CN107385907A - A kind of compounding finishing agent for being used to improve dacron fabric antistatic behaviour - Google Patents

A kind of compounding finishing agent for being used to improve dacron fabric antistatic behaviour Download PDF

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Publication number
CN107385907A
CN107385907A CN201710599585.7A CN201710599585A CN107385907A CN 107385907 A CN107385907 A CN 107385907A CN 201710599585 A CN201710599585 A CN 201710599585A CN 107385907 A CN107385907 A CN 107385907A
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parts
poly
finishing agent
5min
aspartic
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吴佳诚
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Anhui Hua Jinbai Sub Fiber Spinning Technology Co Ltd
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Anhui Hua Jinbai Sub Fiber Spinning Technology Co Ltd
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    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/188—Monocarboxylic acids; Anhydrides, halides or salts thereof
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
    • D06M15/03—Polysaccharides or derivatives thereof
    • D06M15/05—Cellulose or derivatives thereof
    • D06M15/09—Cellulose ethers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/356—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of other unsaturated compounds containing nitrogen, sulfur, silicon or phosphorus atoms
    • D06M15/3562—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of other unsaturated compounds containing nitrogen, sulfur, silicon or phosphorus atoms containing nitrogen
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/53—Polyethers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/59—Polyamides; Polyimides
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16—Synthetic fibres, other than mineral fibres
    • D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/32—Polyesters

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

The invention discloses a kind of compounding finishing agent for being used to improve dacron fabric antistatic behaviour, it is related to textile finishing technical field, is made up of the raw material of following parts by weight：15 25 parts of cactus, 15 parts of poly-aspartic-acid/Glucosamine, 15 parts of hydroxypropyl methyl cellulose, 0.5 1 parts of PAMC, 0.5 1 parts of rice bran wax, 0.05 0.5 parts of PDDA, 0.05 0.5 parts of sodium gluconate.Present invention compounding finishing agent is rich in natural component, and dacron fabric has excellent hydrophily and antistatic behaviour after its arrangement；And the dacron fabric after finishing agent arrangement has stable hydrophily and antistatic behaviour, good endurance.

Description

A kind of compounding finishing agent for being used to improve dacron fabric antistatic behaviour
Technical field：
The present invention relates to textile finishing technical field, and in particular to a kind of to be used to improve dacron fabric antistatic behaviour Compound finishing agent.
Background technology：
Polyester fiber, terylene is commonly called as, is one of the principal item of current synthetic fibers, be that a kind of combination property is preferably closed Into fiber, and a kind of typical hydrophobic fibre.When polyester fiber as personal dress materials in use, snugness of fit It is poor, especially perspiring when can give people to bring feeling of oppression and heat.Meanwhile the hydrophily of polyester fiber is very poor, this results in presence The problems such as easy dust suction, easy static electrification, difficulty degrease.
In order to solve the above problems, it is side the most frequently used at present that dacron fabric, which arrange, using hydrophilic finishing agent Method.The hydrophilic finish agent typically used includes cationic surface active agent, anionic surfactant and nonionic These three surfactants of surfactant.Arrangement through hydrophilic finishing agent can improve the hydrophily or antistatic of polyester fiber Property, but can be to improve polyester fiber hydrophilic while make it have good antistatic there is presently no a kind of hydrophilic finishing agent Property.
The content of the invention：
The technical problems to be solved by the invention, which are to provide, a kind of can improve being used for for hydrophily and antistatic behaviour simultaneously Improve the compounding finishing agent of dacron fabric antistatic behaviour.
