CN106590490A - Glass adhesive and preparation method thereof - Google Patents
Glass adhesive and preparation method thereof Download PDFInfo
- Publication number
- CN106590490A CN106590490A CN201611139353.5A CN201611139353A CN106590490A CN 106590490 A CN106590490 A CN 106590490A CN 201611139353 A CN201611139353 A CN 201611139353A CN 106590490 A CN106590490 A CN 106590490A
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- CN
- China
- Prior art keywords
- parts
- glass adhesive
- preparation
- adhesive according
- filler
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J161/00—Adhesives based on condensation polymers of aldehydes or ketones; Adhesives based on derivatives of such polymers
- C09J161/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
- C09J161/22—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with acyclic or carbocyclic compounds
- C09J161/24—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen of aldehydes with acyclic or carbocyclic compounds with urea or thiourea
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention provides a glass adhesive and a preparation method thereof and relates to the technical field of adhesives. The glass adhesive is prepared from the following raw material components in parts by weight: 100-120 parts of UF (urea-formaldehyde) resin, 10-20 parts of bentonite, 3-4 parts of metallic soap, 30-40 parts of starch, 5-6 parts of dimethyl carbonate, 6-10 parts of a curing agent, 30-50 parts of filler, 4-6 parts of a modifier and 90-110 parts of water. The preparation method comprises the following steps: 1) adding UF resin, coal tar, metallic soap, alkanolamide and water to a mixer for sufficient stirring and adhesive mixing; 2) adding the starch and the filler for stirring until no air mass is left in the mixer; 3) adding the curing agent to be stirred for 5-10 minutes, and then leaving the mixture to stand for 15 minutes; 4) adding the modifier for mixing finally. The glass adhesive has the advantages of good thermosetting property, high viscosity, high strength, good endurance, good waterproof effect and long service life, and is not easy to degenerate or crack.
Description
Technical field：
The present invention relates to glue technical field, specifically a kind of glass adhesive and preparation method thereof.
Background technology：
Existing glass cement, is a kind of conventional adhesive of family, and main component is sodium silicate (Na2OmSiO2) and vinegar
The silicone composition of acid and Organic.Sodium silicate is soluble in water, toughness, and south is also referred to as waterglass, and the north is also referred to as sodium silicate.But
It is that the material with harm such as formaldehyde is usually added with this glass cement, it is larger used in indoor decoration pollution, and adhesive
Caking property is poor, and the process of setting time is longer, and viscosity is not enough, and especially when temperature is higher, viscosity is substantially reduced, and is unfavorable for gluing
The molding of plate, the intensity after molding is not enough, and the effect of adhesive waterproof is poor, and the product produced easily ftractures after rainwater, leads
Cause service life low.
The content of the invention：
The technical problem to be solved is that a kind of thermosetting of offer is good, and viscosity is high, and intensity is high, good water-proof effect
Glass adhesive and preparation method thereof.
The technical problem of solution adopts following technical scheme：
A kind of glass adhesive, it is characterised in that：Including following raw material component：
Described firming agent includes by weight, 2～3 parts of phoxim, 5～7 parts of tartaric acid and hexamethylenetetramine 1～2
Part.
Described filler includes by weight, 2～4 parts of 5～8 parts of wood powder, 2～4 parts of conch meal and heavy calcium carbonate.
Described modifying agent includes by weight, 1～2 part of 1～3 part of tannic extract, 3～8 parts of gelatin and Quercetin.
A kind of preparation method of glass adhesive, it is characterised in that：Comprise the following steps,
1) UF resins, bentonite, metallic soap, dimethyl carbonate and water are added sequentially to be sufficiently stirred in blender
Impregnation；
2) starch and filler stirring are added, to no air mass in blender raw material；
3) add under firming agent vacuum condition and stir 5～10 minutes, 15 minutes are then stood again；
4) finally add modifying agent to be stirred.
Described filler is to be initially charged heavy calcium carbonate during addition, adds wood powder, is eventually adding shell
Powder.
The temperature operated in described step is no more than 40 DEG C.
Production department's adhesive has good waterproof effect in instant component raw material, and the adhesive produced has very high
Gumminess, gumminess reduces very little when hot-forming, and the firming agent in the present invention can cause adhesive to have preferably heat
Gu effect, the speed of thermosetting is fast；And the intensity of the filler of the present invention is high, during preparation and later stage hot-forming mistake
More degeneration will not be produced in journey, with the lasting efficacy of intensity, and modifying agent can be also added in the present invention, can be further
Increase its viscosity, while adhesive can be protected to be not easy to be oxidized.
