CN107308775A - Polychlorinated biphenyls efficiently removes composition in air - Google Patents

Polychlorinated biphenyls efficiently removes composition in air Download PDF

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Publication number
CN107308775A
CN107308775A CN201710660168.9A CN201710660168A CN107308775A CN 107308775 A CN107308775 A CN 107308775A CN 201710660168 A CN201710660168 A CN 201710660168A CN 107308775 A CN107308775 A CN 107308775A
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extract
parts
air
polychlorinated biphenyls
leaf
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王婧宁
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N65/00Biocides, pest repellants or attractants, or plant growth regulators containing material from algae, lichens, bryophyta, multi-cellular fungi or plants, or extracts thereof
    • A01N65/40Liliopsida [monocotyledons]
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/70Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/91Bacteria; Microorganisms
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2258/00Sources of waste gases
    • B01D2258/06Polluted air

Abstract

The present invention relates to air-treatment field, in particular it relates to which Polychlorinated biphenyls efficiently removes composition in a kind of air.Polychlorinated biphenyls, which efficiently removes composition, in the air at least includes metal flocbed and POROUS TITANIUM silicon layer;The preparing raw material of the metal flocbed, in parts by weight, at least including 30~60 parts of hydroxymethyl cellulose;10~30 parts of chitin fiber element;5~20 parts of cetyl trimethylammonium bromide;5~25 parts of plant extracts;0.1~0.5 part of graphene oxide.

Description

Polychlorinated biphenyls efficiently removes composition in air
Technical field
The present invention relates to air-treatment field, in particular it relates to the efficient removal group of Polychlorinated biphenyls in a kind of air Compound.
Background technology
Polychlorinated biphenyls (PCBs) is international convention《Convention of Stockholm on persistence organic pollutant》In it is first batch of One of 12 kinds of persistence organic pollutants controlled the need for announcement.Persistence organic pollutant abbreviation POPs, refers to that a class has There are the physicochemical properties such as half volatile, difficult degradation, fat-solubility, the diffusion mobility of remote even Global Scale can be carried out, and lead to Cross food chain and concentrate accumulation in vivo, the organic pollution of toxic effect is produced to human body and ecological environment.
PCBs, by being volatized into air, directly pollution is caused to atmospheric environment during using and handling. PCBs pollutions are initially, under the line to mid latitudes, but to have had been found that PCBs's in the arctic and other far zones at present " footprint ", the among these effect of propagation in atmosphere is not sneezed at.PCBs in air mainly passes through two kinds of approach " purification ":(l) it is straight Connect photodissociation and with the Free Radical such as hydroxyl.Especially it is the most notable with the effect of hydroxyl among these;(2) rain-out and dry and wet are heavy Drop.Hydrophobic organic compound is main in an atmosphere to be existed in two kinds of forms of gaseous state and ADSORPTION STATE, regardless of whether being rain-out or dry Wet deposition, can be such that the PCBs that gaseous state or particle are fettered is shifted from air to water body and soil.
Thus, it is also very desirable to Polychlorinated biphenyls efficiently removes composition in a kind of air, has solved air pollution problems inherent.
The content of the invention
In order to solve the above problems, first aspect present invention provides Polychlorinated biphenyls in a kind of air and efficiently removes composition, Polychlorinated biphenyls, which efficiently removes composition, in the air at least includes metal flocbed and POROUS TITANIUM silicon layer;
The preparing raw material of the metal flocbed, in parts by weight, at least includes
As a kind of preferred technical scheme of the present invention, the preparing raw material of the metal flocbed, in parts by weight, at least Including
As a kind of preferred technical scheme of the present invention, the plant extracts at least includes following raw material:
Ginkgo biloba p.e, Senna P.E, Rosmarinus officinalis extract, Shitake Mushroom P.E, mulberry-leaf extract, honeysuckle carry Take thing, hawthorne leaf P.E, extract of soybean, kudzu root extract, wolfberry fruit extract, Astragalus Root P.E, Passion flower P.E, stone Pomegranate extract, yam extract, Herb Gynostemmae Pentaphylli extract, tartary buckwheat extract, purple daisy extract.
As a kind of preferred technical scheme of the present invention, the plant extracts at least includes following raw material:
20~50 parts of ginkgo biloba p.e, 10~25 parts of Senna P.E, 5~15 parts of Rosmarinus officinalis extract, mushroom are carried 3~20 parts of thing, 5~15 parts of mulberry-leaf extract, 3~18 parts of Honegsukle flower P.E, 10~20 parts of hawthorne leaf P.E, soybean is taken to carry 5~15 parts of thing, 5~20 parts of kudzu root extract, 1~10 part of wolfberry fruit extract, 10~15 parts of Astragalus Root P.E, passionflower is taken to extract 5~30 parts of thing, 1~10 part of Punica granatum L. extract, 1~20 part of yam extract, 5~10 parts of Herb Gynostemmae Pentaphylli extract, tartary buckwheat extract 3 ~17 parts, 1~15 part of purple daisy extract.
As a kind of preferred technical scheme of the present invention, also include ethylene glycol in the metal flocbed.
As a kind of preferred technical scheme of the present invention, the POROUS TITANIUM silicon layer is TS-1.
As a kind of preferred technical scheme of the present invention, the POROUS TITANIUM silicon layer is the POROUS TITANIUM handled through silane coupler Silicon layer.
Second aspect of the present invention provides Polychlorinated biphenyls in a kind of air and efficiently removes the preparation method of composition, including with Lower step:
First POROUS TITANIUM silicon layer is poured into mould, metal flocbed is then being added into mould, air is obtained after drying Middle Polychlorinated biphenyls efficiently removes composition.
Third aspect present invention provides the application method that Polychlorinated biphenyls in air efficiently removes composition, and it is directly put Put in atmosphere.
The fourth aspect of the present invention provides Polychlorinated biphenyls in air and efficiently removes composition answering in environmentally friendly, catalytic field With.
The above-mentioned of the application and other features, aspect and advantage is more readily understood with reference to described further below.
Embodiment
The participation in the election detailed description of the invention below for being preferable to carry out method and including embodiment this hair can be more easily understood Bright content.Unless otherwise defined, all technologies used herein and scientific terminology have common with art of the present invention The identical implication that technical staff is generally understood that.When there is contradiction, the definition in this specification is defined.
As used herein term " by ... prepare " it is synonymous with "comprising".Term "comprising" used herein, " comprising ", " having ", " containing " or its any other deformation, it is intended that cover including for non-exclusionism.For example, the combination comprising listed elements Thing, step, method, product or device are not necessarily limited to those key elements, but can include not expressly listed other key elements or Such a composition, step, method, product or the intrinsic key element of device.
Conjunction " Consists of " excludes any key element do not pointed out, step or component.If be used in claim, this Phrase will make claim be closed, it is not included the material in addition to materials of those descriptions, but relative normal Except rule impurity.When being rather than immediately following in the clause that phrase " Consists of " appears in claim main body after theme, It is only limited to the key element described in the clause;Other key elements are not excluded outside as the overall claim.
Equivalent, concentration or other values or parameter are excellent with scope, preferred scope or a series of upper limit preferred values and lower limit During the Range Representation that choosing value is limited, this, which is appreciated that, specifically discloses by any range limit or preferred value and any scope All scopes that any pairing of lower limit or preferred value is formed, regardless of whether whether the scope separately discloses.For example, when open During scope " 1 to 5 ", described scope should be interpreted as including scope " 1 to 4 ", " 1 to 3 ", " 1 to 2 ", " 1 to 2 and 4 to 5 ", " 1 to 3 and 5 " etc..When number range is described herein, unless otherwise indicated, otherwise the scope is intended to include its end Value and all integers and fraction within the range.
Singulative includes plural number and object is discussed, unless the context clearly dictates otherwise." optional " or it is " any It is a kind of " refer to that the item or event that describe thereafter may or may not occur, and the description include situation that event occurs and The situation that event does not occur.
Approximate term in specification and claims is used for modifying quantity, represents that the present invention is not limited to this specific Quantity, includes the part of the amendment of the acceptable change without cause related basic function close to the quantity.Phase Answer, modify a numerical value with " about ", " about " etc., mean that the invention is not restricted to the exact numerical.In some examples, approximately Term likely corresponds to the precision of the instrument of measured value.In present specification and claims, scope is limited can be with Combine and/or exchange, these scopes include all subranges contained therebetween if not stated otherwise.
In addition, the indefinite article " one kind " and " one " before key element of the present invention or component are to key element or the quantitative requirement of component (i.e. occurrence number) unrestriction.Therefore " one " or " one kind " should be read as including one or at least one, and odd number The key element or component of form also include plural form, unless the obvious purport of the quantity refers to singulative.
