CN107258808A - A kind of fertilizer granules and its application containing Diacloden and cyfloxylate - Google Patents
A kind of fertilizer granules and its application containing Diacloden and cyfloxylate Download PDFInfo
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- CN107258808A CN107258808A CN201710547796.6A CN201710547796A CN107258808A CN 107258808 A CN107258808 A CN 107258808A CN 201710547796 A CN201710547796 A CN 201710547796A CN 107258808 A CN107258808 A CN 107258808A
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- fertilizer
- diacloden
- cyfloxylate
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N51/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds having the sequences of atoms O—N—S, X—O—S, N—N—S, O—N—N or O-halogen, regardless of the number of bonds each atom has and with no atom of these sequences forming part of a heterocyclic ring
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/60—Biocides or preservatives, e.g. disinfectants, pesticides or herbicides; Pest repellants or attractants
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- Life Sciences & Earth Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- General Health & Medical Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
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- Environmental Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical & Material Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Fertilizers (AREA)
Abstract
The invention discloses a kind of fertilizer granules containing Diacloden and cyfloxylate and its application, the fertilizer granules are made up of the auxiliary element in pesticide activity component, fertilizer and Pesticide formulation.The composition of each composition is Diacloden 0.01 20%, cyfloxylate 0.01 10%, fertilizer 10 50% and pesticidal preparations auxiliary element surplus.The fertilizer granules have the purposes of preventing and treating subterranean pest-insect, especially have good prevention effect to grub, cutworm, mole cricket, wireworm and with significant effect of increasing production.
Description
Technical field
The invention belongs to agrochemical fertilizer technical field, it is related to fertilizer granules containing Diacloden and on crop pests
Using having desinsection and the double effects of Fertilizer nutrient concurrently.
Background technology
Medicine fertilizer is to mix agricultural chemicals and fertilizer, and fertilizer and agricultural chemicals are stable in specific compound system by processing and
The mixture of formation, is a new technology using in agricultural in recent years, refers to desinsection, weeding, bactericidal action and effect life
Two or more functions in long regulation, and nutrition can be provided for crops or while there is offer nutrition and fertilizer and agriculture is improved
The multi-Functional Fertilizers of medicine utilization rate.Medicine fertilizer has agreed with the new demand of modern agriculture to a certain extent.Medicine and fertilizer unite two into one, will
Fertilising and work twice of going and buy Chinese medicine are integrated into and once worked, and are conducive to raising labour efficiency, liberating rural labour, reduction agricultural is raw
Produce the continuous surging pressure of cost.Therefore, develop and new have agricultural chemicals concurrently and the medicine fertilizer of fertilizer is significant.
Diacloden：English common name：Thiamethoxam, chemical name：3- (the chloro- 1,3- thiazoles -5- Ji Jia of 2-
Base) -5- methyl isophthalic acids, 3,5- oxadiazines -4- bases fork (nitro) amine, molecular formula：C8H10ClN5O3S.It is the second of a kind of brand new
For nicotinoids high-efficient low toxicity insecticide, the anabasine insecticide developed in 1991 by Novartis Co., Ltd, its mechanism of action and pyrrole
Worm quinoline is similar, and alternative suppresses insect CNS nicotinic acetylcholine esterase acceptor, and then blocks insect maincenter god
Normal conduction through system, causes insect to occur dead during paralysis machine.Not only but with tagging, stomach toxicity, systemic activity, and tool
Have higher active, more preferable security, wider array of insecticidal spectrum and work fast, the features such as the lasting period is long, be substitution those
High to mammalian toxicity, to have residual and environmental problem organophosphor, carbamate, the preferable product of organochlorine insecticides
Kind.There is high activity to coleoptera, Diptera, Lepidoptera, especially homoptera pest, can effectively prevent and treat various aphids, leafhopper, fly
The insects such as lice class, aleyrodid, chafer larva, colorado potato bug, nematode, ground beetle, leaf miner and the chemical agriculture of knot polytype
Medicine produces the insect of resistance.With imidacloprid, Acetamiprid, Nitenpyram no interactions resistance.It can be not only used for cauline leaf process, at seed
Manage, can also be used for soil treatment.Suitable for crop be rice class crop, beet, rape, potato, cotton, Kidney bean, fruit tree, peanut,
Sunflower, soybean, tobacco and citrus etc..Used under recommended dose to crop safety, without poisoning.
