CN103214629A - Antistatic agent for dacron textile and preparation method of antistatic agent - Google Patents
Antistatic agent for dacron textile and preparation method of antistatic agent Download PDFInfo
- Publication number
- CN103214629A CN103214629A CN2013101695022A CN201310169502A CN103214629A CN 103214629 A CN103214629 A CN 103214629A CN 2013101695022 A CN2013101695022 A CN 2013101695022A CN 201310169502 A CN201310169502 A CN 201310169502A CN 103214629 A CN103214629 A CN 103214629A
- Authority
- CN
- China
- Prior art keywords
- polyester
- antistatic agent
- hyper
- static inhibitor
- preparation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Images
Abstract
The invention discloses an antistatic agent for a dacron textile as well as a preparation method and an application of the antistatic agent. The preparation method comprises the following steps of: carrying out grafting modification on hyperbranched polyester BoltornH20 by trimethyl oxiranemethaminium chloride and acrylic acid according to the ratio of the amount of substance from 1: 1 to 1: 2; and taking an obtained modified substance to react with acrylamide, dimethyl diallyl ammonium chloride and allyl glycidyl ether to prepare the antistatic agent. According to the antistatic agent of the dacron textile as well as the preparation method and the application of the antistatic agent disclosed by the invention, the process is simpler and a reaction process is convenient to control; the prepared antistatic agent has the stronger cation property and the antistatic function of the dacron textile can be obviously improved; and meanwhile, a lot of reactive functional groups in the antistatic agent can generate cross-linking effect in a finishing and drying process of the dacron textile, the antistatic water-washing resisting performance of the finished textile can be effectively improved, the influences on the hand feel of the textile by the antistatic agent are small.
Description
Technical field
The present invention relates to a kind of static inhibitor and synthetic method thereof, be specifically related to a kind of static inhibitor and synthetic method thereof that is used for polyester piece good.
Background technology
Terylene is a kind of widely used synthon, and it has durable, good springiness, advantage such as not yielding, well-pressed, quick-drying washable, is loved by the people.But hydrophilic radical is less in the Structure of PET Fiber, and water absorbability is poor, very easily produces static, and this just causes in the process of taking, the dust of polyester piece good in not only can absorbed air, and be easy to generate the electric shock phenomenon.Therefore, factory's static inhibitor commonly used is in process of production done antistatic treatment to polyester piece good, but the difficult durable antistatic effect that obtains.
Quaternary ammonium compound is used more as cationic static inhibitor, not only antistatic effect is good, and has good flexibility, can be used as the static inhibitor of synthon such as terylene, acrylic fibers, polypropylene fibre.But because synthon surface reaction group is less, static inhibitor only just is adsorbed on the surface of fiber, so its weather resistance is relatively poor.
In recent years, hyper-branched polyester relies on its special structure, and excellent performance is paid close attention to by more and more researchers.The double bond containing hyper-branched polyester of end group is used widely in paint field, and a large amount of unsaturated groups increase reactive behavior, not only self are easy to crosslinked film forming, can also carry out copolymerization with other monomer.But the hyper-branched polyester that contains two key groups is poorly soluble, is insoluble in some conventional organic solvents such as water and ethanol, acetone, toluene, and its use finally can be restricted.
Summary of the invention
The objective of the invention is to overcome the deficiency that prior art exists, provide a kind of and can satisfy excellent antistatic and water-wash resistance requirement, less to the fabric feeling influence simultaneously, cost performance is high is used for terylene fabrics antistatic agent and preparation method thereof.
For achieving the above object, the technical solution used in the present invention is a kind of preparation method who is used for the static inhibitor of polyester piece good, comprises the steps:
1, be raw material with modified ultra-branching polyester, acrylamide, glycidyl allyl ether, dimethyldiallylammonchloride chloride monomer, under the agitation condition, by mass ratio 0.1:1:1:3～5 each raw material is added to the water, obtains massfraction and be 25%～30% monomer mixed solution; The ammonium persulphate of monomer total mass 0.6%～1.0% is dissolved in the water, obtains initiator solution;
2, get 0.2～0.4 part monomer mixed solution and initiator solution respectively, join under the agitation condition in the reaction vessel that condensation reflux unit is housed, be warming up to 80～90 ℃, in 2～3 hours, slowly drip remaining monomer mixed solution and initiator solution, after the insulation reaction 5～6 hours, be cooled to room temperature, obtain pH and be 8.0～9.0 light yellow transparent liquid, be the static inhibitor that is used for polyester piece good.