The technical problems to be solved by the invention are realized using following technical scheme：
A kind of compounding finishing agent for being used to improve dacron fabric antistatic behaviour, by the raw material system of following parts by weight Into：
Cactus 15-25 parts, poly-aspartic-acid/Glucosamine 1-5 parts, hydroxypropyl methyl cellulose 1-5 parts, sun from Sub- polyacrylamide 0.5-1 parts, rice bran wax 0.5-1 parts, PDDA 0.05-0.5 parts, sodium gluconate 0.05-0.5 parts；
Its preparation method comprises the following steps：
(1) cactus of chopping is mixed with the deionized water of 3 times of weight, and ground repeatedly using power 1.5kW fiberizers Slurry 3 times, 100 mesh sieves are crossed, gained filtrate is sent into ball mill, is milled to discharging-material size less than 50 μm, produces cactus extraction；
(2) rice bran wax and PDDA are added into hydroxypropyl methyl cellulose, and is warming up to 80- 90 DEG C of insulation mixing 15-30min, are made micro mist using micronizer after naturally cool to after room temperature, produce modified cellulose；
(3) poly-aspartic-acid/Glucosamine, modified cellulose, cation poly- third are added into cactus extraction Acrylamide and sodium gluconate, 10-15min is stood after being sufficiently mixed, gained mixture is sent into ball mill, is milled to discharging grain Degree is less than 30 μm, produces compounding finishing agent.
Poly-aspartic-acid/the Glucosamine be by poly-aspartic-acid, Glucosamine after esterification again Modified processing is made, and its specific preparation method is：Into the mixture of poly-aspartic-acid and Glucosamine be added dropwise go from Sub- water is up to being completely dissolved, and the microwave reflow treatment 5min under microwave frequency 2450MHz, power output 700W, stands 5min Continue microwave reflow treatment 5min afterwards, continue microwave reflow treatment 5min after standing 5min again, then add polyethyleneglycol Methyl ether and N-methylmorpholine-N- oxides, microwave reflow treatment 5min again after being sufficiently mixed, continue microwave after standing 10min Reflow treatment 5min, room temperature is naturally cooled to, gained mixture is sent into freeze drier, dries gained solid through ultramicro grinding Micro mist is made in machine.
The poly-aspartic-acid, Glucosamine, poly glycol monomethyl ether, the quality of N-methylmorpholine-N- oxides Than for 5-10:5-10:1-5:0.1-1.
The rice bran wax passes through modification before using, and its specific preparation method is：Rice bran wax is heated to molten condition Insulation mixing 5min, adds stearic acid and NIPA, is continuously maintained at molten condition insulation mixing 15min, Then gained mixture is added drop-wise in deionized water, 10min is stirred after being added dropwise, filtered after standing 30min, gained ball Shape thing is modified rice bran wax.
The rice bran wax, stearic acid, the mass ratio of NIPA are 5:0.05-0.5:0.01-0.1.
The beneficial effects of the invention are as follows：The present invention is aided with a variety of auxiliary agents and is made for carrying using cactus as primary raw material The compounding finishing agent of superpolyester fabric antistatic behaviour, the compounding finishing agent are rich in natural component, and dacron fabric is through it There is excellent hydrophily and antistatic behaviour, the clothes penetrability that is made by polyester fiber is poor and easy band so as to solve after arrangement The problem of electrostatic；And the dacron fabric after finishing agent arrangement has stable hydrophily and antistatic behaviour, durable Property it is good, so as to use as high-grade fabric.
Embodiment：
In order that the technical means, the inventive features, the objects and the advantages of the present invention are easy to understand, tie below Specific embodiment is closed, the present invention is expanded on further.
Embodiment 1
(1) the 20g cactuses of chopping are mixed with the deionized water of 3 times of weight, and using power 1.5kW fiberizers repeatedly Defibrination 3 times, 100 mesh sieves are crossed, gained filtrate is sent into ball mill, is milled to discharging-material size less than 50 μm, produces cactus extraction Liquid；
(2) 0.5g rice bran waxs and 0.5g PDDAs are added into 5g hydroxypropyl methyl celluloses, And 80-90 DEG C of insulation mixing 30min is warming up to, micro mist is made using micronizer after naturally cool to after room temperature, produces and changes Property cellulose；
(3) added into cactus extraction 3g poly-aspartic-acids/Glucosamine, modified cellulose, 0.5g sun from Sub- polyacrylamide and 0.05g sodium gluconate, 10min is stood after being sufficiently mixed, gained mixture is sent into ball mill, ball milling It is less than 30 μm to discharging-material size, produces compounding finishing agent.
