CN107281922A - Deodorant compositions and preparation method thereof - Google Patents
Deodorant compositions and preparation method thereof Download PDFInfo
- Publication number
- CN107281922A CN107281922A CN201710507969.1A CN201710507969A CN107281922A CN 107281922 A CN107281922 A CN 107281922A CN 201710507969 A CN201710507969 A CN 201710507969A CN 107281922 A CN107281922 A CN 107281922A
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- deodorant compositions
- deodorant
- compositions according
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/77—Liquid phase processes
- B01D53/78—Liquid phase processes with gas-liquid contact
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/30—Sulfur compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/40—Nitrogen compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
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- Environmental & Geological Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Biomedical Technology (AREA)
- Analytical Chemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
Abstract
The invention discloses a kind of deodorant compositions and its application, the deodorant compositions include by mass percentage：1.5%~2.0% zinc ricinate, 2.0%~3.5% ferrous sulfate, 6.0%~7.0% dipropylene glycol, 5.0%~6.0% sodium citrate, 1.5%~2.0% disecoctylmaleate sodium sulfonate, 0.5%~1.0% polyethers, 3.0%~4.0% essence, 74.5%~80.5% water.The deodorant compositions are prepared from using environmental sound, safe to the human body and biodegradable component, with safety and environmental protection, good deodorization effect, have no irritating odor the features such as, daily life and the deodorization of working environment are can be widely used for, the deodorization in the industrial production that is particularly suitable for use in workshop.
Description
Technical field
The present invention relates to environment-friendly deodorant agent field, more particularly to deodorant compositions and preparation method thereof.
Background technology
Foul gas refers to that all stimulate olfactory organ to cause people unhappy and damage the gaseous matter of living environment, dislikes
Smelly substance classes are various, wide material sources, and different journeys can be all caused to human body respiration, digestion, angiocarpy, endocrine and nervous system
The murder by poisoning of degree.
With the continuous improvement of living standard, people increasingly pay attention to healthy life, working environment, in economic development
While the consciousness of environmental protection is also constantly strengthened, position of the deodorant in people live is more and more important.
At present, the remover for being used to eliminate foul gas both at home and abroad is more, can substantially be divided into sense organ deodorant, physical deodorization
Agent, biology deodorant and the class of chemical deodorizing agent four.Sense organ deodorant is to utilize some pleasant aromatic compounds such as wooden vinegar
Stink is covered or offset to acid, camphor, volatile oil extracted from eucalyptus' leaves or twigs etc., reaches the deodorization on sense organ, but after aromatic compounds volatilize foul smell
Molecule is still present, it is impossible to eliminate.Main physical deodorization agent is adsorbed with the porous mass of some similar activated carbon, diatomite etc.
Firmly foul smell molecule, the shortcoming of this method is that absorption has selectivity (smelly eliminating of such as activated carbon to ammonia, trimethylamine amine substance
Effect it is just extremely undesirable), and activated carbon need be periodically replaced or reactivated, cost is higher.Biological deodorant mainly includes enzyme system
Product deodorant, plant deodorant and microbial deodorant, at present for feasibility it is also not high.Chemical deodorizing agent is mainly used
Between active material and odorous substance occur neutralize, oxidation, reduction, condensation, complexing, substitution etc. reaction, odorous substance is converted into
It is destitute of smell or the less novel substance of stink is so as to reach smelly purpose of dispelling.
Deodorant is as one of major way for eliminating foul gas, and domestic market demand is huge, but the country is removed
Smelly dose of quality is very different, and has that deodorizing effect is poor, have the shortcomings that strong and stimulating smell, especially in industrial deodorization side
Face, because the construction history of Environmental Protection in China career development is not long, the research and application of industrial deodorant are less, and it is suitable to be more the absence of
Efficient, environment-friendly type deodorant.
The content of the invention
Based on this, it is necessary in view of the above-mentioned problems, offer one kind has no irritating odor, good deodorization effect, and preparation method
It is all simple with application method, it is easy to the deodorant compositions for producing and using.
In order to solve the above-mentioned technical problem, the present invention is achieved through the following technical solutions.
A kind of deodorant compositions, include the component of following mass percent：
The mass percent summation of above-mentioned each component is 100%.
