CN107337976A - Anti-aging exterior coating of a kind of anticracking and preparation method thereof - Google Patents
Anti-aging exterior coating of a kind of anticracking and preparation method thereof Download PDFInfo
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- CN107337976A CN107337976A CN201710744443.5A CN201710744443A CN107337976A CN 107337976 A CN107337976 A CN 107337976A CN 201710744443 A CN201710744443 A CN 201710744443A CN 107337976 A CN107337976 A CN 107337976A
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- exterior coating
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/004—Reflecting paints; Signal paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Plant Pathology (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention relates to construction material, anti-aging exterior coating of specifically a kind of anticracking and preparation method thereof, described exterior coating includes the material of following parts by weight：20~35 parts of organosilicon-modified acrylic emulsion, 3~15 parts of silica aerogel particles, 2~8 parts of titanium dioxide, 2~8 parts of white cement, 3~7 parts of calcium carbonate, 1~5 part of quartz sand, 0.1~2 part of defoamer, 0.1~0.8 part of dispersant, 0.01~0.5 part of hydroxylated cellulose, 0.1~1 part of antifreezing agent, 40~50 parts of deionized water；Wherein, the weight ratio of anatase crystal and rutile-type crystal is 1 in titanium dioxide：1；Contain silica aerogel particles in exterior coating, form loose structure in the coating, improve the flexibility of materials for wall, avoid the internal stress in wall coating uneven or caused by external force cracked；Contain titanium dioxide in coating, certain reflection can not only be carried out to ambient, there is extremely strong suppression and killing simultaneously for the microorganism for being attached to exterior wall surface, improve the service life of outer wall coating.
Description
Technical field
The present invention relates to building material technical field, the anti-aging exterior coating of specifically a kind of anticracking and its preparation
Method.
Background technology
Exterior coating is usually used in brushing on building outside wall, plays role in decoration.Because outer wall coating is directly exposed to
In natural environment, be subjected to exposing to the weather for a long time the invasion and attack to drench with rain, therefore its requirement is often higher, typically requires that exterior coating has
Water-fast, guarantor's color, anti-pollution, ageing-resistant and good adhesive force, for some colder regional construction walls, outer wall coating is also
Need with the characteristics of freezing and thawing performance is good, film-forming temperature is low.
With the development of technology, the coating for wall body outside building gradually develops to the following aspects：(1) to water
Propertyization develops, and coating variety develops towards the direction such as VOC is reduced, and water paint is wherein one of developing direction.Chinese tradition
Solvent based coating proportion is gradually reduced, the development speed of water paint also quickly, but polyvinyl alcohol low grade kind still account for it is larger
Proportion.It is to consolidate and develop the important step of water paint to improve the quality of water paint, develop new kind；(2) to high property
Can, high-grade development, as a kind of ideal performance of coating, not only to protect and beautify base material, and give base material in itself without
The specific function that method has, using some new base-materials can just make coating obtain very surprising high performance, high value-added,
Advanced effect, such as the fluorine resin coating of high-weatherability, the effect good for acquirement in terms of building；(3) sent out to functionalization
Exhibition, in the prior art, gradually proposes fire prevention, insect prevention, gas defence, desinsection, the functional paint of heat-insulation and heat-preservation.
And present inventor thinks, as the decorative layer of external walls, the most basic requirement of outer wall coating is true
Protect it and keep crackless effect for a long time under various adverse circumstances, adhere to its setting out substantially as decorative cover beautification matrix
Point, from cost is reduced, improve efficiency of construction etc. and further exterior coating of the prior art is improved.
The content of the invention
An object of the present invention is to provide a kind of anticracking anti-aging exterior coating, reduces the cost of exterior coating,
Improve efficiency of construction.
To achieve these goals, the present invention is achieved using following technical scheme：A kind of anti-aging exterior wall of anticracking
Coating, include the material of following parts by weight：20~35 parts of organosilicon-modified acrylic emulsion, silica aerogel particles 3~
15 parts, it is 2~8 parts of titanium dioxide, 2~8 parts of white cement, 3~7 parts of calcium carbonate, 1~5 part of quartz sand, 0.1~2 part of defoamer, scattered
0.1~0.8 part of agent, 0.01~0.5 part of hydroxylated cellulose, 0.1~1 part of antifreezing agent, 40~50 parts of deionized water；
Wherein, the weight ratio of anatase crystal and rutile-type crystal is 1 in titanium dioxide：1.
