CN103102775A - Low-gloss clear finishing coat and preparation method thereof - Google Patents
Low-gloss clear finishing coat and preparation method thereof Download PDFInfo
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- CN103102775A CN103102775A CN2013100231694A CN201310023169A CN103102775A CN 103102775 A CN103102775 A CN 103102775A CN 2013100231694 A CN2013100231694 A CN 2013100231694A CN 201310023169 A CN201310023169 A CN 201310023169A CN 103102775 A CN103102775 A CN 103102775A
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- dimethylbenzene
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- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims abstract description 38
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 36
- DKPFZGUDAPQIHT-UHFFFAOYSA-N butyl acetate Chemical compound CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 claims abstract description 22
- 229920000180 alkyd Polymers 0.000 claims abstract description 16
- 229920000742 Cotton Polymers 0.000 claims abstract description 15
- 239000007788 liquid Substances 0.000 claims abstract description 15
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 claims abstract description 12
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims abstract description 11
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 30
- 239000006185 dispersion Substances 0.000 claims description 26
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 24
- 239000002966 varnish Substances 0.000 claims description 22
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 16
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 16
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 claims description 16
- 239000002253 acid Substances 0.000 claims description 16
- 239000013530 defoamer Substances 0.000 claims description 12
- 239000000377 silicon dioxide Substances 0.000 claims description 12
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 claims description 10
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 10
- -1 organically-modified silica alkane Chemical class 0.000 claims description 10
- 238000002156 mixing Methods 0.000 claims description 9
- 238000010792 warming Methods 0.000 claims description 9
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 claims description 8
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 claims description 8
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 claims description 8
- 235000011187 glycerol Nutrition 0.000 claims description 8
- 229940059574 pentaerithrityl Drugs 0.000 claims description 8
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 claims description 8
- 235000015112 vegetable and seed oil Nutrition 0.000 claims description 8
- 239000008158 vegetable oil Substances 0.000 claims description 8
- 238000001816 cooling Methods 0.000 claims description 6
- 239000012467 final product Substances 0.000 claims description 6
- 238000003756 stirring Methods 0.000 claims description 6
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical group CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 claims description 5
- 239000012975 dibutyltin dilaurate Substances 0.000 claims description 5
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 5
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 5
- 238000006243 chemical reaction Methods 0.000 claims description 3
- 230000032050 esterification Effects 0.000 claims description 3
- 238000005886 esterification reaction Methods 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 3
- 239000002023 wood Substances 0.000 abstract description 4
- SVONRAPFKPVNKG-UHFFFAOYSA-N 2-ethoxyethyl acetate Chemical compound CCOCCOC(C)=O SVONRAPFKPVNKG-UHFFFAOYSA-N 0.000 abstract 1
- 239000002518 antifoaming agent Substances 0.000 abstract 1
- 229910000278 bentonite Inorganic materials 0.000 abstract 1
- 239000000440 bentonite Substances 0.000 abstract 1
- 230000008033 biological extinction Effects 0.000 abstract 1
- 239000002270 dispersing agent Substances 0.000 abstract 1
- 239000004615 ingredient Substances 0.000 abstract 1
- 239000000843 powder Substances 0.000 abstract 1
- 230000002035 prolonged effect Effects 0.000 abstract 1
- 238000006748 scratching Methods 0.000 abstract 1
- 239000003973 paint Substances 0.000 description 7
- 238000005516 engineering process Methods 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- 230000000007 visual effect Effects 0.000 description 3
- 230000003245 working effect Effects 0.000 description 3
- 238000005507 spraying Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000004922 lacquer Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000000047 product Substances 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention discloses a low-gloss clear finishing coat. The low-gloss clear finishing coat comprises the following components in parts by weight: 71.5-72.5 parts of modified alkyd resin, 4.8-5.3 parts of dimethylbenzene, 4.6-5.0 parts of n-butyl acetate, 0.15-0.25 part of dispersing agent, 0.10-0.20 part of antifoaming agent, 3.8-4.2 parts of bentonite, 4.8-5.1 parts of extinction powder, 3.6-4.2 parts of nitro-cotton liquid, 1.8-2.4 parts of cyclohexanone, 0.28-0.40 part of flatting agent, 1.8-2.1 parts of ethylene glycol monoethyl ether acetate and 0.15-0.25 part of dryer. The hardness of the low-gloss clear finishing coat obtained by adopting the special ingredients and the preparation method is twice more than that of the common low-gloss clear finishing coat, the anti-scratching capacity is strong and the service life is greatly prolonged. Meanwhile, the other the other performances also completely satisfy the standards, and the hand feeling is good, and so the low-gloss clear finishing coat is applicable to the decorative field of the solid-wood furniture.
