CN107517959A - A kind of dispersible oil-suspending agent containing mesosulfuron and clodinafop-propargyl and preparation method thereof - Google Patents
A kind of dispersible oil-suspending agent containing mesosulfuron and clodinafop-propargyl and preparation method thereof Download PDFInfo
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- CN107517959A CN107517959A CN201710661682.4A CN201710661682A CN107517959A CN 107517959 A CN107517959 A CN 107517959A CN 201710661682 A CN201710661682 A CN 201710661682A CN 107517959 A CN107517959 A CN 107517959A
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- Prior art keywords
- clodinafop
- propargyl
- mesosulfuron
- suspending agent
- dispersible oil
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/36—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< directly attached to at least one heterocyclic ring; Thio analogues thereof
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- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Dispersion Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Toxicology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of dispersible oil-suspending agent containing mesosulfuron and clodinafop-propargyl and preparation method thereof, belongs to technical field of pesticide, and dispersible oil-suspending agent of the invention includes mesosulfuron and clodinafop-propargyl;The quality accounting of mesosulfuron and clodinafop-propargyl is (0.01%~1%):(21%~50%);Mesosulfuron and clodinafop-propargyl are 1%~90% in dispersible oil-suspending agent gross mass percentage composition.Reactor is added after first emulsifying agent, dispersant, mesosulfuron and clodinafop-propargyl are ground to below particle diameter 0.01cm, mixes, be uniformly dispersed;Thickener is added under high speed shear state, it is ground to below 5 μm of particle diameter and again together adds stabilizer, vegetable oil and deionized water in reactor, mix, be uniformly dispersed the dispersible oil-suspending agent that can be prepared by containing mesosulfuron and clodinafop-propargyl, a kind of dispersible oil-suspending agent containing mesosulfuron and clodinafop-propargyl of the present invention has notable synergistic effect.
Description
Technical field
It is outstanding more particularly to a kind of dispersible oil containing mesosulfuron and clodinafop-propargyl the invention belongs to technical field of pesticide
Floating agent and preparation method thereof.The dispersible oil-suspending agent is applied to wheat paddock weeding.
Background technology
Wheat is one of main cereal crops in China, and weeding for wheat is a great problem in production.Chemical weed control is mesh
The Main Means of preceding control weeds.In recent years, because some herbicide kind large area are used alone, many weeds are already led to
Generate the resistance to the action of a drug.Simultaneously as mutually complexity, species are various for grass when weeds occur, single variety is used and can not effectively solved
Farmland weed, the defects of showing in a certain respect.Herbicide is wide in variety in the market, while application technology also requires
Height, it is careless slightly in the application, poisoning will occur, the problems such as herbicidal effect is bad.Herbicide will be directly affected from improper
People or the safety or yield of crops.With the development of weeding technique and the emergence of herbicide, many weeds of farmland
Then it is increasingly difficult to kill.
Mesosulfuron (Mesosulfuron-methyl), [3- (4, the 6-=methoxy pyrimidine -2- of chemical name methyl -2
Base) a ureido sulfuryl l-4- methanesulfonylaminobenzene formic acid esters, belong to sulfonylurea highy potent herbicide, mainly pass through plant
Cauline leaf absorbs, and is conducted through bast and xylem, on a small quantity by soil absorption, suppresses the acetolactic acid synthesis in sensitive plant body
The activity of enzyme, cause the numerous sour biosynthesis block of side chain ammonia, so as to suppress cell division, cause sensitive plant dead.Ordinary circumstance
Under, after dispenser 2~4 hours, the uptake of susceptible weeds peaks, and is stopped growing after 2 days, and rear blade starts Huang within 4~7 days
Change, withered spot then occur, it is dead after 2~4 weeks.The safener contained in this product, it can be promoted to be decomposed rapidly in crop body, and
Its degraded in target weeds body is not influenceed, so as to reach the purpose for killing weeds, cover crop.Suitable in soft and
Used in semi-rigid type winter wheat variety.Amur foxtail, wild oat can be prevented and kill off, caput grass, annual bluegrass, hard grass, alkali thatch, spend more rye
The weeds such as grass, lolium temulentum, bromegrass, candle grass, Triticum tauschii, Tong grass, wheatgrass, shepherd's purse, Descurainia sophia, ox chickweed, spontaneous rape.
