CN106883459A - A kind of textile material of ventilation wear-resistance and preparation method thereof - Google Patents
A kind of textile material of ventilation wear-resistance and preparation method thereof Download PDFInfo
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L1/00—Compositions of cellulose, modified cellulose or cellulose derivatives
- C08L1/02—Cellulose; Modified cellulose
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29B—PREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
- B29B9/00—Making granules
- B29B9/02—Making granules by dividing preformed material
- B29B9/06—Making granules by dividing preformed material in the form of filamentary material, e.g. combined with extrusion
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- C—CHEMISTRY; METALLURGY
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- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
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Abstract
The invention discloses a kind of textile material of ventilation wear-resistance and preparation method thereof, it is with apocynum fibre, viscose rayon, PLA, metasilicic acid trimethyl is main component, by adding dilauryl thiodipropionate, neopelex, phosphatidyl-ethanolamine, potassium metabisulfite, cetyl trimethylammonium bromide, hydroxypropul starch, nano silicon, cetanol sulfuric ester sodium salt, linoleic acid, silane coupler, adhesive, deionized water, it is aided with magnetic agitation, rise tepidarium, ball-milling treatment, it is high-pressure homogeneous, the techniques such as Screw Extrusion, so that the textile material good air permeability being prepared from, crocking resistance is strong, disclosure satisfy that the requirement of industry, with preferable application prospect.
Description
Technical field
The present invention relates to textile material technical field, the textile material of more particularly to a kind of ventilation wear-resistance and its preparation side
Method.
Background technology
Textile material refers to fiber and fibre, is embodied in fiber, yarn, fabric and its compound.Modern times are spun
In knitting, the exploitation of the research and development of new textile material, particularly nanofiber and use, breach traditional textile material general
Read.Textile material turns into the important component of soft material, is weaving material by study subject of " shape " and its complex form
One of essential characteristic of material.
Traditional textile material is primarily referred to as fiber, and fiber is the elementary cell of textile material.The source of fiber, composition,
Preparation, form, performance are extremely enriched and complexity.In simple terms, fiber is divided into natural fiber and the major class of chemical fibre two.According to fibre
Natural fiber is divided into plant fiber, animal fiber and mineral fiber by the material source attribute of dimension.By raw material, processing side
The difference of method and constituent, can be divided into regenerated fiber, synthetic fibers and the class of inorfil three again.Current chemical fibre is excellent because of its
Different performance occupies the leading of market.But every kind of chemical fibre is while possessing advantage, many deficiencies are there is also.
The characteristics of several main chemical fibres are listed below：
Acrylic fibers：Acrylic fiber has the title of artificial wool.With soft, bulk, easy dye, lovely luster, fast light, antibacterial, no
The advantages of fearness is damaged by worms.But it has the disadvantage easy balling-up, electrostatic is easily played, easily adsorb dust, wrinkle resistance is poor, and elastic force difference.
Spandex, is the abbreviation of polyurethane fibre, is a kind of elastomer.Spandex can be used for will to meet comfortableness
The clothes for asking needs to stretch, elasticity preferably, there is preferable fast light, acidproof, alkaline-resisting, wearability.It is soft and do not rise
Wrinkle, can remain original profile.But its intensity difference, moisture absorption is poor.
Polyamide fibre, also known as " polyamides fiber ", there are titles such as " nylon " in foreign countries.No matter fiber is in dry state or hygrometric state, all unsuitable
Break, strength is big, there is no silk soft.Great advantage is solid wear-resisting, is optimal one kind.Density is small, and fabric is light, elasticity
Good, endurance destruction, chemical stability is also fine, alkaline-resisting not acidproof.Disadvantage is bad sunlight resistance, and fabric shines long will
Turn yellow, intensity declines, and moisture absorption is also bad, but than acrylic fibers, terylene is good.Poor heat resistance, sun-resistant property is poor, there is electrostatic.Terylene, is called
Polyester fiber, knitted polyester fabric is divided into Grade A, goods of inferior quality, third grade product and off standard by its quality good or not.Advantage is bullet
Property it is good and smooth；Wrinkle resistance and good heat preservation performance；Intensity is high, quick-drying washable；It is heat-resist；Light resistance stabilization；Wearability is strong；Chemistry
Stable performance；Have the disadvantage that water imbibition is poor；It is also easy to produce electrostatic.
