniformly mixed to get black and pulls out red ink paste used for seals material, according to figure
Paper design pull out to printing area stamping color.Different floral designs enhancing aesthetic feelings is designed on the idiosome of white pottery porcelain, is being painted
The pH value adjustment of red ink paste used for seals material will be pulled out during stamp to 2~3.
S5 biscuiting process: by green compact at 1300~1400 DEG C 3~5h of biscuiting.Biscuiting refers to the green compact of non-glazing through certain
Temperature heat treatment, makes green body have the process of certain mechanical strength.The temperature was then adjusted to when 1300~1400 DEG C of progress biscuitings, temperature
It is small to spend range, is not necessarily to constantly regulate temperature and power during biscuiting.
S6 be fired by glaze process: will be carried out after green body glazing obtained in S5 biscuiting process at 1000~1050 DEG C glaze firing 1~
1.5h.White pottery porcelain glazing is clear frit；Also known as glazing, rest, cover glaze.Refer to and imposes glaze slip on molding ceramic body surface.
Its method dips in glaze, swings that glaze, to pour glaze, brushing glazing, glazing by sufflation, glaze spraying, wheel glaze etc. a variety of.By the different shape of green body, thickness, using phase
The enameling method answered.Glazing process is one kind of antique pottery porcelain Manufacturing Techniques, refers to and applies on molding ceramic body surface
With glaze slip.Mainly dip in glaze, swing glaze, pour glaze, brushing glazing, spill glaze, wheel seven kinds of methods such as glaze are adopted by the different shape of green body, thickness
With corresponding enameling method.It dips in glaze and is called " leaching glaze ", be most basic one of enameling method.Green body is immersed in glaze slip in a moment
It takes out, using the water imbibition of green body, glaze slip is made equably to be attached to billet surface.Water absorption rate, glaze slip of the glazed thickness by green body
Concentration and immersion time determine.The former porcelain of Ming and Qing is mostly used this method and adds glaze, and often less than foot, glaze is arranged the glaze juice on implements at top
And tire is revealed in lower part.It swings glaze and " swings interior glaze ", inside glaze slip injection green body, green body is applied up and down then and is swung, glaze slip cloth is made
Full green body, then extra glaze slip is poured out, subsequent green body continues to turn round, and device mouth is made not stay residual glaze.Glaze is once swung, also there is two
Secondary, but cannot be more after twice, otherwise it is easy to produce bubble.Glaze method is swung suitable for small and abdomen depth product.After glazing again with compared with
Low temperature is fired by glaze.The temperature of glaze firing controls in 1000~1050 DEG C, and temperature fluctuation is small during glaze firing, in this way
It is bright and clean to be fired by glaze obtained whiteware handicraft surface.
Further, the composition parts by weight of mud raw material processed are in the S1 step are as follows:
64~66 parts by weight of lithium porcelain stone；
34~36 parts by weight of kaolin；
15~20 parts by weight of polymethyl methacrylate.
Kaolinic crystal-chemical formula is 2SiO2Al2O32H2O, theoretical chemistry group become 46.54% SiO2,
39.5% Al2O3, 13.96% H2O.Kaolin families mineral belong to 1:1 type phyllosilicate, and crystal is mainly by silicon oxygen four sides
Body and the hydrogen-oxygen octahedron composition that continues, wherein oxygen-octahedron links to form six sides row along two-dimensional directional in a manner of sharing apex angle
The clathrum of column, the not common pinnacle oxygen of each oxygen-octahedron is towards one side；By oxygen-octahedron layer and recruit oxygen octahedra
The pinnacle oxygen of the public oxygen-octahedron layer of layer constitutes the Institutional Layer of 1:1 type.How matt kaolin is, face white exquisiteness when matter is pure,
It can be with ash, Huang, brown color when such as impure.Appearance can be in loose soil block shape and densifie state sillar shape according to origin cause of formation difference.
Density: 2.54~2.60g/S3m3.Fusing point: about 1785 DEG C.Kaolin have plasticity, wet soil can be moulded into various shape and will not
It is broken, and can remain unchanged for a long time.Therefore, kaolin is the optimum feed stock of fire porcelain.
Lithium porcelain stone quality is pure, and whiteness is good, Li2O,K2O,Na2The alkalides content such as O is higher, and containing suitable
P2O5And S6, other compositions are reasonable.Therefore its preferable fluxing capabilities and opacifying power are imparted.
