CN107384414A - Rice field heavy metal absorbent - Google Patents
Rice field heavy metal absorbent Download PDFInfo
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- CN107384414A CN107384414A CN201710510155.3A CN201710510155A CN107384414A CN 107384414 A CN107384414 A CN 107384414A CN 201710510155 A CN201710510155 A CN 201710510155A CN 107384414 A CN107384414 A CN 107384414A
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- parts
- heavy metal
- rice field
- soil
- metal absorbent
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K17/00—Soil-conditioning materials or soil-stabilising materials
- C09K17/40—Soil-conditioning materials or soil-stabilising materials containing mixtures of inorganic and organic compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B09—DISPOSAL OF SOLID WASTE; RECLAMATION OF CONTAMINATED SOIL
- B09C—RECLAMATION OF CONTAMINATED SOIL
- B09C1/00—Reclamation of contaminated soil
- B09C1/08—Reclamation of contaminated soil chemically
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K2101/00—Agricultural use
Abstract
The invention discloses a kind of rice field heavy metal absorbent, mainly it is made up of following raw material：Peat, biological carbon, vinasse, marine alga, bentonite, volcano lime, citric acid, humic acid, oyster shell whiting, ground phosphate rock, diatomite, furfural dregs and filter mud.Rice field heavy metal absorbent of the present invention, after heavy metal contaminated soil carries out adsorption treatment, the adsorption effect of heavy metal absorbent is good.Heavy metal element in the thorough strong adsorption soil of energy, it is set to cannot participate in cation exchange, it will be exchanged to the heavy metal adsorbed in the soil liquid, the heavy metal of plant absorption is available in soil to be largely reduced in allowable range, solves soil compaction phenomenon simultaneously, soil is become soft, it is solid to be not easy knot.Application method is simple, and adsorbent is dissipated such as Tanaka, and is discharged water toward Tanaka, then beats field with tractor, is mixed into soil, mixes and stands a period of time afterwards, to be adsorbed dose with the heavy metal reaction absorption of Tanaka, the heavy metal ion that removal Tanaka dissociates.
Description
Technical field
The present invention relates to heavy metal to administer field, more particularly to a kind of rice field heavy metal absorbent.
Background technology
Reservoir is one of widely used engineering measure of China's flood control.Being built in flood control zone upper river appropriate location to adjust
The multiple purpose reservoir of flood storage water, using reservoir capacity water conservation, the crest discharge into downstream river course is cut down, reaches deduction and exemption
The purpose of flood damage.Reservoir has two kinds of different modes to the adjustment effect of flood, and one kind plays retention effect of lake, and another kind plays flood storage
Effect.
Heavy metal refers to the metal that proportion is equal to or more than 5.0, such as Fe, Mn, Zn, Cd, Hg, Ni, Co；As is a kind of accurate
Metal, but because its chemical property and environmental behaviour have similarity more with heavy metal, therefore frequently included when discussing heavy metal
Arsenic, some are then directly included into the range of heavy metal.Because iron and manganese content are higher in soil, thus it is generally acknowledged that them
It is not soil pollution element, but under strong reducing condition, the murder by poisoning caused by iron and manganese also causes enough attention.China is multiple
It is exceeded that the rice produced is found cadmium, and soil pollution is into " public hazards ".The appearance of " cadmium rice crisis ", beats soil pollution again
Alarm bell.In the season that amount of rainfall is larger, the water of upstream is washed into reservoir, and life of the reservoir generally also as resident nearby is used
Water.The water quality of reservoir is polluted if subjected to heavy metal pollution, then easily immerse reservoir by rain drop erosion for the soil of upstream.Soil
It is contaminated, after Planting Crops, crops absorb the heavy metal in soil, can cause crop production reduction or the product of crops
Matter is affected.
The information for being disclosed in the background section is merely intended to understanding of the increase to the general background of the present invention, without answering
It has been the prior art well known to persons skilled in the art when being considered as recognizing or implying the information structure in any form.
