CN107254253B - A kind of painting and calligraphy fixing material and its preparation method and application - Google Patents
A kind of painting and calligraphy fixing material and its preparation method and application Download PDFInfo
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- CN107254253B CN107254253B CN201710536717.1A CN201710536717A CN107254253B CN 107254253 B CN107254253 B CN 107254253B CN 201710536717 A CN201710536717 A CN 201710536717A CN 107254253 B CN107254253 B CN 107254253B
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D189/00—Coating compositions based on proteins; Coating compositions based on derivatives thereof
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B44—DECORATIVE ARTS
- B44D—PAINTING OR ARTISTIC DRAWING, NOT OTHERWISE PROVIDED FOR; PRESERVING PAINTINGS; SURFACE TREATMENT TO OBTAIN SPECIAL ARTISTIC SURFACE EFFECTS OR FINISHES
- B44D7/00—Preserving paintings, e.g. by varnishing
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/10—Transparent films; Clear coatings; Transparent materials
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The present invention provides a kind of painting and calligraphy fixing material, the component including following mass fraction: 5 parts of fish glue, 1 part of water soluble chitosan, 0.1 part of konjaku glucomannan, 1~2 part of potassium sorbate.Painting and calligraphy fixing material provided by the invention has good weatherability, and it is easy to use, fixing property is excellent, statistics indicate that, after 72h hydrothermal aging, the color difference Δ E of painting and calligraphy fixing material provided by the invention is 3.35, pH value reduced rate is 6.3%, tensile strength (cross) retention rate is 93.6%, tensile strength (vertical) retention rate is 98.2%, tearability (cross) retention rate is 81.3%, tearability (vertical) retention rate is 81.25%, folding strength (cross) is 60%, (vertical) folding strength is 53.6%, compared with traditional glue alum water fixing material, anti-tensile retention rate is higher by 4.1%, folding strength retention rate is higher by 13.4%, tearability retention rate low 14.3%, chromatic aberration is smaller, pH value reduced rate is substantially less than control sample.
Description
Technical field
The present invention relates to traditional painting and calligraphy fixation technical field more particularly to a kind of painting and calligraphy fixing material and preparation method thereof and
Using.
Background technique
In traditional painting and calligraphy Conservative restoration, plastic alum water often is prepared with the animal glue such as oxhide gelatin and alum, for fixing face
Color and prevent mass colour is dizzy from dissipating etc..The long period can be needed due to colloidal sol, Jiao Fanshui configuration is inconvenient,
The concentration and expection often configured understands difference.Development and painting and calligraphy class historical relic with modern material technology
Conservative restoration research is goed deep into, and more and more painting and calligraphy Conservative restoration workers have gradually recognized that Jiao Fanshui is long to painting and calligraphy historical relic
The drawbacks of phase saves, especially the alum in glue alum water easily leads to traditional paper acidizing corrosion, accelerates the rate of its aging.
Currently, the alternative materials of Jiao Fanshui mainly have natural polymer, change in related painting and calligraphy protection fixing material both at home and abroad
Property natural polymer and synthesis macromolecule, such as Shanghai Museum of Art and History Xu Wenjuan and its seminar " soybean milk water is in Chinese Painting and Calligraphy
Application and research in reparation " in disclose and Jiao Fanshui can be substituted using soybean milk water, applied to the panchromatic link of painting and calligraphy,
When Doris A.Hambury repairs French landscape wallpaper, selected methylcellulose pigment is reinforced (referring to
《The In-situ Conservation Treament of a Nineteenth-Century French Scenic
Wallpaper:Les Paysages de Telemaque dans L ' ile de calypso ", DA Hamburg, Journal
Ofthe American Institute for Conserva., 1981,20 (2): 91~99), Frederick is repairing Yi Si
1.5% N methoxymethyl nylon methanol solution has been used to reinforce (referring to " The Repair pigment when blue handwritten book
ofIslamic Illuminated Manuscript Leaves and the Conservation ofPalm-
LeafManuscripts ", Marsh F, International Symposium on the Conservation and
Restoration of Cultural Property:conservation ofFar Eastern art objects:
November 26-29,1979, Tokyo, Japan (1980) pp.3~16).It is high with going deep into for historical relic's protection investigation of materials
Molecular application gradually appears in the drawbacks of historical relic, and wherein weatherability is poor becomes synthesis macromolecule fixing material major defect.
