CN107337921A - A kind of textile material added with crushed crude pearlite and preparation method thereof - Google Patents

A kind of textile material added with crushed crude pearlite and preparation method thereof Download PDF

Info

Publication number
CN107337921A
CN107337921A CN201710549704.8A CN201710549704A CN107337921A CN 107337921 A CN107337921 A CN 107337921A CN 201710549704 A CN201710549704 A CN 201710549704A CN 107337921 A CN107337921 A CN 107337921A
Authority
CN
China
Prior art keywords
parts
textile material
crushed crude
crude pearlite
ball
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710549704.8A
Other languages
Chinese (zh)
Inventor
陈洁琼
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Suzhou Chencai Textile Research Development Co Ltd
Original Assignee
Suzhou Chencai Textile Research Development Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Suzhou Chencai Textile Research Development Co Ltd filed Critical Suzhou Chencai Textile Research Development Co Ltd
Priority to CN201710549704.8A priority Critical patent/CN107337921A/en
Priority to PCT/CN2017/109640 priority patent/WO2019006942A1/en
Publication of CN107337921A publication Critical patent/CN107337921A/en
Pending legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/32—Phosphorus-containing compounds
    • C08K2003/321—Phosphates
    • C08K2003/322—Ammonium phosphate
    • C08K2003/323—Ammonium polyphosphate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/16—Fibres; Fibrils

Abstract

The invention discloses a kind of textile material added with crushed crude pearlite and preparation method thereof, it is with tetraethyl orthosilicate, nylon fiber, bamboo-carbon fibre, polyester fiber is main component, by adding ammonium polyphosphate, ascorbyl palmitate, vinyl carbonate, soya bean fatty acid ethoxylate, diglycidyl ether, double methyl methacrylate triethylene glycol ester, hydroxypropyl methyl cellulose, crushed crude pearlite, silica, silane coupler, adhesive, deionized water, it is aided with magnetic agitation, heat up water-bath, ball-milling treatment, it is high-pressure homogeneous, the techniques such as Screw Extrusion, so that the textile material being prepared is not easy to stain, easy decontamination, and grease proofing work well, it disclosure satisfy that the requirement of industry, with preferable application prospect.

