CN106305750A - Dispersible oil suspension containing mesosulfuron and clodinafop-propargyl and preparation method thereof - Google Patents
Dispersible oil suspension containing mesosulfuron and clodinafop-propargyl and preparation method thereof Download PDFInfo
- Publication number
- CN106305750A CN106305750A CN201610697810.6A CN201610697810A CN106305750A CN 106305750 A CN106305750 A CN 106305750A CN 201610697810 A CN201610697810 A CN 201610697810A CN 106305750 A CN106305750 A CN 106305750A
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- CN
- China
- Prior art keywords
- clodinafop
- propargyl
- oil
- mesosulfuron
- suspending agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/36—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< directly attached to at least one heterocyclic ring; Thio analogues thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
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- Life Sciences & Earth Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Dispersion Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Toxicology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention relates to a dispersible oil suspension containing mesosulfuron and clodinafop-propargyl, made from mesosulfuron and clodinafop-propargyl as effective ingredients, including, by weight, 1-10% of mesosulfuron, 10-20% of clodinafop-propargyl, 10-20% of an emulsifying agent, 1-3% of a dispersant, 1-3% of a thickener, 1-3% of white carbon black, and the balance of an oil solvent. The mesosulfuron, clodinafop-propargyl, the emulsifying agent, the dispersant and the white carbon black are added in the oil solvent and are mixed and stirred and sheared for 20-30 min, the thickener is added after grinding by a grinding machine, and the dispersible oil suspension containing mesosulfuron and clodinafop-propargyl is produced. The dispersible oil suspension containing mesosulfuron and clodinafop-propargyl is applicable to the control and removal of part of broad-leaved weeds such as winter wheat and spring wheat annual grassy weeds and starwort, the control effect is significantly better than that of a single agent, and drug resistance in weeds can be delayed.
Description
Technical field
The present invention relates to one and can be used for winter wheat, spring wheat annual gramineous weed and Herba stellariae mediae etc., and can prevent and kill off part
Broad leaved weed, a kind of dispersibles oil-suspending agent containing mesosulfuron and clodinafop-propargyl.
Background technology
Clodinafop-propargyl is phenoxy phenoxy propionic acid herbicide, and the biosynthesis that can effectively suppress class ester is the auxiliary quick A hydroxylase of acetyl
Inhibitor, this product is quickly degraded to free acid phenyl in soil and pyridine moiety enters soil.This product can prevent and treat Semen Tritici aestivi vole
The grassy weeds such as tail amur foxtail, Herba avenae fatuae, rye grass, rough stalked blue grass Herba Setariae Viridis.
Mesosulfuron is sulfonylurea herbicide, the main stem and leaf absorption by plant, passes through phloem and xylem
Lead, on a small quantity by soil absorption, the activity of the acetolactate synthestase in suppression sensitive plant body, cause the conjunction of the numerous acid of side chain ammonia
One-tenth is obstructed, thus suppresses cell division, causes sensitive plant dead.
Both contribute to making up the generation of respective deficiency and herbicide resistance by combination preparation.
Dispersibling the formulations of pesticide that oil-suspending agent is a kind of great development prospect, stable performance, cohesiveness is good, to target
Potentiation is notable, decreases dosage and environmental pollution, and it is more steady than aqueous suspension agent performance that halosulfuronmethyl dispersibles oil-suspending agent
Fixed, and one-pack type is placed for a long time and is not the most decomposed, and can use with other mixture of herbicides, solve and other herbicide
The problem that the compounding complex preparation resolution ratio obtained is high, and produce and during use without powder, it is difficult to damage to people, than
Powder is more environmentally-friendly.
Summary of the invention
It is an object of the invention to provide and a kind of dispersible oil-suspending agent containing mesosulfuron and clodinafop-propargyl, be used for preventing
Except part broad leaved weeds such as winter wheat, spring wheat annual gramineous weed and Herba stellariae mediaes.
Technical scheme is: the oil-suspending agent that dispersibles containing mesosulfuron and clodinafop-propargyl includes following component, each component
According to mass percent proportioning: mesosulfuron 1%-10%, clodinafop-propargyl 10%-20%, emulsifying agent 10-20%, dispersant 1-
3%, thickening agent 1-3%, white carbon 1-3%, surplus is oil solvent.
Described emulsifying agent is that oleophylic hydrophilic emulsifying agent is compounding to be used, selected from NPE, Oleum Ricini polyoxy
Vinyl Ether, polyol fatty acid ester, styryl phenol polyethenoxy ether, fatty polyoxyethylene esters, alkaryl phenol polyethenoxy ether
The mixing of one or more in phosphate ester.
