CN107384183A - A kind of ultra-thin coating and preparation method thereof - Google Patents

A kind of ultra-thin coating and preparation method thereof Download PDF

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Publication number
CN107384183A
CN107384183A CN201710690467.7A CN201710690467A CN107384183A CN 107384183 A CN107384183 A CN 107384183A CN 201710690467 A CN201710690467 A CN 201710690467A CN 107384183 A CN107384183 A CN 107384183A
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CN
China
Prior art keywords
ultra
initiator
film
preparation
thin coating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710690467.7A
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Chinese (zh)
Inventor
姜阀
孙庆兵
吴瑞华
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Anhui Kangrui High-Tech New Material Technology Engineering Co Ltd
Original Assignee
Anhui Kangrui High-Tech New Material Technology Engineering Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Anhui Kangrui High-Tech New Material Technology Engineering Co Ltd filed Critical Anhui Kangrui High-Tech New Material Technology Engineering Co Ltd
Priority to CN201710690467.7A priority Critical patent/CN107384183A/en
Publication of CN107384183A publication Critical patent/CN107384183A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • C09D175/14Polyurethanes having carbon-to-carbon unsaturated bonds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/32Phosphorus-containing compounds
    • C08K2003/321Phosphates
    • C08K2003/322Ammonium phosphate
    • C08K2003/323Ammonium polyphosphate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The invention discloses a kind of ultra-thin coating and preparation method thereof.Its main constituents and weight proportion are:Polyurethane acrylic resin 20% 29%, polyphosphoric acid ammonia 25% 28%, initiator 1.5% 3.5%, titanium dioxide 20% 24%, acrylic acid 0.8% 1%, fluorine richness surfactant 0.5% 1%, chlorinated paraffin 20.5% 22.5%, solvent 15% 20%, hollow glass microbead 3% 7%.It provides a kind of ultra-thin coating and preparation method thereof to the present invention, and it is mainly suitable for wet environment decline low-heat construction equipment surface temperature and is lost in and reduces equipment energy consumption.