Description

A kind of textile material added with crushed crude pearlite and preparation method thereof
Technical field
The present invention relates to textile material technical field, more particularly to added with the textile material of crushed crude pearlite and its preparation side Method.
Background technology
Textile material refers to fiber and fibre, is embodied in fiber, yarn, fabric and its compound.Modern times are spun In knitting, the exploitation and use of the research and development of new textile material, particularly nanofiber, it is general to breach traditional textile material Read.Textile material turns into the important component of soft material, is weaving material using " shape " and its complex form as study subject One of essential characteristic of material.
Traditional textile material is primarily referred to as fiber, and fiber is the elementary cell of textile material.The source of fiber, composition, Preparation, form, performance are extremely abundant and complicated.In simple terms, fiber is divided into natural fiber and the major class of chemical fibre two.According to fibre Natural fiber is divided into plant fiber, animal fiber and mineral fiber by the material source attribute of dimension.By raw material, processing side The difference of method and constituent, regenerated fiber, synthetic fibers and the class of inorfil three can be divided into again.Chemical fibre is because its is excellent at present Different performance occupies the leading of market.But every kind of chemical fibre, while possessing advantage, there is also many deficiencies.
The characteristics of several main chemical fibres are listed below：
Acrylic fibers：Acrylic fiber has the title of artificial wool.With soft, bulk, easy dye, bright in colour, fast light, antibacterial, worm is not afraid of it The advantages that moth.But its shortcoming is easy balling-up, electrostatic is easily played, easily adsorbs dust, wrinkle resistance is poor, and elastic force difference.
Spandex, it is the abbreviation of polyurethane fibre, is a kind of elastomer.Spandex can be used for meet that comfortableness will The clothes for asking needs to stretch, elasticity preferably, there is preferable fast light, acidproof, alkaline-resisting, wearability.It is soft and do not rise Wrinkle, can remain original profile.But its intensity difference, moisture absorption are poor.
Polyamide fibre, also known as " polyamides fiber ", there are titles such as " nylon " in foreign countries.No matter fiber is in dry state or hygrometric state, all unsuitable Break, strength is big, soft without silk.Great advantage is solid wear-resisting, is optimal one kind.Density is small, and fabric is light, elasticity Good, endurance is destroyed, and chemical stability is also fine, alkaline-resisting not acidproof.Disadvantage is that sunlight resistance is bad, and fabric shines long will Turn yellow, intensity declines, and moisture absorption is also bad, but better than acrylic fibers, terylene.Poor heat resistance, sun-resistant property is poor, there is electrostatic.Terylene, it is called Polyester fiber, knitted polyester fabric are divided into Grade A, goods of inferior quality, third grade product and off standard by its quality good or not.Advantage is bullet Property it is good and smooth；Wrinkle resistance and good heat preservation performance；Intensity is high, quick-drying washable；It is heat-resist；Light resistance is stable；Wearability is strong；Chemistry Stable performance；Shortcoming is that water imbibition is poor；It is also easy to produce electrostatic.
Polypropylene fibre, it is with the China that the accessory substance propylene of petroleum refining is synthetic fibers isotactic polypropylene fibre made from raw material Trade name.Also known as polypropylene fibre.The hygroscopicity very little of polypropylene fibre, almost non-hygroscopic, the regain under the conditions of general atmosphere approaches In zero.But it has core sucting action, vapor can be transmitted by the capillary in fabric, but itself does not play any absorption.Lack Point is that polypropylene fibre light resistance is poor, and heat endurance is also poor, easy to aging, intolerant to flatiron.
Viscose rayon, it is made of the various strings such as timber, cotton linter and bamboo, reed, bagasse, straw.12 In kind main textile fabric, the moisture percentage of viscose rayon best suits the physiological requirement of human body skin, have it is smooth it is nice and cool, ventilative, Antistatic, the dyeing characteristic such as gorgeous.But it is yielding simultaneously there is also lacking flexibility, the defects of crumpling and produce sagging.
