CN107320871A - A kind of lithium ion battery case special gas extinguishing device and fire extinguishing implementation method - Google Patents

A kind of lithium ion battery case special gas extinguishing device and fire extinguishing implementation method Download PDF

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Publication number
CN107320871A
CN107320871A CN201710559915.XA CN201710559915A CN107320871A CN 107320871 A CN107320871 A CN 107320871A CN 201710559915 A CN201710559915 A CN 201710559915A CN 107320871 A CN107320871 A CN 107320871A
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China
Prior art keywords
gas
lithium ion
battery case
pressure
ion battery
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CN201710559915.XA
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Chinese (zh)
Inventor
张少禹
董海斌
李毅
于东兴
洪伟艺
洪清泉
刘欣
盛彦锋
韩光
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Tianjin Fire Fighting Institute Ministry of Public Security
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Tianjin Fire Fighting Institute Ministry of Public Security
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Priority to CN201710559915.XA priority Critical patent/CN107320871A/en
Publication of CN107320871A publication Critical patent/CN107320871A/en
Pending legal-status Critical Current

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    • AHUMAN NECESSITIES
    • A62LIFE-SAVING; FIRE-FIGHTING
    • A62CFIRE-FIGHTING
    • A62C3/00Fire prevention, containment or extinguishing specially adapted for particular objects or places
    • A62C3/16Fire prevention, containment or extinguishing specially adapted for particular objects or places in electrical installations, e.g. cableways
    • AHUMAN NECESSITIES
    • A62LIFE-SAVING; FIRE-FIGHTING
    • A62CFIRE-FIGHTING
    • A62C37/00Control of fire-fighting equipment
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/05Accumulators with non-aqueous electrolyte
    • H01M10/052Li-accumulators
    • H01M10/0525Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/42Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
    • H01M10/4207Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells for several batteries or cells simultaneously or sequentially
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Emergency Management (AREA)
  • Health & Medical Sciences (AREA)
  • Business, Economics & Management (AREA)
  • Manufacturing & Machinery (AREA)
  • Public Health (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Secondary Cells (AREA)
  • Fire-Extinguishing By Fire Departments, And Fire-Extinguishing Equipment And Control Thereof (AREA)

Abstract

The present invention, which is set, is related to a kind of lithium ion battery case special gas extinguishing device and fire extinguishing implementation method, device includes extinction using gas agent container, level pressure relieving mechanism, air inlet locking device, aerogenesis driver, gas generating agent, initiator, fire detector, aerogenesis driver is inserted in foamite container, and connect initiator, level pressure relieving mechanism is arranged at the extinguishing chemical liberation port of foamite container, gas generating agent explodes under initiator initiation, heating, gas extinguishing agent is set to become gas by liquid, sprayed from level pressure relieving mechanism, fire extinguishing, have the technical effect that small volume, it is easy for installation, and, foamite container internal pressure is low under normal circumstances, safety, reliably, the very first time it can implement effective fire extinguishing to lithium ion battery case, noresidue after extinguishing chemical release, it is corrosion-free to damage, effectively suppress the extension of battery thermal runaway.