Polypropylene fibre, is with the China that the accessory substance propylene of petroleum refining is synthetic fibers isotactic polypropylene fibre obtained in raw material
Trade name.Also known as polypropylene fibre.The hygroscopicity very little of polypropylene fibre, almost non-hygroscopic, the regain under the conditions of general atmosphere is approached
In zero.But it has core sucting action, the capillary that can pass through in fabric transmits vapor, but itself does not play any absorption.Lack
Point is that polypropylene fibre light resistance is poor, and heat endurance is also poor, easily aging, intolerant to flatiron.
Viscose rayon, is made of the various strings such as timber, cotton linter and bamboo, reed, bagasse, straw.12
In kind main textile fabric, the moisture percentage of viscose rayon best suits the physiological requirement of human body skin, with it is smooth it is nice and cool, ventilative,
It is antistatic, dye the characteristic such as gorgeous.But there is also simultaneously and lack flexibility, it is yielding, crumple and produce the defects such as sagging.
Therefore, from from the perspective of material science development, simple chemical fibre or natural fiber can not meet the modern times
The growing requirement for preventing material property of society, how on the basis of existing fibrous material, by adding other
Organic or electrodeless class chemical composition, and coordinate corresponding production technology, prepare a kind of Compound spinning better than general fibre material
Knit material and just seem particularly necessary.
The content of the invention
In order to solve the above technical problems, the present invention provides a kind of textile material of ventilation wear-resistance, by using specific former
Material is combined, and coordinates specific production technology so that the textile material good air permeability being prepared from, and crocking resistance is strong,
The requirement of industry is disclosure satisfy that, with preferable application prospect.
The purpose of the present invention can be achieved through the following technical solutions：
A kind of textile material of ventilation wear-resistance, is made from the following raw materials in parts by weight：Apocynum fibre 50-55 parts, viscose glue
Fiber 40-50 parts, PLA 35-45 parts, 30-40 parts of metasilicic acid trimethyl, dilauryl thiodipropionate 20-26 parts, 12
Sodium alkyl benzene sulfonate 18-22 parts, phosphatidyl-ethanolamine 12-16 parts, potassium metabisulfite 8-12 parts, cetyl trimethyl bromination
Ammonium 6-8 parts, hydroxypropul starch 6-8 parts, nano silicon 4-6 parts, 4-6 parts of cetanol sulfuric ester sodium salt, linoleic acid 3-5 parts,
Silane coupler 2-4 parts, adhesive 2-4 parts, 160 parts of deionized water.
Preferably, the silane coupler is selected from silane coupler KH-590, silane resin acceptor kh-550, silane coupler
Any one in KH-560.
Preferably, described adhesive is selected from any one in sulfenamide, epoxy resin, polyvinyl alcohol.
The preparation method of the textile material of described ventilation wear-resistance, comprises the following steps：
(1) each raw material is weighed according to weight portion；
(2) by PLA, metasilicic acid trimethyl, dilauryl thiodipropionate, neopelex, phosphatidyl second
The mixing of hydramine, potassium metabisulfite, cetyl trimethylammonium bromide, hydroxypropul starch and deionized water, is placed in magnetic agitation
35-45min is stirred with rotating speed 650-750r/min on machine, 80-90 DEG C is then raised temperature to, water-bath 15-25min is tentatively mixed
Compound；
(3) apocynum fibre, viscose rayon, nano silicon, cetanol sulfuric ester sodium salt are collectively disposed at ball mill
In carry out ball-milling treatment, the rotating speed of ball mill is 220-280r/min, and Ball-milling Time is 1-2h, and each component disperses in making mixture
Uniformly, ball-milled mixtures are obtained；
(4) ball-milled mixtures of the initial mixture of step (2) and step (3) are added into high pressure homogenizer jointly, then is added
Enter linoleic acid, silane coupler, adhesive, be well mixed, then melted at 350-360 DEG C, obtain intermediate product；
(5) extrusion molding is carried out in the intermediate product obtained by step (4) being added into double screw extruder, then in an oven
Dry, pelletizing, obtains finished product textile material under the conditions of 40-50 DEG C.
Preferably, the pressure of step (4) the mesohigh homogenizer is 16-18Mpa.
Preferably, in the step (5), the screw speed of double screw extruder is 250-280r/min, twin-screw extrusion
The temperature of each section of machine is：One 170-190 DEG C of area's temperature, two 200-210 DEG C of area's temperature, three 235-250 DEG C of area's temperature, four area's temperature
175-185 DEG C of degree.