The invention has the beneficial effects as follows：The present invention can have thermosetting good, and viscosity height, intensity is high, and endurance is good, does not allow
It is perishable, good water-proof effect, long service life, it is not easy to ftracture.
Specific embodiment：
In order that technological means, creation characteristic, reached purpose and effect that the present invention is realized are easy to understand, tie below
Instantiation is closed, the present invention is expanded on further.
Embodiment one
A kind of glass adhesive, including following raw material component：
Firming agent includes by weight, 1 part of 2 parts of phoxim, 5 parts of tartaric acid and hexamethylenetetramine.
Filler includes by weight, 2 parts of 5 parts of wood powder, 2 parts of conch meal and heavy calcium carbonate.
Modifying agent includes by weight, 1 part of 1 part of tannic extract, 3 parts of gelatin and Quercetin.
A kind of preparation method of glass adhesive, comprises the following steps,
1) UF resins, bentonite, metallic soap, dimethyl carbonate and water are added sequentially to be sufficiently stirred in blender
Impregnation；
2) starch and filler stirring are added, to no air mass in blender raw material；
3) add under firming agent vacuum condition and stir 5～10 minutes, 15 minutes are then stood again；
4) finally add modifying agent to be stirred.
Filler is to be initially charged heavy calcium carbonate during addition, adds wood powder, is eventually adding conch meal.Do not allow
It is perishable.
The temperature operated in step is no more than 40 DEG C.
Embodiment two
A kind of glass adhesive, including following raw material component：
Firming agent includes by weight, 1.5 parts of 2.53 parts of phoxim, 6 parts of tartaric acid and hexamethylenetetramine.
Filler includes by weight, 3 parts of 6 parts of wood powder, 3 parts of conch meal and heavy calcium carbonate.
Modifying agent includes by weight, 1.5 parts of 2 parts of tannic extract, 5 parts of gelatin and Quercetin.
A kind of preparation method of glass adhesive, comprises the following steps,
1) UF resins, bentonite, metallic soap, dimethyl carbonate and water are added sequentially to be sufficiently stirred in blender
Impregnation；
2) starch and filler stirring are added, to no air mass in blender raw material；
3) add under firming agent vacuum condition and stir 5～10 minutes, 15 minutes are then stood again；
4) finally add modifying agent to be stirred.
Filler is to be initially charged heavy calcium carbonate during addition, adds wood powder, is eventually adding conch meal.Do not allow
It is perishable.
The temperature operated in step is no more than 40 DEG C.
Embodiment three
A kind of glass adhesive, including following raw material component：
Firming agent includes by weight, 2 parts of 3 parts of phoxim, 7 parts of tartaric acid and hexamethylenetetramine.
Filler includes by weight, 4 parts of 8 parts of wood powder, 4 parts of conch meal and heavy calcium carbonate.
Modifying agent includes by weight, 2 parts of 3 parts of tannic extract, 8 parts of gelatin and Quercetin.
A kind of preparation method of glass adhesive, comprises the following steps,
1) UF resins, bentonite, metallic soap, dimethyl carbonate and water are added sequentially to be sufficiently stirred in blender
Impregnation；
2) starch and filler stirring are added, to no air mass in blender raw material；
3) add under firming agent vacuum condition and stir 5～10 minutes, 15 minutes are then stood again；
4) finally add modifying agent to be stirred.
Filler is to be initially charged heavy calcium carbonate during addition, adds wood powder, is eventually adding conch meal.Do not allow
It is perishable.
The temperature operated in step is no more than 40 DEG C.
The ultimate principle and principal character and advantages of the present invention of the present invention has been shown and described above.The technology of the industry
Personnel it should be appreciated that the present invention is not restricted to the described embodiments, the simply explanation described in above-described embodiment and description this
The principle of invention, without departing from the spirit and scope of the present invention, the present invention also has various changes and modifications, these changes
Change and improvement is both fallen within scope of the claimed invention.The claimed scope of the invention by appending claims and its
Equivalent thereof.
Claims (7)
1. a kind of glass adhesive, it is characterised in that：Including following raw material component：
2. a kind of glass adhesive according to claim 1, it is characterised in that：Described firming agent includes by weight,
1～2 part of 2～3 parts of phoxim, 5～7 parts of tartaric acid and hexamethylenetetramine.
3. a kind of glass adhesive according to claim 1, it is characterised in that：Described filler includes by weight, wooden
2～4 parts of 5～8 parts of powder, 2～4 parts of conch meal and heavy calcium carbonate.