Modified ultra-branching polyester of the present invention, its synthetic method is:
1, hyper-branched polyester Boltorn H20 is heated to molten state, add hydroquinone of polymerization retarder successively, vinylformic acid, toluene and catalyzer tosic acid, maintain the temperature at 100～110 ℃ and constantly react 1～1.5 h under the stirring condition after, place ice-water bath to cool off reaction mixture again, wherein, the Resorcinol consumption is 0.3～0.5% of a hyper-branched polyester quality, the vinylformic acid consumption is 25%～45% of a hyper-branched polyester quality, catalyzer tosic acid consumption is 0.5～1.0% of a hyper-branched polyester quality, and the toluene consumption is 1～2 times of hyper-branched polyester quality;
2, the product that step 1 is obtained is dissolved in N, in the dinethylformamide, add the catalyzer sodium hydrate solid, agitation condition slowly drips chlorination Racemic glycidol trimethyl ammonium down, react 12～24h under 40～50 ℃ temperature condition, decompress filter is removed sodium hydroxide; By mass, N, dinethylformamide are 1.5～2 times of hyper-branched polyester, and sodium hydrate solid is 3～5% of a chlorination Racemic glycidol trimethyl ammonium; Press the amount of substance ratio, chlorination Racemic glycidol trimethyl ammonium and vinylformic acid are 1:1～1:2; Prioritization scheme provided by the invention is: press the amount of substance ratio, chlorination Racemic glycidol trimethyl ammonium and vinylformic acid are 1:1.5.
3, be that 60～70 ℃, vacuum tightness are to handle 0.5～1h under the condition of 0.09～0.10Mpa to the filtrate that obtains behind the suction filtration in temperature, obtain a kind of modified ultra-branching polyester, its general structure is:
The ester modified chemical equation of hyperbranched poly is:
，
Wherein,
The concrete structure formula be:
Technical solution of the present invention also comprises the static inhibitor that is used for polyester piece good that obtains by above-mentioned preparation method, and described static inhibitor is to the application in the antistatic finish of polyester piece good.
Principle of the present invention is: adopt vinylformic acid that the part terminal hydroxy group of hyper-branched polyester is carried out modification, another part terminal hydroxy group and the reaction of chlorination Racemic glycidol trimethyl ammonium, control chlorination Racemic glycidol trimethyl ammonium and acrylic acid amount of substance ratio.Acrylic acid consumption can not too much can not be very few, and consumption is too much, and the quantity of two keys is just many in institute's synthetic modified ultra-branching polyester, and water soluble group quantity is few, causes its decreased solubility, hinders the carrying out of polyreaction; Consumption is very few, and the quantity of two key groups is few, and the side chain that can participate in polyreaction also just reduces, and causes molecular weight of product low, and film-forming properties is relatively poor.Hyper-branched polyester after the modification carries out solution polymerization with acrylamide, dimethyl diallyl ammonium chloride and glycidyl allyl ether again, prepares a kind of novel cationic static inhibitor.
Test antistatic property provided by the invention by FZ/T 01042-1996 " textile materials antistatic property, static voltage half life determination " method, press its washing fastness of GB/T3921.1-1997 standard testing, the induction static voltage of the polyester piece good after the arrangement of this static inhibitor is 0.00～0.03kV, transformation period is 0.00s, the induction static voltage of washing polyester piece good after 15 times is 0.45～0.69kV, and the transformation period is 1.23～1.60s.
Because the utilization of technique scheme, the present invention compares with prior art, has following advantage:
1, hyper-branched polyester of the present invention has and the similar highly branched structure of dendrimer, and the structure end has a large amount of terminal hydroxy group, and the chemical modification of terminal hydroxy group is easier to;
2, one aspect of the present invention adopts the cationic monomer diallyldimethylammonChloride Chloride and the hyper-branched polyester after the modification that have than strongly hydrophilic to carry out polymerization, a large amount of reactive functional groups that the modified ultra-branching polyester is provided can improve the quantity of cation group in the polymkeric substance by a relatively large margin; On the other hand, employing bridging property glycidyl allyl ether preferably is a cross-linking monomer, make cation superpolymer in the crosslinked film forming of fiber surface with reactive functional groups, can improve the wash durability of static inhibitor effectively, the amide group that acrylamide provided simultaneously can remedy the crosslinked problem of bringing feel to descend as soft chain segment, so the arrangement back is less to the feel influence of fabric;
3, technology of the present invention is simpler, and reaction process is convenient to control, is fit to suitability for industrialized production.