Clodinafop-propargyl (clodinafop-propargyl), chemical name:R-2- [4- (the fluoro- 2- epoxides pyridines of the chloro- 3- of 5-)-benzene
Epoxide]-propionic acid-propynyl ester, belong to fragrant phenoxy phenoxy propionic acid herbicide, the biosynthesis that can effectively suppress class ester is the auxiliary quick A of acetyl
Hydroxylase inhibitors, are degraded to free acid phenyl quickly in soil and pyridine moiety enters soil.The medicament can prevent and treat wheat
The grassy weeds such as vole tail amur foxtail, tall oat grass, rye grass, rough stalked blue grass green bristlegrass.
The content of the invention
The purpose of the present invention is to be directed to problems of the prior art, a kind of dividing containing mesosulfuron and clodinafop-propargyl
Dissipate oil-suspending agent and preparation method thereof, there is provided a kind of component is reasonable, and herbicidal spectrum is wide, and preventive effect is good, and drug cost is low, is not likely to produce anti-
A kind of dispersible oil-suspending agent containing mesosulfuron and clodinafop-propargyl of the property of medicine.
In order to solve the above technical problems, the present invention is achieved by the following technical solutions:
A kind of dispersible oil-suspending agent containing mesosulfuron and clodinafop-propargyl, the dispersible oil-suspending agent include effectively living
Property composition mesosulfuron and clodinafop-propargyl;The mesosulfuron and the mass ratio of clodinafop-propargyl are (0.01%~1%):(21%
~50%).
Preferably, a kind of described dispersible oil-suspending agent containing mesosulfuron and clodinafop-propargyl includes mesosulfuron
0.01%~2%, clodinafop-propargyl 1%~100%, thickener 1%~30%, emulsifying agent 1%~30%, dispersant 0.1%~
30%th, stabilizer 0.1%~30%, vegetable oil 0.1%~20% and deionized water 1%~80%, each component quality percentage contain
It is 100% to measure sum.
Preferably, the quality accounting of the mesosulfuron and clodinafop-propargyl is (0.5%~1%):(21%~30%);Institute
It is 21.5%~37% that both mesosulfuron and clodinafop-propargyl, which are stated, in dispersible oil-suspending agent gross mass percentage composition.
Preferably, the thickener is one kind in bentonite, gaseous silicon oxide, Magnesiumaluminumsilicate, xanthans, white carbon
It is or a variety of.
Preferably, the emulsifying agent is phenethyl phenol polyethenoxy ether, calcium dodecyl benzene sulfonate, polysorbate, dehydration
Span, phenethyl phenol polyethenoxy ether, NPE, APES, poly alkyl alcohol
One or more in oxygen vinethene, polyethenoxy ether carboxylate, APEO vinethene, castor oil ethylene oxide adduct
Preferably, the dispersant is one kind or more in the salt of ligninsulfonate, alkylnaphthalene sulfonate, formaldehyde condensation products
Kind.
Preferably, the stabilizer BH-2,6- di-t-butyl -4-4 methylphenols, butylated hydroxy anisole, epoxy chloropropionate
One or more in alkane.
Preferably, the vegetable oil is the one or more in epoxidized soybean oil, methyl oleate or corn oil.
Preferably, a kind of preparation method of the dispersible oil-suspending agent containing mesosulfuron and clodinafop-propargyl is as follows:
The first step, mesosulfuron is ground, emulsifying agent and dispersant it is standby to below particle diameter 0.01cm, clodinafop-propargyl heating
45 DEG C obtain the fused mass of clodinafop-propargyl to molten condition;
Second step, by the following particles of particle diameter 0.01cm of mesosulfuron, emulsifying agent and dispersant and the melting of clodinafop-propargyl
Thing is together added in reactor, and heating stirring uniformly obtains primary mix;
3rd step, after primary mix is cooled into less than 20 DEG C, thickener is added under high speed shear state, is ground to
Below 5 μm of particle diameter;
4th step, the product below 5 μm of particle diameter is together added in reactor with stabilizer, vegetable oil, it is mixing, scattered equal
The even dispersible oil-suspending agent that can be prepared by containing mesosulfuron and clodinafop-propargyl.
The invention has the advantages that:
By carrying out rational proportion to the accounting of both mesosulfuron and clodinafop-propargyl in herbicide, enhancing removes the present invention
The property of medicine effect of careless agent, the activity when Weed-control effect of wheat paddock is administered alone better than each component, while expand control of weeds
Spectrum, improve herbicidal effect, to grassy weed, sedge weed and broad leaved weed prevention effect protrude, have it is quick, hold
The effect phase is long, delays the advantages that herbicide resistance, weeding are thorough, residual is low, less toxic, safety and environmental protection.