Therefore, from the perspective of material science development, simple chemical fibre or natural fiber can not meet the modern times The social growing requirement for preventing material property, how on the basis of existing fibrous material, by adding other Organic or electrodeless class chemical composition, and coordinate corresponding production technology, prepare a kind of Compound spinning better than general fibre material Knit material and just seem particularly necessary.
The content of the invention
In order to solve the above technical problems, the invention provides the textile material added with crushed crude pearlite, by using specific Raw material be combined, coordinate specific production technology so that the textile material being prepared is not easy to stain, easy decontamination, and anti- Oil works well, and disclosure satisfy that the requirement of industry, has preferable application prospect.
The purpose of the present invention can be achieved through the following technical solutions：
Textile material added with crushed crude pearlite, is made from the following raw materials in parts by weight：Tetraethyl orthosilicate 40-50 parts, nylon are fine Tie up 35-45 parts, bamboo-carbon fibre 32-38 parts, polyester fiber 30-36 parts, ammonium polyphosphate 15-25 parts, ascorbyl palmitate 12-14 parts, vinyl carbonate 10-15 parts, soya bean fatty acid ethoxylate 8-12 parts, diglycidyl ether 6-8 parts, double methyl Acrylic acid Triethylene Glycol 4-6 parts, hydroxypropyl methyl cellulose 4-6 parts, crushed crude pearlite 3-5 parts, silica 3-5 parts, Silane coupler 2-4 parts, adhesive 2-4 parts, 160 parts of deionized water.
Preferably, the silane coupler is selected from silane coupler KH-590, silane resin acceptor kh-550, silane coupler Any one in KH-560.
Preferably, any one of described adhesive in sulfenamide, epoxy resin, polyvinyl alcohol.
The preparation method of the described textile material added with crushed crude pearlite, comprises the following steps：
（1）Each raw material is weighed according to parts by weight；
（2）By ammonium polyphosphate, double methyl methacrylate triethylene glycol ester, ascorbyl palmitate, vinyl carbonate, big Beans fatty acid ethoxylate, diglycidyl ether and deionized water mixing, are placed on magnetic stirrer with rotating speed 650-750 R/min stirs 35-45 min, then raises temperature to 80-90 DEG C, water-bath 15-25 min, obtains initial mixture；
（3）Nylon fiber, bamboo-carbon fibre, polyester fiber, hydroxypropyl methyl cellulose, crushed crude pearlite, silica are put jointly Ball-milling treatment is carried out in ball mill, the rotating speed of ball mill is 220-280 r/min, and Ball-milling Time is 1-2 h, is made in mixture Each component is uniformly dispersed, and obtains ball-milled mixtures；
（4）By step（2）Initial mixture and step（3）Ball-milled mixtures add high pressure homogenizer jointly, add just Silester, silane coupler, adhesive, it is well mixed, is then melted at 350-360 DEG C, obtain intermediate product；
（5）By step（4）The intermediate product of gained adds in double screw extruder and carries out extrusion molding, then in an oven in Dried under the conditions of 40-50 DEG C, pelletizing, obtain finished product textile material.
Preferably, the step（4）The pressure of mesohigh homogenizer is 16-18Mpa.
Preferably, the step（5）In, the screw speed of double screw extruder is 250-280 r/min, twin-screw extrusion The temperature of each section of machine is：One 170-190 DEG C of area's temperature, two 200-210 DEG C of area's temperature, three 235-250 DEG C of area's temperature, four area's temperature 175-185 DEG C of degree.
Compared with prior art, its advantage is the present invention：
（1）The textile material added with crushed crude pearlite of the present invention is fine with tetraethyl orthosilicate, nylon fiber, bamboo-carbon fibre, terylene Tie up as main component, by add ammonium polyphosphate, double methyl methacrylate triethylene glycol ester, ascorbyl palmitate, Vinyl carbonate, soya bean fatty acid ethoxylate, diglycidyl ether, hydroxypropyl methyl cellulose, crushed crude pearlite, titanium dioxide Silicon, silane coupler, adhesive, deionized water, it is aided with magnetic agitation, heating water-bath, ball-milling treatment, high-pressure homogeneous, screw rod squeeze The technique such as go out so that the textile material being prepared is not easy to stain, easy decontamination, and it is grease proofing work well, disclosure satisfy that industry It is required that there is preferable application prospect.
（2）Textile material raw material added with crushed crude pearlite of the invention is cheap, technique is simple, suitable for heavy industrialization With practical.
Embodiment
The technical scheme of invention is described in detail with reference to specific embodiment.
Embodiment 1