Description of drawings
Fig. 1 is the infrared spectrum of hyper-branched polyester among the embodiment 1, modified ultra-branching polyester and static inhibitor;
Fig. 2 is the infrared spectrum of hyper-branched polyester among the embodiment 2, modified ultra-branching polyester and static inhibitor;
Fig. 3 is the infrared spectrum of hyper-branched polyester among the embodiment 3, modified ultra-branching polyester and static inhibitor.
Embodiment
Below in conjunction with drawings and Examples technical solution of the present invention is further described:
1,10.50g (0.005mol) hyper-branched polyester Boltorn H20 is added in the reaction vessel, be heated to molten, open electric mixer and condensation reflux unit, behind the adding 0.04g Resorcinol, add 2.88g (0.040mol) vinylformic acid and 11.00g toluene again.
2, temperature is controlled at 100 ℃, when system forms homogeneous phase solution, adds the 0.06g tosic acid, back flow reaction 1 hour is cooled off in ice-water bath then.
3, products therefrom is dissolved in 18.90g N, in the dinethylformamide, add the 0.30g solid sodium hydroxide, under constantly stirring, slowly drip 6.06g (0.040mol) chlorination Racemic glycidol trimethyl ammonium, 50 ℃ were reacted 24 hours, and decompress filter is removed solid sodium hydroxide.
4, remove and reclaim solvent.Be evacuated down to 0.10Mpa under 70 ℃, handled 0.5 hour, slough and reclaim N, dinethylformamide obtains the modified ultra-branching polyester.
5, modified ultra-branching polyester and acrylamide, glycidyl allyl ether, dimethyl diallyl ammonium chloride are dissolved in the 50g water by mass ratio 0.1:1:1:3, obtain monomer mixed solution, the 0.20g ammonium persulphate is dissolved in the 20g water and obtains initiator solution.
6, the above-mentioned monomer mixed solution and the initiator solution of adding 1/5 in reaction vessel, open electric mixer and condensation reflux unit, be warming up to 80 ℃ after, drip off residue 4/5 monomer mixed solution and initiator solution in 2 hours, insulation reaction 6 hours obtains the static inhibitor aqueous solution.
Referring to accompanying drawing 1, it is the infrared spectrum of hyper-branched polyester in the present embodiment, modified ultra-branching polyester and static inhibitor; Among the figure, curve 1 is a hyper-branched polyester, and curve 2 is the modified ultra-branching polyester, and curve 3 is a static inhibitor; Compare with curve 1, curve 2 is at 1640cm
-1And 910cm
-1New absorption peak appears in the place, is R-CH=CH
2The characteristic peak of vinyl is at 971cm
-1The absorption peak at place is the charateristic avsorption band of C in the alkyl trimethyl quaternary ammonium salt-N stretching vibration, illustrates that reaction has taken place for vinylformic acid, chlorination Racemic glycidol trimethyl ammonium and hyper-branched polyester; In the curve 3, the asymmetric stretching vibration absorption peak of epoxy group(ing) appears at 870cm
-1Place, 910cm simultaneously
-1The characteristic peak of place's vinyl double bond disappears, and the absorption peak of C in the alkyl trimethyl quaternary ammonium salt-N stretching vibration strengthens, and shows that all reaction is more complete between each monomer.
The resulting static inhibitor aqueous solution is product.This product is a light yellow transparent liquid, and testing its solid content is 25.44%, and pH is 8.1.Get the aqueous solution that this static inhibitor is made into 50g/L, polyester piece good is put in order, press FZ/T 01042-1996 " textile materials antistatic property, static voltage half life determination " method and testing its antistatic property on the H0110.V2 electrostatic attenuation tester and pressing the GB/T3921.1-1997 standard and test its washing fastness on washing fastness instrument WASHTEC-P, test result is as shown in table 1.
