CN102978034A - Antimicrobial nano-silver transparent soap and preparation method thereof - Google Patents
Antimicrobial nano-silver transparent soap and preparation method thereof Download PDFInfo
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Abstract
The invention relates to a skin-care and washing product, and specifically relates to an antimicrobial nano-silver transparent soap and a preparation method thereof. The antimicrobial nano-silver transparent soap comprises a modified nano-silver solution, a surfactant and a cellulose thickening amendment and is prepared according to the following weight parts: 5-15 parts of glycerol, 5-10 parts of propylene glycol, 10-25 parts of sodium palmitoleate, 8-12 parts of sodium cocoate, 5-12 parts of sodium stearate, 10-20 parts of sodium myristate, 8-15 parts of stearic acid, 2-6 parts of EDTA-4Na, 10.5-26.5 parts of a mixed soluble surfactant, 4-12 parts of the modified nano-silver solution, 6-18 parts of the cellulose thickening amendment and 1-5 parts of essence. The soap has pure quality, mild property, rich and meticulous foam and strong decontamination capability, has the function of antisepsis and anti-inflammation, and has very good moistening and protecting effects for human skins.
Description
Technical field
What the present invention relates to is the skin care articles for washing, is specially a kind of antimicrobial nano silver transparent toilet soap and preparation method thereof.
Background technology
Perfumed soap is a kind of traditional articles for washing, also is the necessary articles for use of life that consumers in general almost will use every day, and its quality and quality and human consumer's quality of life quality is closely bound up.Detergent industry has become trend to superior, functionalization development both at home and abroad.The production of antibacterial type perfumed soap, crucial preparation and application at antiseptic-germicide.Its security of the employed antiseptic-germicide of perfumed soap and environment-friendly type require stricter, the continuous increase of realizing along with health of people at present, the sales volume of Antibacterial soaps also is continuous increase, and progressively become a kind of trend, present antibiotic transparent toilet soap normal operation be organic antibacterial agent, deficiency and shortcoming that organic antibacterial agent exists are very obvious, for example for a long time use of organic antibacterial agent can make bacterium produce resistance and ineffective to it gradually, organic antibacterial agent is difficult decomposition generally, easily to environment.
Summary of the invention
The object of the present invention is to provide a kind of antiseptic-germicide that uses to be antimicrobial nano silver transparent toilet soap of inorganic antiseptic nanometer silver and preparation method thereof, thereby improved the transparent toilet soap antimicrobial efficiency.
Technical scheme of the present invention is: a kind of antimicrobial nano silver transparent toilet soap comprises modified Nano silver solution, tensio-active agent and Mierocrystalline cellulose thickening agent, and prepares by following parts by weight:
5～15 parts of glycerine, 5～10 parts of propylene glycol, 10～25 parts in Zoomeric acid sodium, 8～12 parts in cocinic acid sodium, 5～12 parts of sodium stearate, 10～20 parts of Sodium tetradecanoates, 8～15 parts of stearic acid, EDTA-4Na2～6 part, 10.5～26.5 parts in compatibility tensio-active agent, 4～12 parts of modified Nano silver solution, 6～18 parts of Mierocrystalline cellulose thickening agents, 1～5 part in essence;
The preparation method of described modified Nano silver solution is: the silver nitrate solution with 1.8%, in situation about stirring, drip dilute ammonia solution, behind the resolution of precipitate to be generated, add 11 times of deionized water dilutions (with 10 times deionized water dilution), add the tannin aqueous solution 80～120ml (wherein containing the tannin amount is 0.8～1.4 gram) and 60～100ml protective colloid aqueous solution (wherein containing protective colloid 0.8～1.2 gram), heated and stirred to 75 ℃, then constant temperature is 15 ℃, after 20～40 minutes, add properties-correcting agent 7～15 grams, restir can make dispersed stable in 5～10 minutes, the nano-Ag particles mean diameter is the modified Nano silver solution of 5 nanometers;
Described properties-correcting agent is Virahol;
The preparation method of described compatibility tensio-active agent is: the parts by weight of pressing 5～15 parts of 5～10 parts of dehydrated alcohols and deionized waters, after dehydrated alcohol and deionized water mixed, add 0.5～1.5 part in tensio-active agent, under 600～800 rev/mins stirring velocity, stirred 1～3 minute, and both got the compatibility tensio-active agent;
Described tensio-active agent is candy glucoside compound tea saponin;
Described cellulose thickener is carboxymethyl cellulose thickener.
