CN107382465A - A kind of planting fruit trees organic-inorganic water soluble fertilizer and preparation method thereof - Google Patents

A kind of planting fruit trees organic-inorganic water soluble fertilizer and preparation method thereof Download PDF

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Publication number
CN107382465A
CN107382465A CN201710613725.1A CN201710613725A CN107382465A CN 107382465 A CN107382465 A CN 107382465A CN 201710613725 A CN201710613725 A CN 201710613725A CN 107382465 A CN107382465 A CN 107382465A
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parts
animal wastes
water soluble
fruit trees
urea
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Chinese (zh)
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陈圣明
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Anhui Sky Blue Agriculture And Forestry Science And Technology Co Ltd
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Anhui Sky Blue Agriculture And Forestry Science And Technology Co Ltd
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Priority to CN201710613725.1A priority Critical patent/CN107382465A/en
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    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05BPHOSPHATIC FERTILISERS
    • C05B7/00Fertilisers based essentially on alkali or ammonium orthophosphates
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05FORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
    • C05F17/00Preparation of fertilisers characterised by biological or biochemical treatment steps, e.g. composting or fermentation
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05GMIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
    • C05G3/00Mixtures of one or more fertilisers with additives not having a specially fertilising activity
    • C05G3/80Soil conditioners
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/40Bio-organic fraction processing; Production of fertilisers from the organic fraction of waste or refuse

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Pest Control & Pesticides (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Soil Sciences (AREA)
  • Biochemistry (AREA)
  • Biotechnology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Microbiology (AREA)
  • Molecular Biology (AREA)
  • Fertilizers (AREA)

Abstract

The invention discloses a kind of planting fruit trees organic-inorganic water soluble fertilizer, it is characterised in that is made up of the raw material below according to parts by weight:5 25 parts of animal wastes, 6 26 parts of plant ash, 4 16 parts of fulvic acid, 2 12 parts of potassium humate, 3 13 parts of urea, 5 15 parts of ammonium sulfate, 4 20 parts of Chinese medicine slag, black 6 16 parts of carbon, 4 16 parts of phosphorus pentoxide, 2 10 parts of precipitated calcium phosphate, 4 12 parts of phosphoric acid monoamine, 3 15 parts of surfactant, 4 10 parts of effective active composition.The present invention has the advantages that nutrient content abundant, improvement soil quality and easy to process.

