CN107353846A - A kind of novel glass gluing agent and preparation method thereof - Google Patents
A kind of novel glass gluing agent and preparation method thereof Download PDFInfo
- Publication number
- CN107353846A CN107353846A CN201710522036.XA CN201710522036A CN107353846A CN 107353846 A CN107353846 A CN 107353846A CN 201710522036 A CN201710522036 A CN 201710522036A CN 107353846 A CN107353846 A CN 107353846A
- Authority
- CN
- China
- Prior art keywords
- parts
- mixture
- novel glass
- filler
- glass gluing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J109/00—Adhesives based on homopolymers or copolymers of conjugated diene hydrocarbons
- C09J109/06—Copolymers with styrene
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of novel glass gluing agent, include the raw material of following parts by weight：20~40 parts of butadiene-styrene rubber, 13~22 parts of polyacrylic acid, 15~27 parts of epoxy resin, 7~14 parts of methyl methacrylate, 8~17 parts of starch, 11~18 parts of polyurethane, 15~26 parts of acetone, 2~5 parts of mixture of Chinese herbal medicines, 17~28 parts of filler, 3~6 parts of modifying agent, 1~3 part of oxide additive, 4~7 parts of curing agent.The novel glass gluing agent cohesive is good, difficult for drop-off, is not likely to produce chemical residual and causes environmental pollution, service life length.
Description
Technical field
The invention belongs to glass adhesive technical field, and in particular to a kind of novel glass gluing agent and preparation method thereof.
Background technology
Lucite is to be referred to as acrylics with the polymer obtained by acrylicacidandesters Type of Collective, wherein with poly-
Metering system ester methyl ester is most widely used.Polymethyl methacrylate abbreviation code name is PMMA, is commonly called as lucite, has fabulous
Light transmission；Mechanical strength is higher, has certain heat-resisting cold resistance, corrosion-resistant, insulating properties are good, dimensionally stable, are easy into
Type, quality is more crisp, is soluble in organic solvent, and case hardness is inadequate, and easy snag, the material is widely used in advertising lamp box,
The making of nameplate etc..
Lucite quality is more crisp, needs to paste it on other products when in use, it is therefore desirable to using adhesive,
But current lucite adhesive, cohesive is bad, easy to fall off, is also easy to produce chemical residual and causes environmental pollution.
The content of the invention
The invention provides a kind of novel glass gluing agent and preparation method thereof, solve asking in above-mentioned background technology
Topic, the novel glass gluing agent cohesive is good, difficult for drop-off, is not likely to produce chemical residual and causes environmental pollution, service life
It is long.
In order to solve the problems, such as that prior art is present, adopt the following technical scheme that：
A kind of novel glass gluing agent, include the raw material of following parts by weight：20~40 parts of butadiene-styrene rubber, polyacrylic acid 13~22
Part, 15~27 parts of epoxy resin, 7~14 parts of methyl methacrylate, 8~17 parts of starch, 11~18 parts of polyurethane, acetone 15~
26 parts, 2~5 parts of mixture of Chinese herbal medicines, 17~28 parts of filler, 3~6 parts of modifying agent, 1~3 part of oxide additive, curing agent 4
~7 parts.
Preferably, the novel glass gluing agent, the raw material of following parts by weight is included：23~35 parts of butadiene-styrene rubber, poly- third
17~21 parts of olefin(e) acid, 20~25 parts of epoxy resin, 9~12 parts of methyl methacrylate, 12~15 parts of starch, polyurethane 13~16
Part, 17~22 parts of acetone, 3~4 parts of mixture of Chinese herbal medicines, 21~26 parts of filler, 4~5 parts of modifying agent, oxide additive 1.7
~2.6 parts, 5~6 parts of curing agent.
