CN103102775B - Low-gloss clear finishing coat and preparation method thereof - Google Patents
Low-gloss clear finishing coat and preparation method thereof Download PDFInfo
- Publication number
- CN103102775B CN103102775B CN201310023169.4A CN201310023169A CN103102775B CN 103102775 B CN103102775 B CN 103102775B CN 201310023169 A CN201310023169 A CN 201310023169A CN 103102775 B CN103102775 B CN 103102775B
- Authority
- CN
- China
- Prior art keywords
- parts
- dimethylbenzene
- nitro
- low
- finishing coat
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims abstract description 38
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 36
- DKPFZGUDAPQIHT-UHFFFAOYSA-N butyl acetate Chemical compound CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 claims abstract description 22
- 229920000180 alkyd Polymers 0.000 claims abstract description 16
- 229920000742 Cotton Polymers 0.000 claims abstract description 15
- 239000007788 liquid Substances 0.000 claims abstract description 15
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 claims abstract description 12
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims abstract description 11
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 30
- 239000006185 dispersion Substances 0.000 claims description 26
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 24
- 239000002966 varnish Substances 0.000 claims description 21
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 18
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 16
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 16
- 239000002253 acid Substances 0.000 claims description 16
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims description 12
- 239000013530 defoamer Substances 0.000 claims description 12
- 239000000377 silicon dioxide Substances 0.000 claims description 12
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 10
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 10
- -1 organically-modified silica alkane Chemical class 0.000 claims description 10
- 238000002156 mixing Methods 0.000 claims description 9
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 8
- 235000011187 glycerol Nutrition 0.000 claims description 8
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical class OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 8
- LGRFSURHDFAFJT-UHFFFAOYSA-N phthalic anhydride Chemical class C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 claims description 8
- 235000015112 vegetable and seed oil Nutrition 0.000 claims description 8
- 239000008158 vegetable oil Substances 0.000 claims description 8
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 claims description 6
- 229940059574 pentaerithrityl Drugs 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- 238000010792 warming Methods 0.000 claims description 6
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical group CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 claims description 5
- 239000012975 dibutyltin dilaurate Substances 0.000 claims description 5
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 5
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 5
- 238000006243 chemical reaction Methods 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 230000032050 esterification Effects 0.000 claims description 3
- 238000005886 esterification reaction Methods 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 150000007513 acids Chemical class 0.000 claims description 2
- 238000012423 maintenance Methods 0.000 claims description 2
- 150000003504 terephthalic acids Chemical class 0.000 claims description 2
- 239000002023 wood Substances 0.000 abstract description 4
- SVONRAPFKPVNKG-UHFFFAOYSA-N 2-ethoxyethyl acetate Chemical compound CCOCCOC(C)=O SVONRAPFKPVNKG-UHFFFAOYSA-N 0.000 abstract 1
- 239000002518 antifoaming agent Substances 0.000 abstract 1
- 229910000278 bentonite Inorganic materials 0.000 abstract 1
- 239000000440 bentonite Substances 0.000 abstract 1
- 230000008033 biological extinction Effects 0.000 abstract 1
- 239000002270 dispersing agent Substances 0.000 abstract 1
- 239000004615 ingredient Substances 0.000 abstract 1
- 239000000843 powder Substances 0.000 abstract 1
- 230000002035 prolonged effect Effects 0.000 abstract 1
- 238000006748 scratching Methods 0.000 abstract 1
- 239000003973 paint Substances 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 230000000007 visual effect Effects 0.000 description 3
- 230000003245 working effect Effects 0.000 description 3
- 238000005507 spraying Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention discloses a low-gloss clear finishing coat. The low-gloss clear finishing coat comprises the following components in parts by weight: 71.5-72.5 parts of modified alkyd resin, 4.8-5.3 parts of dimethylbenzene, 4.6-5.0 parts of n-butyl acetate, 0.15-0.25 part of dispersing agent, 0.10-0.20 part of antifoaming agent, 3.8-4.2 parts of bentonite, 4.8-5.1 parts of extinction powder, 3.6-4.2 parts of nitro-cotton liquid, 1.8-2.4 parts of cyclohexanone, 0.28-0.40 part of flatting agent, 1.8-2.1 parts of ethylene glycol monoethyl ether acetate and 0.15-0.25 part of dryer. The hardness of the low-gloss clear finishing coat obtained by adopting the special ingredients and the preparation method is twice more than that of the common low-gloss clear finishing coat, the anti-scratching capacity is strong and the service life is greatly prolonged. Meanwhile, the other the other performances also completely satisfy the standards, and the hand feeling is good, and so the low-gloss clear finishing coat is applicable to the decorative field of the solid-wood furniture.
