CN107393794B - A kind of gas-cluster ion sources production method and device - Google Patents

A kind of gas-cluster ion sources production method and device Download PDF

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Publication number
CN107393794B
CN107393794B CN201710664910.3A CN201710664910A CN107393794B CN 107393794 B CN107393794 B CN 107393794B CN 201710664910 A CN201710664910 A CN 201710664910A CN 107393794 B CN107393794 B CN 107393794B
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cluster
gas flow
pulsed
ion sources
dissociator
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CN107393794A (en
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瓦西里·帕里诺维奇
曾晓梅
付德君
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Wuxi New Feige Technology Co ltd
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Shenzhen River Haihang Nano Technology Co Ltd
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J37/00Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
    • H01J37/02Details
    • H01J37/04Arrangements of electrodes and associated parts for generating or controlling the discharge, e.g. electron-optical arrangement, ion-optical arrangement
    • H01J37/08Ion sources; Ion guns
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J27/00Ion beam tubes
    • H01J27/02Ion sources; Ion guns
    • H01J27/026Cluster ion sources
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01JELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS
    • H01J37/00Discharge tubes with provision for introducing objects or material to be exposed to the discharge, e.g. for the purpose of examination or processing thereof
    • H01J37/30Electron-beam or ion-beam tubes for localised treatment of objects
    • H01J37/317Electron-beam or ion-beam tubes for localised treatment of objects for changing properties of the objects or for applying thin layers thereon, e.g. for ion implantation
    • H01J37/3171Electron-beam or ion-beam tubes for localised treatment of objects for changing properties of the objects or for applying thin layers thereon, e.g. for ion implantation for ion implantation

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  • Chemical & Material Sciences (AREA)
  • Analytical Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Combustion & Propulsion (AREA)
  • Physical Vapour Deposition (AREA)
  • Particle Accelerators (AREA)
  • Electron Sources, Ion Sources (AREA)

Abstract

The present invention provides a kind of gas-cluster ion sources production methods, it is controlled using pulse control valve and sprays pulsed gas flow beam, pulsed gas flow beam passes through beam splitter, neutral cluster particle and part is monatomic passes through beam splitter, pulsed gas flow beam carries out ionization by electro-dissociator, pulsed gas flow beam continues through extraction electrode, initial acceleration is obtained in extraction electrode and is converged forms convergent conical air flow stream, conical air flow stream passes through E type permanent magnet after continuing through accelerator and lens, forms cluster ions beam.Invention also provides a kind of gas-cluster ion sources generation devices, including pulse control valve and the beam splitter being sequentially arranged along pulsed air flow stream emission direction, electro-dissociator, extraction electrode, accelerator, lens and E type permanent magnet.The present invention can make neutral cluster ionize in the collision with electronics under normal temperature and certain air pressure, form gas-cluster ion, after the extraction electrode the effects of under, pool cluster ions beam.