Description

A kind of ultra-thin coating and preparation method thereof
Technical field
The present invention relates to technical field of coatings, specially a kind of ultra-thin coating and preparation method thereof.
Background technology
Coating is that one kind can firmly be covered in body surface protection, decoration, sign industry, with the continuous hair of economy Exhibition, scientific and technical continuous progress, its application field is also increasingly wider, and in some application fields, such as thermal technology's kind equipment, its is right Surface heat-insulating property has certain requirement, and as surface heat-insulating property is poor, then it is higher to easily cause surface temperature, especially causes big Heat losses are measured, therefore there is the coating of insulation by applying last layer on surface, are the effective ways for solving this problem Footpath.
The content of the invention
It is an object of the invention to provide a kind of ultra-thin coating and preparation method thereof, and it is mainly suitable for reducing under wet environment Thermal Equipment surface temperature is lost in and reduces equipment energy consumption.
The technical problems to be solved by the invention are realized using following technical scheme:
A kind of ultra-thin coating, its main constituents and weight proportion are:Polyurethane acrylic resin 20%-29%, polyphosphoric acid ammonia 25%-28%, initiator 1.5%-3.5%, titanium dioxide 20%-24%, acrylic acid 0.8%-1%, fluorine richness surfactant 0.5%-1%, chlorinated paraffin 20.5%-22.5%, solvent 15%-20%, hollow glass microbead 3%-7%.
Initiator:For cracking type initiator, UV energy is can absorb, the energy needed for functional group is provided for film;
Titanium dioxide:Assign the more preferable ductility of film;
Acrylic acid:Wetting is provided for coating, improves film coated surface tension force;
Fluorine richness surfactant:Film levelability is provided, improves film coated surface activity.
A kind of preparation method of ultra-thin coating, its preparation flow mainly include the following steps that:
(1)Stock:By polyurethane acrylic resin, polyphosphoric acid ammonia, initiator, titanium dioxide, acrylic acid, fluorine richness surface Activating agent, chlorinated paraffin, solvent and hollow glass microbead are stocked up according to above-mentioned weight proportion;
(2)Batch mixing:By initiator and stirring solvent to being completely dissolved, polyurethane acrylic resin, polyphosphoric acid ammonia, titanium are sequentially added White powder, acrylic acid, fluorine richness surfactant, chlorinated paraffin and hollow glass microbead, stir, are applied Material;
(3)Try film:On experimental products film it is above-mentioned made of coating, stand to being completely dried;
(4)Performance test:After test products film is completely dried, to its surface resistance to 99.5% absolute ethyl alcohol 500g power back and forth 500 Secondary, film is without show-through;The not bottom drain of the paper tape of resistance to RCA 175g power wear-resisting test 200 times;Cross-cut methods adhesive force 100% is tested, 0 grade;
(5)Finished product packing:Step will be passed through(4)The coating of performance test carries out finished product packing.
The beneficial effects of the invention are as follows:It provides a kind of ultra-thin coating and preparation method thereof, and it is mainly suitable for wet environment Decline low-heat construction equipment surface temperature to be lost in and reduce equipment energy consumption.
Embodiment
The technical scheme in the embodiment of the present invention is clearly and completely described below, it is clear that described embodiment Only part of the embodiment of the present invention, rather than whole embodiments.Based on the embodiment in the present invention, the common skill in this area The every other embodiment that art personnel are obtained under the premise of creative work is not made, belong to the model that the present invention protects Enclose.
A kind of ultra-thin coating, its main constituents and weight proportion are:Polyurethane acrylic resin 20%-29%, poly- phosphorus Sour ammonia 25%-28%, initiator 1.5%-3.5%, titanium dioxide 20%-24%, acrylic acid 0.8%-1%, fluorine richness surface-active Agent 0.5%-1%, chlorinated paraffin 20.5%-22.5%, solvent 15%-20%, hollow glass microbead 3%-7%.
Initiator:For cracking type initiator, UV energy is can absorb, the energy needed for functional group is provided for film;
Titanium dioxide:Assign the more preferable ductility of film;
Acrylic acid:Wetting is provided for coating, improves film coated surface tension force;
Fluorine richness surfactant:Film levelability is provided, improves film coated surface activity.
A kind of preparation method of ultra-thin coating, its preparation flow mainly include the following steps that:
(1)Stock:By polyurethane acrylic resin, polyphosphoric acid ammonia, initiator, titanium dioxide, acrylic acid, fluorine richness surface Activating agent, chlorinated paraffin, solvent and hollow glass microbead are stocked up according to above-mentioned weight proportion;
(2)Batch mixing:By initiator and stirring solvent to being completely dissolved, polyurethane acrylic resin, polyphosphoric acid ammonia, titanium are sequentially added White powder, acrylic acid, fluorine richness surfactant, chlorinated paraffin and hollow glass microbead, stir, are applied Material;
(3)Try film:On experimental products film it is above-mentioned made of coating, stand to being completely dried;
(4)Performance test:After test products film is completely dried, to its surface resistance to 99.5% absolute ethyl alcohol 500g power back and forth 500 Secondary, film is without show-through;The not bottom drain of the paper tape of resistance to RCA 175g power wear-resisting test 200 times;Cross-cut methods adhesive force 100% is tested, 0 grade;
(5)Finished product packing:Step will be passed through(4)The coating of performance test carries out finished product packing.
Embodiment 1:
Polyurethane acrylic resin 20%, polyphosphoric acid ammonia 25%, initiator 2%, titanium dioxide 20%, acrylic acid 0.8%, fluorine changes Property surfactant 0.5%, chlorinated paraffin 20.5%, solvent 15%, hollow glass microbead 3%.
Finally it should be noted that:The preferred embodiments of the present invention are the foregoing is only, are not intended to limit the invention, Although the present invention is described in detail with reference to the foregoing embodiments, for those skilled in the art, it still may be used To be modified to the technical scheme described in foregoing embodiments, or equivalent substitution is carried out to which part technical characteristic, Within the spirit and principles of the invention, any modification, equivalent substitution and improvements made etc., it should be included in the present invention's Within protection domain.

