CN102877365A - Manufacturing method of high-bulk coating printing paper - Google Patents
Manufacturing method of high-bulk coating printing paper Download PDFInfo
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Abstract
The invention discloses a manufacturing method of high-bulk coating printing paper. In the method, high proportion chemical pulp is adopted for coating body paper, light calcium carbonate is used as filler, and high bulk is achieved. A door roller coating machine is used for coating the body paper, and the coating paint adopts plastic paint with a given proportion and a hollow structure, so that the bulk of the coat and the formed paper brightness can be effectively improved. Meanwhile, a soft calender is used for pre-calendering and polishing the coated body paper, so that the fineness of the paper surface is greatly improved while the thickness of the original paper is maintained. The bulk of the high-bulk coating printing paper manufactured through the method is 1.3 to 1.5 cm<3>/g and is far better than that of the ordinary copper paper and light coating paper; and meanwhile, the surface of the paper is smooth and fine, so that printed patterns are full and rich in color, image dots are clear and strong in three-dimensional impression, and the paper is applicable to top-grade color printing.
Description
Technical field
The present invention relates to a kind of manufacture method of high bulk coated printing paper, belong to pulp technology for making paper.
Background technology
In recent years, the demand of high bulk printing paper is in continuous growth.The high bulking paper light weight has not only kept thickness and the opacity of original paper, can adopt the low grammes per square metre high bulking paper of condition of equivalent thickness to substitute the common double gummed paper of high grammes per square metre during printing, not only make things convenient for the reader, can reduce the paper pulp use amount simultaneously, save the energy, reduced ambient pollution burden.
At present, the high bulk printing paper is mainly uncoated light offset paper on the market, and domestic papermaking enterprise is not also developed for the coated printing paper of high bulk.In order to fill up this market vacancy, from economizing on resources and the angle of protection of the environment, Zhongye Paper Yinhe Co., Ltd.'s develop goes out bulk at 1.3～1.5cm simultaneously
3The high bulk coated printing paper of/g, and called after " refined matter paper ".This paper bulk is far superior to ordinary copper millboard and light weight coated paper, and paper surface is smoothly fine and smooth simultaneously, and the printed patterns color is full bright-coloured, and the clear third dimension of dot of image is strong, is applicable to high-grade colored printing.The develop of refined matter paper is significant for adjusting China's coated printing paper product structure.
Summary of the invention
The object of the present invention is to provide a kind of manufacture method of high bulk coated printing paper.Its bodystock paper adopts the chemi-mechanical pulp of higher proportion; Adopt simultaneously door roller coating machine that body paper is coated with processing, its coating pigment adopts a certain proportion of plastic pigment with hollow structure, can effectively improve the bulk of coating and become the paper glossiness; Particularly adopted soft press-polishing machine that bodystock paper is also carried out surface finish, the fine and smooth degree of paper surface is greatly improved when keeping the body paper bulk.High bulk coated printing paper bulk of the present invention is 1.3～1.5cm
3/ g is far superior to ordinary copper millboard and light weight coated paper, and paper surface is smoothly fine and smooth simultaneously, and the full third dimension of printed patterns color is strong.
For achieving the above object, technical scheme of the present invention is as follows: a kind of high bulk coated printing paper manufacture method, comprise making beating, with slurry and auxiliary material adding, l Water Paper page or leaf shaping (online, squeezing), front drying, pre-press polish, coating, rear drying and soft calendaring finishing process step, it is characterized in that, adopt soft press-polishing machine to carry out precompressed polishing decorations through front dried bodystock paper, then adopt door roller coating machine that body paper is coated with processing;
Described pre-press polish process conditions:
Adopt two nip patterns, 1. advance soft press-polishing machine paper web moisture: 8～12%; 2. line ball pressure: a 100～160kN/m; One presses stiff dough roller (warm-up mill) operating temperature: 80～120 ℃; 3. two line ball pressure: 120～180kN/m; Two press stiff dough roller (warm-up mill) operating temperature: 100～140 ℃;
Body paper bulk 1.5～1.6cm through the soft press-polishing machine surface finish
3/ g; Smoothness (just/reverse side) all 〉=40s, the smoothness two sides is poor＜10%.