（1）40 parts of tetraethyl orthosilicate, 35 parts of nylon fiber, 32 parts of bamboo-carbon fibre, 30 parts of polyester fiber, more is weighed according to parts by weight 15 parts of APP, 12 parts of ascorbyl palmitate, 10 parts of vinyl carbonate, 8 parts of soya bean fatty acid ethoxylate, two contractings 6 parts of water glycerin ether, 4 parts of double methyl methacrylate triethylene glycol ester, 4 parts of hydroxypropyl methyl cellulose, 3 parts of crushed crude pearlite, two 3 parts of silica, 2 parts of silane coupler KH-590,2 parts of sulfenamide, 160 parts of deionized water；
（2）By ammonium polyphosphate, double methyl methacrylate triethylene glycol ester, ascorbyl palmitate, vinyl carbonate, big Beans fatty acid ethoxylate, diglycidyl ether and deionized water mixing, are placed on magnetic stirrer with the r/min of rotating speed 650 35 min are stirred, 80 DEG C is then raised temperature to, the min of water-bath 15, obtains initial mixture；
（3）Nylon fiber, bamboo-carbon fibre, polyester fiber, hydroxypropyl methyl cellulose, crushed crude pearlite, silica are put jointly Ball-milling treatment is carried out in ball mill, the rotating speed of ball mill is 220 r/min, and Ball-milling Time is 1 h, makes each component in mixture It is uniformly dispersed, obtains ball-milled mixtures；
（4）By step（2）Initial mixture and step（3）Ball-milled mixtures add high pressure homogenizer jointly, add just Silester, silane coupler KH-590, sulfenamide, it is well mixed, is then melted at 350 DEG C, obtain intermediate product, wherein The pressure of high pressure homogenizer is 16Mpa,；
（5）By step（4）The intermediate product of gained adds in double screw extruder and carries out extrusion molding, wherein double screw extruder Screw speed be 250 r/min, the temperature of each section of double screw extruder is：One 170 DEG C of area's temperature, two 200 DEG C of area's temperature, Three 235 DEG C of area's temperature, four 175 DEG C of area's temperature, then dried in an oven under the conditions of 40 DEG C, pelletizing, obtain finished product weaving material Material.
The performance test results of the obtained textile material added with crushed crude pearlite are as shown in table 1.
Embodiment 2
（1）45 parts of tetraethyl orthosilicate, 40 parts of nylon fiber, 35 parts of bamboo-carbon fibre, 33 parts of polyester fiber, more is weighed according to parts by weight 20 parts of APP, 13 parts of ascorbyl palmitate, 12 parts of vinyl carbonate, 10 parts of soya bean fatty acid ethoxylate, two 7 parts of glycidol ether, 5 parts of double methyl methacrylate triethylene glycol ester, 5 parts of hydroxypropyl methyl cellulose, 4 parts of crushed crude pearlite, 4 parts of silica, 3 parts of silane resin acceptor kh-550,3 parts of epoxy resin, 160 parts of deionized water；
（2）By ammonium polyphosphate, double methyl methacrylate triethylene glycol ester, ascorbyl palmitate, vinyl carbonate, big Beans fatty acid ethoxylate, diglycidyl ether and deionized water mixing, are placed on magnetic stirrer with the r/min of rotating speed 700 40 min are stirred, 85 DEG C is then raised temperature to, the min of water-bath 20, obtains initial mixture；
（3）Nylon fiber, bamboo-carbon fibre, polyester fiber, hydroxypropyl methyl cellulose, crushed crude pearlite, silica are put jointly Ball-milling treatment is carried out in ball mill, the rotating speed of ball mill is 250 r/min, and Ball-milling Time is 1.5 h, makes each group in mixture It is uniformly dispersed, obtains ball-milled mixtures；
（4）By step（2）Initial mixture and step（3）Ball-milled mixtures add high pressure homogenizer jointly, add just Silester, silane resin acceptor kh-550, epoxy resin, it is well mixed, is then melted at 355 DEG C, obtain intermediate product, wherein The pressure of high pressure homogenizer is 17Mpa,；
（5）By step（4）The intermediate product of gained adds in double screw extruder and carries out extrusion molding, wherein double screw extruder Screw speed be 265 r/min, the temperature of each section of double screw extruder is：One 180 DEG C of area's temperature, two 205 DEG C of area's temperature, Three 245 DEG C of area's temperature, four 180 DEG C of area's temperature, then dried in an oven under the conditions of 45 DEG C, pelletizing, obtain finished product weaving material Material.
The performance test results of the obtained textile material added with crushed crude pearlite are as shown in table 1.
Embodiment 3
（1）50 parts of tetraethyl orthosilicate, 45 parts of nylon fiber, 38 parts of bamboo-carbon fibre, 36 parts of polyester fiber, more is weighed according to parts by weight 25 parts of APP, 14 parts of ascorbyl palmitate, 15 parts of vinyl carbonate, 12 parts of soya bean fatty acid ethoxylate, two 8 parts of glycidol ether, 6 parts of double methyl methacrylate triethylene glycol ester, 6 parts of hydroxypropyl methyl cellulose, 5 parts of crushed crude pearlite, 5 parts of silica, 4 parts of silane coupler KH-560,4 parts of polyvinyl alcohol, 160 parts of deionized water；
