CN1072670A - 金水 - Google Patents
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- CN1072670A CN1072670A CN 92113913 CN92113913A CN1072670A CN 1072670 A CN1072670 A CN 1072670A CN 92113913 CN92113913 CN 92113913 CN 92113913 A CN92113913 A CN 92113913A CN 1072670 A CN1072670 A CN 1072670A
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- jinsui river
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- chromium
- tin
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- 239000003795 chemical substances by application Substances 0.000 claims abstract description 29
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims abstract description 14
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims abstract description 14
- 229910052804 chromium Inorganic materials 0.000 claims abstract description 12
- 239000011651 chromium Substances 0.000 claims abstract description 12
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229910052737 gold Inorganic materials 0.000 claims abstract description 10
- 239000010931 gold Substances 0.000 claims abstract description 10
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims description 7
- 239000000853 adhesive Substances 0.000 claims description 7
- 239000012916 chromogenic reagent Substances 0.000 claims description 7
- 229910052751 metal Inorganic materials 0.000 claims description 6
- 239000002184 metal Substances 0.000 claims description 6
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims description 5
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims description 5
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 claims description 4
- 239000011347 resin Substances 0.000 claims description 4
- 229920005989 resin Polymers 0.000 claims description 4
- 229910052709 silver Inorganic materials 0.000 claims description 4
- 239000004332 silver Substances 0.000 claims description 4
- 239000002904 solvent Substances 0.000 claims description 4
- 229910052797 bismuth Inorganic materials 0.000 claims description 3
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 claims description 3
- 229960000411 camphor oil Drugs 0.000 claims description 3
- 239000010624 camphor oil Substances 0.000 claims description 3
- NNBZCPXTIHJBJL-UHFFFAOYSA-N decalin Chemical compound C1CCCC2CCCCC21 NNBZCPXTIHJBJL-UHFFFAOYSA-N 0.000 claims description 3
- 239000011259 mixed solution Substances 0.000 claims description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims 2
- 229910052703 rhodium Inorganic materials 0.000 abstract description 16
- 239000010948 rhodium Substances 0.000 abstract description 16
- MHOVAHRLVXNVSD-UHFFFAOYSA-N rhodium atom Chemical compound [Rh] MHOVAHRLVXNVSD-UHFFFAOYSA-N 0.000 abstract description 16
- 238000004519 manufacturing process Methods 0.000 abstract description 7
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 abstract description 3
- 239000011521 glass Substances 0.000 abstract description 3
- 239000000463 material Substances 0.000 abstract description 3
- 239000000919 ceramic Substances 0.000 abstract description 2
- 210000003298 dental enamel Anatomy 0.000 abstract description 2
- 239000007788 liquid Substances 0.000 abstract description 2
- 238000005034 decoration Methods 0.000 abstract 1
- 239000011135 tin Substances 0.000 description 9
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- 238000010438 heat treatment Methods 0.000 description 5