Description
Technical field
The present invention relates to a kind of paint and preparation method thereof, particularly a kind of matte varnish and preparation method thereof.
Background technology
Existing furniture generally adopts solid wood or imitative solid wood material to make, and its surface adopts paint as topcoating usually, and outermost layer passes through spraying high-transparency varnish to strengthen its luminance brightness and slickness, aesthetic property and good waterproof performance.But various furniture in use can artificially be scratched usually, cause the variation such as sight and water-repellancy, work-ing life shortens.In order to solve this shortcoming of clear lacquer, then occurred dumb light paint, dumb light paint has soft visual effect and good feel is extensively favored.But there is a general shortcoming in existing dumb light paint, is exactly that hardness is lower, is easily scratched.And using for a long time and can polishing gradually after rubbing, cause glossiness and feel obviously inconsistent, affect attractive in appearance.
For above-mentioned deficiency, be badly in need of a kind of matte varnish that can improve its hardness of development, make its scratch resistance, wear-resisting, long service life, does not affect its soft visual effect and good feel simultaneously.
Summary of the invention
In view of this, an object of the present invention is to provide a kind of matte varnish, makes its scratch resistance, wear-resisting, greatly extends its work-ing life under normal service condition, does not affect its soft visual effect and good feel simultaneously.
An object of the present invention is realized by following technique means: a kind of matte varnish, composed of the following components by weight: modified alkyd resin 71.5-72.5, dimethylbenzene 4.8-5.3, N-BUTYL ACETATE 4.6-5.0, dispersion agent 0.15-0.25, defoamer 0.10-0.20, wilkinite 3.8-4.2, flatting silica 4.8-5.1, nitro-cotton liquid 3.6-4.2, pimelinketone 1.8-2.4, flow agent 0.28-0.40, ethylene glycol ether acetate 1.8-2.1, siccative 0.15-0.25; Described flow agent by weight part be 0.08-0.10 organically-modified silica alkane and weight part be 0.20-0.30 polyether-modified polydimethylsiloxane mix;
Described modified alkyd resin is made up of 20-25 parts of vegetable oil acids, 15-18 parts of glycerine, 5-6 parts of tetramethylolmethanes, 10-15 parts of terephthalic acids, 0.1-0.15 part of Hypophosporous Acid, 50,3-4 parts of phthalic anhydrides, 5-6 parts of phenylformic acid, 3.5-4.5 parts of dimethylbenzene, 20-25 parts of acetone and 0.1-0.15 part of dispersion agent by weight, its preparation method is: by vegetable oil acid, glycerine, tetramethylolmethane, after terephthalic acid and Hypophosporous Acid, 50 drop into reactor, logical rare gas element in reactor, heating, start to stir after being warming up to 90 DEG C, and continue to be warmed up to 200-210 DEG C, constant temperature leaves standstill 40-50 minutes, then rapid temperature increases to 240-250 DEG C, constant temperature is to the complete transparent rear rapid cooling of reaction solution, phthalic anhydride is dropped into when being down in 190 DEG C of backward reactors, phenylformic acid and dimethylbenzene, again be warming up to 200-205 DEG C of refuxing esterification and be incubated 30-45 minutes, then less than 150 DEG C are cooled to, add acetone and dispersion agent, room temperature is naturally cooled to after stirring.。
Further, composed of the following components by weight: modified alkyd resin 72, dimethylbenzene 5, N-BUTYL ACETATE 5, dispersion agent 0.2, defoamer 0.15, wilkinite 4.0, flatting silica 5.0, nitro-cotton liquid 4.0, pimelinketone 2.0, flow agent 0.35, ethylene glycol ether acetate 2.0, siccative 0.2.