Described door roller coat cloth technological parameter:
Adopt door roll coater, 1. coating solid content: 60～63%; Dope viscosity: 900～1500mpas; Coating pH:8.5～9.3; 2. coating weight: 14～20g/m2; 3. advance coating machine paper web moisture: 6～10%.
Each component of described coating is by weight: 1. pigment is 100 parts, and wherein powdered whiting is 50～90 parts, 0～40 part of china clay, 5～15 parts of hollow type plastic pigments; 2. carboxylic styrene butadiene latex is 10～15 parts; 4～6 parts of coating starch; The PVA(polyvinyl alcohol) 0.5～3 part; The CMC(sodium carboxymethylcellulose) 0.5～2 part; 0.5～1 part of water repellent agent; 1～2 part of lubricant; 0.01～0.05 part of defoamer; Below all to the total umber of pigment.
Described coating process condition is preferably: external door roller and inside door roll nip linear pressure: 7～10kN/m; Inside door roller and applicator roll linear load: 8～14kN/m; Applicator roll linear load: 10～15kN/m.
Further technical scheme of the present invention is: described with slurry step is preferably:
The slurry weight proportioning is: bleached sulphate softwood pulp 20～30, leaf wood bleached chemical thermomechanical pulp 30～40, poplar APMP 35～50;
Each slurry index:
Bleached sulphate softwood pulp: 40～45 ° of SR of beating degree; Weight in wet base 6.8～7.5g;
Leaf wood bleached chemical thermomechanical pulp: 35～40 ° of SR of beating degree; Weight in wet base 1.0～1.4g;
Poplar APMP: 42～50 ° of SR of beating degree; Weight in wet base 1.0～1.4g.
Further technical scheme of the present invention is: described auxiliary material is preferably oven dry stock consumption (weight ratio): 1. the cationic starch consumption 0.6～1.2%; 2. PAE(Polyamide-Polyamsne-Epichlorohydrin resin) consumption 0.2～0.5%; 3. AKD(alkyl ketene dimer) consumption 0.1～0.3%; 4. PEI(polymine) consumption 0.05～0.12%; 5. CPAM(cationic polyacrylamide) consumption 0.02～0.05%; 6. APAM(anionic polyacrylamide) consumption 0.02～0.05%; 7. filler PCC(precipitated calcium carbonate) consumption 12～20%.
The characteristic of the high bulk coated printing paper of the present invention's preparation: quantitative 70～150g/m
2Bulk 1.3～1.5cm
3/ g; Smoothness (just/reverse side) 〉=500s, the smoothness two sides is poor＜and 10%; The print surface roughness (just/reverse side)≤2.0 μ m; Glossiness (just/reverse side) 〉=40%, print gloss (just/reverse side) 〉=60%; Ink absorption≤28%; Picking speed 〉=1.5m/s; Lateral extensometer shrinkage≤2.5%; Whiteness (ISO brightness) 78～82%; Opacity 〉=90%; Horizontal folding strength 〉=8 times; Vertical fracture length 〉=the 4km of roll web; Surface absorption weight≤35g/m
2Moisture 5.0～7.0%.
The invention has the beneficial effects as follows: the present invention relates to a kind of high bulk coated printing paper manufacture method, this bodystock paper adopts the chemi-mechanical pulp of higher proportion, and adopts PCC as filler, has higher bulk.Adopt door roller coating machine that body paper is coated with processing, its coating pigment adopts a certain proportion of plastic pigment with hollow structure, has effectively improved the bulk of coating and has become the paper glossiness.The characteristics that have simultaneously the profile coating in view of door roller coat cloth, so that the bodystock paper smoothness has determined to become smoothness and the surperficial fine and smooth degree of paper to a great extent, and high bulk coated printing paper bodystock paper smoothness is low, so adopt soft press-polishing machine that bodystock paper is carried out precompressed polishing decorations, the fine and smooth degree of paper surface is greatly improved when keeping the body paper bulk.The high bulk coated printing paper that adopts this method to make, the paper bulk is 1.3～1.5cm3/g, be far superior to common art paper and light weight coated paper, paper surface is smoothly fine and smooth simultaneously, the printed patterns color is full bright-coloured, the clear third dimension of dot of image is strong, is applicable to high-grade colored printing, has very high added value and wide market prospects.