First aspect present invention provides Polychlorinated biphenyls in a kind of air and efficiently removes Polychlorinated biphenyls in composition, the air Efficiently removing composition at least includes metal flocbed and POROUS TITANIUM silicon layer;
The preparing raw material of the metal flocbed, in parts by weight, at least includes
As a kind of preferred technical scheme of the present invention, the preparing raw material of the metal flocbed, in parts by weight, at least Including
Hydroxymethyl cellulose
In the present invention, used hydroxymethyl cellulose obtains to be commercially available, is purchased from Shijiazhuang Mao Qing trade Co., Ltds.
Chitin fiber element
In the present invention, used chitin fiber element obtains to be commercially available, and being purchased from the sea blue biological products in Qingdao has company.
Cetyl trimethylammonium bromide
In the present invention, used cetyl trimethylammonium bromide obtains to be commercially available, is purchased from Chinese medicines group.
Graphene oxide
In the present invention, used graphene oxide obtains to be commercially available, is purchased from Suzhou Heng Qiu graphenes Co., Ltd.
Plant extracts
In the present invention, the plant extracts at least includes following raw material:
Ginkgo biloba p.e, Senna P.E, Rosmarinus officinalis extract, Shitake Mushroom P.E, mulberry-leaf extract, honeysuckle carry Take thing, hawthorne leaf P.E, extract of soybean, kudzu root extract, wolfberry fruit extract, Astragalus Root P.E, Passion flower P.E, stone Pomegranate extract, yam extract, Herb Gynostemmae Pentaphylli extract, tartary buckwheat extract, purple daisy extract.
As a kind of preferred technical scheme of the present invention, the plant extracts at least includes following raw material:
20~50 parts of ginkgo biloba p.e, 10~25 parts of Senna P.E, 5~15 parts of Rosmarinus officinalis extract, mushroom are carried 3~20 parts of thing, 5~15 parts of mulberry-leaf extract, 3~18 parts of Honegsukle flower P.E, 10~20 parts of hawthorne leaf P.E, soybean is taken to carry 5~15 parts of thing, 5~20 parts of kudzu root extract, 1~10 part of wolfberry fruit extract, 10~15 parts of Astragalus Root P.E, passionflower is taken to extract 5~30 parts of thing, 1~10 part of Punica granatum L. extract, 1~20 part of yam extract, 5~10 parts of Herb Gynostemmae Pentaphylli extract, tartary buckwheat extract 3 ~17 parts, 1~15 part of purple daisy extract.
As a kind of preferred technical scheme of the present invention, the plant extracts at least includes following raw material:
45 parts of ginkgo biloba p.e, 20 parts of Senna P.E, 10 parts of Rosmarinus officinalis extract, 15 parts of Shitake Mushroom P.E, mulberry 10 parts of leaf extract, 15 parts of Honegsukle flower P.E, 15 parts of hawthorne leaf P.E, 10 parts of extract of soybean, 16 parts of kudzu root extract, 7 parts of wolfberry fruit extract, 12 parts of Astragalus Root P.E, 20 parts of Passion flower P.E, 8 parts of Punica granatum L. extract, 13 parts of yam extract, strand Blue 8 parts of the extract of stock, 13 parts of tartary buckwheat extract, 12 parts of purple daisy extract.
Ginkgo biloba p.e
Ginkgo leaf, is the dried leaf of Ginkgoaceae plant Ginkgo biloba.Autumn leaf is harvested when still green, is dried in time.It is generally artificial Cultivation.Cultivation area north to Liaoning, Nan Da Guangdong, from the east of Zhejiang, west reaches Shaanxi, Gansu, southwest to Sichuan, Guizhou, Yunnan etc. Ground.With promoting blood circulation and removing blood stasis, remove obstruction in channels to relieve pain, astringe the lung and relieving asthma, change effect of turbid lipid-loweringing.For obstruction of collaterals by blood stasis, chest impediment and cardialgia, middle windage yaw Paralysis, deficiency syndrome of the lung cough and asthma, hyperlipidemia.
Ginkgo leaf is fallen leaves megaphanerophyte, and high 30~40 meters, complete stool is hairless, and the diameter of a cross-section of a tree trunk 1.3 meters above the ground is up to 4 meters, and treelet bark is closely smooth, shallow Grey, the skin taupe of big tree, irregular lobe has long shoot and slow-growing away from shape brachyplast.Leaf alternate, is radiated on long shoot Shape is scattered, on brachyplast 3~5 pieces into fasciation shape, have elongated petiole, fan-shaped, how much two sides light green has in broad apical margin Incise or 2 split, wide by 5~8 (~15) centimetre, the most forked and bad handkerchief thready pulses of tool.Dioecism, dilute homophyletic, globe daisy is singly born in short The axil of branch;Male cone Cheng amentum shapes, stamen is most, respectively there is 2 flower pesticide;Female cone has long stalk, and two forks (dilute 3 are often divided at stalk end ~5 fork), fork life 1 have plate-like pearl support ovule, normal 1 Ovule Development into development seed.9~October of seed maturity.
The many fold of this product are broken, and complete person is in sector, long 3~12cm, wide 5~15cm.Yellow green or sundown, on Edge is in irregular wavy bending, and some centres are recessed, deep person up to leaf length 4/5.Have two forked parallel veins, it is thin and close, Glabrous, easy longitudinal tear.Phyllopodium wedge shape, 2~8cm of petiole length.Body is light.Gas is micro-, mildly bitter flavor.
In the application, the ginkgo biloba p.e obtains to be commercially available, is purchased from Xi'an day Biotechnology Ltd..
Senna P.E
Folium sennae, different name senna, rush down leaf, soaked bamboo leaf source for the narrow leaf cassia angustifolia of legume or cassia acutifolia Delile leaflet.
Narrow leaf cassia angustifolia is in long avette or ovum shape lanceolar, long 1.5~5cm, wide 0.4~2cm, full edge, the anxious point of end of blade, phyllopodium It is slightly asymmetric.Narrow leaf cassia angustifolia is draft shape undershrub, up to 1 meter.Even numbers winglike compound leaf, 5~8 pairs of leaflet has short handle;Stipule ovum Shape lanceolar, it is long 2~4 millimeters;Vanelets ovum shape lanceolar is to wire lanceolar, and the anxious point of tip, base portion is slightly asymmetric, it is hairless or It is several hairless.Raceme axillary, spends 6~14;Bennet base portion has an avette bract, Yi Luo;Sepal 5, long avette;Petal 5, Obovate, yellow;Stamen 10, the small shape in 3 pieces of top, infertility, 4 pieces of center is isometric, and bottom 3 pieces are bent downwardly, and flower pesticide is slightly in four It is square, base portion flechette-type, Room 4;Gynoecium bending such as sickle, ovary tool handle, by thin hair.Blade face light green color, blade back celadon, micro- hairiness Young pilose antler, no embossing, matter is thin and crisp.With drying, leaf narrow point, piece is big, complete, color is green, obstruct less, be preferred without silt particle person, and leaf is small, color It is yellow, have stalk, crush more, having silt particle, person is secondary.Upper surface yellow green, lower surface chartreuse, hairless or near hairless, vein is slightly grand Rise.Keratin.Gas is faint and special, mildly bitter flavor, slightly sticky.Cassia acutifolia Delile is in lanceolar or long avette, is slightly crimped, the short point of end of blade Or dimpling, phyllopodium is asymmetric, and two sides has thin undercoat fine and soft.
Cassia Angustifolia leaf contains Sennosides (sennoside) A, B, C, D, Chrysophanol (crysophanol), rheum emodin (emodin), Physcion (physcion), 3- methyl -8- Shens epoxide -2- acetyl group -1,6- naphthalenediol -6-O- β-D- Portugals (kaempferol) containing Kaempferol in grape glucoside (tinnevellinglucoside), leaflet.
Cassia acutifolia Delile leaf contains Sennoside A, B, C, D, rheum emodin, Physcion, Chrysophanol.Contain Kaempferol in tender leaf.This Outside, congener ear leaf cassia angustifolia (Cassiaauriculata) leaf (leucoanthocyanins) containing grey glucoside, bark contains polyphenol Oxidizing ferment (polyphenoloxidase).
In the application, the Senna P.E obtains to be commercially available, is purchased from Xi'an day Biotechnology Ltd..
Rosmarinus officinalis extract
Rosemary, Classification system (Rosmarinus officinalis) Labiatae shrub.Shrub, up to 2 meters.Stem and old Branch cylinder, cortex dark gray, irregular lobe, bulk is peeled off, and the prismatic of sprout four is close by white starlike fine hair.
Leaf is usually grown thickly on branch, has extremely short handle or stockless, and blade is linear, long 1-2.5 centimetres, wide 1-2 millimeters, tip Blunt, base portion is gradually narrow, and full edge is rearwardly crimped, and keratin slightly has gloss above, near hairless, below the close starlike fine hair by white.
