CN107345380A - A kind of manufacture method of literature and art book paper - Google Patents
A kind of manufacture method of literature and art book paper Download PDFInfo
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- CN107345380A CN107345380A CN201710596482.5A CN201710596482A CN107345380A CN 107345380 A CN107345380 A CN 107345380A CN 201710596482 A CN201710596482 A CN 201710596482A CN 107345380 A CN107345380 A CN 107345380A
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- paper
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- starched
- ctmp
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Classifications
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H15/00—Pulp or paper, comprising fibres or web-forming material characterised by features other than their chemical constitution
- D21H15/02—Pulp or paper, comprising fibres or web-forming material characterised by features other than their chemical constitution characterised by configuration
- D21H15/10—Composite fibres
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H17/00—Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
- D21H17/005—Microorganisms or enzymes
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H19/00—Coated paper; Coating material
- D21H19/10—Coatings without pigments
- D21H19/14—Coatings without pigments applied in a form other than the aqueous solution defined in group D21H19/12
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/16—Sizing or water-repelling agents
-
- D—TEXTILES; PAPER
- D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
- D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
- D21H21/00—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
- D21H21/14—Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
- D21H21/22—Agents rendering paper porous, absorbent or bulky
- D21H21/24—Surfactants
Abstract
The invention discloses a kind of manufacture method of literature and art book paper, carried out with bleached sulphate softwood pulp NBKP, bleaching chemithermo mechanical pulp CTMP and alkaline hydrogen peroxide bleaching aspen mechanical slurry APMP as fibrous raw material with copying, product is sieved through underflow, condiment, punching slurry, desanding degasification, starching, fine screen, wet end dehydration forming, squeezing, preceding drying, top sizing, after drying, press polish, batch, packing forms.Product major parameter produced by the present invention is：Quantitative 55 65g/m2, the dynamic mill coefficient of friction of paper are less than 0.4；Paper longitudinal direction deflection 45 60mN, horizontal Ting Du≤25mN；Surface strength >=1.0m/s；Smoothness >=40s；Bulk >=1.6cm3/g；Fracture length >=4000m；Paper color is white, the 80%ISO of whiteness 76.
Description
Technical field
The present invention relates to a kind of manufacture method of literature and art book paper.
Background technology
Literature and art book paper is domestic at present all by import as high-grade books, picture album paper, and it requires paper bulky and soft
It is soft（It is big that paper requirement deflection is used different from conventional book）, printed that machine performance is good, anti-silk specification when adapting to lithographic printing is strong
Degree requires that paper has also required good exquisiteness and feel, and paper is clean, color and luster is soft, while requires surface strength height, can be full
Sufficient high speed printing, printing color is true to nature, and texture is strong.
As our people's living standard improves, more and more higher, especially some high-end print paper are required to paper quality,
It is required that books are light and papery is soft, this proposes very hang-up to paper production, and papery gently then wants bulk high, mechanical pulp dosage
It can increase, it is stiff to inevitably result in papery, meanwhile, smoothness must reduce, and cause paper not fine and smooth enough, and feel is poor, printing
Effect especially color printing effect is bad.
Present invention seek to address that problem above, meets that the country is high-end and is required with paper, mainly take following technology：（1）Slurry
In, preferably beating degree is not high, and bulk is high, the good chemi-thermo-mechanical pulp of flexibility（CTMP）, optimize pulping technique, to obtain
Well disappear latent effect, while mitigates CTMP mashing degree, improves sheet softness and improves bulk；（2）Using cellulase
The mashing of needlebush slurrying is aided in, obtains good strength simultaneously, reduces fibre cutting；（3）Add esterquat surfactant,
Improve sheet softness and bulk；（4）Top sizing adds the cruel potassium of carbonic acid, improves paper dimensional stability and flatness, improves paper
Open lithographic printing and cross machine performance（Anti- silk is the horizontal longitudinal direction as when printing of paper, and machine performance requirement height is crossed to paper）；（5）It is excellent
Change paper fibre orientation angle and deflection aspect ratio, reduce paper lateral stiffness；（6）Using calcium stearate class Cypres, change
Kind paper feel；（7）More preferable bulk is obtained using inorganic bulk agent.
The content of the invention
It is an object of the invention to provide a kind of manufacture method of the paper such as high-grade books, picture album, picture scroll, it requires its requirement
Paper bulky and softness（It is big that paper requirement deflection is used different from conventional book）, it is good to print machine performance, when adapting to lithographic printing
The requirement of anti-silk dimensional strength, paper also required good exquisiteness and feel, and paper is clean, color and luster is soft, while requires table
Surface intensity is high, can meet high speed printing, printing color is true to nature, and texture is strong.