Compared with prior art, its advantage is the present invention：
(1) textile material of ventilation wear-resistance of the invention is with apocynum fibre, viscose rayon, PLA, metasilicic acid front three
Ester is main component, by adding dilauryl thiodipropionate, neopelex, phosphatidyl-ethanolamine, weighting sub-
Potassium sulfate, cetyl trimethylammonium bromide, hydroxypropul starch, nano silicon, cetanol sulfuric ester sodium salt, linoleic acid,
Silane coupler, adhesive, deionized water, are aided with magnetic agitation, rise tepidarium, ball-milling treatment, high-pressure homogeneous, Screw Extrusion etc.
Technique so that the textile material good air permeability being prepared from, crocking resistance is strong, disclosure satisfy that the requirement of industry, with compared with
Good application prospect.
(2) the textile material raw material of ventilation wear-resistance of the invention is cheap, process is simple, is suitable to heavy industrialization utilization,
It is practical.
Specific embodiment
The technical scheme invented is described in detail with reference to specific embodiment.
Embodiment 1
(1) 50 parts of apocynum fibre, 40 parts of viscose rayon, 35 parts of PLA, metasilicic acid trimethyl are weighed according to weight portion
30 parts, 20 parts of dilauryl thiodipropionate, 18 parts of neopelex, 12 parts of phosphatidyl-ethanolamine, lay particular stress on sulfurous acid
8 parts of potassium, 6 parts of cetyl trimethylammonium bromide, 6 parts of hydroxypropul starch, 4 parts of nano silicon, cetanol sulfuric ester sodium salt 4
Part, 3 parts of linoleic acid, 2 parts of silane coupler KH-590,2 parts of sulfenamide, 160 parts of deionized water；
(2) by PLA, metasilicic acid trimethyl, dilauryl thiodipropionate, neopelex, phosphatidyl second
The mixing of hydramine, potassium metabisulfite, cetyl trimethylammonium bromide, hydroxypropul starch and deionized water, is placed in magnetic agitation
35min is stirred with rotating speed 650r/min on machine, 80 DEG C are then raised temperature to, water-bath 15min obtains initial mixture；
(3) apocynum fibre, viscose rayon, nano silicon, cetanol sulfuric ester sodium salt are collectively disposed at ball mill
In carry out ball-milling treatment, the rotating speed of ball mill is 220r/min, and Ball-milling Time is 1h, and each component is uniformly dispersed in making mixture,
Obtain ball-milled mixtures；
(4) ball-milled mixtures of the initial mixture of step (2) and step (3) are added into high pressure homogenizer jointly, then is added
Enter linoleic acid, silane coupler KH-590, sulfenamide, be well mixed, then melted at 350 DEG C, obtain intermediate product, wherein
The pressure of high pressure homogenizer is 16Mpa,；
(5) extrusion molding is carried out in the intermediate product obtained by step (4) being added into double screw extruder, wherein twin-screw is squeezed
Go out the screw speed of machine for 250r/min, the temperature of each section of double screw extruder is：One 170 DEG C of area's temperature, two area's temperature 200
DEG C, three 235 DEG C of area's temperature, four 175 DEG C of area's temperature, the then dry, pelletizing under the conditions of 40 DEG C in an oven obtains finished product weaving
Material.
The performance test results of the textile material of obtained ventilation wear-resistance are as shown in table 1.