A kind of antimicrobial nano silver transparent toilet soap preparation method, preparation process is:
1) preparation of modified Nano silver: take by weighing reagent by said components, and by the deployed modified Nano silver of the preparation method of above-mentioned modified Nano silver solution, stand-by;
2) preparation of compatibility tensio-active agent: take by weighing tea saponin, dehydrated alcohol, deionized water by said components, and prepare as stated above the compatibility tensio-active agent, stand-by;
3) preparation of defoamer: get 60～90 parts of dehydrated alcohols, 10～30 parts of deionized waters, after under 600～800 rev/mins the rotating speed both being mixed, stirring 1～3 minute, add 1～4 part of ethylene glycol, stirred 5～10 minutes under the equal rotating speed, make the defoamer for the production of transparent toilet soap, stand-by;
4) allotment of perfumed soap composition: take by weighing 5～15 parts of glycerine, 5～10 parts of propylene glycol, 10～25 parts in Zoomeric acid sodium, 8～12 parts in cocinic acid sodium, 5～12 parts of sodium stearate, 10～20 parts of Sodium tetradecanoates, 8～15 parts of stearic acid; , EDTA-4Na2～6 part, 10.5～26.5 parts in compatibility tensio-active agent, 4～12 parts of modified Nano silver solution, 6～18 parts of Mierocrystalline cellulose thickening agents, 1～5 part in essence; In container, take stirring velocity as 200～400 rev/mins, add successively glycerine, propylene glycol, Zoomeric acid sodium, cocinic acid sodium, sodium stearate, Sodium tetradecanoate sodium oleate, stearic acid, be warming up to gradually 70 ℃, add the compatibility tensio-active agent after stirring, dissolving, then add thickening material under the constant temperature, mix, after about 40 minutes, be cooled to gradually 35 ℃, Nano silver solution after adding essence, the modification sprays a small amount of defoamer in whipping process, can enter film after stirring;
5) moulding of perfumed soap: before perfumed soap enters film, mould should be cleaned up, the a small amount of defoamer of rear sprinkling to be dried, then the perfumed soap that melts is slowly poured in the mould, with the bubble on defoamer cancellation surface, room temperature cooling or acceleration cooling in refrigerator, after band cools off fully, perfumed soap is deviate from from mould, with the preservative film parcel, be into soap.
The preparation method of described defoamer is: get 60～90 parts of dehydrated alcohols, 10～30 parts of deionized waters, after under 600～800 rev/mins the rotating speed both being mixed, stirring 1～3 minute, add 1～4 part of ethylene glycol, stirred 5～10 minutes under the equal rotating speed, can make for the production of the used defoamer of transparent toilet soap.
Implement the present invention and have following beneficial effect:
1, antibiotic transparent toilet soap of the present invention is take other plant oil such as glycerine, palmitinic acids as basic raw material, take the inorganic antiseptic nanometer silver as antimicrobial component, in the situation of stirring at low speed, allocate and form, preparation is simple for this, cost is lower, for transparent toilet soap and antibiotic transparent toilet soap provide the blending technology that is suitable for suitability for industrialized production.The perfumed soap of preparing not only quality is pure, character is gentle, and foam is careful abundant, and the dirty ability of dispelling is strong, the effect that also has antisepsis and anti-inflammation is to being 100% with the representative bacterial classification streptococcus aureus of gram-positive microorganism with the colibacillary fungistatic effect of representative bacterial classification of Gram-negative bacteria.Antibacterial type transparent toilet soap of the present invention meets the standard of Transparent soap according to industry standard.Because glycerine occupies a certain amount of ratio in the perfumed soap composition, so the character of perfumed soap is comparatively gentle, the skin-moisturizing, skin effect is remarkable.