Description
Technical field
The present invention relates to a kind of paint and preparation method thereof, particularly a kind of matte varnish and preparation method thereof.
Background technology
Existing furniture generally adopts solid wood or imitative solid wood material to make, and its surface adopts paint as topcoating usually, and outermost layer is by spraying high-transparency varnish to strengthen its luminance brightness and slickness, aesthetic property and good waterproof performance.But various furniture in use can artificially be scratched usually, cause the variation such as sight and water-repellancy, and shorten work-ing life.In order to solve this shortcoming of clear lacquer, the dumb light paint has appearred then, and the dumb light paint has soft visual effect and good feel is extensively favored.But there is a general shortcoming in existing dumb light paint, is exactly that hardness is lower, easily is scratched.And use for a long time and rub after can polish gradually, cause glossiness and feel obviously inconsistent, affect attractive in appearance.
For above-mentioned deficiency, be badly in need of a kind of matte varnish that can improve its hardness of development, make its scratch resistance, wear-resisting, long service life does not affect its soft visual effect and good feel simultaneously.
Summary of the invention
In view of this, one of purpose of the present invention is to provide a kind of matte varnish, makes its scratch resistance, and is wear-resisting, greatly extends its work-ing life under normal service condition, do not affect its soft visual effect and good feel simultaneously.
One of purpose of the present invention realizes by following technique means: a kind of matte varnish, and composed of the following components by weight: modified alkyd resin 71.5-72.5, dimethylbenzene 4.8-5.3, N-BUTYL ACETATE 4.6-5.0, dispersion agent 0.15-0.25, defoamer 0.10-0.20, wilkinite 3.8-4.2, flatting silica 4.8-5.1, nitro-cotton liquid 3.6-4.2, pimelinketone 1.8-2.4, flow agent 0.28-0.40, ethylene glycol ether acetate 1.8-2.1, siccative 0.15-0.25;
described modified alkyd resin is comprised of 20-25 part vegetable oil acid, 15-18 part glycerine, 5-6 part tetramethylolmethane, 10-15 part terephthalic acid, 0.1-0.15 part Hypophosporous Acid, 50,3-4 part phthalic anhydride, 5-6 part phenylformic acid, 3.5-4.5 part dimethylbenzene, 20-25 part acetone and 0.1-0.15 part dispersion agent by weight, its preparation method is: with vegetable oil acid, glycerine, tetramethylolmethane, after terephthalic acid and Hypophosporous Acid, 50 drop into reactor, lead to rare gas element in reactor, heating, begin to stir after being warming up to 90 ℃, and continue to be warmed up to 200-210 ℃, the standing 40-50 of constant temperature minute, then be warming up to rapidly 240-250 ℃, constant temperature is to reaction solution transparent rear rapid cooling fully, drop into phthalic anhydride in being down to 190 ℃ of backward reactors, phenylformic acid and dimethylbenzene, again be warming up to 200-205 ℃ of backflow esterification and be incubated 30-45 minute, then be cooled to below 150 ℃, add acetone and dispersion agent, naturally cooling to room temperature after stirring gets final product.。
Further, composed of the following components by weight: modified alkyd resin 72, dimethylbenzene 5, N-BUTYL ACETATE 5, dispersion agent 0.2, defoamer 0.15, wilkinite 4.0, flatting silica 5.0, nitro-cotton liquid 4.0, pimelinketone 2.0, flow agent 0.35, ethylene glycol ether acetate 2.0, siccative 0.2.
Further, described flow agent is that the organically-modified silica alkane of 0.08-0.10 and polyether-modified polydimethylsiloxane that weight part is 0.20-0.30 mix by weight part.
Further, described nitro-cotton liquid is 1/4 nitro-cotton liquid;
Further, described siccative is dibutyltin dilaurate.
Two of purpose of the present invention is achieved through the following technical solutions: a kind of preparation method of matte varnish comprises the following steps:
A, standby by above-mentioned formula feeding;
B, pour modified alkyd resin and dimethylbenzene into mixing machine, with the speed blending dispersion of 800 rev/mins 15-20 minute;
C, keep rotating speed constant, add successively in order N-BUTYL ACETATE, dispersion agent, defoamer, wilkinite, flatting silica, nitro-cotton liquid, pimelinketone, flow agent, ethylene glycol ether acetate and siccative;
D, the speed blending dispersion that then continues with 800 rev/mins got final product in 15-20 minute.