Technical key point is：Silica aerogel particles form mushy structure in outer wall coating,
The flexibility of wall coating is improved, will not be caused for micro external force or internal stress cracked；
Meanwhile the loose structure that coating ingredients of the invention are formed reduces cost compared to coating of the prior art；
Still further aspect, the rutile type titanium white particle in coating ingredients are carried out to inciding the light in outer wall coating
Effective reflection, avoids the phenomenon that aging of the light for outer wall coating causes peeling, crackle occur；
And the photocatalytic Degradation of anatase thpe white powder under light illumination, there is extremely strong suppression to the microorganism in environment
With the effect of killing, the bacterium for being attached to exterior wall has the function that to slaughter, and prevents spot to be adhered to surface of wall, bacterium
Lasting grows in surface of wall and damages wall coating.Also contain white cement and quartz in coating composition in the present invention
Sand, the adhesive force with exterior wall surface can be improved, avoid the occurrence of the phenomenon to come off.
According to the present invention, hydroxylated cellulose as a kind of surfactant of nonionic, have thickening, suspend, bonding,
Floatingization, film forming, scattered, water conservation and the effect that protective coating colloid is provided.
According to the present invention, heretofore described exterior coating includes the material of following parts by weight：Organic-silicon-modified propylene
25~30 parts of yogurt liquid, 5~10 parts of silica aerogel particles, 5~8 parts of titanium dioxide, 3~7 parts of white cement, calcium carbonate 4~5
Part, 2~5 parts of quartz sand, 1~1.5 part of defoamer, 0.2~0.5 part of dispersant, 0.1~0.5 part of hydroxylated cellulose, antifreezing agent
0.2~0.8 part, 45~50 parts of deionized water.
Further, heretofore described exterior coating includes the material of following parts by weight：Organosilicon-modified acrylic
28 parts of emulsion, 8 parts of silica aerogel particles, 6 parts of titanium dioxide, 5 parts of white cement, 5 parts of calcium carbonate, 4 parts of quartz sand, defoamer
1.2 parts, 0.4 part of dispersant, 0.3 part of hydroxylated cellulose, 0.5 part of antifreezing agent, 48 parts of deionized water.
According to the present invention, the effect of heretofore described defoamer is to eliminate bubble during preparing coating stirring
Foam, what described defoamer was well known to those skilled in the art, such as CF-246 defoamers.
According to the present invention, heretofore described dispersant is polyvinylpyrrolidone.
According to the present invention, heretofore described antifreezing agent is propane diols.
According to the present invention, the average grain diameter of heretofore described titanium dioxide is 10~80nm.
According to the present invention, the specific surface areas of silica aerogel particles by its internal pore size and hole number
Determine, the specific surface area of heretofore described silica aerogel particles is 200~2000m2/g；Further, it is described
Silica aerogel particles average grain diameter be 5~25 μm.
It is another object of the present invention to provide a kind of preparation method of the anti-aging exterior coating of anticracking, including it is following
Step：
(1) titanium dioxide, white cement, calcium carbonate, quartz sand is accurately weighed by recipe requirements to mix with high-speed mixer
It is even, it is then transferred in stirring container；
(2) organosilicon-modified acrylic emulsion, aerosil are sequentially added into the stirring container of step (1)
Grain, defoamer, dispersant, hydroxylated cellulose, antifreezing agent, deionized water, stir, and are disperseed with ultrasonic assistant, described
The frequency of ultrasonic wave is 100~20000Hz, and the time of ultrasonic disperse is 10~30min, obtains mixture；
(3) mixture in step (2) is transferred on three-roller further 30~60min of grinding, produced described outer
Wall coating.
The present invention has following technique effect：
1st, contain silica aerogel particles in exterior coating provided by the invention, form loose structure in the coating,
The flexibility of materials for wall is improved, avoids the internal stress in wall coating uneven or is caused by external force cracked；
2nd, contain titanium dioxide in exterior coating provided by the invention, certain reflection can not only be carried out to ambient, together
When there is extremely strong suppression and killing for being attached to the microorganism on exterior wall surface, preventing the growth of bacterium causes it
External wall infringement；
3rd, also contain white cement and quartz sand in coating composition of the invention, the attachment with exterior wall surface can be improved
Power, avoid the occurrence of the phenomenon to come off.
Exterior coating provided by the invention, each component synergy, it is ensured that the excellent anti crack performance of outer wall coating, simultaneously
With excellent adhesive force, the phenomenon that peeling comes off will not be produced, improves the service life of outer wall coating.
Embodiment
In order that the technical means, the inventive features, the objects and the advantages of the present invention are easy to understand, tie below
Specific embodiment is closed, the present invention is furture elucidated.