- 239000003960 organic solvent Substances 0.000 description 5
- 239000006071 cream Substances 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 238000005987 sulfurization reaction Methods 0.000 description 3
- ZSLUVFAKFWKJRC-IGMARMGPSA-N 232Th Chemical compound [232Th] ZSLUVFAKFWKJRC-IGMARMGPSA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 239000005864 Sulphur Substances 0.000 description 2
- 229910052776 Thorium Inorganic materials 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 230000018109 developmental process Effects 0.000 description 2
- PPNKDDZCLDMRHS-UHFFFAOYSA-N dinitrooxybismuthanyl nitrate Chemical compound [Bi+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O PPNKDDZCLDMRHS-UHFFFAOYSA-N 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 2
- 229910021555 Chromium Chloride Inorganic materials 0.000 description 1
- 229910003803 Gold(III) chloride Inorganic materials 0.000 description 1
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 1
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical compound O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 1
- 241001404789 Smilax glabra Species 0.000 description 1
- 229910021626 Tin(II) chloride Inorganic materials 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- QSWDMMVNRMROPK-UHFFFAOYSA-K chromium(3+) trichloride Chemical compound [Cl-].[Cl-].[Cl-].[Cr+3] QSWDMMVNRMROPK-UHFFFAOYSA-K 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- RJHLTVSLYWWTEF-UHFFFAOYSA-K gold trichloride Chemical compound Cl[Au](Cl)Cl RJHLTVSLYWWTEF-UHFFFAOYSA-K 0.000 description 1
- 229940076131 gold trichloride Drugs 0.000 description 1
- 239000000976 ink Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 229910052573 porcelain Inorganic materials 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229910001961 silver nitrate Inorganic materials 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 235000011150 stannous chloride Nutrition 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- AXZWODMDQAVCJE-UHFFFAOYSA-L tin(II) chloride (anhydrous) Chemical compound [Cl-].[Cl-].[Sn+2] AXZWODMDQAVCJE-UHFFFAOYSA-L 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/46—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
- C04B41/49—Compounds having one or more carbon-to-metal or carbon-to-silicon linkages ; Organo-clay compounds; Organo-silicates, i.e. ortho- or polysilicic acid esters ; Organo-phosphorus compounds; Organo-inorganic complexes
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/009—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/82—Coating or impregnation with organic materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/80—Optical properties, e.g. transparency or reflexibility
- C04B2111/82—Coloured materials
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Other Surface Treatments For Metallic Materials (AREA)
Abstract
本发明涉及陶瓷、玻璃、搪瓷等硅酸盐制品的液
体装饰材料，其特点是不含铑，以锡和铬或单纯以铬
作耐温剂，锡和铬的摩尔比为0—2，金水其它组分也
根据需要作了优化调整。本发明的金水，耐高温，达
880℃，生产成本至少可降低10％，彩烤后的黄金饰
膜符合陶瓷行业标准。
Description
本发明涉及一种陶瓷、玻璃、搪瓷等硅酸盐制品的液体装饰材料。
金水是硅酸盐制品如陶瓷、玻璃等的重要装饰材料之一，近几年来有了很大的发展，出现了许多新品种，但各种金水均是由发色剂、调色剂、附着剂、耐温剂、填充剂和溶剂混合均匀后经陈化处理的组合物，且均含有相当数量的铑作耐温剂，这有因为铑具有独特的耐温性，且使彩烤后的金膜具有很好的连续性和高的光泽度，如国内普遍使用的无苯金水，美国墨鹤牌（Hanorla）金水和德国日月名牌（Suncndmoon）金水。可是金属铑的价格十分昂贵，货源短缺，近几年来，铑的价格更是突飞猛涨，近十年间，价格便涨了近二倍，导致金水的生产成本大幅度提高，严重制约着金水的发展，国内外都曾进行过以其它金属替代铑作耐温剂的研究，但进展不大，日本专利昭-93567号曾报道，在陶瓷用金水中（添加部分树脂钍代替一部分铑发挥作用，但因钍是放射性元素，受到工作人员的反对，而且其价格昂贵，最高耐温为700℃，远不能满足陶瓷用金水的使用温度要求，故未能投入生产应用。在本申请人于1991年8月13日申请的名称为金水的专利（申请号91106515.6）中，提供了二种降铑代铑金水，一种是用一部分锡代替一部分铑发挥耐温作用，但金水中仍含有一定数量的铑作耐温剂，另一种是用锡全部代替铑作耐温剂，但金水的耐温性差，最高烤烧温度为800℃，适于低温情况下装饰，不能满足一般陶瓷用金水的烤烧温度要求。因此，寻找一种经济实用的铑代用品，以降低金水的生产成本，成为当前金水生产中亟待解决的问题。