Description

A kind of gas-cluster ion sources production method and device
Technical field
The present invention relates to a kind of gas-cluster ion sources production method and devices, belong to ion implantation device technical field.
Background technique
Ion implantation technique is the semiconductor doping and process for modifying surface that eighties of last century grows up, and passes through change Material surface ingredient, structure, and then optimize material surface property, or even obtain certain new excellent properties.It is i.e. certain with having The ion beam bombardment material of energy and dosage, ion beam due to by atom, molecule in material shock or other are physico Effect gradually loses energy, reduces speed, eventually settles at the position not far apart from material surface.But common ion note Enter to use monatomic ion, there are channelling effects in injection process, can be because when monatomic ion is injected along the crystal orientation of crystal It is incident on very deep position for less collision occurs with lattice atoms, trailing phenomenon is generated, junction depth is caused to increase.Channel effect The presence answered hinders the modified desired realization on an ultra shallow surface.Solution is first is that reduce injection ion energy, or change Incident inclination angle.Second is that using multi-atomic ion or cluster ions, therefore cluster ions beam technology is paid attention to.
Gas cluster ion beam equipment can produce the multi-atomic ion that atomicity reaches thousands of or even up to ten thousand, but whole sets Standby very accurate complexity, needs the perfect cooperation of all parts that can just obtain expected results.And ion source is exactly core technology, from Component it is available whether be directly related to produced by cluster ions superiority and inferiority (energy, dosage), thus, it is necessary to design intense beam The ion source of stream, low energy.On the one hand it requires to generate sufficient amount of cluster particle, on the other hand to design the electronics of high current Rifle is allowed to sufficiently collide with cluster particle, makes cluster particle ionization, turn agglomerate ion beam.
Summary of the invention
In order to solve the deficiencies in the prior art, the present invention provides a kind of gas-cluster ion sources production method and device, Can be used for generating and accelerating thermoelectron, be adequately ionized neutral cluster particle, obtain cluster ions, then extraction pole (also Referred to as extraction electrode), accelerator and E type permanent magnet effect under, numerous cluster ions are gathered into cluster ions beam.
The present invention is that technical solution used by solving its technical problem is: providing a kind of gas-cluster ion sources generation Method, comprising the following steps:
(1) pulsed gas flow beam is sprayed using pulse control valve control, the pulsed gas flow beam includes two different Conical flow, one of conical flow are made of the monatomic of divergence expression, another conical flow is by concentrating on pulsed gas The neutral cluster particle of a fluid stream central axis is constituted;
(2) pulsed gas flow beam passes through beam splitter, and exclusive segment is monatomic, and neutral cluster particle and other part are monatomic Pass through beam splitter;
(3) pulsed gas flow beam passes through electro-dissociator, generates thermoelectron, the neutral cluster grain of pulsed gas flow beam in electro-dissociator Sub- ionization becomes cluster ions, and monatomic ionization is at monatomic ion;
(4) pulsed gas flow beam continues through extraction electrode, and initial acceleration is obtained in extraction electrode and convergence forms convergent circle Conical flow beam;
(5) conical air flow stream continue through accelerator and lens further speed up after by E type permanent magnet, by E When the magnetic field of type permanent magnet, the cluster ions of monatomic ion and atomicity less than or equal to 100 in conical air flow stream exist Deviate under the action of Loulun magnetism, cluster ions of the atomicity greater than 100 maintain original route to pass through magnetic field, form cluster ions Beam.
Invention also provides a kind of gas-cluster ion sources generation device based on the method, including for generating The pulse control valve of pulsed gas flow beam, and the beam splitter, the electro-dissociator, suction that are sequentially arranged along pulsed air flow stream emission direction Pole, accelerator, lens and E type permanent magnet.
The pulse control valve is equipped with ultrasonic nozzle and positioning and collimator apparatus.
The minimum-value aperture of the beam splitter is 1.4~2mm.
The beam splitter uses pure aluminum material, overlay coating Ni.
The electro-dissociator uses central axis and the consistent cylindrical stainless steel grid screen shell of pulsed gas flow beam emission direction, It is internally provided with two cathodes and an anode between described two cathodes, cathode uses tungsten wire, cylindrical stainless steel The both ends of grid screen shell pass through boron nitride insulating disc respectively and are connected with the diaphragm of ground connection.
