CN107400425B - Penetrating gloss oil for vacuum aluminum plating layer and preparation method thereof - Google Patents

Penetrating gloss oil for vacuum aluminum plating layer and preparation method thereof Download PDF

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Publication number
CN107400425B
CN107400425B CN201610347880.9A CN201610347880A CN107400425B CN 107400425 B CN107400425 B CN 107400425B CN 201610347880 A CN201610347880 A CN 201610347880A CN 107400425 B CN107400425 B CN 107400425B
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Prior art keywords
penetrating
aluminum plating
vacuum aluminum
plating layer
agent
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Expired - Fee Related
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CN201610347880.9A
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CN107400425A (en
Inventor
江谷
朱雨川
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Zhejiang Haoshijia Reflection Material Co ltd
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Zhejiang Haoshijia Reflection Material Co ltd
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/36Sulfur-, selenium-, or tellurium-containing compounds
    • C08K5/41Compounds containing sulfur bound to oxygen
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/36Sulfur-, selenium-, or tellurium-containing compounds
    • C08K5/41Compounds containing sulfur bound to oxygen
    • C08K5/42Sulfonic acids; Derivatives thereof
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/36Sulfur-, selenium-, or tellurium-containing compounds
    • C08K5/43Compounds containing sulfur bound to nitrogen
    • C08K5/435Sulfonamides
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Laminated Bodies (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)

Abstract

The invention discloses penetrating gloss oil for vacuum aluminum plating, which consists of matrix resin, an organic solvent, a penetrating material and an auxiliary agent, and comprises the following components in percentage by mass: matrix resin: 5-10%; organic solvent: 85-90%; and (3) penetrating materials: 4-8%; auxiliary agent: 0.1-1%, the penetrating gloss oil is coated on the vacuum aluminum plating layer, has the following advantages of enhancing the permeability of the vacuum aluminum plating layer to gas, opening a channel for volatilizing a solvent or moisture on the aluminum plating layer, and thoroughly avoiding the problem of foaming; the metal luster of the aluminum plating layer is enhanced, and the effect of prolonging the luster aging is achieved; good stability, strong permeability and capability of being seamlessly fused with an aluminum coating.

