CN111643397B - Green mordant, hair dye and hair dyeing method - Google Patents

Green mordant, hair dye and hair dyeing method Download PDF

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Publication number
CN111643397B
CN111643397B CN202010655840.7A CN202010655840A CN111643397B CN 111643397 B CN111643397 B CN 111643397B CN 202010655840 A CN202010655840 A CN 202010655840A CN 111643397 B CN111643397 B CN 111643397B
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mordant
acid
hair
green
dyeing
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CN111643397A (en
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冷崇燕
李艳芳
胡然
刘金坤
王若璇
陈俊智
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Kunming University of Science and Technology
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Kunming University of Science and Technology
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    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A61K8/736—Chitin; Chitosan; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A61K8/731—Cellulose; Quaternized cellulose derivatives
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
    • A61Q17/005—Antimicrobial preparations
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/10—Preparations for permanently dyeing the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/12—Preparations containing hair conditioners
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/42—Colour properties
    • A61K2800/43—Pigments; Dyes

Abstract

The invention discloses a green mordant, a hair dye and a hair dyeing method, wherein the green mordant contains C-O bonds and comprises a No. I mordant, a No. II mordant and a No. III mordant, and the No. I mordant is chitosan-citric acid or malic acid aqueous solution; the mordant II is konjac glucomannan-citric acid or malic acid water solution; the mordant III is carboxymethyl cellulose sodium-citric acid or malic acid water solution; the green hair dye is prepared from pure natural color sources; when the hair dyeing is carried out, the mordant is firstly used, then the dyeing liquid is used, the obtained hair dyeing effect is optimal, and different dyeing effects can be achieved through blending of the dyeing agent; the hair dye and the mordant are all natural edible materials, are green and pollution-free, have no toxicity, no irritation, safe use and lasting hair dyeing effect, have the effects of antibiosis and bacteriostasis, and can ensure that the hair quality and the health of people are not damaged when people have beauty.