Description

A kind of lithium ion battery case special gas extinguishing device and fire extinguishing implementation method
Technical field
The present invention relates to a kind of extinguishing device, more particularly to a kind of lithium ion battery case special gas extinguishing device and go out Fiery implementation method.
Background technology
In recent years, under the catalysis of policy, China's new-energy automobile industry hypergrowth, electrokinetic cell in the market Enterprise is also in fast development.Lithium ion battery characteristic determines situations such as lithium battery spontaneous combustion, blast at this stage, and especially some are small Battery production enterprise battery quality can not more ensure, to battery in itself, vehicle and personnel cause potential safety hazard.For lithium ion Battery fire present situation, Some Enterprises also have developed the extinguishing device for lithium-ion electric Pool fire of putting out a fire to save life and property, and progressively in electric automobile lithium Carry out applying exploratoryly on ion battery case.According to extinguishing device, practical situations and vehicle production are looked forward on electric automobile Industry, field feedback, it is found that existing extinguishing device is primarily present following not enough and problem:One is aerosol, powder extinguishing agent Belong to non-clean fire extinguishing agent, have residue after extinguishing chemical release, part extinguishing chemical can also cause certain corrosion to lithium battery Damage;Two be condensed aerosol fire extinguishing device, dry powder extinguishing installation action after, hot-gas sol fire extinguishing agent, the powder extinguishing agent of release Battery the temperature inside the box can not effectively be reduced, it is impossible to effectively suppress the development of battery thermal runaway and fire.
The content of the invention
In view of the problem of prior art is present, the invention provides a kind of lithium ion battery case special gas extinguishing device and Fire extinguishing implementation method, concrete technical scheme is that a kind of lithium ion battery case special gas extinguishing device, including gas extinguishing agent hold Device, level pressure relieving mechanism, air inlet locking device, aerogenesis driver, gas generating agent, initiator, fire detector and lithium ion battery Case, it is characterised in that:The casing of extinction using gas agent container provided with extinguishing chemical fill mouth install openable air inlet locking device, Level pressure relieving mechanism is installed provided with extinguishing chemical liberation port, aerogenesis driver stretches into the casing of extinction using gas agent container and seals solid Due on casing, gassy extinguishing chemical in the casing of extinction using gas agent container.
Described aerogenesis driver includes the driving cavity equipped with gas generating agent, and the driving cavity bottom is installed provided with gas outlet Constant pressure turn on mechanism, driving cavity upper end has pressure relief opening to set safety relief device, and one end of initiator is from driving cavity top end Stretch into driving chamber body, the other end is connected outside the casing of extinction using gas agent container with electrical connector, set in driving chamber body Filtering cooling device is equipped with, release feedback device is arranged on outside the casing of extinction using gas agent container and connected with the other end of initiator Connect, the fire detector in electrical connector connection lithium ion battery case, by aluminium film coating technology, by aerogenesis driver All parts and gas generating agent are coated completely.
Described level pressure relieving mechanism, including connecting tube, opening device and multi-port jet pipe, opening device include level pressure again Diaphragm, pressure ring and locking member, level pressure diaphragm are fastened on extinguishing chemical liberation port by pressure ring and locking member, and connecting tube connection is opened Opening device is simultaneously fixed on the casing of extinction using gas agent container, and multi-port jet pipe is connected with connecting tube and is fixed on lithium ion battery In case.
Described fire detector, is integrated with temperature sensor, particle sensor, gas sensor, can detect lithium from Gas concentration, flue gas particle, temperature rise and flare up fire in sub- battery case, it is arranged in lithium ion battery case and driven with aerogenesis The electrical connector connection of dynamic device.
Described release feedback device is thermoswitch, and during aerogenesis driver aerogenesis, thermoswitch is by produced gas Action, output contact signal.
Described filtering cooling device is the device built with heat absorbent.
Described constant pressure turn on mechanism is diaphragm, and its diaphragm bears pressure and released with the gases at high pressure setting produced by gas generating agent Bleed off pressure that power is identical, when the high-pressure gas pressure produced by gas generating agent bears pressure equal to diaphragm, rupture of diaphragm, gas is discharged into gas In the casing of body foamite container.