The features such as zinc ricinate has nontoxic, tasteless, readily biodegradable, it can be directly dissolved in water, done rear shape
Into crystal residual, encountering the crystal remained when water or moisture can be reactivated.With conventional by covering, sterilizing, adsorb
Mode carrys out deodorization difference, and zinc ricinate is by bonding mechanism come deodorization, and the zinc atom of activation can be former with the nitrogen in stink, sulphur
Son forms very strong chemical combination key, so as to thoroughly eliminate stink.Inorganic metal salt has to rubbish and people, animal excrement to be removed well
In smelly effect, the present invention, inorganic metal salt can further lift the deodorizing effect of composition as synergist.
The above-mentioned composition for deodorization can effectively eliminate stink, and have no irritating odor.
In one of the embodiments, the inorganic metal salt be selected from iron chloride, ferrous sulfate, ferric sulfate, copper chloride or
One or more in copper sulphate.
It is preferred that, the inorganic metal salt is ferrous sulfate.
In one of the embodiments, the mass ratio of the zinc ricinate and the inorganic metal salt is 0.75:1~2:
1。
It is preferred that, the mass ratio of the zinc ricinate and the inorganic metal salt is 1:1.
In one of the embodiments, the solubilizer is selected from two propyl alcohol of contracting, sodium benzoate, acetamide and polypropylene
One or more in sour fat.
It is preferred that, the solubilizer is two propyl alcohol of contracting.
In one of the embodiments, the complexing agent be selected from Sodium Citrate, usp, Dihydrate Powder, it is ethylenebis carbaminothioic acid sodium, hard
One or more in resin acid sodium and DBPC 2,6 ditertiary butyl p cresol.
It is preferred that, the complexing agent is Sodium Citrate, usp, Dihydrate Powder.
Sodium citrate is soluble in water, and can be chelated with the calcium in water, magnesium, iron plasma, is attracted to incrustation scale crystallization
Surface, does not continue to grow and occur distortion of lattice, so as to prevent the generation of heating surface, equipment surface hard scale.Simultaneously
Sodium citrate can be used as food additives, nontoxic to human body case, biodegradable.Deodorant liquid can be had by adding sodium citrate
Scale inhibition, the dirty ability of change, improve service life of equipment.
In one of the embodiments, the surfactant is selected from disecoctylmaleate sodium sulfonate, polyethers, ten
One or more in dialkyl benzene sulfonic acids sodium, L-AA and maleic acid.
Further, the surfactant includes one kind or two in disecoctylmaleate sodium sulfonate and polyethers
Kind.
Surfactant disecoctylmaleate sodium sulfonate (being also fast penetrant T) and/or polyethers, can drop significantly
Low surface tension of liquid, makes deodorant liquid in use, can be atomized when being especially atomized more completely, atomized drop is smaller,
Make deodorant liquid and foul smell molecule contacts more abundant, improve reaction rate and deodorizing effect.Meanwhile, polyethers is alternatively arranged as useful resist
Electrostatic agent, is added in deodorant liquid, can improve the antistatic effect of deodorant liquid.
In one of the embodiments, the deodorant compositions include following components by mass percentage：
The above-mentioned composition for deodorization prepared using environmental sound, safe to the human body and biodegradable component and
Into, with safety and environmental protection, good deodorization effect, have no irritating odor the features such as, can be widely used for daily life and working environment
Deodorization, the deodorization in the industrial production that is particularly suitable for use in workshop.
In one of the embodiments, the composition for deodorization also includes 3.0%~4.0% essence.For
Essence is added in the composition of deodorization, with fresh air, the sensory effects of optimization lifting deodorant liquid can be made.
Further, the essence is one kind or many in the edible essence such as cinnamic acid, third certain herbaceous plants with big flowers lactone, irisone
Kind.
It is a kind of except the preparation method of composition another object of the present invention is to provide, for preparing above-mentioned deodorization combination
Thing.
The preparation method of deodorant compositions is：Each group is weighed in the ratio of the mass percent of each component in deodorant compositions
Point, sequentially add in water, stirring, well mixed produce deodorant liquid.
Embodiment
For the ease of understanding the present invention, the present invention is described more fully below in conjunction with specific embodiment.But,
The present invention can be realized in many different forms, however it is not limited to embodiment described herein.On the contrary, providing these realities
The purpose for applying example is to make the understanding to the disclosure more thorough comprehensive.