Preferably, the novel glass gluing agent, the raw material of following parts by weight is included：27 parts of butadiene-styrene rubber, polyacrylic acid
18 parts, 23 parts of epoxy resin, 11 parts of methyl methacrylate, 14 parts of starch, 15 parts of polyurethane, 19 parts of acetone, Chinese herbal medicine mixing
3.5 parts of thing, 25 parts of filler, 4.7 parts of modifying agent, 2.4 parts of oxide additive, 5.8 parts of curing agent.
Preferably, the filler includes the component of following parts by weight：5~8 parts of wood powder, 2~4 parts of oyster shell whiting and heavy carbonic acid
2~4 parts of calcium powder.
Preferably, the oxide addition is one or more of in silica, alundum (Al2O3) and boron oxide
Combination.
Preferably, the modifying agent includes the component of following parts by weight：1~3 part of tannin extract, 3~8 parts of gelatin and Quercetin 1
~2 parts.
Preferably, the mixture of Chinese herbal medicines is the mixture of honeysuckle, garlic, ginger, cordate houttuynia, cassia bark and cloves.
A kind of method for preparing the novel glass gluing agent, comprises the following steps：
（1）Butadiene-styrene rubber, polyacrylic acid, epoxy resin, methyl methacrylate, starch, polyurethane, third are weighed by said components
Ketone, mixture of Chinese herbal medicines, filler, modifying agent, oxide additive, curing agent, it is standby；
（2）Mixture of Chinese herbal medicines was ground into 100~200 mesh sieves, first adds the warm water immersion of 5~10 times of mixture of Chinese herbal medicines
1~2 hour, intense fire infusion 20~40 minutes, boil, then be cooked by slow fire 30~60 minutes, be cooled to normal temperature, obtain Chinese medicine mixing
Liquid；
（3）Chinese medicine mixed liquor and butadiene-styrene rubber, polyacrylic acid, epoxy resin, methyl methacrylate and polyurethane are added successively
Enter in reactor, heat while stirring, be heated to 70~90 DEG C, ultrasonication 5~10 minutes, insulation stands 10~30 points
Clock, it is cooled to normal temperature；
（4）To step（3）Sequentially add acetone, oxide additive in obtained mixture, high-speed stirred 13~22 minutes, so
Starch and filler, high-speed stirred to bubble collapse are added afterwards；
（5）To step（4）Curing agent is added in the mixture of gained, is vacuumized, is stirred 7~13 minutes, then stand 20~30 points
Clock；
（6）To step（5）The product China of gained adds modifying agent and is stirred, is modified, produces the novel glass gluing agent.
Preferably, the filler is first to add heavy calcium carbonate during addition, adds wood powder, is eventually adding
Oyster shell whiting.
Preferably, the mixing speed of the high-speed stirred is 700~800r/min.
Compared with prior art, it has the advantages that the present invention：
Novel glass gluing agent cohesive of the present invention is good, difficult for drop-off, is not likely to produce chemical residual and causes environmental pollution, makes
It is specific as follows with long lifespan：
（1）Novel glass gluing agent of the present invention adds butadiene-styrene rubber, polyacrylic acid, epoxy resin as raw material, three
Synergy, has good waterproof effect, the adhesive produced has very high gumminess；
（2）Curing agent is with the addition of in novel glass gluing agent of the present invention, it is more preferable that curing agent can make it that adhesive has
Thermosetting effect, the speed of thermosetting is fast, difficult for drop-off；
（3）Novel glass gluing agent of the present invention addition wood powder, oyster shell whiting and heavy calcium carbonate as filler, filler
Intensity is high, and more denaturation will not be produced during the preparation and during the later stage is hot-forming, can holding with intensity
Long effect；
（4）Novel glass gluing agent of the present invention with the addition of starch, modifying agent and mixture of Chinese herbal medicines, can further increase
Add its viscosity, adhesive can also be protected to be not easy to be oxidized, strengthen its antibacterial ability, extend its service life.
Embodiment
With reference to specific embodiment, the present invention is expanded on further.These embodiments are merely to illustrate the present invention and not had to
In limitation the scope of the present invention.
