CN107318883A - A kind of aqua for including glyphosate Mediben - Google Patents
A kind of aqua for including glyphosate Mediben Download PDFInfo
- Publication number
- CN107318883A CN107318883A CN201710572434.2A CN201710572434A CN107318883A CN 107318883 A CN107318883 A CN 107318883A CN 201710572434 A CN201710572434 A CN 201710572434A CN 107318883 A CN107318883 A CN 107318883A
- Authority
- CN
- China
- Prior art keywords
- mediben
- glyphosate
- aqua
- dimethylamine
- quantitative
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/36—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids
- A01N37/38—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system
- A01N37/40—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a singly bound oxygen or sulfur atom attached to the same carbon skeleton, this oxygen or sulfur atom not being a member of a carboxylic group or of a thio analogue, or of a derivative thereof, e.g. hydroxy-carboxylic acids having at least one oxygen or sulfur atom attached to an aromatic ring system having at least one carboxylic group or a thio analogue, or a derivative thereof, and one oxygen or sulfur atom attached to the same aromatic ring system
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
- A01N57/20—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing acyclic or cycloaliphatic radicals
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Dentistry (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Toxicology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention provides a kind of aqua for including glyphosate Mediben, the composition comprising following weight parts:Glyphosate 10 40%, Mediben 1 10%, dimethylamine 25 35%, APG 5 10%, the double di-sec-octyl succinate sodium sulfonates 1 10% of ethylene glycol, surplus is water.
Description
Technical field
The invention belongs to pesticide field, and in particular to a kind of aqua comprising glyphosate Mediben and preparation method thereof.
Background technology
Glyphosate is that Monsanto Chemicals develop in 1970s, is most widely used in the world
Steriland herbicide, with it is interior inhale, efficiently, wide spectrum, low toxicity, it is safe the features such as.But it is due to the chronic administration of glyphosate, weeds
Resistance problem also gradually highlight.Mediben, as high-efficiency low-toxicity herbicide, is a kind of nonirrigated farmland selection of efficient inner sucting conduction type
Property herbicide, with herbicide power is strong, drug effect is rapid, consumption is few, holding effect is moderate, high financial profit the features such as.Asked to solve resistance
Topic, the compound product of domestic agricultural chemicals enterprise also positive exploitation glyphosate.Wherein compare concerned, compounded with Mediben
Turn into glyphosate and solved Weed Resistance, continue one of the effective way of market life.
Aqua is compared with other formulations, it is not necessary to organic solvent, add appropriate surfactant be it is sprayable use, it is right
Environmental pollution is less, preparation technology is simple.But at present on glyphosate and dicamba aqueous solution formula it is less, and it is irregular not
Together, it is to solve technical problem of the prior art, the present invention have developed surface tension, foaming characteristic, foam stability, viscosity, often
Warm storage stability indicator shows the aqua of excellent glyphosate Mediben.
The content of the invention
To solve technical problem of the prior art, present invention offer is a kind of to include glyphosate wheat with excellent properties
The aqua of grass fear.
The technical scheme that the present invention is provided is as follows:
A kind of aqua for including glyphosate Mediben, the composition comprising following weight parts:Glyphosate 10-40%, wheat straw
Fear 1-10%, dimethylamine 15-35%, APG 5-10%, the double di-sec-octyl succinate sodium sulfonate 1-10% of ethylene glycol, surplus
For water.
Aqua of the present invention, optimization formula is, glyphosate 15-35%, Mediben 2-8%, dimethylamine 15-25%,
APG 5-10%, the double di-sec-octyl succinate sodium sulfonate 2-4% of ethylene glycol, surplus is water.
Dimethylamine can be replaced isopropylamine or sodium hydroxide in aqua of the present invention.
Organic silicon defoamer 1-3% is also included in aqua of the present invention.
Aqua of the present invention can be used for flying anti-spraying.
Compared with prior art, the present invention has the advantages that:
Aqua prepared by the present invention, shows excellent by test surfaces tension force, outward appearance, normal temperature heat storage stability index.
Embodiment
The embodiment of the present invention is described in detail with reference to embodiment, it is to be understood that the guarantor of the present invention
Shield scope is not limited by embodiment.
The aqua of the glyphosate Mediben of embodiment 1 33%
Glyphosate 30%, Mediben 3%, the double butanedioic acid di-sec-octyl sulphurs of dimethylamine 25%, APG 15%, ethylene glycol
Sour sodium 2%, surplus is water.
Quantitative water is added in reaction vessel, quantitative glyphosate raw material is added, stirring is opened, quantitative two are added
Methylamine, after stirring, adds Mediben active compound, stirring adds quantitative dimethylamine, adding other after being stirred until homogeneous helps
Agent, is stirred until homogeneous and can obtain this product.
The aqua of the glyphosate Mediben of embodiment 2 22%
Glyphosate 20%, Mediben 2%, the double butanedioic acid di-sec-octyl sulphurs of dimethylamine 18%, APG 17%, ethylene glycol
Sour sodium 3%, organic silicon defoamer 1.5%, surplus are water.
Quantitative water is added in reaction vessel, quantitative glyphosate raw material is added, stirring is opened, quantitative two are added
Methylamine, after stirring, adds Mediben active compound, stirring adds quantitative dimethylamine, adding other after being stirred until homogeneous helps
Agent, is stirred until homogeneous and can obtain this product.