The preparation of poly-aspartic-acid/Glucosamine：To 10g poly-aspartic-acids and the mixture of 5g Glucosamines Middle dropwise addition deionized water is up to being completely dissolved, and the microwave reflow treatment under microwave frequency 2450MHz, power output 700W 5min, continues microwave reflow treatment 5min after standing 5min, continues microwave reflow treatment 5min, Ran Houjia after standing 5min again Enter 2g poly glycol monomethyl ethers and 0.1g N-methylmorpholine-N- oxides, microwave reflow treatment 5min again after being sufficiently mixed, Continue microwave reflow treatment 5min after standing 10min, naturally cool to room temperature, gained mixture is sent into freeze drier, is done Micro mist is made through micronizer in dry gained solid.
The preparation of modified rice bran wax：5g rice bran waxs are heated to molten condition insulation mixing 5min, add 0.5g tristearin Acid and 0.05g NIPAs, molten condition insulation mixing 15min is continuously maintained at, then drips gained mixture It is added in deionized water, 10min is stirred after being added dropwise, filtered after standing 30min, gained sphere is modified rice bran Wax.
Embodiment 2
(1) the 25g cactuses of chopping are mixed with the deionized water of 3 times of weight, and using power 1.5kW fiberizers repeatedly Defibrination 3 times, 100 mesh sieves are crossed, gained filtrate is sent into ball mill, is milled to discharging-material size less than 50 μm, produces cactus extraction Liquid；
(2) 0.5g rice bran waxs and 0.3g PDDAs are added into 3g hydroxypropyl methyl celluloses, And 80-90 DEG C of insulation mixing 30min is warming up to, micro mist is made using micronizer after naturally cool to after room temperature, produces and changes Property cellulose；
(3) added into cactus extraction 5g poly-aspartic-acids/Glucosamine, modified cellulose, 0.5g sun from Sub- polyacrylamide and 0.05g sodium gluconate, 15min is stood after being sufficiently mixed, gained mixture is sent into ball mill, ball milling It is less than 30 μm to discharging-material size, produces compounding finishing agent.
The preparation of poly-aspartic-acid/Glucosamine：Mixing to 10g poly-aspartic-acids and 10g Glucosamines Deionized water is added dropwise until being completely dissolved in thing, and the microwave reflow treatment under microwave frequency 2450MHz, power output 700W 5min, continues microwave reflow treatment 5min after standing 5min, continues microwave reflow treatment 5min, Ran Houjia after standing 5min again Enter 3g poly glycol monomethyl ethers and 0.2g N-methylmorpholine-N- oxides, microwave reflow treatment 5min again after being sufficiently mixed, Continue microwave reflow treatment 5min after standing 10min, naturally cool to room temperature, gained mixture is sent into freeze drier, is done Micro mist is made through micronizer in dry gained solid.
The preparation of modified rice bran wax：5g rice bran waxs are heated to molten condition insulation mixing 5min, add 0.3g tristearin Acid and 0.1g NIPAs, molten condition insulation mixing 15min is continuously maintained at, then drips gained mixture It is added in deionized water, 10min is stirred after being added dropwise, filtered after standing 30min, gained sphere is modified rice bran Wax.
Embodiment 3
(1) the 25g cactuses of chopping are mixed with the deionized water of 3 times of weight, and using power 1.5kW fiberizers repeatedly Defibrination 3 times, 100 mesh sieves are crossed, gained filtrate is sent into ball mill, is milled to discharging-material size less than 50 μm, produces cactus extraction Liquid；
(2) 0.5g rice bran waxs and 0.3g PDDAs are added into 3g hydroxypropyl methyl celluloses, And 80-90 DEG C of insulation mixing 30min is warming up to, micro mist is made using micronizer after naturally cool to after room temperature, produces and changes Property cellulose；
(3) added into cactus extraction 5g poly-aspartic-acids/Glucosamine, modified cellulose, 0.5g sun from Sub- polyacrylamide and 0.05g sodium gluconate, 15min is stood after being sufficiently mixed, gained mixture is sent into ball mill, ball milling It is less than 30 μm to discharging-material size, produces compounding finishing agent.