A kind of deodorant compositions, include the component of following mass percent：
The mass percent summation of above-mentioned each component is 100%.
In one of the embodiments, inorganic metal salt is selected from iron chloride, ferrous sulfate, ferric sulfate, copper chloride or sulfuric acid
One or more in copper.
It is preferred that, inorganic metal salt is ferrous sulfate.
In one of the embodiments, the mass ratio of zinc ricinate and inorganic metal salt is 0.75:1~2:1.
It is preferred that, the mass ratio of zinc ricinate and inorganic metal salt is 1:1.
In one of the embodiments, solubilizer is in two propyl alcohol of contracting, sodium benzoate, acetamide and polyacrylate
One or more.
It is preferred that, solubilizer is two propyl alcohol of contracting.
In one of the embodiments, complexing agent is selected from Sodium Citrate, usp, Dihydrate Powder, ethylenebis carbaminothioic acid sodium, stearic acid
One or more in sodium and DBPC 2,6 ditertiary butyl p cresol.
It is preferred that, complexing agent is Sodium Citrate, usp, Dihydrate Powder.
In one of the embodiments, surfactant be selected from anion surfactant, cationic surfactant and
One or more combinations in amphoteric surfactant.
Further, surfactant is selected from disecoctylmaleate sodium sulfonate, polyethers, DBSA
One or more in sodium, L-AA and maleic acid.
Specifically, surfactant is disecoctylmaleate sodium sulfonate and/or polyethers.
In one of the embodiments, deodorant compositions include following components by mass percentage：
In one of the embodiments, in order to lift the sensory effects of deodorant compositions, essence can be added.Specifically,
The addition of essence is 3.0%~4.0%.
Specifically, essence may be selected from one kind or many in the edible essence such as cinnamic acid, third certain herbaceous plants with big flowers lactone, irisone
Kind.
Another embodiment of the present invention, which is provided, is used for the preparation method of deodorant compositions in above-described embodiment, for preparing
Have no irritating odor, the composition of good deodorization effect.
Specifically preparation method is：Each component is weighed in the ratio of the mass percent of each component in composition or deodorant liquid,
Sequentially add in water, stir, be well mixed.
The deodorant compositions of the present invention may be used as daily life deodorant, it is also possible to make industrial deodorant；Can be direct
Put on the object for treating deodorization or elimination stink, or put near the object.To the usage amount of deodorant compositions of the present invention
Do not limit strictly, its depend on stench concentration, and required deodorization amount of substance number or space size, to carry out
Dilution is used.Deodorant compositions of the present invention can be directly used as deodorant liquid, can also match somebody with somebody by related deodoriser or odor removal
Close using deodorization is carried out, such as after deodorant compositions of the present invention are diluted, being sprayed onto by high-pressure spraying system needs deodorization
Workshop, carries out deodorization.
The present embodiment deodorant compositions have the advantages that：
1) the present embodiment deodorant compositions include active component zinc ricinate and synergist inorganic metal salt, can be effective
Eliminate foul smell molecule in nitrogen-containing compound (such as trimethylamine, ammonia, histamine, nicotine) and sulfur-containing compound (such as hydrogen sulfide, two
Sulfur oxide, mercaptan, thioether etc.).
2) each component of the present embodiment deodorant compositions has no irritating odor, high safety and biodegradable, therefore
Extensively model it can use among live and work environment.
3) amphoteric surfactant is included in the present embodiment deodorant compositions, the antistatic effect of deodorant liquid is improved, more
Plus it is adapted to the deodorization in inflammable and explosive industrial production workshop.
4) complexing agent is included in the present embodiment deodorant compositions, water demineralization can be made, can prevent from using equipment (such as deodorization
Spray equipment) fouling and clogging, the service life of extension device.
5) essence is included in the present embodiment deodorant compositions, the sensory effects of deodorant liquid can be improved.
It is specific embodiment below
The deodorant compositions of embodiment 1~4, by percentage to the quality, each component constitute and see the table below 1：
Table 1
Note："-" represents without or not contained the material.
For the preparation method of above-mentioned deodorant liquid, comprise the following steps：
Each component is weighed by component ratio in the deodorant compositions of the embodiment 1~6 of table 1 and comparative example 1~2, is sequentially added
Into water, stir, be well mixed.