Antistatic property after the arrangement of table 1 polyester piece good
| Former cloth | After the antistatic finish | After washing 15 times | |
| Transformation period/s | >60 | 0.00 | 1.60 |
| Induction static voltage/kV | 2.09 | 0.02 | 0.69 |
Embodiment 2
1,10.5g (0.005mol) hyper-branched polyester is added in the reaction vessel, under 120 ℃, be heated to molten, electric mixer and condensation reflux unit behind the adding 0.04g Resorcinol, add vinylformic acid and the 13.00g toluene of 3.46g (0.048mol) again.
2, temperature is controlled at 105 ℃, when system forms homogeneous phase solution, adds the 0.08g tosic acid, back flow reaction 1 hour is cooled off in ice-water bath then.
3, products therefrom is dissolved in 19.00g N, in the dinethylformamide, adding 0.20g solid sodium hydroxide slowly drips 4.85g (0.032mol) chlorination Racemic glycidol trimethyl ammonium under constantly stirring, and 45 ℃ were reacted 24 hours.Decompress filter is removed solid.
4, remove and reclaim solvent.Be evacuated down to 0.10Mpa under 65 ℃, handled 1 hour, slough and reclaim N, dinethylformamide obtains the modified ultra-branching polyester.
5, modified ultra-branching polyester and acrylamide, glycidyl allyl ether, dimethyl diallyl ammonium chloride are dissolved in the 50g water by mass ratio 0.1:1:1:4 obtain monomer mixed solution, the 0.24g ammonium persulphate is dissolved in the 20g water and obtains initiator solution.
6, in reaction vessel, add 1/5 above-mentioned monomer mixed solution and initiator solution, open electric mixer and condensation reflux unit, be warming up to 85 ℃ after, drip off residue 4/5 monomer mixed solution and initiator solution in 2 hours, insulation reaction 6 hours obtains the static inhibitor aqueous solution.
Referring to accompanying drawing 2, it is the infrared spectrum of hyper-branched polyester in the present embodiment, modified ultra-branching polyester and static inhibitor; Among the figure, curve 1 is a hyper-branched polyester, and curve 2 is the modified ultra-branching polyester, and curve 3 is a static inhibitor; Similar to embodiment 1, curve 2 is at 1640cm
-1And 910cm
-1New absorption peak appears in the place, is R-CH=CH
2The characteristic peak of vinyl is at 971cm
-1The absorption peak at place is the charateristic avsorption band of C in the alkyl trimethyl quaternary ammonium salt-N stretching vibration, illustrates that reaction has taken place for vinylformic acid, chlorination Racemic glycidol trimethyl ammonium and hyper-branched polyester; In the curve 3, the asymmetric stretching vibration absorption peak of epoxy group(ing) appears at 870cm
-1Place, 910cm simultaneously
-1The characteristic peak of place's vinyl double bond disappears, and the absorption peak of C in the alkyl trimethyl quaternary ammonium salt-N stretching vibration strengthens, and shows that all reaction is more complete between each monomer.
The resulting static inhibitor aqueous solution is product.This product is a light yellow transparent liquid, and testing its solid content is 27.62%, and pH is 8.4.Get the aqueous solution that this static inhibitor is made into 50g/L, polyester piece good is put in order, press FZ/T 01042-1996 " textile materials antistatic property, static voltage half life determination " method and testing its antistatic property on the H0110.V2 electrostatic attenuation tester and pressing the GB/T3921.1-1997 standard and test its washing fastness on washing fastness instrument WASHTEC-P, test result is as shown in table 2.
Antistatic property after the arrangement of table 2 polyester piece good
| Former cloth | After the antistatic finish | After washing 15 times | |
| Transformation period/s | >60 | 0.00 | 1.23 |
| Induction static voltage/kV | 2.09 | 0.00 | 0.45 |
Embodiment 3
1,10.5g (0.005mol) hyper-branched polyester is added in the reaction vessel, under 120 ℃, be heated to molten, open electric mixer and condensation reflux unit, behind the adding 0.04g Resorcinol, add vinylformic acid and the 13.00g toluene of 4.32g (0.060mol) again.