Summary of the invention
In view of this, the purpose of the present invention is to provide a kind of good weatherabilities, painting and calligraphy easy to use, fixing property is excellent
Fixing material.
In order to achieve the above-mentioned object of the invention, the present invention the following technical schemes are provided:
A kind of painting and calligraphy fixing material, the component including following mass fraction:
5 parts of fish glue, 1 part of water soluble chitosan, 0.1 part of konjaku glucomannan, 1~2 part of potassium sorbate.
Preferably, the relative molecular mass of the water soluble chitosan is 2 × 104~10 × 104。
Preferably, the relative molecular mass of the konjaku glucomannan is 20 × 104~200 × 104。
The present invention also provides the preparation methods of painting and calligraphy fixing material described in above-mentioned technical proposal, comprising the following steps:
It is dry after fish glue, water soluble chitosan, konjaku glucomannan, potassium sorbate and water are mixed, it is solid to obtain painting and calligraphy
Color material.
Preferably, the drying is vacuum freeze drying, and the temperature of the vacuum freeze drying is -50~-30 DEG C.
The present invention also provides preparation methods described in painting and calligraphy fixing material described in above-mentioned technical proposal or above-mentioned technical proposal
Application of the obtained painting and calligraphy fixing material in painting and calligraphy fixation, the dosage of the painting and calligraphy fixing material are 1.5~2g/m2。
Preferably, painting and calligraphy fixation is used for after the painting and calligraphy fixing material is mixed with water.
Preferably, the mass ratio of the painting and calligraphy fixing material and water is 1:50~100.
The present invention provides a kind of painting and calligraphy fixing material, the component including following mass fraction: 5 parts of fish glue, water soluble shells
1 part of glycan, 0.1 part of konjaku glucomannan, 1~2 part of potassium sorbate.In the present invention, the fish glue transparent color and luster, viscosity are preferable,
The best performance in animal glue；Water soluble chitosan is a kind of basic natural polysaccharides, can be used for Cypres, improves paper
Mechanical strength；Konjaku glucomannan is a kind of natural plant gum, and viscosity is higher, has good film forming；Potassium sorbate is as a kind of
Food grade preservative has the function of resistance to corruption.Painting and calligraphy fixing material provided by the invention has good weatherability, and fixation
Have excellent performance, embodiment statistics indicate that, after 72h hydrothermal aging, use the color difference of painting and calligraphy fixing material provided by the invention
Δ E is 3.35, pH value reduced rate is 6.3%, tensile strength (cross) retention rate is that 93.6%, tensile strength (vertical) retention rate is
98.2%, tearability (cross) retention rate is 81.3%, tearability (vertical) retention rate is 81.25%, folding strength (cross) is 60%, resistance to
(vertical) folding degree is 53.6%, and compared with traditional glue alum water fixing material, anti-tensile retention rate is higher by 4.1%, folding strength retention rate
It is higher by 13.4%, tearability retention rate low 14.3%, chromatic aberration is smaller, and pH value is substantially less than control sample.
Also, when being used for painting and calligraphy fixation using painting and calligraphy fixing material provided by the invention, dosage is small, greatly reduces into
This, and it is easy to use, colour fixation is excellent, avoids the dizzy scattered problem of the mass colour easily occurred in the prior art.
Detailed description of the invention
The present invention will be further described in detail below with reference to the accompanying drawings and specific embodiments.
Fig. 1 is the microscope test chart in 1 portrait painting of the embodiment of the present invention before the fixation of red cinnabar position；
Fig. 2 is the microscope test chart in 1 portrait painting of the embodiment of the present invention after the fixation of red cinnabar position；
Fig. 3 is the microscope test chart in 1 portrait painting of the embodiment of the present invention before the fixation of blue gypsum position；
Fig. 4 is the microscope test chart in 1 portrait painting of the embodiment of the present invention after the fixation of blue gypsum position.
Specific embodiment
A kind of painting and calligraphy fixing material, the component including following mass fraction:
5 parts of fish glue, 1 part of water soluble chitosan, 0.1 part of konjaku glucomannan, 1~2 part of potassium sorbate.