Polymethyl methacrylate is called PMMA or polymethyl methacrylate, is originated from English S1S3ryliS3 (acrylic plastics).Chemistry
Entitled polymethyl methacrylate is a kind of exploitation important plastic macromolecule material earlier, have the preferable transparency,
Chemical stability and weatherability, easy dyeing, easy processing, attractive appearance, with the transparency as crystal, light transmittance 92% with
On, light is soft, optical clarity, has good color development effect again with the acrylic that dyestuff colours.Acrylic board has splendid
Weatherability, higher surface hardness and lustrous surface and preferable high-temperature behavior.Acrylic board has good processing performance,
Both thermoforming can be used, the mode that can also be machined into.Transparent acrylic material has the light transmittance that can be compared with glass,
But density only has the half of glass.In addition, it is so frangible unlike glass, even if destroying, cutting edge of a knife or a sword will not be formed as glass
The fragment of benefit.The wearability of acrylic board is close in aluminium, and stability is good, the corrosion of resistant to many chemicals.Acrylic board has good
Good printability and sprayability can assign acrylic product ideal incrustation using printing appropriate and spraying process
Effect.
Further, the particle size range of the polymethyl methacrylate is 30~100 μm.Methyl methacrylate is equal
It is even to be blended in lithium porcelain stone and kaolin, water is added and is mixed to form pottery mud later, the granularity control of polymethyl methacrylate exists
The pottery mud formed when in 30~100 μ ms can't generate apparent harsh feeling, can also be uniformly mixed, and avoid corase meal band
The harsh feeling come makes idiosome making link generate the meticulous bring mixture homogeneity deficiency of excessive defect ware and powder,
Cause the problem of the degree uniform in material difference of ceramics.
Further, the pottery mud is by lithium porcelain stone, kaolin and the polymethyl methacrylate of each parts by weight and distillation
Water is formed according to the weight ratio of 1:2~3.The composition parts by weight of mud raw material processed in above-mentioned S1 step are prepared after completing, will be made
Mud raw material and distilled water are mixed to get pottery mud, the pottery mud feel refinement being mixed to get uniformly, will not overdrying easily there is slight crack or mistake
Wet not easily molded, using distilled water, reducing foreign ion influences the color uniformity of ceramics.
Further, in the S3 step black pull out red ink paste used for seals material the preparation method comprises the following steps:
The preparation of A raw material:
5~8 parts by weight of iron chloride；
3~5 parts by weight of cerous sulfate；
6~9 parts by weight of copper sulphate；
Wherein iron chloride is yellow metal salt, and cerous sulfate is red metal salt, and copper sulphate is blue metal salt.It was mixing colours
These three color mixing are modulated in journey to obtain black pigment, wherein the coloring effect of cerous sulfate is good, and usage amount is lower than iron chloride
And copper sulphate.
The preparation of B colorant: iron chloride, cerous sulfate and the copper sulphate of above-mentioned each parts by weight are placed in the container of a upper opening
It is interior, it is previously added 100mL distilled water in container, slowly injects the sulfuric acid solution of the 0.1mol/L of 1~10mL.The three kinds of face selected
Chromogen material is strong acid salt, therefore strong acid is selected to adjust the pH value that black pulls out print pigment.
Further, it is 2~3 that the black, which pulls out the PH of red ink paste used for seals material,.Strict control PH is needed when preparing black and pulling out red ink paste used for seals material
Value, is strict controlled in 2~3 for pH value, and the stamp printed at this time is more completely without dizzy dye, the phenomenon that being not in dizzy dye,
By the pH value of control black printing and dyeing colorant, ceramics is reduced in the defect ware of dyeing process.
Further, the temperature of biscuiting is 1300~1400 DEG C in the S5 step.The temperature of biscuiting in sintering procedure
Control is in lesser fluctuation range, and the stress variation in sintering procedure is small, the ceramics mechanical strength fired
It is higher.
Further, the temperature being fired by glaze in the S6 step is 1000~1050 DEG C.The temperature being fired by glaze in sintering procedure
Control is in lesser fluctuation range, and the stress variation in sintering procedure is small, the ceramics mechanical strength fired
It is higher.
