CN108385393A - A kind of dacron antistatic agent and its application method - Google Patents

A kind of dacron antistatic agent and its application method Download PDF

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CN108385393A
CN108385393A CN201810178105.4A CN201810178105A CN108385393A CN 108385393 A CN108385393 A CN 108385393A CN 201810178105 A CN201810178105 A CN 201810178105A CN 108385393 A CN108385393 A CN 108385393A
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dacron
antistatic agent
acrylamide
antistatic
dipping
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江兵
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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/285Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acid amides or imides
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/73Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof
    • D06M11/76Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with carbon or compounds thereof with carbon oxides or carbonates
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/11Compounds containing epoxy groups or precursors thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/184Carboxylic acids; Anhydrides, halides or salts thereof
    • D06M13/188Monocarboxylic acids; Anhydrides, halides or salts thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/10Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
    • D06M13/224Esters of carboxylic acids; Esters of carbonic acid
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/248Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
    • D06M13/256Sulfonated compounds esters thereof, e.g. sultones
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    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/244Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
    • D06M13/282Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing phosphorus
    • D06M13/292Mono-, di- or triesters of phosphoric or phosphorous acids; Salts thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/325Amines
    • D06M13/342Amino-carboxylic acids; Betaines; Aminosulfonic acids; Sulfo-betaines
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/21Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/263Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/53Polyethers
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    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/16Synthetic fibres, other than mineral fibres
    • D06M2101/30Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M2101/32Polyesters

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

The invention discloses a kind of dacron antistatic agent and its application methods, are related to textile processing technical field, are made of the raw material of following weight percent:Acrylamide biacetone acrylamide copolymer 3 10%, Phosphoric acid monohexadecyl ester potassium 1 5%, 60 rilanit specials 0.5 2% of PEG, ethylene glycol diglycidylether 0.5 2%, laruyl alcohol sulfosuccinate disodium 0.5 2%, two tricaprylate 0.5 2% of triethylene glycol, sodium lauroyl glutamate 0.5 2%, hydrolysis of polymaleic anhydride 0.1 0.5%, zinc Isoocatanoate 0.1 0.5%, water surplus.The present invention strengthens antistatic finish effect by impregnating twice with baking operation twice, to improve the antistatic property of dacron, improves the use quality of dacron, and then be conducive to be processed into high-grade polyester fabric product.