（2）By ammonium polyphosphate, double methyl methacrylate triethylene glycol ester, ascorbyl palmitate, vinyl carbonate, big Beans fatty acid ethoxylate, diglycidyl ether and deionized water mixing, are placed on magnetic stirrer with the r/min of rotating speed 750 45 min are stirred, 90 DEG C is then raised temperature to, the min of water-bath 25, obtains initial mixture；
（3）Nylon fiber, bamboo-carbon fibre, polyester fiber, hydroxypropyl methyl cellulose, crushed crude pearlite, silica are put jointly Ball-milling treatment is carried out in ball mill, the rotating speed of ball mill is 280 r/min, and Ball-milling Time is 2 h, makes each component in mixture It is uniformly dispersed, obtains ball-milled mixtures；
（4）By step（2）Initial mixture and step（3）Ball-milled mixtures add high pressure homogenizer jointly, add just Silester, silane coupler KH-560, polyvinyl alcohol, it is well mixed, is then melted at 360 DEG C, obtain intermediate product, wherein The pressure of high pressure homogenizer is 18Mpa,；
（5）By step（4）The intermediate product of gained adds in double screw extruder and carries out extrusion molding, wherein double screw extruder Screw speed be 280 r/min, the temperature of each section of double screw extruder is：One 190 DEG C of area's temperature, two 210 DEG C of area's temperature, Three 250 DEG C of area's temperature, four 185 DEG C of area's temperature, then dried in an oven under the conditions of 50 DEG C, pelletizing, obtain finished product weaving material Material.
The performance test results of the obtained textile material added with crushed crude pearlite are as shown in table 1.
Embodiment 4
（1）50 parts of tetraethyl orthosilicate, 35 parts of nylon fiber, 38 parts of bamboo-carbon fibre, 30 parts of polyester fiber, more is weighed according to parts by weight 25 parts of APP, 12 parts of ascorbyl palmitate, 15 parts of vinyl carbonate, 8 parts of soya bean fatty acid ethoxylate, two contractings 8 parts of water glycerin ether, 4 parts of double methyl methacrylate triethylene glycol ester, 6 parts of hydroxypropyl methyl cellulose, 3 parts of crushed crude pearlite, two 5 parts of silica, 2 parts of silane coupler KH-590,4 parts of epoxy resin, 160 parts of deionized water；
（2）By ammonium polyphosphate, double methyl methacrylate triethylene glycol ester, ascorbyl palmitate, vinyl carbonate, big Beans fatty acid ethoxylate, diglycidyl ether and deionized water mixing, are placed on magnetic stirrer with the r/min of rotating speed 650 45 min are stirred, 80 DEG C is then raised temperature to, the min of water-bath 25, obtains initial mixture；
（3）Nylon fiber, bamboo-carbon fibre, polyester fiber, hydroxypropyl methyl cellulose, crushed crude pearlite, silica are put jointly Ball-milling treatment is carried out in ball mill, the rotating speed of ball mill is 220 r/min, and Ball-milling Time is 2 h, makes each component in mixture It is uniformly dispersed, obtains ball-milled mixtures；
（4）By step（2）Initial mixture and step（3）Ball-milled mixtures add high pressure homogenizer jointly, add just Silester, silane coupler KH-590, epoxy resin, it is well mixed, is then melted at 350 DEG C, obtain intermediate product, wherein The pressure of high pressure homogenizer is 18Mpa,；
（5）By step（4）The intermediate product of gained adds in double screw extruder and carries out extrusion molding, wherein double screw extruder Screw speed be 250 r/min, the temperature of each section of double screw extruder is：One 190 DEG C of area's temperature, two 200 DEG C of area's temperature, Three 250 DEG C of area's temperature, four 175 DEG C of area's temperature, then dried in an oven under the conditions of 50 DEG C, pelletizing, obtain finished product weaving material Material.
The performance test results of the obtained textile material added with crushed crude pearlite are as shown in table 1.
Comparative example 1
（1）45 parts of tetraethyl orthosilicate, 40 parts of nylon fiber, 35 parts of bamboo-carbon fibre, 33 parts of polyester fiber, more is weighed according to parts by weight 20 parts of APP, 13 parts of ascorbyl palmitate, 12 parts of vinyl carbonate, 10 parts of soya bean fatty acid ethoxylate, two 7 parts of glycidol ether, 5 parts of hydroxypropyl methyl cellulose, 4 parts of crushed crude pearlite, 3 parts of silane resin acceptor kh-550, epoxy resin 3 Part, 160 parts of deionized water；
（2）Ammonium polyphosphate, ascorbyl palmitate, vinyl carbonate, soya bean fatty acid ethoxylate, two are shunk sweet Oily ether and deionized water mixing, are placed on magnetic stirrer and stir 40 min with the r/min of rotating speed 700, then raise temperature to 85 DEG C, The min of water-bath 20, obtains initial mixture；
（3）Nylon fiber, bamboo-carbon fibre, polyester fiber, hydroxypropyl methyl cellulose, crushed crude pearlite are collectively disposed in ball mill Ball-milling treatment is carried out, the rotating speed of ball mill is 250 r/min, and Ball-milling Time is 1.5 h, makes each component in mixture scattered equal It is even, obtain ball-milled mixtures；