Certainly, any product for implementing the present invention it is not absolutely required to reach all the above advantage simultaneously.
Brief description of the drawings
For the ease of it will be appreciated by those skilled in the art that the present invention is further illustrated below in conjunction with the accompanying drawings.
Fig. 1 is a kind of preparation method flow chart of the dispersible oil-suspending agent of mesosulfuron clodinafop-propargyl of the present invention.
Embodiment
Below in conjunction with the embodiment of the present invention, the technical scheme in the embodiment of the present invention is clearly and completely described,
Obviously, described embodiment is only part of the embodiment of the present invention, rather than whole embodiments.Based in the present invention
Embodiment, all other embodiment that those of ordinary skill in the art are obtained under the premise of creative work is not made, all
Belong to the scope of protection of the invention.
In these embodiments, unless otherwise indicated, all percentages are mass percent.
Embodiment 1
A kind of dispersible oil-suspending agent of mesosulfuron clodinafop-propargyl, containing accounting for gross mass point in the dispersible oil-suspending agent
Mesosulfuron and clodinafop-propargyl active compound of the number for 22%;Wherein, mesosulfuron active compound mass fraction is 0.9%, and clodinafop-propargyl is former
Medicine mass fraction is 21.1%.
Also containing castor oil oxirane of the mass fraction for 10%, 3% organic swelling in the dispersible oil-suspending agent
Soil, 8% epoxy chloroethanes, 6% ligninsulfonate, 5% epoxidized soybean oil and 46% deionized water.
Embodiment 2
A kind of dispersible oil-suspending agent of mesosulfuron clodinafop-propargyl, containing accounting for gross mass point in the dispersible oil-suspending agent
Mesosulfuron and clodinafop-propargyl active compound of the number for 22%;Wherein, mesosulfuron active compound mass fraction is 0.5%, and clodinafop-propargyl is former
Medicine mass fraction is 21.5%.
Also containing castor oil oxirane of the mass fraction for 10%, 3% organic swelling in the dispersible oil-suspending agent
Soil, 8% epoxy chloroethanes, 6% ligninsulfonate, 5% epoxidized soybean oil and 42% deionized water.
Embodiment 3
A kind of dispersible oil-suspending agent of mesosulfuron clodinafop-propargyl, containing accounting for gross mass point in the dispersible oil-suspending agent
Mesosulfuron and clodinafop-propargyl active compound of the number for 22%;Wherein, mesosulfuron active compound mass fraction is 0.1%, and clodinafop-propargyl is former
Medicine mass fraction is 21.9%.
Also containing castor oil oxirane of the mass fraction for 10%, 3% organic swelling in the dispersible oil-suspending agent
Soil, 8% epoxy chloroethanes, 6% ligninsulfonate, 5% epoxidized soybean oil and 42% deionized water.
Referring to Fig. 1, processing method of the present invention comprises the steps:
The first step, mesosulfuron is ground, emulsifying agent and dispersant it is standby to below particle diameter 0.01cm, clodinafop-propargyl heating
45 DEG C of fused mass that clodinafop-propargyl is obtained to molten condition are standby;
Second step, by the following particles of particle diameter 0.01cm of mesosulfuron, emulsifying agent and dispersant and the melting of clodinafop-propargyl
Thing is together added in reactor, and heating stirring uniformly obtains primary mix;
3rd step, after primary mix is cooled into less than 20 DEG C, thickener is added under high speed shear state, is ground to
Below 5 μm of particle diameter;
4th step, the product below 5 μm of particle diameter is together added in reactor with stabilizer, vegetable oil, it is mixing, scattered equal
The even dispersible oil-suspending agent that can be prepared by containing mesosulfuron and clodinafop-propargyl.
The 22% dispersible oil-suspending agent of mesosulfuron clodinafop-propargyl prevents and kill off corn field annual gramineae, monocotyledon weed
And part broad leaved weed, 35-45 grams/acre of preparation dosage, in the weeds 2-3 leaf phases, cauline leaf spraying.This product be by mesosulfuron and
Both clodinafop-propargyls mixture forms, to rice safety, broad weed-killing spectrum.The two mixture has preferable prevention effect to corn field weed.