Further, described nitro-cotton liquid is 1/4 nitro-cotton liquid;
Further, described siccative is dibutyltin dilaurate.
Two of object of the present invention is achieved through the following technical solutions: a kind of preparation method of matte varnish, comprises the following steps:
A, for subsequent use by above-mentioned formula feeding;
B, pour modified alkyd resin and dimethylbenzene into mixing machine, with the speed blending dispersion 15-20 minutes of 800 revs/min;
C, maintenance rotating speed are constant, add N-BUTYL ACETATE successively in order, dispersion agent, defoamer, wilkinite, flatting silica, nitro-cotton liquid, pimelinketone, flow agent, ethylene glycol ether acetate and siccative;
D, the speed blending dispersion 15-20 minutes then continuing with 800 revs/min.
Beneficial effect of the present invention: the matte varnish adopting special formulation of the present invention and preparation method's gained, its hardness is more than 2 times of existing common matte varnish hardness, and scratch resistance capability is extremely strong, substantially prolongs its work-ing life; Other performances also complete conformance with standard simultaneously, feel is better, is applicable to the furnishing fields of solid wood furniture.
Embodiment
Example 1
A kind of matte varnish, composed of the following components: modified alkyd resin 71.5kg, dimethylbenzene 5.3kg, N-BUTYL ACETATE 4.6kg, dispersion agent 0.25kg, defoamer 0.10kg, wilkinite 4.2kg, flatting silica 4.8kg, 1/4 nitro-cotton liquid 4.2kg, pimelinketone 1.8kg, flow agent 0.40kg, ethylene glycol ether acetate 1.8kg, siccative 0.25kg; In the present embodiment, described flow agent is mixed by the organically-modified silica alkane of 0.10kg and the polyether-modified polydimethylsiloxane of 0.30kg, and described siccative is dibutyltin dilaurate;
Described modified alkyd resin is made up of 20kg vegetable oil acid, 18kg glycerine, 5kg tetramethylolmethane, 15kg terephthalic acid, 0.1kg Hypophosporous Acid, 50,4kg phthalic anhydride, 5kg phenylformic acid, 4.5kg dimethylbenzene, 20kg acetone and 0.15kg dispersion agent, its preparation method is: by vegetable oil acid, glycerine, tetramethylolmethane, after terephthalic acid and Hypophosporous Acid, 50 drop into reactor, logical rare gas element in reactor, heating, start to stir after being warming up to 90 DEG C, and continue to be warmed up to 200-210 DEG C, constant temperature leaves standstill 40-50 minutes, then rapid temperature increases to 240-250 DEG C, constant temperature is to the complete transparent rear rapid cooling of reaction solution, phthalic anhydride is dropped into when being down in 190 DEG C of backward reactors, phenylformic acid and dimethylbenzene, again be warming up to 200-205 DEG C of refuxing esterification and be incubated 30-45 minutes, then less than 150 DEG C are cooled to, add acetone and dispersion agent, room temperature is naturally cooled to after stirring.
The concrete production method of described color inhibition Brilliant white paint is: pour modified alkyd resin and dimethylbenzene into mixing machine, with the speed blending dispersion 15-20 minutes of 800 revs/min; Keep rotating speed constant, add N-BUTYL ACETATE successively in order, dispersion agent, defoamer, wilkinite, flatting silica, nitro-cotton liquid, pimelinketone, flow agent, ethylene glycol ether acetate and siccative; Then the speed blending dispersion 15-20 minutes with 800 revs/min is continued.