To realize requirements above, the present invention uses following technical scheme, a kind of manufacture method of literature and art book paper, with bleaching
Sulfate softwood pulp（NBKP）, bleaching chemithermo mechanical pulp（CTMP）And alkaline hydrogen peroxide bleaching aspen mechanical slurry
（APMP）Carried out as fibrous raw material with copying, product is sieved through underflow, condiment, punching slurry, desanding degasification, starching, fine screen, wet end are dehydrated into
Type, squeezing, preceding drying, top sizing, rear drying, press polish, batch, packing forms, it is characterised in that：
（1）Slurry is bleached sulphate softwood pulp（NBKP）, bleaching chemithermo mechanical pulp（CTMP）And alkaline peroxide
Change hydrogen bleaching aspen mechanical slurry（APMP）, slurry weight, which matches, is：NBKP10~20%； APMP10-30%；CTMP50-80%.Its
In, not being beaten CTMP beating degrees 24-30SR, CTMP needs, bulk high product not high from beating degree, its pulping temperature need
Control is disappeared latent with improvement at 80-90 DEG C, is sufficiently spread out CTMP fibers.In addition, CTMP again through appropriate mashing, be beaten only with
Light knife processing, prevents that wire-dividing broom purification is excessively good, causes paper sheet stiffness excessive, and CTMP beating degrees are controlled in 28-34SR after mashing,
APMP is used from pulp production, beating degree 51-55SR；
（2）Using cellulase auxiliary needlebush slurrying mashing, obtain good strength simultaneously, reduce fibre cutting, dosage is
0.05-0.20kg/t is starched；Needlebush slurrying beating degree is controlled in 40-46SR；
（3）Esterquat surfactant is added, improves sheet softness and bulk, dosage is starched for 0.5-2.0kg/t, added
Access point be fine screen before, i.e. before one section of selectifier；
（4）Top sizing adds the cruel potassium of carbonic acid, improves paper dimensional stability and flatness, improves paper lithographic printing and crosses machine performance
（Anti- silk is the horizontal longitudinal direction as when printing of paper, and machine performance requirement height is crossed to paper）, dosage is 1.0-3.0kg/t slurries, is added
In surface sizing starch；
（5）Optimize paper fibre orientation angle and deflection aspect ratio, reduce paper lateral stiffness；2.9- is arrived into the control of deflection aspect ratio
Between 3.3, paper lateral stiffness is reduced.Because books flexibility is mainly reflected in horizontal flexibility, and horizontal flexibility can lead to
Cross control lateral stiffness（It is opposite with flexibility）Method realizes, Cultural Paper deflection aspect ratio can typically be less than 2.8, horizontal to reduce
To deflection, it is to compare effective means to improve deflection aspect ratio；
（6）Using calcium stearate class Cypres, improve paper feel, dosage is starched for 0.5-1.5kg/t, is added in top sizing
In starch；
（7）More preferable bulk is obtained using inorganic bulk agent, reaches light paper requirement, dosage is that 2-5kg/t is starched, addition point for
Stock tank.
Product major parameter produced by the present invention is：Quantitative 55-65g/m2, the dynamic mill coefficient of friction of paper are less than 0.4；Paper
Longitudinal deflection 45-60mN, horizontal Ting Du≤25mN；Surface strength >=1.0m/s；Smoothness >=40s；Bulk >=1.6cm3/g；
Fracture length >=4000m；Paper color is white, whiteness 76-80%ISO.
Main innovation point of the present invention is：
（1）It is preferred that bleach chemithermo mechanical pulp（CTMP）, CTMP is beaten only with light knife from beating degree not high product
Reason, prevents that wire-dividing broom purification is excessively good, causes paper sheet stiffness excessive；
（2）Using cellulase auxiliary needlebush slurrying mashing, obtain good strength simultaneously, reduce fibre cutting；
（3）Esterquat surfactant is added, improves sheet softness and bulk；
（4）Top sizing adds the cruel potassium of carbonic acid, improves paper dimensional stability and flatness, improves paper lithographic printing and crosses machine performance；
（5）Deflection aspect ratio is controlled between 2.9-3.3（Cultural Paper aspect ratio is often in 1.8-2.6）, it is horizontal to reduce paper
Deflection；
（6）Using calcium stearate class Cypres, improve paper feel；
（7）More preferable bulk is obtained using inorganic bulk agent.