Description

Penetrating gloss oil for vacuum aluminum plating layer and preparation method thereof
Technical Field
The invention relates to the technical field of manufacturing of heat transfer films, in particular to penetrating gloss oil for vacuum aluminum plating layers and a preparation method thereof.
Background
Along with the improvement of national economy and the development of printing and packaging industries, people require high-grade, exquisite, environment-friendly and personalized outer packaging of products, in the post-printing processing of packaging products, a hot stamping process is always favored by people due to the unique surface finishing effect, hot stamping mainly has three functions, surface decoration is realized, hot stamped pictures and texts show strong metallic luster, the colors are bright and attractive, and the products are never faded. Particularly, the bronzing silver decorates the surface of the printed matter by the magnificent, exquisite and elegant decoration, enhances the artistry of the printed matter, plays a role in promoting the outstanding theme, greatly exceeds the bronzing and the bronzing silver in brightness, enables the product to have high-grade feeling and beautiful enjoyment, and greatly improves the added value of the product. Secondly, endowing the product with higher anti-counterfeiting performance, adopting holographic positioning hot stamping trademark identification to prevent counterfeiting and protect the brand; and thirdly, the printed matter is protected, and the gold stamping layer has excellent physical and chemical properties, so that the printed matter is well protected.
The vacuum aluminum-plated decorative material has a very prominent metal effect, so that the application range of the vacuum aluminum-plated decorative material is continuously expanded, and the existing aluminum-plated layer has poor gas permeability, which is shown in a macroscopic aspect that the residual solvent or moisture can continuously volatilize in a period of time after the construction of the decorative material, so that the surface of the decorative material is foamed or protruded, and therefore, the residual solvent or moisture in the vacuum aluminum-plated decorative material is reduced as much as possible, but the residual solvent or moisture is reduced as much as possible, and the solvent or moisture cannot be thoroughly removed.
Disclosure of Invention
Based on the technical problems in the background art, the invention provides the penetrating gloss oil for the vacuum aluminum coating and the preparation method thereof.
The penetrating gloss oil for the vacuum aluminum plating layer consists of matrix resin, an organic solvent, a penetrating material and an auxiliary agent, and comprises the following components in percentage by mass:
matrix resin: 5-10%;
organic solvent: 85-90%;
and (3) penetrating materials: 4-8%;
auxiliary agent: 0.1 to 1 percent.
Preferably, the matrix resin is modified acrylic resin.
Preferably, the organic solvent is one or more of ethyl ester, deionized water and ethanol.
Preferably, the penetrating material is one or more of sulfated castor oil, sodium alkyl sulfonate, sodium alkyl benzene sulfonate, sodium alkyl sulfate, secondary sodium alkyl sulfonate, secondary sodium alkyl sulfate, sodium a-alkenyl sulfonate, sodium alkyl naphthalene sulfonate, sodium alkyl sulfosuccinate, tryptone T, sodium sulfamate, fatty alcohol-polyoxyethylene ether, alkylphenol ethoxylate, polyether, phosphate compound, alcohol compound, ketone compound and ether compound.
Preferably, the auxiliary agent is one or more of a leveling agent, a defoaming agent, an antistatic agent and a dispersing agent.
The invention also provides a preparation method of the vacuum aluminum-plated layer penetrating gloss oil, which comprises the following steps:
s1, mixing the resin and the organic solvent in proportion, dispersing at high speed to dissolve the mixture into resin liquid;
s2, taking a proper amount of dissolved resin liquid, adding a certain proportion of penetrating materials and related auxiliary agents into the resin liquid, and dispersing the mixture at a high speed to form a preparation agent;
s3, pouring the dispersed mixture into the resin liquid to disperse again at high speed to obtain the vacuum aluminum plating layer penetrating gloss oil.
The invention adopts the technical scheme and has the following characteristics: the penetrating gloss oil is coated on the surface 1 of the aluminum-plated layer, so that the permeability of the aluminum-plated layer to gas is enhanced, and a solvent or a moisture volatilization channel is opened for the aluminum-plated layer, thereby thoroughly avoiding the problem of foaming; 2. the metal luster of the aluminum plating layer is enhanced, and the effect of prolonging the luster aging is achieved; 3. good stability, strong permeability and capability of being seamlessly fused with an aluminum coating.
Detailed Description
The present invention will be further illustrated with reference to the following specific examples.
The first embodiment is as follows: the raw material proportion of the vacuum aluminum plating layer penetrating gloss oil is that the matrix resin: modified acrylic resin: 5 kg; organic solvent: ethyl ester: 45kg, ethanol: 45 kg; and (3) penetrating materials: alkylphenol ethoxylates: 2kg, phosphate compound: 1.5kg, sodium alkyl sulfosuccinate: 1 kg; auxiliary agent: dispersing agent: 0.3kg, leveling agent: 0.2 kg.