The beneficial effects of the present invention are:
1.. pottery mud is prepared using kaolin mixing lithium porcelain stone and polymethyl methacrylate, the addition portion in pottery mud
Divide polymethyl methacrylate, polymethyl methacrylate has good transparency and impact strength, and is also in high temperature
Under the conditions of shape, addition polymethyl methacrylate significantly improves the hardness of ceramics, modulus of elasticity in comperssion and anti-
Impact strength, so that the mechanical property of ceramics is more excellent；The pottery mud that three is mixed in a certain ratio is fired to obtain
Ceramics it is purer in coloration, have certain translucent both visual senses；
2. methyl methacrylate is evenly mixed in lithium porcelain stone and kaolin, water is added and is mixed to form pottery mud later,
The pottery mud that the granularity of polymethyl methacrylate is formed when controlling in 30~100 μ ms can't generate apparent coarse
Sense, can also be uniformly mixed, avoid corase meal bring harsh feeling that idiosome making link is made to generate excessive defect ware, and
The meticulous bring mixture homogeneity of powder is insufficient, causes the problem of the degree uniform in material difference of ceramics；
3. mud raw material processed and distilled water are mixed to get pottery mud, the pottery mud feel refinement being mixed to get uniformly, will not overdrying
Easily there is slight crack or overly moist not easily molded, using distilled water, reducing foreign ion influences the color uniformity of ceramics；
4. iron chloride is yellow metal salt, cerous sulfate is red metal salt, and copper sulphate is blue metal salt, in toning process
Middle to modulate these three color mixing to obtain black pigment, wherein the coloring effect of cerous sulfate is good, usage amount lower than iron chloride and
Three kinds of color stocks of copper sulphate, selection are strong acid salt, select strong acid to adjust the pH value that black pulls out print pigment, are preparing black
Need strict control pH value when pulling out red ink paste used for seals material, pH value be strict controlled in 2~3, the stamp printed at this time more completely without dizzy dye,
The phenomenon that being not in dizzy dye, reduces ceramics in dyeing process by the pH value of control black printing and dyeing colorant
Defect ware；
5. the price of lithium porcelain stone, kaolin and polymethyl methacrylate is more cheap, at low cost, component proportion is simple,
For the control of the temperature of biscuiting and glaze firing in lesser fluctuation range, the stress variation in sintering procedure is small in sintering procedure,
It is higher to fire obtained ceramics mechanical strength；
Specific embodiment
Technical solution of the present invention is described in further detail combined with specific embodiments below, but protection scope of the present invention is not
It is confined to as described below.
Embodiment 1
A kind of preparation process of white pottery ceramic handiwork, includes the following steps:
S1 pottery mud process: removing impurity for kaolin and lithium porcelain stone, be uniformly mixed so as to obtain pottery mud, and pottery mud is separated ceramic art
Product come, and pile up pillared pile mud；
S2 throwing process: the pile mud in S1 is put into traffic cycle, by rotary turnplate, with hand and throwing tool, by porcelain
Mud pulls into porcelain billet；
S3 copper sheet process: the white film and copper-nickel alloy plate are made according to layout design；
S4 pulls out print process: black is added in pulling out print magma and pulls out print powder, is uniformly mixed to get black and pulls out red ink paste used for seals material, according to figure
Paper design, which pull out to printing area, stamps color, and it is 2 that black, which pulls out red ink paste used for seals material PH,；
S5 biscuiting process: by green compact at 1300 DEG C biscuiting 5h；
S6 is fired by glaze process: will carry out glaze firing 1.5h at 1000 DEG C after green body glazing obtained in S5 biscuiting process.
Specifically, the parts by weight of the kaolin and lithium porcelain stone are as follows:
66 parts by weight of lithium porcelain stone；
34 parts by weight of kaolin；
15 parts by weight of polymethyl methacrylate
Specifically, the glazing is glazing.
Specifically, the particle size range of the polymethyl methacrylate is 30 μm.
Specifically, the pottery mud is by lithium porcelain stone, kaolin and the polymethyl methacrylate and distilled water of each parts by weight
It is formed according to the weight ratio of 1:2.
Specifically, in the S3 step black pull out red ink paste used for seals material the preparation method comprises the following steps:
The preparation of A raw material:
5 parts by weight of iron chloride；
3 parts by weight of cerous sulfate；
6 parts by weight of copper sulphate；
The preparation of B colorant: iron chloride, cerous sulfate and the copper sulphate of above-mentioned each parts by weight are placed in the container of a upper opening
It is interior, it is previously added 100mL distilled water in container, slowly injects the sulfuric acid solution of the 0.1mol/L of 10mL.