Embodiment
Below by embodiment, the present invention is described in detail：
Embodiment 1
Poplar raw material is by stock, using PRC-APMP（P represents the pretreatment before defibrination, represents the chemistry that mill promotes slurry
Effect, APMP represent APMP）Whiteness 75%ISO, beating degree 53 is made in pulping process0SR poplar machine plasmas,
Outsourcing chemi-thermo-mechanical pulp CTMP beating degree 31SR, outsourcing bleached sulphate softwood pulp mashing to 420SR, wherein,
In NBKP pulping process, the cellulase of 0.1kg/t slurries is added during pulping.Above-mentioned three kinds of slurries are by 15% poplar machine plasma, 15% drift
White kp softwood pulp, the ratio progress of 70% chemi-thermo-mechanical pulp are with slurry, and mixing disposed slurry is deployed into concentration 3.0%
Mixing slurry.In mixing slurry, add inorganic bulk agent and obtain more preferable bulk, dosage is starched for 3kg/t.Mixing slurry is sieved through underflow,
Starch enhancer is added during condiment, then rushes slurry, desanding degasification, starching, fine screen, before fine screen, adds ester based quaternary ammonium salt surface-active
Agent, dosage are starched for 1.0kg/t；Thereafter net forming is dehydrated on paper pulp（Control online concentration 1.04%, pH value 8.5 of surfing the Net）, squeezing,
Drying, press polish after preceding drying, top sizing, batch, packing forms literature and art book paper.
In terms of top sizing, resin added is controlled by 3.5g/m2.Top sizing adds the cruel potassium of carbonic acid, dosage 1.5kg/t
Slurry；Using calcium stearate class Cypres, improve paper feel, dosage is starched for 1.0kg/t；
Through measuring：Quantitative 60g/m2, paper dyanainic friction coefficient 0.3；Paper longitudinal direction deflection 55mN, lateral stiffness 18mN；Surface is strong
Spend 1.2m/s；Smoothness 41s；Bulk 1.62cm3/g；Fracture length 4150m；Paper color is white, whiteness 77%ISO.
Embodiment 2
Whiteness 75%ISO, beating degree 54 is made using PRC-APMP pulping process by stock in poplar raw material0SR poplar machines
Slurry, outsourcing chemi-thermo-mechanical pulp CTMP beating degree 30SR, outsourcing bleached sulphate softwood pulp mashing to 410SR, wherein,
In NBKP pulping process, the cellulase of 0.08kg/t slurries is added during pulping.Above-mentioned three kinds of slurries are by 18% poplar machine plasma, 20% drift
White kp softwood pulp, the ratio progress of 62% chemi-thermo-mechanical pulp are with slurry, and mixing disposed slurry is deployed into concentration 3.2%
Mixing slurry.In mixing slurry, add inorganic bulk agent and obtain more preferable bulk, dosage is starched for 3.5kg/t.Mixing slurry is sieved through underflow,
Starch enhancer is added during condiment, then rushes slurry, desanding degasification, starching, fine screen, before fine screen, adds ester based quaternary ammonium salt surface-active
Agent, dosage are starched for 0.8kg/t；Thereafter net forming is dehydrated on paper pulp（Control online concentration 1.08%, pH value 8.4 of surfing the Net）, squeezing,
Drying, press polish after preceding drying, top sizing, batch, packing forms literature and art book paper.
In terms of top sizing, resin added is controlled by 3.8g/m2.Top sizing adds the cruel potassium of carbonic acid, dosage 1.6kg/t
Slurry；Using calcium stearate class Cypres, improve paper feel, dosage is starched for 0.9kg/t；
Through measuring：Quantitative 64.5g/m2, paper dyanainic friction coefficient 0.35；Paper longitudinal direction deflection 58mN, lateral stiffness 19mN；Table
Surface intensity 1.1m/s；Smoothness 42s；Bulk 1.61cm3/g；Fracture length 4210m；Paper color is white, whiteness 78%ISO.
Embodiment 3
Whiteness 75%ISO, beating degree 52 is made using PRC-APMP pulping process by stock in poplar raw material0SR poplar machines
Slurry, outsourcing chemi-thermo-mechanical pulp CTMP beating degree 29SR, outsourcing bleached sulphate softwood pulp mashing to 450SR, wherein,
In NBKP pulping process, the cellulase of 0.08kg/t slurries is added during pulping.Above-mentioned three kinds of slurries are by 11% poplar machine plasma, 19% drift
White kp softwood pulp, the ratio progress of 70% chemi-thermo-mechanical pulp are with slurry, and mixing disposed slurry is deployed into concentration 3.1%
Mixing slurry.In mixing slurry, add inorganic bulk agent and obtain more preferable bulk, dosage is starched for 4.5 kg/t.Mixing slurry is sieved through underflow,
Starch enhancer is added during condiment, then rushes slurry, desanding degasification, starching, fine screen, before fine screen, adds ester based quaternary ammonium salt surface-active
Agent, dosage are starched for 1.5kg/t；Thereafter net forming is dehydrated on paper pulp（Control online concentration 1.00%, pH value 8.2 of surfing the Net）, squeezing,
Drying, press polish after preceding drying, top sizing, batch, packing forms literature and art book paper.