Described safety relief device is pressure release diaphragm, bears pressure to ensure the maximum pressure of aerogenesis driver safety, When the high-pressure gas pressure produced by gas generating agent is too high, when bearing pressure more than or equal to pressure release diaphragm, pressure release rupture of diaphragm, gas Body is discharged into the casing of extinction using gas agent container.
Fire extinguishing implementation method comprises the following steps, and 1. whether has fire letter in fire detector detection lithium ion battery case Number, no fire signal, lithium ion battery case special gas extinguishing device attonity;There is fire signal, when fire detector detection During to any of gas concentration, flue gas particle, temperature rise and the flare up fire in detection lithium ion battery case signal, fire is sent Calamity pre-warning signal, when fire detector detects two or more signal in above-mentioned signal, sends fire alarm, connection Initiator is acted in movable property gas driver;2. gas generating agent burns in the driving chamber body of aerogenesis driver, produces high temperature, high pressure gas Body, high temperature, gases at high pressure enter in the casing of gas extinguishing agent container through filtering after cooling device absorbs heat.Meanwhile, release feedback Device sends initiator action message to control centre;3. when high temperature, the temperature of gases at high pressure, pressure reach unlatching setting value When, the level pressure rupture of diaphragm of opening device;4. gas extinguishing agent enter level pressure relieving mechanism connecting tube to multi-port jet pipe to Sprayed in lithium ion battery case, complete fire extinguishing.
The beneficial effects of the invention are as follows, foamite container internal pressure is low under normal circumstances, small volume, moulding arbitrarily, energy Enough very first times when the condition of a fire occurs in lithium ion battery case implement effective fire extinguishing to lithium ion battery case, will not after extinguishing chemical release There is residue, certain corrosion and damage will not be caused to lithium ion battery, supervisor can grasp the dynamic of extinguishing device at any time State, can be monitored and handle to the state of extinguishing device.
Brief description of the drawings
Fig. 1 is the schematic cross-sectional view of the present invention;
Fig. 2 is the schematic diagram that the present invention is installed on lithium ion battery case;
Fig. 3 is the step flow chart that the present invention realizes fire extinguishing.
Embodiment
As shown in Figure 1, 2, a kind of lithium ion battery case special gas extinguishing device, including extinction using gas agent container 1, level pressure Set on relieving mechanism 3, air inlet locking device 4, aerogenesis driver 5, gas generating agent 6, initiator 7, the casing of extinction using gas agent container 1 There is extinguishing chemical to fill mouth openable air inlet locking device 4 is installed, level pressure relieving mechanism 3, production are installed provided with extinguishing chemical liberation port Gas driver 5 is stretched into the casing of extinction using gas agent container 1 and is sealingly fastened on casing, the casing of extinction using gas agent container 1 Interior gassy extinguishing chemical 2.
Level pressure relieving mechanism 3, including connecting tube 301, opening device 302 and multi-port jet pipe 303, opening device 302 is again Including level pressure diaphragm, pressure ring and locking member, level pressure diaphragm is fastened on extinguishing chemical liberation port by pressure ring and locking member, connection Pipe 301 connects opening device 302 and is fixed on the casing of extinction using gas agent container 1, multi-port jet pipe 303 and connecting tube 301 Connect and be fixed in lithium ion battery case, multi-port jet pipe 303 is provided with several apertures, single hole diameter is 2mm, position of opening For, the top of multi-port jet pipe 303 and side, interlaced arrangement two-by-two, the number of openings, size and location ensure that extinguishing chemical is uniformly distributed Diverse location in battery case, reaches the effect of total flooding fire extinguishing, and multi-port jet pipe 303 can also be replaced using multiple nozzles.
Extinction using gas agent container 1 is arranged on outside battery case 9, and multi-port jet pipe 303 is stretched into battery case 9, and the gas goes out The installation site of fiery agent container 1 is not limited to this, for example, can also be built in battery case 9.