The content of the invention
It is an object of the invention to provide a kind of rice field heavy metal absorbent, so as to overcome soil by heavy metal pollution,
The inapparent shortcoming of regulation effect.
It is another object of the present invention to provide a kind of preparation method of rice field heavy metal absorbent, and provide rice field
The application method of heavy metal absorbent.
To achieve the above object, the invention provides a kind of rice field heavy metal absorbent, mainly it is made up of following raw material：Mud
Charcoal, biological carbon, vinasse, marine alga, bentonite, volcano lime, citric acid, humic acid, oyster shell whiting, ground phosphate rock, diatomite, furfural dregs
And filter mud.
Preferably, in above-mentioned technical proposal, described rice field heavy metal absorbent, count in parts by weight, mainly by following
Raw material is made：Peat 33-55 parts, biological carbon 12-25 parts, vinasse 5-15 parts, marine alga 17-27 parts, bentonite 12-25 parts, volcano
Lime 9-17 parts, citric acid 3-9 parts, humic acid 10-15 parts, oyster shell whiting 5-18 parts, ground phosphate rock 5-14 parts, diatomite 9-18 parts,
Furfural dregs 11-24 parts and filter mud 23-35 parts.
Preferably, in above-mentioned technical proposal, described rice field heavy metal absorbent, count in parts by weight, mainly by following
Raw material is made：45 parts of peat, 17 parts of biological carbon, 9 parts of vinasse, 23 parts of marine alga, 17 parts of bentonite, 12 parts of volcano lime, citric acid 6
Part, 12 parts of humic acid, 12 parts of oyster shell whiting, 8 parts of ground phosphate rock, 13 parts of diatomite, 17 parts of furfural dregs and 29 parts of filter mud.
A kind of preparation method of rice field heavy metal absorbent, comprises the following steps：
(1) peat, vinasse, marine alga, humic acid, filter mud and aerobic fermentation bacterium are well mixed, heap piles up temperature as 20 DEG C
More than, fermentation obtains mixed fermentation thing in 10-20 days；
(2) by mixed fermentation thing made from step (1) with, biological carbon, bentonite, volcano lime, citric acid, oyster shell whiting,
Ground phosphate rock, diatomite, furfural dregs are well mixed, and obtain rice field heavy metal absorbent.
Preferably, in above-mentioned technical proposal, the aerobic fermentation bacterium is VT zymophytes, and its dosage is marine alga quality
0.03-0.1%.
A kind of application method of rice field heavy metal absorbent, comprises the following steps：Every mu is applied 400-500 kilograms of rice field weight
Metal absorbent, uniformly give in farmland, Tanaka there need to be water, then beat field with tractor, be mixed into soil, quiet after mixing
Put 3-10 days, the water during this in paddy field, which does not enter, also not to be gone out.
Compared with prior art, the present invention has the advantages that：
(1) rice field heavy metal absorbent of the present invention, after heavy metal contaminated soil carries out adsorption treatment, heavy metal absorbent
Adsorption effect it is good.Heavy metal element in the thorough strong adsorption soil of energy, makes it cannot participate in cation exchange, will be with suction
Attached heavy metal firmly is exchanged in the soil liquid, and model can be allowed by being available for the heavy metal of plant absorption to be largely reduced in soil
In enclosing, while solve soil compaction phenomenon, soil is become soft, it is solid to be not easy knot.And preparation method is simple, it is easy to produce.
(2) adsorbent application method of the present invention is simple, and adsorbent dissipates such as Tanaka, and is discharged water toward Tanaka, then uses tractor
Field is beaten, is mixed into soil, mixes and stands a period of time afterwards, to be adsorbed dose adsorbs with the reaction of the heavy metal of Tanaka, removal Tanaka
Free heavy metal ion.