Description

A kind of dacron antistatic agent and its application method
Technical field:
The present invention relates to textile processing technical fields, and in particular to a kind of dacron antistatic agent and its user Method.
Background technology:
Terylene belongs to an important kind in synthetic fibers, is the trade name of China's polyester fiber.It is right with essence Phthalic acid or dimethyl terephthalate (DMT) and ethylene glycol are raw material through esterification or prepared by transesterification and polycondensation reaction at fibre High polymer-polyethylene terephthalate, through fiber made of spinning and post-processing.Characteristic of the terylene due to itself so that Its antistatic effect is poor, it is therefore desirable to by antistatic finish to reach preferable antistatic effect.
In order to improve the antistatic property of dacron, people generally use antistatic agent method for sorting at present.Through anti-quiet Antistatic property of polyester fiber fabrics after electric agent arranges is obviously improved, but it is found that dacron during long-time use, Antistatic effect can be gradually reduced, and antistatic stability is poor, to ensure the permanent antistatic use of terylene product Quality.
Invention content:
Technical problem to be solved by the present invention lies in provide a kind of antistatic property and antistatic steady of capable of improving simultaneously The dacron antistatic agent and its application method of qualitative energy.
The technical problems to be solved by the invention are realized using technical solution below:
A kind of dacron antistatic agent is made of the raw material of following weight percent:
Acrylamide-biacetone acrylamide copolymer 3-10%, Phosphoric acid monohexadecyl ester potassium 1-5%, PEG-60 hydrogenate castor Sesame oil 0.5-2%, ethylene glycol diglycidylether 0.5-2%, laruyl alcohol sulfosuccinate disodium 0.5-2%, triethylene glycol Two tricaprylate 0.5-2%, sodium lauroyl glutamate 0.5-2%, hydrolysis of polymaleic anhydride 0.1-0.5%, zinc Isoocatanoate 0.1- 0.5%, water surplus.
The acrylamide-biacetone acrylamide copolymer is using acrylamide and Diacetone Acrylamide as singly Body, potassium peroxydisulfate synthesize obtained, mole of acrylamide and Diacetone Acrylamide as initiator, using water as reaction dissolvent Than for 2-2.5:1, for initiator amount in 0.1-0.3wt%, reaction temperature is 20-35 DEG C.
The application method of above-mentioned dacron antistatic agent, includes the following steps:
(1) it impregnates:Dacron is immersed in antistatic agent, antistatic agent temperature maintains 60-70 DEG C, dip time Control is dehydrated dacron after 15-30min, dipping, pick-up 60-70%;
(2) it dries:By the dacron after above-mentioned dipping first with 70-80 DEG C of hot-air seasoning to constant weight, recycle 115-125 DEG C of heated-air drying 3-5min;
(3) double-steeping:Dacron after above-mentioned drying is immersed in antistatic agent again, antistatic agent used By adding saturated sodium bicarbonate solution regulation system pH value to 8-9, antistatic agent temperature maintains 70-80 DEG C, dip time Control is dehydrated dacron after 15-30min, dipping, pick-up 70-80%;
(4) secondary drying:By the dacron after above-mentioned double-steeping first with 70-80 DEG C of hot-air seasoning to constant weight, 130-140 DEG C of heated-air drying 3-5min is recycled, that is, completes the antistatic finish of dacron.
The saturated sodium bicarbonate solution is the saturated sodium bicarbonate solution at 25 DEG C.
The beneficial effects of the invention are as follows:
(1) antistatic agent used in the present invention is different from this field routine antistatic agent, routinely antistatic using non-this field Agent prepares raw material and is made, and antistatic effect is notable, while wastewater produced intractability is small;
(2) present invention strengthens antistatic finish effect by impregnating twice with baking operation twice, to improve terylene The antistatic property of fabric improves the use quality of dacron, and then is conducive to be processed into high-grade polyester fabric product.Its In, in double-steeping by the pH value adjustment effect of sodium bicarbonate solution to be improved while ensureing dacron flexibility Its antistatic property, and enhance by dried by hot air stream at high temperature the stability of antistatic property of polyester fiber fabrics, it avoids due to washing Reduce antistatic property.
Specific implementation mode:
In order to make the technical means, the creative features, the aims and the efficiencies achieved by the present invention be easy to understand, tie below Specific embodiment is closed, the present invention is further explained.
Embodiment 1
Dacron antistatic agent is made of the raw material of following weight percent:
Acrylamide-biacetone acrylamide copolymer 4%, Phosphoric acid monohexadecyl ester potassium 2%, PEG-60 rilanit specials 1%, ethylene glycol diglycidylether 1%, laruyl alcohol sulfosuccinate disodium 0.5%, two tricaprylate of triethylene glycol 0.5%, sodium lauroyl glutamate 0.5%, hydrolysis of polymaleic anhydride 0.3%, zinc Isoocatanoate 0.3%, water surplus.