Anode voltage is up to 40mA relative to the high 60~200V of cathode, anode current, and cathode current is up to 1.4A.
The extraction electrode is center axis and the consistent cylinder of pulsed gas flow beam emission direction, and electro-dissociator anode voltage is Uan When, extraction electrode institute making alive Uan–Uan/20。
The accelerator is made of the three-level electrostatic lenses arranged along pulsed air flow stream emission direction, in-between electrostatic Lens are added with negative voltage -7~12kV, other two electrostatic lenses ground connection.
The long 50mm of E type permanent magnet, is made of iron core and two magnetic poles, and the center magnetic field is 50~150mT.
The present invention is based on beneficial effects possessed by its technical solution to be:
(1) gas-cluster ion sources production method of the invention can be realized under normal temperature and certain air pressure, so that By the neutral cluster of conical nozzle, ionized in the collision with electronics, formed gas-cluster ion, after extraction electrode, plus Under fast device and the effect of E type permanent magnet, cluster ions beam is pooled;
(2) in gas-cluster ion sources generation device of the invention, electro-dissociator cathode material is tungsten wire, for radiating thermoelectricity Son, thermoelectron from cathode reach anode during with cluster particle encounter, so that it is ionized into cluster ions, entire electro-dissociator by Cylindrical stainless steel grid screen package, grid screen can prevent thermoelectron from escaping, it made to come into full contact with cluster, and electro-dissociator both ends pass through nitridation Boron insulating disc is connected with the light bar of ground connection, and boron nitride insulating disc is for being isolated electro-dissociator and diaphragm, while sustainable anode, cathode With stainless steel grid screen;
(3) in gas-cluster ion sources generation device of the invention, extraction electrode is cylindrical, for converging cluster ions with shape At convergent conical ion beam;
(4) in gas-cluster ion sources generation device of the invention, the long 50mm of E type permanent magnet, by iron core and two Co- Sm magnetic pole is constituted, the center magnetic field about 150mT, plays mass separation according to Lorentz force magnet, monatomic ion with gently Cluster deviates, and weight cluster almost maintains original route to pass through magnetic field, finally pools cluster ions beam.
Detailed description of the invention
Fig. 1 is the structural schematic diagram of gas-cluster ion sources generation device of the invention.
In figure: 1- pulse control valve, 2- ultrasonic nozzle, 3- positioning and collimator apparatus, 4- cluster air-flow, the monatomic taper of 5- Air-flow, 6- beam splitter, 7- diaphragm, 8- pass through the pulsed gas flow beam of electro-dissociator, 9- electro-dissociator, 10- cylinder stainless steel grid screen Shell, 11- cathode, 12- anode, 13- the first boron nitride insulating disc, 14- the second boron nitride insulating disc, 15- extraction electrode, 16- accelerate Device, the first electrostatic lenses of 17-, the second electrostatic lenses of 18-, 19- third electrostatic lenses, 20-E type permanent magnet.
Specific embodiment
Present invention will be further explained below with reference to the attached drawings and examples.
The present invention provides a kind of gas-cluster ion sources production methods, comprising the following steps:
(1) pulsed gas flow beam is sprayed using pulse control valve control, the pulsed gas flow beam includes two different Conical flow, one of conical flow are made of the monatomic of divergence expression, another conical flow is by concentrating on pulsed gas The neutral cluster particle of a fluid stream central axis is constituted;
(2) pulsed gas flow beam passes through beam splitter, and exclusive segment is monatomic, and neutral cluster particle and other part are monatomic Pass through beam splitter;
(3) pulsed gas flow beam passes through electro-dissociator, generates thermoelectron, the neutral cluster grain of pulsed gas flow beam in electro-dissociator Sub- ionization becomes cluster ions, and monatomic ionization is at monatomic ion;
(4) pulsed gas flow beam continues through extraction electrode, and initial acceleration is obtained in extraction electrode and convergence forms convergent circle Conical flow beam;
(5) conical air flow stream continue through accelerator and lens further speed up after by E type permanent magnet, by E When the magnetic field of type permanent magnet, the cluster ions of monatomic ion and atomicity less than or equal to 100 in conical air flow stream exist Deviate under the action of Loulun magnetism, cluster ions of the atomicity greater than 100 maintain original route to pass through magnetic field, form cluster ions Beam.