Hua Jinwu obstructs, to life, and minority is gathered in the top composition raceme of brachyplast;Bract is small, has handle.Calyx ovate clock Shape, is about 4 millimeters, outside is close by white starlike fine hair and body of gland, and inner face is hairless, 11 arteries and veins, two lips, upper lip subcircular, full edge Or have 3 very short teeth, the tooth of lower lip 2, tooth oval shape triangle.Corolla bluish violet, it is long not as good as 1 centimetre, it is outer by thin pubescence, inner face Hairless, corolla tube is slightly overhanging, and the lip of limb two, upper lip is directly stretched, 2 it is shallow split, sliver oval, lower lip is roomy, and 3 split, and middle sliver is maximum, Indent, has a down dip, and edge is dentation, and base portion, which is hung, shortens handle into, side sliver Long Circle.2 pieces of developments of stamen, are born under corolla lower lip There is 1 downward small tooth in the middle part of side, filigree, coyote hole is parallel, and only Room 1 can educate.Style is elongated, exceeds well over stamen, and tip unequal 2 is shallow Split, sliver bores shape, rear sliver is short.Floral disc flat-top, has equal sliver.Ovary sliver and floral disc sliver alternate.November at florescence.
Rosemary likes temperature climate, but slow-growing in the TaiWan, China level land megathermal period, and winter does not have the temperature of cold current Relatively it is adapted to its growth, moisture supply aspect inherently belongs to keratin due to rosemary blade, drought-enduring compared with energy, therefore the soil of plantation Earth is good advantageous in growing to enable draining rich in chiltern, it should be noted that rosemary is slow-growing, therefore regeneration It is indifferent.
In the application, the Rosmarinus officinalis extract obtains to be commercially available, is purchased from Xi'an day Biotechnology Ltd..
Shitake Mushroom P.E
Mushroom, also known as flower mushroom, mushroom, fragrant letter, fragrant bacterium, dried mushroom, fragrant wild rice, are the fructification of Pleurotaceae plant mushroom.Mushroom It is second-biggest-in-the-world edible mushroom, is also one of China's special product, in the title among the people for have " mountain delicacy ".It is that one kind is grown on timber Fungi.Delicious flavour, fragrance make people mentally refreshing is nutritious.Mushroom is rich in vitamin B complex, iron, potassium, provitamin D (after Exposure to Sunlight Change into vitamin D), it is sweet, it is mild-natured.Anorexia is cured mainly, few gas is weak.
Mushroom have the title of the king of mountain delicacy, is high protein, low-fat nutritional health food.Chinese dynasties physician is to perfume (or spice) Mushroom has famous discussion.Modern medicine and nutrition are deepened continuously research, and the medical value of mushroom is also constantly exploited.In mushroom Quantitative Determination of Ergosterol is very high, effective to preventing and treating rickets;Lentinan (β~1,3 glucans) can strengthen cell immunocompetent, from And suppress the growth of cancer cell;Mushroom contains more than 40 kinds of enzyme of six big enzymes, can correct human chitinase deficiency disease;Fat in mushroom Fat institute fatty acids, reduce blood fat beneficial to human body.
In the application, the Shitake Mushroom P.E obtains to be commercially available, is purchased from Xi'an day Biotechnology Ltd..
Mulberry-leaf extract
Mulberry leaf, (Mulberry Leaf), scientific name:Folium Mori.Chinese medicine name, is the dried leaf of moraceae plants mulberry, is The conventional food of silkworm, also known as mulberry, thorn mulberry, mulberry fruit tree, yellow wood leaf etc., mulberry tree, mulberry yield are planted in China north and south various regions extensively It is abundant.The Major Foods of silkworm.Intact leaf is in or width egg shape to be about 15 centimetres, and wide about 10 centimetres, petiole is about 4 centimetres, blade Base portion is heart-shaped, the micro- point in top, and there are sawtooth, vein Mi Shengbai pubescences in edge.The thicker dirty-green of old leaf.Tender leaf is relatively thin, yellow green. Matter is crisp easily, holds prick the hand.Gas is light, and mildly bitter flavor is puckery.
Machaka or dungarunga, high 3-15m.Bark lark or yellowish-brown, shallow lobe, sprout hairiness.Leaf alternate, ovum Shape grows 6~15cm, wide 4~12cm to wealthy avette.Tip is sharp or blunt, and there is bastard at basal circular or near heart-shaped, edge, above nothing Hair, it is glossy, below green, have hairiness between thin hair, arteries and veins on arteries and veins;1~2.5cm of petiole length.Dioecism, flower bud inflorescence armpit It is raw;Male inflorescence is caducous;Female inflorescence 1~2cm of length, style not substantially or nothing, column cap 2.
Intact leaf is about 15 centimetres, wide about 10 centimetres, petiole is about 4 centimetres, blade in avette, width egg shape, heart etc. Base portion is heart-shaped, the micro- point in top, and there are sawtooth, vein Mi Shengbai pubescences in edge.The thicker yellow green of old leaf.Tender leaf is relatively thin, dirty-green. Matter is crisp frangible, holds prick the hand.Gas is light, and mildly bitter flavor is puckery.It is medicinal to be generally acknowledged that after frost that the person's of adopting matter is good.Purple is black when collective fruits (mulberry fruit) is ripe Color, red or milky.4~May of florescence, 6~July of fruiting period.
Many shrinkages, are crushed.Complete person has yellow green or light yellowish brown above handle, blade, and what is had has small verruca;Following table Complexion is shallower, and vein projection, scun is netted, by thin hair on arteries and veins, arteries and veins base tool tuft.Matter is crisp.Gas is micro-, lightly seasoned, slight bitter, puckery.
Main component:
1. flavonoids
Flavone compound accounts for the 1%~3% of mulberry leaf dry weight in mulberry leaf, is that the higher class of cauline leaf content is planted in plant kingdom Thing.South Korea and Japanese scholars isolate 9 kinds of flavonoids from mulberry leaf, mainly rutin sophorin (rutin), Quercetin, isoquercitrin, The compounds such as the glucosides of Quercetin -3- three.
2. alkaloid
Alkaloid is the main active ingredient of mulberry leaf, and Japanese scholars Asano etc. (1994) isolates a variety of many from mulberry leaf Hydroxyl alkaloid, including DNJ (1-DNJ), N- methyl isophthalic acids-DNJ (N-Me-DNJ), 2- oxygen-α-D gala pyranoses Glycosides -1-DNJ, fagomine, Isosorbide-5-Nitrae-dideoxy-Isosorbide-5-Nitrae-imido grpup-D-R alcohol, Isosorbide-5-Nitrae-dideoxy-Isosorbide-5-Nitrae-imido grpup - (2- oxygen-β-D- glucopyranosides)-D-R alcohol and 1 α, 2 β, 3 α, 4 β-tetrahydroxy-go first gelsemium henbane alkane (to go first gelsemium henbane Alkali) etc. 7 kinds of alkaloids.Wherein DNJ (1-DNJ) is in plant kingdom, and only mulberry leaf are exclusive.
3. phytosterol
Content of phytosterol is higher than general plant 3~4 times in mulberry leaf.Mainly cupreol (β-sitosterol), beans Sterol (Stigmasterol), campesterol (Camposterol), cupreol β-D-Glucose glycosides (β-sitolsterol β- D-glucoside), Lupeol (lupeol, Lupeol), meso inositol (Myoinositol), molting hormone, Inokosterone (Inokosterone), ecdysterone (Ecdysterone) etc..
4. γ-aminobutyric acid (γ-aminobutyric acid)
The γ-aminobutyric acid (average content is 226mg/100g) enriched in mulberry leaf is noticeable, and γ-aminobutyric acid is by paddy Propylhomoserin is transformed, and gamma-glutamic acid content highest (2323mg/100g) in mulberry leaf.
5. mulberry leaf polysaccharide
Mulberry leaf polysaccharide is rich in mulberry leaf, with the significant hypoglycemic and suppression elevated effect of blood fat.
In the application, the mulberry-leaf extract obtains to be commercially available, is purchased from Xi'an day Biotechnology Ltd..
Honegsukle flower P.E
Honeysuckle, also known as honeysuckle (scientific name:Lonicera japonica)." honeysuckle " one is come from《Compendium of Materia Medica》, by Opened at the beginning of honeysuckle flowers as white, after switch to yellow, hence obtain one's name honeysuckle.Medicinal material honeysuckle is Caprifoliaceae woodbine honeysuckle And congener dry flower or with the flower just opened.
Honeysuckle, March blooms, and five go out, micro-perfume, and redly, then color is white by Hua Chukai for the base of a fruit, through one, two days then color it is yellow, it is therefore named Honeysuckle.Again because a base of a fruit two is spent, two pistils are visited outside, in pairs, are never left each other, and shape is such as male female associated, and like mandarin duck To dance, therefore there is the title of mandarin duck rattan.
This kind be most significantly characterized by big shape lobate bract.It in person somewhat like Lonicera confusa, but that The bract of individual kind is narrow thin rather than lobate, the close raw pubescence of calyx tube, the pubescence of the close raw curling of sprig, significantly different with this kind.This The morphological variation of individual kind is very big, no matter branch, the fleece of leaf, the shapes and sizes of leaf and corolla length, fleece and lip Valve is with terms of the length ratio in cylinder portion, all varying widely.But all these changes are apparently more with ecological environment phase Contact, does not show and the correlation between geographical distribution.