Embodiment 1
The present embodiment is related to a kind of novel glass gluing agent, includes the raw material of following parts by weight：20 parts of butadiene-styrene rubber, polyacrylic acid
13 parts, 15 parts of epoxy resin, 7 parts of methyl methacrylate, 8 parts of starch, 11 parts of polyurethane, 15 parts of acetone, mixture of Chinese herbal medicines 2
Part, 17 parts of filler, 3 parts of modifying agent, 1 part of oxide additive, 4 parts of curing agent.
Wherein, the filler includes the component of following parts by weight：2 parts of 5 parts of wood powder, 2 parts of oyster shell whiting and heavy calcium carbonate.
Wherein, the oxide addition is silica.
Wherein, the modifying agent includes the component of following parts by weight：1 part of 1 part of tannin extract, 3 parts of gelatin and Quercetin.
Wherein, the mixture of Chinese herbal medicines is the mixture of honeysuckle, garlic, ginger, cordate houttuynia, cassia bark and cloves.
A kind of method for preparing the novel glass gluing agent, comprises the following steps：
（1）Butadiene-styrene rubber, polyacrylic acid, epoxy resin, methyl methacrylate, starch, polyurethane, third are weighed by said components
Ketone, mixture of Chinese herbal medicines, filler, modifying agent, oxide additive, curing agent, it is standby；
（2）Mixture of Chinese herbal medicines was ground into 100~200 mesh sieves, first adds the warm water immersion 1 of 5 times of mixture of Chinese herbal medicines small
When, intense fire infusion 20 minutes, boil, then be cooked by slow fire 30 minutes, normal temperature is cooled to, obtains Chinese medicine mixed liquor；
（3）Chinese medicine mixed liquor and butadiene-styrene rubber, polyacrylic acid, epoxy resin, methyl methacrylate and polyurethane are added successively
Enter in reactor, heat while stirring, be heated to 70 DEG C, ultrasonication 5 minutes, insulation stands 10 minutes, is cooled to normal temperature；
（4）To step（3）Acetone, oxide additive, high-speed stirred 13 minutes, Ran Houjia are sequentially added in obtained mixture
Enter starch and filler, high-speed stirred to bubble collapse；
（5）To step（4）Curing agent is added in the mixture of gained, is vacuumized, is stirred 7 minutes, then stand 20 minutes；
（6）To step（5）The product China of gained adds modifying agent and is stirred, is modified, produces the novel glass gluing agent.
Wherein, the filler is first to add heavy calcium carbonate during addition, adds wood powder, is eventually adding shellfish
Shell powder.
Wherein, the mixing speed of the high-speed stirred is 700r/min.
Embodiment 2
The present embodiment is related to a kind of novel glass gluing agent, includes the raw material of following parts by weight：40 parts of butadiene-styrene rubber, polyacrylic acid
22 parts, 27 parts of epoxy resin, 14 parts of methyl methacrylate, 17 parts of starch, 18 parts of polyurethane, 26 parts of acetone, Chinese herbal medicine mixing
5 parts of thing, 28 parts of filler, 6 parts of modifying agent, 3 parts of oxide additive, 7 parts of curing agent.
Wherein, the filler includes the component of following parts by weight：4 parts of 8 parts of wood powder, 4 parts of oyster shell whiting and heavy calcium carbonate.
Wherein, the oxide addition is alundum (Al2O3).
Wherein, the modifying agent includes the component of following parts by weight：2 parts of 3 parts of tannin extract, 8 parts of gelatin and Quercetin.
Wherein, the mixture of Chinese herbal medicines is the mixture of honeysuckle, garlic, ginger, cordate houttuynia, cassia bark and cloves.