Acrylamide-biacetone acrylamide copolymer is using acrylamide and Diacetone Acrylamide as monomer, mistake Synthesis is obtained as initiator, using water as reaction dissolvent for potassium sulfate, and the molar ratio of acrylamide and Diacetone Acrylamide is 2.5:1, for initiator amount in 0.2wt%, reaction temperature is 35 DEG C.
The application method of above-mentioned dacron antistatic agent, includes the following steps:
(1) it impregnates:Dacron is immersed in antistatic agent, antistatic agent temperature maintains 60-70 DEG C, dip time Control is dehydrated dacron after 15min, dipping, pick-up 60-70%;
(2) it dries:By the dacron after above-mentioned dipping first with 70-80 DEG C of hot-air seasoning to constant weight, recycle 115-125 DEG C of heated-air drying 5min;
(3) double-steeping:Dacron after above-mentioned drying is immersed in antistatic agent again, antistatic agent used By adding saturated sodium bicarbonate solution regulation system pH value to 8-9, antistatic agent temperature maintains 70-80 DEG C, dip time Control is dehydrated dacron after 15min, dipping, pick-up 70-80%;
(4) secondary drying:By the dacron after above-mentioned double-steeping first with 70-80 DEG C of hot-air seasoning to constant weight, 130-140 DEG C of heated-air drying 5min is recycled, that is, completes the antistatic finish of dacron.
Wherein, saturated sodium bicarbonate solution is the saturated sodium bicarbonate solution at 25 DEG C.
Embodiment 2
Dacron antistatic agent is made of the raw material of following weight percent:
Acrylamide-biacetone acrylamide copolymer 5%, Phosphoric acid monohexadecyl ester potassium 2%, PEG-60 rilanit specials 1%, ethylene glycol diglycidylether 1%, laruyl alcohol sulfosuccinate disodium 0.5%, two tricaprylate of triethylene glycol 0.5%, sodium lauroyl glutamate 0.5%, hydrolysis of polymaleic anhydride 0.3%, zinc Isoocatanoate 0.3%, water surplus.
Acrylamide-biacetone acrylamide copolymer is using acrylamide and Diacetone Acrylamide as monomer, mistake Synthesis is obtained as initiator, using water as reaction dissolvent for potassium sulfate, and the molar ratio of acrylamide and Diacetone Acrylamide is 2.5:1, for initiator amount in 0.2wt%, reaction temperature is 35 DEG C.
The application method of above-mentioned dacron antistatic agent, includes the following steps:
(1) it impregnates:Dacron is immersed in antistatic agent, antistatic agent temperature maintains 60-70 DEG C, dip time Control is dehydrated dacron after 15min, dipping, pick-up 60-70%;
(2) it dries:By the dacron after above-mentioned dipping first with 70-80 DEG C of hot-air seasoning to constant weight, recycle 115-125 DEG C of heated-air drying 5min;
(3) double-steeping:Dacron after above-mentioned drying is immersed in antistatic agent again, antistatic agent used By adding saturated sodium bicarbonate solution regulation system pH value to 8-9, antistatic agent temperature maintains 70-80 DEG C, dip time Control is dehydrated dacron after 15min, dipping, pick-up 70-80%;
(4) secondary drying:By the dacron after above-mentioned double-steeping first with 70-80 DEG C of hot-air seasoning to constant weight, 130-140 DEG C of heated-air drying 5min is recycled, that is, completes the antistatic finish of dacron.
Wherein, saturated sodium bicarbonate solution is the saturated sodium bicarbonate solution at 25 DEG C.
Reference examples 1
Dacron antistatic agent is made of the raw material of following weight percent:
Acrylamide-biacetone acrylamide copolymer 5%, Phosphoric acid monohexadecyl ester potassium 2%, PEG-60 rilanit specials 1%, ethylene glycol diglycidylether 1%, laruyl alcohol sulfosuccinate disodium 0.5%, two tricaprylate of triethylene glycol 0.5%, sodium lauroyl glutamate 0.5%, hydrolysis of polymaleic anhydride 0.3%, zinc Isoocatanoate 0.3%, water surplus.
Acrylamide-biacetone acrylamide copolymer is using acrylamide and Diacetone Acrylamide as monomer, mistake Synthesis is obtained as initiator, using water as reaction dissolvent for potassium sulfate, and the molar ratio of acrylamide and Diacetone Acrylamide is 2.5:1, for initiator amount in 0.2wt%, reaction temperature is 35 DEG C.
The application method of above-mentioned dacron antistatic agent, includes the following steps:
(1) it impregnates:Dacron is immersed in antistatic agent, antistatic agent temperature maintains 60-70 DEG C, dip time Control is dehydrated dacron after 15min, dipping, pick-up 60-70%;
(2) it dries:By the dacron after above-mentioned dipping first with 70-80 DEG C of hot-air seasoning to constant weight;
(3) double-steeping:Dacron after above-mentioned drying is immersed in antistatic agent again, antistatic agent used By adding saturated sodium bicarbonate solution regulation system pH value to 8-9, antistatic agent temperature maintains 70-80 DEG C, dip time Control is dehydrated dacron after 15min, dipping, pick-up 70-80%;
(4) secondary drying:By the dacron after above-mentioned double-steeping first with 70-80 DEG C of hot-air seasoning to constant weight, 130-140 DEG C of heated-air drying 5min is recycled, that is, completes the antistatic finish of dacron.