Cyfloxylate：English common name：Cyfluthrin, chemical name：Alpha-cyano -3- phenoxy group -4- luorobenzyls
(1R, 3R) -3- (2,2- dichloroethylene) -2,2- dimethyl cyclopropane carboxylic acid's esters, molecular formula：C22H18Cl2FNO3.Visitd by Germany
Ear company develops, and with tagging and stomach poison function, the lasting period is long.Suitable for cotton, fruit tree, vegetables, tea tree, tobacco, soybean etc.
The desinsection of plant.Coleoptera, Semiptera, Homoptera and the squama on cereal crop, cotton, fruit tree and vegetables can effectively be prevented and treated
Wing mesh insect, such as stupid moth of bollworm, pink bollworm, tobacco budworm, anthonomus grandis, alfalfa weevil, cabbage butterfly, looper, apple,
The insects such as cabbage caterpillar, small apple moth, America mythimna separata, colorado potato bug, aphid, corn borer, cutworm.
Inventor has found Pesticidal combination Diacloden and fluorine chlorine by the checking of a large amount of indoor biometricses and field control effectiveness test
Cyano chrysanthemate is combined application with fertilizer, can not only play after the double effects of desinsection and fertilizer, and both compoundings than independent
Compared, all increased significantly in terms of insecticidal effect, crop yield with agricultural chemicals using chemical fertilizer, it is possible to decrease use cost,
Medicine section fertilizer is saved, labor cost is saved and high to crop safety.Diacloden and cyfloxylate Pesticidal combination are answered with fertilizer
The research matched somebody with somebody, so far, there is not yet relevant report.
The content of the invention
The purpose of the present invention is to propose to it is a kind of with synergistic function, can play desinsection and fertilizer double effects,
Use cost, section medicine section fertilizer are reduced, labor cost is saved and Diacloden and cyfluthrin chrysanthemum is contained to the high one kind of crop safety
The fertilizer granules of ester and its application.
The technical scheme is that：
A kind of fertilizer granules and its application containing Diacloden and cyfloxylate, it is characterised in that：It is described to contain Diacloden and fluorine
The fertilizer granules of cypermethrin are made up of the auxiliary element in pesticide activity component, fertilizer and Pesticide formulation.
Described fertilizer granules, it is characterised in that：Described pesticide activity component is Diacloden and cyfloxylate.
Described fertilizer granules, it is characterised in that：Described fertilizer is macroelement fertilizer, secondary nutrients, micro-
Secondary element fertilizer, organic fertilizer, amino acid fertilizer or its combination.
Described fertilizer granules, it is characterised in that：Auxiliary element in described Pesticide formulation is binding agent, carried
Body or its combination.
Described fertilizer granules, it is characterised in that：The composition of each composition is Diacloden 0.01-20%, cyfloxylate
0.01-10%, fertilizer 10-50% and pesticidal preparations auxiliary element surplus.
Described fertilizer granules have the purposes of preventing and treating subterranean pest-insect, especially to grub, cutworm, mole cricket, wireworm
With good prevention effect.
Described fertilizer granules are used for the purposes increased production.
The present invention has the advantage that：
Firstth, the invention provides a kind of fertilizer granules containing Diacloden and cyfloxylate and its application, by Diacloden, fluorine
Cypermethrin, fertilizer and auxiliary agent are prepared from.
Secondth, the present invention is initiative compounds Diacloden, cyfloxylate and fertilizer, forms fertilizer granules, be by
Fertilising and insect prevention are combined, while having reached insect prevention, the effect of volume increase.