Embodiment
With reference to specific embodiment, the embodiment of the present invention is described in detail, it is to be understood that this hair
Bright protection domain is not limited by embodiment.
Embodiment 1
A kind of rice field heavy metal absorbent, is counted in parts by weight, is mainly made up of following raw material：45 parts of peat, biological carbon
17 parts, 9 parts of vinasse, 23 parts of marine alga, 17 parts of bentonite, 12 parts of volcano lime, 6 parts of citric acid, 12 parts of humic acid, oyster shell whiting 12
Part, 8 parts of ground phosphate rock, 13 parts of diatomite, 17 parts of furfural dregs and 29 parts of filter mud.
A kind of preparation method of rice field heavy metal absorbent, comprises the following steps：
(1) peat, vinasse, marine alga, humic acid, filter mud and aerobic fermentation bacterium are well mixed, aerobic fermentation bacterium sends out for VT
Yeast-like fungi, its dosage are the 0.06% of marine alga quality, and heap piles up temperature as more than 20 DEG C, and fermentation obtains mixed fermentation thing in 16 days；
(2) by mixed fermentation thing made from step (1) with, biological carbon, bentonite, volcano lime, citric acid, oyster shell whiting,
Ground phosphate rock, diatomite, furfural dregs are well mixed, and obtain rice field heavy metal absorbent.
Rice field heavy metal absorbent is used in field, application method comprises the following steps：450 kilograms of rice field weights of every mu of administration
Metal absorbent, uniformly give in farmland, Tanaka there need to be water, then beat field with tractor, and field is beaten more thin better, will adsorbed
Agent is mixed into soil, is mixed and is stood 7 days afterwards, the water during this in paddy field, which does not enter, also not to be gone out.
Heavy metal-polluted soil processing experiment：It is native as trying soil sample by the table in the rice field of heavy metal using Guangxi Fangcheng Port.Institute
The heavy metal contained has cadmium, chromium, lead etc., pedotheque is air-dried after grinding, standby by being collected after 10-mesh screen clothes, with chloroazotic acid
Digestion method and ICP-AES analysis heavy metal content in soil.Cadmium in soil is predominantly detected, the tenor of chromium, uses the present embodiment
Rice field heavy metal absorbent is handled soil sample, and cadmium content reduces by 24.3% in rice field, and chromium content reduces by 21.1%, lead content
Reduce by 22.3%.
Embodiment 2
A kind of rice field heavy metal absorbent, is counted in parts by weight, is mainly made up of following raw material：33 parts of peat, biological carbon
25 parts, 15 parts of vinasse, 17 parts of marine alga, 25 parts of bentonite, 9 parts of volcano lime, 3 parts of citric acid, 10 parts of humic acid, oyster shell whiting 18
Part, 5 parts of ground phosphate rock, 9 parts of diatomite, 24 parts of furfural dregs and 23 parts of filter mud.
A kind of preparation method of rice field heavy metal absorbent, comprises the following steps：
(1) peat, vinasse, marine alga, humic acid, filter mud and aerobic fermentation bacterium are well mixed, aerobic fermentation bacterium sends out for VT
Yeast-like fungi, its dosage are the 0.03% of marine alga quality, and heap piles up temperature as more than 20 DEG C, and fermentation obtains mixed fermentation thing in 20 days；
(2) by mixed fermentation thing made from step (1) with, biological carbon, bentonite, volcano lime, citric acid, oyster shell whiting,
Ground phosphate rock, diatomite, furfural dregs are well mixed, and obtain rice field heavy metal absorbent.
Rice field heavy metal absorbent is used in field, application method comprises the following steps：400 kilograms of rice field weights of every mu of administration
Metal absorbent, uniformly give in farmland, Tanaka there need to be water, then beat field with tractor, and field is beaten more thin better, will adsorbed
Agent is mixed into soil, is mixed and is stood 10 days afterwards, the water during this in paddy field, which does not enter, also not to be gone out.
