CN107382526A - A kind of environment-protective compound fertilizer with soil remediation function and preparation method thereof - Google Patents
A kind of environment-protective compound fertilizer with soil remediation function and preparation method thereof Download PDFInfo
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- CN107382526A CN107382526A CN201710768855.2A CN201710768855A CN107382526A CN 107382526 A CN107382526 A CN 107382526A CN 201710768855 A CN201710768855 A CN 201710768855A CN 107382526 A CN107382526 A CN 107382526A
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- Prior art keywords
- parts
- environment
- compound fertilizer
- soil
- soil remediation
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05B—PHOSPHATIC FERTILISERS
- C05B7/00—Fertilisers based essentially on alkali or ammonium orthophosphates
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05F—ORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
- C05F17/00—Preparation of fertilisers characterised by biological or biochemical treatment steps, e.g. composting or fermentation
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/80—Soil conditioners
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/40—Bio-organic fraction processing; Production of fertilisers from the organic fraction of waste or refuse
Abstract
The invention discloses a kind of environment-protective compound fertilizer with soil remediation function and preparation method thereof.The environment-protective compound fertilizer with soil remediation function includes following raw material:Pearl white, polyacrylamide, starch xanthate, crab shell powder, plant polyose, poly-aspartate, Hydrolysable Tannins, river sand micro mist, sodium selenate, tartaric acid, bismuth subcarbonate, montmorillonite, volcanic ash, chitin, glycerin monostearate, vermiculite power, bamboo charcoal powder, diammonium hydrogen phosphate.The environment-protective compound fertilizer with soil remediation function of the present invention, the heavy metals such as nickel in soil, cadmium can be effectively removed, realize the reparation to soil;The improvement to soil is realized simultaneously, lifts soil quality;And soil will not be polluted, reduce the burden of soil;Dose is small, advantages of nontoxic raw materials, more environmentally-friendly.
Description
Technical field
The present invention relates to technical field of soil remediation, specifically a kind of environment-protective compound fertilizer with soil remediation function and its
Preparation method.
Background technology
Compound fertilizer refers to the chemical fertilizer containing two or more nutrient, and composite fertilizer has nutrient content high, secondary
Composition is few and the advantages that physical behavior is good, for balance fertilizing, improves utilization rate of fertilizer, promoting the stable high yield of crop has ten
Divide important effect.Existing compound fertilizer still has following shortcoming:Dose is larger, and raw material has certain toxicity, right
Soil causes certain burden, causes soil quality to decline, or even causes soil pollution, and it is unfavorable that the production to crops causes
Influence.Therefore, the present invention provides a kind of environment-protective compound fertilizer with soil remediation function and preparation method thereof.
The content of the invention
It is an object of the invention to provide a kind of environment-protective compound fertilizer with soil remediation function and preparation method thereof, with solution
The problem of being proposed in certainly above-mentioned background technology.
To achieve the above object, the present invention provides following technical scheme:
A kind of environment-protective compound fertilizer with soil remediation function, include the raw material of following parts by weight:Pearl white 22-35 parts, gather
Acrylamide 8-14 parts, starch xanthate 6-12 parts, crab shell powder 5-15 parts, plant polyose 5-10 parts, poly-aspartate 6-10
Part, Hydrolysable Tannins 4-8 parts, river sand micro mist 5-10 parts, sodium selenate 5-8 parts, tartaric acid 5-11 parts, bismuth subcarbonate 5-9 parts, montmorillonite
4-10 parts, volcanic ash 5-11 parts, chitin 2-8 parts, glycerin monostearate 2-5 parts, vermiculite power 2-5 parts, bamboo charcoal powder 1-3 parts,
Diammonium hydrogen phosphate 5-8 parts.
As the further scheme of the present invention:Include the raw material of following parts by weight:28 parts of pearl white, polyacrylamide 10
Part, 8 parts of starch xanthate, 12 parts of crab shell powder, 8 parts of plant polyose, 8 parts of poly-aspartate, 6 parts of Hydrolysable Tannins, river sand micro mist 7
Part, 6 parts of sodium selenate, 8 parts of tartaric acid, 7 parts of bismuth subcarbonate, 6 parts of montmorillonite, 8 parts of volcanic ash, 4 parts of chitin, glycerol monostearate
3 parts of ester, 4 parts of vermiculite power, 2 parts of bamboo charcoal powder, 7 parts of diammonium hydrogen phosphate.
