CN107410323A - Seed treatment compositions containing bromine cyanogen insect amide and kasugarnycin - Google Patents

Seed treatment compositions containing bromine cyanogen insect amide and kasugarnycin Download PDF

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Publication number
CN107410323A
CN107410323A CN201710397583.XA CN201710397583A CN107410323A CN 107410323 A CN107410323 A CN 107410323A CN 201710397583 A CN201710397583 A CN 201710397583A CN 107410323 A CN107410323 A CN 107410323A
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CN
China
Prior art keywords
seed
seed treatment
treatment compositions
kasugarnycin
insect amide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710397583.XA
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Chinese (zh)
Inventor
陈劲礼
李新杰
梁明龙
陈悦
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JIANGMEN PLANT PROTECTION CO Ltd
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JIANGMEN PLANT PROTECTION CO Ltd
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Priority to CN201710397583.XA priority Critical patent/CN107410323A/en
Publication of CN107410323A publication Critical patent/CN107410323A/en
Pending legal-status Critical Current

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Classifications

    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/561,2-Diazoles; Hydrogenated 1,2-diazoles
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N25/00Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
    • A01N25/02Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
    • A01N25/04Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/04Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
    • A01N43/14Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
    • A01N43/16Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings with oxygen as the ring hetero atom

Abstract

The invention belongs to composition pesticide and field of pesticide preparation, and in particular to be it is a kind of be used to handling the composition of seed, it is more particularly to a kind of for rice, the seed treatment compositions and application thereof of potato seed subprocessing.The seed treatment compositions composition of the present invention comprises at least active insecticidal components and fungicide active ingredient, wherein, active insecticidal components are bromine cyanogen insect amide, and fungicide active ingredient is kasugarnycin, wherein, the weight ratio of bromine cyanogen insect amide and kasugarnycin is 1:20‑20:1, remaining is the agricultural chemicals auxiliary element commonly used in seed treatment processing.Mutual synergistic function can be played between the seed treatment compositions active component of the present invention, it is possible to reduce times for spraying, reduced drug cost, be worthy of popularization.