Invention also provides a kind of gas-cluster ion sources generation device based on the method, referring to Fig.1, including For generating the pulse control valve 1 of pulsed gas flow beam, and the beam splitter being sequentially arranged along pulsed air flow stream emission direction 6, electro-dissociator 9, extraction electrode 15, accelerator, lens 16 and E type permanent magnet 20.
The pulse control valve 1 is equipped with ultrasonic nozzle 2 and positioning and collimator apparatus 3.
The minimum-value aperture of the beam splitter 6 is 1.4~2mm.
The beam splitter 6 uses pure aluminum material, overlay coating Ni.
The electro-dissociator 9 is using the consistent cylindrical stainless steel grid screen shell of central axis and pulsed gas flow beam emission direction 10, it is internally provided with two cathodes 11 and an anode 12 between described two cathodes 11, cathode 11 uses tungsten wire, circle The both ends of cylindrical stainless steel grid screen shell 10 pass through a boron nitride insulating disc respectively and are connected with the diaphragm 7 of ground connection, both ends difference For the first boron nitride insulating disc 13 and the second boron nitride insulating disc 14.
Anode voltage is relative to the high 60~200V of cathode, and for anode current maximum up to 40mA, cathode current maximum is reachable 1.4A。
The extraction electrode is center axis and the consistent cylinder of pulsed gas flow beam emission direction, and electro-dissociator anode voltage is Uan When, extraction electrode institute making alive Uan–Uan/20。
The lens use the three-level electrostatic lenses by arranging along pulsed air flow stream emission direction, are followed successively by first electrode 17, second electrode 18 and third electrode 19, first electrode be equipped with accelerator, in-between second electrode added with negative voltage -7~ 12kV, first electrode and second electrode are grounded.
The long 50mm of E type permanent magnet, is made of iron core and two magnetic poles, and the center magnetic field is 50~150mT.
The course of work of gas-cluster ion sources generation device are as follows:
(1) under normal temperature and certain air pressure (T=300K, Psource=1~10bar), pulse control valve control is utilized System sprays pulsed hyperbar air flow stream, and pulsed gas flow beam is tapered, can be divided into two parts, a portion distribution compared with Extensively, it is mainly made of monatomic, is monatomic conical flow 5, another part is distributed Relatively centralized, closer to central axis, serves as reasons Concentrate on the cluster air-flow 4 that the neutral cluster particle of pulsed gas flow beam center axis is constituted;
(2) pulsed gas flow beam passes through beam splitter 6, when air-flow enters beam splitter from the minimum of aperture, is only distributed concentration Cluster can just pass through, can exclusive segment it is monatomic, neutral cluster particle and other part are monatomic by beam splitter, By the cluster of beam splitter still can in cone, and with electro-dissociator center overlapping of axles;
(3) pulsed gas flow beam passes through electro-dissociator 9, and cathode material is tungsten wire in electro-dissociator, for radiating thermoelectron.Anode Voltage is relative to the high 60-200V of cathode, for accelerating thermoelectron until its energy reaches the ionization energy of cluster particle, thermoelectron from With cluster particle encounter during cathode arrival anode, it is made to be ionized into cluster ions;Anode current about 40mA, cathode current 1.4A.Entire electro-dissociator is wrapped up by cylindrical stainless steel grid screen, and grid screen can prevent thermoelectron from escaping, it is made to come into full contact with cluster; Electro-dissociator both ends are connected by boron nitride insulating disc with the light bar of ground connection, and boron nitride insulating disc is used to that electro-dissociator and diaphragm to be isolated, Supporting anodes, cathode and stainless steel grid screen simultaneously;The neutral cluster particle ionization of pulsed gas flow beam becomes cluster ions, Dan Yuan Sub- ionization is at monatomic ion;
(4) extraction electrode 15 is continued through by the pulsed gas flow beam 8 of electro-dissociator, initial acceleration is obtained in extraction electrode and converged Combinate form is at convergent conical air flow stream;
(5) conical air flow stream is continued through by E type permanent magnet after accelerator is further speeded up, permanent by E type The cluster ions (weight cluster) of monatomic ion and atomicity less than or equal to 100 when the magnetic field of magnet, in conical air flow stream Deviate under the action of Loulun magnetism, cluster ions (light cluster) of the atomicity greater than 100 maintain original route to pass through magnetic field, are formed Cluster ions beam.
A kind of gas-cluster ion sources production method and device provided by the invention, can be in normal temperature and certain air pressure Under so that ionize in the collision with electronics by the neutral cluster of conical nozzle, form gas-cluster ion, after Under extraction electrode, accelerator and the effect of E type permanent magnet, cluster ions beam is pooled.