2, temperature is controlled at 110 ℃, when system forms homogeneous phase solution, adds the 0.08g tosic acid, back flow reaction 1 hour is cooled off in ice-water bath then.
3, products therefrom is dissolved in 18.80g N, in the dinethylformamide, adds the 0.20g solid sodium hydroxide, under constantly stirring, slowly drip 4.55g (0.030mol) chlorination Racemic glycidol trimethyl ammonium, answered 24 hours for 50 ℃.Decompress filter is removed solid.
4, remove and reclaim solvent.Be evacuated down to 0.10Mpa under 70 ℃, handled 0.5 hour, slough and reclaim N, dinethylformamide obtains the modified ultra-branching polyester.
5, modified ultra-branching polyester and acrylamide, glycidyl allyl ether, dimethyl diallyl ammonium chloride are dissolved in the 50g water by mass ratio 0.1:1:1:5 obtain monomer mixed solution, the 0.30g ammonium persulphate is dissolved in the 20g water and obtains catalyst solution.
6, in reaction vessel, add 2/5 above-mentioned monomer mixed solution and catalyst solution, open electric mixer and condensation reflux unit, be warming up to 90 ℃ after, drip off residue 3/5 monomer mixed solution and catalyst solution in 2 hours, insulation reaction 5 hours obtains the static inhibitor aqueous solution.
Referring to accompanying drawing 3, it is the infrared spectrum of hyper-branched polyester in the present embodiment, modified ultra-branching polyester and static inhibitor; Among the figure, curve 1 is a hyper-branched polyester, and curve 2 is the modified ultra-branching polyester, and curve 3 is a static inhibitor; Compare with 2 with embodiment 1, each absorption peak position of curve 2 is roughly the same, at 1640cm
-1And 910cm
-1New absorption peak appears in the place, is R-CH=CH
2The characteristic peak of vinyl is at 971cm
-1The absorption peak at place is the charateristic avsorption band of C in the alkyl trimethyl quaternary ammonium salt-N stretching vibration, illustrates that reaction has taken place for vinylformic acid, chlorination Racemic glycidol trimethyl ammonium and hyper-branched polyester; In the curve 3, the asymmetric stretching vibration absorption peak of epoxy group(ing) appears at 870cm
-1Place, 910cm simultaneously
-1The characteristic peak of place's vinyl double bond disappears, and the absorption peak of C in the alkyl trimethyl quaternary ammonium salt-N stretching vibration strengthens, and shows that all reaction is more complete between each monomer.
The resulting static inhibitor aqueous solution is product.This product is a light yellow transparent liquid, and testing its solid content is 26.67%, and pH is 8.0.Get the aqueous solution that this static inhibitor is made into 50g/L, polyester piece good is put in order, press FZ/T 01042-1996 " textile materials antistatic property, static voltage half life determination " method and testing its antistatic property on the H0110.V2 electrostatic attenuation tester and pressing the GB/T3921.1-1997 standard and test its washing fastness on washing fastness instrument WASHTEC-P, test result is as shown in table 3.
Antistatic property after the arrangement of table 3 polyester piece good
| Former cloth | After the antistatic finish | After washing 15 times | |
| Transformation period/s | >60 | 0.00 | 1.50 |
| Induction static voltage/kV | 2.09 | 0.03 | 0.65 |
Claims (5)
1. a preparation method who is used for the static inhibitor of polyester piece good is characterized in that comprising the steps:
(1) be raw material with modified ultra-branching polyester, acrylamide, glycidyl allyl ether, dimethyldiallylammonchloride chloride monomer, under the agitation condition, by mass ratio 0.1:1:1:3～5 each raw material is added to the water, obtains massfraction and be 25%～30% monomer mixed solution; The ammonium persulphate of monomer total mass 0.6%～1.0% is dissolved in the water, obtains initiator solution;
(2) get 0.2～0.4 part monomer mixed solution and initiator solution respectively, join under the agitation condition in the reaction vessel that condensation reflux unit is housed, be warming up to 80～90 ℃, in 2～3 hours, slowly drip remaining monomer mixed solution and initiator solution, after the insulation reaction 5～6 hours, be cooled to room temperature, obtain pH and be 8.0～9.0 light yellow transparent liquid, be the static inhibitor that is used for polyester piece good.