Description

Seed treatment compositions containing bromine cyanogen insect amide and kasugarnycin
Technical field
The invention belongs to composition pesticide and field of pesticide preparation, and in particular to be a kind of to be used to handle the combination of seed Thing, more particularly to it is a kind of for rice, the seed treatment compositions and application thereof of potato seed subprocessing.
Background technology
As the development cost of novel pesticide active component is continuously increased, old medicine is newly with the side for being increasingly becoming current more prevalence Formula, people give full play to its effect, as far as possible to greatest extent in the use value of the upper raising medicament of application, while by using side The improvement of method and object, the usage amount of agricultural chemicals is reduced as far as possible, its influence to environment is minimized.Thus, agricultural chemicals is developed to live The new application and application method of property composition, it is an important directions of agricultural chemicals research and development.Seed treatment is as comprehensive plant protection skill Art, turn into a kind of world today's crop protection means very prevailing.This method medication is few, effect is high, and people and animals and environment are influenceed It is small, can be prevented and treated since plant growth starting point it is each it is a variety of biography and soil-borne disease insect pest, the lasting period length, be growth belt greatly profit Benefit, it can additionally evade some harmful effects of medicament.In recent years, seriously break out in pest and disease damage, cost of labor increase year by year with And carry out under the overall situation of agricultural chemicals zero growth rate, seed treatment is received by increasing grower, and obtains fast development. Domestic seed treatment market is skyrocketed through, and domestic seed treatment market annual growth has reached 20% within 2010-2015 years.It is more Kind agricultural chemicals is developed as seed treatment, and in cereal(Wheat class), the field crop such as corn and soybean occupy suitable share. In the world, soybean, corn, wheat are the crop varieties that seed treatment is mainly applied, and three has occupied 80% or so market Share.Seed treatment product develops from single active ingredient to polynary active ingredient, from single preventing and treating target to more Change in terms of weight preventive effect, if seed treatment once is to kill based on nematode, and the seed treatment product of many enterprises now With killing the multi-functionals such as nematode, desinsection and sterilization.
Bromine cyanogen insect amide be E.I.Du Pont Company reported after Rynaxypyr another is new anthranilamide-based Insecticide, it have efficiently, low toxicity, mechanism of action it is novel, to non-target organism safety, to existing insecticide no interactions resistance etc. Feature.Compared with Rynaxypyr, bromine cyanogen insect amide has broader spectrum of insecticidal activity, has to sucking pest excellent Different preventive effect, and there is preferable absorbability, wide market.Bromine cyanogen insect amide is excellent except having to Hemipteran pest Activity it is outer, also there is activity well to Lepidoptera, Diptera pest, drosophila etc., because there is bromine cyanogen insect amide interior inhale to live Property, therefore various ways can be used to use, including spraying, pouring root, soil mix apply, seed treatment and other manner.
Kasugarnycin belongs to antibioticses bactericide, and it is egg to have protection, treatment and stronger systemic activity, kasugarnycin White matter synthetic inhibitor, by disturbing the esterase system of amino acid metabolism, so as to influence the synthesis of protein, suppress hyphal elongation With cause cell granulations magnificent.Kasugarnycin permeability is strong, can be moved in plant, and therapeutic effect is particularly significant, after spray It is quick, resistance of rainwater washing against, lasting period length, and the melon leaf color after dispenser can be made dark green and extend harvest time, it is preventing and treating therefore The various bacteria and fungal disease of the crops such as vegetables, melon and fruit and rice such as rice blast, leaf muld of tomato, cucumber are bacillary The favourable agents of angular leaf spot, pepper bacterial scab disease, fruit and vegetable anthracnose etc..
In recent years, the pesticide activity component due to long-term use of single kind and other unscientific medication preventing and treatings, it is most The all different degrees of a great problem for generating certain resistance to the action of a drug, turning into chemical prevention of phytopathy, insect pest.Due to disease, insect pest Drug-fast generation, directly results in that pesticide activity component declines to the prevention effect of diseases and pests of agronomic crop, formulation rate is increased, applied Medicine number is frequent, further increases peasant's drug cost and the threat to environment.In order to meet people it is food-safe and The higher and higher demand of medication labour, delay the drug-fast generation of pest and disease damage, so as to extend the use longevity of pesticide activity component Life, exploitation is with prevention effect is good, the pesticide new variety of lasting period length turns into the focus studied at present.