3rd, fertilizer granules provided by the present invention are easy to use, also applied fertilizer, reduced while dispenser
Labor intensity, reaches the purpose of time and labour saving.
4th, after fertilizer granules provided by the present invention are applied, the growth of crop is promoted, the immune of crop is improved
Power, enhances the ability for resisting pest and disease damage, prevention effect is improved indirectly.
5th, the slow releasing function of fertilizer granules provided by the present invention, extends the lasting period, reduces whole breeding time
Pesticide dosage, can reach reduction environmental pollution, reduce use cost.
6th, there is directionality, drift is small, and environmental pollution is small during fertilizer granules dispenser provided by the present invention；
It is not attached on the cauline leaf of plant, it is to avoid directly contact produces poisoning etc..
Embodiment
With reference to embodiment to further instruction of the present invention, the percentage in embodiment is weight percentage, but
The invention is not limited in this.
Implementation of an application example one：Pesticide activity component Diacloden, cyfloxylate and fertilizer compound product example of formulations（With
Lower content is hundred percentage compositions of folding）, but the present invention is not limited to the proportion in following examples.
It is sufficiently mixed after pesticide activity component Diacloden, cyfloxylate and binding agent are crushed, agricultural chemicals is fully adsorbed
On binding agent, crushed by pulverizer；When fertilizer is crushed into certain fineness, Diacloden, cyfluthrin chrysanthemum after addition crushing
Ester and carrier, are granulated after being sufficiently mixed, you can Diacloden cyfloxylate fertilizer granules are made.
The Diacloden cyfloxylate fertilizer granules of embodiment 1 0.09%
Diacloden 0.08%, cyfloxylate 0.01%, macroelement fertilizer 40%, binding agent 5%, supply surplus.
The Diacloden cyfloxylate fertilizer granules of embodiment 2 0.1%
Diacloden 0.08%, cyfloxylate 0.02%, macroelement fertilizer 25%, binding agent 5%, supply surplus.
The Diacloden cyfloxylate fertilizer granules of embodiment 3 0.6%
Diacloden 0.5%, cyfloxylate 0.1%, a great number of elements 30%, moderate-element 10%, binding agent 5%, supply surplus.
The Diacloden cyfloxylate fertilizer granules of embodiment 4 1%
Diacloden 0.5%, cyfloxylate 0.5%, a great number of elements 30%, trace element 10%, binding agent 6%, supply surplus.
The Diacloden cyfloxylate fertilizer granules of embodiment 5 2%
Diacloden 1.5%, cyfloxylate 0.5%, trace element 5%, amino acid/11 0%, binding agent 6%, supply surplus.
The Diacloden cyfloxylate fertilizer granules of embodiment 6 7%
Diacloden 6%, cyfloxylate 1%, humic acid 30%, binding agent 6%, supply surplus.
The Diacloden cyfloxylate fertilizer granules of embodiment 7 15%
Diacloden 10%, cyfloxylate 5%, amino acid 30%, binding agent 8%, supply surplus.
Implementation of an application example two：
The field control effectiveness test of pesticide activity component Diacloden, cyfloxylate and fertilizer compounding
Field information embodiment 1 prevents and treats the field control effectiveness test of wheat grub
Test site：This test arrangement is chosen insect and caused harm heavier plot in Shanxi Province Linyi County.
Subjects：Wheat grub
Test method：Test medicine, comparison medicament and the processing of the cell of blank control use random alignment, and each cell is minimum
66.6 m2, 4 repetitions are often handled, blank control is used as using the processing of equivalent clear water.Application process is to spread fertilizer over the fields.
Investigation and statistical method：
Aggrieved strain rate investigation：The 5 points of samplings of each cell of the dense planting crop test such as wheat " Z " font, it is long per sampling point 1m ridges, look into sampling point
The victimization states such as interior total strain number, dead strain number；The larger crop of the spacing in the rows such as crop such as corn, sorghum, can be according to plot area depending on,
It is total in sampling investigation cell if plot area is compared with total seedling number and affected seedling number is investigated in the I whole district, if plot area is larger
/ to two/3rds of seedling number, investigates total strain number and aggrieved strain respectively.While investigating aggrieved strain, according to killed shape,
Pest species are recorded respectively.