The preparation of poly-aspartic-acid/Glucosamine：Mixing to 10g poly-aspartic-acids and 10g Glucosamines Deionized water is added dropwise until being completely dissolved in thing, and the microwave reflow treatment under microwave frequency 2450MHz, power output 700W 5min, continues microwave reflow treatment 5min after standing 5min, continues microwave reflow treatment 5min, Ran Houjia after standing 5min again Enter 3g poly glycol monomethyl ethers and 0.2g N-methylmorpholine-N- oxides, microwave reflow treatment 5min again after being sufficiently mixed, Continue microwave reflow treatment 5min after standing 10min, naturally cool to room temperature, gained mixture is sent into freeze drier, is done Micro mist is made through micronizer in dry gained solid.
Reference examples 1
(1) the 25g cactuses of chopping are mixed with the deionized water of 3 times of weight, and using power 1.5kW fiberizers repeatedly Defibrination 3 times, 100 mesh sieves are crossed, gained filtrate is sent into ball mill, is milled to discharging-material size less than 50 μm, produces cactus extraction Liquid；
(2) added into cactus extraction 5g poly-aspartic-acids/Glucosamine, 3g hydroxypropyl methyl celluloses, 0.5g PAMCs and 0.05g sodium gluconates, stand 15min after being sufficiently mixed, gained mixture is sent into ball milling In machine, discharging-material size is milled to less than 30 μm, produces compounding finishing agent.
The preparation of poly-aspartic-acid/Glucosamine：Mixing to 10g poly-aspartic-acids and 10g Glucosamines Deionized water is added dropwise until being completely dissolved in thing, and the microwave reflow treatment under microwave frequency 2450MHz, power output 700W 5min, continues microwave reflow treatment 5min after standing 5min, continues microwave reflow treatment 5min, Ran Houjia after standing 5min again Enter 3g poly glycol monomethyl ethers and 0.2g N-methylmorpholine-N- oxides, microwave reflow treatment 5min again after being sufficiently mixed, Continue microwave reflow treatment 5min after standing 10min, naturally cool to room temperature, gained mixture is sent into freeze drier, is done Micro mist is made through micronizer in dry gained solid.
The preparation of modified rice bran wax：5g rice bran waxs are heated to molten condition insulation mixing 5min, add 0.3g tristearin Acid and 0.1g NIPAs, molten condition insulation mixing 15min is continuously maintained at, then drips gained mixture It is added in deionized water, 10min is stirred after being added dropwise, filtered after standing 30min, gained sphere is modified rice bran Wax.
Reference examples 2
(1) the 25g cactuses of chopping are mixed with the deionized water of 3 times of weight, and using power 1.5kW fiberizers repeatedly Defibrination 3 times, 100 mesh sieves are crossed, gained filtrate is sent into ball mill, is milled to discharging-material size less than 50 μm, produces cactus extraction Liquid；
(2) 0.5g rice bran waxs and 0.3g PDDAs are added into 3g hydroxypropyl methyl celluloses, And 80-90 DEG C of insulation mixing 30min is warming up to, micro mist is made using micronizer after naturally cool to after room temperature, produces and changes Property cellulose；
(3) added into cactus extraction 5g poly-aspartic-acids/Glucosamine, modified cellulose, 0.5g sun from Sub- polyacrylamide and 0.05g sodium gluconate, 15min is stood after being sufficiently mixed, gained mixture is sent into ball mill, ball milling It is less than 30 μm to discharging-material size, produces compounding finishing agent.