Aerogenesis driver 5 includes the driving cavity 501 equipped with gas generating agent 6, and the bottom of driving cavity 501 is provided with gas outlet, Constant pressure turn on mechanism 506 is fixed at the gas outlet;Driving cavity is stretched into one end of the initiator 7 from driving cavity 501 top In 501, the other end of initiator 7 is connected with the other end with initiator 7 in vitro positioned at the outer container of extinction using gas agent container 1, described Filtering cooling device 502 is additionally provided with driving cavity 501, was carried out by the gas of 502 pairs of generations of the filtering cooling device Filter and cooling, except this, can also fully be absorbed heat in the driving built-in heat absorbent of cavity 501 using heat absorbent, the gas produced by reduction The temperature of body.The maximum temperature of the gas of the gas outlet release of driving cavity 501 is not more than 100 DEG C, and aerogenesis pressure is 1.0MPa. By aluminium film coating technology, part, gas generating agent 6 in cavity 501 etc. will be driven to be coated completely, make itself and gas extinguishing agent 2 are effectively isolated, and prevent extinguishing chemical corrosion the driving inner part of cavity 501 and gas generating agent 6 etc., and driving cavity 501 is additionally provided with pressure relief opening, Safety relief device 503 is provided with the pressure relief opening, release feedback device 505 is arranged on outside the casing of extinction using gas agent container 1 And be connected with the other end of initiating device 7, linkage release feedback device 505 is acted during aerogenesis 5 aerogenesis of driver, makes its output anti- Feedback signal, release feedback device 505 is thermoswitch, and the operating temperature of the thermoswitch is 120 DEG C, and aerogenesis driver 5 is acted High pressure, high-temperature gas are produced afterwards, thermoswitch is acted under high-temperature gas effect, output contact signal represents that extinguishing chemical is normal Release.
The fire detector 8 is integrated with temperature sensor, particle sensor, gas sensor etc., can detect lithium from Gas concentration, flue gas particle, temperature rise and flare up fire in sub- battery case 9, it is arranged in lithium ion battery case 9.
As shown in figure 3, when fire detector 8 detects the one of which signal in above-mentioned signal, sending fire alarm Signal;When fire detector 8 detects two or more signal in above-mentioned signal, fire alarm is sent, linkage is drawn Hair device 7 is acted, and release feedback device 505 is provided with the extinction using gas agent container 1, the release feedback device 505 is with triggering Device 7 is all connected with the electrical connector 504, is connected by electrical connector 504 with remote monitoring device, is visited in fire detector 8 When measuring the condition of a fire, initiator 7 is triggered.
Embodiment,
Extinction using gas agent container 1 is in rectangular parallelepiped structure, is welded by upper and lower two housing sections, aerogenesis driver 5 is fixed on Portion's case inside, the lower case of extinction using gas agent container 1 fills mouth and extinguishing chemical liberation port provided with extinguishing chemical.Gas extinguishing agent Setting for container 1 pushes up constant-pressure as 1.5MPa, and Novec1230 gas extinguishing agents 2 fill mouth by the extinguishing chemical and filled, and fill Sealed after dress with openable sealed air inlet locking device 4.The operating temperature range of Novec1230 gas extinguishing agents 2 is -40 DEG C~120 DEG C, pressure is the saturated vapour pressure of Novec1230 gas extinguishing agents 2 in extinction using gas agent container 1, at 20 DEG C The saturated vapour pressure of Novec1230 gas extinguishing agents 2 is about 0MPa, 49 DEG C of the boiling temperature of Novec1230 gas extinguishing agents 2, - 108 DEG C of freezing point temperature, therefore during -40 DEG C of low temperature, Novec1230 extinguishing chemicals will not solidify, gas generating agent 6 is neutral inorganic The mixture of salt, active metal powder, stabilization agent etc..
The profile of aerogenesis driver 5 is cylinder, when initiating device 7 is triggered, and drives the aerogenesis in driving cavity 501 The burning of agent 6 produces gases at high pressure, and high temperature, gases at high pressure enter gas extinguishing agent container 1 through filtering after cooling device 502 absorbs heat In casing, meanwhile, release feedback device 505 sends the action message of initiator 7 to control centre;When the pressure of high temperature, gases at high pressure When power reaches unlatching setting value 1.0MPa, the level pressure rupture of diaphragm of opening device 302;Novec1230 gas extinguishing agents 2 enter fixed The connecting tube 301 of pressure relieving mechanism 3 is sprayed to multi-port jet pipe 303 into lithium ion battery case, completes fire extinguishing, reaches and put out lithium The purpose of fire in ion battery case 9.
Above-described embodiment is only used for further illustrating a kind of lithium ion battery case special gas extinguishing device of the present invention, but The invention is not limited in embodiment, what every technical spirit according to the present invention was made to above example any simply repaiies Change, equivalent variations and modification, each fall within the protection domain of technical solution of the present invention.