Example 2
A kind of matte varnish, composed of the following components: modified alkyd resin 72.5kg, dimethylbenzene 4.8kg, N-BUTYL ACETATE 4.8kg, dispersion agent 0.15kg, defoamer 0.20kg, wilkinite 3.8kg, flatting silica 5.1kg, 1/4 nitro-cotton liquid 3.6kg, pimelinketone 2.4kg, flow agent 0.28kg, ethylene glycol ether acetate 2.1kg, siccative 0.15kg; In the present embodiment, described flow agent is mixed by the organically-modified silica alkane of 0.20kg and the polyether-modified polydimethylsiloxane of 0.08kg, and described siccative is dibutyltin dilaurate;
Described modified alkyd resin is made up of 25kg vegetable oil acid, 15kg glycerine, 6kg tetramethylolmethane, 10kg terephthalic acid, 0.15kg Hypophosporous Acid, 50,3kg phthalic anhydride, 6kg phenylformic acid, 3.5kg dimethylbenzene, 25kg acetone and 0.1kg dispersion agent; Its preparation method is with embodiment 1.
The production method of described matte varnish is with embodiment 1.
Example 3
A kind of matte varnish, composed of the following components: modified alkyd resin 72kg, dimethylbenzene 5kg, N-BUTYL ACETATE 5kg, dispersion agent 0.2kg defoamer 0.15kg, wilkinite 4.0kg, flatting silica 5.0kg, 1/4 nitro-cotton liquid 4.0kg, pimelinketone 2.0kg, flow agent 0.35kg; In the present embodiment, described flow agent is mixed by the organically-modified silica alkane of 0.09kg and the polyether-modified polydimethylsiloxane of 0.26kg, and ethylene glycol ether acetate 2.0kg, siccative 0.2kg, described siccative is dibutyltin dilaurate.
Described modified alkyd resin is made up of 23kg vegetable oil acid, 16kg glycerine, 5.5kg tetramethylolmethane, 12kg terephthalic acid, 0.12kg Hypophosporous Acid, 50,3.5kg phthalic anhydride, 5.5kg phenylformic acid, 4.0kg dimethylbenzene, 22kg acetone and 0.12kg dispersion agent; Its preparation method is with embodiment 1.
The production method of described matte varnish is with embodiment 1.
In above-mentioned three embodiments, the EFKA-4010 dispersion agent that described dispersion agent adopts the holy high chemical Science and Technology Ltd. in Guangzhou to produce; The EFKA-2020 defoamer that described defoamer adopts the holy high chemical Science and Technology Ltd. in Guangzhou to produce; The flatting silica A360 that described flatting silica adopts Loudi City Hong Sheng Chemical Co., Ltd. to manufacture.
By carrying out Performance Detection to above-described embodiment gained clear finish, property indices sees the following form:
As can be seen from the above table, matte varnish finish fineness≤25 μm of the present invention, quick levelling after spraying, paint film is full, good hand touch, and hardness is all at more than 2H, scratch resistance capability is strong, strong covering power, property indices is all higher than GB-P-R-010C, and over-all properties is apparently higher than the matte varnish product on existing market.
What finally illustrate is, above embodiment is only in order to illustrate technical scheme of the present invention and unrestricted, although with reference to preferred embodiment to invention has been detailed description, those of ordinary skill in the art is to be understood that, can modify to technical scheme of the present invention or equivalent replacement, and not departing from aim and the scope of technical solution of the present invention, it all should be encompassed in the middle of right of the present invention.