Described dispersant is alkylphenol polyoxyethylene formaldehyde condensation products, lignosulfonates, polycarboxylate, LOMAR PWA EINECS 246-676-2
Salt formaldehyde condensation products, to the mixing of one or more in methoxyl group fatty acyl anilinesulfonic acid.
Described white carbon fineness is crossed 325 mesh standard sieve percent of pass and is more than 98%, and oil suction is more than or equal to 3mL/g.
Described thickening agent is one or both the mixing in organobentonite, xanthan gum.
Described oil solvent is turpentine-based vegetable oil, methyl oleate, soybean oil, Oleum Arachidis hypogaeae semen, mineral oil, solvent naphtha, formicester
Change one or several the mixing in Petiolus Trachycarpi oil.
Of the present invention a kind of containing mesosulfuron with the preparation method dispersibling oil-suspending agent of clodinafop-propargyl: in oil soluble
Adding mesosulfuron and clodinafop-propargyl, emulsifying agent, dispersant, white carbon, mixing in agent, stirring, at high-speed shearing machine 1000-
Under the rotating speed of 2000 turns every point, stirring is sheared, and shears 20-30 minute, is less than till 8 microns being ground to D95 through sand mill,
It is subsequently adding the rotating speed that thickening agent turns every point at cutter 1000-2000 to stir 30-40 minute, records D95 less than 8 microns, i.e.
Prepare mesosulfuron clodinafop-propargyl and dispersible oil-suspending agent.
Mesosulfuron and clodinafop-propargyl are used environment-friend auxiliaries (to divide as active component, auxiliary material additive by the present invention
Powder, emulsifying agent, wetting agent), it is made into the stable oil-suspending agent that dispersibles, preparation stabilization is reliable, and production method is simple.And use
Oil base flash-point high, it is ensured that the safety produce, transported.Product cost is high, is a kind of broad spectrum type herbicide, and instant effect reduces
The pollution of environment and the actual bodily harm of user, improve drug effect.
Specific embodiments
In order to be better understood from the essence of the present invention, the technology contents of the present invention is described by embodiment below, but this
Bright content is not limited thereto.
Embodiment 1
In cutting kettle, add 667.2g after methyl oleate, add emulsifying agent castor oil polyoxyethylene ether 100g, fat
Polyoxyethylene ether 50g, dispersant naphthalenesulfonate formaldehyde condensation compound 10g, white carbon 20g, mixing, stirring, add 31.6g95% first
Base two sulphur is grand, 206.2g97% clodinafop-propargyl, and under high-speed shearing machine 1000-2000 turns the rotating speed of every point, stirring is sheared, and shears 20-
30 minutes, it is being ground to D95 less than till 8 microns through sand mill, is being subsequently adding thickening agent organoclay 15g, at cutter
1000-2000 turns the rotating speed of every point and stirs 30-40 minute, records D95 and is less than 8 microns, i.e. prepares breast Lycoperdon polymorphum Vitt 3% mesosulfuron
20% clodinafop-propargyl dispersibles oil-suspending agent.
Embodiment 2
Adding 517g after soybean oil in cutting kettle, adding emulsifying agent polyol fatty acid ester ether 150g, nonyl phenol gathers
Oxygen vinyl Ether 50g, dispersant lignosulfonates 20g, white carbon 10g, mixing, stirring, add 31.6g95% mesosulfuron
Former medicine, 206.2g97% clodinafop-propargyl, under high-speed shearing machine 1000-2000 turns the rotating speed of every point, stirring is sheared, and shears 20-30 and divides
Clock, is being ground to D95 less than till 8 microns through sand mill, is being subsequently adding thickening agent organoclay 15g, at cutter 1000-
The rotating speed of 2000 turns every point stirs 30-40 minute, records D95 and is less than 8 microns, i.e. prepares Lycoperdon polymorphum Vitt 3% mesosulfuron 20% alkynes
Grass ester dispersibles oil-suspending agent.