Description

A kind of planting fruit trees organic-inorganic water soluble fertilizer and preparation method thereof
Technical field
The present invention relates to fertilizer manufacture field, more particularly to a kind of planting fruit trees organic-inorganic water soluble fertilizer and its system Preparation Method.
Background technology
Organic fertilizer refers to containing organic substance, can provide a variety of inorganic nutrients of crops and organic nutrient, and can training A kind of fertilizer of fertile improved soil, wherein the overwhelming majority is gathered materials on the spot for farmers', voluntarily product is made, and organic fertilizer is manured into soil, warp Microorganism decomposition, it can continuously discharge various nutrients and supply plant absorption, moreover it is possible to discharge carbon dioxide, improve crop carbon Plain nutrition;In decomposable process, humus, humic acid, amino acid, fulvic acid etc. is produced, seed is sprouted, root growth has Stimulation, promote crop biochemical metabolism;Organic fertilizer is the main matter of improved soil.Microorganism generates in decomposable process Secretase, humus, regulation soil material and progress energy conversion, promote soil granular structure to be formed, and enhancing soil water-retaining is protected Fertile ability;Organic fertilizer can improve soil slightly solubility P availability;Yield and improving quality can be increased, but organic fertilizer also has It is low to there is nutrient content, is not easily decomposed, it is impossible to meets the requirement of high crop yield in time, the product of traditional organic fertilizer is made and used Very inconvenient, the debirs such as livestock and poultry manure, rubbish are a kind of dirty, rotten, sordes matter again, wherein containing the micro- life of many cause of diseases Thing, or some poisonous substances are mixed into, it is important pollution sources, it is particularly noteworthy that with the development of Modern Animal Husbandry, feed adds Agent is added to apply more and more extensive, feed addictive often contains a certain amount of heavy metal, and these heavy metals are just discharged with animal manure, meeting Serious pollution environment, influence the health of people.
Inorganic fertilizer is mineral fertilizer, is also chemical fertilizer, abbreviation chemical fertilizer.It has that composition is simple, high containing active ingredient, easily Be dissolved in water, decompose it is fast, easily by Root Absorption the features such as, therefore claim " quick action fertilizer ", the nutrient contained in inorganic fertilizer Species is single or less, but nutrient content is high, and fertilizer efficiency is rapid, and for fertilizer efficiency suddenly without length, it is less big to improve the effect of soil, or even has Destroy the side effect of soil property.
People need to apply fertilizer when raising fruit trees provides nutrient for the growth of fruit tree, but single selection organic fertilizer Or inorganic fertilizer is unfavorable for growing for fruit tree, it is impossible to the long-term use being convenient for people to, and existing fertilizer is placed for a long time During, fertilizer is easy to situation about luming occur, and causes fertilizer rotten situation occur, is unfavorable for the use in people.
The content of the invention
The defects of in order to overcome above-mentioned prior art, it is an object of the invention to provide a kind of planting fruit trees organic-inorganic water Soluble fertilizers and preparation method thereof.
The present invention takes following technical scheme to realize:A kind of planting fruit trees organic-inorganic water soluble fertilizer, by Formed below according to the raw material of parts by weight:Animal wastes 5-25 parts, plant ash 6-26 parts, fulvic acid 4-16 parts, potassium humate 2-12 parts, urea 3-13 parts, ammonium sulfate 5-15 parts, Chinese medicine slag 4-20 parts, black carbon 6-16 parts, phosphorus pentoxide 4-16 parts, precipitation Calcium phosphate 2-10 parts, phosphoric acid monoamine 4-12 parts, surfactant 3-15 parts, effective active composition 4-10 parts.
The surfactant is that neopelex, sorbitan monostearate and polyoxyethylene polyoxypropylene are embedding Section copolymer.
The parts by weight of the surfactant are neopelex 1-5 parts, sorbitan monostearate 1-5 Part, polyoxyethylene polyoxypropylene block copolymer 1-5 parts.
The effective active composition is disodium ethylene diamine tetraacetate and sorbitan monooleate.
The parts by weight of the effective active composition are disodium ethylene diamine tetraacetate 2-5 parts, sorbitan monooleate 2-5 Part.
A kind of above-mentioned planting fruit trees organic-inorganic water soluble fertilizer, is made up of the raw material below according to parts by weight: 15 parts of animal wastes, 16 parts of plant ash, 10 parts of fulvic acid, 7 parts of potassium humate, 8 parts of urea, 10 parts of ammonium sulfate, 12 parts of Chinese medicine slag, Black 11 parts of carbon, 10 parts of phosphorus pentoxide, 6 parts of precipitated calcium phosphate, 8 parts of phosphoric acid monoamine, 3 parts of neopelex, sorb is smooth 3 parts of monoleate, 3 parts of sorbitan monostearate, 4 parts of polyoxyethylene polyoxypropylene block copolymer, ethylenediamine tetra-acetic acid two 4 parts of sodium.
