CN107312655A - A kind of basic zirconium phosphate handmade soap - Google Patents
A kind of basic zirconium phosphate handmade soap Download PDFInfo
- Publication number
- CN107312655A CN107312655A CN201710624979.3A CN201710624979A CN107312655A CN 107312655 A CN107312655 A CN 107312655A CN 201710624979 A CN201710624979 A CN 201710624979A CN 107312655 A CN107312655 A CN 107312655A
- Authority
- CN
- China
- Prior art keywords
- zirconium phosphate
- basic zirconium
- parts
- handmade soap
- nano silver
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/02—Compositions of detergents based essentially on soap on alkali or ammonium soaps
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/06—Inorganic compounds
- C11D9/18—Water-insoluble compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/22—Organic compounds, e.g. vitamins
- C11D9/225—Polymers
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/22—Organic compounds, e.g. vitamins
- C11D9/26—Organic compounds, e.g. vitamins containing oxygen
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D9/00—Compositions of detergents based essentially on soap
- C11D9/04—Compositions of detergents based essentially on soap containing compounding ingredients other than soaps
- C11D9/22—Organic compounds, e.g. vitamins
- C11D9/26—Organic compounds, e.g. vitamins containing oxygen
- C11D9/262—Organic compounds, e.g. vitamins containing oxygen containing carbohydrates
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Engineering & Computer Science (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Inorganic Chemistry (AREA)
- Molecular Biology (AREA)
- Cosmetics (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
Abstract
The invention discloses a kind of basic zirconium phosphate handmade soap, the basic zirconium phosphate handmade soap includes following raw material components：Natural soap base, basic zirconium phosphate, Nano Silver, silver nitrate, sapindoside, borneol.Nano Silver containing more amount in the present invention, and Nano Silver can stablize, be evenly dispersed in soap body, with good antibacterial effect.
Description
Technical field
The present invention relates to the technical field of the cleaning supplies of phosphoric acid zirconium.
Background technology
Basic zirconium phosphate is a kind of inorganic carrier with catalysis, absorption and ion-exchange performance, is resistant to stronger acid and certain
Basicity, its stability and mechanical strength are very strong, including two kinds of configurations of alpha zirconium phosphate and γ-basic zirconium phosphate, be rule stratiform
Structure, with extremely strong load effect, can introduce interlayer by supported ionic and remain in that stable layer structure behind.
Basic zirconium phosphate load silver particles it is very competent, therefore have in terms of carrying silver antimicrobials are prepared larger application prospect.
Handmade soap is generally prepared using natural materials, and such as addition without antiseptic does not simply fail to play the work of antibiotic and sterilizing
With while the hold period of its own is also shorter.
Nano Silver is a kind of effective and biological good antiseptic, substantial amounts of to be applied in all kinds of antibiotic cleaning articles for use.
But its usual dispersibility is poor, easily reunite in cleaning supplies, particularly colloid or solid kind cleaning supplies.
The content of the invention
Make the hand that the Nano Silver of more amount is stable, be evenly dispersed in soap body it is an object of the invention to provide a kind of
Work soap.
Technical scheme is as follows：
A kind of basic zirconium phosphate handmade soap, it includes following raw material components：Natural soap base, basic zirconium phosphate, Nano Silver, silver nitrate, soapberry
Saponin(e, borneol.
Preferably：The basic zirconium phosphate handmade soap also includes following raw material components：Tea Polyphenols, chitosan.
It is also preferred that：The raw material includes in parts by mass：Natural 60 ~ 80 parts of soap base, 3 ~ 5 parts of basic zirconium phosphate, nanometer
0.1 ~ 0.5 part of silver, 0.1 ~ 0.3 part of silver nitrate, 10 ~ 30 parts of sapindoside, 0.5 ~ 1.5 part of borneol.
It is also preferred that：The raw material also includes in parts by mass：0.5 ~ 1.5 part of Tea Polyphenols, chitosan 1.0 ~ 3.0
Part.
It is also preferred that：The Nano Silver particle diameter is 5 ~ 30nm.