Honeysuckle is described as clearing heat and detoxicating good medicine from ancient times.The sweet cold air fragrance of its property, clear heat with drugs of sweet flavour and cold nature is without injuring one's stomach, and fragrance is thoroughly Up to again can eliminating evil.Honeysuckle can dispelling wind-heat, also kind removing summer-heat blood poison, for various febrile diseases, such as body heat, dermexanthesis, hair spot, heat The diseases such as carbuncle carbuncle, abscess of throat, equal effect is notable
Honeysuckle adaptability is very strong, and happiness sun, shade tolerant, cold resistance are strong, and also drought-resistant and water is wet, requires not tight to soil, but Optimal with growth on moistening, fertile deep sandy earth, annual spring and summer sends out the tip twice.The dense prosperity of root system, sprout tillers is strong, vines Landing to take root.The environment of sunlight and gentle moistening is liked, viability is strong, wide adaptability resists cold, drought-enduring, at concealment, raw Length is bad.Be born in hillside shrubbery or sparse woods, riprap, the sufficient roadside in mountain and village hedge side, height above sea level is up to 1500 meters.
In the application, the Honegsukle flower P.E obtains to be commercially available, is purchased from Xi'an day Biotechnology Ltd..
Hawthorne leaf P.E
Leaves of Hawthorn, Chinese medicine name.For rosaceous plant large-fruited Chinese hawthorn Crataegus pinnatifida Bge.var.major N.E.Br. or hawthorn Grataegus pinnati fida Bge. dried leaf.Summer, the harvesting of season in autumn two, dry.It is distributed in east The ground such as north, North China.With promoting blood circulation and removing blood stasis, qi-regulating is promoted blood circulation, and changes effect of turbid lipid-loweringing.For qi depression to blood stasis, chest impediment and cardialgia is uncomfortable in chest to suppress Gas, palpitation and amnesia, dizziness and tinnitus, hyperlipidemia.
Machaka.The close life of branch, has spinelet, sprout has pubescence.Sprig puce, old branch taupe.Blade triangular shape ovum Shape is avette to prismatic, long 2~6cm, wide 0.8~2.5cm, base portion section shape or wide wedge shape, and respectively there are 3~5 pinniform drastic crack pieces, base in both sides Portion 1 divides deeper to sliver, and there is irregular sharp sawtooth at edge.Compound corymb, peduncle, anthocaulus have long pubescence;Floral white, Diameter about 1.5cm;There is inside and outside long pubescence, sepal two sides hairless outside calyx tube or inner face top hairiness.The operatic circle peony, it is subsphaeroidal. 5~June of florescence, 9~October of fruiting period.
In the application, the hawthorne leaf P.E obtains to be commercially available, is purchased from Xi'an day Biotechnology Ltd..
Extract of soybean
Soybean (scientific name:Glycine max (Linn.) Merr.) common name soya bean.Pulse family Glycine annual herb, high 30- 90 centimetres.Stem is sturdy, uprightly, close by the long bristle of brown.Leaf generally 3 leaflets of tool;Stipule has vein, by yellow pubescence;Petiole is long 2-20 centimetres;Leaflet width egg shape, papery;The short few flower of raceme, long spends more;Total bennet generally has 5-8 stockless, tightly squeezed Flower;Bract lanceolar, by strigose;Squamella lanceolar, by submissive bristle;Calyx lanceolar, flower purple, lavender or White, base portion tool valve handle, ala castor shape.Pod is loose, and slightly curved, sagging, yellow green is close to be become mildewed by isabelline;2-5, seed, Oval, subsphaeroidal, kind skin is smooth, has pale green, Huang, brown and black etc. various.The month at florescence 6-7, the fruiting period 7-9 months.
The happiness of soybean property is warm, and seed starts germination at 10-12 DEG C, most suitable with 15-20 DEG C, grows 20-25 DEG C of thermophilic, knot of blooming Bear pods delay, can not be bloomed less than 14 DEG C under 20-28 DEG C of pod phase thermophilic, low temperature, the too high plant of temperature then terminates growth in advance.Kind Son germination requires more moisture content, and florescence requires soil moisture content in 70%-80%, otherwise flower abscission rate increase.Soybean exists Fertilizer-sucting quantity is less than the 15% of total amount before blooming, and fruiting period of blooming accounts for more than the 80% of total fertilizer-sucting quantity
In the application, the extract of soybean obtains to be commercially available, is purchased from Xi'an day Biotechnology Ltd..
Kudzu root extract
The root of kudzu vine, Chinese medicine name.For the dry root of legume pueraria lobata, practise and claim elegant jessamine.Autumn, the excavation of season in winter two, take advantage of fresh-cut into thickness Piece or fritter;Dry.It is sweet, pungent, it is cool.There is expelling pathogenic factors from muscles and skin to bring down a fever, promoting eruption promotes the production of body fluid to quench thirst, the work(of Shengyang Zhixie.It is usually used in exterior syndrome heating, Stiff nape and back, measles without adequate eruption, pyreticosis is thirsty, and the deficiency of Yin is quenched one's thirst, and heat is purged heat dysentery, splenasthenic diarrhea.
Sturdy liana, long up to 8 meters, entirety is by the long bristle of yellow, and basal part of stem is wooden, the tuberous root for having thick thickness.Pinniform is answered Leaf has 3 leaflets;Stipule is carried, ovate Long Circle, has lines;Stipel wire lanceolar, it is isometric or longer with petiolule;Leaflet Three split, once in a while full edge, terminal leaflet width egg shape or tiltedly avette, long 8-15 (- 19) centimetre, wide 5-12 (- 18) centimetre, and tip length is gradually Point, side life leaflet tiltedly avette is slightly smaller, above by faint yellow, calm vegetable pubescence.It is closeer below;Petiolule takes off color fine hair by Huang. Pod oblong, it is long 5-9 centimetres, it is wide 8-11 millimeters, it is flat, by the long bristle of brown.The month at florescence 9-10, the fruiting period 11-12 months.It is raw In the thick grass of hillside or roadside and more dark and damp place, or it is born in the gully woods of 1000-3200 meters of height above sea level.
In the application, the kudzu root extract obtains to be commercially available, is purchased from Xi'an day Biotechnology Ltd..
Wolfberry fruit extract
Fruit (Chinese medicine claims the fruit of Chinese wolfberry), medicinal function is same with lycium barbarum;Root skin (Chinese medicine claims the root bark of Chinese wolf-berry), there is antipyretic cough-relieving Effectiveness.
Pick and process:The fruit of Chinese wolfberry:6-11 month fruits are red ripe successively, to harvest in batches, and fresh fruit is spread out on reed sugarcane rapidly, thick No more than 3 centimetres, typically it is advisable with 1.5 centimetres, puts shady place and dry in the air to rhicnosis, then exposure is hard to pericarp, when pulp is soft Carpopodium is removed, then is dried.Folium lycii:Spring to early summer plucks, and cleans, many using fresh herbs.
Main Ingredients and Appearance:The fruit of Chinese wolfberry (betane) containing glycine betaine, atropine (atropine), hyoscyamine (gyoscyamine)。
LBP-X:LBP-X is a kind of water-soluble polysaccharide, is topmost active component in matrimony vine, average molecular matter Measure as 68-200, as domestic and international study hotspot.Wherein and with the immunological regulation of LBP-X and the research of antitumor action most It is many.There is now many researchs show LBP-X have promote immune, anti-aging, it is antitumor, remove free radical, it is antifatigue, anti- The effects such as radiation, liver protection, reproductive function protection and improvement.
Glycine betaine:Chemical name is 1- carboxy-Ns, N, N- betaines, with amino acid phase in chemical constitution Seemingly, quaternary amine alkaloids are belonged to.Glycine betaine is one of main alkaloid in fructus lycii, leaf, handle.Matrimony vine is to lipid-metabolism or anti- The effect of fatty liver is mainly due to caused by contained glycine betaine, and it plays methyl supplying in vivo.On matrimony vine The research of glycine betaine is only limitted to the country in the measure of content, extraction process and the physiological action (enhancing salt tolerance) to lycium plant In terms of research, the pharmacological effect research on matrimony vine glycine betaine is seldom.
Wolfberry pigment:Wolfberry pigment is all kinds of present-color materials being present in matrimony vine berry, is the important physiology of matrimony vine seed Active component.It is main to include-carrotene, lutein and other coloring matters.Carotenoid contained by matrimony vine then has non- Often important medical value.Verified matrimony vine seed pigment has raising immune function of human body, prevention and suppresses swollen for many researchs Knurl and prevention of arterial atherosis etc. are acted on.Carrotene is the main active of wolfberry pigment, with anti-oxidant and conduct dimension The important physiological functions such as raw element A synthesis precursor.
In the application, the wolfberry fruit extract obtains to be commercially available, is purchased from Xi'an day Biotechnology Ltd..