Insect density is investigated：Mainly cut the earth sampling survey, method is 5 points of samplings of " Z " font, every 50cm in every cell
×5 0cm(2500 cm2), digging depth typically can be advisable with 30cm depending on temperature.When spring is investigated, wait as far as possible
Depths, which is survived the winter after worm moves up or moved up substantially, to be carried out, and worm amount and worm kind in unit area are recorded in detail.
Control time and number of times：The control time of various crops is different with number of times, and twice, wheat paddock exists first for look-see
Insemination and emergence investigates dead seedling situation in latter month, and Adult plant reinvestigates an extent of injury.Spring sowing thinning crop is typically going out
Investigate once, looked into again once in two weeks after final singling before after seedling final singling.After harvesting, determination of yield is carried out, its rate of growth is calculated.
Attacked trees rate（%）=（Killed strain number/investigation total strain number）×100%；
Preventive effect（%）=[（Blank district attacked trees rate-chemicals treatment district attacked trees rate）/ blank district attacked trees rate] ×
100%
Rate of growth（%）=（Chemicals treatment yield-blank control yield）/ blank control yield × 100%
As can be known from Table 1, Diacloden of embodiment of the present invention cyfloxylate fertilizer granules preventive effect on preventing and treating wheat grub shows
Write, preventive effect is above 98%, preventive effect is up to 98.51% ~ 99.77%；It is notable to wheat increase yield, rate of growth up to 30.35% ~ 36.70%, and
The rate of growth of fertilizer is 7.12% ~ 9.27%.Field test results fully show, Diacloden cyfloxylate fertilizer granules pair
Wheat grub has synergistic function, can play the double effects of desinsection and fertilizer, right in the range of this experiment dosage
Wheat safety, has no adverse effects.
Field information embodiment 2 prevents and treats the field control effectiveness test of peanut mole cricket
Test site：This test arrangement is chosen insect and caused harm heavier plot in Shanxi Province Linyi County.
Subjects：Peanut mole cricket
Test method：Test medicine, comparison medicament and the processing of the cell of blank control use random alignment, and each cell is minimum
66.6 m2, 4 repetitions are often handled, blank control is used as using the processing of equivalent clear water.Application process is to spread fertilizer over the fields.
Investigation and statistical method：
Aggrieved strain rate investigation：The 5 points of samplings of each cell " Z " font are tested, it is long per sampling point 1m ridges, look into total strain number in sampling point, dead strain number
Deng victimization state.While investigating aggrieved strain, according to killed shape, pest species are recorded respectively.
Insect density is investigated：Mainly cut the earth sampling survey, method is 5 points of samplings of " Z " font, every 50cm in every cell
×5 0cm(2500 cm2), digging depth typically can be advisable with 30cm depending on temperature.When spring is investigated, wait as far as possible
Depths, which is survived the winter after worm moves up or moved up substantially, to be carried out, and worm amount and worm kind in unit area are recorded in detail.
Control time and number of times：The control time of various crops is different with number of times, and twice, wheat paddock exists first for look-see
Insemination and emergence investigates dead seedling situation in latter month, and Adult plant reinvestigates an extent of injury.Spring sowing thinning crop is typically going out
Investigate once, looked into again once in two weeks after final singling before after seedling final singling.After harvesting, determination of yield is carried out, its rate of growth is calculated.