It is also preferred that：The basic zirconium phosphate is alpha zirconium phosphate.
Two parts are come from as the Nano Silver of antiseptic in the present invention, a part is the Nano Silver being directly added into, another portion
It is divided into the Nano Silver after being reduced through sapindoside, this two parts Nano Silver can be loaded by basic zirconium phosphate, by the layer of basic zirconium phosphate
Shape structure obtains stabilization, uniform, effective load, while sapindoside forms jelly during silver nitrate is reduced,
The basic zirconium phosphate for being loaded with Nano Silver can be coated, thus avoid basic zirconium phosphate and contacted with the direct of the natural soap base of alkalescence.
The preferred technical solution of the present invention can further increase the dispersion effect and the parcel effect to basic zirconium phosphate of Nano Silver,
Such as the further active material Tea Polyphenols of addition reproducibility, and the chitosan of microballoon can be formed by Ionic gelation method in raw material.
Contain more antiseptic Nano Silver in the present invention, it is evenly distributed, in order in soap body, thus with good
Anti-microbial property and stability.
Embodiment
Embodiment 1
Basic zirconium phosphate handmade soap is prepared by procedure below：
（1）Sapindoside is added in deionized water, then it is 0.1mol/L's that silver nitrate and deionized water are configured into concentration
Solution is added thereto, and 30min is stirred at 40 DEG C, obtains the first dispersion liquid；
（2）Particle diameter is added in the first dispersion liquid for 5nm nano silver particles with alpha zirconium phosphate, continues to stir at 40 DEG C
30min, obtains the second dispersion liquid；
（3）After natural soap base stripping and slicing is melted, the second dispersion liquid and borneol are added, mould molding is poured into after being well mixed, produces
To the basic zirconium phosphate handmade soap；
Wherein raw material includes in parts by mass：Natural 60 parts of soap base, 3 parts of basic zirconium phosphate, 0.1 part of Nano Silver, 0.1 part of silver nitrate, nothing
Suffer from sub- 10 parts of saponin(e, 0.5 part of borneol.
Embodiment 2
（1）Sapindoside is added in deionized water, then it is 0.1mol/L's that silver nitrate and deionized water are configured into concentration
Solution is added thereto, and 20min is stirred at 50 DEG C, obtains the first dispersion liquid；
（2）Particle diameter is added in the first dispersion liquid for 30nm nano silver particles with alpha zirconium phosphate, continues to stir at 50 DEG C
10min, obtains the second dispersion liquid；
（3）After natural soap base stripping and slicing is melted, the second dispersion liquid and borneol are added, mould molding is poured into after being well mixed, produces
To the basic zirconium phosphate handmade soap；
Wherein raw material includes in parts by mass：Natural 80 parts of soap base, 5 parts of basic zirconium phosphate, 0.5 part of Nano Silver, 0.3 part of silver nitrate, nothing
Suffer from sub- 30 parts of saponin(e, 1.5 parts of borneol.
Embodiment 3
（1）Sapindoside is added in deionized water, then it is 0.1mol/L's that silver nitrate and deionized water are configured into concentration
Solution is added thereto, and Tea Polyphenols is added thereafter, and 30min is stirred at 25 DEG C, and it obtains the first dispersion liquid；
（2）Particle diameter is added in the first dispersion liquid for 5nm nano silver particles with alpha zirconium phosphate, continues to stir at 40 DEG C
30min, obtains the second dispersion liquid；
（3）0.1mol/L acetic acid is added into the second dispersion liquid, chitosan is added thereafter, after stirring, NaOH is added and adjusts
It is 5 to save pH value, and the sodium tripolyphosphate that concentration is 1.2wt% is slowly added to thereafter, high-speed stirred is carried out, and forms stable into solution
Particulate；
（4）After natural soap base stripping and slicing is melted, the particulate and borneol added after filtering, washing, it is well mixed after pour into mould into
Type, that is, obtain the basic zirconium phosphate handmade soap；
Wherein raw material includes in parts by mass：Natural 60 parts of soap base, 3 parts of basic zirconium phosphate, 0.1 part of Nano Silver, 0.1 part of silver nitrate, nothing
Suffer from sub- 10 parts of saponin(e, 0.5 part of borneol, 0.5 part of Tea Polyphenols, 1.0 parts of chitosan.