2, the nanometer silver selected of antiseptic-germicide, it is a kind of inorganic antiseptic, its Antibacterial Mechanism have following some: 1. combine with DNA, the RNA of cytolemma, cell walls, thymus pyrimidine in the displacement dna molecular double-spiral structure and the hydrogen bond between purine pyrimidine, cytosine(Cyt) and the bird pyrimidine, cause the distortion of DNA of bacteria molecular structure, suppress the synthetic of DNA, RNA, protein, thereby germ is lost activity, reach antibacterial, antibacterial effect.2. the chemical structure of silver has determined that silver has higher catalytic capability, and the reduction potential of high oxidation state silver is high, is enough to make surrounding space to produce atomic oxygen, and atomic oxygen has extremely strong oxidation susceptibility, can sterilize, kill virus.③ causes bacterium dead Yu the combination of Liu base with the combination of proteolytic enzyme Shang De Liu base, loses activity proteolytic enzyme.But after bacterium was killed, silver ions is free from bacterial body again out contact with other floras again, went round and began again and carried out said process, and this also is the reason of silver-colored why lastingly sterilization.
3, promote tissue repair and regeneration, during chronic injury, metal proteinase activity strengthens in the wound, contain in the metalloprotein enzymatic structure Liu base is arranged, activity needs the participation of zine ion, and metal proteinase activity is too high can to destroy somatomedin and cambium, thereby hinders wound healing; And silver can with the metalloprotein enzymatic structure in the combination of Liu base, or by reducing the wound surface zine ion, thereby reduce the metal proteinase activity of transition, promote tissue repair and regeneration.
4, tensio-active agent of the present invention is selected the natural surface active agent tea saponin; it is a kind of natural nonionic surface active agent; it not only has good emulsifying, dispersion, foaming, the function such as moistening; and have anti-inflammatory, analgesia; the pharmacological actions such as impermeabilisation have well moist and defencive function to human body skin.
5, the antibacterial type transparent toilet soap of the present invention preparation washing that not only the possesses general perfumed soap dirty function of dispelling, also have antisepsis and anti-inflammation and other given efficacy, common people use and can play health care, prophylactic effect, and skin has the patient of inflammation, also available its as assisting therapy.
Embodiment
Embodiment 1:
(1) preparation of nanometer silver: get massfraction and be 1.8% silver nitrate solution 100 grams; be to drip dilute ammonia solution in 800～1000 rev/mins the situation at mixing speed, behind the resolution of precipitate to be generated, add 11 times of deionized water dilutions (diluting with 10 times deionized waters); add tannin aqueous solution 10ml and the 8ml protective colloid aqueous solution; heated and stirred to 75 ℃, constant temperature is 15 ℃ again, after 20 minutes; add Virahol 9 grams; continue to stir 20 minutes, Nano silver solution, stand-by.Because of the best proportioning that is prepared with of nanometer silver, be the proportioning of this example, will no longer narrate the preparation method of nanometer silver in the example below, only according to different situations, change the consumption of Nano silver solution.
(2) preparation of compatibility tensio-active agent: claim accurately to take by weighing tea saponin 1 gram, dehydrated alcohol 6 grams, deionized water 8 grams by said components, after dehydrated alcohol and deionized water mixed, add tensio-active agent, under 600～800 rev/mins stirring velocity, stirred 1～3 minute, both got the compatibility tensio-active agent, stand-by.
(3) preparation of defoamer: get 85 parts of dehydrated alcohols, 13 parts of deionized waters are after under 600～800 rev/mins the rotating speed both being mixed, stirring 1～3 minute, add 2 parts of ethylene glycol, stirred 5～10 minutes under the equal rotating speed, make the defoamer for the production of transparent toilet soap, stand-by.The best proportioning that is prepared with because of defoamer, be the proportioning of this example, the defoamer of this proportioning preparation, best results in practical process, so will no longer narrate the preparation method of defoamer in the example below, employed defoamer is the defoamer for preparing in this example.