As the further scheme of the present invention:The plant polyose uses artemisia desertorum polysaccharide.
As the further scheme of the present invention:Vermiculite power particle diameter is 50-70 mesh, and montmorillonite particle diameter is 40-70 mesh.
A kind of preparation method of the environment-protective compound fertilizer with soil remediation function, comprises the following steps:
(1)Pearl white, crab shell powder, river sand micro mist, montmorillonite, volcanic ash, vermiculite power and bamboo charcoal powder are mixed, at 125-140 DEG C
Lower mixing 1-3h, obtains mixture A;
(2)By diammonium hydrogen phosphate, polyacrylamide, starch xanthate, artemisia desertorum polysaccharide, poly-aspartate, sodium selenate and secondary carbon
Sour bismuth mixes 2-4h at 35-40 DEG C, obtains mixture B;
(3)Chitin, Hydrolysable Tannins, glycerin monostearate, tartaric acid are mixed with 5-20 part water, mixed at 15-20 DEG C
3-5h is stirred, is dried at 10-15 DEG C, obtains mixture C;
(4)Mixture A, mixture B and mixture C are mixed evenly, compound is sealed at a temperature of 15-25 DEG C
15-30h;Granulation is got product after being uniformly mixed.
As the further scheme of the present invention:Step(1)By pearl white, crab shell powder, river sand micro mist, montmorillonite, volcanic ash,
Vermiculite power and bamboo charcoal powder mixing, mix 2h at 130 DEG C, obtain mixture A.
As the further scheme of the present invention:Step(2)By diammonium hydrogen phosphate, polyacrylamide, starch xanthate, sand
Wormwood artemisia polysaccharide, poly-aspartate, sodium selenate and bismuth subcarbonate mix 3h at 38 DEG C, obtain mixture B.
As the further scheme of the present invention:Step(3)By chitin, Hydrolysable Tannins, glycerin monostearate, tartaric acid
Mixed with 15 parts of water, 4h is mixed at 17 DEG C, dried at 12 DEG C, obtain mixture C.
As the further scheme of the present invention:Step(4)Mixture A, mixture B and mixture C are mixed evenly,
Compound is sealed into 25h at a temperature of 22 DEG C;Granulation is got product after being uniformly mixed.
Compared with prior art, the beneficial effects of the invention are as follows:
The environment-protective compound fertilizer with soil remediation function of the present invention, it can effectively remove the heavy metals such as nickel in soil, cadmium, realization
Reparation to soil;A variety of nutriments are added simultaneously, increase soil nutrient, can effectively realize the improvement to soil, lifting soil
Loamy texture amount;And soil will not be polluted, the burden of soil is reduced, is advantageous to the production of crops;Dose is small, raw material
Nontoxicity, it is more environmentally-friendly;Good in economic efficiency, market prospects are good.
Embodiment
The technical scheme of this patent is described in more detail with reference to embodiment.
Embodiment 1
A kind of environment-protective compound fertilizer with soil remediation function, include the raw material of following parts by weight:22 parts of pearl white, polypropylene
8 parts of acid amides, 6 parts of starch xanthate, 5 parts of crab shell powder, 5 parts of plant polyose, 6 parts of poly-aspartate, 4 parts of Hydrolysable Tannins, river sand
5 parts of micro mist, 5 parts of sodium selenate, 5 parts of tartaric acid, 5 parts of bismuth subcarbonate, 4 parts of montmorillonite, 5 parts of volcanic ash, 2 parts of chitin, single tristearin
2 parts of acid glyceride, 2 parts of vermiculite power, 1 part of bamboo charcoal powder, 5 parts of diammonium hydrogen phosphate.The plant polyose uses artemisia desertorum polysaccharide.Vermiculite power
Particle diameter is 50 mesh, and montmorillonite particle diameter is 40 mesh.