The aqua of the glyphosate Mediben of embodiment 3 42%
Glyphosate 34%, Mediben 8%, the double butanedioic acid di-sec-octyl sulphurs of isopropylamine 30%, APG 15%, ethylene glycol
Sour sodium 6%, organic silicon defoamer 2%, surplus are water.
Quantitative water is added in reaction vessel, quantitative glyphosate raw material is added, stirring is opened, added quantitative different
Propylamine, after stirring, adds Mediben active compound, stirring adds quantitative isopropylamine, adding other after being stirred until homogeneous helps
Agent, is stirred until homogeneous and can obtain this product.
The aqua of the glyphosate Mediben of embodiment 4 11%
Glyphosate 10%, Mediben 1%, the double butanedioic acid di-sec-octyls of sodium hydroxide 8%, APG 10%, ethylene glycol
Sodium sulfonate 1%, organic silicon defoamer 0.5%, surplus are water.
Quantitative water is added in reaction vessel, quantitative glyphosate raw material is added, stirring is opened, quantitative hydrogen is added
Sodium oxide molybdena, after stirring, adds Mediben active compound, stirring adds quantitative sodium hydroxide, it is added after being stirred until homogeneous
His auxiliary agent, is stirred until homogeneous and can obtain this product.
The aqua of the glyphosate Mediben of comparative example 1 30%
Glyphosate 30%, Mediben 3%, the double butanedioic acid di-sec-octyl sulphurs of dimethylamine 25%, APG 5%, ethylene glycol
Sour sodium 1%, organic silicon defoamer 1%, surplus are water.
Quantitative water is added in reaction vessel, quantitative glyphosate raw material is added, stirring is opened, quantitative two are added
Methylamine, after stirring, adds Mediben active compound, stirring adds quantitative dimethylamine, adding other after being stirred until homogeneous helps
Agent, is stirred until homogeneous and can obtain this product.
Test one, glyphosate dicamba aqueous solution performance measurement
Aqua is diluted 100 times, the surface tension and heat storage stability of aqua is then tested.Aqua surface tension≤
30mN/m is qualified.Heat storage stability method of testing is referring to GB/T 19136-2003.Preserved in (54 ± 2) DEG C insulating box
After 14d, aqua is observed.If aqua is still as clear as crystal, deposit-free is separated out, and no floating oil phenomenon is then to be qualified.
As seen from the above table, the aqua that prepared by the present invention has excellent preparation performance parameters.Found compared with comparative example, this
The double di-sec-octyl succinate sodium sulfonates of invention auxiliary agent APG, ethylene glycol play mutual synergy.
Further narration has been done to the present invention above in conjunction with embodiment, but the present invention is not limited to above-mentioned embodiment,
In the knowledge that one skilled in the relevant art possesses, it can also be made on the premise of present inventive concept is not departed from
Various change.
Claims (5)
1. a kind of aqua for including glyphosate Mediben, it is characterised in that the composition comprising following weight parts:Glyphosate 10-
40%, Mediben 1-10%, dimethylamine 15-35%, APG 5-10%, the double di-sec-octyl succinate sodium sulfonate 1- of ethylene glycol
10%, surplus is water.
2. aqua according to claim 1, it is characterised in that glyphosate 15-35%, Mediben 2-8%, dimethylamine 15-
25%, APG 5-10%, the double di-sec-octyl succinate sodium sulfonate 2-4% of ethylene glycol, surplus is water.
3. aqua according to claim 1 or 2, it is characterised in that dimethylamine can be replaced isopropylamine or sodium hydroxide.
4. the aqua according to claim any one of 1-3, it is characterised in that also comprising organic silicon defoamer 1-3%.
5. the aqua according to claim any one of 1-4 can be used for flying anti-spraying.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201710572434.2A CN107318883A (en) | 2017-07-14 | 2017-07-14 | A kind of aqua for including glyphosate Mediben |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201710572434.2A CN107318883A (en) | 2017-07-14 | 2017-07-14 | A kind of aqua for including glyphosate Mediben |
Publications (1)
Publication Number | Publication Date |
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CN107318883A true CN107318883A (en) | 2017-11-07 |
Family
ID=60227116
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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CN201710572434.2A Pending CN107318883A (en) | 2017-07-14 | 2017-07-14 | A kind of aqua for including glyphosate Mediben |
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CN (1) | CN107318883A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109757482A (en) * | 2017-11-09 | 2019-05-17 | 山东润博生物科技有限公司 | A kind of continuous preparation method of pesticide dimethylamine salt aqua |
CN111034738A (en) * | 2019-12-30 | 2020-04-21 | 江苏腾龙生物药业有限公司 | Dicamba and glyphosate compound aqueous solution and preparation method thereof |
-
2017
- 2017-07-14 CN CN201710572434.2A patent/CN107318883A/en active Pending
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109757482A (en) * | 2017-11-09 | 2019-05-17 | 山东润博生物科技有限公司 | A kind of continuous preparation method of pesticide dimethylamine salt aqua |
CN111034738A (en) * | 2019-12-30 | 2020-04-21 | 江苏腾龙生物药业有限公司 | Dicamba and glyphosate compound aqueous solution and preparation method thereof |
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Application publication date: 20171107 |