(4) allotment of perfumed soap composition: according to the method described above, take by weighing 10 parts of glycerine; 6 parts of propylene glycol; 12 parts in Zoomeric acid sodium; 10 parts in cocinic acid sodium; 6 parts of sodium stearate; 12 parts of Sodium tetradecanoates; 8 parts of stearic acid; EDTA-4Na3 part; 6 parts of modified Nano silver solution; 15 parts in compatibility tensio-active agent; 8 parts of Mierocrystalline cellulose thickening agents; 2 parts in essence.Blending means: in container, low whipping speed is in 200～400 rev/mins the situation, add successively glycerine, propylene glycol, Zoomeric acid sodium, cocinic acid sodium, stearic acid, Sodium tetradecanoate, EDTA-4Na, be warming up to gradually 70 ℃, add the compatibility tensio-active agent after stirring, dissolving.Then add thickening material under the constant temperature, mix, after about 40 minutes, be cooled to gradually 35 ℃, Nano silver solution after adding essence, the modification sprays a small amount of defoamer in whipping process, can enter film after stirring.
(5) moulding of perfumed soap: before perfumed soap enters film, mould should be cleaned up, the a small amount of defoamer of rear sprinkling to be dried, then the perfumed soap that melts is slowly poured in the mould, with the bubble on defoamer cancellation surface, room temperature cooling or acceleration cooling in refrigerator, after band cools off fully, perfumed soap is deviate from from mould, with the preservative film parcel, be into soap.
Embodiment 2:
(1) preparation of compatibility tensio-active agent: claim accurately to take by weighing tea saponin 0.8 gram, dehydrated alcohol 8 grams, deionized water 12 grams by said components, after dehydrated alcohol and deionized water mixed, add tensio-active agent, under 600～800 rev/mins stirring velocity, stirred 1～3 minute, both got the compatibility tensio-active agent, stand-by.The preparation of Nano silver solution and defoamer is with embodiment 1.
(2) allotment of perfumed soap composition: according to the method described above, take by weighing 10 parts of glycerine; 6 parts of propylene glycol; 12 parts in Zoomeric acid sodium; 10 parts in cocinic acid sodium; 6 parts of sodium stearate; 12 parts of Sodium tetradecanoates; 8 parts of stearic acid; EDTA-4Na3 part; 6 parts of modified Nano silver solution; 20.8 parts in compatibility tensio-active agent; 8 parts of Mierocrystalline cellulose thickening agents; 3 parts in essence.Blending means: in container, low whipping speed is in 200～400 rev/mins the situation, add successively glycerine, propylene glycol, Zoomeric acid sodium, cocinic acid sodium, stearic acid, Sodium tetradecanoate, EDTA-4Na, be warming up to gradually 70 ℃, add the compatibility tensio-active agent after stirring, dissolving.Then add thickening material under the constant temperature, mix, after about 40 minutes, be cooled to gradually 35 ℃, Nano silver solution after adding essence, the modification sprays a small amount of defoamer in whipping process, can enter film after stirring.
(3) moulding of perfumed soap: before perfumed soap enters film, mould should be cleaned up, the a small amount of defoamer of rear sprinkling to be dried, then the perfumed soap that melts is slowly poured in the mould, with the bubble on defoamer cancellation surface, room temperature cooling or acceleration cooling in refrigerator, after band cools off fully, perfumed soap is deviate from from mould, with the preservative film parcel, be into soap.
Embodiment 3:
(1) preparation of compatibility tensio-active agent: claim accurately to take by weighing tea saponin 0.8 gram, dehydrated alcohol 8 grams, deionized water 12 grams by said components, after dehydrated alcohol and deionized water mixed, add tensio-active agent, under 600～800 rev/mins stirring velocity, stirred 1～3 minute, both got the compatibility tensio-active agent, stand-by.