Embodiment 1
Exterior coating component formula：
Organosilicon-modified acrylic emulsion 28kg
Silica aerogel particles (specific surface area 10000m215 μm of/g, average grain diameter) 8kg
Anatase thpe white powder (average grain diameter 50nm) 3kg
Rutile type titanium white (average grain diameter 50nm) 3kg
White cement 5kg
Calcium carbonate 5kg
Quartz sand 4kg
CF-246 defoamers 1.2kg
Polyvinylpyrrolidone 0.4kg
Hydroxylated cellulose 0.3kg
Propane diols 0.5kg
Deionized water 48kg
(1) titanium dioxide, white cement, calcium carbonate, quartz sand is accurately weighed by recipe requirements to mix with high-speed mixer
It is even, it is then transferred in stirring container；
(2) organosilicon-modified acrylic emulsion, aerosil are sequentially added into the stirring container of step (1)
Grain, CF-246 defoamers, polyvinylpyrrolidone, hydroxylated cellulose, propane diols, deionized water, stir, auxiliary with ultrasonic wave
The frequency for helping scattered, described ultrasonic wave is 8000Hz, and the time of ultrasonic disperse is 20min, obtains mixture；
(3) mixture in step (2) is transferred on three-roller further grinding 50min, produces described exterior wall and apply
Material.
Embodiment 2
Exterior coating component formula：
Organosilicon-modified acrylic emulsion 25kg
Silica aerogel particles (specific surface area 200m210 μm of/g, average grain diameter) 5kg
Anatase thpe white powder (average grain diameter 10nm) 2.5kg
Rutile type titanium white (average grain diameter 10nm) 2.5kg
White cement 3kg
Calcium carbonate 4kg
Quartz sand 2kg
CF-246 defoamers 1kg
Polyvinylpyrrolidone 0.2kg
Hydroxylated cellulose 0.1kg
Propane diols 0.2kg
Deionized water 45kg
(1) titanium dioxide, white cement, calcium carbonate, quartz sand is accurately weighed by recipe requirements to mix with high-speed mixer
It is even, it is then transferred in stirring container；
(2) organosilicon-modified acrylic emulsion, aerosil are sequentially added into the stirring container of step (1)
Grain, CF-246 defoamers, polyvinylpyrrolidone, hydroxylated cellulose, propane diols, deionized water, stir, auxiliary with ultrasonic wave
The frequency for helping scattered, described ultrasonic wave is 100Hz, and the time of ultrasonic disperse is 30min, obtains mixture；
(3) mixture in step (2) is transferred on three-roller further grinding 60min, produces described exterior wall and apply
Material.
Embodiment 3
Exterior coating component formula：
Organosilicon-modified acrylic emulsion 30kg
Silica aerogel particles (specific surface area 20000m220 μm of/g, average grain diameter) 10kg
Anatase thpe white powder (average grain diameter 80nm) 4kg
Rutile type titanium white (average grain diameter 80nm) 4kg
White cement 7kg
Calcium carbonate 5kg
Quartz sand 5kg
CF-246 defoamers 1.5kg
Polyvinylpyrrolidone 0.5kg
Hydroxylated cellulose 0.5kg
Propane diols 0.8kg
Deionized water 50kg
(1) titanium dioxide, white cement, calcium carbonate, quartz sand is accurately weighed by recipe requirements to mix with high-speed mixer
It is even, it is then transferred in stirring container；
(2) organosilicon-modified acrylic emulsion, aerosil are sequentially added into the stirring container of step (1)
Grain, CF-246 defoamers, polyvinylpyrrolidone, hydroxylated cellulose, propane diols, deionized water, stir, auxiliary with ultrasonic wave
The frequency for helping scattered, described ultrasonic wave is 20000Hz, and the time of ultrasonic disperse is 10min, obtains mixture；
(3) mixture in step (2) is transferred on three-roller further grinding 30min, produces described exterior wall and apply
Material.
Embodiment 4
Exterior coating component formula：
Organosilicon-modified acrylic emulsion 20kg
Silica aerogel particles (specific surface area 5000m25 μm of/g, average grain diameter) 3kg
Anatase thpe white powder (average grain diameter 10nm) 1kg
Rutile type titanium white (average grain diameter 10nm) 1kg
White cement 2kg
Calcium carbonate 3kg
Quartz sand 1kg
CF-246 defoamers 0.1kg
Polyvinylpyrrolidone 0.1kg
Hydroxylated cellulose 0.01kg
Propane diols 0.1kg
Deionized water 40kg
(1) titanium dioxide, white cement, calcium carbonate, quartz sand is accurately weighed by recipe requirements to mix with high-speed mixer
It is even, it is then transferred in stirring container；
(2) organosilicon-modified acrylic emulsion, aerosil are sequentially added into the stirring container of step (1)
Grain, CF-246 defoamers, polyvinylpyrrolidone, hydroxylated cellulose, propane diols, deionized water, stir, auxiliary with ultrasonic wave
The frequency for helping scattered, described ultrasonic wave is 100Hz, and the time of ultrasonic disperse is 30min, obtains mixture；
(3) mixture in step (2) is transferred on three-roller further grinding 60min, produces described exterior wall and apply
Material.