Heavy metal-polluted soil processing experiment：It is native as trying soil sample by the table in the rice field of heavy metal using tourist resources.
Contained heavy metal has cadmium, chromium, lead etc., pedotheque is air-dried after grinding, standby by being collected after 10-mesh screen clothes, with king
Water digestion method and ICP-AES analysis heavy metal content in soil.Cadmium in soil is predominantly detected, the tenor of chromium, uses this implementation
Example rice field heavy metal absorbent is handled soil sample, and cadmium content reduces by 23.8% in rice field, and chromium content reduces by 20.8%, and lead contains
Amount reduces by 21.6%.
Embodiment 3
A kind of rice field heavy metal absorbent, is counted in parts by weight, is mainly made up of following raw material：55 parts of peat, biological carbon
12 parts, 5 parts of vinasse, 27 parts of marine alga, 12 parts of bentonite, 17 parts of volcano lime, 9 parts of citric acid, 15 parts of humic acid, 5 parts of oyster shell whiting,
35 parts of 14 parts of ground phosphate rock, 18 parts of diatomite, 11 parts of furfural dregs and filter mud.
A kind of preparation method of rice field heavy metal absorbent, comprises the following steps：
(1) peat, vinasse, marine alga, humic acid, filter mud and aerobic fermentation bacterium are well mixed, aerobic fermentation bacterium sends out for VT
Yeast-like fungi, its dosage are the 0.1% of marine alga quality, and heap piles up temperature as more than 20 DEG C, and fermentation obtains mixed fermentation thing in 10 days；
(2) by mixed fermentation thing made from step (1) with, biological carbon, bentonite, volcano lime, citric acid, oyster shell whiting,
Ground phosphate rock, diatomite, furfural dregs are well mixed, and obtain rice field heavy metal absorbent.
Soil heavy mental adsorbent is used in field, application method comprises the following steps：500 kilograms of soil weights of every mu of administration
Metal absorbent, uniformly give in farmland, Tanaka there need to be water, then beat field with tractor, and field is beaten more thin better, will adsorbed
Agent is mixed into soil, is mixed and is stood 3 days afterwards, the water during this in paddy field, which does not enter, also not to be gone out.
Heavy metal-polluted soil processing experiment：It is native as trying soil sample by the table in the rice field of heavy metal using Guangxi Fangcheng Port.Institute
The heavy metal contained has cadmium, chromium, lead etc., pedotheque is air-dried after grinding, standby by being collected after 10-mesh screen clothes, with chloroazotic acid
Digestion method and ICP-AES analysis heavy metal content in soil.Cadmium in soil is predominantly detected, the tenor of chromium, uses the present embodiment
Rice field heavy metal absorbent is handled soil sample, and cadmium content reduces by 23.9% in rice field, and chromium content reduces by 21.0%, lead content
Reduce by 22.4%.
Embodiment 4
A kind of rice field heavy metal absorbent, is counted in parts by weight, is mainly made up of following raw material：45 parts of peat, biological carbon
17 parts, 17 parts of bentonite, 12 parts of volcano lime, 6 parts of citric acid, 12 parts of oyster shell whiting, 8 parts of ground phosphate rock, 13 parts of diatomite, furfural dregs
17 parts and 29 parts of filter mud.
A kind of preparation method of rice field heavy metal absorbent, comprises the following steps：
(1) peat, filter mud and aerobic fermentation bacterium are well mixed, aerobic fermentation bacterium is VT zymophytes, and its dosage is filter mud
The 0.06% of quality, heap pile up temperature as more than 20 DEG C, and fermentation obtains mixed fermentation thing in 16 days；
(2) by mixed fermentation thing made from step (1) with, biological carbon, bentonite, volcano lime, citric acid, oyster shell whiting,
Ground phosphate rock, diatomite, furfural dregs are well mixed, and obtain rice field heavy metal absorbent.