Claims (2)

1. a kind of ultra-thin coating, it is characterised in that its main constituents and weight proportion are:Polyurethane acrylic resin 20%- 29%, polyphosphoric acid ammonia 25%-28%, initiator 1.5%-3.5%, titanium dioxide 20%-24%, acrylic acid 0.8%-1%, fluorine richness Surfactant 0.5%-1%, chlorinated paraffin 20.5%-22.5%, solvent 15%-20%, hollow glass microbead 3%-7%.
2. a kind of preparation method of ultra-thin coating, it is characterised in that its preparation flow mainly includes the following steps that:
(1)Stock:By polyurethane acrylic resin, polyphosphoric acid ammonia, initiator, titanium dioxide, acrylic acid, fluorine richness surface Activating agent, chlorinated paraffin, solvent and hollow glass microbead are stocked up according to above-mentioned weight proportion;
(2)Batch mixing:By initiator and stirring solvent to being completely dissolved, polyurethane acrylic resin, polyphosphoric acid ammonia, titanium are sequentially added White powder, acrylic acid, fluorine richness surfactant, chlorinated paraffin and hollow glass microbead, stir, are applied Material;
(3)Try film:On experimental products film it is above-mentioned made of coating, stand to being completely dried;
(4)Performance test:After test products film is completely dried, to its surface resistance to 99.5% absolute ethyl alcohol 500g power back and forth 500 Secondary, film is without show-through;The not bottom drain of the paper tape of resistance to RCA 175g power wear-resisting test 200 times;Cross-cut methods adhesive force 100% is tested, 0 grade;
(5)Finished product packing:Step will be passed through(4)The coating of performance test carries out finished product packing.
CN201710690467.7A 2017-08-14 2017-08-14 A kind of ultra-thin coating and preparation method thereof Pending CN107384183A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710690467.7A CN107384183A (en) 2017-08-14 2017-08-14 A kind of ultra-thin coating and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710690467.7A CN107384183A (en) 2017-08-14 2017-08-14 A kind of ultra-thin coating and preparation method thereof

Publications (1)

Publication Number Publication Date
CN107384183A true CN107384183A (en) 2017-11-24

Family

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Family Applications (1)

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CN201710690467.7A Pending CN107384183A (en) 2017-08-14 2017-08-14 A kind of ultra-thin coating and preparation method thereof

Country Status (1)

Country Link
CN (1) CN107384183A (en)

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1488692A (en) * 2002-10-10 2004-04-14 公安部四川消防研究所 Ultrathin expansion steel-structure fireproofing coating
CN101519559A (en) * 2008-10-10 2009-09-02 兰州理工大学 Ultra-thin intumescent fire-retardant coating for steel structure and preparation method thereof
CN103992705A (en) * 2014-04-08 2014-08-20 王洪卫 Outdoor ultrathin type steel structure water resistance and fireproof coating material and preparation method thereof
CN104804594A (en) * 2015-05-15 2015-07-29 沈阳建筑大学 Ultra-thin steel structure fireproof paint and preparing method thereof
CN105505026A (en) * 2016-02-19 2016-04-20 徐冉 Water-based ultra-thin expansive type steel structure fire-retardant coating and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1488692A (en) * 2002-10-10 2004-04-14 公安部四川消防研究所 Ultrathin expansion steel-structure fireproofing coating
CN101519559A (en) * 2008-10-10 2009-09-02 兰州理工大学 Ultra-thin intumescent fire-retardant coating for steel structure and preparation method thereof
CN103992705A (en) * 2014-04-08 2014-08-20 王洪卫 Outdoor ultrathin type steel structure water resistance and fireproof coating material and preparation method thereof
CN104804594A (en) * 2015-05-15 2015-07-29 沈阳建筑大学 Ultra-thin steel structure fireproof paint and preparing method thereof
CN105505026A (en) * 2016-02-19 2016-04-20 徐冉 Water-based ultra-thin expansive type steel structure fire-retardant coating and preparation method thereof

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Application publication date: 20171124

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