4. a kind of glass adhesive according to claim 1, it is characterised in that：Described modifying agent includes by weight,
1～2 part of 1～3 part of tannic extract, 3～8 parts of gelatin and Quercetin.
5. the preparation method of a kind of glass adhesive according to claim 1,2,3 or 4, it is characterised in that：Including following
Step,
1) UF resins, bentonite, metallic soap, dimethyl carbonate and water are added sequentially to carry out being sufficiently stirred for adjusting in blender
Glue；
2) starch and filler stirring are added, to no air mass in blender raw material；
3) add under firming agent vacuum condition and stir 5～10 minutes, 15 minutes are then stood again；
4) finally add modifying agent to be stirred.
6. the preparation method of a kind of glass adhesive according to claim 5, it is characterised in that：Described filler is being added
During be to be initially charged heavy calcium carbonate, add wood powder, be eventually adding conch meal.
7. the preparation method of a kind of glass adhesive according to claim 5, it is characterised in that：Operate in described step
Temperature be no more than 40 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611139353.5A CN106590490A (en) | 2016-12-12 | 2016-12-12 | Glass adhesive and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611139353.5A CN106590490A (en) | 2016-12-12 | 2016-12-12 | Glass adhesive and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN106590490A true CN106590490A (en) | 2017-04-26 |
Family
ID=58599385
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611139353.5A Pending CN106590490A (en) | 2016-12-12 | 2016-12-12 | Glass adhesive and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN106590490A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107189731A (en) * | 2017-06-22 | 2017-09-22 | 合肥钢骨玻璃制品有限公司 | A kind of novel glass binding agent and preparation method thereof |
| CN107353846A (en) * | 2017-06-30 | 2017-11-17 | 合肥利裕泰玻璃制品有限公司 | A kind of novel glass gluing agent and preparation method thereof |
| CN113637439A (en) * | 2021-08-03 | 2021-11-12 | 四川天邑康和通信股份有限公司 | Glue formula applied to packaging of core optical device of optical module and blending method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105567147A (en) * | 2014-10-14 | 2016-05-11 | 南京新德利复合材料有限公司 | Glass adhesive and preparation method thereof |
| CN106118564A (en) * | 2016-07-21 | 2016-11-16 | 和县薛氏木制品制造有限公司 | A kind of plywood adhesive and preparation method thereof |
| CN106189966A (en) * | 2016-07-21 | 2016-12-07 | 和县薛氏木制品制造有限公司 | A kind of waterproof pluwood adhesive and preparation method thereof |
| CN106189936A (en) * | 2016-07-21 | 2016-12-07 | 和县薛氏木制品制造有限公司 | A kind of high-temperature plastic plywood adhesive and preparation method thereof |
-
2016
- 2016-12-12 CN CN201611139353.5A patent/CN106590490A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105567147A (en) * | 2014-10-14 | 2016-05-11 | 南京新德利复合材料有限公司 | Glass adhesive and preparation method thereof |
| CN106118564A (en) * | 2016-07-21 | 2016-11-16 | 和县薛氏木制品制造有限公司 | A kind of plywood adhesive and preparation method thereof |
| CN106189966A (en) * | 2016-07-21 | 2016-12-07 | 和县薛氏木制品制造有限公司 | A kind of waterproof pluwood adhesive and preparation method thereof |
| CN106189936A (en) * | 2016-07-21 | 2016-12-07 | 和县薛氏木制品制造有限公司 | A kind of high-temperature plastic plywood adhesive and preparation method thereof |
Non-Patent Citations (2)
| Title |
|---|
| （加）GEORGE WYPYCH编著、程斌等译: "《填料手册（第二版）》", 31 December 2003, 中国石化出版社 * |
| 吴世敏、印德麟: "《简明精细化工大辞典》", 30 June 1999, 辽宁科学技术出版社 * |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107189731A (en) * | 2017-06-22 | 2017-09-22 | 合肥钢骨玻璃制品有限公司 | A kind of novel glass binding agent and preparation method thereof |
| CN107353846A (en) * | 2017-06-30 | 2017-11-17 | 合肥利裕泰玻璃制品有限公司 | A kind of novel glass gluing agent and preparation method thereof |
| CN113637439A (en) * | 2021-08-03 | 2021-11-12 | 四川天邑康和通信股份有限公司 | Glue formula applied to packaging of core optical device of optical module and blending method thereof |
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| PB01 | Publication | ||
| PB01 | Publication | ||
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| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
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Application publication date: 20170426 |