Claims (5)
1. a matte varnish, is characterized in that: composed of the following components by weight: modified alkyd resin 71.5-72.5, dimethylbenzene 4.8-5.3, N-BUTYL ACETATE 4.6-5.0, dispersion agent 0.15-0.25, defoamer 0.10-0.20, wilkinite 3.8-4.2, flatting silica 4.8-5.1, nitro-cotton liquid 3.6-4.2, pimelinketone 1.8-2.4, flow agent 0.28-0.40, ethylene glycol ether acetate 1.8-2.1, siccative 0.15-0.25; Wherein, described flow agent by weight part be 0.08-0.10 organically-modified silica alkane and weight part be 0.20-0.30 polyether-modified polydimethylsiloxane mix;
Described modified alkyd resin is made up of 20-25 parts of vegetable oil acids, 15-18 parts of glycerine, 5-6 parts of tetramethylolmethanes, 10-15 parts of terephthalic acids, 0.1-0.15 part of Hypophosporous Acid, 50,3-4 parts of phthalic anhydrides, 5-6 parts of phenylformic acid, 3.5-4.5 parts of dimethylbenzene, 20-25 parts of acetone and 0.1-0.15 part of dispersion agent by weight, its preparation method is: by vegetable oil acid, glycerine, tetramethylolmethane, after terephthalic acid and Hypophosporous Acid, 50 drop into reactor, rare gas element is passed in reactor, heating, start to stir after being warming up to 90 DEG C, and continue to be warmed up to 200-210 DEG C, constant temperature leaves standstill 40-50 minutes, then rapid temperature increases to 240-250 DEG C, constant temperature is to the complete transparent rear rapid cooling of reaction solution, phthalic anhydride is dropped into when being down in 190 DEG C of backward reactors, phenylformic acid and dimethylbenzene, again be warming up to 200-205 DEG C of refuxing esterification and keep constant temperature 30-45 minutes, then less than 150 DEG C are cooled to, add acetone and dispersion agent, room temperature is naturally cooled to after stirring.
2. matte varnish according to claim 1, is characterized in that: composed of the following components by weight: modified alkyd resin 72, dimethylbenzene 5, N-BUTYL ACETATE 5, dispersion agent 0.2, defoamer 0.15, wilkinite 4.0, flatting silica 5.0, nitro-cotton liquid 4.0, pimelinketone 2.0, flow agent 0.35, ethylene glycol ether acetate 2.0, siccative 0.2.
3. matte varnish according to claim 1, is characterized in that: described nitro-cotton liquid is 1/4 nitro-cotton liquid.
4. matte varnish according to claim 1, is characterized in that: described siccative is dibutyltin dilaurate.
5. a preparation method for matte varnish described in any one of claim 1-4, is characterized in that: comprise the following steps:
A, for subsequent use by described formula feeding;
B, pour modified alkyd resin and dimethylbenzene into mixing machine, with the speed blending dispersion 15-20 minutes of 800 revs/min;
C, maintenance rotating speed are constant, add N-BUTYL ACETATE successively in order, dispersion agent, defoamer, wilkinite, flatting silica, nitro-cotton liquid, pimelinketone, flow agent, ethylene glycol ether acetate and siccative;
D, the speed blending dispersion 15-20 minutes then continuing with 800 revs/min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310023169.4A CN103102775B (en) | 2013-01-22 | 2013-01-22 | Low-gloss clear finishing coat and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310023169.4A CN103102775B (en) | 2013-01-22 | 2013-01-22 | Low-gloss clear finishing coat and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103102775A CN103102775A (en) | 2013-05-15 |
| CN103102775B true CN103102775B (en) | 2015-04-22 |
Family
ID=48310991
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310023169.4A Expired - Fee Related CN103102775B (en) | 2013-01-22 | 2013-01-22 | Low-gloss clear finishing coat and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103102775B (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104387933A (en) * | 2014-11-07 | 2015-03-04 | 南宁市老永淳红木家具厂 | Mahogany primer and preparation method thereof |
| CN104479526A (en) * | 2014-12-09 | 2015-04-01 | 三棵树涂料股份有限公司 | Fast-drying polyurethane primer used in winter and preparation method of fast-drying polyurethane primer |
| CN105295682A (en) * | 2015-11-24 | 2016-02-03 | 安徽旺家源门业有限公司 | Alkyd paint for door and preparation method of alkyd paint |