The preparation of poly-aspartic-acid/Glucosamine：Mixing to 10g poly-aspartic-acids and 10g Glucosamines Deionized water is added dropwise until being completely dissolved in thing, and the microwave reflow treatment under microwave frequency 2450MHz, power output 700W 5min, continue microwave reflow treatment 5min after standing 5min, continuation microwave reflow treatment 5min after standing 5min, naturally cold again But it is sent into room temperature, gained mixture in freeze drier, dries gained solid and micro mist is made through micronizer.
The preparation of modified rice bran wax：5g rice bran waxs are heated to molten condition insulation mixing 5min, add 0.3g tristearin Acid and 0.1g NIPAs, molten condition insulation mixing 15min is continuously maintained at, then drips gained mixture It is added in deionized water, 10min is stirred after being added dropwise, filtered after standing 30min, gained sphere is modified rice bran Wax.
Reference examples 3
(1) the 25g cactuses of chopping are mixed with the deionized water of 3 times of weight, and using power 1.5kW fiberizers repeatedly Defibrination 3 times, 100 mesh sieves are crossed, gained filtrate is sent into ball mill, is milled to discharging-material size less than 50 μm, produces cactus extraction Liquid；
(2) 0.5g rice bran waxs and 0.3g PDDAs are added into 3g hydroxypropyl methyl celluloses, And 80-90 DEG C of insulation mixing 30min is warming up to, micro mist is made using micronizer after naturally cool to after room temperature, produces and changes Property cellulose；
(3) added into cactus extraction 2.5g poly-aspartic-acids, 2.5g Glucosamines, modified cellulose, 0.5g PAMCs and 0.05g sodium gluconates, stand 15min after being sufficiently mixed, gained mixture is sent into ball milling In machine, discharging-material size is milled to less than 30 μm, produces compounding finishing agent.
The preparation of modified rice bran wax：5g rice bran waxs are heated to molten condition insulation mixing 5min, add 0.3g tristearin Acid and 0.1g NIPAs, molten condition insulation mixing 15min is continuously maintained at, then drips gained mixture It is added in deionized water, 10min is stirred after being added dropwise, filtered after standing 30min, gained sphere is modified rice bran Wax.
Embodiment 4
Respectively by equivalent embodiment 1, embodiment 2, embodiment 3, reference examples 1, reference examples 2,3 made finishing agent of reference examples profit It is used for the arrangement of dacron fabric of the same race with identical method for sorting, and according to standard AATCC79-2007, GB/T12703.2- The hydrophily and antistatic behaviour of dacron fabric after 2009 tests are collated, as a result as shown in table 1, with untrimmed poly- Ester fiber fabric is as reference examples 4.
The hydrophily and antistatic behaviour of dacron fabric after table 1 is collated
Group Water droplet extinction time s Quantity of electric charge μ C Surface density of charge μ C/m2
Embodiment 1 3.3 0.129 1.412
Embodiment 2 3.0 0.125 1.368
Embodiment 3 4.1 0.138 1.543
Reference examples 1 5.8 0.152 1.754
Reference examples 2 8.9 0.186 1.937
Reference examples 3 15.6 0.225 2.365
Reference examples 4 138.0 0.257 3.028
The general principle and principal character and advantages of the present invention of the present invention has been shown and described above.The technology of the industry Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and the simply explanation described in above-described embodiment and specification is originally The principle of invention, without departing from the spirit and scope of the present invention, various changes and modifications of the present invention are possible, these changes Change and improvement all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appended claims and its Equivalent thereof.