Wherein, saturated sodium bicarbonate solution is the saturated sodium bicarbonate solution at 25 DEG C.
Reference examples 2
Dacron antistatic agent is made of the raw material of following weight percent:
Acrylamide-biacetone acrylamide copolymer 5%, Phosphoric acid monohexadecyl ester potassium 2%, PEG-60 rilanit specials 1%, ethylene glycol diglycidylether 1%, laruyl alcohol sulfosuccinate disodium 0.5%, two tricaprylate of triethylene glycol 0.5%, sodium lauroyl glutamate 0.5%, hydrolysis of polymaleic anhydride 0.3%, zinc Isoocatanoate 0.3%, water surplus.
Acrylamide-biacetone acrylamide copolymer is using acrylamide and Diacetone Acrylamide as monomer, mistake Synthesis is obtained as initiator, using water as reaction dissolvent for potassium sulfate, and the molar ratio of acrylamide and Diacetone Acrylamide is 2.5:1, for initiator amount in 0.2wt%, reaction temperature is 35 DEG C.
The application method of above-mentioned dacron antistatic agent, includes the following steps:
(1) it impregnates:Dacron is immersed in antistatic agent, antistatic agent temperature maintains 60-70 DEG C, dip time Control is dehydrated dacron after 15min, dipping, pick-up 60-70%;
(2) it dries:By the dacron after above-mentioned dipping first with 70-80 DEG C of hot-air seasoning to constant weight, recycle 115-125 DEG C of heated-air drying 5min;
(3) double-steeping:Dacron after above-mentioned drying is immersed in antistatic agent again, antistatic agent used By adding saturated sodium bicarbonate solution regulation system pH value to 8-9, antistatic agent temperature maintains 70-80 DEG C, dip time Control is dehydrated dacron after 15min, dipping, pick-up 70-80%;
(4) secondary drying:By the dacron after above-mentioned double-steeping first with 70-80 DEG C of hot-air seasoning to constant weight, Complete the antistatic finish of dacron.
Wherein, saturated sodium bicarbonate solution is the saturated sodium bicarbonate solution at 25 DEG C.
Reference examples 3
Dacron antistatic agent is made of the raw material of following weight percent:
Acrylamide-biacetone acrylamide copolymer 5%, Phosphoric acid monohexadecyl ester potassium 2%, PEG-60 rilanit specials 1%, ethylene glycol diglycidylether 1%, laruyl alcohol sulfosuccinate disodium 0.5%, two tricaprylate of triethylene glycol 0.5%, sodium lauroyl glutamate 0.5%, hydrolysis of polymaleic anhydride 0.3%, zinc Isoocatanoate 0.3%, water surplus.
Acrylamide-biacetone acrylamide copolymer is using acrylamide and Diacetone Acrylamide as monomer, mistake Synthesis is obtained as initiator, using water as reaction dissolvent for potassium sulfate, and the molar ratio of acrylamide and Diacetone Acrylamide is 2.5:1, for initiator amount in 0.2wt%, reaction temperature is 35 DEG C.
The application method of above-mentioned dacron antistatic agent, includes the following steps:
(1) it impregnates:Dacron is immersed in antistatic agent, antistatic agent temperature maintains 60-70 DEG C, dip time Control is dehydrated dacron after 30min, dipping, pick-up 60-70%;
(2) it dries:By the dacron after above-mentioned dipping first with 70-80 DEG C of hot-air seasoning to constant weight, recycle 130-140 DEG C of heated-air drying 5min completes the antistatic finish of dacron.
Wherein, saturated sodium bicarbonate solution is the saturated sodium bicarbonate solution at 25 DEG C.
Reference examples 4
Dacron antistatic agent uses the myristyl monomethyl two of the 20g/L of patent CN201410337779.6 preparations Second hydroxyl bromination aqueous ammonium.
The application method of above-mentioned dacron antistatic agent, includes the following steps:
(1) it impregnates:Dacron is immersed in antistatic agent, antistatic agent temperature maintains 60-70 DEG C, dip time Control is dehydrated dacron after 30min, dipping, pick-up 60-70%;
(2) it dries:By the dacron after above-mentioned dipping first with 70-80 DEG C of hot-air seasoning to constant weight, recycle 130-140 DEG C of heated-air drying 5min completes the antistatic finish of dacron.
Wherein, saturated sodium bicarbonate solution is the saturated sodium bicarbonate solution at 25 DEG C.
Embodiment 3
Be utilized respectively embodiment 1-2, reference examples 1-4 to series-produced same specification dacron carry out antistatic finish, And it measures the collated surface resistivity of dacron and volume resistivity afterwards with reference to GB/T16801-2013 and washes 50 times Surface resistivity afterwards and volume resistivity, as shown in table 1.
The above shows and describes the basic principles and main features of the present invention and the advantages of the present invention.The technology of the industry Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and the above embodiments and description only describe this The principle of invention, without departing from the spirit and scope of the present invention, various changes and improvements may be made to the invention, these changes Change and improvement all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appended claims and its Equivalent thereof.