Embodiment 2
A kind of preparation process of white pottery ceramic handiwork, includes the following steps:
S1 pottery mud process: removing impurity for kaolin and lithium porcelain stone, be uniformly mixed so as to obtain pottery mud, and pottery mud is separated ceramic art
Product come, and pile up pillared pile mud；
S2 throwing process: the pile mud in S1 is put into traffic cycle, by rotary turnplate, with hand and throwing tool, by porcelain
Mud pulls into porcelain billet；
S3 copper sheet process: the white film and copper-nickel alloy plate are made according to layout design；
S4 pulls out print process: black is added in pulling out print magma and pulls out print powder, is uniformly mixed to get black and pulls out red ink paste used for seals material, according to figure
Paper design, which pull out to printing area, stamps color, and it is 2.5 that black, which pulls out red ink paste used for seals material PH,；
S5 biscuiting process: by green compact at 1400 DEG C biscuiting 3h；
S6 is fired by glaze process: will carry out glaze firing 1h at 1050 DEG C after green body glazing obtained in S5 biscuiting process.
Specifically, the parts by weight of the kaolin and lithium porcelain stone are as follows:
65 parts by weight of lithium porcelain stone；
35 parts by weight of kaolin；
17 parts by weight of polymethyl methacrylate.
Specifically, the glazing is rest.
Specifically, the particle size range of the polymethyl methacrylate is 80 μm.
Specifically, the pottery mud is by lithium porcelain stone, kaolin and the polymethyl methacrylate and distilled water of each parts by weight
It is formed according to the weight ratio of 1:3.
Specifically, in the S3 step black pull out red ink paste used for seals material the preparation method comprises the following steps:
The preparation of A raw material:
6 parts by weight of iron chloride；
4 parts by weight of cerous sulfate；
7 parts by weight of copper sulphate；
The preparation of B colorant: iron chloride, cerous sulfate and the copper sulphate of above-mentioned each parts by weight are placed in the container of a upper opening
It is interior, it is previously added 100mL distilled water in container, slowly injects the sulfuric acid solution of the 0.1mol/L of 5mL.
Embodiment 3
A kind of preparation process of white pottery ceramic handiwork, includes the following steps:
S1 pottery mud process: removing impurity for kaolin and lithium porcelain stone, be uniformly mixed so as to obtain pottery mud, and pottery mud is separated ceramic art
Product come, and pile up pillared pile mud；
S2 throwing process: the pile mud in S1 is put into traffic cycle, by rotary turnplate, with hand and throwing tool, by porcelain
Mud pulls into porcelain billet；
S3 copper sheet process: the white film and copper-nickel alloy plate are made according to layout design；
S4 pulls out print process: black is added in pulling out print magma and pulls out print powder, is uniformly mixed to get black and pulls out red ink paste used for seals material, according to figure
Paper design, which pull out to printing area, stamps color, and it is 3 that black, which pulls out red ink paste used for seals material PH,；
S5 biscuiting process: by green compact at 1350 DEG C biscuiting 4h；
S6 is fired by glaze process: will carry out glaze firing 1.3h at 1020 DEG C after green body glazing obtained in S5 biscuiting process.
Specifically, the parts by weight of the kaolin and lithium porcelain stone are as follows:
64 parts by weight of lithium porcelain stone；
35 parts by weight of kaolin；
18 parts by weight of polymethyl methacrylate.
Specifically, the glazing is cover glaze.
Specifically, the particle size range of the polymethyl methacrylate is 100 μm.
Specifically, the pottery mud is by lithium porcelain stone, kaolin and the polymethyl methacrylate and distilled water of each parts by weight
It is formed according to the weight ratio of 1:2.
Specifically, in the S3 step black pull out red ink paste used for seals material the preparation method comprises the following steps:
The preparation of A raw material:
8 parts by weight of iron chloride；
5 parts by weight of cerous sulfate；
9 parts by weight of copper sulphate；
The preparation of B colorant: iron chloride, cerous sulfate and the copper sulphate of above-mentioned each parts by weight are placed in the container of a upper opening
It is interior, it is previously added 100mL distilled water in container, slowly injects the sulfuric acid solution of the 0.1mol/L of 1mL.