Claims (5)

  1. A kind of 1. compounding finishing agent for being used to improve dacron fabric antistatic behaviour, it is characterised in that：By following parts by weight Raw material be made：
    Cactus 15-25 parts, poly-aspartic-acid/Glucosamine 1-5 parts, hydroxypropyl methyl cellulose 1-5 parts, cation gather Acrylamide 0.5-1 parts, rice bran wax 0.5-1 parts, PDDA 0.05-0.5 parts, sodium gluconate 0.05-0.5 parts；
    Its preparation method comprises the following steps：
    (1) cactus of chopping is mixed with the deionized water of 3 times of weight, and utilizes power 1.5kW fiberizers defibrination 3 repeatedly It is secondary, 100 mesh sieves are crossed, gained filtrate is sent into ball mill, is milled to discharging-material size less than 50 μm, produces cactus extraction；
    (2) rice bran wax and PDDA are added into hydroxypropyl methyl cellulose, and is warming up to 80-90 DEG C Insulation mixing 15-30min, is made micro mist using micronizer after naturally cool to after room temperature, produces modified cellulose；
    (3) poly-aspartic-acid/Glucosamine, modified cellulose, cation polypropylene acyl are added into cactus extraction Amine and sodium gluconate, 10-15min is stood after being sufficiently mixed, gained mixture is sent into ball mill, and it is small to be milled to discharging-material size In 30 μm, compounding finishing agent is produced.
  2. 2. the compounding finishing agent according to claim 1 for being used to improve dacron fabric antistatic behaviour, it is characterised in that： Poly-aspartic-acid/the Glucosamine be by poly-aspartic-acid, Glucosamine after esterification it is modified again Reason is made, and its specific preparation method is：Into the mixture of poly-aspartic-acid and Glucosamine be added dropwise deionized water until It is completely dissolved, and continues after the microwave reflow treatment 5min under microwave frequency 2450MHz, power output 700W, standing 5min micro- Ripple reflow treatment 5min, continue microwave reflow treatment 5min after standing 5min again, then add poly glycol monomethyl ether and N- Methyhnorpholine-N-oxide, microwave reflow treatment 5min again after being sufficiently mixed, continue microwave reflow treatment after standing 10min 5min, room temperature is naturally cooled to, gained mixture is sent into freeze drier, and dry gained solid is made micro- through micronizer Powder.
  3. 3. the compounding finishing agent according to claim 2 for being used to improve dacron fabric antistatic behaviour, it is characterised in that： The poly-aspartic-acid, Glucosamine, poly glycol monomethyl ether, the mass ratio of N-methylmorpholine-N- oxides are 5-10: 5-10:1-5:0.1-1。
  4. 4. the compounding finishing agent according to claim 1 for being used to improve dacron fabric antistatic behaviour, it is characterised in that： The rice bran wax passes through modification before using, and its specific preparation method is：Rice bran wax is heated to molten condition insulation mixing 5min, stearic acid and NIPA are added, molten condition insulation mixing 15min is continuously maintained at, then by institute Obtain mixture to be added drop-wise in deionized water, stir 10min after being added dropwise, filtered after standing 30min, gained sphere is Modified rice bran wax.
  5. 5. the compounding finishing agent according to claim 4 for being used to improve dacron fabric antistatic behaviour, it is characterised in that： The rice bran wax, stearic acid, the mass ratio of NIPA are 5:0.05-0.5:0.01-0.1.
CN201710599585.7A 2017-07-21 2017-07-21 A kind of compounding finishing agent for being used to improve dacron fabric antistatic behaviour Pending CN107385907A (en)

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CN107841867A (en) * 2017-11-30 2018-03-27 苏州绣艳天下刺绣工艺有限公司 A kind of preparation method of resistance to washing oil sense coating fabric
CN107904931A (en) * 2017-11-30 2018-04-13 苏州绣艳天下刺绣工艺有限公司 A kind of preparation method for exempting to press cotton fabric
CN108385393A (en) * 2018-03-05 2018-08-10 江兵 A kind of dacron antistatic agent and its application method
CN109055633A (en) * 2018-09-21 2018-12-21 佛山市森昂生物科技有限公司 A kind of preparation method of genuine leather fabric finishing agent
CN109055633B (en) * 2018-09-21 2021-09-10 佛山市森昂生物科技有限公司 Preparation method of leather fabric finishing agent
CN111893767A (en) * 2020-07-29 2020-11-06 日华化学（中国）有限公司 Durable antistatic agent for polyester fabric and preparation method of polyester antistatic fabric

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Application publication date: 20171124