Beneficial effect of the present invention: adopt the matte varnish of special formulation of the present invention and preparation method's gained, its hardness is existing more than 2 times of common matte varnish hardness, and scratch resistance is very competent, has greatly extended its work-ing life; Other performances of while are complete conformance with standard also, and feel is better, is applicable to the decoration field of solid wood furniture.
Embodiment
Example 1
A kind of matte varnish, composed of the following components: modified alkyd resin 71.5kg, dimethylbenzene 5.3kg, N-BUTYL ACETATE 4.6kg, dispersion agent 0.25kg, defoamer 0.10kg, wilkinite 4.2kg, flatting silica 4.8kg, 1/4 nitro-cotton liquid 4.2kg, pimelinketone 1.8kg, flow agent 0.40kg, ethylene glycol ether acetate 1.8kg, siccative 0.25kg; In the present embodiment, described flow agent is mixed by the organically-modified silica alkane of 0.10kg and the polyether-modified polydimethylsiloxane of 0.30kg, and described siccative is dibutyltin dilaurate;
described modified alkyd resin is comprised of 20kg vegetable oil acid, 18kg glycerine, 5kg tetramethylolmethane, 15kg terephthalic acid, 0.1kg Hypophosporous Acid, 50,4kg phthalic anhydride, 5kg phenylformic acid, 4.5kg dimethylbenzene, 20kg acetone and 0.15kg dispersion agent, its preparation method is: with vegetable oil acid, glycerine, tetramethylolmethane, after terephthalic acid and Hypophosporous Acid, 50 drop into reactor, lead to rare gas element in reactor, heating, begin to stir after being warming up to 90 ℃, and continue to be warmed up to 200-210 ℃, the standing 40-50 of constant temperature minute, then be warming up to rapidly 240-250 ℃, constant temperature is to reaction solution transparent rear rapid cooling fully, drop into phthalic anhydride in being down to 190 ℃ of backward reactors, phenylformic acid and dimethylbenzene, again be warming up to 200-205 ℃ of backflow esterification and be incubated 30-45 minute, then be cooled to below 150 ℃, add acetone and dispersion agent, naturally cooling to room temperature after stirring gets final product.
The concrete production method of the described light of anti-xanthochromia white finish paint is: pour modified alkyd resin and dimethylbenzene into mixing machine, with the speed blending dispersion of 800 rev/mins 15-20 minute; Keep rotating speed constant, add successively in order N-BUTYL ACETATE, dispersion agent, defoamer, wilkinite, flatting silica, nitro-cotton liquid, pimelinketone, flow agent, ethylene glycol ether acetate and siccative; Then the speed blending dispersion that continues with 800 rev/mins got final product in 15-20 minute.
Example 2
A kind of matte varnish, composed of the following components: modified alkyd resin 72.5kg, dimethylbenzene 4.8kg, N-BUTYL ACETATE 4.8kg, dispersion agent 0.15kg, defoamer 0.20kg, wilkinite 3.8kg, flatting silica 5.1kg, 1/4 nitro-cotton liquid 3.6kg, pimelinketone 2.4kg, flow agent 0.28kg, ethylene glycol ether acetate 2.1kg, siccative 0.15kg; In the present embodiment, described flow agent is mixed by the organically-modified silica alkane of 0.20kg and the polyether-modified polydimethylsiloxane of 0.08kg, and described siccative is dibutyltin dilaurate;
Described modified alkyd resin is comprised of 25kg vegetable oil acid, 15kg glycerine, 6kg tetramethylolmethane, 10kg terephthalic acid, 0.15kg Hypophosporous Acid, 50,3kg phthalic anhydride, 6kg phenylformic acid, 3.5kg dimethylbenzene, 25kg acetone and 0.1kg dispersion agent; Its preparation method is with embodiment 1.
The production method of described matte varnish is with embodiment 1.