Embodiment 3
In cutting kettle, add 521.2g after turpentine-based vegetable oil, add emulsifying agent NPE 120g,
Castor oil polyoxyethylene ether 75g, dispersant alkylphenol polyoxyethylene formaldehyde condensation products 16g, white carbon 15g, mixing, stirring,
Add the former medicine of 31.6g95% mesosulfuron, 206.2g97% clodinafop-propargyl, high-speed shearing machine 1000-2000 turn every point turn
Stir shearing under speed, shear 20-30 minute, be ground to D95 less than till 8 microns through sand mill, be subsequently adding thickening agent
Organoclay 15g, the rotating speed turning every point at cutter 1000-2000 stirs 30-40 minute, records D95 and is less than 8 microns, the most prepared
Lycoperdon polymorphum Vitt 3% mesosulfuron 20% clodinafop-propargyl dispersibles oil-suspending agent.
Embodiment 4
In cutting kettle, add solvent naphtha 200g, formicester Petiolus Trachycarpi oil 298.2g, add emulsifying agent polyol fatty acid
Ester 110g, castor oil polyoxyethylene ether 70g, dispersant polycarboxylate 30g, white carbon 24g, mixing, stirring, add
The former medicine of 31.6g95% mesosulfuron, 206.2g97% clodinafop-propargyl, under high-speed shearing machine 1000-2000 turns the rotating speed of every point
Stirring is sheared, and shears 20-30 minute, is less than till 8 microns being ground to D95 through sand mill, is subsequently adding thickening agent organic
Soil 30g, the rotating speed turning every point at cutter 1000-2000 stirs 30-40 minute, records D95 and is less than 8 microns, i.e. prepares Lycoperdon polymorphum Vitt
3% mesosulfuron 20% clodinafop-propargyl dispersibles oil-suspending agent.
Embodiment 5
In cutting kettle, add mineral oil 515.2g, add emulsifying agent styryl phenol polyethenoxy ether 110g, benzene second
Thiazolinyl phenol polyethenoxy ether 70g, dispersant, to methoxyl group fatty acyl anilinesulfonic acid 32g, white carbon 14g, mixing, stirring, adds
Enter the former medicine of 31.6g95% mesosulfuron, 206.2g97% clodinafop-propargyl, turn the rotating speed of every point at high-speed shearing machine 1000-2000
Lower stirring is sheared, and shears 20-30 minute, is less than till 8 microns being ground to D95 through sand mill, and being subsequently adding thickening agent has
Machine soil 21g, the rotating speed turning every point at cutter 1000-2000 stirs 30-40 minute, records D95 and is less than 8 microns, i.e. prepares ash
Color 3% mesosulfuron 20% clodinafop-propargyl dispersibles oil-suspending agent.
Claims (7)
1. one kind dispersibles oil-suspending agent containing mesosulfuron and clodinafop-propargyl, it is characterised in that the percent mass of each component
Ratio is: mesosulfuron 1%-10%, clodinafop-propargyl 10%-20%, emulsifying agent 10%-20%, dispersant 1%-3%, thickening agent
1%-3%, white carbon 1%-3%, surplus is oil solvent.
The most according to claim 1 a kind of dispersible oil-suspending agent containing mesosulfuron and clodinafop-propargyl, it is characterised in that
Described emulsifying agent is that oleophylic hydrophilic emulsifying agent is compounding to be used, selected from NPE, castor oil polyoxyethylene ether, many
In unit alcohol fatty acid ester, styryl phenol polyethenoxy ether, fatty polyoxyethylene esters, alkaryl phenol polyethenoxy ether phosphate
The mixing of one or more.
The most according to claim 1 a kind of dispersible oil-suspending agent containing mesosulfuron and clodinafop-propargyl, it is characterised in that
Described dispersant is alkylphenol polyoxyethylene formaldehyde condensation products, lignosulfonates, polycarboxylate, naphthalene sulphonate formaldehyde contracting
Compound, to the mixing of one or more in methoxyl group fatty acyl anilinesulfonic acid.
The most according to claim 1 a kind of dispersible oil-suspending agent containing mesosulfuron and clodinafop-propargyl, it is characterised in that
Described white carbon fineness is crossed 325 mesh standard sieve percent of pass and is more than 98%, and oil suction is more than or equal to 3mL/g.
The most according to claim 1 a kind of dispersible oil-suspending agent containing mesosulfuron and clodinafop-propargyl, it is characterised in that
Described thickening agent is one or both the mixing in organobentonite, xanthan gum.
The most according to claim 1 a kind of dispersible oil-suspending agent containing mesosulfuron and clodinafop-propargyl, it is characterised in that
Described oil solvent is turpentine-based vegetable oil, methyl oleate, soybean oil, Oleum Arachidis hypogaeae semen, mineral oil, solvent naphtha, formicester Petiolus Trachycarpi oil
In one or several mixing.