The specific embodiment
Embodiment 1:
Each component of coating is by weight: 70 parts of powdered whitings, 20 parts of china clay, 10 parts of hollow type plastic pigments (polystyrene/acrylate spherical particle); 12 parts of carboxylic styrene butadiene latexs; 5 parts of coating starch; The PVA(polyvinyl alcohol) 1 part; The CMC(sodium carboxymethylcellulose) 1 part; 0.6 part of water repellent agent (zirconium carbonate ammonium); 1.5 parts of lubricants (calcium stearate); 0.03 part of defoamer (polyether modified silicon oil type).
(1) bleached sulphate softwood pulp (42 ° of SR of beating degree after will pulling an oar, weight in wet base 7.3g), leaf wood bleached chemical thermomechanical pulp (36 ° of SR of beating degree, weight in wet base 1.3g), three kinds of slurries of poplar APMP (46 ° of SR of beating degree, weight in wet base 1.2g) carry out with slurry according to the ratio of 25:35:40;
(2) add successively afterwards cationic starch to oven dry stock consumption 0.8%, 0.3% PAE, 0.1% PEI and 16% precipitated calcium carbonate filler, slurry is sent into three sections hydrocyclones of one-level through fan pump and is carried out purified treatment, enters degassing tank again and carries out degassed processing; Then enter pressurized screen and carry out Screening Treatment (add the AKD of oven dry stock consumption 0.15% and 0.04% CPAM in the pressurized screen porch, add the APAM to oven dry stock consumption 0.05% in the pressurized screen exit);
(3) send into afterwards the head box online, regulate surfing flow, the control page quantification is at 66g/m
2Online process conditions: the concentration of 1. surfing the Net: 0.6～1.0%; 2. pH:7.4～8.2 of surfing the Net; 3. 47～55 ° of SR of beating degree are starched in online; 4. total head: 16～19kPa;
(4) the l Water Paper page or leaf goes out to enter press section behind the wet end and carry out five rollers, three nip unipress, squeezes to mass dryness fraction and is dried to web dryness greater than 92% greater than entering front drying section after 45%; Press section process conditions: 1. line ball pressure: a 40～50kN/m; 2. two line ball pressure: 55～65kN/m; 3. three line ball pressure: 60～75kN/m;
(5) then enter soft press-polishing machine and carry out precompressed polishing decorations, soft press-polishing machine paper web moisture 10%, one line ball pressure 120kN/m is advanced in control, and one presses 90 ℃ of stiff dough roll temperatures, two line ball pressure 150kN/m, and two press 130 ℃ of stiff dough roll temperatures; Go out soft press-polishing machine paper web bulk 1.6cm
3/ g, smoothness (just/and reverse side) 45/42s;
(6) paper web goes out that to make paper web moisture through one group of drying cylinder first behind the soft press-polishing machine be 8%, access door roll-coater again, coating solid content 60%, viscosity 1000mpas, pH value 9.0, control coating weight 14g/m
2External door roller and inside door roll nip linear pressure: 7～10kN/m; Inside door roller and applicator roll linear load: 8～14kN/m; Applicator roll linear load: 10～15kN/m;
(7) paper web goes out that door roller coating machine is laggard to enter rear drying section, then enters soft press-polishing machine and carries out surface finish, adopts two nip patterns: a 1. line ball pressure 140kN/m, and one presses 130 ℃ of stiff dough roll temperatures; 2. two line ball pressure 160kN/m, two press 140 ℃ of stiff dough roll temperatures;
(8) paper web goes out soft press-polishing machine and enters rewinding machine, makes quantitatively to be 80g/m
2, bulk 1.35cm
3/ g, smoothness (just/and reverse side) 530/510s, the print surface roughness (just/and reverse side) 1.8/2.0 μ m, glossiness (just/and reverse side) 44/42%, print gloss (just/and reverse side) 65/63%, ink absorption 28%, picking speed 1.5m/s, lateral extensometer shrinkage 2.5%, whiteness (ISO brightness) 80%, opacity 92%, laterally folding strength is 8 times, vertical fracture length 4.5km, Surface absorption weight 30g/m
2, the high bulk coated printing paper of moisture 6.0%.