Embodiment 2
(1) 53 parts of apocynum fibre, 45 parts of viscose rayon, 40 parts of PLA, metasilicic acid trimethyl are weighed according to weight portion
35 parts, 23 parts of dilauryl thiodipropionate, 20 parts of neopelex, 14 parts of phosphatidyl-ethanolamine, lay particular stress on sulfurous acid
10 parts of potassium, 7 parts of cetyl trimethylammonium bromide, 7 parts of hydroxypropul starch, 5 parts of nano silicon, cetanol sulfuric ester sodium salt
5 parts, 4 parts of linoleic acid, 3 parts of silane resin acceptor kh-550,3 parts of epoxy resin, 160 parts of deionized water；
(2) by PLA, metasilicic acid trimethyl, dilauryl thiodipropionate, neopelex, phosphatidyl second
The mixing of hydramine, potassium metabisulfite, cetyl trimethylammonium bromide, hydroxypropul starch and deionized water, is placed in magnetic agitation
40min is stirred with rotating speed 700r/min on machine, 85 DEG C are then raised temperature to, water-bath 20min obtains initial mixture；
(3) apocynum fibre, viscose rayon, nano silicon, cetanol sulfuric ester sodium salt are collectively disposed at ball mill
In carry out ball-milling treatment, the rotating speed of ball mill is 250r/min, and Ball-milling Time is 1.5h, and each component dispersion is equal in making mixture
It is even, obtain ball-milled mixtures；
(4) ball-milled mixtures of the initial mixture of step (2) and step (3) are added into high pressure homogenizer jointly, then is added
Enter linoleic acid, silane resin acceptor kh-550, epoxy resin, be well mixed, then melted at 355 DEG C, obtain intermediate product, wherein
The pressure of high pressure homogenizer is 17Mpa,；
(5) extrusion molding is carried out in the intermediate product obtained by step (4) being added into double screw extruder, wherein twin-screw is squeezed
Go out the screw speed of machine for 265r/min, the temperature of each section of double screw extruder is：One 180 DEG C of area's temperature, two area's temperature 205
DEG C, three 245 DEG C of area's temperature, four 180 DEG C of area's temperature, the then dry, pelletizing under the conditions of 45 DEG C in an oven obtains finished product weaving
Material.
The performance test results of the textile material of obtained ventilation wear-resistance are as shown in table 1.
Embodiment 3
(1) 55 parts of apocynum fibre, 50 parts of viscose rayon, 45 parts of PLA, metasilicic acid trimethyl are weighed according to weight portion
40 parts, 26 parts of dilauryl thiodipropionate, 22 parts of neopelex, 16 parts of phosphatidyl-ethanolamine, lay particular stress on sulfurous acid
12 parts of potassium, 8 parts of cetyl trimethylammonium bromide, 8 parts of hydroxypropul starch, 6 parts of nano silicon, cetanol sulfuric ester sodium salt
6 parts, 5 parts of linoleic acid, 4 parts of silane coupler KH-560,4 parts of polyvinyl alcohol, 160 parts of deionized water；
(2) by PLA, metasilicic acid trimethyl, dilauryl thiodipropionate, neopelex, phosphatidyl second
The mixing of hydramine, potassium metabisulfite, cetyl trimethylammonium bromide, hydroxypropul starch and deionized water, is placed in magnetic agitation
45min is stirred with rotating speed 750r/min on machine, 90 DEG C are then raised temperature to, water-bath 25min obtains initial mixture；
(3) apocynum fibre, viscose rayon, nano silicon, cetanol sulfuric ester sodium salt are collectively disposed at ball mill
In carry out ball-milling treatment, the rotating speed of ball mill is 280r/min, and Ball-milling Time is 2h, and each component is uniformly dispersed in making mixture,
Obtain ball-milled mixtures；
(4) ball-milled mixtures of the initial mixture of step (2) and step (3) are added into high pressure homogenizer jointly, then is added
Enter linoleic acid, silane coupler KH-560, polyvinyl alcohol, be well mixed, then melted at 360 DEG C, obtain intermediate product, wherein
The pressure of high pressure homogenizer is 18Mpa,；
(5) extrusion molding is carried out in the intermediate product obtained by step (4) being added into double screw extruder, wherein twin-screw is squeezed
Go out the screw speed of machine for 280r/min, the temperature of each section of double screw extruder is：One 190 DEG C of area's temperature, two area's temperature 210
DEG C, three 250 DEG C of area's temperature, four 185 DEG C of area's temperature, the then dry, pelletizing under the conditions of 50 DEG C in an oven obtains finished product weaving
Material.
The performance test results of the textile material of obtained ventilation wear-resistance are as shown in table 1.