Painting and calligraphy fixing material provided by the invention preferably includes 1 part of potassium sorbate.In the present invention, the potassium sorbate is
It is preservative, has the function of resistance to corruption, can effectively inhibit the activity of the aerobic microbiologicals such as mould, there is biological safety, and
Adverse effect will not be caused to painting and calligraphy ontology.
In the present invention, the fish glue transparent color and luster, viscosity are preferable, and performance is more excellent in animal glue, while meeting painting and calligraphy text
Requirement after object reparation to transparency.
In the present invention, the water soluble chitosan is a kind of basic natural polysaccharides, can be used for Cypres, improves paper
Mechanical strength.
In the present invention, the relative molecular mass of the water soluble chitosan is 2 × 104~10 × 104, more preferably 3 ×
104~6 × 104。
In the present invention, the relative molecular mass of the konjaku glucomannan is 20 × 104~200 × 104, more preferably
30×104~100 × 104.In the present invention, the konjaku glucomannan has good filming as thickener.
The present invention is not special to the source of the fish glue, water soluble chitosan, konjaku glucomannan and potassium sorbate
Restriction, using commercial goods well known to those skilled in the art.
The present invention also provides the preparation methods of painting and calligraphy fixing material described in above-mentioned technical proposal, comprising the following steps:
It is dry after fish glue, water soluble chitosan, konjaku glucomannan, potassium sorbate and water are mixed, it is solid to obtain painting and calligraphy
Color material.
The present invention mixes fish glue, water soluble chitosan, konjaku glucomannan, potassium sorbate and water, obtains mixture
Material.The present invention is to the charging sequence of the fish glue, water soluble chitosan, konjaku glucomannan, potassium sorbate and water without spy
Different restriction, using raw material addition sequence well known to those skilled in the art.In the present invention, the fish glue, water solubility
Chitosan, konjaku glucomannan, potassium sorbate and water mixing preferably include following steps:
(1) fish glue is mixed with water, obtains fish gelatin solution；
(2) it mixes after heating the fish gelatin solution that the step (1) obtains with water soluble chitosan, is then separated by solid-liquid separation,
It obtains reinforcing liquid；
(3) it mixes, is mixed with konjaku glucomannan and potassium sorbate after heating the reinforcing liquid that the step (2) obtains
Close material.
The present invention preferably mixes fish glue with water, obtains fish gelatin solution.In the present invention, the quality of the fish gelatin solution point
Number preferably 0.5%.
After obtaining fish gelatin solution, the present invention is mixed after preferably heating fish gelatin solution with water soluble chitosan, is separated by solid-liquid separation,
It obtains reinforcing liquid.In the present invention, fish gelatin solution heating can be made into fish glue dissolution sufficiently, is conducive to accelerate dissolution water-soluble
Property chitosan.
In the present invention, the heating temperature of the fish gelatin solution is preferably 50~80 DEG C, and more preferably 60~70 DEG C；This hair
The bright heating time to the fish gelatin solution does not have special restriction, and fish gelatin solution can be made to reach the heating temperature；
The present invention does not have special restriction to the mode of the heating, using heating method well known to those skilled in the art, originally
Invention preferably uses heating water bath.
After the completion of heating, the present invention preferably mixes the fish gelatin solution after the heating with water soluble chitosan, solid-liquid point
From, obtain reinforce liquid.It is special that the present invention does not have the charging sequence of fish gelatin solution and water soluble chitosan after the heating
It limits, using charging sequence well known to those skilled in the art.
The present invention does not have special restriction to the mixed mode, using hybrid mode well known to those skilled in the art
, the present invention preferably stirring.The present invention does not have special restriction to the revolving speed of the stirring, and feed liquid can be made to be uniformly mixed
?；In the present invention, the temperature of the stirring is preferably 50~80 DEG C, and more preferably 60~70 DEG C；The time of the stirring
Preferably 15~30min, more preferably 20~25min.
After the completion of mixing, the mixed product is preferably separated by solid-liquid separation by the present invention, obtains reinforcing liquid.In the present invention
In, the separation of solid and liquid can remove insoluble sediment.It is special that the present invention does not have the concrete mode of the separation of solid and liquid
It limits, preferably filters in the present invention.