Consider, herbicidal effect, synergy situation, had when carrying out the compounding production of product from clodinafop-propargyl and mesosulfuron
It is 0.9% to imitate the ratio between composition:21.1% ratio is compounded.
Composition and outward appearance:This product should be processed by standard compliant mesosulfuron, clodinafop-propargyl active compound, auxiliary agent and vegetable oil and made
Into, should be it is flowable, it is easy measurement volume suspension liquid;Precipitation is likely to occur during storage, but handles shake, should recover former
Shape, there should not be caking.
The 22% dispersible oil-suspending agent of mesosulfuron clodinafop-propargyl should meet table 1 and require.
Field control effectiveness test report summaries test name:The dispersible oil-suspending agent of mesosulfuron clodinafop-propargyl prevents and kill off wheat
Field life grass family, sedge weed and part broad leaved weed field control effectiveness test,
Trial crops:Wheat,
Controlling object:Weeds;
Application method:Cauline leaf sprays;
Pharmacy type:Dispersible oil-suspending agent
Result of the test:Table 2
The dispersible oil of the clodinafop-propargyl of 0.5% mesosulfuron 21.5% suspends it can be seen from the field test results of table 2
Agent preventive effect is that the dispersible oil-suspending agent preventive effect of the clodinafop-propargyl of 83%, 0.1% mesosulfuron 21.9% is 81%, 0.9% methyl
The dispersible oil-suspending agent preventive effect of grand 21.1% clodinafop-propargyl of two sulphurs is 85%, and drug effect is better than 22% clodinafop-propargyl, the sulphur of 2% methyl two
It is grand, while do not found to wheat generation poisoning during pilot survey.
Above content is only citing made for the present invention and explanation, and affiliated those skilled in the art are to being retouched
The specific embodiment stated is made various modifications or supplement or substituted using similar mode, without departing from invention or super
More scope defined in the claims, protection scope of the present invention all should be belonged to.
In the description of this specification, the description of reference term " one embodiment ", " example ", " specific example " etc. means
At least one implementation of the present invention is contained in reference to specific features, structure, material or the feature that the embodiment or example describe
In example or example.In this manual, identical embodiment or example are not necessarily referring to the schematic representation of above-mentioned term.
Moreover, specific features, structure, material or the feature of description can close in any one or more embodiments or example
Suitable mode combines.
Present invention disclosed above preferred embodiment is only intended to help and illustrates the present invention.Preferred embodiment is not detailed
All details are described, it is only described embodiment also not limit the invention.Obviously, according to the content of this specification,
It can make many modifications and variations.This specification is chosen and specifically describes these embodiments, is to preferably explain the present invention
Principle and practical application so that skilled artisan can be best understood by and utilize the present invention.The present invention is only
Limited by claims and its four corner and equivalent.
Claims (9)
- A kind of 1. dispersible oil-suspending agent containing mesosulfuron and clodinafop-propargyl, it is characterised in that:The dispersible oil-suspending agent Include effective active composition mesosulfuron and clodinafop-propargyl;The mesosulfuron and the mass ratio of clodinafop-propargyl for (0.01%~ 1%):(21%~50%).
- A kind of 2. dispersible oil-suspending agent containing mesosulfuron and clodinafop-propargyl according to claim 1, it is characterised in that; A kind of described dispersible oil-suspending agent containing mesosulfuron and clodinafop-propargyl includes mesosulfuron 0.01%~2%, alkynes grass Ester 1%~100%, thickener 1%~30%, emulsifying agent 1%~30%, dispersant 0.1%~30%, stabilizer 0.1%~ 30%th, vegetable oil 0.1%~20% and deionized water 1%~80%, each component weight/mass percentage composition sum are 100%.
- A kind of 3. dispersible oil-suspending agent containing mesosulfuron and clodinafop-propargyl according to claim 1, it is characterised in that The quality accounting of the mesosulfuron and clodinafop-propargyl is (0.5%~1%):(21%~30%);The mesosulfuron and Both clodinafop-propargyls are 21.5%~37% in dispersible oil-suspending agent gross mass percentage composition.
- A kind of 4. dispersible oil-suspending agent containing mesosulfuron and clodinafop-propargyl according to claim 1, it is characterised in that The thickener is the one or more in bentonite, gaseous silicon oxide, Magnesiumaluminumsilicate, xanthans, white carbon.