Embodiment 4
（1）Sapindoside is added in deionized water, then it is 0.1mol/L's that silver nitrate and deionized water are configured into concentration
Solution is added thereto, and Tea Polyphenols is added thereafter, and 20min is stirred at 35 DEG C, and it obtains the first dispersion liquid；
（2）Particle diameter is added in the first dispersion liquid for 30nm nano silver particles with alpha zirconium phosphate, continues to stir at 50 DEG C
10min, obtains the second dispersion liquid；
（3）0.1mol/L acetic acid is added into the second dispersion liquid, chitosan is added thereafter, after stirring, NaOH is added and adjusts
It is 6 to save pH value, and the sodium tripolyphosphate that concentration is 1.2wt% is slowly added to thereafter, high-speed stirred is carried out, and forms stable into solution
Particulate；
（4）After natural soap base stripping and slicing is melted, the particulate and borneol added after filtering, washing, it is well mixed after pour into mould into
Type, that is, obtain the basic zirconium phosphate handmade soap；
Wherein raw material includes in parts by mass：Natural 80 parts of soap base, 5 parts of basic zirconium phosphate, 0.5 part of Nano Silver, 0.3 part of silver nitrate, nothing
Suffer from sub- 30 parts of saponin(e, 1.5 parts of borneol, 1.5 parts of Tea Polyphenols, 3.0 parts of chitosan.
Claims (6)
1. a kind of basic zirconium phosphate handmade soap, it is characterised in that：The basic zirconium phosphate handmade soap includes following raw material components：Natural soap base,
Basic zirconium phosphate, Nano Silver, silver nitrate, sapindoside, borneol.
2. basic zirconium phosphate handmade soap according to claim 1, it is characterised in that：The basic zirconium phosphate handmade soap also includes following original
Expect component：Tea Polyphenols, chitosan.
3. basic zirconium phosphate handmade soap according to claim 1, it is characterised in that：The raw material includes in parts by mass：Naturally
60 ~ 80 parts of soap base, 3 ~ 5 parts of basic zirconium phosphate, 0.1 ~ 0.5 part of Nano Silver, 0.1 ~ 0.3 part of silver nitrate, 10 ~ 30 parts of sapindoside, ice
0.5 ~ 1.5 part of piece.
4. basic zirconium phosphate handmade soap according to claim 1, it is characterised in that：The raw material also includes in parts by mass：Tea
0.5 ~ 1.5 part of polyphenol, 1.0 ~ 3.0 parts of chitosan.
5. basic zirconium phosphate handmade soap according to claim 1, it is characterised in that：The Nano Silver particle diameter is 5 ~ 30nm.