Astragalus Root P.E
The Radix Astragali, also known as continuous stilbene.Perennial herb is high 50-100 centimetres.Main root is plump, wooden, normal branch, canescence.Stem Uprightly, top multi-branched, there is thin rib, by white pubescence.Perennial herb is high 50-100 centimetres.Originate in the Inner Mongol, it is Shanxi, sweet The ground such as respectful, Heilungkiang.
The Radix Astragali, winglike compound leaf has 13-27 piece leaflets, long 5-10 centimetres;Petiole is long 0.5-1 centimetres;Stipule is avette from life, Lanceolar or wire lanceolar, it is long 4-10 millimeters, below by white pubescence or near hairless;Leaflet is oval or long round shape is avette, It is long 7-30 millimeters, wide 3-12 millimeters, tip blunt circle or nick, tool small cusp or not substantially, basal circular, above green, nearly nothing Hair, below by submissive white pubescence.
Raceme is slightly close, there is 10-20 flower;Total bennet is near isometric or longer with leaf, to fruiting period significant elongation;Bract line Shape lanceolar, long 2-5 millimeters, the back side is by white pubescence;Bennet is long 3-4 millimeters, slightly close soft by brown or black together with rachis Hair;Squamella 2;Calyx mitriform, long 5-7 millimeters, outside is bordering on hairless by white or black pubescence, sometimes calyx tube, and only calyx tooth has Hair, calyx tooth is short, and triangle is to shape is bored, and long is only the 1/4-1/5 of calyx tube;Corolla yellow is faint yellow, vexil obovate, long 12- 20 millimeters, top nick, base portion has short valve handle, and ala is slightly shorter compared with vexil, limb Long Circle, base portion tool cropped ear, and valve handle is compared with limb 1.5 times are about, fossil fragments are closely isometric with ala, limb semioval shape, valve handle is slightly long compared with limb;Ovary has handle, by fine and soft hair.
Pod film matter, slightly expands, half elliptic, long 20-30 millimeters, wide 8-12 millimeters, and top tool puncture tip, two sides is white Color or the thin pubescence of black, fruit neck is outside calyx;3-8, seed.The month at florescence 6-8, the fruiting period 7-9 months.
In the application, the Astragalus Root P.E obtains to be commercially available, is purchased from Xi'an day Biotechnology Ltd..
Passion flower P.E
Passionflower (scientific name:Passiflora caerulea L.), it is that perennial evergreen climbs bejuco, is one The tasty fruit of fragrance is planted, there is the good reputation of " king of fruit juice ".Also known as fruit of suffering a calamity or disaster, Brazil nut, rattan peach, enthusiasm fruit, turn heart lotus, the West Bring up, turn Zhi Lian, the sour nightshade in ocean, Shi Jicao.
Passionflower stem it is cylindrical and it is micro- have a corner angle, it is hairless;Leaf papery, base portion is heart-shaped, the drastic crack of palmate 5, middle sliver ovate Long Circle, two side slivers are smaller, hairless, full edge;Cyme, which is degenerated, only deposits 1 flower, with tendril to life, Hua great, light green;Berry Spherical to the nearly spheroidal of oval, orange-yellow when ripe or yellow;Seed is most, and reversed cardioid is about 5 millimeters.The month at florescence 5-7.
Herbaceous species;Stem it is cylindrical and it is micro- have a corner angle, it is hairless, slightly by white powder;Leaf papery, it is long 5-7 centimetres, it is wide 6-8 centimetres, Base portion is heart-shaped, and the drastic crack of palmate 5, middle sliver ovate Long Circle, two side slivers are smaller, hairless, full edge;Petiole is long 2-3 centimetres, in There are the tiny bodies of gland of 2-4 (- 6) in portion;Stipule is larger, kidney shape, embraces stem, up to 1.2 centimetres, marginal wavy.
Cyme, which is degenerated, only deposits 1 flower, with tendril to life.Hua great, light green, diameter is big, 6-8 (- 10) centimetre;Bennet is long 3-4 centimetres;Bract width egg shape, long 3 centimetres, full edge;5 pieces of sepal, long 3-4.5 centimetres, outside light green, inner face is green white, outer Face top has 1 horn shape appendicle;5 pieces of petal, light green is closely isometric with sepal;Outer paracorolla sliver 3 is taken turns, thread, and foreign steamer is with Sliver is taken turns, up to 1-1.5 centimetres, top sky blue, middle part white, bottom aubergine, lubrication groove sliver is thread, long 1-2 millimeters, top End 1 aubergine capitulum of tool, bottom light green;Interior paracorolla tasselled shape, sliver aubergine, its 1 close gland ring of lower tool;Have floral disc, It is high about 1-2 millimeters;Androgynophore is long 8-10 millimeters;5 pieces of stamen, filigree separation, is about 1 centimetre, flat;Flower pesticide Long Circle, it is long About 1.3 centimetres;Ovary oval is spherical;3 pieces of style, separation, aubergine is about 1.6 centimetres;Column cap kidney shape.
Spherical to the nearly spheroidal of berry oval, is about 6 centimetres, orange-yellow when ripe or yellow;Seed is most, reversed cardioid, long About 5 millimeters.The month at florescence 5-7.
In the application, the Passion flower P.E obtains to be commercially available, is purchased from Xi'an day Biotechnology Ltd..
Punica granatum L. extract
Pomegranate (scientific name:Punica granatum L.) deciduous tree or shrub;Dan Ye, generally to raw or fasciation, no support Leaf.Flower basidixed or nearly basidixed, single raw or several fasciations or composition cyme, nearly bell, sliver 5-9, petal 5-9, many gauffers, Imbricate is arranged;Ovule is most.Berry is spherical, and top harbors calyx lobes, and pericarp is thick;Seed is most, and berry is subsphaeroidal, fruit The ripe phase 9-10 months.Exosper meat is translucent, succulence;Endotesta keratin.
Nature and flavor are sweet, sour and astringent, temperature, the effects such as with desinsection, convergence, puckery intestines, stop dysentery.Pomegranate fruit is nutritious, vitamin C Content will be higher by one or two times than apple, pears.
Pomegranate is machaka or dungarunga, is evergreen tree in the torrid zone.Tree crown plexi nature globular model.Tree root yellowish-brown. Growth is strong, and rhizosphere is easily taken root tiller.The height of tree is up to 5-7m, general 3-4m, but the only high about 1m or shorter of short raw pomegranate.Trunk is in ash Brown, above there is strumae, dry to reverse to the left more.
Branch is more in tree crown, and spray has rib, is square more.Sprig is flexible, is not easily broken.Primary tiller is eugonic small Staggeredly to life on branch, has spinule.The length of thorn is relevant with kind and growing state.Prosperous tree thorniness, veteran pierces less.Bud color is with season And change, there is purple, green, orange three color.
Leaf is to raw or fasciation, in long lanceolar to Long Circle, or ellipticity lanceolar, long 2-8cm, wide 1-2cm, top Point, surface is glossy, and back side middle arteries are raised;There is short petiole.
Flower both sexes, it is whether flourishing according to ovary, there are mitriform flower and tubular flower not, result of being fertilized is good in the former ovary prosperity, The latter is often withered and fallen unreal;General 1 to several it is raw between young sprout top and below Xiang Duan axil then;Sepal is hard, meat, Tubulose, 5-7 splits, and with ovary adhesion, harbors;Petal obovate, with sepal with number alternate, imbricate arrangement.Flower has single-lobe, again Point of valve.The many hemp nettles of double variety Pistil And Stamen and infertile, up to tens of pieces of petal;Spend more red, also have it is white and yellow, pink, The colors such as agate.Stamen is most, and filigree is hairless.Gynoecium has style 1, and length exceedes stamen, and carpel 4-8, ovary is the next.
In the application, the Punica granatum L. extract obtains to be commercially available, is purchased from Xi'an day Biotechnology Ltd..
Yam extract
Chinese yam is also known as Chinese yam, native potato, sweet potato Chinese yam, RHIIZOMA DIOSCOREAE from Henan of China, Chinese yam, white Chinese yam, is《Chinese book on Chinese herbal medicine》The herbal medicine recorded, medicine It is Dioscoreaceae plant Chinese yam dry rhizome with source.
Chinese yam, which has, nourishes strong, aid digestion, the effect of holding back abnormal sweating, antidiarrheal, cures mainly insufficiency of the spleen diarrhoea, cough due to deficiency of the lung, glycosuria Disease is quenched one's thirst, oliguria frequency, seminal emission, women is with lower and dyspeptic chronic enteritis.
Reed head is harvested then after planting, and bulbil Second Year is received.November leaf it is yellow after, adopt bulbil, per hectare receives bulbil 1,500,000 Gram or so.Tear support open, remove overground part, fallen with a ditch ditch method excavation, remove reed head make kind plant, be sure not Chinese yam to roll over It is disconnected, influence quality.The root tuber of bottom is put into cylinder and soaked 1~2 day, is cleaned, using fresh herb bamboo hilt crust profit is taken advantage of only, is fitted into basket It is put on a heatable brick bed with sulphur smoked 24 hours, 0.8~1 kilogram of sulphur of every hundred kilograms of fresh yams softens to Chinese yam, has many on surface The globule, takes out Exposure to Sunlight or is dried to after crust dries, be put into it is vexed in basket, it is vexed after shine again, until dry.Other simple processing method It is to clean soil, takes advantage of using fresh herb bamboo knife profit and remove outside tertia, section is dried.Packed with wooden case or basket.It is required that packing case is sealed, Surrounding patch oilpaper or plastic sheeting, moistureproof, mould proof, Anti-moth-eating.