Attacked trees rate（%）=（Killed strain number/investigation total strain number）×100%；
Preventive effect（%）=[（Blank district attacked trees rate-chemicals treatment district attacked trees rate）/ blank district attacked trees rate] ×
100%
Rate of growth（%）=（Chemicals treatment yield-blank control yield）/ blank control yield × 100%
As can be known from Table 2, Diacloden of embodiment of the present invention cyfloxylate fertilizer granules preventive effect on preventing and treating peanut mole cricket shows
Write, preventive effect is above 94%, preventive effect is up to 94.45% ~ 96.04%；It is notable to peanut yield increasing, rate of growth up to 20.23% ~ 30.01%, and
The rate of growth of fertilizer is 5.92% ~ 7.81%.Field test results fully show, Diacloden cyfloxylate fertilizer granules pair
Peanut mole cricket has synergistic function, can play the double effects of desinsection and fertilizer, right in the range of this experiment dosage
Peanut safety, has no adverse effects.
Field information embodiment 3 prevents and treats the field control effectiveness test of cotton cutworm
Test site：This test arrangement is chosen insect and caused harm heavier plot in Shanxi Province Linyi County.
Subjects：Cotton cutworm
Test method：Test medicine, comparison medicament and the processing of the cell of blank control use random alignment, and each cell is minimum
66.6 m2, 4 repetitions are often handled, blank control is used as using the processing of equivalent clear water.Application process is to spread fertilizer over the fields.
Investigation and statistical method：
Aggrieved strain rate investigation：/ to two/3rds of total seedling number in cell is investigated, total strain number and aggrieved strain are investigated respectively.
While investigating aggrieved strain, according to killed shape, pest species are recorded respectively.
Insect density is investigated：Mainly cut the earth sampling survey, method is 5 points of samplings of " Z " font, every 50cm in every cell
×5 0cm(2500 cm2), digging depth typically can be advisable with 30cm depending on temperature.When spring is investigated, wait as far as possible
Depths, which is survived the winter after worm moves up or moved up substantially, to be carried out, and worm amount and worm kind in unit area are recorded in detail.
Control time and number of times：The control time of various crops is different with number of times, and twice, wheat paddock exists first for look-see
Insemination and emergence investigates dead seedling situation in latter month, and Adult plant reinvestigates an extent of injury.Spring sowing thinning crop is typically going out
Investigate once, looked into again once in two weeks after final singling before after seedling final singling.After harvesting, determination of yield is carried out, its rate of growth is calculated.
Attacked trees rate（%）=（Killed strain number/investigation total strain number）×100%；
Preventive effect（%）=[（Blank district attacked trees rate-chemicals treatment district attacked trees rate）/ blank district attacked trees rate] ×
100%
Rate of growth（%）=（Chemicals treatment yield-blank control yield）/ blank control yield × 100%
As can be known from Table 3, Diacloden of embodiment of the present invention cyfloxylate fertilizer granules preventive effect on preventing and treating cotton cutworm
Significantly, preventive effect is above 98%, and preventive effect is up to 98.12% ~ 99.51%；It is notable to Yield Increase In Cotton, rate of growth up to 30.74% ~ 32.35%,
And the rate of growth of fertilizer is 8.09% ~ 9.74%.Field test results fully show, Diacloden cyfloxylate fertilizer granules
There is synergistic function to cotton cutworm, the double effects of desinsection and fertilizer can be played, in this experiment dosage scope
It is interior, to cotton safety, have no adverse effects.
Field information embodiment 4 prevents and treats the field control effectiveness test of corn wireworm
Test site：This test arrangement is chosen insect and caused harm heavier plot in Shanxi Province Linyi County.
Subjects：Corn wireworm
Test method：Test medicine, comparison medicament and the processing of the cell of blank control use random alignment, and each cell is minimum
66.6 m2, 4 repetitions are often handled, blank control is used as using the processing of equivalent clear water.Application process is to spread fertilizer over the fields.
Investigation and statistical method：
Aggrieved strain rate investigation：/ to two/3rds of total seedling number in cell is investigated, total strain number and aggrieved strain are investigated respectively.
While investigating aggrieved strain, according to killed shape, pest species are recorded respectively.