The pesticide activity component of some different mechanisms of action is compounded, by rational compound screening, may be improved The prevention effect of pesticide species, reduce dosage, reduce drug cost, so as to reach the mesh for reducing residues of pesticides and environmental pollution 's.For present inventor by substantial amounts of screening, being found surprisingly that can be right after compounding bromine cyanogen insect amide and kasugarnycin Synergy mutually is played well in the preventing and treating of pest and disease damage, after further research, completes the present invention.
The content of the invention
The purpose of the present invention is for the disease of crops of causing harm in the prior art, insect pest, there is provided one kind can diseases prevention again Can insect prevention composition pesticide, the composition pesticide, which is particularly suitable for use in, seed treatment and is prepared into a kind of combination of seed treatment Thing.
It is wonderful, active component bromine cyanogen insect amide and kasugarnycin mixture in the seed treatment compositions of the application Afterwards, the preventing and treating spectrum of single pesticide activity component can not only be expanded, so as to reduce times for spraying, and bromine cyanogen insect amide and spring thunder After mycin mixture, mutual effect be not only it is simple plus and, but between the two no matter to some crops of causing harm Insect pest or corps diseases show certain synergistic function.
Another object of the present invention is to provide the composition pesticide containing bromine cyanogen insect amide and kasugarnycin and/or Seed treatment compositions are used to prevent and treat corps diseases, the application of insect pest, the crops include but is not limited to rice, vegetables, The crops such as fruit tree, the disease, insect pest include but is not limited to thrips, diamondback moth, beet armyworm, bollworm, aphid, trialeurodes vaporariorum, cigarette Aleyrodid, rice blast, leaf muld of tomato, cucumber bacterial angular leaf spot, pepper bacterial scab disease, fruit and vegetable anthracnose etc..
In order to achieve the above object, the present invention adopts the following technical scheme that:
A kind of seed treatment compositions, its active component comprise at least active insecticidal components and fungicide active ingredient, wherein, kill Worm active component is bromine cyanogen insect amide, and fungicide active ingredient is kasugarnycin.
Further, active component bromine cyanogen insect amide and the weight of kasugarnycin ratio are 1 in the seed treatment compositions: 20-20:1, remaining is the agricultural chemicals auxiliary element commonly used in seed treatment processing.
Further, in seed treatment compositions of the invention composition shared by bromine cyanogen insect amide and kasugarnycin weight Percentage composition is 1-80%, preferably 6-60%.
Further, the formulation of seed treatment compositions of the invention be selected from suspension seed-coating agent, can wet-milling seed coat agent, dry powder Any of seed coat agent, wet seed dressing etc..
Further, the formulation of seed treatment compositions of the invention is preferably suspension seed-coating agent.
Further, removed in seed treatment compositions of the invention outside active component, can also include solvent, hydrotropy In agent, emulsifying agent, dispersant, wetting agent, thickener, antifreezing agent, defoamer, pH adjusting agent, stabilizer, preservative, warning coloration One or more, be all the conventional auxiliary element in Pesticide formulation, be not particularly limited, its dosage and species can Selection adjustment is carried out with the ordinary technical knowledge in Pesticide formulation.
Further, when seed treatment compositions of the invention are used to handle seed, can simultaneously or dividually use Other agricultural active compositions, including but not limited to fungicide, insecticide, nematicide, fertilizer and plant growth regulator.
Further, active component can be provided in the form of finished product preparation in of the invention and Zongzi treatment compositions, i.e., Each material of composition is blended, can also be provided with single dose combining form, using it is preceding in bucket or tank directly according to the ratio Example mixing, is then diluted to required concentration.
Compared with prior art, seed treatment compositions of the invention have the beneficial effect that:
(1)Active component both includes active insecticidal components in the seed treatment compositions of the present invention, includes fungicide active ingredient again, Both are used in mixed way and can reach applied once, can pest control and can diseases prevention effect, drug cost can be saved;
(2)Active component bromine cyanogen insect amide and the kasugarnycin mechanism of action are different in the seed treatment compositions of the present invention, Both are used in combination, it is possible to reduce and/or delay the drug-fast generation of disease, insect pest, so as to provide making for pesticide activity component Use the life-span;
(3)It is not simple add between each other after bromine cyanogen insect amide and kasugarnycin compound in the seed treatment compositions of the present invention And effect, no matter for crop pests or disease, it can show certain synergistic function.
Embodiment
In order that the purpose of the present invention, technical scheme and advantage are more explicit, with reference to embodiment to this hair It is bright to be described in further detail.It should be pointed out that specific embodiment described herein is used only for explaining the present invention, without It is understood that and is limited and be defined by claims for limitation of the invention, protection scope of the present invention.
First, example of formulations