Method of preparation example one: firstly, 5Kg of modified acrylic resin, 45Kg of ethyl ester and 45Kg of ethanol are mixed and then dispersed at a high speed of 2000 rpm for 30 minutes under the action of a high-speed dispersion machine to dissolve the resin into resin liquid; then 10Kg of resin liquid is taken, 2Kg of alkylphenol polyoxyethylene ether, 1.5Kg of phosphate compound, 1Kg of sodium alkyl sulfosuccinate, 0.3Kg of dispersant and 0.2Kg of leveling agent are added into the resin liquid, and then the resin liquid is dispersed uniformly by dispersing at a high speed of 1800 rpm for 35 minutes to obtain a preparation agent, finally the dispersed preparation agent and the resin liquid are poured back into the resin liquid and dispersed at a high speed of 2000 rpm for 30 minutes to prepare the vacuum aluminum plating layer penetrating gloss oil, and the penetrating gloss oil is coated on the surface of the aluminum plating layer to greatly improve the permeability of the aluminum plating layer to ensure that the aluminum plating layer opens a channel for solvent or water volatilization, thereby thoroughly avoiding the foaming problem, simultaneously enhancing the metal gloss of the aluminum plating layer and having the effect of prolonging the gloss aging, and having good stability and permeability.
Example two: the raw material proportion of the vacuum aluminum plating layer penetrating gloss oil is that the matrix resin: modified acrylic resin: 10 kg; organic solvent: ethyl ester: 30kg, ethanol: 30kg, deionized water: 25; and (3) penetrating materials: sodium alkyl sulfonate: 1kg, sodium alkyl benzene sulfonate: 1kg, sodium alkyl sulfate: 1kg, secondary sodium alkyl sulfonate: 1.5 kg; auxiliary agent: dispersing agent: 0.15kg, leveling agent: 0.15kg, antistatic agent: 0.1kg of defoamer: 0.1 kg.
Method of making example two: firstly, 10Kg of modified acrylic resin, 30Kg of ethyl ester, 30Kg of ethanol and 25Kg of deionized water are mixed and then dispersed at a high speed of 1800 rpm for 35 minutes under the action of a high-speed dispersion machine to dissolve the resin into resin liquid; then taking 18Kg of resin liquid, and adding 1Kg of alkyl sodium sulfonate, 1Kg of sodium alkyl benzene sulfonate, 1Kg of alkyl sodium sulfate and 1.5Kg of secondary alkyl sodium sulfonate into the resin liquid; 0.2kg of dispersing agent, 0.2kg of flatting agent and 0.1kg of antistatic agent, then dispersing for 40 minutes at a high speed of 1800 rpm to obtain a preparation agent, finally dispersing the dispersed preparation agent and resin liquid at a high speed of 1800 rpm for 35 minutes to prepare the vacuum aluminum coating layer penetrating gloss oil, compared with the first embodiment, the penetrating gloss oil has a little improvement on gas permeability, but has the advantages of stability, permeability and gloss enhancement.
Example three: the raw material proportion of the vacuum aluminum plating layer penetrating gloss oil is that the matrix resin: modified acrylic resin: 7 kg; organic solvent: ethyl ester: 30kg, ethanol: 30kg, deionized water: 25; and (3) penetrating materials: sodium alkyl sulfonate: 1kg, sodium alkyl benzene sulfonate: 1kg, sodium alkyl sulfate: 1kg, sodium alkyl sulfosuccinate: 1kg, pancreas plus float T: 1kg, sodium sulfamate: 1kg, secondary sodium alkyl sulfonate: 1.5 kg; auxiliary agent: dispersing agent: 0.2kg, leveling agent: 0.2kg, antistatic agent: 0.1 kg.
Method of preparation example three: firstly, mixing 7Kg of modified acrylic resin, 30Kg of ethyl ester, 30Kg of ethanol and 25Kg of deionized water, and dispersing at a high speed of 2000 revolutions per minute for 35 minutes under the action of a high-speed dispersion machine to dissolve the resin into a resin liquid; then taking 15Kg of resin liquid, adding 1Kg of alkyl sodium sulfonate, 1Kg of sodium alkyl benzene sulfonate, 1Kg of alkyl sodium sulfate, 1Kg of succinic acid alkyl ester sodium sulfonate, 1Kg of pancreatic bleaching T1Kg, 1Kg of amino sodium sulfonate and 1.5Kg of secondary alkyl sodium sulfonate; 0.15kg of dispersing agent, 0.15kg of flatting agent, 0.1kg of antistatic agent and 0.1kg of antistatic agent, then dispersing for 40 minutes at a high speed of 2000 r/min to obtain a preparation agent, finally, dispersing the dispersed preparation agent and resin liquid at a high speed of 2000 r/min for 35 minutes to prepare the vacuum aluminum plating layer penetrating gloss oil, wherein the penetrating gloss oil is superior to the above 2 in the aspects of gas permeability, stability, permeability and gloss enhancement, so the preparation method and the proportion of the third embodiment are preferred.
The above description is only for the preferred embodiment of the present invention, but the scope of the present invention is not limited thereto, and any person skilled in the art should be considered to be within the technical scope of the present invention, and the technical solutions and the inventive concepts thereof according to the present invention should be equivalent or changed within the scope of the present invention.