Embodiment 4
(1) 55 parts of apocynum fibre, 40 parts of viscose rayon, 45 parts of PLA, metasilicic acid trimethyl are weighed according to weight portion
30 parts, 26 parts of dilauryl thiodipropionate, 18 parts of neopelex, 16 parts of phosphatidyl-ethanolamine, lay particular stress on sulfurous acid
8 parts of potassium, 8 parts of cetyl trimethylammonium bromide, 6 parts of hydroxypropul starch, 6 parts of nano silicon, cetanol sulfuric ester sodium salt 4
Part, 5 parts of linoleic acid, 2 parts of silane coupler KH-590,4 parts of epoxy resin, 160 parts of deionized water；
(2) by PLA, metasilicic acid trimethyl, dilauryl thiodipropionate, neopelex, phosphatidyl second
The mixing of hydramine, potassium metabisulfite, cetyl trimethylammonium bromide, hydroxypropul starch and deionized water, is placed in magnetic agitation
45min is stirred with rotating speed 650r/min on machine, 80 DEG C are then raised temperature to, water-bath 25min obtains initial mixture；
(3) apocynum fibre, viscose rayon, nano silicon, cetanol sulfuric ester sodium salt are collectively disposed at ball mill
In carry out ball-milling treatment, the rotating speed of ball mill is 220r/min, and Ball-milling Time is 2h, and each component is uniformly dispersed in making mixture,
Obtain ball-milled mixtures；
(4) ball-milled mixtures of the initial mixture of step (2) and step (3) are added into high pressure homogenizer jointly, then is added
Enter linoleic acid, silane coupler KH-590, epoxy resin, be well mixed, then melted at 350 DEG C, obtain intermediate product, wherein
The pressure of high pressure homogenizer is 18Mpa,；
(5) extrusion molding is carried out in the intermediate product obtained by step (4) being added into double screw extruder, wherein twin-screw is squeezed
Go out the screw speed of machine for 250r/min, the temperature of each section of double screw extruder is：One 190 DEG C of area's temperature, two area's temperature 200
DEG C, three 250 DEG C of area's temperature, four 175 DEG C of area's temperature, the then dry, pelletizing under the conditions of 50 DEG C in an oven obtains finished product weaving
Material.
The performance test results of the textile material of obtained ventilation wear-resistance are as shown in table 1.
Comparative example 1
(1) 53 parts of apocynum fibre, 45 parts of viscose rayon, 40 parts of PLA, metasilicic acid trimethyl are weighed according to weight portion
35 parts, 23 parts of dilauryl thiodipropionate, 20 parts of neopelex, 14 parts of phosphatidyl-ethanolamine, lay particular stress on sulfurous acid
10 parts of potassium, 7 parts of cetyl trimethylammonium bromide, 7 parts of hydroxypropul starch, 5 parts of cetanol sulfuric ester sodium salt, 4 parts of linoleic acid, silicon
3 parts of alkane coupling agent KH-550,3 parts of epoxy resin, 160 parts of deionized water；
(2) by PLA, metasilicic acid trimethyl, dilauryl thiodipropionate, neopelex, phosphatidyl second
The mixing of hydramine, potassium metabisulfite, cetyl trimethylammonium bromide, hydroxypropul starch and deionized water, is placed in magnetic agitation
40min is stirred with rotating speed 700r/min on machine, 85 DEG C are then raised temperature to, water-bath 20min obtains initial mixture；
(3) apocynum fibre, viscose rayon, cetanol sulfuric ester sodium salt are collectively disposed in ball mill and are carried out at ball milling
Reason, the rotating speed of ball mill is 250r/min, and Ball-milling Time is 1.5h, and each component is uniformly dispersed in making mixture, obtains ball milling mixing
Thing；
(4) ball-milled mixtures of the initial mixture of step (2) and step (3) are added into high pressure homogenizer jointly, then is added
Enter linoleic acid, silane resin acceptor kh-550, epoxy resin, be well mixed, then melted at 355 DEG C, obtain intermediate product, wherein
The pressure of high pressure homogenizer is 17Mpa,；
(5) extrusion molding is carried out in the intermediate product obtained by step (4) being added into double screw extruder, wherein twin-screw is squeezed
Go out the screw speed of machine for 265r/min, the temperature of each section of double screw extruder is：One 180 DEG C of area's temperature, two area's temperature 205
DEG C, three 245 DEG C of area's temperature, four 180 DEG C of area's temperature, the then dry, pelletizing under the conditions of 45 DEG C in an oven obtains finished product weaving
Material.
The performance test results of the textile material of obtained ventilation wear-resistance are as shown in table 1.