It is the most according to claim 1 a kind of containing mesosulfuron with the preparation method dispersibling oil-suspending agent of clodinafop-propargyl,
It is characterized in that: in oil solvent, add mesosulfuron and clodinafop-propargyl, emulsifying agent, dispersant, white carbon, mixing, stir,
High-speed shearing machine 1000-2000 turns stirring under the rotating speed of every point and shears, and shears 20-30 minute, is being ground to D95 through sand mill
Till 8 microns, be subsequently adding thickening agent cutter 1000-2000 turn every point rotating speed stir 30-40 minute, record
D95 is less than 8 microns, i.e. prepares mesosulfuron clodinafop-propargyl and dispersibles oil-suspending agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610697810.6A CN106305750A (en) | 2016-08-20 | 2016-08-20 | Dispersible oil suspension containing mesosulfuron and clodinafop-propargyl and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610697810.6A CN106305750A (en) | 2016-08-20 | 2016-08-20 | Dispersible oil suspension containing mesosulfuron and clodinafop-propargyl and preparation method thereof |
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| CN106305750A true CN106305750A (en) | 2017-01-11 |
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| CN201610697810.6A Pending CN106305750A (en) | 2016-08-20 | 2016-08-20 | Dispersible oil suspension containing mesosulfuron and clodinafop-propargyl and preparation method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107517959A (en) * | 2017-08-04 | 2017-12-29 | 安徽圣丰生化有限公司 | A kind of dispersible oil-suspending agent containing mesosulfuron and clodinafop-propargyl and preparation method thereof |
| CN112075436A (en) * | 2020-09-25 | 2020-12-15 | 江苏富田农化有限公司 | Weeding composition, preparation and preparation method thereof |
| CN112841208A (en) * | 2021-01-22 | 2021-05-28 | 安徽润农腾辉生物科技有限公司 | Weeding composition containing pyroxsulam, mesosulfuron and clodinafop-propargyl |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102228046A (en) * | 2011-05-06 | 2011-11-02 | 浙江泰达作物科技有限公司 | Mesosulfuron-methyl and clodinafop-propargyl compounded herbicide suspending agent and its preparation method |
| CN102308830A (en) * | 2011-10-11 | 2012-01-11 | 联保作物科技有限公司 | Weeding composition |
| US20150157018A1 (en) * | 2013-12-06 | 2015-06-11 | Sumitomo Chemical Company, Limited | Weed control composition |
| CN105010374A (en) * | 2015-07-25 | 2015-11-04 | 海利尔药业集团股份有限公司 | Weeding composition containing tribenuron methyl |
| CN105594694A (en) * | 2015-12-24 | 2016-05-25 | 安徽美兰农业发展股份有限公司 | Mesosulfuron and clodinafop-propargyl compound dispersible oil suspending agent and preparation method thereof |
-
2016
- 2016-08-20 CN CN201610697810.6A patent/CN106305750A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102228046A (en) * | 2011-05-06 | 2011-11-02 | 浙江泰达作物科技有限公司 | Mesosulfuron-methyl and clodinafop-propargyl compounded herbicide suspending agent and its preparation method |
| CN102308830A (en) * | 2011-10-11 | 2012-01-11 | 联保作物科技有限公司 | Weeding composition |
| US20150157018A1 (en) * | 2013-12-06 | 2015-06-11 | Sumitomo Chemical Company, Limited | Weed control composition |
| CN105010374A (en) * | 2015-07-25 | 2015-11-04 | 海利尔药业集团股份有限公司 | Weeding composition containing tribenuron methyl |
| CN105594694A (en) * | 2015-12-24 | 2016-05-25 | 安徽美兰农业发展股份有限公司 | Mesosulfuron and clodinafop-propargyl compound dispersible oil suspending agent and preparation method thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107517959A (en) * | 2017-08-04 | 2017-12-29 | 安徽圣丰生化有限公司 | A kind of dispersible oil-suspending agent containing mesosulfuron and clodinafop-propargyl and preparation method thereof |
| CN112075436A (en) * | 2020-09-25 | 2020-12-15 | 江苏富田农化有限公司 | Weeding composition, preparation and preparation method thereof |
| CN112841208A (en) * | 2021-01-22 | 2021-05-28 | 安徽润农腾辉生物科技有限公司 | Weeding composition containing pyroxsulam, mesosulfuron and clodinafop-propargyl |
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