It obtains after reinforcing liquid, the present invention will mix after preferably reinforcing liquid heating with konjaku glucomannan and potassium sorbate, obtain
To mixed material.In the present invention, by reinforcing liquid heating can konjaku glucomannan and potassium sorbate dissolve it is abundant.
In the present invention, the heating temperature for reinforcing liquid is preferably 30~50 DEG C, and more preferably 35~45 DEG C；The present invention
There is no special restriction to the heating time for reinforcing liquid, reinforcing liquid can be made to reach the heating temperature；The present invention
There is no special restriction to the mode of the heating, using heating method well known to those skilled in the art, the present invention is excellent
Choosing uses heating water bath.
It reinforces after the completion of liquid heating, the present invention is preferably by the reinforcing liquid and konjaku glucomannan and sorbic acid after the heating
Potassium mixing, obtains mixed material.
The present invention does not have special restriction to the mixed mode, using hybrid mode well known to those skilled in the art
, the present invention preferably stirring, the present invention do not have special restriction to the revolving speed of the stirring, time, feed liquid can be made mixed
It closes uniform；In the present invention, the temperature of the stirring is preferably 30~50 DEG C, and more preferably 35~45 DEG C.
After obtaining mixed material, the present invention is dry by the mixed material, obtains painting and calligraphy fixing material.In the present invention,
The drying is preferably vacuum freeze drying, and preferably -50~-30 DEG C of the temperature of the vacuum freeze drying, more preferably -40
~-35 DEG C, the time of the vacuum freeze drying is preferably 48~72h, more preferably preferably 55~65h；The vacuum is cold
It is preferably 1.3~13Pa that dry pressure, which is lyophilized, more preferably 5~10Pa.
The painting and calligraphy fixing material that the present invention obtains is the white crystalline powder for being instantly dissolved in water.
The present invention also provides preparation methods described in painting and calligraphy fixing material described in above-mentioned technical proposal or above-mentioned technical proposal
Application of the obtained painting and calligraphy fixing material in painting and calligraphy fixation.In the present invention, the dosage of the painting and calligraphy fixing material is preferably
1.5~2g/m2, more preferably 1.8~2g/m2。
The present invention is used for painting and calligraphy fixation after preferably mixing the painting and calligraphy fixing material with water, the painting and calligraphy fixing material with
The mass ratio of water is preferably 1:50~100:, more preferably 1:80~100.
After painting and calligraphy fixing material and water are mixed to get color fixing agent, the present invention is preferably also included in the color fixing agent and second is added
Alcohol, the quality of the ethyl alcohol are preferably the 5~10% of color fixing agent quality, more preferably 7.5~8%.In the present invention, the second
Alcohol has better penetration reinforcement effect as penetration-assisting agent, to painting and calligraphy color.
Specific reinforcing mode of the present invention to the painting and calligraphy fixing material for painting and calligraphy fixation does not have special restriction, uses
Reinforcing mode well known to those skilled in the art.In embodiments of the present invention, preferably by painting and calligraphy fixing material, water and ethyl alcohol
After mixing, the reinforcing mode for passing sequentially through atomizing spraying and brushing carries out fixation.In the present invention, the atomizing spraying can be real
Existing pre-reinforcement effect is completely immersed in pigment to painting and calligraphy fixing material, water and the mixed product of ethyl alcohol, reuses writing brush after dry
Brushing painting and calligraphy fixing material, water and the mixed product of ethyl alcohol.The present invention is to painting and calligraphy fixation material in the atomizing spraying and brushing
The dosage of material, water and the mixed product of ethyl alcohol does not have special restriction, and those skilled in the art can select according to actual needs
The dosage of painting and calligraphy fixing material, water and the mixed product of ethyl alcohol in selecting atomizing spraying and brushing.The present invention sprays the atomization
The design parameter for applying and brushing does not have special restriction, can make painting and calligraphy fixing material, water and the mixed product dispersion of ethyl alcohol
Uniformly.
Painting and calligraphy fixing material provided by the invention and its preparation method and application is carried out below with reference to embodiment detailed
Illustrate, but they cannot be interpreted as limiting the scope of the present invention.