Embodiment 4
A kind of preparation process of white pottery ceramic handiwork, includes the following steps:
S1 pottery mud process: removing impurity for kaolin and lithium porcelain stone, be uniformly mixed so as to obtain pottery mud, and pottery mud is separated ceramic art
Product come, and pile up pillared pile mud；
S2 throwing process: the pile mud in S1 is put into traffic cycle, by rotary turnplate, with hand and throwing tool, by porcelain
Mud pulls into porcelain billet；
S3 copper sheet process: the white film and copper-nickel alloy plate are made according to layout design；
S4 pulls out print process: black is added in pulling out print magma and pulls out print powder, is uniformly mixed to get black and pulls out red ink paste used for seals material, according to figure
Paper design, which pull out to printing area, stamps color, and it is 2.4 that black, which pulls out red ink paste used for seals material PH,；
S5 biscuiting process: by green compact at 1380 DEG C biscuiting 3.7h；
S6 is fired by glaze process: will carry out glaze firing 1.3h at 1020 DEG C after green body glazing obtained in S5 biscuiting process.
Specifically, the parts by weight of the kaolin and lithium porcelain stone are as follows:
66 parts by weight of lithium porcelain stone；
36 parts by weight of kaolin；
20 parts by weight of polymethyl methacrylate.
Specifically, the glazing is to swing glaze.
Specifically, the particle size range of the polymethyl methacrylate is 80 μm.
Specifically, the pottery mud is by lithium porcelain stone, kaolin and the polymethyl methacrylate and distilled water of each parts by weight
It is formed according to the weight ratio of 1:3.
Specifically, in the S3 step black pull out red ink paste used for seals material the preparation method comprises the following steps:
The preparation of A raw material:
8 parts by weight of iron chloride；
5 parts by weight of cerous sulfate；
9 parts by weight of copper sulphate；
The preparation of B colorant: iron chloride, cerous sulfate and the copper sulphate of above-mentioned each parts by weight are placed in the container of a upper opening
It is interior, it is previously added 100mL distilled water in container, slowly injects the sulfuric acid solution of the 0.1mol/L of 6mL.
Embodiment 5
A kind of preparation process of white pottery ceramic handiwork, includes the following steps:
S1 pottery mud process: removing impurity for kaolin and lithium porcelain stone, be uniformly mixed so as to obtain pottery mud, and pottery mud is separated ceramic art
Product come, and pile up pillared pile mud；
S2 throwing process: the pile mud in S1 is put into traffic cycle, by rotary turnplate, with hand and throwing tool, by porcelain
Mud pulls into porcelain billet；
S3 copper sheet process: the white film and copper-nickel alloy plate are made according to layout design；
S4 pulls out print process: black is added in pulling out print magma and pulls out print powder, is uniformly mixed to get black and pulls out red ink paste used for seals material, according to figure
Paper design, which pull out to printing area, stamps color, and it is 4 that black, which pulls out red ink paste used for seals material PH,；
S5 biscuiting process: by green compact at 1380 DEG C biscuiting 3.7h；
S6 is fired by glaze process: will carry out glaze firing 1.3h at 1020 DEG C after green body glazing obtained in S5 biscuiting process.
Specifically, the parts by weight of the kaolin and lithium porcelain stone are as follows:
66 parts by weight of lithium porcelain stone；
36 parts by weight of kaolin；
20 parts by weight of polymethyl methacrylate.
Specifically, the glazing is to swing glaze.
Specifically, the particle size range of the polymethyl methacrylate is 80 μm.
Specifically, the pottery mud is by lithium porcelain stone, kaolin and the polymethyl methacrylate and distilled water of each parts by weight
It is formed according to the weight ratio of 1:3.
Specifically, in the S3 step black pull out red ink paste used for seals material the preparation method comprises the following steps:
The preparation of A raw material:
8 parts by weight of iron chloride；
5 parts by weight of cerous sulfate；
9 parts by weight of copper sulphate；
The preparation of B colorant: iron chloride, cerous sulfate and the copper sulphate of above-mentioned each parts by weight are placed in the container of a upper opening
It is interior, it is previously added 100mL distilled water in container, slowly injects the sulfuric acid solution of the 0.1mol/L of 6mL.