2. a kind of preparation method who is used for the static inhibitor of polyester piece good according to claim 1 is characterized in that: described modified ultra-branching polyester, and its synthetic method is:
(1) hyper-branched polyester Boltorn H20 is heated to molten state, add hydroquinone of polymerization retarder successively, vinylformic acid, toluene and catalyzer tosic acid, maintain the temperature at 100～110 ℃ and constantly react 1～1.5 h under the stirring condition after, place ice-water bath to cool off reaction mixture again, wherein, the Resorcinol consumption is 0.3～0.5% of a hyper-branched polyester quality, the vinylformic acid consumption is 25%～45% of a hyper-branched polyester quality, catalyzer tosic acid consumption is 0.5～1.0% of a hyper-branched polyester quality, and the toluene consumption is 1～2 times of hyper-branched polyester quality;
(2) product that step (1) is obtained is dissolved in N, in the dinethylformamide, add the catalyzer sodium hydrate solid, agitation condition slowly drips chlorination Racemic glycidol trimethyl ammonium down, react 12～24h under 40～50 ℃ temperature condition, decompress filter is removed sodium hydroxide; By mass, N, dinethylformamide are 1.5～2 times of hyper-branched polyester, and sodium hydrate solid is 3～5% of a chlorination Racemic glycidol trimethyl ammonium; Press the amount of substance ratio, chlorination Racemic glycidol trimethyl ammonium and vinylformic acid are 1:1～1:2;
(3) be that 60～70 ℃, vacuum tightness are to handle 0.5～1h under the condition of 0.09～0.10Mpa to the filtrate that obtains behind the suction filtration in temperature, obtain a kind of modified ultra-branching polyester, its general structure is:
，
Wherein, n is an integer, and 8≤n≤16.
3. a kind of preparation method who is used for the static inhibitor of polyester piece good according to claim 2 is characterized in that: press the amount of substance ratio, chlorination Racemic glycidol trimethyl ammonium and vinylformic acid are 1:1.5.
4. static inhibitor that is used for polyester piece good that obtains by claim 1 preparation method.
5. a static inhibitor as claimed in claim 4 is to the application in the antistatic finish of polyester piece good.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310169502.2A CN103214629B (en) | 2013-05-09 | 2013-05-09 | Antistatic agent for dacron textile and preparation method of antistatic agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310169502.2A CN103214629B (en) | 2013-05-09 | 2013-05-09 | Antistatic agent for dacron textile and preparation method of antistatic agent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103214629A true CN103214629A (en) | 2013-07-24 |
| CN103214629B CN103214629B (en) | 2014-11-05 |
Family
ID=48812826
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310169502.2A Expired - Fee Related CN103214629B (en) | 2013-05-09 | 2013-05-09 | Antistatic agent for dacron textile and preparation method of antistatic agent |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103214629B (en) |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104674550A (en) * | 2015-02-10 | 2015-06-03 | 浙江鑫涛纺织科技有限公司 | Method for preparing domestic shading curtain fabric with mould-proof, flame-retardant and anti-static performances |
| CN104727143A (en) * | 2015-03-19 | 2015-06-24 | 苏州陈恒织造有限公司 | Preparation method of composite antistatic agent for fiber fabric |
| CN105625031A (en) * | 2016-04-01 | 2016-06-01 | 广州闵邦化工有限公司 | Multifunctional finishing agent |
| CN107217487A (en) * | 2017-06-17 | 2017-09-29 | 常州琨瑶纺织品有限公司 | A kind of preparation method of dacron composite antistatic agent |
| CN108385393A (en) * | 2018-03-05 | 2018-08-10 | 江兵 | A kind of dacron antistatic agent and its application method |
| CN109322164A (en) * | 2018-09-28 | 2019-02-12 | 东华大学 | One kind is based on hyperbranched poly ester derivant multifunction finishing agent and its preparation and application |
| CN111733614A (en) * | 2020-07-28 | 2020-10-02 | 诸暨凯发实业有限公司 | Printing and dyeing process of cotton knitted fabric |