（4）By step（2）Initial mixture and step（3）Ball-milled mixtures add high pressure homogenizer jointly, add just Silester, silane resin acceptor kh-550, epoxy resin, it is well mixed, is then melted at 355 DEG C, obtain intermediate product, wherein The pressure of high pressure homogenizer is 17Mpa,；
（5）By step（4）The intermediate product of gained adds in double screw extruder and carries out extrusion molding, wherein double screw extruder Screw speed be 265 r/min, the temperature of each section of double screw extruder is：One 180 DEG C of area's temperature, two 205 DEG C of area's temperature, Three 245 DEG C of area's temperature, four 180 DEG C of area's temperature, then dried in an oven under the conditions of 45 DEG C, pelletizing, obtain finished product weaving material Material.
The performance test results of the obtained textile material added with crushed crude pearlite are as shown in table 1.
Comparative example 2
（1）50 parts of tetraethyl orthosilicate, 35 parts of nylon fiber, 38 parts of bamboo-carbon fibre, 30 parts of polyester fiber, more is weighed according to parts by weight 25 parts of APP, 12 parts of ascorbyl palmitate, 15 parts of vinyl carbonate, 8 parts of soya bean fatty acid ethoxylate, two contractings 8 parts of water glycerin ether, 4 parts of double methyl methacrylate triethylene glycol ester, 6 parts of hydroxypropyl methyl cellulose, 5 parts of silica, silicon 2 parts of alkane coupling agent KH-590,4 parts of epoxy resin, 160 parts of deionized water；
（2）By ammonium polyphosphate, double methyl methacrylate triethylene glycol ester, ascorbyl palmitate, vinyl carbonate, big Beans fatty acid ethoxylate, diglycidyl ether and deionized water mixing, are placed on magnetic stirrer with the r/min of rotating speed 650 45 min are stirred, 80 DEG C is then raised temperature to, the min of water-bath 25, obtains initial mixture；
（3）Nylon fiber, bamboo-carbon fibre, polyester fiber, hydroxypropyl methyl cellulose, silica are collectively disposed in ball mill Ball-milling treatment is carried out, the rotating speed of ball mill is 220 r/min, and Ball-milling Time is 2 h, each component in mixture is uniformly dispersed, Obtain ball-milled mixtures；
（4）By step（2）Initial mixture and step（3）Ball-milled mixtures add high pressure homogenizer jointly, add just Silester, silane coupler KH-590, epoxy resin, it is well mixed, is then melted at 350 DEG C, obtain intermediate product, wherein The pressure of high pressure homogenizer is 18Mpa,；
（5）By step（4）The intermediate product of gained adds in double screw extruder and carries out extrusion molding, wherein double screw extruder Screw speed be 250 r/min, the temperature of each section of double screw extruder is：One 190 DEG C of area's temperature, two 200 DEG C of area's temperature, Three 250 DEG C of area's temperature, four 175 DEG C of area's temperature, then dried in an oven under the conditions of 50 DEG C, pelletizing, obtain finished product weaving material Material.
The performance test results of the obtained textile material added with crushed crude pearlite are as shown in table 1.
By the embodiment 1-4 and comparative example 1-2 textile material added with crushed crude pearlite respectively according to GB/T30159.1- 2013rd, FZ/T01118-2012 and GB19977-2014 method carries out stain resistant, easy decontamination, grease proofing this several performance tests.
Table 1
　 Stain resistance（Level） Easy decontamination（Level） It is grease proofing（Level）
Embodiment 1 5 5 5
Embodiment 2 5 5 6
Embodiment 3 5 5 5
Embodiment 4 5 5 6
Comparative example 1 4 4 4
Comparative example 2 4 5 4
The present invention the textile material added with crushed crude pearlite using tetraethyl orthosilicate, nylon fiber, bamboo-carbon fibre, polyester fiber as Main component, by adding ammonium polyphosphate, double methyl methacrylate triethylene glycol ester, ascorbyl palmitate, ethene Carbonic ester, soya bean fatty acid ethoxylate, diglycidyl ether, hydroxypropyl methyl cellulose, crushed crude pearlite, silica, Silane coupler, adhesive, deionized water, it is aided with magnetic agitation, heating water-bath, ball-milling treatment, high-pressure homogeneous, Screw Extrusion etc. Technique so that the textile material being prepared is not easy to stain, easy decontamination, and the grease proofing requirement for working well, disclosure satisfy that industry, With preferable application prospect.Textile material raw material added with crushed crude pearlite of the invention is cheap, technique is simple, suitable for big rule Mould industrialization is used, practical.
Embodiments of the invention are the foregoing is only, are not intended to limit the scope of the invention, it is every to utilize this hair The equivalent structure or equivalent flow conversion that bright description is made, or directly or indirectly it is used in other related technology necks Domain, it is included within the scope of the present invention.