In the application, the yam extract obtains to be commercially available, is purchased from Xi'an day Biotechnology Ltd..
Herb Gynostemmae Pentaphylli extract
Gynostemma pentaphylla (scientific name:Gynostemma pentaphyllum (Thunb.) Makino) Curcurbitaceae, gynostemma pentaphyllum genus herbaceous stem Climbing Plant;Stem is thin and delicate, has branch, tool vertical rib and groove, hairless or thin by pubescence.Japan is referred to as sweet climing tea.Gynostemma pentaphylla happiness is cloudy The weather of damp-warm syndrome sum, it is how wild at the concealments such as sylvan life, brook bank, it is perennial to climb up by holding on to draft.
Herbaceous stem Climbing Plant;Stem is thin and delicate, has branch, tool vertical rib and groove, hairless or thin by pubescence.Leaf film quality or papery, Bird foot shape, has 3-9 leaflets, usual 5-7 leaflets, petiole is long 3-7 centimetres, by pubescence or hairless;Vanelets ovate Long Circle or Lanceolar, central lobule is long 3-12 centimetres, wide 1.5-4 centimetres, and side life is small, and tip is suddenly sharp or short tapering, and base portion is gradually narrow, side Edge has wave-formed mouth or crenation tooth, above bottle green, back side light green, two sides dredged by short bristle, 6-8 pairs of lateral vein, above Flat, the back side is raised, and thready pulse is netted;Petiolule is slightly diverged, long 1-5 millimeters.Tendril is very thin, 2 discriminations, dilute single, hairless or base portion By pubescence.Flower dioecism.Male flower panicle, rachis is very thin, multi-branched, and long 10-15 (- 30) centimetre, branch is extensively opened up, Long 3-4 (- 15) centimetre, sometimes base portion tool leaflet, by pubescence;Bennet is thread, long 1-4 millimeters, and base portion tool bores shape squamella;Flower Calyx tube is extremely short, and 5 split, sliver triangle, is about 0.7 millimeter, the anxious point of tip;Corolla light green or white, 5 drastic cracks, sliver ovate Lanceolar, long 2.5-3 millimeters, wide about 1 millimeter, tip length is tapering, has 1 arteries and veins, the edge tool small tooth of echinid shape;Stamen 5, filigree is short, Post is unified into, flower pesticide is born in the top of post.Female flower panicle is short and small far beyond male flower, and calyx and corolla are like male flower;Ovary Spherical, 2-3 rooms, 3 pieces of style is short and diverge, and column cap 2 splits;5 pieces short and small of staminodium of tool.Flesh texture does not split, spherical, footpath 5-6 millimeters, it is ripe after black, Glabrous includes down 2, the seed that hangs down.Seed ovate is heart-shaped, about 4 millimeters of footpath, taupe or depth Brown, top is blunt, and base portion is heart-shaped, flattens, and two mask papillaries are raised.The month at florescence 3-11, the fruiting period 4-12 months.
In the application, the Herb Gynostemmae Pentaphylli extract obtains to be commercially available, is purchased from Xi'an day Biotechnology Ltd..
Tartary buckwheat extract
Bitter buckwheat is medicine-food two-purpose crop very few in nature, and bitter buckwheat-seven major nutrient rolls into one completely, is not medicine, It is not health products, is that can work as the food that meal is eaten, because its special growing environment, bitter buckwheat itself is just rich in selenium, can be to people Body plays a part of nature Selenium Supplement, the healthy nutritive value and outstanding dietotherapy effect for having brilliance.
According to《Compendium of Materia Medica》Record:Bitter buckwheat bitter, it is cold, can real stomach, benefiting energy, continuous spirit, sharp knowledge, refining the five internal organs Slag is dirty;《Qianjin Yao Fang》、《Dictionary of medicinal plant》And it is all on the books to bitter buckwheat in pertinent literature:Can calm the nerves, lively atmosphere blood, sending down abnormally ascending it is wide Intestines, heat-clearing swell wind pain, stagnant productization of dispelling, gut purge, ease constipation, defaecation, cough-relieving, relieving asthma, anti-inflammatory, antiallergy, cardiac stimulant, fat-reducing, beauty etc. Effect.
First, flavone compound.
The content highest in leaf, flower, wheat bran is higher more than 8 times than in flour.Predominantly rutin, Quercetin, morin, Kan Fei Alcohol, Hyperoside, Vitexin, catechin, resveratrol.Bitter buckwheat flavone mainly has following several functions:
1. prevention, treatment angiocardiopathy;
2. reducing blood lipid, hypotensive, hypoglycemic effect;
3. strengthen immunity;
4. antioxidation;
5. restraining and sterilizing bacteria, brain cell aging is prevented, as anticancer agent;
6. protect stomach lining, repair brain damage, antidepression;
7. promoting insulin secretion, the affinity of insulin receptor is improved.There is inhibitory action to aldose reductase, be conducive to The treatment of fro diabetic cataract;
8. pair cerebral ischemia and renal ischemic damage have protective effect
2nd, phenolic compound
OPC (tartary buckwheat bran content reaches as high as 5.03%), gallic acid, protocatechuic acid, vanillic acid, syringic acid, Forulic acid.
The physiological function of bitter buckwheat polyphenol:
1. with anti-inflammatory, antiallergic action, antiviral and anticancer characteristic.
2. the ability with phagocytosis free radical, is the important sources of polyphenoils.
3. lipid oxidation can be reduced and formed and resist cardiopathic protection.
4. the growth of leukaemia can be suppressed.
3rd, DCI.
There is positive effect to preventing and treating diabetes, have therapeutic action to PCO disease.
4th, alkalescent starch.
Bitter buckwheat starch can delay the content of the generation level of postprandial blood sugar, reduction total plasma cholesterol and triglycerides, protect Protect stomach lining.
5th, activated protein.
It is cleaning albumen that bitter buckwheat albumen, which has 1/3, can clear up internal toxin and foreign matter, the content that can improve SOD, suppression fat The unique effects such as fat accumulation, improvement constipation, generation, the absorption of suppression harmful substance for suppressing colorectal cancer and gall stone.
In the application, the tartary buckwheat extract obtains to be commercially available, is purchased from Xi'an day Biotechnology Ltd..
Purple daisy extract
Echinacea is the most popular medicinal plant of Plain Yin Dian clans, is generally used for flu, has a toothache, venomous snake bite With other wounds.U.S. original inhabitants are for many years using it as enhancing immune system and the replacement purified the blood medicine, particularly in season Section change and cold cough multiple season.In 1887, its be introduced into U.S.'s complex treatment system and advocated for from Catch a cold to a variety of diseases of syphilis.The Germany of the thirties is started to the modern study of the herbal medicine.
The main active of Echinacea, polyphenol, caffeic acid derivative and polysaccharide have following functions:
1. immunostimulation
Synanthrin:Played a role by increasing the number of granulocyte and leucocyte, improve monocyte and neutral virus Chemotaxis and produce bacteriolysis.
Polysaccharide:The hydrocarbon receptor of T lymphocytes and Macrophage Surface produces immunostimulation, can increase huge The phagocytic activity of phagocyte, and stimulating expression of macrophage increase TNF, interferon, the number of leucocyte betweenness, energy Destroy tumour cell.
Alkylamine and caffeic acid derivative:Lipophilic alkyl amine can increase macrophages phagocytic capacity.
Echinacea:The activity of non-specific T-cell is improved, interferon is produced, promotes the secretion of lymphocyte, T- is reduced auxiliary Synergidae, reduction T- auxiliary cells and inhibiting factor ratio.
2. tissue updates and anti-infectious function
Suppress hyaluronidase (hyaluronidase), the growth of fibroblast and the synthesis of glucosaminidase can be stimulated, produce Rawhide matter ketone is acted on, and promotes the secretion of cortex hormone of aadrenaline.Polysaccharide has anti-infectious effect.
3. antibacterial action
Echinacea glycosides has weak antibacterial activity with caffeic acid derivative.
4. antivirus action
Influenza, bleb and foaming virus can be suppressed, antiviral activity is given the credit to the inhibitory action of hyaluronidase, can hindered The virus receptor of cell surface.
5. toxicity
Consumption excessively agrees to cause to have a low fever, and sensitive group is likely to occur dermatitis.