Embodiment 5
Exterior coating component formula：
Organosilicon-modified acrylic emulsion 35kg
Silica aerogel particles (specific surface area 10000m225 μm of/g, average grain diameter) 15kg
Anatase thpe white powder (average grain diameter 80nm) 4kg
Rutile type titanium white (average grain diameter 80nm) 4kg
White cement 8kg
Calcium carbonate 7kg
Quartz sand 5kg
CF-246 defoamers 2kg
Polyvinylpyrrolidone 0.8kg
Hydroxylated cellulose 0.5kg
Propane diols 1kg
Deionized water 50kg
(1) titanium dioxide, white cement, calcium carbonate, quartz sand is accurately weighed by recipe requirements to mix with high-speed mixer
It is even, it is then transferred in stirring container；
(2) organosilicon-modified acrylic emulsion, aerosil are sequentially added into the stirring container of step (1)
Grain, CF-246 defoamers, polyvinylpyrrolidone, hydroxylated cellulose, propane diols, deionized water, stir, auxiliary with ultrasonic wave
The frequency for helping scattered, described ultrasonic wave is 20000Hz, and the time of ultrasonic disperse is 10min, obtains mixture；
(3) mixture in step (2) is transferred on three-roller further grinding 30min, produces described exterior wall and apply
Material.
Performance test：
1st, artificial weathering ageing resistance 400h is tested
The exterior coating of each embodiment is painted on wall respectively, brushing quality 20g, normal temperature maintenance 168h, is transferred to people
The ageing-resistant machine of work places 400h, by anti-stick patch property (180 ° of peel strengths) method of testing test after taking-up, and test result is remembered
Record in table 1.
2nd, adhesive force is tested
The exterior coating of each embodiment is painted on wall respectively, brushing quality 20g, normal temperature maintenance 168h, uses 2mm
Draw lattice device and lattice are drawn on metope, application adhesive tape is viscous to be pulled, and whether observation coating, which has, comes off, and without coming off as 0 grade, the area that comes off is small
2 grades are designated as in drawing lattice area 10%, and test result recorded in table 1.
The performance test of the exterior coating of the embodiment 1~5 of table 1
The exterior coating being prepared by above-described embodiment, adhesive force is strong, has excellent anticracking ageing resistace.
General principle, principal character and the features of the present invention of the present invention has been shown and described above.The technology of the industry
Personnel are it should be appreciated that the present invention is not limited to the above embodiments, and the simply explanation described in above-described embodiment and specification is originally
The principle of invention, without departing from the spirit and scope of the present invention, various changes and modifications of the present invention are possible, these changes
Change and improvement is both fallen within the range of claimed invention.The scope of protection of present invention is by appended claims
And its equivalent thereof.
Claims (7)
- A kind of 1. anti-aging exterior coating of anticracking, it is characterised in that：Include the material of following parts by weight：Organic-silicon-modified propylene 20~35 parts of yogurt liquid, 3~15 parts of silica aerogel particles, 2~8 parts of titanium dioxide, 2~8 parts of white cement, calcium carbonate 3~7 Part, 1~5 part of quartz sand, 0.1~2 part of defoamer, 0.1~0.8 part of dispersant, 0.01~0.5 part of hydroxylated cellulose, antifreezing agent 0.1~1 part, 40~50 parts of deionized water；Wherein, the weight ratio of anatase crystal and rutile-type crystal is 1 in titanium dioxide：1.
- 2. the anti-aging exterior coating of anticracking according to claim 1, it is characterised in that：Described exterior coating include with The material of lower parts by weight：25~30 parts of organosilicon-modified acrylic emulsion, 5~10 parts of silica aerogel particles, titanium dioxide 5 ~8 parts, 3~7 parts of white cement, 4~5 parts of calcium carbonate, 2~5 parts of quartz sand, 1~1.5 part of defoamer, 0.2~0.5 part of dispersant, 0.1~0.5 part of hydroxylated cellulose, 0.2~0.8 part of antifreezing agent, 45~50 parts of deionized water.