本发明的目的，在于提供一种不含铑的金水，用价格低廉的金属铬和锡或单独用铬替代目前金水中的金属铑作耐温剂，性能达到含铑金水原有的使用效果，从而大大降低金水的生产成本。
本发明的目的可以通过以下途径来实现：
本发明金水，以铬和锡的松脂酸盐作耐温剂，锡和铬的摩尔数比为0-2，加入量为（以下均以加入金属量与金水总量的%表示）：0.1-0.52;金的有机树脂盐为发色剂，加入量为8-12;银的松脂酸盐为调色剂，加入量为0-0.3;铋的松脂酸盐为附着剂，加入量为0.30-0.52;20-40%四氢萘，10-50%樟油，5-10%环己酮，5-10%松节油的混合液作溶剂，加入量（以下以加入重量与金水总重的%表示）为2-10;以硝化松香作填充剂，加入量为20-50。
其中：耐温剂锡、铬的摩尔比最佳为0.1-0.7，加入量最佳为0.12-0.35;
调色剂银的松脂酸盐的加入量最佳为0.02-0.15;
附着剂铋的松脂酸盐的加入量，最佳为0.30-0.45;
作为发色剂的金的有机树脂盐，可以是松脂酸金，芳香油硫化香脂金、松节油硫化香脂金、硫醇金，以松节油硫化香脂金最佳;
制备上述金水的方法可以是：
1、以氯化亚锡重量为：0-1，氯化铬重量为1.2-2.5，与重量为3-8的松香，重量为10-16的有机溶剂混合加热生成混合耐温剂。
2、以硝酸银重量为1，与重量为2-6的含硫量8-15%的硫化油，混合加热组成调色剂。
3、以硝酸铋重量为1，与重量为2-5的松香，重量为8-15的有机溶剂混合加热制得附着剂。
4、以氯化金重量为1，加入重量为2-6含硫量8-15%的硫化油，混合加热组成发色剂。
5、以松香重量为1，加入重量为0.3浓度为30%的稀硝酸，重量为1-1.5有机溶剂，混合加热组成填充剂。
6、以四氢萘重量为20-40，樟油重量10-50，环己酮重量为5-10，松节油重量为5-10，混合组成有机溶剂。
7、将发色剂、铬、锡混合耐温剂、调色剂和附着剂、填充剂、有机溶剂充分混合搅拌，陈化一周即得金水。
本发明充分利用铬、锡松脂酸盐的耐温性能，找到了金水各组分之间的合理配比，满足了金水的耐温度要求，彩烤后黄金膜符合陶瓷行业技术标准，与现有技术相比，具有以下优点：
1、由于本发明以价格低廉、储量丰富的金属铬、锡替代金属铑作耐温剂，产品成本大大降低，生产成本至少可降低10%，而且易于推广应用。
2、本发明的产品无论从内在性能和烤烧后质量均达到目前含铑金水的质量及使用要求以陶瓷用金水为例，与国内外名牌产品性能对比如下：
备注：无苯陶瓷金水系山东省硅酸盐研究所设计院生产的“春蕾”牌陶瓷金水，批号为9206，生产日期92年6月18日，1978年获全国科学大会奖，国家A级产品。
英国Matthey金水系英国Johnson Matthey公司出品，生产日期1992年1月。
测试条件：45/0，所用仪器是日本岛津GM-260色度、光泽度仪。
本发明的实施例如下：
瓷用金水
制备方法如前所述。
Claims (3)
1、一种金水，由发色剂、调色剂、附着剂、混合耐温剂、溶剂和填充剂构成，
A20-40%四氢萘，10-50%樟油，5-10%环已酮，5-10%松节油的混合液作溶剂，加入量(以下以加入重量与金水总重的%表示)为2-10；
B硝化松香作填充剂，加入量为20-50；
C金的有机树脂为发色剂，加入量(以下均以加入金属重量与金水总重的%表示)为8-12；
D铋的树脂酸盐为附着剂，加入量为0.30-0.45；
其特征在于：
E以铬和锡的松脂酸盐作混合耐温剂，锡和铬的摩尔比为0-2，加入量为0.1-0.52；
F银的松脂酸盐为调色剂，加入量为0-0.3。
2、如权利要求1所述的金水，其特征在于所述耐温剂，锡和铬的摩尔比为0.1-0.7，加入量为0.12-0.35。
3、如权利要求1所述的金水，其特征在于调色剂银松脂酸盐的加入量为0.02-0.15。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 92113913 CN1072670A (zh) | 1992-11-15 | 1992-11-15 | 金水 |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 92113913 CN1072670A (zh) | 1992-11-15 | 1992-11-15 | 金水 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1072670A true CN1072670A (zh) | 1993-06-02 |
Family
ID=4946664
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 92113913 Pending CN1072670A (zh) | 1992-11-15 | 1992-11-15 | 金水 |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1072670A (zh) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1043294B1 (de) * | 1999-04-09 | 2000-12-06 | W.C. Heraeus GmbH & Co. KG | Glanzedelmetallpräparat |
| CN1313642C (zh) * | 2001-10-23 | 2007-05-02 | 南京大学 | 耐高温烧结金水及其生产方法 |
| CN103387419A (zh) * | 2013-08-21 | 2013-11-13 | 景德镇市欧格陶瓷有限公司 | 一种适用于微波炉的瓷用金水及其使用方法 |
-
1992
- 1992-11-15 CN CN 92113913 patent/CN1072670A/zh active Pending
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1043294B1 (de) * | 1999-04-09 | 2000-12-06 | W.C. Heraeus GmbH & Co. KG | Glanzedelmetallpräparat |
| US8309171B1 (en) | 1999-04-09 | 2012-11-13 | Heraeus Precious Metals Gmbh & Co. Kg | Bright noble metal preparation |
| US8569533B2 (en) | 1999-04-09 | 2013-10-29 | Heraeus Precious Metals Gmbh & Co. Kg | Bright noble metal preparation |
| CN1313642C (zh) * | 2001-10-23 | 2007-05-02 | 南京大学 | 耐高温烧结金水及其生产方法 |
| CN103387419A (zh) * | 2013-08-21 | 2013-11-13 | 景德镇市欧格陶瓷有限公司 | 一种适用于微波炉的瓷用金水及其使用方法 |
| CN103387419B (zh) * | 2013-08-21 | 2017-04-05 | 景德镇市欧格陶瓷有限公司 | 一种适用于微波炉的瓷用金水及其使用方法 |
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