1st, embodiment 1:22% bromine cyanogen insect amide kasugarnycin suspension seed-coating agent(10:1)
Bromine cyanogen insect amide 20%
Kasugarnycin 2%
Alkylaryl polyglycol ether 4%
APES formaldehyde condensation products sulfat 4%
Aluminium-magnesium silicate 3%
Propane diols 2%
Hydroxymethyl cellulose 10%
Arabic gum 2%
Sodium benzoate 1%
Organic silicone 1%
Water-based rhodo 3%
Deionized water surplus
The preparation method of the suspension seed-coating agent is:First bromine cyanogen insect amide, kasugarnycin are crushed through airslide disintegrating mill, then will After dispersant, wetting agent, colouring agent, thickener, antifreezing agent, preservative, defoamer and film forming agent and distilled water are completely dissolved, press Ground 2 times in ratio input sand mill so that preparation particle diameter is below 5 microns, you can the kind of the present invention that suspends is made Clothing agent.
2nd, embodiment 2:24.5% bromine cyanogen insect amide kasugarnycin suspension seed-coating agent(40:9)
Bromine cyanogen insect amide 20%
Kasugarnycin 4.5%
Dibutyl naphthalenesulfonic acid salt 5%
Polyoxyethylene ether phosphate 5%
Xanthans 3%
Propane diols 2%
Polyvinylpyrrolidone 8%
Chitosan 3%
Arabic gum 2%
OIT 1%
Organic silicone 1%
Water-based rhodo 3%
Deionized water surplus
The preparation method of the suspension seed-coating agent is:First bromine cyanogen insect amide, kasugarnycin are crushed through airslide disintegrating mill, then will After dispersant, wetting agent, colouring agent, thickener, antifreezing agent, preservative, defoamer and film forming agent and distilled water are completely dissolved, press Ground 2 times in ratio input sand mill so that preparation particle diameter is below 5 microns, you can the kind of the present invention that suspends is made Clothing agent.
3rd, comparative example 1:20% bromine cyanogen insect amide suspension seed-coating agent
Bromine cyanogen insect amide 20%
Alkylaryl polyglycol ether 4%
APES formaldehyde condensation products sulfat 4%
Aluminium-magnesium silicate 3%
Propane diols 2%
Hydroxymethyl cellulose 10%
Arabic gum 2%
Sodium benzoate 1%
Organic silicone 1%
Water-based rhodo 3%
Deionized water surplus
The preparation method of the suspension seed-coating agent is:First bromine cyanogen insect amide is crushed through airslide disintegrating mill, then by dispersant, profit After humectant, colouring agent, thickener, antifreezing agent, preservative, defoamer and film forming agent and distilled water are completely dissolved, put into proportion Ground 2 times in sand mill so that preparation particle diameter is below 5 microns, you can suspension seed-coating agent of the present invention is made.
4th, comparative example 2:4.5% kasugarnycin suspension seed-coating agent
Kasugarnycin 4.5%
Dibutyl naphthalenesulfonic acid salt 3%
Polyoxyethylene ether phosphate 3%
Xanthans 2%
Propane diols 2%
Polyvinylpyrrolidone 8%
Chitosan 3%
Arabic gum 2%
OIT 1%
Organic silicone 1%
Water-based rhodo 3%
Deionized water surplus
The preparation method of the suspension seed-coating agent is:First kasugarnycin is crushed through airslide disintegrating mill, then by dispersant, wetting After agent, colouring agent, thickener, antifreezing agent, preservative, defoamer and film forming agent and distilled water are completely dissolved, sand is put into proportion Ground 2 times in grinding machine so that preparation particle diameter is below 5 microns, you can suspension seed-coating agent of the present invention is made.
2nd, it is raw to survey embodiment
1st, reagent agent:Example of formulations 1-2, comparative example 1-2 pesticidal preparations.
2nd, subjects:Rice thrips, rice green smut.
3rd, test method:Experiment is arranged on the progress of Jiangmen city LongXi village, is experimental field sandy loam, middle fertility, arranges the side of irrigating Just, surrounding is rice terrace.Soaked seed with embodiment 1-2, comparative example 1-2 agricultural-chemical suspension seed coat agent, seed soaking time is 48h, sowed after drying, fine day during sowing, wind-force 2-3 levels.
4th, pilot survey:Incidence is investigated in rice blast peak period, investigates per district's groups at 2 points, every 5-10 m2, Total strain number and diseased plant number are investigated, calculates diseased plant rate and strain preventive effect.
The random 5 points of samplings of rice thripses, 10 plants every, quantity and insect bite strain number occur for investigation thrips, calculate prevention effect.
Result of the test is as shown in table 1.
It is as shown in table 1 to the prevention effect of rice rice thripses, rice blast after different suspension seed-coating agent processing Rice seeds treateds, by Table 1 as can be seen that the seed treatment compositions of embodiment 1,2 are balanced to the prevention effect of rice rice thripses and false smut, compared with While preventing and treating rice thrips well, also preferably simultaneous rice green smut can be controlled.And the agricultural chemicals single dose kind of comparative example 1,2, only It only can preferably prevent and treat a kind of insect pest or disease;In addition, no matter embodiment 1,2 is for rice green smut or rice thripses, Prevention effect is greatly improved, and shows that phase can be played between active component in the seed treatment compositions of the present invention Mutual synergistic function.In addition, not finding the seed treatment compositions of the present invention during experiment has poisoning generation to rice, to water Rice emergence also without ill-effect, shows that the seed treatment compositions of the present invention are good to crop compatibility, safe and harmless.