A kind of method for preparing the novel glass gluing agent, comprises the following steps：
（1）Butadiene-styrene rubber, polyacrylic acid, epoxy resin, methyl methacrylate, starch, polyurethane, third are weighed by said components
Ketone, mixture of Chinese herbal medicines, filler, modifying agent, oxide additive, curing agent, it is standby；
（2）Mixture of Chinese herbal medicines was ground into 100~200 mesh sieves, first adds the warm water immersion 2 of 10 times of mixture of Chinese herbal medicines small
When, intense fire infusion 40 minutes, boil, then be cooked by slow fire 60 minutes, normal temperature is cooled to, obtains Chinese medicine mixed liquor；
（3）Chinese medicine mixed liquor and butadiene-styrene rubber, polyacrylic acid, epoxy resin, methyl methacrylate and polyurethane are added successively
Enter in reactor, heat while stirring, be heated to 90 DEG C, ultrasonication 10 minutes, insulation stands 30 minutes, is cooled to often
Temperature；
（4）To step（3）Acetone, oxide additive, high-speed stirred 22 minutes, Ran Houjia are sequentially added in obtained mixture
Enter starch and filler, high-speed stirred to bubble collapse；
（5）To step（4）Curing agent is added in the mixture of gained, is vacuumized, is stirred 13 minutes, then stand 30 minutes；
（6）To step（5）The product China of gained adds modifying agent and is stirred, is modified, produces the novel glass gluing agent.
Wherein, the filler is first to add heavy calcium carbonate during addition, adds wood powder, is eventually adding shellfish
Shell powder.
Wherein, the mixing speed of the high-speed stirred is 800r/min.
Embodiment 3
The present embodiment is related to a kind of novel glass gluing agent, includes the raw material of following parts by weight：23 parts of butadiene-styrene rubber, polyacrylic acid
17 parts, 20 parts of epoxy resin, 9 parts of methyl methacrylate, 12 parts of starch, 13 parts of polyurethane, 17 parts of acetone, mixture of Chinese herbal medicines
3 parts, 21 parts of filler, 4 parts of modifying agent, 1.7 parts of oxide additive, 5 parts of curing agent.
Wherein, the filler includes the component of following parts by weight：6 parts of wood powder, 2.5 parts of oyster shell whiting and heavy calcium carbonate
3.8 part.
Wherein, the oxide addition is boron oxide.
Wherein, the modifying agent includes the component of following parts by weight：1.2 parts of 1.3 parts of tannin extract, 4 parts of gelatin and Quercetin.
Wherein, the mixture of Chinese herbal medicines is the mixture of honeysuckle, garlic, ginger, cordate houttuynia, cassia bark and cloves.
A kind of method for preparing the novel glass gluing agent, comprises the following steps：
（1）Butadiene-styrene rubber, polyacrylic acid, epoxy resin, methyl methacrylate, starch, polyurethane, third are weighed by said components
Ketone, mixture of Chinese herbal medicines, filler, modifying agent, oxide additive, curing agent, it is standby；
（2）Mixture of Chinese herbal medicines was ground into 100~200 mesh sieves, first adds the warm water immersion 1.2 of 6 times of mixture of Chinese herbal medicines
Hour, intense fire infusion 25 minutes, boil, then be cooked by slow fire 35 minutes, normal temperature is cooled to, obtains Chinese medicine mixed liquor；
（3）Chinese medicine mixed liquor and butadiene-styrene rubber, polyacrylic acid, epoxy resin, methyl methacrylate and polyurethane are added successively
Enter in reactor, heat while stirring, be heated to 75 DEG C, ultrasonication 6 minutes, insulation stands 15 minutes, is cooled to normal temperature；
（4）To step（3）Acetone, oxide additive, high-speed stirred 15 minutes, Ran Houjia are sequentially added in obtained mixture
Enter starch and filler, high-speed stirred to bubble collapse；
（5）To step（4）Curing agent is added in the mixture of gained, is vacuumized, is stirred 9 minutes, then stand 23 minutes；
（6）To step（5）The product China of gained adds modifying agent and is stirred, is modified, produces the novel glass gluing agent.
Wherein, the filler is first to add heavy calcium carbonate during addition, adds wood powder, is eventually adding shellfish
Shell powder.
Wherein, the mixing speed of the high-speed stirred is 730r/min.