Embodiment 6
A kind of preparation process of white pottery ceramic handiwork, includes the following steps:
S1 pottery mud process: removing impurity for kaolin and lithium porcelain stone, be uniformly mixed so as to obtain pottery mud, and pottery mud is separated ceramic art
Product come, and pile up pillared pile mud；
S2 throwing process: the pile mud in S1 is put into traffic cycle, by rotary turnplate, with hand and throwing tool, by porcelain
Mud pulls into porcelain billet；
S3 copper sheet process: the white film and copper-nickel alloy plate are made according to layout design；
S4 pulls out print process: black is added in pulling out print magma and pulls out print powder, is uniformly mixed to get black and pulls out red ink paste used for seals material, according to figure
Paper design, which pull out to printing area, stamps color, and it is 3 that black, which pulls out red ink paste used for seals material PH,；
S5 biscuiting process: by green compact at 1380 DEG C biscuiting 3.7h；
S6 is fired by glaze process: will carry out glaze firing 1.3h at 1020 DEG C after green body glazing obtained in S5 biscuiting process.
Specifically, the parts by weight of the kaolin and lithium porcelain stone are as follows:
66 parts by weight of lithium porcelain stone；
36 parts by weight of kaolin.
Specifically, the glazing is to swing glaze.
Specifically, the particle size range of the polymethyl methacrylate is 80 μm.
Specifically, the pottery mud is by lithium porcelain stone, kaolin and the polymethyl methacrylate and distilled water of each parts by weight
It is formed according to the weight ratio of 1:3.
Specifically, in the S3 step black pull out red ink paste used for seals material the preparation method comprises the following steps:
The preparation of A raw material:
8 parts by weight of iron chloride；
5 parts by weight of cerous sulfate；
9 parts by weight of copper sulphate；
The preparation of B colorant: iron chloride, cerous sulfate and the copper sulphate of above-mentioned each parts by weight are placed in the container of a upper opening
It is interior, it is previously added 100mL distilled water in container, slowly injects the sulfuric acid solution of the 0.1mol/L of 6mL.
1~embodiment of embodiment 6 is subjected to following performance test, tests the coloration, density, hole of six kinds of ceramic materials
Rate, to acid, alkali, the corrosion stability of salt and hardness, elasticity modulus and impact strength, the results are shown in Table 1:
1 1~embodiment of embodiment of table, 6 performance test data table
From the data in table 1, it can be concluded that, the performance of material is similar in 1~embodiment of embodiment 4, has good color
Pool uniform translucence is functional to acid, alkali, salt；The PH of black printing and dyeing colorant is controlled between 2~3, and
The phenomenon that being not in dizzy dye, reduces ceramics in the residual of dyeing process by the pH value of control black printing and dyeing colorant
There is the phenomenon that part dizzy dye when pH value control is 4 in embodiment 5, cause craftwork unqualified in substandard products；It is added in pottery mud
Part polymethyl methacrylate, polymethyl methacrylate have good transparency and impact strength, and are also in height
Shaped under the conditions of temperature, addition polymethyl methacrylate significantly improve the hardness of ceramics, modulus of elasticity in comperssion and
Impact strength, so that the mechanical property of ceramics is more excellent.
The above is only a preferred embodiment of the present invention, it should be understood that the present invention is not limited to described herein
Form should not be regarded as an exclusion of other examples, and can be used for other combinations, modifications, and environments, and can be at this
In the text contemplated scope, modifications can be made through the above teachings or related fields of technology or knowledge.And those skilled in the art institute into
Capable modifications and changes do not depart from the spirit and scope of the present invention, then all should be in the protection scope of appended claims of the present invention
It is interior.
Claims (7)
1. a kind of preparation process of white pottery ceramic handiwork, which comprises the steps of:
S1 pottery mud process: removing impurity for mud raw material processed, be uniformly mixed so as to obtain pottery mud, and pottery mud is divided, pillared pile mud is piled up；
S2 throwing process: the pile mud in S1 is put into traffic cycle, is drawn porcelain mud with hand and throwing tool by rotary turnplate
At porcelain billet；
S3 copper sheet process: the white film and copper-nickel alloy plate are made according to layout design；
S4 pulls out print process: black is added in pulling out print magma and pulls out print powder, is uniformly mixed to get black and pulls out red ink paste used for seals material, set according to drawing
Meter pull out to printing area stamping color；
S5 biscuiting process: by 3~5h of green compact biscuiting；
S6 is fired by glaze process: will carry out 1~1.5h of glaze firing after green body glazing obtained in S5 biscuiting process；
Mud raw material processed is made of the following raw material in the S1 step:
64 ~ 66 parts by weight of lithium porcelain stone；
34 ~ 36 parts by weight of kaolin；
15 ~ 20 parts by weight of polymethyl methacrylate.