Comparative example 2
(1) 55 parts of apocynum fibre, 40 parts of viscose rayon, 45 parts of PLA, metasilicic acid trimethyl are weighed according to weight portion
30 parts, 26 parts of dilauryl thiodipropionate, 18 parts of neopelex, 16 parts of phosphatidyl-ethanolamine, lay particular stress on sulfurous acid
8 parts of potassium, 8 parts of cetyl trimethylammonium bromide, 6 parts of hydroxypropul starch, 6 parts of nano silicon, silane coupler KH-590
2 parts, 4 parts of epoxy resin, 160 parts of deionized water；
(2) by PLA, metasilicic acid trimethyl, dilauryl thiodipropionate, neopelex, phosphatidyl second
The mixing of hydramine, potassium metabisulfite, cetyl trimethylammonium bromide, hydroxypropul starch and deionized water, is placed in magnetic agitation
45min is stirred with rotating speed 650r/min on machine, 80 DEG C are then raised temperature to, water-bath 25min obtains initial mixture；
(3) apocynum fibre, viscose rayon, nano silicon are collectively disposed in ball mill carries out ball-milling treatment, ball
The rotating speed of grinding machine is 220r/min, and Ball-milling Time is 2h, and each component is uniformly dispersed in making mixture, obtains ball-milled mixtures；
(4) ball-milled mixtures of the initial mixture of step (2) and step (3) are added into high pressure homogenizer jointly, then is added
Enter silane coupler KH-590, epoxy resin, be well mixed, then melted at 350 DEG C, obtain intermediate product, its mesohigh is equal
The pressure of matter machine is 18Mpa,；
(5) extrusion molding is carried out in the intermediate product obtained by step (4) being added into double screw extruder, wherein twin-screw is squeezed
Go out the screw speed of machine for 250r/min, the temperature of each section of double screw extruder is：One 190 DEG C of area's temperature, two area's temperature 200
DEG C, three 250 DEG C of area's temperature, four 175 DEG C of area's temperature, the then dry, pelletizing under the conditions of 50 DEG C in an oven obtains finished product weaving
Material.
The performance test results of the textile material of obtained ventilation wear-resistance are as shown in table 1.
The textile material of embodiment 1-4 and the ventilation wear-resistance of comparative example 1-2 is carried out into permeability test respectively, and utilizes horse
The damaged Rubbing number of Ding Daier wear resistant instruments test and abrasion loss quality.
Table 1
| Damaged Rubbing number (ten thousand times) | Abrasion loss quality (mg) | ||
| Embodiment 1 | 363 | 6.2 | 1.26 |
| Embodiment 2 | 368 | 6.5 | 1.09 |
| Embodiment 3 | 359 | 6.3 | 1.14 |
| Embodiment 4 | 366 | 6.1 | 1.28 |
| Comparative example 1 | 327 | 5.3 | 2.66 |
| Comparative example 2 | 314 | 5.0 | 2.75 |
The textile material of ventilation wear-resistance of the invention is with apocynum fibre, viscose rayon, PLA, metasilicic acid trimethyl
Main component, by adding dilauryl thiodipropionate, neopelex, phosphatidyl-ethanolamine, weighting sulfurous acid
Potassium, cetyl trimethylammonium bromide, hydroxypropul starch, nano silicon, cetanol sulfuric ester sodium salt, linoleic acid, silane
Coupling agent, adhesive, deionized water, are aided with magnetic agitation, rise the works such as tepidarium, ball-milling treatment, high-pressure homogeneous, Screw Extrusion
Skill so that the textile material good air permeability being prepared from, crocking resistance is strong, the requirement of industry is disclosure satisfy that, with preferable
Application prospect.The textile material raw material of ventilation wear-resistance of the invention is cheap, process is simple, is suitable to heavy industrialization utilization,
It is practical.
Embodiments of the invention are the foregoing is only, the scope of the claims of the invention is not thereby limited, it is every to utilize this hair
Equivalent structure or equivalent flow conversion that bright description is made, or directly or indirectly it is used in other related technology necks
Domain, is included within the scope of the present invention.
Claims (6)
1. a kind of textile material of ventilation wear-resistance, it is characterised in that：It is made from the following raw materials in parts by weight：Apocynum fibre 50-
55 parts, viscose rayon 40-50 parts, PLA 35-45 parts, 30-40 parts of metasilicic acid trimethyl, dilauryl thiodipropionate 20-
26 parts, neopelex 18-22 parts, phosphatidyl-ethanolamine 12-16 parts, potassium metabisulfite 8-12 parts, cetyl
Trimethylammonium bromide 6-8 parts, hydroxypropul starch 6-8 parts, nano silicon 4-6 parts, it is 4-6 parts of cetanol sulfuric ester sodium salt, sub-
Oleic acid 3-5 parts, silane coupler 2-4 parts, adhesive 2-4 parts, 160 parts of deionized water.