Claims (4)

1. a kind of dacron antistatic agent, which is characterized in that be made of the raw material of following weight percent:
Acrylamide-biacetone acrylamide copolymer 3-10%, Phosphoric acid monohexadecyl ester potassium 1-5%, PEG-60 rilanit special 0.5-2%, ethylene glycol diglycidylether 0.5-2%, laruyl alcohol sulfosuccinate disodium 0.5-2%, triethylene glycol two are different Caprylate 0.5-2%, sodium lauroyl glutamate 0.5-2%, hydrolysis of polymaleic anhydride 0.1-0.5%, zinc Isoocatanoate 0.1- 0.5%, water surplus.
2. dacron antistatic agent according to claim 1, it is characterised in that:The acrylamide-biacetone propylene Amide copolymer is using acrylamide and Diacetone Acrylamide as monomer, potassium peroxydisulfate as initiator, using water as instead Solvent synthesis is answered to be made, the molar ratio of acrylamide and Diacetone Acrylamide is 2-2.5:1, initiator amount is in 0.1- 0.3wt%, reaction temperature are 20-35 DEG C.
3. the application method of dacron antistatic agent as claimed in claim 1 or 2, which is characterized in that include the following steps:
(1) it impregnates:Dacron is immersed in antistatic agent, antistatic agent temperature maintains 60-70 DEG C, dip time control Dacron is dehydrated after 15-30min, dipping, pick-up 60-70%;
(2) it dries:By the dacron after above-mentioned dipping first with 70-80 DEG C of hot-air seasoning to constant weight, 115-125 is recycled DEG C heated-air drying 3-5min;
(3) double-steeping:Dacron after above-mentioned drying is immersed in antistatic agent again, antistatic agent used passes through Saturated sodium bicarbonate solution regulation system pH value is added to 8-9, antistatic agent temperature maintains 70-80 DEG C, dip time control Dacron is dehydrated after 15-30min, dipping, pick-up 70-80%;
(4) secondary drying:By the dacron after above-mentioned double-steeping first with 70-80 DEG C of hot-air seasoning to constant weight, then profit With 130-140 DEG C of heated-air drying 3-5min, that is, complete the antistatic finish of dacron.
4. the application method of dacron antistatic agent according to claim 3, it is characterised in that:The unsaturated carbonate hydrogen Sodium solution is the saturated sodium bicarbonate solution at 25 DEG C.
CN201810178105.4A 2018-03-05 2018-03-05 A kind of dacron antistatic agent and its application method Pending CN108385393A (en)

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Application publication date: 20180810