Heavy metal-polluted soil processing experiment：It is native as trying soil sample by the table in the rice field of heavy metal using tourist resources.
Contained heavy metal has cadmium, chromium, lead etc., pedotheque is air-dried after grinding, standby by being collected after 10-mesh screen clothes, with king
Water digestion method and ICP-AES analysis heavy metal content in soil.Cadmium in soil is predominantly detected, the tenor of chromium, uses this implementation
Example rice field heavy metal absorbent is handled soil sample, and cadmium content reduces by 18.2% in rice field, and chromium content reduces by 17.4%, and lead contains
Amount reduces by 16.3%.
The description of the foregoing specific illustrative embodiment to the present invention is to illustrate and the purpose of illustration.These descriptions
It is not wishing to limit the invention to disclosed precise forms, and it will be apparent that according to above-mentioned teaching, can be much changed
And change.The purpose of selecting and describing the exemplary embodiment is that explain that the certain principles of the present invention and its reality should
With so that those skilled in the art can realize and utilize the present invention a variety of exemplaries and
Various chooses and changes.The scope of the present invention is intended to be limited by claims and its equivalents.
Claims (6)
1. a kind of rice field heavy metal absorbent, it is characterised in that be mainly made up of following raw material：Peat, biological carbon, vinasse, sea
Algae, bentonite, volcano lime, citric acid, humic acid, oyster shell whiting, ground phosphate rock, diatomite, furfural dregs and filter mud.
2. rice field heavy metal absorbent according to claim 1, it is characterised in that count in parts by weight, mainly by following
Raw material is made：Peat 33-55 parts, biological carbon 12-25 parts, vinasse 5-15 parts, marine alga 17-27 parts, bentonite 12-25 parts, volcano
Lime 9-17 parts, citric acid 3-9 parts, humic acid 10-15 parts, oyster shell whiting 5-18 parts, ground phosphate rock 5-14 parts, diatomite 9-18 parts,
Furfural dregs 11-24 parts and filter mud 23-35 parts.
3. rice field heavy metal absorbent according to claim 1, it is characterised in that count in parts by weight, mainly by following
Raw material is made：45 parts of peat, 17 parts of biological carbon, 9 parts of vinasse, 23 parts of marine alga, 17 parts of bentonite, 12 parts of volcano lime, citric acid 6
Part, 12 parts of humic acid, 12 parts of oyster shell whiting, 8 parts of ground phosphate rock, 13 parts of diatomite, 17 parts of furfural dregs and 29 parts of filter mud.
4. the preparation method of the rice field heavy metal absorbent described in a kind of claim 1, it is characterised in that comprise the following steps：
(1) peat, vinasse, marine alga, humic acid, filter mud and aerobic fermentation bacterium being well mixed, heap piles up temperature as more than 20 DEG C,
Fermentation obtains mixed fermentation thing in 10-20 days；
(2) by mixed fermentation thing made from step (1) with, biological carbon, bentonite, volcano lime, citric acid, oyster shell whiting, phosphorus ore
Powder, diatomite, furfural dregs are well mixed, and obtain rice field heavy metal absorbent.
5. the preparation method of rice field heavy metal absorbent according to claim 4, it is characterised in that the aerobic fermentation bacterium is
VT zymophytes, its dosage are the 0.03-0.1% of marine alga quality.