2. the textile material of ventilation wear-resistance according to claim 1, it is characterised in that：The silane coupler is selected from silane
Any one in coupling agent KH-590, silane resin acceptor kh-550, silane coupler KH-560.
3. the textile material of ventilation wear-resistance according to claim 1, it is characterised in that：Described adhesive is selected from sulfenyl
Any one in amine, epoxy resin, polyvinyl alcohol.
4. the preparation method of the textile material according to any described ventilation wear-resistance of claims 1 to 3, it is characterised in that including
Following steps：
(1) each raw material is weighed according to weight portion；
(2) by PLA, metasilicic acid trimethyl, dilauryl thiodipropionate, neopelex, phosphatidyl ethanol
The mixing of amine, potassium metabisulfite, cetyl trimethylammonium bromide, hydroxypropul starch and deionized water, is placed in magnetic stirrer
On with rotating speed 650-750r/min stir 35-45min, then raise temperature to 80-90 DEG C, water-bath 15-25min is tentatively mixed
Thing；
(3) apocynum fibre, viscose rayon, nano silicon, cetanol sulfuric ester sodium salt are collectively disposed in ball mill
Row ball-milling treatment, the rotating speed of ball mill is 220-280r/min, and Ball-milling Time is 1-2h, and each component dispersion is equal in making mixture
It is even, obtain ball-milled mixtures；
(4) ball-milled mixtures of the initial mixture of step (2) and step (3) are added into high pressure homogenizer jointly, adds Asia
Oleic acid, silane coupler, adhesive, are well mixed, and are then melted at 350-360 DEG C, obtain intermediate product；
(5) will intermediate product obtained by step (4) add double screw extruder in carry out extrusion molding, then in an oven in
Dry, pelletizing, obtains finished product textile material under the conditions of 40-50 DEG C.
5. the preparation method of the textile material of ventilation wear-resistance according to claim 4, it is characterised in that the step (4)
The pressure of mesohigh homogenizer is 16-18Mpa.
6. the preparation method of the textile material of ventilation wear-resistance according to claim 4, it is characterised in that the step (5)
In, the screw speed of double screw extruder is 250-280r/min, and the temperature of each section of double screw extruder is：One area's temperature
170-190 DEG C, two 200-210 DEG C of area's temperature, three 235-250 DEG C of area's temperature, four 175-185 DEG C of area's temperature.
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN107740197A (en) * | 2017-09-19 | 2018-02-27 | 江苏澳洋世家服装有限公司 | A kind of ventilation wear-resistance and the fabric of antistatic waterproof and preparation method thereof |
| CN108193313A (en) * | 2017-12-29 | 2018-06-22 | 付主枝 | A kind of preparation process of textile material for adding amino silane and its application |
| CN108691062A (en) * | 2018-05-29 | 2018-10-23 | 安徽英士博纺织发展有限公司 | A kind of outdoor wear production fabric |
| CN109234838A (en) * | 2018-08-31 | 2019-01-18 | 吕雄伟 | A kind of preparation method and applications of the textile fabric for automobile interior decoration |
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| CN104878472A (en) * | 2015-06-09 | 2015-09-02 | 苏州市轩德纺织科技有限公司 | Waterproof and breathable textile material and preparation method thereof |
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| CN104172614A (en) * | 2014-09-12 | 2014-12-03 | 刘喜 | Novel breathable moisture absorption blend fiber fabric |
| CN104878472A (en) * | 2015-06-09 | 2015-09-02 | 苏州市轩德纺织科技有限公司 | Waterproof and breathable textile material and preparation method thereof |
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Cited By (4)
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| CN107740197A (en) * | 2017-09-19 | 2018-02-27 | 江苏澳洋世家服装有限公司 | A kind of ventilation wear-resistance and the fabric of antistatic waterproof and preparation method thereof |
| CN108193313A (en) * | 2017-12-29 | 2018-06-22 | 付主枝 | A kind of preparation process of textile material for adding amino silane and its application |
| CN108691062A (en) * | 2018-05-29 | 2018-10-23 | 安徽英士博纺织发展有限公司 | A kind of outdoor wear production fabric |
| CN109234838A (en) * | 2018-08-31 | 2019-01-18 | 吕雄伟 | A kind of preparation method and applications of the textile fabric for automobile interior decoration |
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Application publication date: 20170623 |