(2) allotment of perfumed soap composition: according to the method described above, take by weighing 12 parts of glycerine; 9 parts of propylene glycol; 10 parts in Zoomeric acid sodium; 10 parts in cocinic acid sodium; 5 parts of sodium stearate; 12 parts of Sodium tetradecanoates; 8 parts of stearic acid; EDTA-4Na3 part; 10 parts of modified Nano silver solution; 20.8 parts in compatibility tensio-active agent; 6 parts of Mierocrystalline cellulose thickening agents; 3 parts in essence.Blending means: in container, low whipping speed is in 200～400 rev/mins the situation, add successively glycerine, propylene glycol, Zoomeric acid sodium, cocinic acid sodium, stearic acid, Sodium tetradecanoate, EDTA-4Na, be warming up to gradually 70 ℃, add the compatibility tensio-active agent after stirring, dissolving.Then add thickening material under the constant temperature, mix, after about 40 minutes, be cooled to gradually 35 ℃, Nano silver solution after adding essence, the modification sprays a small amount of defoamer in whipping process, can enter film after stirring.
(3) moulding of perfumed soap: before perfumed soap enters film, mould should be cleaned up, the a small amount of defoamer of rear sprinkling to be dried, then the perfumed soap that melts is slowly poured in the mould, with the bubble on defoamer cancellation surface, room temperature cooling or acceleration cooling in refrigerator, after band cools off fully, perfumed soap is deviate from from mould, with the preservative film parcel, be into soap.
Below in conjunction with the embodiments the present invention is had been described in detail; but within the protection domain of spirit of the present invention and claim; those skilled in the art can also make multiple remodeling and modification; the functional materials composition that perhaps adds other; should say that some such remodeling and modification are all within protection scope of the present invention.
Claims (8)
1. an antimicrobial nano silver transparent toilet soap is characterized in that, comprises modified Nano silver solution, tensio-active agent and Mierocrystalline cellulose thickening agent, and prepares by following parts by weight:
5～15 parts of glycerine, 5～10 parts of propylene glycol, 10～25 parts in Zoomeric acid sodium, 8～12 parts in cocinic acid sodium, 5～12 parts of sodium stearate, 10～20 parts of Sodium tetradecanoates, 8～15 parts of stearic acid, EDTA-4Na2～6 part, 4～12 parts of modified Nano silver solution, 6～18 parts of Mierocrystalline cellulose thickening agents, 1～5 part in essence.
2. a kind of antimicrobial nano silver transparent toilet soap according to claim 1, it is characterized in that, the preparation method of modified Nano silver solution is: the silver nitrate solution with 1.8%, in situation about stirring, drip dilute ammonia solution, behind the resolution of precipitate to be generated, add 11 times of deionized water dilutions (with 10 times deionized water dilution), add the tannin aqueous solution 80～120ml (wherein containing the tannin amount is 0.8～1.4 gram) and 60～100ml protective colloid aqueous solution (wherein containing protective colloid 0.8～1.2 gram), heated and stirred to 75 ℃, then constant temperature is 15 ℃, after 20～40 minutes, add properties-correcting agent 7～15 grams, restir can make dispersed stable in 5～10 minutes, the nano-Ag particles mean diameter is the modified Nano silver solution of 5 nanometers;
3. a kind of antimicrobial nano silver transparent toilet soap according to claim 2 is characterized in that, described properties-correcting agent is Virahol;
4. a kind of antimicrobial nano silver transparent toilet soap according to claim 1, it is characterized in that, the preparation method of described compatibility tensio-active agent is: the parts by weight of pressing 5～15 parts of 5～10 parts of dehydrated alcohols and deionized waters, after dehydrated alcohol and deionized water mixed, add 0.5～1.5 part in tensio-active agent, under 600～800 rev/mins stirring velocity, stirred 1～3 minute, both got the compatibility tensio-active agent;
5. a kind of antimicrobial nano silver transparent toilet soap according to claim 4 is characterized in that, described tensio-active agent is candy glucoside compound tea saponin;
6. a kind of antimicrobial nano silver transparent toilet soap according to claim 1 is characterized in that, described cellulose thickener is carboxymethyl cellulose thickener.