A kind of above-mentioned planting fruit trees preparation method of organic-inorganic water soluble fertilizer, is comprised the steps of:
(1)The composition number of each raw material in claim 2 is weighed, animal wastes are dynamic after anaerobism and oxygen consumption are fermented Thing excrement;
(2)By the animal wastes after being fermented in step 1 and plant ash, fulvic acid, potassium humate, urea, ammonium sulfate, Chinese medicine Slag, black carbon, phosphorus pentoxide, precipitated calcium phosphate, phosphoric acid monoamine, neopelex, sorbitan monooleate, sorb are smooth Monostearate, polyoxyethylene polyoxypropylene block copolymer and disodium ethylene diamine tetraacetate, which are put into agitating device, to be stirred Processing, mixing time 4h, whipping temp are 20 DEG C -40 DEG C, obtain mixed material;
(3)The mixed material obtained in step 2 is subjected to granulation processing by prilling granulator, the material that granulation obtains is dried Dry-cure, you can obtain finished product.
In summary the invention has the advantages that:The present invention have nutrient content is abundant, improve soil quality with And the advantages that easy to process, the disodium ethylene diamine tetraacetate added in fertilizer have preferable antioxidant effect, avoid fertilizer Because exposure in atmosphere and occurs it is oxidized cause rotten situation, extend the holding time of fertilizer, and the ethylenediamine tetraacetic The inhibition of heavy metal ion can be shielded during two sodium polymerization of acetic acid to be influenceed, so as to eliminate shadow of the heavy metal ion to environment Ring;The sorbitan monooleate, neopelex and polyoxyethylene polyoxypropylene block copolymer are lived as surface Property agent can reduce surface tension of liquid, make fertilizer quick and aqueous phase dissolved, improve its dissolved efficiency, and organic fertilizer and nothing The combination of machine fertilizer can eliminate the shortcomings that independent organic fertilizer and inorganic fertilizer, in time for fruit tree growth provide enrich nutrition into Point, improve soil soil property, and there is the preferable feature of environmental protection.
Embodiment
Embodiment 1
Weigh 5 parts of animal wastes, 6 parts of plant ash, 4 parts of fulvic acid, 2 parts of potassium humate, 3 parts of urea, 5 parts of ammonium sulfate, Chinese medicine slag 4 Part, black 6 parts of carbon, 4 parts of phosphorus pentoxide, 2 parts of precipitated calcium phosphate, 4 parts of phosphoric acid monoamine, 1 part of neopelex, sorb are smooth 1 part of monostearate, 1 part of polyoxyethylene polyoxypropylene block copolymer, 2 parts of disodium ethylene diamine tetraacetate, the smooth single oleic acid of sorb 2 parts of ester, by animal wastes of the animal wastes after anaerobism and oxygen consumption are fermented, by the animal wastes after fermentation and vegetation Ash, fulvic acid, potassium humate, urea, ammonium sulfate, Chinese medicine slag, black carbon, phosphorus pentoxide, precipitated calcium phosphate, phosphoric acid monoamine, ten Dialkyl benzene sulfonic acids sodium, sorbitan monooleate, sorbitan monostearate, polyoxyethylene polyoxypropylene block copolymer and second Edetate disodium is put into agitating device and is stirred, mixing time 4h, and whipping temp is 20 DEG C -40 DEG C, is obtained To mixed material;Then mixed material is subjected to granulation processing by prilling granulator, the material that granulation obtains is carried out at drying Reason, you can obtain finished product.
Embodiment 2
Weigh 10 parts of animal wastes, 12 parts of plant ash, 8 parts of fulvic acid, 4 parts of potassium humate, 6 parts of urea, 10 parts of ammonium sulfate, Chinese medicine 8 parts of slag, black 10 parts of carbon, 8 parts of phosphorus pentoxide, 4 parts of precipitated calcium phosphate, 8 parts of phosphoric acid monoamine, 2 parts of neopelex, mountain 2 parts of the smooth monostearate of pears, 2 parts of polyoxyethylene polyoxypropylene block copolymer, 4 parts of disodium ethylene diamine tetraacetate, the smooth list of sorb 4 parts of oleate, by animal wastes of the animal wastes after anaerobism and oxygen consumption are fermented, by the animal wastes after fermentation and grass Wood ash, fulvic acid, potassium humate, urea, ammonium sulfate, Chinese medicine slag, black carbon, phosphorus pentoxide, precipitated calcium phosphate, phosphoric acid monoamine, Neopelex, sorbitan monooleate, sorbitan monostearate, polyoxyethylene polyoxypropylene block copolymer and Disodium ethylene diamine tetraacetate is put into agitating device and is stirred, mixing time 4h, and whipping temp is 20 DEG C -40 DEG C, Obtain mixed material;Then mixed material is subjected to granulation processing by prilling granulator, the material that granulation obtains is dried Processing, you can obtain finished product.
Embodiment 3