Claims (6)

  1. A kind of 1. textile material added with crushed crude pearlite, it is characterised in that：It is made from the following raw materials in parts by weight：Positive silicic acid second Ester 40-50 parts, nylon fiber 35-45 parts, bamboo-carbon fibre 32-38 parts, polyester fiber 30-36 parts, ammonium polyphosphate 15-25 parts, Ascorbyl palmitate 12-14 parts, vinyl carbonate 10-15 parts, soya bean fatty acid ethoxylate 8-12 parts, two shrinks are sweet Oily ether 6-8 parts, double methyl methacrylate triethylene glycol ester 4-6 parts, hydroxypropyl methyl cellulose 4-6 parts, crushed crude pearlite 3-5 Part, silica 3-5 parts, silane coupler 2-4 parts, adhesive 2-4 parts, 160 parts of deionized water.
  2. 2. the textile material according to claim 1 added with crushed crude pearlite, it is characterised in that：The silane coupler choosing From any one in silane coupler KH-590, silane resin acceptor kh-550, silane coupler KH-560.
  3. 3. the textile material according to claim 1 added with crushed crude pearlite, it is characterised in that：Described adhesive is selected from Asia Any one in sulfonamide, epoxy resin, polyvinyl alcohol.
  4. 4. according to the preparation method of any described textile material added with crushed crude pearlite of claims 1 to 3, its feature exists In comprising the following steps：
    （1）Each raw material is weighed according to parts by weight；
    （2）By ammonium polyphosphate, double methyl methacrylate triethylene glycol ester, ascorbyl palmitate, vinyl carbonate, big Beans fatty acid ethoxylate, diglycidyl ether and deionized water mixing, are placed on magnetic stirrer with rotating speed 650-750 R/min stirs 35-45 min, then raises temperature to 80-90 DEG C, water-bath 15-25 min, obtains initial mixture；
    （3）Nylon fiber, bamboo-carbon fibre, polyester fiber, hydroxypropyl methyl cellulose, crushed crude pearlite, silica are put jointly Ball-milling treatment is carried out in ball mill, the rotating speed of ball mill is 220-280 r/min, and Ball-milling Time is 1-2 h, is made in mixture Each component is uniformly dispersed, and obtains ball-milled mixtures；
    （4）By step（2）Initial mixture and step（3）Ball-milled mixtures add high pressure homogenizer jointly, add just Silester, silane coupler, adhesive, it is well mixed, is then melted at 350-360 DEG C, obtain intermediate product；
    （5）By step（4）The intermediate product of gained adds in double screw extruder and carries out extrusion molding, then in an oven in Dried under the conditions of 40-50 DEG C, pelletizing, obtain finished product textile material.
  5. 5. the preparation method of the textile material according to claim 4 added with crushed crude pearlite, it is characterised in that the step Suddenly（4）The pressure of mesohigh homogenizer is 16-18Mpa.
  6. 6. the preparation method of the textile material according to claim 4 added with crushed crude pearlite, it is characterised in that the step Suddenly（5）In, the screw speed of double screw extruder is 250-280 r/min, and the temperature of each section of double screw extruder is：One area 170-190 DEG C of temperature, two 200-210 DEG C of area's temperature, three 235-250 DEG C of area's temperature, four 175-185 DEG C of area's temperature.
CN201710549704.8A 2017-07-07 2017-07-07 A kind of textile material added with crushed crude pearlite and preparation method thereof Pending CN107337921A (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CN201710549704.8A CN107337921A (en) 2017-07-07 2017-07-07 A kind of textile material added with crushed crude pearlite and preparation method thereof
PCT/CN2017/109640 WO2019006942A1 (en) 2017-07-07 2017-11-07 Textile material added with perlite powder and preparation method therefor