7. antimicrobial nano silver transparent toilet soap preparation method is characterized in that preparation process is:
1) preparation of modified Nano silver: take by weighing reagent by said components, and by the deployed modified Nano silver of the preparation method of above-mentioned modified Nano silver solution, stand-by;
2) preparation of compatibility tensio-active agent: take by weighing tea saponin, dehydrated alcohol, deionized water by said components, and prepare as stated above the compatibility tensio-active agent, stand-by;
3) preparation of defoamer: get 60～90 parts of dehydrated alcohols, 10～30 parts of deionized waters, after under 600～800 rev/mins the rotating speed both being mixed, stirring 1～3 minute, add 1～4 part of ethylene glycol, stirred 5～10 minutes under the equal rotating speed, make the defoamer for the production of transparent toilet soap, stand-by;
4) allotment of perfumed soap composition: take by weighing 5～15 parts of glycerine, 5～10 parts of propylene glycol, 10～25 parts in Zoomeric acid sodium, 8～12 parts in cocinic acid sodium, 5～12 parts of sodium stearate, 10～20 parts of Sodium tetradecanoates, 8～15 parts of stearic acid; , EDTA-4Na2～6 part, 4～12 parts of modified Nano silver solution, 6～18 parts of Mierocrystalline cellulose thickening agents, 1～5 part in essence; In container, take stirring velocity as 200～400 rev/mins, add successively glycerine, propylene glycol, Zoomeric acid sodium, cocinic acid sodium, sodium stearate, Sodium tetradecanoate sodium oleate, stearic acid, be warming up to gradually 70 ℃, add the compatibility tensio-active agent after stirring, dissolving, then add thickening material under the constant temperature, mix, after about 40 minutes, be cooled to gradually 35 ℃, Nano silver solution and deionized water after adding essence, the modification spray a small amount of defoamer in whipping process, can enter film after stirring;
5) moulding of perfumed soap: before perfumed soap enters film, mould should be cleaned up, the a small amount of defoamer of rear sprinkling to be dried, then the perfumed soap that melts is slowly poured in the mould, with the bubble on defoamer cancellation surface, room temperature cooling or acceleration cooling in refrigerator, after band cools off fully, perfumed soap is deviate from from mould, with the preservative film parcel, be into soap.
8. a kind of antimicrobial nano silver transparent toilet soap preparation method according to claim 7, it is characterized in that, the preparation method of described defoamer is: get 60～90 parts of dehydrated alcohols, 10～30 parts of deionized waters, after under 600～800 rev/mins the rotating speed both being mixed, stirring 1～3 minute, add 1～4 part of ethylene glycol, stirred 5～10 minutes under the equal rotating speed, can make for the production of the used defoamer of transparent toilet soap.