2. a kind of preparation process of white pottery ceramic handiwork according to claim 1, which is characterized in that the polymethyl
The particle size range of sour methyl esters is 30 ~ 100 μm.
3. a kind of preparation process of white pottery ceramic handiwork according to claim 1, which is characterized in that the pottery mud will be by that will make
Mud raw material is uniformly mixed to obtain with distilled water according to the weight ratio of 1:2 ~ 3.
4. a kind of preparation process of white pottery ceramic handiwork according to claim 1, which is characterized in that black in the S3 step
Color pull out red ink paste used for seals material the preparation method comprises the following steps:
A in parts by weight, prepares the following raw material:
5 ~ 8 parts by weight of iron chloride；
3 ~ 5 parts by weight of cerous sulfate；
6 ~ 9 parts by weight of copper sulphate；
The preparation of B colorant: iron chloride, cerous sulfate and the copper sulphate of above-mentioned each parts by weight are placed in the container of a upper opening,
It is previously added 100mL distilled water in container, slowly injects the sulfuric acid solution of the 0.1mol/L of 1 ~ 10mL.
5. a kind of preparation process of white pottery ceramic handiwork according to claim 1, which is characterized in that the black pulls out red ink paste used for seals
The PH of material is 2 ~ 3.
6. a kind of preparation process of white pottery ceramic handiwork according to claim 1, which is characterized in that plain in the S5 step
The temperature of burning is 1300~1400 DEG C.
7. a kind of preparation process of white pottery ceramic handiwork according to claim 1, which is characterized in that glaze in the S6 step
The temperature of burning is 1000~1050 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710654548.1A CN107415024B (en) | 2017-08-03 | 2017-08-03 | A kind of preparation process of white pottery ceramic handiwork |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710654548.1A CN107415024B (en) | 2017-08-03 | 2017-08-03 | A kind of preparation process of white pottery ceramic handiwork |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN107415024A CN107415024A (en) | 2017-12-01 |
| CN107415024B true CN107415024B (en) | 2019-07-26 |
Family
ID=60437284
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710654548.1A Active CN107415024B (en) | 2017-08-03 | 2017-08-03 | A kind of preparation process of white pottery ceramic handiwork |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107415024B (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113087506B (en) * | 2021-03-02 | 2022-08-05 | 福建省春秋陶瓷实业有限公司 | Ceramic artwork and preparation method thereof |
| CN113321534A (en) * | 2021-05-27 | 2021-08-31 | 湖南银和瓷业有限公司 | Glazing method and device for ceramic special-shaped product |
| CN115042296B (en) * | 2022-06-21 | 2023-12-05 | 白怀宾 | Ceramic large statue forming process |
Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1290672A (en) * | 1999-10-05 | 2001-04-11 | 罗姆和哈斯公司 | Method for preparing ceramic composition |
| CN1962535A (en) * | 2005-11-07 | 2007-05-16 | 上海斯米克陶瓷有限公司 | Super white ceramic tile |
| CN101386520A (en) * | 2008-10-31 | 2009-03-18 | 景德镇哈哈尼陶瓷文化发展有限公司 | Colorful ceramic and preparation method thereof |
| CN101828786A (en) * | 2010-05-20 | 2010-09-15 | 郑菁菁 | Production method of simulation plaque |
| CN102249654A (en) * | 2011-04-29 | 2011-11-23 | 广西南山瓷器有限公司 | Ancient blue and white porcelain and production method thereof |
| CN102260095A (en) * | 2011-05-18 | 2011-11-30 | 山东省安华瓷业有限公司 | Low temperature yellow glaze firing process |
| CN102617187A (en) * | 2012-03-16 | 2012-08-01 | 湖南港鹏实业有限公司 | Process for producing black pigment ceramic at high temperature |
| CN104788079A (en) * | 2015-04-15 | 2015-07-22 | 江苏省宜兴彩陶工艺厂 | Slip casting preparation method for high-whiteness earthenware |
-
2017
- 2017-08-03 CN CN201710654548.1A patent/CN107415024B/en active Active