The scope of application:
Echinacea and its extract are used for common infection or wound, flu or influenza, monilia, candida albicans larynx Inflammation, staphy lococcus infection, urinary tract infections, pelvic (P.I.D), tonsillotome inflammation, the infection of the upper respiratory tract, wound inflammation, tooth Pain or mouth infection, mosquito, animal or snake bite, blood food poisoning, furuncle, abscess, eczema etc..Improve acute and chronic Abscess of throat caused by pharyngitis, dryness and heat, hoarseness;Strengthen immune system, flu-prevention shortens cold, mitigated Abscess of throat, mild or moderate infection, flu, cough, influenza and other upper respiratory tract malaise symptoms.Promote protein synthesis and join Played an important role with synthesis and the immune aspect about enzyme.Moisten nourishing the bone marrow, improve immune.Recurrent oral is effectively improved to burst The symptoms such as ulcer, respiratory tract and infection of digestive canal.
In the application, the Echinacea Purpurea Herb P.E obtains to be commercially available, is purchased from Xi'an day Biotechnology Ltd..
In a preferred embodiment, the preparation method of described plant extracts is:By ginkgo biloba p.e, kind Rush down leaf extract, Rosmarinus officinalis extract, Shitake Mushroom P.E, mulberry-leaf extract, Honegsukle flower P.E, hawthorne leaf P.E, soybean Extract, kudzu root extract after uniform mixing, stand 5h at 0 DEG C, obtain component A at 40 DEG C;By wolfberry fruit extract, the Radix Astragali Extract, Passion flower P.E, Punica granatum L. extract, yam extract, Herb Gynostemmae Pentaphylli extract, tartary buckwheat extract, purple daisy are extracted Thing after uniform mixing, stands 2h at 20 DEG C, obtains component B, component A is added drop-wise in component B at 20 DEG C, obtained at 60 DEG C To plant extracts.
In a preferred embodiment, the preparation method of the metal flocbed is:
Hydroxymethyl cellulose, chitin fiber element, cetyl trimethylammonium bromide, oxidation are added into microwave reactor Graphene, deionized water, rise temperature is to 50 DEG C, and then insulation reaction 10min adds plant extracts, at 30 DEG C, insulation 30min is reacted, metal flocbed is obtained.
As a kind of preferred technical scheme of the present invention, also include ethylene glycol in the metal flocbed.
As a kind of preferred technical scheme of the present invention, the POROUS TITANIUM silicon layer is TS-1.
Term " TS-1 " refers to HTS, buys in Nanjing Ji Cang nanosecond science and technology Co., Ltd.
As a kind of preferred technical scheme of the present invention, the POROUS TITANIUM silicon layer is the POROUS TITANIUM handled through silane coupler Silicon layer.
In a preferred embodiment, the preparation method of the POROUS TITANIUM silicon layer handled through silane coupler is:
In the reactor, solvent 1000ml toluene and 100g TS-1, ultrasonic disperse 30min are added, 20gN- is then added β-(aminoethyl)-γ-aminopropyltriethoxy dimethoxysilane, adds the triethylamine solution that 100mL volumetric concentrations are 10%, Back flow reaction 5h at 100 DEG C, filtering, ethanol is washed 3 times, is drying to obtain the POROUS TITANIUM silicon layer handled through silane coupler.
In a preferred embodiment, the weight ratio between the metal flocbed and POROUS TITANIUM silicon layer is:5:(1 ~5).
In a preferred embodiment, the weight ratio between the metal flocbed and POROUS TITANIUM silicon layer is:5:4.
Second aspect of the present invention provides Polychlorinated biphenyls in a kind of air and efficiently removes the preparation method of composition, including with Lower step:
First POROUS TITANIUM silicon layer is poured into mould, metal flocbed is then being added into mould, air is obtained after drying Middle Polychlorinated biphenyls efficiently removes composition.
Third aspect present invention provides the application method that Polychlorinated biphenyls in air efficiently removes composition, and it is directly put Put in atmosphere.
The fourth aspect of the present invention provides Polychlorinated biphenyls in air and efficiently removes composition answering in environmentally friendly, catalytic field With.
The present invention is specifically described below by embodiment.It is necessarily pointed out that, following examples are only used In the invention will be further described, it is impossible to be interpreted as limiting the scope of the invention, professional and technical personnel in the field Some the nonessential modifications and adaptations made according to the content of the invention described above, still fall within protection scope of the present invention.
In addition, if without other explanations, it is raw materials used be all it is commercially available, be purchased from traditional Chinese medicines chemical reagent.
Embodiment 1
Embodiments of the invention 1 provide Polychlorinated biphenyls in a kind of air and efficiently remove many chlorine in composition, the air Biphenyl, which efficiently removes composition, at least includes metal flocbed and POROUS TITANIUM silicon layer;
The preparing raw material of the metal flocbed, in parts by weight, at least includes
Used hydroxymethyl cellulose is purchased from Shijiazhuang Mao Qing trade Co., Ltds;
Used chitin fiber element, which is purchased from the sea blue biological products in Qingdao, company;
Used cetyl trimethylammonium bromide is purchased from Chinese medicines group;
Used graphene oxide is purchased from Suzhou Heng Qiu graphenes Co., Ltd.
The plant extracts at least includes following raw material:
45 parts of ginkgo biloba p.e, 20 parts of Senna P.E, 10 parts of Rosmarinus officinalis extract, 15 parts of Shitake Mushroom P.E, mulberry 10 parts of leaf extract, 15 parts of Honegsukle flower P.E, 15 parts of hawthorne leaf P.E, 10 parts of extract of soybean, 16 parts of kudzu root extract, 7 parts of wolfberry fruit extract, 12 parts of Astragalus Root P.E, 20 parts of Passion flower P.E, 8 parts of Punica granatum L. extract, 13 parts of yam extract, strand Blue 8 parts of the extract of stock, 13 parts of tartary buckwheat extract, 12 parts of purple daisy extract.
The preparation method of described plant extracts is:Ginkgo biloba p.e, Senna P.E, rosemary are extracted Thing, Shitake Mushroom P.E, mulberry-leaf extract, Honegsukle flower P.E, hawthorne leaf P.E, extract of soybean, kudzu root extract are 40 At DEG C after uniform mixing, 5h is stood at 0 DEG C, component A is obtained;By wolfberry fruit extract, Astragalus Root P.E, Passion flower P.E, After Punica granatum L. extract, yam extract, Herb Gynostemmae Pentaphylli extract, tartary buckwheat extract, purple daisy extract are uniformly mixed at 60 DEG C, 2h is stood at 20 DEG C, component B is obtained, component A is added drop-wise in component B at 20 DEG C, plant extracts is obtained.
The preparation method of the metal flocbed:
Hydroxymethyl cellulose, chitin fiber element, cetyl trimethylammonium bromide, oxidation are added into microwave reactor Graphene, deionized water, rise temperature is to 50 DEG C, and then insulation reaction 10min adds plant extracts, at 30 DEG C, insulation 30min is reacted, metal flocbed is obtained.
The POROUS TITANIUM silicon layer is SBA-15.
Polychlorinated biphenyls efficiently removes the preparation method of composition in air:
First POROUS TITANIUM silicon layer is poured into mould, metal flocbed is then being added into mould, air is obtained after drying Middle Polychlorinated biphenyls efficiently removes composition.
Weight ratio between the metal flocbed and POROUS TITANIUM silicon layer is:5:4.
Embodiment 2
Embodiments of the invention 2 are same as Example 1, and difference is, the preparing raw material of the metal flocbed, with weight Part meter is measured, including
Embodiment 3
Embodiments of the invention 3 are same as Example 1, and difference is, the preparing raw material of the metal flocbed, with weight Part meter is measured, including
Embodiment 4
Embodiments of the invention 4 are same as Example 3, and difference is, 1 parts by weight are also included in the metal flocbed Ethylene glycol.
The preparation method of the metal flocbed:Into microwave reactor add hydroxymethyl cellulose, chitin fiber element, Cetyl trimethylammonium bromide, graphene oxide, deionized water, rise temperature to 60 DEG C, insulation reaction 10min, Ran Houzai Plant extracts and ethylene glycol are added, at 30 DEG C, insulation reaction 30min obtains metal flocbed.
Embodiment 5
Embodiments of the invention 5 are same as Example 4, and difference is, the POROUS TITANIUM silicon layer is through silane coupler The POROUS TITANIUM silicon layer of processing.
The preparation method of the POROUS TITANIUM silicon layer handled through silane coupler is:
In the reactor, solvent 1000ml toluene and 100g TS-1, ultrasonic disperse 30min are added, 20gN- is then added β-(aminoethyl)-γ-aminopropyltriethoxy dimethoxysilane, adds the triethylamine solution that 100mL volumetric concentrations are 10%, Back flow reaction 5h at 100 DEG C, filtering, ethanol is washed 3 times, is drying to obtain the POROUS TITANIUM silicon layer handled through silane coupler.
Comparative example 1
The comparative example 1 of the present invention is same as Example 1, and difference is, not including POROUS TITANIUM silicon layer.
Comparative example 2
The comparative example 2 of the present invention is same as Example 1, and difference is, not including metal flocbed.