6. basic zirconium phosphate handmade soap according to claim 1, it is characterised in that：The basic zirconium phosphate is alpha zirconium phosphate.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710624979.3A CN107312655A (en) | 2017-07-27 | 2017-07-27 | A kind of basic zirconium phosphate handmade soap |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710624979.3A CN107312655A (en) | 2017-07-27 | 2017-07-27 | A kind of basic zirconium phosphate handmade soap |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107312655A true CN107312655A (en) | 2017-11-03 |
Family
ID=60170234
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710624979.3A Pending CN107312655A (en) | 2017-07-27 | 2017-07-27 | A kind of basic zirconium phosphate handmade soap |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107312655A (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105296192A (en) * | 2015-11-19 | 2016-02-03 | 黑龙江大学 | Nano silver added powerful sterilizing and lasting bacteria-resisting laundry detergent and manufacturing method therefor |
| CN106479748A (en) * | 2016-10-10 | 2017-03-08 | 福建省轻工业研究所 | A kind of medical detergent of the silver complex of nanometer containing sapindoside |
| CN106520415A (en) * | 2016-10-10 | 2017-03-22 | 福建省轻工业研究所 | Antidandruff itch-stopping shampoo soap containing sapindus saponin-nano silver complex |
| CN106675866A (en) * | 2017-01-23 | 2017-05-17 | 钟苏 | Zirconium phosphate germicidal soap and preparation method thereof |
| CN106883956A (en) * | 2017-03-24 | 2017-06-23 | 福建师范大学 | A kind of preparation method of pure natural anti-inflammation laundry soap |
-
2017
- 2017-07-27 CN CN201710624979.3A patent/CN107312655A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105296192A (en) * | 2015-11-19 | 2016-02-03 | 黑龙江大学 | Nano silver added powerful sterilizing and lasting bacteria-resisting laundry detergent and manufacturing method therefor |
| CN106479748A (en) * | 2016-10-10 | 2017-03-08 | 福建省轻工业研究所 | A kind of medical detergent of the silver complex of nanometer containing sapindoside |
| CN106520415A (en) * | 2016-10-10 | 2017-03-22 | 福建省轻工业研究所 | Antidandruff itch-stopping shampoo soap containing sapindus saponin-nano silver complex |
| CN106675866A (en) * | 2017-01-23 | 2017-05-17 | 钟苏 | Zirconium phosphate germicidal soap and preparation method thereof |
| CN106883956A (en) * | 2017-03-24 | 2017-06-23 | 福建师范大学 | A kind of preparation method of pure natural anti-inflammation laundry soap |
Non-Patent Citations (1)
| Title |
|---|
| 张玉龙 等: "《功能塑料制品配方设计与加工实例》", 31 January 2006, 国防工业出版社 * |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101498061B (en) | Method for improving antibiosis of silk fibroin material | |
| CN101463145A (en) | Carboxymethyl chitosan / oxidized sodium alginate self-crosslinking antibacterial hydrogel material | |
| CN103898798B (en) | Coated paper | |
| CN106750576A (en) | A kind of Antibacterial composite preservative film and preparation method thereof | |
| CN102105524A (en) | Three-dimensional nanocomposite materials consisting of a polysaccharidic matrix and metallic nanoparticles, preparation and use thereof | |
| CN105360162B (en) | Compound potassium hydrogen persulfate powder disinfectant and preparation method thereof | |
| CN106178125A (en) | A kind of preparation method of nanometer hydroxyapatite chitosan compound microsphere | |
| CN102167936A (en) | Marine organism shell powder paint | |
| CN105038090A (en) | Method for preparing novel antibacterial electronic cigarette appearance material | |
| CN106665651A (en) | Preparation method of stable sepiolite antibacterial powder | |
| CN1124161C (en) | Functional forming materialand its making method | |
| CN104958229A (en) | Walnut shell skin cleaning and moistening scrubbing cream and preparation method thereof | |
| CN107022241A (en) | A kind of Nano Silver and gelatin modified antibacterial prepared Chinese ink and preparation method thereof | |
| JPWO2010103682A1 (en) | Antibacterial agent and method of use | |
| CN110934819A (en) | Special nano-silver sol for gel and preparation method thereof | |
| CN105165892A (en) | Preparation process of antibacterial composition applicable to hygienic paper | |
| CN107312655A (en) | A kind of basic zirconium phosphate handmade soap | |
| CN107177428A (en) | A kind of preparation method of basic zirconium phosphate handmade soap | |
| CN106350219A (en) | Essence microcapsule, medical dressing preparation material and medical dressing | |
| CN107668474A (en) | A kind of nisin peptide nanoparticles and its preparation method and application | |
| CN102242026A (en) | Skin care fancy soap | |
| CN104403249A (en) | Preparation method of antibacterial super absorbent resin | |
| CN105250200B (en) | A kind of preparation method of microcapsule-type eye shadow cream | |
| JP6045942B2 (en) | Solid detergent | |
| CN103262859B (en) | Preparation method of persimmon tannin-modified nanometer silver composite antibacterial powder |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20171103 |
|
| RJ01 | Rejection of invention patent application after publication |