Embodiment 4
The present embodiment is related to a kind of novel glass gluing agent, includes the raw material of following parts by weight：35 parts of butadiene-styrene rubber, polyacrylic acid
21 parts, 25 parts of epoxy resin, 12 parts of methyl methacrylate, 15 parts of starch, 16 parts of polyurethane, 22 parts of acetone, Chinese herbal medicine mixing
4 parts of thing, 26 parts of filler, 5 parts of modifying agent, 2.6 parts of oxide additive, 6 parts of curing agent.
Wherein, the filler includes the component of following parts by weight：7 parts of wood powder, 3.3 parts of oyster shell whiting and heavy calcium carbonate
2.5 part.
Wherein, the oxide addition is the combination of silica, alundum (Al2O3).
Wherein, the modifying agent includes the component of following parts by weight：1.7 parts of 2.3 parts of tannin extract, 7 parts of gelatin and Quercetin.
Wherein, the mixture of Chinese herbal medicines is the mixture of honeysuckle, garlic, ginger, cordate houttuynia, cassia bark and cloves.
A kind of method for preparing the novel glass gluing agent, comprises the following steps：
（1）Butadiene-styrene rubber, polyacrylic acid, epoxy resin, methyl methacrylate, starch, polyurethane, third are weighed by said components
Ketone, mixture of Chinese herbal medicines, filler, modifying agent, oxide additive, curing agent, it is standby；
（2）Mixture of Chinese herbal medicines was ground into 100~200 mesh sieves, first adds the warm water immersion 1.8 of 9 times of mixture of Chinese herbal medicines
Hour, intense fire infusion 35 minutes, boil, then be cooked by slow fire 50 minutes, normal temperature is cooled to, obtains Chinese medicine mixed liquor；
（3）Chinese medicine mixed liquor and butadiene-styrene rubber, polyacrylic acid, epoxy resin, methyl methacrylate and polyurethane are added successively
Enter in reactor, heat while stirring, be heated to 85 DEG C, ultrasonication 7 minutes, insulation stands 25 minutes, is cooled to normal temperature；
（4）To step（3）Acetone, oxide additive, high-speed stirred 20 minutes, Ran Houjia are sequentially added in obtained mixture
Enter starch and filler, high-speed stirred to bubble collapse；
（5）To step（4）Curing agent is added in the mixture of gained, is vacuumized, is stirred 12 minutes, then stand 28 minutes；
（6）To step（5）The product China of gained adds modifying agent and is stirred, is modified, produces the novel glass gluing agent.
Wherein, the filler is first to add heavy calcium carbonate during addition, adds wood powder, is eventually adding shellfish
Shell powder.
Wherein, the mixing speed of the high-speed stirred is 790r/min.
Embodiment 5
The present embodiment is related to a kind of novel glass gluing agent, includes the raw material of following parts by weight：27 parts of butadiene-styrene rubber, polyacrylic acid
18 parts, 23 parts of epoxy resin, 11 parts of methyl methacrylate, 14 parts of starch, 15 parts of polyurethane, 19 parts of acetone, Chinese herbal medicine mixing
3.5 parts of thing, 25 parts of filler, 4.7 parts of modifying agent, 2.4 parts of oxide additive, 5.8 parts of curing agent.
Wherein, the filler includes the component of following parts by weight：6.5 parts of wood powder, 3 parts of oyster shell whiting and heavy calcium carbonate 3
Part.
Wherein, the oxide addition is the combination in silica, alundum (Al2O3) and boron oxide.
Wherein, the modifying agent includes the component of following parts by weight：1.5 parts of 2 parts of tannin extract, 5 parts of gelatin and Quercetin.
Wherein, the mixture of Chinese herbal medicines is the mixture of honeysuckle, garlic, ginger, cordate houttuynia, cassia bark and cloves.