A kind of preparation method of the environment-protective compound fertilizer with soil remediation function, comprises the following steps:(1)By pearl white,
Crab shell powder, river sand micro mist, montmorillonite, volcanic ash, vermiculite power and bamboo charcoal powder mixing, mix 1h at 125 DEG C, are mixed
Thing A;(2)By diammonium hydrogen phosphate, polyacrylamide, starch xanthate, artemisia desertorum polysaccharide, poly-aspartate, sodium selenate and secondary carbon
Sour bismuth mixes 2h at 35 DEG C, obtains mixture B;(3)By chitin, Hydrolysable Tannins, glycerin monostearate, tartaric acid
Mixed with 5 parts of water, 3h is mixed at 15 DEG C, dried at 10 DEG C, obtain mixture C;(4)By mixture A, mixture B
It is mixed evenly with mixture C, compound is sealed into 15h at a temperature of 15 DEG C;Pelletize and produce into after being uniformly mixed
Product.
Embodiment 2
A kind of environment-protective compound fertilizer with soil remediation function, include the raw material of following parts by weight:35 parts of pearl white, polypropylene
14 parts of acid amides, 12 parts of starch xanthate, 15 parts of crab shell powder, 10 parts of plant polyose, 10 parts of poly-aspartate, 8 parts of Hydrolysable Tannins,
10 parts of river sand micro mist, 8 parts of sodium selenate, 11 parts of tartaric acid, 9 parts of bismuth subcarbonate, 10 parts of montmorillonite, 11 parts of volcanic ash, chitin 8
Part, 5 parts of glycerin monostearate, 5 parts of vermiculite power, 3 parts of bamboo charcoal powder, 8 parts of diammonium hydrogen phosphate.The plant polyose is more using sand sagebrush (Artemisia filifolia)
Sugar.Vermiculite power particle diameter is 70 mesh, and montmorillonite particle diameter is 70 mesh.
A kind of preparation method of the environment-protective compound fertilizer with soil remediation function, comprises the following steps:(1)By pearl white,
Crab shell powder, river sand micro mist, montmorillonite, volcanic ash, vermiculite power and bamboo charcoal powder mixing, mix 3h at 140 DEG C, are mixed
Thing A;(2)By diammonium hydrogen phosphate, polyacrylamide, starch xanthate, artemisia desertorum polysaccharide, poly-aspartate, sodium selenate and secondary carbon
Sour bismuth mixes 4h at 40 DEG C, obtains mixture B;(3)By chitin, Hydrolysable Tannins, glycerin monostearate, tartaric acid
Mixed with 20 parts of water, 5h is mixed at 20 DEG C, dried at 15 DEG C, obtain mixture C;(4)By mixture A, mixture B
It is mixed evenly with mixture C, compound is sealed into 30h at a temperature of 25 DEG C;Pelletize and produce into after being uniformly mixed
Product.
Embodiment 3
A kind of environment-protective compound fertilizer with soil remediation function, include the raw material of following parts by weight:28 parts of pearl white, polypropylene
10 parts of acid amides, 8 parts of starch xanthate, 12 parts of crab shell powder, 8 parts of plant polyose, 8 parts of poly-aspartate, 6 parts of Hydrolysable Tannins, river
Husky 7 parts of micro mist, 6 parts of sodium selenate, 8 parts of tartaric acid, 7 parts of bismuth subcarbonate, 6 parts of montmorillonite, 8 parts of volcanic ash, 4 parts of chitin, list are hard
3 parts of glycerol, 4 parts of vermiculite power, 2 parts of bamboo charcoal powder, 7 parts of diammonium hydrogen phosphate.The plant polyose uses artemisia desertorum polysaccharide.Vermiculite
Powder footpath is 50-70 mesh, and montmorillonite particle diameter is 40-70 mesh.
A kind of preparation method of the environment-protective compound fertilizer with soil remediation function, comprises the following steps:(1)By pearl white,
Crab shell powder, river sand micro mist, montmorillonite, volcanic ash, vermiculite power and bamboo charcoal powder mixing, mix 2h at 130 DEG C, are mixed
Thing A;(2)By diammonium hydrogen phosphate, polyacrylamide, starch xanthate, artemisia desertorum polysaccharide, poly-aspartate, sodium selenate and secondary carbon
Sour bismuth mixes 3h at 38 DEG C, obtains mixture B;(3)By chitin, Hydrolysable Tannins, glycerin monostearate, tartaric acid
Mixed with 15 parts of water, 4h is mixed at 17 DEG C, dried at 12 DEG C, obtain mixture C;(4)By mixture A, mixture B
It is mixed evenly with mixture C, compound is sealed into 25h at a temperature of 22 DEG C;Pelletize and produce into after being uniformly mixed
Product.