Example 3
A kind of matte varnish, composed of the following components: modified alkyd resin 72kg, dimethylbenzene 5kg, N-BUTYL ACETATE 5kg, dispersion agent 0.2kg defoamer 0.15kg, wilkinite 4.0kg, flatting silica 5.0kg, 1/4 nitro-cotton liquid 4.0kg, pimelinketone 2.0kg, flow agent 0.35kg; In the present embodiment, described flow agent is mixed by the organically-modified silica alkane of 0.09kg and the polyether-modified polydimethylsiloxane of 0.26kg, ethylene glycol ether acetate 2.0kg, and siccative 0.2kg, described siccative are dibutyltin dilaurate.
Described modified alkyd resin is comprised of 23kg vegetable oil acid, 16kg glycerine, 5.5kg tetramethylolmethane, 12kg terephthalic acid, 0.12kg Hypophosporous Acid, 50,3.5kg phthalic anhydride, 5.5kg phenylformic acid, 4.0kg dimethylbenzene, 22kg acetone and 0.12kg dispersion agent; Its preparation method is with embodiment 1.
The production method of described matte varnish is with embodiment 1.
In above-mentioned three embodiment, the EFKA-4010 dispersion agent that described dispersion agent adopts the holy high chemical Science and Technology Ltd. in Guangzhou to produce; The EFKA-2020 defoamer that described defoamer adopts the holy high chemical Science and Technology Ltd. in Guangzhou to produce; Described flatting silica adopts the Loudi City letter to contain the flatting silica A360 that Chemical Co., Ltd. is made.
By above-described embodiment gained clear finish is carried out Performance Detection, property indices sees the following form:
As can be seen from the above table, matte varnish finish fineness of the present invention≤25 μ m, quick levelling after spraying, paint film is full, good hand touch, and also hardness is all more than 2H, the scratch resistance ability is strong, strong covering power, property indices be all higher than GB-P-R-010C, the matte varnish product of over-all properties on the existing market.
Explanation is at last, above embodiment is only unrestricted in order to technical scheme of the present invention to be described, although with reference to preferred embodiment, the present invention is had been described in detail, those of ordinary skill in the art is to be understood that, can modify or be equal to replacement technical scheme of the present invention, and not breaking away from aim and the scope of technical solution of the present invention, it all should be encompassed in the middle of claim scope of the present invention.
Claims (6)
1. a matte varnish, is characterized in that: composed of the following components by weight: modified alkyd resin 71.5-72.5, dimethylbenzene 4.8-5.3, N-BUTYL ACETATE 4.6-5.0, dispersion agent 0.15-0.25, defoamer 0.10-0.20, wilkinite 3.8-4.2, flatting silica 4.8-5.1, nitro-cotton liquid 3.6-4.2, pimelinketone 1.8-2.4, flow agent 0.28-0.40, ethylene glycol ether acetate 1.8-2.1, siccative 0.15-0.25;
described modified alkyd resin is comprised of 20-25 part vegetable oil acid, 15-18 part glycerine, 5-6 part tetramethylolmethane, 10-15 part terephthalic acid, 0.1-0.15 part Hypophosporous Acid, 50,3-4 part phthalic anhydride, 5-6 part phenylformic acid, 3.5-4.5 part dimethylbenzene, 20-25 part acetone and 0.1-0.15 part dispersion agent by weight, its preparation method is: with vegetable oil acid, glycerine, tetramethylolmethane, after terephthalic acid and Hypophosporous Acid, 50 drop into reactor, pass into rare gas element in reactor, heating, begin to stir after being warming up to 90 ℃, and continue to be warmed up to 200-210 ℃, the standing 40-50 of constant temperature minute, then be warming up to rapidly 240-250 ℃, constant temperature is to reaction solution transparent rear rapid cooling fully, drop into phthalic anhydride in being down to 190 ℃ of backward reactors, phenylformic acid and dimethylbenzene, again be warming up to 200-205 ℃ of backflow esterification and kept constant temperature 30-45 minute, then be cooled to below 150 ℃, add acetone and dispersion agent, naturally cooling to room temperature after stirring gets final product.
2. matte varnish according to claim 1, is characterized in that: composed of the following components by weight: modified alkyd resin 72, dimethylbenzene 5, N-BUTYL ACETATE 5, dispersion agent 0.2, defoamer 0.15, wilkinite 4.0, flatting silica 5.0, nitro-cotton liquid 4.0, pimelinketone 2.0, flow agent 0.35, ethylene glycol ether acetate 2.0, siccative 0.2.
3. matte varnish according to claim 1 is characterized in that: described flow agent is that the organically-modified silica alkane of 0.08-0.10 and polyether-modified polydimethylsiloxane that weight part is 0.20-0.30 mix by weight part.