Weigh 15 parts of animal wastes, 18 parts of plant ash, 12 parts of fulvic acid, 8 parts of potassium humate, 10 parts of urea, 15 parts of ammonium sulfate, in 12 parts of the dregs of a decoction, black 16 parts of carbon, 12 parts of phosphorus pentoxide, 8 parts of precipitated calcium phosphate, 12 parts of phosphoric acid monoamine, neopelex 5 Part, 5 parts of sorbitan monostearate, 5 parts of polyoxyethylene polyoxypropylene block copolymer, 5 parts of disodium ethylene diamine tetraacetate, sorb Smooth 5 parts of monoleate, by animal wastes of the animal wastes after anaerobism and oxygen consumption are fermented, by the animal wastes after fermentation With plant ash, fulvic acid, potassium humate, urea, ammonium sulfate, Chinese medicine slag, black carbon, phosphorus pentoxide, precipitated calcium phosphate, phosphoric acid one Amine, neopelex, sorbitan monooleate, sorbitan monostearate, polyoxyethylene polyoxypropylene block copolymerization Thing and disodium ethylene diamine tetraacetate, which are put into agitating device, to be stirred, mixing time 4h, and whipping temp is 20 DEG C -40 DEG C, obtain mixed material;Then mixed material is subjected to granulation processing by prilling granulator, the material that granulation obtains is dried Dry-cure, you can obtain finished product.
Comparative example 1
Weigh 5 parts of animal wastes, 6 parts of plant ash, 4 parts of fulvic acid, 2 parts of potassium humate, 3 parts of urea, 5 parts of ammonium sulfate, Chinese medicine slag 4 Part, black 6 parts of carbon, 4 parts of phosphorus pentoxide, 2 parts of precipitated calcium phosphate, 4 parts of phosphoric acid monoamine, 1 part of neopelex, sorb are smooth 1 part of monostearate, 1 part of polyoxyethylene polyoxypropylene block copolymer, animal wastes are fermented by anaerobism and oxygen consumption Animal wastes afterwards are black by the animal wastes after fermentation and plant ash, fulvic acid, potassium humate, urea, ammonium sulfate, Chinese medicine slag Carbon, phosphorus pentoxide, precipitated calcium phosphate, phosphoric acid monoamine, neopelex, sorbitan monostearate, polyoxyethylene Polyoxypropylene block copolymers are put into agitating device and are stirred, mixing time 4h, and whipping temp is 20 DEG C -40 DEG C, obtain mixed material;Then mixed material is subjected to granulation processing by prilling granulator, the material that granulation obtains is dried Dry-cure, you can obtain finished product.
Comparative example 2
Weigh 10 parts of animal wastes, 6 parts of urea, 10 parts of ammonium sulfate, 8 parts of Chinese medicine slag, black 10 parts of carbon, 8 parts of phosphorus pentoxide, precipitation 4 parts of calcium phosphate, 8 parts of phosphoric acid monoamine, 2 parts of neopelex, 2 parts of sorbitan monostearate, polyoxyethylene polyoxy third 2 parts of alkene block copolymer, by animal wastes of the animal wastes after anaerobism and oxygen consumption are fermented, by the animal excreta after fermentation Just with plant ash, fulvic acid, potassium humate, urea, ammonium sulfate, Chinese medicine slag, black carbon, phosphorus pentoxide, precipitated calcium phosphate, phosphoric acid One amine, neopelex, sorbitan monostearate, polyoxyethylene polyoxypropylene block copolymer are put into agitating device In be stirred, mixing time 4h, whipping temp be 20 DEG C -40 DEG C, obtain mixed material;Then mixed material is led to Cross prilling granulator and carry out granulation processing, the material that granulation is obtained carries out drying and processing, you can obtains finished product.
Comparative example 3
15 parts of animal wastes are weighed, 18 parts of plant ash, 12 parts of fulvic acid, 8 parts of potassium humate, 12 parts of Chinese medicine slag, black 16 parts of carbon, are sunk 8 parts of shallow lake calcium phosphate, 12 parts of phosphoric acid monoamine, 5 parts of neopelex, 5 parts of sorbitan monostearate, polyoxyethylene polyoxy 5 parts of propylene-based block copolymer, by animal wastes of the animal wastes after anaerobism and oxygen consumption are fermented, by the animal after fermentation Excrement and plant ash, fulvic acid, potassium humate, urea, ammonium sulfate, Chinese medicine slag, black carbon, phosphorus pentoxide, precipitated calcium phosphate, phosphorus A sour amine, neopelex, sorbitan monostearate, polyoxyethylene polyoxypropylene block copolymer are put into stirring dress It is stirred in putting, mixing time 4h, whipping temp is 20 DEG C -40 DEG C, obtains mixed material;Then by mixed material Granulation processing is carried out by prilling granulator, the material that granulation is obtained carries out drying and processing, you can obtains finished product.
Comparative example 1-3 and comparative example 1-3, concrete outcome such as following table:
Heavy metal ion content Cu(mg/kg) Per mu yield(Kg/ mus) Insect pest rate(%) Mean fruit weight(g)
Embodiment 1 1.56 4890 9.6 283
Embodiment 2 1.43 4930 9.3 290
Embodiment 3 1.32 5100 8.5 294
Comparative example 1 5.65 3430 23.3 213
Comparative example 2 6.13 3390 24.6 202
Comparative example 3 5.74 3510 25.4 212
Described above is embodiments of the invention, therefore what all construction, feature and principles according to described in the present patent application scope were done Equivalent change or modification, it is included in the range of present patent application.