Claims (9)

1. a kind of gas-cluster ion sources production method, it is characterised in that the following steps are included:
(1) pulsed gas flow beam is sprayed using pulse control valve control, the pulsed gas flow beam includes two different tapers Air-flow, one of conical flow are made of the monatomic of divergence expression, another conical flow is by concentrating on pulsed gas flow beam The neutral cluster particle of central axis is constituted;
(2) pulsed gas flow beam passes through beam splitter, and exclusive segment is monatomic, neutral cluster particle and other part is monatomic passes through Beam splitter;
(3) pulsed gas flow beam passes through electro-dissociator, generates thermoelectron in electro-dissociator, the neutral cluster particle of pulsed gas flow beam from Chemical conversion is cluster ions, and monatomic ionization is at monatomic ion;The electro-dissociator is sprayed using central axis and pulsed gas flow beam The consistent cylindrical stainless steel grid screen shell in direction is internally provided with two cathodes and one between described two cathodes Anode, cathode use tungsten wire, and the both ends of cylindrical stainless steel grid screen shell pass through the diaphragm of boron nitride insulating disc and ground connection respectively It is connected;
(4) pulsed gas flow beam continues through extraction electrode, and initial acceleration is obtained in extraction electrode and convergence forms convergent cone Air flow stream;
(5) conical air flow stream continue through accelerator and lens further speed up after by E type permanent magnet, forever by E type When the magnetic field of long magnet, the cluster ions of monatomic ion and atomicity less than or equal to 100 in conical air flow stream are in Lip river logical sequence Deviate under the action of magnetic force, cluster ions of the atomicity greater than 100 maintain original route to pass through magnetic field, form cluster ions beam.
2. a kind of gas-cluster ion sources generation device based on claim 1 the method, it is characterised in that: including for producing The pulse control valve of raw pulsed gas flow beam, and be sequentially arranged along pulsed air flow stream emission direction beam splitter, electro-dissociator, Extraction electrode, accelerator, lens and E type permanent magnet.
3. gas-cluster ion sources generation device according to claim 2, it is characterised in that: the pulse control valve is equipped with Ultrasonic nozzle and positioning and collimator apparatus.
4. gas-cluster ion sources generation device according to claim 2, it is characterised in that: the minimum aperture of the beam splitter Diameter is 1.4~2mm.
5. gas-cluster ion sources generation device according to claim 2, it is characterised in that: the beam splitter uses fine aluminium Material, overlay coating Ni.
6. gas-cluster ion sources generation device according to claim 2, it is characterised in that: the electro-dissociator uses center Axis and the consistent cylindrical stainless steel grid screen shell of pulsed gas flow beam emission direction, are internally provided with two cathodes and a position Anode between described two cathodes, cathode use tungsten wire, and the both ends of cylindrical stainless steel grid screen shell pass through nitridation respectively Boron insulating disc is connected with the diaphragm of ground connection.
7. gas-cluster ion sources generation device according to claim 6, it is characterised in that: anode voltage is relative to cathode High 60~200V, anode current are up to 40mA, and cathode current is up to 1.4A.
8. gas-cluster ion sources generation device according to claim 2, it is characterised in that: the extraction electrode be center axis with The consistent cylinder of pulsed gas flow beam emission direction, electro-dissociator anode voltage are UanWhen, extraction electrode institute making alive Uan–Uan/20。
9. gas-cluster ion sources generation device according to claim 2, it is characterised in that: the E type permanent magnet is long 50mm is made of iron core and two magnetic poles, and the center magnetic field is 50~150mT.
CN201710664910.3A 2017-08-07 2017-08-07 A kind of gas-cluster ion sources production method and device Active CN107393794B (en)

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CN109115660A (en) * 2018-08-23 2019-01-01 金华职业技术学院 A kind of particle imaging method
CN108972230B (en) * 2018-09-07 2020-11-27 中国工程物理研究院激光聚变研究中心 Optical element processing device and processing method
CN109413835A (en) * 2018-10-31 2019-03-01 宜昌后皇真空科技有限公司 A kind of method and device for the method generating transition metal positive ion beam
CN109786204B (en) * 2019-01-18 2021-01-26 武汉江海行纳米科技有限公司 Method for leading out ion beam current by using gas cluster sputtering target and ion source
CN113458876A (en) * 2021-06-21 2021-10-01 武汉大学深圳研究院 Cluster ion beam surface polishing method with cluster energy gradually reduced

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US20110240602A1 (en) * 2010-03-30 2011-10-06 Tel Epion Inc. High-voltage gas cluster ion beam (gcib) processing system
US10181402B2 (en) * 2010-08-23 2019-01-15 Exogenesis Corporation Method and apparatus for neutral beam processing based on gas cluster ion beam technology and articles produced thereby
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