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1290672A (en) * | 1999-10-05 | 2001-04-11 | 罗姆和哈斯公司 | Method for preparing ceramic composition |
| CN1962535A (en) * | 2005-11-07 | 2007-05-16 | 上海斯米克陶瓷有限公司 | Super white ceramic tile |
| CN101386520A (en) * | 2008-10-31 | 2009-03-18 | 景德镇哈哈尼陶瓷文化发展有限公司 | Colorful ceramic and preparation method thereof |
| CN101828786A (en) * | 2010-05-20 | 2010-09-15 | 郑菁菁 | Production method of simulation plaque |
| CN102249654A (en) * | 2011-04-29 | 2011-11-23 | 广西南山瓷器有限公司 | Ancient blue and white porcelain and production method thereof |
| CN102260095A (en) * | 2011-05-18 | 2011-11-30 | 山东省安华瓷业有限公司 | Low temperature yellow glaze firing process |
| CN102617187A (en) * | 2012-03-16 | 2012-08-01 | 湖南港鹏实业有限公司 | Process for producing black pigment ceramic at high temperature |
| CN104788079A (en) * | 2015-04-15 | 2015-07-22 | 江苏省宜兴彩陶工艺厂 | Slip casting preparation method for high-whiteness earthenware |
Also Published As
| Publication number | Publication date |
|---|---|
| CN107415024A (en) | 2017-12-01 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107415024B (en) | A kind of preparation process of white pottery ceramic handiwork | |
| CN108546081B (en) | Firing method of porcelain body painting enamel | |
| CN104177064B (en) | China's celadon iron tire is without the composition of the manufacture technique of sheet line kuan yao procelain and tire, glaze | |
| CN105601127B (en) | A kind of color method of devitrified glass | |
| CN113773118B (en) | Jun porcelain overglaze color drawing process | |
| CN107021632A (en) | A kind of blue an ancient unit of weight fancy glaze | |
| CN105884197A (en) | Method for preparing series iron-series colored glaze from iron-ore slag and decoration method based on colored glaze | |
| CN110818262B (en) | Double-layer fancy glaze and preparation method of product thereof | |
| CN107032832A (en) | A kind of Ceramic Tiles with color changeable effect and preparation method thereof | |
| CN106630633A (en) | Underglaze five-color polished and glazed tile and preparation method thereof | |
| CN110217991A (en) | A kind of high strength china glaze and preparation method thereof | |
| CN110498668A (en) | A kind of colorful glaze ceramic plate and preparation method thereof | |
| CN107010922B (en) | Preparation method of transmutation glaze purple sand fine pottery | |
| CN108975708A (en) | A kind of high rigidity imitates the secret color glaze of Over-summer cultivation household china and its manufacture craft | |
| CN107721393B (en) | Preparation method of underglaze color painted porcelain with micro characters | |
| CN106746649A (en) | The light yellow glaze of high temperature light and its ceramic and preparation method | |
| CN106517779A (en) | Red glaze and preparation method thereof | |
| CN100402459C (en) | Color ceramic and its preparing method | |
| CN100593523C (en) | Manganese-neodymium-zinc kiln undertone purple flower glaze | |
| CN106565203A (en) | Yellow waste slurry ceramic product and preparation method thereof | |
| CN110963786A (en) | Colored art porcelain based on Dehua white porcelain body and preparation process thereof | |
| CN1165122A (en) | High-temp. | |
| CN105330259B (en) | Colored paintings ceramics and its preparation technology in a kind of mud | |
| WO2016065891A1 (en) | Colour ceramic and preparation method therefor | |
| CN109293237A (en) | A kind of roe Bluepoint shape pottery glaze and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| CB02 | Change of applicant information | ||
| CB02 | Change of applicant information |
Address after: No. 27, South Section of Longjin Road, Chengguan, Dehua County, Quanzhou City, Fujian Province Applicant after: Lusheng (Fujian) Group Co., Ltd. Address before: No. 27, South Section of Longjin Road, Chengguan, Dehua County, Quanzhou City, Fujian Province Applicant before: FUJIAN DEHUA XIEFA GUANGYANG POTTERY CO., LTD. |
|
| GR01 | Patent grant | ||
| GR01 | Patent grant |