Embodiment 1
It configures fish glue 5g to distilled water 0.5% aqueous solution, obtains fish gelatin solution, fish gelatin solution is heated to 80 DEG C
Afterwards, the water soluble chitosan for adding 1g forms blended liquid, and reinforcing liquid is obtained by filtration after stirring 30 minutes at 80 DEG C.It will reinforce
After liquid is heated to 50 DEG C, the konjaku glucomannan of 0.1g, the potassium sorbate of 1g is added, stirred at 80 DEG C 15 minutes to completely it is molten
Solution, obtain mixed material, then by mixed material 1.3Pa, temperature be -50 DEG C at carry out vacuum freeze drying 48h, obtain white
Color crystalline powder, i.e. painting and calligraphy fixing material.
Embodiment 2
Mixed liquor is obtained after painting and calligraphy fixing material, 100g water and 10g ethyl alcohol in 2g embodiment 1 is mixed, painting and calligraphy are solid
Color material can be instantly dissolved in water, atomizing spraying be carried out to the portrait painting containing red cinnabar and blue gypsum of 1m*1m, to mixed
It closes after liquid has been completely immersed in pigment, drying and reuses writing brush brushing mixed liquor, complete fixation.
Micro- test is carried out before and after fixation containing red cinnabar position in portrait painting, Fig. 1 is that red cinnabar position is solid
Microscope test chart before color, Fig. 2 are the microscope test chart after the fixation of red cinnabar position；To containing blue stone in portrait painting
Cream position carries out micro- test before and after fixation, and Fig. 3 is the microscope test chart before the fixation of blue gypsum position, and Fig. 4 is blue
Microscope test chart after the fixation of gypsum position.The fixing material that the present embodiment improves it can be seen from Fig. 1~4 permeates substantially
Into in portrait painting coat of colo(u)r, pigment layer surface, which eliminates, to warp and cracking phenomena, is rendered as the state of smooth, soft, has illustrated
The effect of effective reinforcing pigment is arrived.
Mixed liquor is obtained after painting and calligraphy fixing material, 100g water and 10g ethyl alcohol in 2g embodiment 1 is mixed, to 1m*1m
Rice paper brushed, 80 DEG C, humidity be 65% under conditions of carry out hydrothermal aging experiment.After 72h hydrothermal aging, survey
Test result is as follows: color difference Δ E=3.35；PH value reduced rate η %=(pattern pH value after unaged pattern pH value-aging)/not old
Change pattern pH value=6.3%；Pattern tensile strength/unaged pattern anti-tensile is strong after the η %=aging of tensile strength (cross) retention rate
Degree=93.6%, tensile strength (vertical) retention rate η %=98.2%；Pattern is torn after the η %=aging of tearability (cross) retention rate
Degree/unaged pattern tearability=81.3%, tearability (vertical) retention rate η %=81.25%；Folding strength (cross) η %=aging
Pattern folding strength/unaged pattern folding strength=60% afterwards, folding strength (vertical)=53.6%.Specific data are as shown in table 1.
Fixing material hydrothermal aging experimental results made from 1 embodiment 1 of table
Wherein, L- represents black and white departure；Then table is partially white for positive number, and then table is partially black for negative；
A- represents red green departure；Then table is partially red for positive number, and then table is partially green for negative；
B- represents champac departure；Then table is partially yellow for positive number, and then table is partially blue for negative.
Comparative example
It is mixed to prepare traditional fixing material with 5g gelatin, 0.75g alum, is tested for rice paper hydrothermal aging, hydrothermal aging
Experiment condition is in the same manner as in Example 1；Hydrothermal aging experiment directly is carried out to rice paper, as blank example, hydrothermal aging tests item
Part is in the same manner as in Example 1, to the anti-tensile retention rate of the rice paper after hydrothermal aging experiment, folding retention rate, tearing retention rate, color
Difference and pH value reduced rate are calculated, and the results are shown in Table 2.