Claims (9)

1. a kind of lithium ion battery case special gas extinguishing device, including extinction using gas agent container(1), level pressure relieving mechanism(3)、 Air inlet locking device(4), aerogenesis driver(5), gas generating agent(6), initiator(7), fire detector(8)And lithium ion battery case (9), it is characterised in that:Extinction using gas agent container(1)Casing provided with extinguishing chemical fill mouth install it is openable enter gas locked Device(4), provided with extinguishing chemical liberation port install level pressure relieving mechanism(3), aerogenesis driver(5)Stretch into extinction using gas agent container (1)Casing in and be sealingly fastened on casing, extinction using gas agent container(1)Casing in gassy extinguishing chemical(2).
2. a kind of lithium ion battery case special gas extinguishing device as claimed in claim 1, it is characterised in that:Described aerogenesis Driver(5)Including equipped with gas generating agent(6)Driving cavity(501), the driving cavity(501)Install fixed provided with gas outlet in bottom Press opener(506), drive cavity(501)Upper end has pressure relief opening to set safety relief device(503), initiator(7)One Hold from driving cavity(501)Driving cavity is stretched on top(501)The interior, other end is located at extinction using gas agent container(1)Casing outside With electrical connector(504)Connection, drives cavity(501)Inside it is provided with filtering cooling device(502), discharge feedback device (505)Installed in extinction using gas agent container(1)Casing outside and and initiator(7)The other end connection, electrical connector(504) Connect lithium ion battery case(9)Interior fire detector(8), by aluminium film coating technology, by aerogenesis driver(5)Interior is all Part and gas generating agent(6)Coated completely.
3. a kind of lithium ion battery case special gas extinguishing device as claimed in claim 1, it is characterised in that:Described level pressure Relieving mechanism(3), including connecting tube(301), opening device(302)And multi-port jet pipe(303), opening device(302)Wrap again Level pressure diaphragm, pressure ring and locking member are included, level pressure diaphragm is fastened on extinguishing chemical liberation port, connecting tube by pressure ring and locking member (301)Connect opening device(302)And it is fixed on extinction using gas agent container(1)Casing on, multi-port jet pipe(303)With being connected Pipe(301)Connect and be fixed in lithium ion battery case.
4. a kind of lithium ion battery case special gas extinguishing device as claimed in claim 1, it is characterised in that:Described fire Detector(8), temperature sensor, particle sensor, gas sensor are integrated with, lithium ion battery case can be detected(9)Interior Gas concentration, flue gas particle, temperature rise and flare up fire, it is arranged at lithium ion battery case(9)It is interior and with aerogenesis driver(5)'s Electrical connector(504)Connection.
5. a kind of lithium ion battery case special gas extinguishing device as claimed in claim 1, it is characterised in that:Described release Feedback device(505)For thermoswitch, the aerogenesis driver(5)During aerogenesis, thermoswitch is acted on dynamic by produced gas Make, output contact signal.
6. a kind of lithium ion battery case special gas extinguishing device as claimed in claim 1 or 2, it is characterised in that:Described Filter cooling device(502)For the device built with heat absorbent.
7. a kind of lithium ion battery case special gas extinguishing device as claimed in claim 1 or 2, it is characterised in that:Described Constant pressure turn on mechanism(506)For diaphragm, its diaphragm bears pressure and gas generating agent(6)Unlatching setting value it is identical, work as gas generating agent(6) When produced high-pressure gas pressure bears pressure equal to diaphragm, rupture of diaphragm, gas is discharged into extinction using gas agent container(1)Case In vivo.
8. a kind of lithium ion battery case special gas extinguishing device as claimed in claim 1 or 2, it is characterised in that:Described Safety relief device(503)For pressure release diaphragm, pressure and gas generating agent are born(6)Pressure release setting value is identical, works as gas generating agent(6)Produced Raw high-pressure gas pressure is too high, when bearing pressure more than or equal to pressure release diaphragm, and pressure release rupture of diaphragm, gas is discharged into extinction using gas Agent container(1)Casing in.
9. using a kind of lithium ion battery case special gas described in claim 1 or 2 or 3 or 4 or 5 or 6 or 7 or 8 The fire extinguishing implementation method of extinguishing device, it is characterised in that:Implementation method comprises the following steps,
1. fire detector(8)Detect lithium ion battery case(9)Inside whether there are fire signal, nothing, lithium ion battery case special gas Body extinguishing device attonity;Have, work as fire detector(8)Detect detection lithium ion battery case(9)Interior gas concentration, flue gas During any of particle, temperature rise and flare up fire signal, fire alarm signal is sent, works as fire detector(8)Detect When stating two or more signal in signal, fire alarm is sent, link aerogenesis driver(5)Middle initiator(7)Action;
2. gas generating agent(6)In aerogenesis driver(5)Driving cavity(501)Interior burning, produces high temperature, gases at high pressure, high temperature, height Body is calmed the anger through filtering cooling device(502)Enter gas extinguishing agent container after heat absorption(1)Casing in, meanwhile, release feedback dress Put(505)Initiator is sent to control centre(7)Action message;
3. when high temperature, the temperature of gases at high pressure, pressure reach unlatching setting value, opening device(302)Level pressure rupture of diaphragm;
4. gas extinguishing agent(2)Into level pressure relieving mechanism(3)Connecting tube(301)To multi-port jet pipe(303)To lithium ion Sprayed in battery case, complete fire extinguishing.
CN201710559915.XA 2017-07-11 2017-07-11 A kind of lithium ion battery case special gas extinguishing device and fire extinguishing implementation method Pending CN107320871A (en)

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CN107961464A (en) * 2017-12-15 2018-04-27 安徽中科中涣防务装备技术有限公司 A kind of extinguishing device of temperature and pressure release
CN109065984A (en) * 2018-08-13 2018-12-21 上海纳晓能源科技有限公司 The safety charging device of battery
CN109939388A (en) * 2019-04-03 2019-06-28 应急管理部天津消防研究所 A kind of automobile extinguishing device and implementation method
CN111359118A (en) * 2020-04-14 2020-07-03 杭州中传消防设备有限公司 Non-pressure-storage type automatic fire extinguishing device for lithium battery fire
CN111632326A (en) * 2020-06-10 2020-09-08 湖北航天化学技术研究所 Thermal runaway detection device and application thereof
CN113577621A (en) * 2021-07-29 2021-11-02 世纪联保消防新技术(江西)有限公司 Starting device and fire extinguishing apparatus
CN114633646A (en) * 2022-02-24 2022-06-17 国网山东省电力公司泰安供电公司 Charger, and automatic fire extinguishing method and system thereof
WO2023024040A1 (en) * 2021-08-26 2023-03-02 华为数字能源技术有限公司 Firefighting device, battery pack, energy storage system, and electric vehicle

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CN111632326A (en) * 2020-06-10 2020-09-08 湖北航天化学技术研究所 Thermal runaway detection device and application thereof
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