| CN112227070A (en) * | 2020-10-21 | 2021-01-15 | 宁波帕罗玛防坠落装备有限公司 | Modified polyester fiber woven tape and preparation method thereof |
| CN112522955A (en) * | 2020-12-02 | 2021-03-19 | 广西漫迪丽生物科技有限公司 | Preparation method of environmentally-friendly and durable fabric antistatic agent |
| CN115467163A (en) * | 2022-09-29 | 2022-12-13 | 淮阴工学院 | Preparation method of surface antistatic fiber fabric |
| CN116099492A (en) * | 2023-02-08 | 2023-05-12 | 杭州尚善若水环保科技有限公司 | Mineral agent for water recovery system and preparation method and application thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20100069601A1 (en) * | 2006-06-16 | 2010-03-18 | Baumer Raphael | Compositions based on hyperbranched condensation polymers and novel hyperbranched condensation polymers |
| CN102151234A (en) * | 2003-07-03 | 2011-08-17 | 马拉德·克里克聚合物公司 | Antimicrobial and antistatic polymers and methods of using such polymers on various substrates |
| CN102959011A (en) * | 2010-04-23 | 2013-03-06 | 拜耳知识产权有限责任公司 | Polymeric anti-static agent |
-
2013
- 2013-05-09 CN CN201310169502.2A patent/CN103214629B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102151234A (en) * | 2003-07-03 | 2011-08-17 | 马拉德·克里克聚合物公司 | Antimicrobial and antistatic polymers and methods of using such polymers on various substrates |
| US20100069601A1 (en) * | 2006-06-16 | 2010-03-18 | Baumer Raphael | Compositions based on hyperbranched condensation polymers and novel hyperbranched condensation polymers |
| CN102959011A (en) * | 2010-04-23 | 2013-03-06 | 拜耳知识产权有限责任公司 | Polymeric anti-static agent |
Non-Patent Citations (4)
| Title |
|---|
| YINGYING DU等: "Synthesis and Application of Long-Chain Alkyl Quarternary Ammonium-Functionalized Hyperbranched Polyester", 《JOURNAL OF APPLIED POLYMER SCIENCE》, vol. 121, 30 March 2011 (2011-03-30), pages 2927 - 2935 * |
| 刘晓云等: "PDMDAAC/AM在涤纶织物上的抗静电性能", 《纺织学报》, vol. 33, no. 8, 31 August 2012 (2012-08-31), pages 92 - 96 * |
| 杜英英等: "超支化聚酯季铵盐的合成与表征", 《印染助剂》, vol. 28, no. 5, 31 May 2011 (2011-05-31), pages 15 - 18 * |
| 陈焜等: "超支化聚酯季铵盐抗静电剂的合成及其应用", 《印染》, no. 9, 1 May 2013 (2013-05-01), pages 1 - 4 * |
Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104674550A (en) * | 2015-02-10 | 2015-06-03 | 浙江鑫涛纺织科技有限公司 | Method for preparing domestic shading curtain fabric with mould-proof, flame-retardant and anti-static performances |
| CN104727143A (en) * | 2015-03-19 | 2015-06-24 | 苏州陈恒织造有限公司 | Preparation method of composite antistatic agent for fiber fabric |
| CN105625031A (en) * | 2016-04-01 | 2016-06-01 | 广州闵邦化工有限公司 | Multifunctional finishing agent |
| CN107217487A (en) * | 2017-06-17 | 2017-09-29 | 常州琨瑶纺织品有限公司 | A kind of preparation method of dacron composite antistatic agent |
| CN107217487B (en) * | 2017-06-17 | 2019-06-21 | 揭阳市庆兴化纤实业有限公司 | A kind of preparation method of dacron composite antistatic agent |
| CN108385393A (en) * | 2018-03-05 | 2018-08-10 | 江兵 | A kind of dacron antistatic agent and its application method |
| CN109322164A (en) * | 2018-09-28 | 2019-02-12 | 东华大学 | One kind is based on hyperbranched poly ester derivant multifunction finishing agent and its preparation and application |
| CN111733614A (en) * | 2020-07-28 | 2020-10-02 | 诸暨凯发实业有限公司 | Printing and dyeing process of cotton knitted fabric |
| CN112227070A (en) * | 2020-10-21 | 2021-01-15 | 宁波帕罗玛防坠落装备有限公司 | Modified polyester fiber woven tape and preparation method thereof |
| CN112227070B (en) * | 2020-10-21 | 2022-11-11 | 宁波帕罗玛防坠落装备有限公司 | Modified polyester fiber woven tape and preparation method thereof |
| CN112522955A (en) * | 2020-12-02 | 2021-03-19 | 广西漫迪丽生物科技有限公司 | Preparation method of environmentally-friendly and durable fabric antistatic agent |
| CN112522955B (en) * | 2020-12-02 | 2021-11-05 | 浙江轩日科技股份有限公司 | Preparation method of environmentally-friendly and durable fabric antistatic agent |
| CN115467163A (en) * | 2022-09-29 | 2022-12-13 | 淮阴工学院 | Preparation method of surface antistatic fiber fabric |