Claims (7)

1. a kind of seed treatment compositions, it is characterised in that its active component comprises at least a kind of active insecticidal components and one Kind fungicide active ingredient, wherein, active insecticidal components are bromine cyanogen insect amide, and fungicide active ingredient is kasugarnycin.
2. seed treatment compositions according to claim 1, it is characterised in that the bromine cyanogen insect amide and kasugarnycin Weight ratio is 1:20-20:1.
3. seed treatment compositions according to claim 2, it is characterised in that the bromine cyanogen insect amide and kasugarnycin Weight ratio preferably 40:9.
4. according to the seed treatment compositions described in any one of claim 1-3 claim, it is characterised in that the seed The formulation for the treatment of compositions is suspension seed-coating agent, can be any in wet-milling seed coat agent, dry-powder seed coating agent, wet seed dressing.
5. seed treatment compositions according to claim 4, it is characterised in that the formulation is preferably suspension seed-coating agent.
6. the seed treatment compositions according to claim 1-5 are used for the purposes of disinsection prophylaxis.
7. seed treatment compositions according to claim 1-5 be used to preventing and treating thrips, diamondback moth, beet armyworm, bollworm, Aphid, trialeurodes vaporariorum, Bemisia tabaci, rice blast, leaf muld of tomato, cucumber bacterial angular leaf spot, pepper bacterial scab disease, fruit The purposes of vegetable anthracnose.
CN201710397583.XA 2017-05-31 2017-05-31 Seed treatment compositions containing bromine cyanogen insect amide and kasugarnycin Pending CN107410323A (en)

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Application Number Priority Date Filing Date Title
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108432397A (en) * 2018-04-17 2018-08-24 黄必飞 A method of prevention dragon fruit anthracnose, stem wilt
CN112400908A (en) * 2020-11-27 2021-02-26 中国热带农业科学院椰子研究所 Medicament composition for preventing and treating rhinoceros

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101606523A (en) * 2009-07-23 2009-12-23 北京燕化永乐农药有限公司 A kind of paddy rice desinsection, bactericidal composition
CN104585172A (en) * 2014-12-24 2015-05-06 陈燕婷 Antibiotic seed treatment agent composition
CN106172449A (en) * 2016-07-08 2016-12-07 广东中迅农科股份有限公司 Containing thifluzamide and Fluoxastrobin and the seed treatment compositions of bromine cyanogen insect amide

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101606523A (en) * 2009-07-23 2009-12-23 北京燕化永乐农药有限公司 A kind of paddy rice desinsection, bactericidal composition
CN104585172A (en) * 2014-12-24 2015-05-06 陈燕婷 Antibiotic seed treatment agent composition
CN106172449A (en) * 2016-07-08 2016-12-07 广东中迅农科股份有限公司 Containing thifluzamide and Fluoxastrobin and the seed treatment compositions of bromine cyanogen insect amide

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108432397A (en) * 2018-04-17 2018-08-24 黄必飞 A method of prevention dragon fruit anthracnose, stem wilt
CN112400908A (en) * 2020-11-27 2021-02-26 中国热带农业科学院椰子研究所 Medicament composition for preventing and treating rhinoceros
CN112400908B (en) * 2020-11-27 2021-08-20 中国热带农业科学院椰子研究所 Medicament composition for preventing and treating rhinoceros

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Application publication date: 20171201