- 3. the anti-aging exterior coating of anticracking according to claim 1, it is characterised in that：Described exterior coating include with The material of lower parts by weight：28 parts of organosilicon-modified acrylic emulsion, 8 parts of silica aerogel particles, 6 parts of titanium dioxide, plain boiled water 5 parts of mud, 5 parts of calcium carbonate, 4 parts of quartz sand, 1.2 parts of defoamer, 0.4 part of dispersant, 0.3 part of hydroxylated cellulose, antifreezing agent 0.5 Part, 48 parts of deionized water.
- 4. the anti-aging exterior coating of anticracking according to claim 1, it is characterised in that：The average grain of described titanium dioxide Footpath is 10~80nm.
- 5. the anti-aging exterior coating of anticracking according to claim 1, it is characterised in that：Described aerosil The specific surface area of particle is 200~2000m2/g；And/orThe average grain diameter of described silica aerogel particles is 5~25 μm.
- A kind of 6. preparation method of the anti-aging exterior coating of anticracking as described in Claims 1 to 5, it is characterised in that：Including Following steps：(1) accurately weigh titanium dioxide, white cement, calcium carbonate, quartz sand by recipe requirements to be well mixed with high-speed mixer, so After be transferred in stirring container；(2) sequentially added into the stirring container of step (1) organosilicon-modified acrylic emulsion, silica aerogel particles, Defoamer, dispersant, hydroxylated cellulose, antifreezing agent, deionized water, stir, and obtain mixture；(3) mixture in step (2) is transferred on three-roller further 30~60min of grinding, produces described exterior wall and apply Material.
- 7. the preparation method of the anti-aging exterior coating of anticracking according to claim 6, it is characterised in that：In step (2) In be aided with ultrasonic wave and disperse, the frequency of described ultrasonic wave is 100~20000Hz, and the time of ultrasonic disperse is 10~30min.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710744443.5A CN107337976A (en) | 2017-08-25 | 2017-08-25 | Anti-aging exterior coating of a kind of anticracking and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710744443.5A CN107337976A (en) | 2017-08-25 | 2017-08-25 | Anti-aging exterior coating of a kind of anticracking and preparation method thereof |
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| CN107337976A true CN107337976A (en) | 2017-11-10 |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108285315A (en) * | 2018-02-09 | 2018-07-17 | 戴方均 | A kind of Multifunction wall clothing and the preparation method and application thereof |
| CN109880416A (en) * | 2019-01-09 | 2019-06-14 | 苏德祥 | A kind of mould-proof-type hydroscopic fast-drying type concrete outer layer coating |
| CN111500136A (en) * | 2020-05-15 | 2020-08-07 | 成都新柯力化工科技有限公司 | Anti-aging polymer-based waterproof coating for outer wall |
| CN113604120A (en) * | 2021-07-24 | 2021-11-05 | 詹娜芝 | Anti-cracking coating and preparation method thereof |
| WO2023153252A1 (en) * | 2022-02-14 | 2023-08-17 | デクセリアルズ株式会社 | Coating liquid, method for producing coating liquid, and coating film |
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| CN106396572A (en) * | 2016-08-30 | 2017-02-15 | 福州金博建材有限公司 | Coating product for exterior wall decoration |
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| CN106396572A (en) * | 2016-08-30 | 2017-02-15 | 福州金博建材有限公司 | Coating product for exterior wall decoration |
| CN106946532A (en) * | 2017-04-24 | 2017-07-14 | 山东汉诺宝嘉节能科技股份有限公司 | A kind of polychromy heat insulation and waterproof mortar |
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| 丁浩: "《矿物 TiO2微纳米颗粒复合与功能化》", 31 May 2016 * |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108285315A (en) * | 2018-02-09 | 2018-07-17 | 戴方均 | A kind of Multifunction wall clothing and the preparation method and application thereof |
| CN109880416A (en) * | 2019-01-09 | 2019-06-14 | 苏德祥 | A kind of mould-proof-type hydroscopic fast-drying type concrete outer layer coating |
| CN111500136A (en) * | 2020-05-15 | 2020-08-07 | 成都新柯力化工科技有限公司 | Anti-aging polymer-based waterproof coating for outer wall |
| CN113604120A (en) * | 2021-07-24 | 2021-11-05 | 詹娜芝 | Anti-cracking coating and preparation method thereof |
| WO2023153252A1 (en) * | 2022-02-14 | 2023-08-17 | デクセリアルズ株式会社 | Coating liquid, method for producing coating liquid, and coating film |
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Application publication date: 20171110 |
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