For the application of above-mentioned deodorant compositions, after deodorant compositions are diluted, it is sprayed onto and treats on deodorization object, removed
It is smelly.
Specifically, embodiment 1~6 and the deodorant liquid 5kg and 1000kg of comparative example 1~2 water are stirred dilute respectively
After releasing, intersperse among waste plastics respectively through atomizing sprinkling system and stack workshop and sludge composting workshop.It is appreciated that deodorant liquid makes
Consumption or/and extension rate can be adjusted according to use environment.
Workshop and sludge composting workshop are stacked to waste plastics to the deodorant liquid using embodiment 1~6 and comparative example 1~2
Deodorizing effect is detected, wherein passing through《Ammonia Berthelot spectrophotometry》(HJ533-2009) method detects it to ammonia
Elimination situation, passes through《Stink damp phase chromatography》(GB/T14678-1993) method detects its elimination situation to hydrogen sulfide,
Pass through《The measure triangle odor bag method of air quality foul smell》(GB/T14657-1993) method detects that it disappears to foul smell
Except situation, concrete outcome see the table below 2~4.
Elimination situation of the deodorant liquid of table 2 to ammonia
Elimination situation of the deodorant liquid of table 3 to hydrogen sulfide
Note：ND is represented to use after deodorant liquid less than detection standard limited value 0.01mg/m3
Elimination situation of the deodorant liquid of table 4 to foul smell
The species of foul smell is a lot, mainly due to containing following three classes compound in gas：The first kind is nitrogen-containing compound,
Such as trimethylamine, ammonia, histamine, nicotine；Equations of The Second Kind is sulfur-containing compound, such as hydrogen sulfide, sulfur dioxide, mercaptan, thioether；3rd class is
Acid, aldehyde, ketone and ester etc., and the peculiar smell produced by the odoring substance such as high concentration alcohol, ester sometimes.The present embodiment is to the main of foul smell
Index substance such as ammonia, hydrogen sulfide and foul smell total concentration are detected, removing for comparative example 1~2 is can be seen that from upper table 2~4
Smelly effect is substantially not so good as embodiment 1~6, the deodorant liquid of the embodiment of the present invention 1~2 clearance of workshop foul smell is reached 93% with
On, more than 95% is reached to the clearance of ammonia, after deodorant liquid of the present invention, the detection value of the hydrogen sulfide in workshop is less than mark
Quasi- limit value 0.01mg/m3, illustrate the good deodorization effect of deodorant liquid of the present invention.
Each technical characteristic of embodiment described above can be combined arbitrarily, to make description succinct, not to above-mentioned reality
Apply all possible combination of each technical characteristic in example to be all described, as long as however, the combination of these technical characteristics is not deposited
In contradiction, the scope of this specification record is all considered to be.
Embodiment described above only expresses the several embodiments of the present invention, and it describes more specific and detailed, but simultaneously
Can not therefore it be construed as limiting the scope of the patent.It should be pointed out that coming for one of ordinary skill in the art
Say, without departing from the inventive concept of the premise, various modifications and improvements can be made, these belong to the protection of the present invention
Scope.Therefore, the protection domain of patent of the present invention should be determined by the appended claims.
Claims (10)
1. a kind of deodorant compositions, it is characterised in that include the component of following mass percent：
2. deodorant compositions according to claim 1, it is characterised in that the inorganic metal salt is selected from iron chloride, sulfuric acid
One or more in ferrous, ferric sulfate or copper sulphate.
3. deodorant compositions according to claim 1, it is characterised in that the zinc ricinate and the inorganic metal salt
Mass ratio be 0.75:1~2:1.
4. deodorant compositions according to claim 1, it is characterised in that the solubilizer is selected from dipropylene glycol, benzene
One or more in sodium formate, acetamide and polyacrylate.
5. deodorant compositions according to claim 1, it is characterised in that the complexing agent is selected from Sodium Citrate, usp, Dihydrate Powder, Asia
One or more in ethyl bisdithiocarbamic sodium, odium stearate and DBPC 2,6 ditertiary butyl p cresol.
6. deodorant compositions according to claim 1, it is characterised in that the surfactant is selected from maleic acid two
One or more in secondary dioctyl sodium sulfosuccinate, polyethers, neopelex, L-AA and maleic acid.