In terms of top sizing, resin added is controlled by 3.6g/m2.Top sizing adds the cruel potassium of carbonic acid, dosage 2.3kg/t
Slurry；Using calcium stearate class Cypres, improve paper feel, dosage is starched for 1.2kg/t；
Through measuring：Quantitative 55.5g/m2, paper dyanainic friction coefficient 0.33；Paper longitudinal direction deflection 50mN, lateral stiffness 15mN；Table
Surface intensity 1.2m/s；Smoothness 43s；Bulk 1.63cm3/g；Fracture length 4350m；Paper color is white, whiteness 79%ISO.
Claims (1)
- A kind of 1. manufacture method of literature and art book paper, with bleached sulphate softwood pulp NBKP, bleaching chemithermo mechanical pulp CTMP and alkaline hydrogen peroxide bleaching aspen mechanical slurry APMP are carried out with copying as fibrous raw material, product sieves through underflow, condiment, punching Slurry, desanding degasification, starching, fine screen, wet end dehydration forming, squeezing, preceding drying, top sizing, rear drying, press polish, batch, pack Form, it is characterised in that：（1）The slurry weight matches：NBKP10~20%； APMP10-30%；CTMP50-80%；（2）Chemithermo mechanical pulp CTMP is bleached, is not beaten CTMP beating degree 24-30SR, its pulping temperature need to be controlled in 80-90 DEG C, the control of CTMP beating degrees is in 28-34SR after mashing；APMP is used from pulp production, beating degree 51-55SR；（3）Bleached sulphate softwood pulp NBKP addition cellulase auxiliary mashing, dosage are starched for 0.05-0.20kg/t, Its beating degree is controlled in 40-46SR；（4）Esterquat surfactant is added, dosage is starched for 0.5-2.0kg/t, and addition point is before fine screen；（5）Top sizing adds the cruel potassium of carbonic acid, and dosage is starched for 1.0-3.0kg/t, is added in surface sizing starch；（6）The control of deflection aspect ratio is 2.9-3.3；（7）Using calcium stearate class Cypres, dosage is starched for 0.5-1.5kg/t, is added in surface sizing starch；（8）Using inorganic bulk agent, dosage is starched for 2-5kg/t, and addition point is with stock tank.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201710596482.5A CN107345380B (en) | 2017-07-20 | 2017-07-20 | Method for manufacturing literature and art paper |
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| CN201710596482.5A CN107345380B (en) | 2017-07-20 | 2017-07-20 | Method for manufacturing literature and art paper |
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| CN107345380A true CN107345380A (en) | 2017-11-14 |
| CN107345380B CN107345380B (en) | 2020-03-24 |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109281218A (en) * | 2018-11-13 | 2019-01-29 | 岳阳林纸股份有限公司 | A kind of high white ring protects the manufacturing process of highmulti paper |
| CN109457531A (en) * | 2018-11-13 | 2019-03-12 | 岳阳林纸股份有限公司 | A kind of manufacturing method of brilliant white light weight papers |
| CN110331612A (en) * | 2019-05-23 | 2019-10-15 | 岳阳林纸股份有限公司 | A kind of manufacturing method of high proportion reducing rules sketch paper |
| CN111395038A (en) * | 2020-03-26 | 2020-07-10 | 东营华泰清河实业有限公司 | Cultural paper making process |
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| CN109281218A (en) * | 2018-11-13 | 2019-01-29 | 岳阳林纸股份有限公司 | A kind of high white ring protects the manufacturing process of highmulti paper |
| CN109457531A (en) * | 2018-11-13 | 2019-03-12 | 岳阳林纸股份有限公司 | A kind of manufacturing method of brilliant white light weight papers |
| CN110331612A (en) * | 2019-05-23 | 2019-10-15 | 岳阳林纸股份有限公司 | A kind of manufacturing method of high proportion reducing rules sketch paper |
| CN111395038A (en) * | 2020-03-26 | 2020-07-10 | 东营华泰清河实业有限公司 | Cultural paper making process |
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| Publication number | Publication date |
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| CN107345380B (en) | 2020-03-24 |
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