A kind of method for preparing the novel glass gluing agent, comprises the following steps：
（1）Butadiene-styrene rubber, polyacrylic acid, epoxy resin, methyl methacrylate, starch, polyurethane, third are weighed by said components
Ketone, mixture of Chinese herbal medicines, filler, modifying agent, oxide additive, curing agent, it is standby；
（2）Mixture of Chinese herbal medicines was ground into 100~200 mesh sieves, first adds the warm water immersion 1.5 of 7 times of mixture of Chinese herbal medicines
Hour, intense fire infusion 30 minutes, boil, then be cooked by slow fire 45 minutes, normal temperature is cooled to, obtains Chinese medicine mixed liquor；
（3）Chinese medicine mixed liquor and butadiene-styrene rubber, polyacrylic acid, epoxy resin, methyl methacrylate and polyurethane are added successively
Enter in reactor, heat while stirring, be heated to 80 DEG C, ultrasonication 7 minutes, insulation stands 20 minutes, is cooled to normal temperature；
（4）To step（3）Acetone, oxide additive, high-speed stirred 18 minutes, Ran Houjia are sequentially added in obtained mixture
Enter starch and filler, high-speed stirred to bubble collapse；
（5）To step（4）Curing agent is added in the mixture of gained, is vacuumized, is stirred 10 minutes, then stand 25 minutes；
（6）To step（5）The product China of gained adds modifying agent and is stirred, is modified, produces the novel glass gluing agent.
Wherein, the filler is first to add heavy calcium carbonate during addition, adds wood powder, is eventually adding shellfish
Shell powder.
Wherein, the mixing speed of the high-speed stirred is 750r/min.
The specific embodiment of the present invention is described above.It is to be appreciated that the invention is not limited in above-mentioned
Particular implementation, those skilled in the art can make various deformations or amendments within the scope of the claims, this not shadow
Ring the substantive content of the present invention.
Claims (10)
1. a kind of novel glass gluing agent, it is characterised in that include the raw material of following parts by weight：20~40 parts of butadiene-styrene rubber, gather
13~22 parts of acrylic acid, 15~27 parts of epoxy resin, 7~14 parts of methyl methacrylate, 8~17 parts of starch, polyurethane 11~
18 parts, 15~26 parts of acetone, 2~5 parts of mixture of Chinese herbal medicines, 17~28 parts of filler, 3~6 parts of modifying agent, oxide additive 1
~3 parts, 4~7 parts of curing agent.
2. novel glass gluing agent according to claim 1, it is characterised in that include the raw material of following parts by weight：Butylbenzene
23~35 parts of rubber, 17~21 parts of polyacrylic acid, 20~25 parts of epoxy resin, 9~12 parts of methyl methacrylate, starch 12~
15 parts, 13~16 parts of polyurethane, 17~22 parts of acetone, 3~4 parts of mixture of Chinese herbal medicines, 21~26 parts of filler, modifying agent 4~5
Part, 1.7~2.6 parts of oxide additive, 5~6 parts of curing agent.
3. novel glass gluing agent according to claim 1, it is characterised in that include the raw material of following parts by weight：Butylbenzene
27 parts of rubber, 18 parts of polyacrylic acid, 23 parts of epoxy resin, 11 parts of methyl methacrylate, 14 parts of starch, 15 parts of polyurethane, third
19 parts of ketone, 3.5 parts of mixture of Chinese herbal medicines, 25 parts of filler, 4.7 parts of modifying agent, 2.4 parts of oxide additive, 5.8 parts of curing agent.
4. novel glass gluing agent according to claim 1, it is characterised in that the filler includes the group of following parts by weight
Point：2~4 parts of 5~8 parts of wood powder, 2~4 parts of oyster shell whiting and heavy calcium carbonate.
5. novel glass gluing agent according to claim 1, it is characterised in that the oxide addition is titanium dioxide
One or more of combinations in silicon, alundum (Al2O3) and boron oxide.
6. novel glass gluing agent according to claim 1, it is characterised in that the modifying agent includes following parts by weight
Component：1~2 part of 1~3 part of tannin extract, 3~8 parts of gelatin and Quercetin.