Insect density is investigated：Mainly cut the earth sampling survey, method is 5 points of samplings of " Z " font, every 50cm in every cell
×5 0cm(2500 cm2), digging depth typically can be advisable with 30cm depending on temperature.When spring is investigated, wait as far as possible
Depths, which is survived the winter after worm moves up or moved up substantially, to be carried out, and worm amount and worm kind in unit area are recorded in detail.
Control time and number of times：The control time of various crops is different with number of times, and twice, wheat paddock exists first for look-see
Insemination and emergence investigates dead seedling situation in latter month, and Adult plant reinvestigates an extent of injury.Spring sowing thinning crop is typically going out
Investigate once, looked into again once in two weeks after final singling before after seedling final singling.After harvesting, determination of yield is carried out, its rate of growth is calculated.
Attacked trees rate（%）=（Killed strain number/investigation total strain number）×100%；
Preventive effect（%）=[（Blank district attacked trees rate-chemicals treatment district attacked trees rate）/ blank district attacked trees rate] ×
100%
Rate of growth（%）=（Chemicals treatment yield-blank control yield）/ blank control yield × 100%
As can be known from Table 4, Diacloden of embodiment of the present invention cyfloxylate fertilizer granules preventive effect on preventing and treating corn wireworm
Significantly, preventive effect is above 97%, and preventive effect is up to 97.12% ~ 99.45%；It is notable to corn yield increasing, rate of growth up to 23.46% ~ 28.24%,
And the rate of growth of fertilizer is 7.46% ~ 9.96%.Field test results fully show, Diacloden cyfloxylate fertilizer granules
There is synergistic function to corn wireworm, the double effects of desinsection and fertilizer can be played, in this experiment dosage scope
It is interior, to corn safety, have no adverse effects.
In summary, Diacloden cyfloxylate fertilizer granules of the present invention, to subterranean pest-insect wheat grub,
Corn wireworm, cotton cutworm, peanut mole cricket have synergistic function, can play the double effects of desinsection and fertilizer.
Claims (7)
1. a kind of fertilizer granules and its application containing Diacloden and cyfloxylate, it is characterised in that：It is described containing Diacloden and
The fertilizer granules of cyfloxylate are made up of the auxiliary element in pesticide activity component, fertilizer and Pesticide formulation.
2. fertilizer granules according to claim 1, it is characterised in that：Described pesticide activity component is Diacloden and fluorine
Cypermethrin.
3. the fertilizer granules according to claim 1 to 2, it is characterised in that：Described fertilizer be macroelement fertilizer, in
Secondary element fertilizer, trace-element fertilizer, organic fertilizer, amino acid fertilizer or its combination.
4. the fertilizer granules according to claims 1 to 3, it is characterised in that：Auxiliary in described Pesticide formulation
Composition is binding agent, carrier or its combination.
5. the fertilizer granules according to Claims 1-4, it is characterised in that：The composition of each composition is Diacloden 0.01-
20%th, cyfloxylate 0.01-10%, fertilizer 10-50% and pesticidal preparations auxiliary element surplus.
6. fertilizer granules according to claim 1 to 5 have the purposes of preventing and treating subterranean pest-insect, especially to grub, it is old
Tiger, mole cricket, wireworm have good prevention effect.
7. the fertilizer granules according to claim 1 to 6 are used for the purposes increased production.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710547796.6A CN107258808A (en) | 2017-07-06 | 2017-07-06 | A kind of fertilizer granules and its application containing Diacloden and cyfloxylate |
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| CN201710547796.6A CN107258808A (en) | 2017-07-06 | 2017-07-06 | A kind of fertilizer granules and its application containing Diacloden and cyfloxylate |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112500238A (en) * | 2021-01-08 | 2021-03-16 | 中诚国联（河南）生物科技有限公司 | High tower pesticide-fertilizer containing imidacloprid and cyfluthrin and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN112500238A (en) * | 2021-01-08 | 2021-03-16 | 中诚国联（河南）生物科技有限公司 | High tower pesticide-fertilizer containing imidacloprid and cyfluthrin and preparation method thereof |
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