Experimental example 1
Experimental subjects is the clay that nickel concentration is 1500mg/kg, has soil remediation function by prepared by the embodiment of the present invention 3
Environment-protective compound fertilizer is with clay according to mass ratio 0.01:1 is well mixed, and whole experimental period is 20 days, after measured, the soil after processing
Nickel concentration is 145mg/kg in earth, and clearance reaches 90.3%, and effect is clearly.
Experimental example 2
Certain heavy-metal contaminated soil is taken to do wheat pot experiment, prepared by experimental group addition embodiment 1 has soil remediation work(
The environment-protective compound fertilizer of energy is into basin in soil, and wherein blank control group is added without the environment-protective compound fertilizer with soil remediation function, its
He is identical.The end of the year is sowed, at the beginning of 6 months next years close to it is ripe when gather in, the cadmium content of measure wheat different parts.
Experimental group:Aerial part cadmium content 0.051mg/kg, under ground portion cadmium content:0.167mg/kg.
Control group:Aerial part cadmium content 0.514mg/kg, under ground portion cadmium content:1.602mg/kg.
The environment-protective compound fertilizer with soil remediation function of the present invention, the heavy metals such as nickel in soil, cadmium can be effectively removed,
Realize the reparation to soil;A variety of nutriments are added simultaneously, are increased soil nutrient, can effectively be realized the improvement to soil, carry
Rise soil quality;And soil will not be polluted, the burden of soil is reduced, is advantageous to the production of crops;Dose is small,
Advantages of nontoxic raw materials, it is more environmentally-friendly;Good in economic efficiency, market prospects are good.
The better embodiment of this patent is explained in detail above, but this patent is not limited to above-mentioned embodiment party
Formula, can also be on the premise of this patent objective not be departed from one skilled in the relevant art's possessed knowledge
Make a variety of changes.
Claims (9)
1. a kind of environment-protective compound fertilizer with soil remediation function, it is characterised in that include the raw material of following parts by weight:Fish scale
It is powder 22-35 parts, polyacrylamide 8-14 parts, starch xanthate 6-12 parts, crab shell powder 5-15 parts, plant polyose 5-10 parts, poly-
Aspartic acid 6-10 parts, Hydrolysable Tannins 4-8 parts, river sand micro mist 5-10 parts, sodium selenate 5-8 parts, tartaric acid 5-11 parts, bismuth subcarbonate
5-9 parts, montmorillonite 4-10 parts, volcanic ash 5-11 parts, chitin 2-8 parts, glycerin monostearate 2-5 parts, vermiculite power 2-5 parts,
Bamboo charcoal powder 1-3 parts, diammonium hydrogen phosphate 5-8 parts.
2. the environment-protective compound fertilizer according to claim 1 with soil remediation function, it is characterised in that including following weight
The raw material of number:28 parts of pearl white, 10 parts of polyacrylamide, 8 parts of starch xanthate, 12 parts of crab shell powder, 8 parts of plant polyose,
8 parts of poly-aspartate, 6 parts of Hydrolysable Tannins, 7 parts of river sand micro mist, 6 parts of sodium selenate, 8 parts of tartaric acid, 7 parts of bismuth subcarbonate, montmorillonite 6
Part, 8 parts of volcanic ash, 4 parts of chitin, 3 parts of glycerin monostearate, 4 parts of vermiculite power, 2 parts of bamboo charcoal powder, 7 parts of diammonium hydrogen phosphate.
3. the environment-protective compound fertilizer according to claim 1 with soil remediation function, it is characterised in that the plant polyose
Using artemisia desertorum polysaccharide.
4. the environment-protective compound fertilizer according to claim 1 with soil remediation function, it is characterised in that vermiculite power particle diameter is
50-70 mesh, montmorillonite particle diameter are 40-70 mesh.