Comparative example 3
The comparative example 3 of the present invention is same as Example 1, and difference is, difference is, not including hydroxylmethyl cellulose Element.
Comparative example 4
The comparative example 4 of the present invention is same as Example 1, and difference is, not including chitin fiber element.
Comparative example 5
The comparative example 5 of the present invention is same as Example 1, and difference is, not including cetyl trimethylammonium bromide.
Comparative example 6
The comparative example 6 of the present invention is same as Example 1, and difference is, not including plant extracts.
Comparative example 7
The comparative example 7 of the present invention is same as Example 1, and difference is, not including graphene oxide.
Comparative example 8
The comparative example 8 of the present invention is same as Example 1, and difference is, the plant extracts is only carried including ginkgo leaf Thing, Senna P.E, Rosmarinus officinalis extract, Shitake Mushroom P.E, mulberry-leaf extract, Honegsukle flower P.E, leaves of Hawthorn is taken to extract Thing, extract of soybean, kudzu root extract.
Comparative example 9
The comparative example 9 of the present invention is same as Example 1, and difference is, the plant extracts only includes matrimony vine and extracted Thing, Astragalus Root P.E, Passion flower P.E, Punica granatum L. extract, yam extract, Herb Gynostemmae Pentaphylli extract, tartary buckwheat extract, purple young bird Chrysanthemum extract.
Comparative example 10
The comparative example 10 of the present invention is same as Example 1, and difference is, the preparation method of the plant extracts is not Together, the preparation method of the plant extracts is:Ginkgo biloba p.e, Senna P.E, Rosmarinus officinalis extract, mushroom are carried Take thing, mulberry-leaf extract, Honegsukle flower P.E, hawthorne leaf P.E, extract of soybean, kudzu root extract, wolfberry fruit extract, Huang Stilbene extract, Passion flower P.E, Punica granatum L. extract, yam extract, Herb Gynostemmae Pentaphylli extract, tartary buckwheat extract, purple daisy carry Thing is taken after uniform mixing, to stand 2h at 60 DEG C at 20 DEG C, obtain plant extracts.
Comparative example 11
The comparative example 11 of the present invention is same as Example 1, and difference is, TS-1 is replaced with into SBA-15.
Comparative example 12
The comparative example 12 of the present invention is same as Example 5, and difference is, the POROUS TITANIUM silicon handled through silane coupler Layer.The silane coupler is replaced with γ-(2,3- the third oxygen of epoxy) propyl trimethoxy silicane.
Performance test:
1st, Polychlorinated biphenyls in the air of 1g embodiments 1~5 and comparative example 1~12 is efficiently removed into composition respectively to add In the middle part of quartz ampoule, Polychlorinated biphenyls efficiently removes the lower end addition silica wool of composition and makees support in air, then puts quartz ampoule In in vertical tube furnace.Connect gas circuit:Nitrogen-vaporizer-reactor-absorption plant-catalyst.Adjusting nitrogen flow is 50mL/min, 30min emptying air of ventilating.Vaporizer heater is connected, 350 DEG C of temperature is controlled, tube furnace is opened, is warming up to 200℃.10mL is measured, solubility is 10 μ g/mL industrial Polychlorinated biphenyls Aroclor 1254, using syringe pump with 50 μ L/min Speed to be uniformly injected into after vaporizer, gasification in gas phase PCBs concentration be 100ng/mL, while injecting 1ng/mL into vaporizer Iron granule, iron granule be 10 μm, then react 5h.The removal of Polychlorinated biphenyls and iron granule is calculated respectively Rate.The clearance of Polychlorinated biphenyls is:(initial concentration-ultimate density)/initial concentration * 100%;The clearance of iron granule For:(initial concentration-ultimate density)/initial concentration * 100%.
Gas phase and catalyst phase product are detected with GC-MS after reaction.Chromatographic condition is as follows:Injector temperature is 250 DEG C, inspection It is 300 DEG C to survey device temperature, and flow rate of carrier gas is 1.0mLmin-1, make-up gas flow velocity is 30mLmin-1, sampling volume is 1 μ L (detection is limited to 50ng mL-1), temperature programming is 150 DEG C of reservation 2min, then with 15 DEG C of min-1Speed is warming up to 280 DEG C.
The performance test results of table 1
From table 1 it follows that Polychlorinated biphenyls efficiently removes composition for the gold in air in air in the application Belonging to iron particle and Polychlorinated biphenyls has higher clearance, the reason is that Polychlorinated biphenyls efficiently removes composition in air Including metal flocbed and POROUS TITANIUM silicon layer, metal flocbed has preferable absorption property for the iron particle in air, together When POROUS TITANIUM silicon layer binding activity central metal flocbed have preferable degradation property for Polychlorinated biphenyls, detected through instrument, it is main The catabolite wanted is parachlorobenzoic-acid, also detects small molecule carbon dioxide and water in certain system, illustrates many chlorine in air Biphenyl efficiently removes composition has good degradation effect for Polychlorinated biphenyls, while parachlorobenzoic-acid is for Ozone in Atmosphere Degraded, plays a role, can also play a part of sterilization to air, contributes to optimization purification air.
Foregoing example is merely illustrative, some features of the feature for explaining the disclosure.Appended claim The scope as wide as possible for requiring to be contemplated that is intended to, and embodiments as presented herein is only according to all possible embodiment Combination selection embodiment explanation.Therefore, the purpose of applicant is appended claim not by the explanation present invention Feature example selectional restriction.And the progress in science and technology by formed language performance it is inaccurate due to and not The possible equivalent or son being presently considered are replaced, and these changes should also be interpreted by appended in the conceived case Claim is covered.

Claims (10)

1. Polychlorinated biphenyls efficiently removes composition in a kind of air, it is characterised in that Polychlorinated biphenyls is efficiently removed in the air Composition at least includes metal flocbed and POROUS TITANIUM silicon layer;
The preparing raw material of the metal flocbed, in parts by weight, at least includes
2. Polychlorinated biphenyls efficiently removes composition in air as claimed in claim 1, it is characterised in that the metal flocbed Preparing raw material, in parts by weight, at least include
3. Polychlorinated biphenyls efficiently removes composition in air as claimed in claim 1 or 2, it is characterised in that the plant carries Thing is taken at least to include following raw material:
Ginkgo biloba p.e, Senna P.E, Rosmarinus officinalis extract, Shitake Mushroom P.E, mulberry-leaf extract, honeysuckle are extracted Thing, hawthorne leaf P.E, extract of soybean, kudzu root extract, wolfberry fruit extract, Astragalus Root P.E, Passion flower P.E, pomegranate Extract, yam extract, Herb Gynostemmae Pentaphylli extract, tartary buckwheat extract, purple daisy extract.
4. Polychlorinated biphenyls efficiently removes composition in air as claimed in claim 3, it is characterised in that the plant extracts At least include following raw material:
20~50 parts of ginkgo biloba p.e, 10~25 parts of Senna P.E, 5~15 parts of Rosmarinus officinalis extract, Shitake Mushroom P.E 3 ~20 parts, 5~15 parts of mulberry-leaf extract, 3~18 parts of Honegsukle flower P.E, 10~20 parts of hawthorne leaf P.E, extract of soybean 5 ~15 parts, 5~20 parts of kudzu root extract, 1~10 part of wolfberry fruit extract, 10~15 parts of Astragalus Root P.E, Passion flower P.E 5~ 30 parts, 1~10 part of Punica granatum L. extract, 1~20 part of yam extract, 5~10 parts of Herb Gynostemmae Pentaphylli extract, tartary buckwheat extract 3~17 Part, 1~15 part of purple daisy extract.
5. Polychlorinated biphenyls efficiently removes composition in air as claimed in claim 1, it is characterised in that the metal flocbed In also include ethylene glycol.
6. Polychlorinated biphenyls efficiently removes composition in air as claimed in claim 1, it is characterised in that the POROUS TITANIUM silicon layer For TS-1.
7. Polychlorinated biphenyls efficiently removes composition in air as claimed in claim 6, it is characterised in that the POROUS TITANIUM silicon layer For the POROUS TITANIUM silicon layer handled through silane coupler.
8. Polychlorinated biphenyls efficiently removes the preparation method of composition in air described in claim 1~7, it is characterised in that including Following steps:
First POROUS TITANIUM silicon layer is poured into mould, metal flocbed is then being added into mould, is obtaining many in air after drying Chlordiphenyl efficiently removes composition.
9. Polychlorinated biphenyls efficiently removes the application method of composition in air described in claim 1~7, it is characterised in that by it It is directly placed in air.
10. Polychlorinated biphenyls efficiently removes composition in environmental protection, the application of catalytic field in air described in claim 1~7.
CN201710660168.9A 2017-08-04 2017-08-04 Polychlorinated biphenyls efficiently removes composition in air Pending CN107308775A (en)

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CN103480333A (en) * 2013-09-16 2014-01-01 华南理工大学 Compound grapheme absorption agent, method for preparing compound grapheme absorption agent and application of compound grapheme absorption agent
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Application publication date: 20171103