7. novel glass gluing agent according to claim 1, it is characterised in that the mixture of Chinese herbal medicines be honeysuckle,
Garlic, ginger, cordate houttuynia, the mixture of cassia bark and cloves.
A kind of 8. method for preparing the novel glass gluing agent of any one of claim 1~7, it is characterised in that the preparation
Method comprises the following steps：
（1）Butadiene-styrene rubber, polyacrylic acid, epoxy resin, methyl methacrylate, starch, polyurethane, third are weighed by said components
Ketone, mixture of Chinese herbal medicines, filler, modifying agent, oxide additive, curing agent, it is standby；
（2）Mixture of Chinese herbal medicines was ground into 100~200 mesh sieves, first adds the warm water immersion of 5~10 times of mixture of Chinese herbal medicines
1~2 hour, intense fire infusion 20~40 minutes, boil, then be cooked by slow fire 30~60 minutes, be cooled to normal temperature, obtain Chinese medicine mixing
Liquid；
（3）Chinese medicine mixed liquor and butadiene-styrene rubber, polyacrylic acid, epoxy resin, methyl methacrylate and polyurethane are added successively
Enter in reactor, heat while stirring, be heated to 70~90 DEG C, ultrasonication 5~10 minutes, insulation stands 10~30 points
Clock, it is cooled to normal temperature；
（4）To step（3）Sequentially add acetone, oxide additive in obtained mixture, high-speed stirred 13~22 minutes, so
Starch and filler, high-speed stirred to bubble collapse are added afterwards；
（5）To step（4）Curing agent is added in the mixture of gained, is vacuumized, is stirred 7~13 minutes, then stand 20~30 points
Clock；
（6）To step（5）The product China of gained adds modifying agent and is stirred, is modified, produces the novel glass gluing agent.
9. preparation method according to claim 8, it is characterised in that the filler is first to add weight during addition
Matter Paris white, adds wood powder, is eventually adding oyster shell whiting.
10. preparation method according to claim 8, it is characterised in that the mixing speed of the high-speed stirred be 700~
800r/min。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710522036.XA CN107353846A (en) | 2017-06-30 | 2017-06-30 | A kind of novel glass gluing agent and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710522036.XA CN107353846A (en) | 2017-06-30 | 2017-06-30 | A kind of novel glass gluing agent and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107353846A true CN107353846A (en) | 2017-11-17 |
Family
ID=60272542
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710522036.XA Withdrawn CN107353846A (en) | 2017-06-30 | 2017-06-30 | A kind of novel glass gluing agent and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107353846A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110939378A (en) * | 2019-11-16 | 2020-03-31 | 河北金河电力器具有限公司 | Glued full-insulation ladder and special glue |
| CN111218253A (en) * | 2020-03-27 | 2020-06-02 | 山东有利尔胶业有限公司 | Preparation method of glass cement with improved viscosity |
| CN115521741A (en) * | 2022-09-30 | 2022-12-27 | 江苏天顺印业有限公司 | Alcohol-resistant waterproof glass cement and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103937432A (en) * | 2014-02-14 | 2014-07-23 | 上海禧合应用材料有限公司 | Sealant |
| CN105440976A (en) * | 2015-12-03 | 2016-03-30 | 三友（天津）高分子技术有限公司 | Single-component solvent-free sealing adhesive capable of being quickly cured at 100 DEG C and preparation method |
| CN106281109A (en) * | 2016-08-26 | 2017-01-04 | 桐乡嘉力丰实业股份有限公司 | A kind of high stability mildew-resistant environmental protection Oryza glutinosa glue and preparation technology thereof |
| CN106590490A (en) * | 2016-12-12 | 2017-04-26 | 天豪玻璃制品集团有限公司 | Glass adhesive and preparation method thereof |
-
2017
- 2017-06-30 CN CN201710522036.XA patent/CN107353846A/en not_active Withdrawn