5. a kind of preparation method of environment-protective compound fertilizer with soil remediation function as described in claim 1-4 is any, it is special
Sign is, comprises the following steps:
(1)Pearl white, crab shell powder, river sand micro mist, montmorillonite, volcanic ash, vermiculite power and bamboo charcoal powder are mixed, at 125-140 DEG C
Lower mixing 1-3h, obtains mixture A;
(2)By diammonium hydrogen phosphate, polyacrylamide, starch xanthate, artemisia desertorum polysaccharide, poly-aspartate, sodium selenate and secondary carbon
Sour bismuth mixes 2-4h at 35-40 DEG C, obtains mixture B;
(3)Chitin, Hydrolysable Tannins, glycerin monostearate, tartaric acid are mixed with 5-20 part water, mixed at 15-20 DEG C
3-5h is stirred, is dried at 10-15 DEG C, obtains mixture C;
(4)Mixture A, mixture B and mixture C are mixed evenly, compound is sealed at a temperature of 15-25 DEG C
15-30h;Granulation is got product after being uniformly mixed.
6. the preparation method of the environment-protective compound fertilizer according to claim 5 with soil remediation function, it is characterised in that step
Suddenly(1)Pearl white, crab shell powder, river sand micro mist, montmorillonite, volcanic ash, vermiculite power and bamboo charcoal powder are mixed, mixed at 130 DEG C
2h is stirred, obtains mixture A.
7. the preparation method of the environment-protective compound fertilizer according to claim 5 with soil remediation function, it is characterised in that step
Suddenly(2)By diammonium hydrogen phosphate, polyacrylamide, starch xanthate, artemisia desertorum polysaccharide, poly-aspartate, sodium selenate and secondary carbonic acid
Bismuth mixes 3h at 38 DEG C, obtains mixture B.
8. the preparation method of the environment-protective compound fertilizer according to claim 5 with soil remediation function, it is characterised in that step
Suddenly(3)Chitin, Hydrolysable Tannins, glycerin monostearate, tartaric acid are mixed with 15 parts of water, 4h is mixed at 17 DEG C,
Dried at 12 DEG C, obtain mixture C.
9. the preparation method of the environment-protective compound fertilizer according to claim 5 with soil remediation function, it is characterised in that step
Suddenly(4)Mixture A, mixture B and mixture C are mixed evenly, compound is sealed into 25h at a temperature of 22 DEG C;Stir
Mix to pelletize after being well mixed and get product.
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108296277A (en) * | 2018-01-23 | 2018-07-20 | 天津科创复兴科技咨询有限公司 | A kind of renovation agent and preparation method thereof for lead-contaminated soil |
US20200361832A1 (en) * | 2019-05-14 | 2020-11-19 | Allen Pyle | Effectiveness of water soluble pam |
CN115250870A (en) * | 2022-08-18 | 2022-11-01 | 黄河水利委员会黄河水利科学研究院 | Consolidation vegetation ecological composite material and preparation method thereof |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
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CN106118683A (en) * | 2016-06-30 | 2016-11-16 | 山东爱福地生物科技有限公司 | A kind of heavy-metal contaminated soil renovation agent |
-
2017
- 2017-08-31 CN CN201710768855.2A patent/CN107382526A/en active Pending
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106118683A (en) * | 2016-06-30 | 2016-11-16 | 山东爱福地生物科技有限公司 | A kind of heavy-metal contaminated soil renovation agent |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108296277A (en) * | 2018-01-23 | 2018-07-20 | 天津科创复兴科技咨询有限公司 | A kind of renovation agent and preparation method thereof for lead-contaminated soil |
US20200361832A1 (en) * | 2019-05-14 | 2020-11-19 | Allen Pyle | Effectiveness of water soluble pam |
CN115250870A (en) * | 2022-08-18 | 2022-11-01 | 黄河水利委员会黄河水利科学研究院 | Consolidation vegetation ecological composite material and preparation method thereof |
CN115250870B (en) * | 2022-08-18 | 2023-06-27 | 黄河水利委员会黄河水利科学研究院 | Consolidated plant ecological composite material and preparation method thereof |
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Application publication date: 20171124 |