4. matte varnish according to claim 1, it is characterized in that: described nitro-cotton liquid is 1/4 nitro-cotton liquid.
5. matte varnish according to claim 1, it is characterized in that: described siccative is dibutyltin dilaurate.
6. the preparation method of the described matte varnish of claim 1-5 any one is characterized in that: comprise the following steps:
A, standby by described formula feeding;
B, pour modified alkyd resin and dimethylbenzene into mixing machine, with the speed blending dispersion of 800 rev/mins 15-20 minute;
C, keep rotating speed constant, add successively in order N-BUTYL ACETATE, dispersion agent, defoamer, wilkinite, flatting silica, nitro-cotton liquid, pimelinketone, flow agent, ethylene glycol ether acetate and siccative;
D, the speed blending dispersion that then continues with 800 rev/mins got final product in 15-20 minute.
Priority Applications (1)
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CN201310023169.4A CN103102775B (en) | 2013-01-22 | 2013-01-22 | Low-gloss clear finishing coat and preparation method thereof |
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CN201310023169.4A CN103102775B (en) | 2013-01-22 | 2013-01-22 | Low-gloss clear finishing coat and preparation method thereof |
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CN103102775A true CN103102775A (en) | 2013-05-15 |
CN103102775B CN103102775B (en) | 2015-04-22 |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104387933A (en) * | 2014-11-07 | 2015-03-04 | 南宁市老永淳红木家具厂 | Mahogany primer and preparation method thereof |
CN104479526A (en) * | 2014-12-09 | 2015-04-01 | 三棵树涂料股份有限公司 | Fast-drying polyurethane primer used in winter and preparation method of fast-drying polyurethane primer |
CN105295682A (en) * | 2015-11-24 | 2016-02-03 | 安徽旺家源门业有限公司 | Alkyd paint for door and preparation method of alkyd paint |
CN106893464A (en) * | 2017-03-03 | 2017-06-27 | 肇庆市哈力化工有限公司 | A kind of plastic roller coating dumb light paint and preparation method thereof |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101962511A (en) * | 2010-10-25 | 2011-02-02 | 江苏冠军涂料科技集团有限公司 | Novel polyurethane white primer for wooden ware protection |
CN101967344A (en) * | 2010-10-25 | 2011-02-09 | 江苏冠军涂料科技集团有限公司 | Novel transparent semi-matte polyurethane varnish used for woodenware protection |
CN102051110A (en) * | 2010-12-14 | 2011-05-11 | 惠州市长润发涂料有限公司 | Alkyd resin for wood lacquer and preparation method thereof |
CN102816510A (en) * | 2012-08-10 | 2012-12-12 | 三棵树涂料股份有限公司 | Hand-sweeping PU transparent priming paint used in furniture factory |
-
2013
- 2013-01-22 CN CN201310023169.4A patent/CN103102775B/en not_active Expired - Fee Related
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101962511A (en) * | 2010-10-25 | 2011-02-02 | 江苏冠军涂料科技集团有限公司 | Novel polyurethane white primer for wooden ware protection |
CN101967344A (en) * | 2010-10-25 | 2011-02-09 | 江苏冠军涂料科技集团有限公司 | Novel transparent semi-matte polyurethane varnish used for woodenware protection |
CN102051110A (en) * | 2010-12-14 | 2011-05-11 | 惠州市长润发涂料有限公司 | Alkyd resin for wood lacquer and preparation method thereof |
CN102816510A (en) * | 2012-08-10 | 2012-12-12 | 三棵树涂料股份有限公司 | Hand-sweeping PU transparent priming paint used in furniture factory |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104387933A (en) * | 2014-11-07 | 2015-03-04 | 南宁市老永淳红木家具厂 | Mahogany primer and preparation method thereof |
CN104479526A (en) * | 2014-12-09 | 2015-04-01 | 三棵树涂料股份有限公司 | Fast-drying polyurethane primer used in winter and preparation method of fast-drying polyurethane primer |
CN105295682A (en) * | 2015-11-24 | 2016-02-03 | 安徽旺家源门业有限公司 | Alkyd paint for door and preparation method of alkyd paint |
CN106893464A (en) * | 2017-03-03 | 2017-06-27 | 肇庆市哈力化工有限公司 | A kind of plastic roller coating dumb light paint and preparation method thereof |
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