6. the application method of the rice field heavy metal absorbent described in a kind of claim 1, it is characterised in that comprise the following steps：
Every mu is applied 400-500 kilograms of rice field heavy metal absorbent, is uniformly given in farmland, Tanaka need to have water, then use tractor
Field is beaten, is mixed into soil, mixes and stands 3-10 days afterwards, the water during this in paddy field, which does not enter, also not to be gone out.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710510155.3A CN107384414A (en) | 2017-06-28 | 2017-06-28 | Rice field heavy metal absorbent |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710510155.3A CN107384414A (en) | 2017-06-28 | 2017-06-28 | Rice field heavy metal absorbent |
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| CN107384414A true CN107384414A (en) | 2017-11-24 |
Family
ID=60333785
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| CN201710510155.3A Pending CN107384414A (en) | 2017-06-28 | 2017-06-28 | Rice field heavy metal absorbent |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108326038A (en) * | 2017-12-27 | 2018-07-27 | 华中农业大学 | Purposes of the vinasse in activating soil arsenic and in increasing soil fertility |
| CN108728107A (en) * | 2018-05-25 | 2018-11-02 | 合肥慧谷农业科技有限公司 | A kind of soil conditioner and preparation method thereof handling heavy metal |
| CN108841398A (en) * | 2018-08-09 | 2018-11-20 | 北京泷涛环境修复有限公司 | Medicament, preparation method and restorative procedure are repaired in passivation for As polluted soil |
| CN110452705A (en) * | 2019-07-31 | 2019-11-15 | 安徽禾美环保集团有限公司 | A kind of heavy metal pollution of soil renovation agent and preparation method thereof |
| CN110885265A (en) * | 2018-09-08 | 2020-03-17 | 深圳市夸克生物科技有限公司 | Soil rejuvenation ecological fertilizer and preparation method thereof |
| CN114031461A (en) * | 2021-10-26 | 2022-02-11 | 中冶南方都市环保工程技术股份有限公司 | Organic silicon fertilizer for reducing chromium and arsenic content in rice and preparation method and application thereof |
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| CN105435752A (en) * | 2016-01-05 | 2016-03-30 | 郭菲 | Heavy metal ions absorbent and preparation method thereof |
| CN106495939A (en) * | 2016-10-14 | 2017-03-15 | 上海诺同农业科技有限公司 | Heavy metal-polluted soil renovation agent, preparation method and application |
| CN106669609A (en) * | 2016-12-27 | 2017-05-17 | 河南八灵电子科技有限公司 | Heavy metal adsorbent and preparation method thereof |
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| CN102389776A (en) * | 2011-10-09 | 2012-03-28 | 广东省生态环境与土壤研究所 | Metal heavy absorbent and preparation method and use thereof |
| CN105435752A (en) * | 2016-01-05 | 2016-03-30 | 郭菲 | Heavy metal ions absorbent and preparation method thereof |
| CN106495939A (en) * | 2016-10-14 | 2017-03-15 | 上海诺同农业科技有限公司 | Heavy metal-polluted soil renovation agent, preparation method and application |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108326038A (en) * | 2017-12-27 | 2018-07-27 | 华中农业大学 | Purposes of the vinasse in activating soil arsenic and in increasing soil fertility |
| CN108728107A (en) * | 2018-05-25 | 2018-11-02 | 合肥慧谷农业科技有限公司 | A kind of soil conditioner and preparation method thereof handling heavy metal |
| CN108841398A (en) * | 2018-08-09 | 2018-11-20 | 北京泷涛环境修复有限公司 | Medicament, preparation method and restorative procedure are repaired in passivation for As polluted soil |
| CN110885265A (en) * | 2018-09-08 | 2020-03-17 | 深圳市夸克生物科技有限公司 | Soil rejuvenation ecological fertilizer and preparation method thereof |
| CN110452705A (en) * | 2019-07-31 | 2019-11-15 | 安徽禾美环保集团有限公司 | A kind of heavy metal pollution of soil renovation agent and preparation method thereof |
| CN114031461A (en) * | 2021-10-26 | 2022-02-11 | 中冶南方都市环保工程技术股份有限公司 | Organic silicon fertilizer for reducing chromium and arsenic content in rice and preparation method and application thereof |
| CN114031461B (en) * | 2021-10-26 | 2023-07-14 | 中冶南方都市环保工程技术股份有限公司 | Organic silicon fertilizer for reducing chromium and arsenic content in rice, and preparation method and application thereof |
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Application publication date: 20171124 |