Embodiment 2:
Each component of coating is by weight: 60 parts of powdered whitings, 30 parts of china clay, 10 parts of hollow type plastic pigments (polystyrene/acrylate spherical particle); 10 parts of carboxylic styrene butadiene latexs; 6 parts of coating starch; The PVA(polyvinyl alcohol) 1.5 part; The CMC(sodium carboxymethylcellulose) 1.2 part; 0.7 part of water repellent agent (zirconium carbonate ammonium); 1.6 parts of lubricants (calcium stearate); 0.02 part of defoamer (polyether modified silicon oil type).
(1) bleached sulphate softwood pulp (45 ° of SR of beating degree after will pulling an oar, weight in wet base 7.0g), leaf wood bleached chemical thermomechanical pulp (36 ° of SR of beating degree, weight in wet base 1.3g), three kinds of slurries of poplar APMP (48 ° of SR of beating degree, weight in wet base 1.2g) carry out with slurry according to the ratio of 20:35:45.
(2) add successively afterwards cationic starch to oven dry stock consumption 0.8%, 0.3% PAE, 0.1% PEI and 18% precipitated calcium carbonate filler, slurry is sent into three sections hydrocyclones of one-level through fan pump and is carried out purified treatment, enters degassing tank again and carries out degassed processing; Then enter pressurized screen and carry out Screening Treatment (add the AKD of oven dry stock consumption 0.15% and 0.045% CPAM in the pressurized screen porch, add the APAM to oven dry stock consumption 0.05% in the pressurized screen exit);
(3) send into afterwards the head box online, regulate surfing flow, the control page quantification is at 84g/m
2Online process conditions: the concentration of 1. surfing the Net: 0.6～1.0%; 2. pH:7.4～8.2 of surfing the Net; 3. 47～55 ° of SR of beating degree are starched in online; 4. total head: 16～19kPa;
(4) the l Water Paper page or leaf goes out to enter press section behind the wet end and carry out five rollers, three nip unipress, squeezes to mass dryness fraction and is dried to web dryness greater than 92% greater than entering front drying section after 45%; Press section process conditions: 1. line ball pressure: a 40～50kN/m; 2. two line ball pressure: 55～65kN/m; 3. three line ball pressure: 60～75kN/m;
(5) then enter soft press-polishing machine and carry out precompressed polishing decorations, soft press-polishing machine paper web moisture 10%, one line ball pressure 130kN/m is advanced in control, and one presses 100 ℃ of stiff dough roll temperatures, two line ball pressure 150kN/m, and two press 130 ℃ of stiff dough roll temperatures; Go out soft press-polishing machine paper web bulk 1.6cm
3/ g, smoothness (just/and reverse side) 46/44s;
(6) paper web goes out that to make paper web moisture through one group of drying cylinder first behind the soft press-polishing machine be 8%, access door roll-coater again, coating solid content 60%, viscosity 1000mpas, pH value 9.0, control coating weight 16g/m
2External door roller and inside door roll nip linear pressure: 7～10kN/m; Inside door roller and applicator roll linear load: 8～14kN/m; Applicator roll linear load: 10～15kN/m;
(7) paper web goes out that door roller coating machine is laggard to enter rear drying section, then enters soft press-polishing machine and carries out surface finish, adopts two nip patterns: a 1. line ball pressure 130kN/m, and one presses 120 ℃ of stiff dough roll temperatures; 2. two line ball pressure 140kN/m, two press 130 ℃ of stiff dough roll temperatures;
(8) paper web goes out soft press-polishing machine and enters rewinding machine, makes quantitatively to be 100g/m
2, bulk 1.45cm
3/ g, smoothness (just/and reverse side) 550/520s, the print surface roughness (just/and reverse side) 1.7/1.8 μ m, glossiness (just/and reverse side) 43/42%, print gloss (just/and reverse side) 67/65%, ink absorption 28%, picking speed 1.5m/s, lateral extensometer shrinkage 2.5%, whiteness (ISO brightness) 80%, opacity 93%, laterally folding strength is 9 times, vertical fracture length 4.2km, Surface absorption weight 27g/m
2, the high bulk coated printing paper of moisture 6.0%.