- A kind of 5. dispersible oil-suspending agent containing mesosulfuron and clodinafop-propargyl according to claim 1, it is characterised in that The emulsifying agent be phenethyl phenol polyethenoxy ether, calcium dodecyl benzene sulfonate, polysorbate, sorbitan fatty acid ester, Phenethyl phenol polyethenoxy ether, NPE, APES, AEO, polyoxy second One or more in alkene ether carboxylate, APEO vinethene, castor oil ethylene oxide adduct.
- A kind of 6. dispersible oil-suspending agent containing mesosulfuron and clodinafop-propargyl according to claim 1, it is characterised in that The dispersant is the one or more in the salt of ligninsulfonate, alkylnaphthalene sulfonate, formaldehyde condensation products.
- A kind of 7. dispersible oil-suspending agent containing mesosulfuron and clodinafop-propargyl according to claim 1, it is characterised in that The stabilizer BH-2,6- di-t-butyl -4-4 methylphenols, one kind or more in butylated hydroxy anisole, epoxychloropropane Kind.
- A kind of 8. dispersible oil-suspending agent containing mesosulfuron and clodinafop-propargyl according to claim 1, it is characterised in that The vegetable oil is the one or more in epoxidized soybean oil, methyl oleate or corn oil.
- 9. a kind of prepare a kind of preparation of the dispersible oil-suspending agent containing mesosulfuron and clodinafop-propargyl as claimed in claim 1 Method, it is characterised in that:The first step, mesosulfuron is ground, emulsifying agent and dispersant it is standby to below particle diameter 0.01cm, clodinafop-propargyl heat 45 DEG C The fused mass of clodinafop-propargyl is obtained to molten condition;Second step, by the following particles of particle diameter 0.01cm of mesosulfuron, emulsifying agent and dispersant and the fused mass one of clodinafop-propargyl With adding in reactor, heating stirring uniformly obtains primary mix;3rd step, after primary mix is cooled into less than 20 DEG C, thickener is added under high speed shear state, is ground to particle diameter Less than 5 μm;4th step, the product below 5 μm of particle diameter is together added in reactor with stabilizer, vegetable oil, mixes, be uniformly dispersed i.e. The dispersible oil-suspending agent containing mesosulfuron and clodinafop-propargyl can be made.
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN109452267A (en) * | 2018-11-22 | 2019-03-12 | 深圳诺普信农化股份有限公司 | The preparation method and aqueous pesticide formulations of aqueous pesticide formulations |
CN112841208A (en) * | 2021-01-22 | 2021-05-28 | 安徽润农腾辉生物科技有限公司 | Weeding composition containing pyroxsulam, mesosulfuron and clodinafop-propargyl |
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CN104012526A (en) * | 2014-06-09 | 2014-09-03 | 浙江天丰生物科学有限公司 | Dispersible oil suspension agent for low-melting-point compound and preparation method thereof |
CN105594694A (en) * | 2015-12-24 | 2016-05-25 | 安徽美兰农业发展股份有限公司 | Mesosulfuron and clodinafop-propargyl compound dispersible oil suspending agent and preparation method thereof |
CN106305750A (en) * | 2016-08-20 | 2017-01-11 | 广东中迅农科股份有限公司 | Dispersible oil suspension containing mesosulfuron and clodinafop-propargyl and preparation method thereof |
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CN102228046A (en) * | 2011-05-06 | 2011-11-02 | 浙江泰达作物科技有限公司 | Mesosulfuron-methyl and clodinafop-propargyl compounded herbicide suspending agent and its preparation method |
CN104012526A (en) * | 2014-06-09 | 2014-09-03 | 浙江天丰生物科学有限公司 | Dispersible oil suspension agent for low-melting-point compound and preparation method thereof |
CN105594694A (en) * | 2015-12-24 | 2016-05-25 | 安徽美兰农业发展股份有限公司 | Mesosulfuron and clodinafop-propargyl compound dispersible oil suspending agent and preparation method thereof |
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CN109452267A (en) * | 2018-11-22 | 2019-03-12 | 深圳诺普信农化股份有限公司 | The preparation method and aqueous pesticide formulations of aqueous pesticide formulations |
CN112841208A (en) * | 2021-01-22 | 2021-05-28 | 安徽润农腾辉生物科技有限公司 | Weeding composition containing pyroxsulam, mesosulfuron and clodinafop-propargyl |
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Application publication date: 20171229 |