7. deodorant compositions according to claim 1, it is characterised in that the deodorant compositions include by mass percentage
Following components：
8. the deodorant compositions according to claim any one of 1-7, it is characterised in that the deodorant compositions also include
3.0%~4.0% essence.
9. deodorant compositions according to claim 8, it is characterised in that the essence is edible essence.
10. the preparation method of any deodorant compositions of claim 1~9, it is characterised in that by each component in composition
The ratio of mass percent weighs each component, sequentially adds in water, stirring, well mixed produces the deodorant compositions.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710507969.1A CN107281922B (en) | 2017-06-28 | 2017-06-28 | Deodorant composition and process for producing the same |
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|---|---|---|---|
| CN201710507969.1A CN107281922B (en) | 2017-06-28 | 2017-06-28 | Deodorant composition and process for producing the same |
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| CN107281922A true CN107281922A (en) | 2017-10-24 |
| CN107281922B CN107281922B (en) | 2020-04-17 |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107935388A (en) * | 2017-11-24 | 2018-04-20 | 任合超 | A kind of the pottery fish jar and its preparation process of energy deodorizing antibiotic |
| CN109381959A (en) * | 2018-11-06 | 2019-02-26 | 广州市奥因环保科技有限公司 | Fit up compound eliminating smell agent |
| CN110292649A (en) * | 2018-03-24 | 2019-10-01 | 来景辉 | Sheep raising peculiar smell ecology remover and preparation method |
| CN112979123A (en) * | 2021-04-01 | 2021-06-18 | 福州大学 | Method for removing sludge odor and harmful substances by reduction-oxidation and deodorized sludge |
| CN113262421A (en) * | 2021-06-08 | 2021-08-17 | 江苏乐尔环境科技股份有限公司 | Fly ash chelating agent capable of effectively inhibiting zinc leaching and preparation method thereof |
| CN113426277A (en) * | 2021-07-02 | 2021-09-24 | 深圳市锦明环保科技有限公司 | Garbage deodorant and preparation method and use method thereof |
| CN115252863A (en) * | 2022-06-28 | 2022-11-01 | 上海康恒环境修复有限公司 | Deodorant for refuse landfill, preparation method and application thereof |
| CN116750822A (en) * | 2023-08-17 | 2023-09-15 | 清有生态科技(上海)有限公司 | Deodorant for sludge and wastewater and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107935388A (en) * | 2017-11-24 | 2018-04-20 | 任合超 | A kind of the pottery fish jar and its preparation process of energy deodorizing antibiotic |
| CN110292649A (en) * | 2018-03-24 | 2019-10-01 | 来景辉 | Sheep raising peculiar smell ecology remover and preparation method |
| CN109381959A (en) * | 2018-11-06 | 2019-02-26 | 广州市奥因环保科技有限公司 | Fit up compound eliminating smell agent |
| CN112979123A (en) * | 2021-04-01 | 2021-06-18 | 福州大学 | Method for removing sludge odor and harmful substances by reduction-oxidation and deodorized sludge |
| CN112979123B (en) * | 2021-04-01 | 2022-03-29 | 福州大学 | Method for removing sludge odor and harmful substances by reduction-oxidation and deodorized sludge |
| CN113262421A (en) * | 2021-06-08 | 2021-08-17 | 江苏乐尔环境科技股份有限公司 | Fly ash chelating agent capable of effectively inhibiting zinc leaching and preparation method thereof |
| CN113426277A (en) * | 2021-07-02 | 2021-09-24 | 深圳市锦明环保科技有限公司 | Garbage deodorant and preparation method and use method thereof |
| CN115252863A (en) * | 2022-06-28 | 2022-11-01 | 上海康恒环境修复有限公司 | Deodorant for refuse landfill, preparation method and application thereof |
| CN115252863B (en) * | 2022-06-28 | 2023-10-31 | 上海康恒环境修复有限公司 | Deodorant for landfill site, preparation method and application thereof |
| CN116750822A (en) * | 2023-08-17 | 2023-09-15 | 清有生态科技(上海)有限公司 | Deodorant for sludge and wastewater and preparation method thereof |
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| Publication number | Publication date |
|---|---|
| CN107281922B (en) | 2020-04-17 |
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