Claims (7)
1. high bulk coated printing paper manufacture method, comprise making beating, with slurry and auxiliary material adding, the shaping of l Water Paper page or leaf, front drying, pre-press polish, coating, rear drying and soft calendaring finishing process step, it is characterized in that, adopt soft press-polishing machine to carry out precompressed polishing decorations through front dried bodystock paper, then adopt door roller coating machine that body paper is coated with processing; Filler adopts precipitated calcium carbonate in the described auxiliary material;
Described pre-press polish process conditions: adopt two nip patterns, 1. advance soft press-polishing machine paper web moisture: 8～12%; 2. line ball pressure: a 100～160kN/m; One presses stiff dough roller operating temperature: 80～120 ℃; 3. two line ball pressure: 120～180kN/m; Two press stiff dough roller operating temperature: 100～140 ℃;
Described coating process parameter: adopt door roll coater, 1. coating solid content: 60～63%; Dope viscosity: 900～1500mpas; Coating pH:8.5～9.3; 2. coating weight: 14～20g/m
23. advance coating machine paper web moisture: 6～10%.
2. a kind of high bulk coated printing paper manufacture method as claimed in claim 1 is characterized in that, each component of described coating by weight: 1. pigment is 100 parts, and wherein powdered whiting is 50～90 parts, 0～40 part of china clay, 5～15 parts of hollow type plastic pigments; 2. carboxylic styrene butadiene latex is 10～15 parts; 4～6 parts of coating starch; 0.5～3 part of polyvinyl alcohol; 0.5～2 part of sodium carboxymethylcellulose; 0.5～1 part of water repellent agent; 1～2 part of lubricant; 0.01～0.05 part of defoamer; Below all to the total umber of pigment.
3. a kind of high bulk coated printing paper manufacture method as claimed in claim 1 or 2 is characterized in that described coating process condition is: external door roller and inside door roll nip linear pressure: 7～10kN/m; Inside door roller and applicator roll linear load: 8～14kN/m; Applicator roll linear load: 10～15kN/m.
4. a kind of high bulk coated printing paper manufacture method as claimed in claim 2, it is characterized in that, described with slurry step slurry weight proportioning is: bleached sulphate softwood pulp 20～30, leaf wood bleached chemical thermomechanical pulp 30～40, poplar APMP 35～50.
5. a kind of high bulk coated printing paper manufacture method as claimed in claim 4 is characterized in that,
Each slurry index:
Bleached sulphate softwood pulp: 40～45 ° of SR of beating degree; Weight in wet base 6.8～7.5g;
Leaf wood bleached chemical thermomechanical pulp: 35～40 ° of SR of beating degree; Weight in wet base 1.0～1.4g;
Poplar APMP: 42～50 ° of SR of beating degree; Weight in wet base 1.0～1.4g.
6. a kind of high bulk coated printing paper manufacture method as claimed in claim 4, it is characterized in that described auxiliary material is counted with weight ratio the oven dry stock consumption: 1. the cationic starch consumption 0.6～1.2%; 2. the Polyamide-Polyamsne-Epichlorohydrin resin demand 0.2～0.5%; 3. the alkyl ketene dimer consumption 0.1～0.3%; 4. the polymine consumption 0.05～0.12%; 5. the cationic polyacrylamide consumption 0.02～0.05%; 6. the anionic polyacrylamide consumption 0.02～0.05%; 7. filler precipitated calcium carbonate consumption 12～20%.
7. the high bulk coated printing paper that the described method of any one is made among the claim 4-6 is characterized in that quantitative 70～150g/m
2Bulk 1.3～1.5cm
3/ g; Smoothness (just/reverse side) 〉=500s, the smoothness two sides is poor＜and 10%; The print surface roughness (just/reverse side)≤2.0 μ m; Glossiness (just/reverse side) 〉=40%, print gloss (just/reverse side) 〉=60%; Ink absorption≤28%; Picking speed 〉=1.5m/s; Lateral extensometer shrinkage≤2.5%; Whiteness 78～82%; Opacity 〉=90%; Horizontal folding strength 〉=8 times; Vertical fracture length 〉=the 4km of roll web; Surface absorption weight≤35g/m
2Moisture 5.0～7.0%.
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