| CN106893464A (en) * | 2017-03-03 | 2017-06-27 | 肇庆市哈力化工有限公司 | A kind of plastic roller coating dumb light paint and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101962511A (en) * | 2010-10-25 | 2011-02-02 | 江苏冠军涂料科技集团有限公司 | Novel polyurethane white primer for wooden ware protection |
| CN101967344A (en) * | 2010-10-25 | 2011-02-09 | 江苏冠军涂料科技集团有限公司 | Novel transparent semi-matte polyurethane varnish used for woodenware protection |
| CN102051110A (en) * | 2010-12-14 | 2011-05-11 | 惠州市长润发涂料有限公司 | Alkyd resin for wood lacquer and preparation method thereof |
| CN102816510A (en) * | 2012-08-10 | 2012-12-12 | 三棵树涂料股份有限公司 | Hand-sweeping PU transparent priming paint used in furniture factory |
-
2013
- 2013-01-22 CN CN201310023169.4A patent/CN103102775B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101962511A (en) * | 2010-10-25 | 2011-02-02 | 江苏冠军涂料科技集团有限公司 | Novel polyurethane white primer for wooden ware protection |
| CN101967344A (en) * | 2010-10-25 | 2011-02-09 | 江苏冠军涂料科技集团有限公司 | Novel transparent semi-matte polyurethane varnish used for woodenware protection |
| CN102051110A (en) * | 2010-12-14 | 2011-05-11 | 惠州市长润发涂料有限公司 | Alkyd resin for wood lacquer and preparation method thereof |
| CN102816510A (en) * | 2012-08-10 | 2012-12-12 | 三棵树涂料股份有限公司 | Hand-sweeping PU transparent priming paint used in furniture factory |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103102775A (en) | 2013-05-15 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102719181B (en) | Priming paint with absorption resistance, preparation method and application | |
| CN103102775B (en) | Low-gloss clear finishing coat and preparation method thereof | |
| CN102229779B (en) | UV (Ultraviolent) deglossing paint and preparation method thereof | |
| CN102850916B (en) | Unsaturated polyester prime coat and preparation method thereof | |
| CN101638544A (en) | Coating for forming flexible imitation marble facing and preparation method thereof | |
| CN110540783B (en) | Matte water-in-water base paint, preparation method and matte water-in-water coating | |
| CN103937402A (en) | scratch resistant polyurethane woodenware glossy black finish paint | |
| CN103396725A (en) | Simulated copper coating and production process thereof | |
| CN103102783B (en) | 30%-glossiness varnish and preparation method thereof | |
| CN103937400B (en) | A kind of preparation method of scratch resistance anti-yellowing polyurethane woodenware Brilliant white paint | |
| CN103102777B (en) | Anti-yellowing quinary spectral white finish and preparation method thereof | |
| CN107400455A (en) | A kind of thermal transfer UV mould releases and preparation method thereof | |
| CN103102784B (en) | Red wood primer and preparation method thereof | |
| CN103102782B (en) | Anti-yellowing brightening white finish and preparation method thereof | |
| CN103102779B (en) | High-grade and high-firmness transparent primer and preparation method thereof | |
| CN105316948A (en) | Water-based skin-feeling treating agent for synthetic leather and preparation method thereof | |
| CN103102769B (en) | A kind of High-clarity transparent primer and preparation method thereof | |
| CN103102781B (en) | Ultra-bright crystal varnish and preparation method thereof | |
| CN103102778B (en) | Transparent solid-wood filling primer and preparation method thereof | |
| CN103102776B (en) | 70%-glossiness varnish and preparation method thereof | |
| CN105421076A (en) | Aqueous high-gloss gloss oil used for artificial leather and preparation method thereof | |
| CN103102780B (en) | High-grade crystal and transparent primer and preparation method thereof | |
| CN103360887B (en) | A kind of high spreading floating coating and preparation method thereof | |
| CN104231903A (en) | Preparation method of non-benzene odor-less type scratch-resistant polyurethane woodware light white finish | |
| CN103740239A (en) | PE (polyethylene) true-color paint |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CP03 | Change of name, title or address | ||
| CP03 | Change of name, title or address |
Address after: 400 000 District B of Zhaojia Industrial Park, Kaizhou District, Chongqing Patentee after: CHONGQING PINSHENG NEW MATERIAL CO.,LTD. Address before: 405400 Zhaojia Industrial Park Area B, Kaixian County, Chongqing Patentee before: CHONGQING PINSHENG PAINT Co.,Ltd. |
|
| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20150422 |