| CN115467163B (en) * | 2022-09-29 | 2023-12-08 | 淮阴工学院 | Preparation method of surface antistatic fiber fabric |
| CN116099492A (en) * | 2023-02-08 | 2023-05-12 | 杭州尚善若水环保科技有限公司 | Mineral agent for water recovery system and preparation method and application thereof |
| CN116099492B (en) * | 2023-02-08 | 2023-09-12 | 杭州尚善若水环保科技有限公司 | Mineral agent for water recovery system and preparation method and application thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103214629B (en) | 2014-11-05 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103214629B (en) | Antistatic agent for dacron textile and preparation method of antistatic agent | |
| CN106555248B (en) | The preparation method of moisture absorption acrylic fibers | |
| CN107043466B (en) | A kind of modification of chitosan-silicon dioxide composite aerogel material and its preparation method and application | |
| CN105368150B (en) | A kind of water-based weather-proof glass ink | |
| CN103232826B (en) | Heat-stabilized acrylate adhesive used for waterproof coiled material blank base cloth, and preparation method thereof | |
| CN114086421B (en) | Fluorine-free waterproof and oil-proof agent and preparation method and application thereof | |
| CN103483491A (en) | Carbomer and preparation method thereof | |
| TW201345934A (en) | Polymers, polymer blends, and flame retardant materials | |
| CN102643390B (en) | Cationic grafted starch and preparation method thereof | |
| CN106146694B (en) | A kind of polyaniline nano-composite material and its preparation method and application | |
| CN102199263B (en) | Amphiphobic fluoro-containing crosslinkable block copolymer and preparation method and application thereof | |
| CN104861113B (en) | Alcoxyl ethers temperature sensitive polymer nanoparticle and preparation method thereof | |
| CN104927064B (en) | A kind of preparation method of the high molecular dye based on hyperbranched polyurethane | |
| CN106832278A (en) | One class high transparency copoly type fluorine-containing polyimide film material and preparation method thereof | |
| CN104562708A (en) | Preparation method for antistatic terylene tablecloth | |
| Zhang et al. | Synthesis, characterization and properties of a novel fluorinated methacrylate polymer | |
| CN103113569A (en) | Hyper-branched unsaturated resin and application thereof | |
| CN103214674B (en) | Method for efficiently producing an organic silicone resin microsphere | |
| CN104592483A (en) | Environment-friendly polyurethane curing agent as well as preparation method and application of curing agent | |
| CN107574666A (en) | A kind of durable antistatic agent and its preparation method and application | |
| CN110423333A (en) | A kind of soft cryobranding color-changing polyurethane resin and its preparation method and application | |
| CN106496557A (en) | A kind of preparation method of high transparency high temperature resistant fluorinated polyimide resin | |
| CN107434851B (en) | Preparation method of photosensitive hydrogel | |
| CN105755865B (en) | A kind of hyperbranched dyeing assistant is improving the chromatic application of superfine fiber polyurethane leather | |
| CN110863261A (en) | Phase-change temperature-regulating composite fiber with chitosan as matrix and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| EE01 | Entry into force of recordation of patent licensing contract |
Application publication date: 20130724 Assignee: SUZHOU YISITE NEW MATERIAL TECHNOLOGY CO., LTD. Assignor: Soochow University Contract record no.: 2015320010060 Denomination of invention: Antistatic agent for dacron textile and preparation method of antistatic agent Granted publication date: 20141105 License type: Exclusive License Record date: 20150511 |
|
| LICC | Enforcement, change and cancellation of record of contracts on the licence for exploitation of a patent or utility model | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20141105 Termination date: 20190509 |
|
| CF01 | Termination of patent right due to non-payment of annual fee |