Claims (5)

1. The penetrating gloss oil for the vacuum aluminum plating layer is characterized in that: the penetrating gloss oil of the vacuum aluminum-plated layer consists of matrix resin, an organic solvent, a penetrating material and an auxiliary agent, and comprises the following components in percentage by mass:
matrix resin: 5-10%;
organic solvent: 85-90%;
and (3) penetrating materials: 4-8%;
auxiliary agent: 0.1-1%;
the penetrating material is one or more of sulfated castor oil, alkyl sodium sulfonate, sodium alkyl benzene sulfonate, sodium alkyl sulfate, secondary alkyl sodium sulfonate, secondary alkyl sodium sulfate, alpha-alkenyl sodium sulfonate, alkyl naphthalene sodium sulfonate, succinic acid alkyl ester sodium sulfonate, pancreatic bleaching T, sodium sulfamate, fatty alcohol polyoxyethylene ether and alkylphenol polyoxyethylene ether.
2. The varnish for vacuum aluminum plating according to claim 1, wherein: the matrix resin is modified acrylic resin.
3. The varnish for vacuum aluminum plating according to claim 1, wherein: the organic solvent is one or more of ethyl ester and ethanol.
4. The varnish for vacuum aluminum plating according to claim 1, wherein: the auxiliary agent is one or more of a leveling agent, a defoaming agent, an antistatic agent and a dispersing agent.
5. The method for preparing the vacuum aluminum plating layer penetrating gloss oil according to any one of claims 1 to 4, which is characterized by comprising the following steps:
s1, mixing the resin and the organic solvent in proportion, dispersing at high speed to dissolve the mixture into resin liquid;
s2, taking a proper amount of dissolved resin liquid, adding a certain proportion of penetrating materials and related auxiliary agents into the resin liquid, and dispersing the mixture at a high speed to form a preparation agent;
s3, pouring the dispersed mixture into the resin liquid to disperse again at high speed to obtain the vacuum aluminum plating layer penetrating gloss oil.
CN201610347880.9A 2016-05-19 2016-05-19 Penetrating gloss oil for vacuum aluminum plating layer and preparation method thereof Expired - Fee Related CN107400425B (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101041280A (en) * 2006-03-21 2007-09-26 顺天保暖制品(昆山)有限公司 Application of aluminum foil material in the warmer bag
CN101377065A (en) * 2007-08-29 2009-03-04 安徽双永包装装饰材料有限公司 Wholly-degradable emulation empty aluminums plating or aluminum platinum composite paper
CN102864682A (en) * 2012-08-09 2013-01-09 常德市武陵金德镭射科技有限公司 Method for preparing acrylic resin emulsion and paper coating emulsion
CN102966000A (en) * 2012-11-23 2013-03-13 常德市武陵金德镭射科技有限公司 Barrier coating for cigarette lining paper and production method thereof

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1219130C (en) * 2002-09-12 2005-09-14 汕头方大应用包装科技有限公司 Production process of twisted candy packing paper
CN101225622A (en) * 2008-02-03 2008-07-23 李中明 Vacuum-coated aluminum paper and method for manufacturing same
CN101879819B (en) * 2010-06-13 2011-11-09 高邮市卫星卷烟材料有限公司 Production method of hot stamping foil
CN103320004B (en) * 2013-06-17 2016-02-10 上海良虹印务有限公司 The method of the mute oil of a kind of water borne soft-feel and making soft feeling film thereof
CN104118156B (en) * 2013-11-28 2016-08-24 海南必凯水性涂料有限公司 A kind of high-barrier environmental protection coating internal lining paper and manufacture method thereof
CN104017636B (en) * 2014-06-06 2016-07-13 清华大学 A kind of complete synthesis metal grinding fluid of water solublity

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101041280A (en) * 2006-03-21 2007-09-26 顺天保暖制品(昆山)有限公司 Application of aluminum foil material in the warmer bag
CN101377065A (en) * 2007-08-29 2009-03-04 安徽双永包装装饰材料有限公司 Wholly-degradable emulation empty aluminums plating or aluminum platinum composite paper
CN102864682A (en) * 2012-08-09 2013-01-09 常德市武陵金德镭射科技有限公司 Method for preparing acrylic resin emulsion and paper coating emulsion
CN102966000A (en) * 2012-11-23 2013-03-13 常德市武陵金德镭射科技有限公司 Barrier coating for cigarette lining paper and production method thereof

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