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| CN103695217A (en) * | 2013-12-20 | 2014-04-02 | 广州市浪奇实业股份有限公司 | Tea saponin washing soap |
| CN103999873A (en) * | 2014-06-18 | 2014-08-27 | 杜一挺 | Nano-silver antibacterial agent and preparation method thereof |
| CN104403844A (en) * | 2014-12-09 | 2015-03-11 | 韦爱琴 | Bactericidal and aromatic washing soap |
| CN104498240A (en) * | 2014-12-09 | 2015-04-08 | 韦爱琴 | Skincare washing soap |
| CN104498239A (en) * | 2014-12-09 | 2015-04-08 | 韦爱琴 | Washing soap capable of sterilizing and moistening skin |
| CN104498241A (en) * | 2014-12-09 | 2015-04-08 | 韦爱琴 | Washing soap capable of protecting hands and sterilizing |
| CN104498238A (en) * | 2014-12-09 | 2015-04-08 | 韦爱琴 | High-efficient sterilization washing soap |
| CN106978284A (en) * | 2017-05-03 | 2017-07-25 | 东莞市文嘉乐商贸有限公司 | A kind of how both effectiveness essential oil nourishes soap |
| CN107574028A (en) * | 2017-09-13 | 2018-01-12 | 安徽农业大学 | A kind of nanometer silver antimicrobial Wool cleaning agent |
| CN107893001A (en) * | 2017-11-29 | 2018-04-10 | 深圳市地藏心文化传播有限公司 | A kind of natural handmade soap of the extract solution containing vine tea |
| CN109135972A (en) * | 2018-09-21 | 2019-01-04 | 杭州萧山钱江洗涤用品有限公司 | Perfumed soap and its production technology |
| CN109536312A (en) * | 2018-12-28 | 2019-03-29 | 天津金汇药业集团有限公司 | A kind of coconut oil crystal soap |
| CN109971569A (en) * | 2019-03-29 | 2019-07-05 | 电子科技大学中山学院 | Nano-silver transparent amino acid handmade soap and preparation method thereof |
| CN112300878A (en) * | 2019-07-25 | 2021-02-02 | 宋敬镐 | Transparent soap with three-dimensional information display function and manufacturing method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103695217A (en) * | 2013-12-20 | 2014-04-02 | 广州市浪奇实业股份有限公司 | Tea saponin washing soap |
| CN103695217B (en) * | 2013-12-20 | 2016-08-17 | 广州市浪奇实业股份有限公司 | Tea saponin laundry soap |
| CN103999873A (en) * | 2014-06-18 | 2014-08-27 | 杜一挺 | Nano-silver antibacterial agent and preparation method thereof |
| CN104403844A (en) * | 2014-12-09 | 2015-03-11 | 韦爱琴 | Bactericidal and aromatic washing soap |
| CN104498240A (en) * | 2014-12-09 | 2015-04-08 | 韦爱琴 | Skincare washing soap |
| CN104498239A (en) * | 2014-12-09 | 2015-04-08 | 韦爱琴 | Washing soap capable of sterilizing and moistening skin |
| CN104498241A (en) * | 2014-12-09 | 2015-04-08 | 韦爱琴 | Washing soap capable of protecting hands and sterilizing |
| CN104498238A (en) * | 2014-12-09 | 2015-04-08 | 韦爱琴 | High-efficient sterilization washing soap |
| CN106978284A (en) * | 2017-05-03 | 2017-07-25 | 东莞市文嘉乐商贸有限公司 | A kind of how both effectiveness essential oil nourishes soap |
| CN107574028A (en) * | 2017-09-13 | 2018-01-12 | 安徽农业大学 | A kind of nanometer silver antimicrobial Wool cleaning agent |
| CN107893001A (en) * | 2017-11-29 | 2018-04-10 | 深圳市地藏心文化传播有限公司 | A kind of natural handmade soap of the extract solution containing vine tea |
| CN109135972A (en) * | 2018-09-21 | 2019-01-04 | 杭州萧山钱江洗涤用品有限公司 | Perfumed soap and its production technology |
| CN109536312A (en) * | 2018-12-28 | 2019-03-29 | 天津金汇药业集团有限公司 | A kind of coconut oil crystal soap |
| CN109971569A (en) * | 2019-03-29 | 2019-07-05 | 电子科技大学中山学院 | Nano-silver transparent amino acid handmade soap and preparation method thereof |
| CN112300878A (en) * | 2019-07-25 | 2021-02-02 | 宋敬镐 | Transparent soap with three-dimensional information display function and manufacturing method thereof |
| CN113493725A (en) * | 2021-06-21 | 2021-10-12 | 广东菁萃生物科技有限公司 | Mild non-irritating nursing handmade soap and preparation method thereof |
| NL2036824B1 (en) * | 2023-04-25 | 2024-07-16 | Univ Taishan | Preparation method of rust-transformed waterproof coating |
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Application publication date: 20130320 |