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710549704.8A CN107337921A (en) 2017-07-07 2017-07-07 A kind of textile material added with crushed crude pearlite and preparation method thereof

Publications (1)

Publication Number Publication Date
CN107337921A true CN107337921A (en) 2017-11-10

Family

ID=60218387

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710549704.8A Pending CN107337921A (en) 2017-07-07 2017-07-07 A kind of textile material added with crushed crude pearlite and preparation method thereof

Country Status (2)

Country Link
CN (1) CN107337921A (en)
WO (1) WO2019006942A1 (en)

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101049557A (en) * 2007-03-28 2007-10-10 浙江理工大学 Method for preparing photocatalysis functional terylene fiber
CN103820945A (en) * 2014-03-12 2014-05-28 东华大学 Preparation method of organic/inorganic hybridization nano super-hydrophobic fiber film
CN104947236A (en) * 2015-06-26 2015-09-30 安徽皖翎羽绒制品有限公司 Composite down feather fiber having good ultraviolet resistance

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101792939B (en) * 2009-01-16 2012-10-10 张洪泽 Functional fiber
CN104928794A (en) * 2015-06-26 2015-09-23 安徽皖翎羽绒制品有限公司 Feather fiber textile composite material with high firmness

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101049557A (en) * 2007-03-28 2007-10-10 浙江理工大学 Method for preparing photocatalysis functional terylene fiber
CN103820945A (en) * 2014-03-12 2014-05-28 东华大学 Preparation method of organic/inorganic hybridization nano super-hydrophobic fiber film
CN104947236A (en) * 2015-06-26 2015-09-30 安徽皖翎羽绒制品有限公司 Composite down feather fiber having good ultraviolet resistance

Also Published As

Publication number Publication date
WO2019006942A1 (en) 2019-01-10

Similar Documents

Publication Publication Date Title
CN103361997B (en) Pupa albumen, cotton and blend polyester fabric
CN104757724B (en) A kind of knitting fabric of absorbing fast-drying shitosan
CN102719952A (en) Preparation method of banana fibre yarns and application thereof
CN105350299B (en) A kind of automatic temperature-control air-permeable outdoor sport suit fabric and preparation method thereof
CN104372439B (en) Bio-based protein composite fiber and preparation method thereof
CN1990946A (en) Preparation method and application of ceiba fiber in spinning and weave field
CN106883459A (en) A kind of textile material of ventilation wear-resistance and preparation method thereof
CN1990947A (en) Preparation method and application of ceiba fiber in non-weave non-woven fabrics field
CN102733024A (en) Preparation method and application for pineapple fiber yarns
CN103031664B (en) Filler and preparation method thereof spins in the family of a kind of polyester fiber and Lyocell fibers mixing
CN107142552A (en) A kind of waterproof composite textile materials and preparation method thereof
CN105002652A (en) Antimicrobial mildew-proof down composite warmth retention material and preparation method thereof
CN109706545B (en) Microporous hollow graphene sea-island fiber and manufacturing method thereof
CN107034546A (en) A kind of composite fibre textile material and preparation method thereof
CN103088662A (en) Rapid water absorption bamboo fiber cloth
CN103993383B (en) One kind imitates numb core-skin composite fiber and preparation method thereof
CN106521951A (en) Bamdal/cotton blended yarn size, preparation method thereof and sizing effect evaluation method
CN106977772A (en) Fire-type textile material for fire-fighting operation and preparation method thereof
CN1240887C (en) Process for making synthetic fiber colored cloth with high color stability
CN110861363B (en) High-strength TPU composite thermal fabric and preparation method thereof
CN102839472A (en) Nylon-viscose fiber-collagen fiber blended yarn
CN107337921A (en) A kind of textile material added with crushed crude pearlite and preparation method thereof
CN104313877A (en) Coupling agent modifying method for bamboo fibers
CN104328575A (en) Bamboo fiber, wool and vinylon blended fabric
CN103031663B (en) Filler and preparation method thereof spins in the family of a kind of polyester fiber and soybean fiber mixing

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication

Application publication date: 20171110

RJ01 Rejection of invention patent application after publication