Claims (3)

1. a kind of planting fruit trees organic-inorganic water soluble fertilizer, it is characterised in that by below according to the raw material group of parts by weight Into:Animal wastes 5-25 parts, plant ash 6-26 parts, fulvic acid 4-16 parts, potassium humate 2-12 parts, urea 3-13 parts, ammonium sulfate 5-15 parts, Chinese medicine slag 4-20 parts, black carbon 6-16 parts, phosphorus pentoxide 4-16 parts, precipitated calcium phosphate 2-10 parts, phosphoric acid monoamine 4-12 Part, surfactant 3-15 parts, effective active composition 4-10 parts;
The surfactant is that neopelex, sorbitan monostearate and polyoxyethylene polyoxypropylene block are total to Polymers;
The parts by weight of the surfactant are neopelex 1-5 parts, sorbitan monostearate 1-5 parts, are gathered Oxygen ethene polyoxypropylene block copolymers 1-5 parts;
The effective active composition is disodium ethylene diamine tetraacetate and sorbitan monooleate;
The parts by weight of the effective active composition are disodium ethylene diamine tetraacetate 2-5 parts, sorbitan monooleate 2-5 parts.
2. a kind of planting fruit trees organic-inorganic water soluble fertilizer according to claim 1, it is characterised in that by pressing below Formed according to the raw material of parts by weight:15 parts of animal wastes, 16 parts of plant ash, 10 parts of fulvic acid, 7 parts of potassium humate, 8 parts of urea, 10 parts of ammonium sulfate, 12 parts of Chinese medicine slag, black 11 parts of carbon, 10 parts of phosphorus pentoxide, 6 parts of precipitated calcium phosphate, 8 parts of phosphoric acid monoamine, 12 3 parts of sodium alkyl benzene sulfonate, 3 parts of sorbitan monooleate, 3 parts of sorbitan monostearate, polyoxyethylene polyoxypropylene block is total to 4 parts of polymers, 4 parts of disodium ethylene diamine tetraacetate.
3. a kind of preparation method of planting fruit trees organic-inorganic water soluble fertilizer according to claim 1 or 2, its feature It is, comprises the steps of:
(1)The composition number of each raw material in claim 2 is weighed, animal wastes are dynamic after anaerobism and oxygen consumption are fermented Thing excrement;
(2)By the animal wastes after being fermented in step 1 and plant ash, fulvic acid, potassium humate, urea, ammonium sulfate, Chinese medicine Slag, black carbon, phosphorus pentoxide, precipitated calcium phosphate, phosphoric acid monoamine, neopelex, sorbitan monooleate, sorb are smooth Monostearate, polyoxyethylene polyoxypropylene block copolymer and disodium ethylene diamine tetraacetate, which are put into agitating device, to be stirred Processing, mixing time 4h, whipping temp are 20 DEG C -40 DEG C, obtain mixed material;
(3)The mixed material obtained in step 2 is subjected to granulation processing by prilling granulator, the material that granulation obtains is dried Dry-cure, you can obtain finished product.
CN201710613725.1A 2017-07-25 2017-07-25 A kind of planting fruit trees organic-inorganic water soluble fertilizer and preparation method thereof Pending CN107382465A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109824435A (en) * 2019-03-21 2019-05-31 甘肃苏地肥业有限公司 A kind of improvement soil disease-resistant synergy fertilizer and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104692914A (en) * 2015-01-28 2015-06-10 和县常乐蔬菜种植专业合作社 Polymerized coated fertilizer for reducing pest and disease damage of strawberries by utilizing modified bamboo fiber
CN105198668A (en) * 2015-08-18 2015-12-30 宁夏共享生物化工有限公司 Preparation method of special biochemical-humic-acid-containing bottom fertilizer for litchis
CN106242715A (en) * 2016-07-15 2016-12-21 董向波 A kind of preparation method of the organic and inorganic fertilizer with effect of taking root
CN106962343A (en) * 2017-04-20 2017-07-21 临沧邦泰昔归庄园有限公司 A kind of growth of tea plant conditioning agent and its application method

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104692914A (en) * 2015-01-28 2015-06-10 和县常乐蔬菜种植专业合作社 Polymerized coated fertilizer for reducing pest and disease damage of strawberries by utilizing modified bamboo fiber
CN105198668A (en) * 2015-08-18 2015-12-30 宁夏共享生物化工有限公司 Preparation method of special biochemical-humic-acid-containing bottom fertilizer for litchis
CN106242715A (en) * 2016-07-15 2016-12-21 董向波 A kind of preparation method of the organic and inorganic fertilizer with effect of taking root
CN106962343A (en) * 2017-04-20 2017-07-21 临沧邦泰昔归庄园有限公司 A kind of growth of tea plant conditioning agent and its application method

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109824435A (en) * 2019-03-21 2019-05-31 甘肃苏地肥业有限公司 A kind of improvement soil disease-resistant synergy fertilizer and preparation method thereof

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