The different fixing material hydrothermal aging experimental results of table 2
| Sample situation | Anti-tensile retention rate | Folding retention rate | Tear retention rate | Value of chromatism | PH value reduced rate |
| Blank example | 91.1% | 61.4% | 98.0% | 3.9 | 12.4% |
| Comparative example | 91.8% | 43.4% | 95.6% | 5.4 | 23.2% |
| Embodiment 1 | 95.9% | 56.8% | 81.3% | 3.4 | 6.3% |
As can be seen from Table 2, fixing material anti-tensile retention rate made from embodiment 1 is higher by 4.1% compared with comparative example, folding strength
Degree retention rate is higher by 13.4% compared with comparative example, tearability retention rate low compared with comparative example 14.3%, chromatic aberration then with blank sample phase
Closely, pH value reduced rate is substantially less than blank sample and comparative example.
The above is only a preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art
For member, various improvements and modifications may be made without departing from the principle of the present invention, these improvements and modifications are also answered
It is considered as protection scope of the present invention.
Claims (8)
1. a kind of painting and calligraphy fixing material, the component including following mass fraction:
5 parts of fish glue, 1 part of water soluble chitosan, 0.1 part of konjaku glucomannan, 1~2 part of potassium sorbate.
2. painting and calligraphy fixing material according to claim 1, which is characterized in that the average molecular matter of the water soluble chitosan
Amount is 2 × 104~10 × 104。
3. painting and calligraphy fixing material according to claim 1, which is characterized in that the average molecular matter of the konjaku glucomannan
Amount is 20 × 104~200 × 104。
4. the preparation method of painting and calligraphy fixing material described in claims 1 to 3 any one, comprising the following steps:
It is dry after fish glue, water soluble chitosan, konjaku glucomannan, potassium sorbate and water are mixed, obtain painting and calligraphy fixation material
Material.
5. the preparation method according to claim 4, which is characterized in that the drying is vacuum freeze drying, the vacuum
The temperature of freeze-drying is -50~-30 DEG C.
6. preparation method described in painting and calligraphy fixing material or claim 4~5 any one described in claims 1 to 3 any one
Application of the obtained painting and calligraphy fixing material in painting and calligraphy fixation, the dosage of the painting and calligraphy fixing material are 1.5~2g/m2。
7. application according to claim 6, which is characterized in that the painting and calligraphy fixing material is solid for painting and calligraphy after mixing with water
Color.
8. application according to claim 7, which is characterized in that the mass ratio of the painting and calligraphy fixing material and water be 1:50~
100。
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| CN108221483B (en) * | 2018-03-29 | 2020-05-29 | 安阳博物馆 | Novel ancient calligraphy and painting repairing and paper dyeing method |
| CN109440503A (en) * | 2018-10-31 | 2019-03-08 | 嘉兴珠韵服装有限公司 | Coconut shell extract/modified konjac glucomannan compound color fixing agent preparation method |
| CN109577088B (en) * | 2018-11-29 | 2021-05-25 | 苏州盛风文化创意发展有限公司 | Alum covering method for improving fan-shaped paper performance |
| CN110003793A (en) * | 2019-02-25 | 2019-07-12 | 常州市蓝勖化工有限公司 | A kind of preparation method of ageing-resistant painting and calligraphy fixing material |
| CN111643397B (en) * | 2020-07-09 | 2021-07-02 | 昆明理工大学 | Green mordant, hair dye and hair dyeing method |
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| CN102418301A (en) * | 2011-10-10 | 2012-04-18 | 甘肃省博物馆 | Composition for protecting paper document as well as preparation method and application of composition |
| CN105113301A (en) * | 2015-09-08 | 2015-12-02 | 湖州宏鑫绸厂 | Novel natural animal and plant source color fixing agent as well as preparation method and color fixing process |
| CN106368065A (en) * | 2016-11-21 | 2017-02-01 | 陕西师范大学 | Method for augmentation of soluble handwriting on paper historical relics |
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102418301A (en) * | 2011-10-10 | 2012-04-18 | 甘肃省博物馆 | Composition for protecting paper document as well as preparation method and application of composition |
| CN105113301A (en) * | 2015-09-08 | 2015-12-02 | 湖州宏鑫绸厂 | Novel natural animal and plant source color fixing agent as well as preparation method and color fixing process |
| CN106368065A (en) * | 2016-11-21 | 2017-02-01 | 陕西师范大学 | Method for augmentation of soluble handwriting on paper historical relics |
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