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103937432A (en) * | 2014-02-14 | 2014-07-23 | 上海禧合应用材料有限公司 | Sealant |
| CN105440976A (en) * | 2015-12-03 | 2016-03-30 | 三友（天津）高分子技术有限公司 | Single-component solvent-free sealing adhesive capable of being quickly cured at 100 DEG C and preparation method |
| CN106281109A (en) * | 2016-08-26 | 2017-01-04 | 桐乡嘉力丰实业股份有限公司 | A kind of high stability mildew-resistant environmental protection Oryza glutinosa glue and preparation technology thereof |
| CN106590490A (en) * | 2016-12-12 | 2017-04-26 | 天豪玻璃制品集团有限公司 | Glass adhesive and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 洪仲苓主编: "《化工有机原料深加工》", 30 June 1997, 化学工业出版社 * |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110939378A (en) * | 2019-11-16 | 2020-03-31 | 河北金河电力器具有限公司 | Glued full-insulation ladder and special glue |
| CN110939378B (en) * | 2019-11-16 | 2021-10-22 | 河北金河电力器具有限公司 | Glued full-insulation ladder and special glue |
| CN111218253A (en) * | 2020-03-27 | 2020-06-02 | 山东有利尔胶业有限公司 | Preparation method of glass cement with improved viscosity |
| CN115521741A (en) * | 2022-09-30 | 2022-12-27 | 江苏天顺印业有限公司 | Alcohol-resistant waterproof glass cement and preparation method thereof |
| CN115521741B (en) * | 2022-09-30 | 2023-08-22 | 江苏天顺印业有限公司 | Alcohol-resistant waterproof glass cement and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107353846A (en) | A kind of novel glass gluing agent and preparation method thereof | |
| CN105038588B (en) | A kind of environment protecting wood wax oil and preparation method thereof | |
| CN105565974A (en) | Environment-friendly efficient multifunctional fertilizer wrapping agent as well as preparation method and application | |
| CN102302123B (en) | Glutinous rice dessert sausage and making method thereof | |
| CN103173173A (en) | Bi-component epoxy adhesive and preparation method thereof | |
| CN110305494A (en) | A kind of preparation method of the nontoxic ultralight clay of colour | |
| CN109575697A (en) | A kind of starch-based aqueous coating composition and preparation method thereof | |
| CN104710717B (en) | Macromolecule clay material | |
| CN104194700A (en) | Corrosion-resistant acid-resistant solvent-free epoxy resin adhesive formula and preparation process thereof | |
| CN108003838A (en) | Colored snowmaking and preparation method thereof | |
| CN105272023A (en) | Environment-friendly paint | |
| CN106590490A (en) | Glass adhesive and preparation method thereof | |
| CN104026548A (en) | Method for preparing compound seasoning with flavor of tomato braised beef brisket by combining vacuum frying technology and microcapsule embedding technology | |
| CN103865442A (en) | Mouldproof and environmentally-friendly glass adhesive | |
| CN101531485B (en) | Air entraining admixture of concrete | |
| CN105166908A (en) | Micro-capsule powder rich in omega-3 fatty acid and preparation method thereof | |
| CN101191006A (en) | Controllable solidifying type technologic clay sculpture material | |
| CN101744207B (en) | Method for preparing high-pungency chilli extract | |
| CN108359304A (en) | A kind of high-performance powder of lacquer putty for use on of exterior wall and preparation method thereof | |
| CN104305143A (en) | Production process of chili sauce | |
| CN103450446B (en) | A kind of synthetic method of modified bisphenol A epoxy acrylate | |
| CN109355021A (en) | A kind of environmental protection high-heat-conductivity glue and manufacturing method | |
| RU2009110884A (en) | METHOD FOR OBTAINING A BINDER FOR A PREPARATION (OPTIONS), A BINDER FOR A PREPARATION (OPTIONS), A PREPARATION AND PRODUCT | |
| CN106116302B (en) | A kind of inner wall of building attapulgite coating | |
| CN102745635A (en) | Filling technology of pest-sticking glue |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20171117 |