Description

Green mordant, hair dye and hair dyeing method
Technical Field
The invention belongs to the field of hair dyeing, and particularly relates to a green mordant, a hair dye and a hair dyeing method.
Background
Since 21 st century, hair dyeing becomes a favorite cosmetic mode, and the aim of beautifying hair is fulfilled by changing the color of the hair. For young people, most of the people like to pursue fashion and show youth and vitality, the standards are different, and some people who produce white hair due to the old, the heredity, diseases and the like want to modify themselves by dyeing hair, so that the people look more spiritual and younger. Therefore, the consumption of the hair dye is increasing, and various products are produced.
However, most hair dyes in the market are chemical hair dyes, most of the hair dyes contain aromatic amine and phenolic substances, the aromatic amine is a carcinogen, the hair dyeing effect is good, the color duration is long, the long-term use of the hair dyes can bring great harm to the human body, and the chemical hair dyes contain various heavy metals such as lead, mercury and arsenic, so that the functions of the human liver organs are possibly greatly damaged.
Disclosure of Invention
The invention aims to solve the problems and provide a green mordant, a hair dye and a hair dyeing method, wherein the mordant and the hair dye are prepared from natural edible raw materials, are green and pollution-free, have no toxicity or irritation, are safe to use, have the effects of resisting and inhibiting bacteria, moistening hair and scalp and brightening hair, and can ensure that people can not damage the hair quality and health while having beauty.
The invention realizes the purpose through the following technical scheme:
the invention provides a green mordant, which contains C-O bonds, wherein the C-O bonds are attached to hair in the mordant dyeing process, and play an important role in the dyeing process, and comprise a No. I mordant, a No. II mordant and a No. III mordant; the mordant I is chitosan-acid water solution; the mordant II is water solution of konjac glucomannan-acid; the mordant III is water solution of sodium carboxymethylcellulose-acid.
The total concentration of chitosan and acid in the aqueous solution of the mordant I chitosan-acid is 0.03-0.07g/mL, the mass ratio of chitosan to acid is 1:1, and the acid is citric acid or malic acid; the preparation method comprises the following specific steps: the method comprises the steps of mixing chitosan and acid in a mass ratio of 1:1 in deionized water, stirring the mixture at 50 ℃ by using a magnetic stirrer until the chitosan is completely dissolved to prepare transparent viscous liquid, wherein the mordant I has antibacterial and bacteriostatic effects because the chitosan has the antibacterial and bacteriostatic effects.
The total concentration of konjac glucomannan and acid in the aqueous solution of the mordant II konjac glucomannan-acid is 0.03-0.07g/mL, the mass ratio of the konjac glucomannan to the acid is 1:1, and the acid is citric acid or malic acid.
The total concentration of the sodium carboxymethyl cellulose and the acid in the aqueous solution of the mordant No. III sodium carboxymethyl cellulose-acid is 0.03-0.07g/mL, the mass ratio of the sodium carboxymethyl cellulose to the acid is 1:1, and the acid is citric acid or malic acid.
The invention also provides a green hair dye, wherein the color source material is one or a mixture of several of coffee powder, black sesame, black soya bean, purple rice, pomegranate, red bean, dragon fruit peel, amaranth, purple cabbage, walnut peel, isatis root, tea and gallnut in any proportion.
The preparation method of the green hair dye comprises the following specific steps: wrapping 3-7g of the color source material with gauze, putting into 50mL of purified water, and boiling to 20mL at 100 ℃ to obtain the green hair dye.
The invention also provides a green hair dyeing method, which is characterized in that the green mordant is used firstly, and then the green hair dye is used for dyeing hair.
The invention has the beneficial effects that: the hair dye and the mordant are made of natural edible materials, are green and pollution-free, have no toxicity, no irritation and safe use, have the effects of resisting and inhibiting bacteria, and can ensure that people can not damage the hair quality and health while having beauty.
Drawings
FIG. 1 is a diagram of hair dyed in example 8;
FIG. 2 is an SEM photograph of dyed hair of example 9;
FIG. 3 is an SEM image of hair dyed by a comparative example henna powder pure plant natural hair dye.
Detailed Description
The present invention will be described in more detail with reference to the following examples, but the scope of the present invention is not limited to the following examples.
Example 1
The preparation method of the mordant I comprises the following specific steps:
adding chitosan and citric acid into deionized water according to the mass ratio of 1:1, mixing, wherein the total concentration of chitosan and citric acid is 0.03g/mL, and magnetically stirring at 50 deg.C until chitosan is completely dissolved to obtain transparent viscous liquid.
Example 2
The preparation method of the mordant I comprises the following specific steps:
the chitosan and the malic acid are put into deionized water according to the mass ratio of 1:1 to be mixed, wherein the total concentration of the chitosan and the malic acid is 0.07g/mL, and the mixture is stirred by magnetic force at 50 ℃ until the chitosan is completely dissolved to prepare transparent viscous liquid.
Example 3
The preparation method of the mordant I comprises the following specific steps:
the chitosan and the citric acid are put into deionized water according to the mass ratio of 1:1 to be mixed, wherein the total concentration of the chitosan and the citric acid is 0.05g/mL, and the mixture is stirred by magnetic force at 50 ℃ until the chitosan is completely dissolved to prepare transparent viscous liquid.
Example 4
A preparation method of a green hair dye comprises the following specific steps:
respectively taking 3g of coffee powder, black sesame, black beans, purple rice, pomegranate and red beans, respectively wrapping the coffee powder, the black sesame, the black beans, the purple rice, the pomegranate and the red beans with gauze, respectively putting the coffee powder, the black sesame, the black beans, the purple rice, the pomegranate and the red beans into beakers filled with 50mL of purified water, putting the beakers into a constant-temperature water bath kettle, and boiling the beakers to 20mL at a high temperature of 100 ℃ to sequentially obtain a first hair dye, a second hair dye, a third hair dye, a.
Example 5
A preparation method of a green hair dye comprises the following specific steps:
respectively taking 5g of pitaya fruit, pitaya peel, amaranth and purple cabbage, respectively wrapping with gauze, respectively putting into beakers filled with 50mL of purified water, then putting the beakers into a constant-temperature water bath kettle, and boiling to 20mL at a high temperature of 100 ℃ to sequentially obtain a seven-hair dye, an eight-hair dye, a nine-hair dye and a ten-hair dye.
Example 6
A preparation method of a green hair dye comprises the following specific steps:
7g of walnut peel, isatis root, tea and gallnut are respectively wrapped by gauze and respectively put into beakers filled with 50mL of purified water, and then the beakers are put into a constant-temperature water bath kettle and are boiled to 20mL at a high temperature of 100 ℃, so that the hair dye of No. eleven, the hair dye of No. twelve, the hair dye of No. thirteen and the hair dye of No. fourteen are sequentially obtained.
Example 7
Uniformly mixing the first hair dye and the fourth hair dye according to the volume ratio of 1:1 to obtain a fifteen hair dye, uniformly mixing the first hair dye, the fourth hair dye and the thirteenth hair dye according to the volume ratio of 1:1:1 to obtain a sixteen hair dye, and uniformly mixing the first hair dye and the eighth hair dye according to the volume ratio of 1:1 to obtain a seventeen hair dye.
Example 8
A green hair dyeing method comprises the following specific steps:
after the white hair is wetted, the hair is pre-dyed by the mordant I prepared in the embodiment 1, the mordant I is uniformly coated on the hair, the hair is dried at 40 ℃ by using a hair drying cover, the hair is dyed by the hair dye I prepared in the embodiment 4, the hair dye treatment time can be determined according to the requirement of a customer on the dyeing depth, the hair dye is treated for 15 minutes in the embodiment, the hair is dried at 40 ℃ by using the hair drying cover again, the hair is cleaned, the color of the dried hair is consistent with the expected color, and the effect is good.
The effect of example 8 can be achieved with the total concentration of chitosan and citric acid in the mordant I chitosan-citric acid aqueous solution being in the range of 0.03-0.07g/mL, wherein the mass ratio of chitosan to citric acid is 1: 1; the effect of example 8 can also be achieved by replacing citric acid with malic acid.
Example 9
A green hair dyeing method comprises the following specific steps:
wetting white hair, pre-dyeing the hair by using a konjac glucomannan-citric acid aqueous solution with the total concentration of a mordant II, namely konjac glucomannan and citric acid of 0.05g/mL, wherein the konjac glucomannan-citric acid aqueous solution with the total concentration of the citric acid and the konjac glucomannan is prepared by dissolving the konjac glucomannan and the citric acid in water, the mass ratio of the konjac glucomannan to the citric acid is 1:1, uniformly coating a mordant II on the hair, drying the hair at 40 ℃ by using a hair drying cover, treating the hair by using the hair dye fifteen prepared in the embodiment 7, the treatment time of the hair dye can be determined according to the requirement of a customer on the dyeing depth, treating the hair dye for 20 minutes, drying the hair by using the hair drying cover at 40 ℃, cleaning, and drying the hair, wherein the color of the hair is consistent with the expected color after drying, the effect is good.
The effect of example 9 can be achieved when the total concentration of the mordant konjac glucomannan-citric acid aqueous solution is 0.03-0.07g/mL, wherein the mass ratio of konjac glucomannan to citric acid is 1: 1; the effect of example 9 can also be achieved by replacing citric acid with malic acid.
Example 10
Wetting white hair, pre-dyeing the hair by adopting a carboxymethyl cellulose sodium solution with the total concentration of a No. III mordant and a carboxymethyl cellulose sodium-citric acid aqueous solution with the total concentration of citric acid of 0.07g/mL, wherein the carboxymethyl cellulose sodium solution with the total concentration of the carboxymethyl cellulose and the citric acid of 0.07g/mL is prepared by dissolving the carboxymethyl cellulose sodium solution and the citric acid in water, the mass ratio of the carboxymethyl cellulose sodium to the citric acid is 1:1, uniformly coating a No. III mordant on the hair, drying the hair at 40 ℃ by using a hair drying hood, treating the hair dye with the No. sixteen hair dye prepared in the embodiment 7, wherein the treatment time of the hair dye can be determined according to the requirement of a customer on the dyeing depth, treating the hair dye for 30 minutes, drying the hair at 40 ℃ by using the hair drying hood again, cleaning, drying the hair color is consistent with the expectation, the effect is good.
The effect of the embodiment 10 can be achieved when the total concentration of the mordant No. III sodium carboxymethylcellulose-citric acid aqueous solution is in the range of 0.03-0.07g/mL, wherein the mass ratio of the sodium carboxymethylcellulose to the citric acid is 1: 1; the effect of example 10 can also be achieved by replacing citric acid with malic acid.
Evaluation of degree of discoloration:
the white hair dyed in examples 8 to 10 was not faded after being rinsed 10 times, indicating that the coloring effect was stable and was not faded after being rinsed ten times.
Comparative example
The hair dyeing effect of the commercial India henna powder pure plant natural hair dye is compared with that of the embodiment.
Fig. 1 is a picture of hair obtained by dyeing white hair in example 8, and it can be clearly seen from the picture that the hair line is dark brown, which shows that the dyeing effect of example 8 is good and in accordance with expectations.
FIG. 2 is an SEM photograph of dyed hair of example 9; FIG. 3 is an SEM image of hair dyed with a comparative henna powder pure plant natural hair dye; in comparison between fig. 2 and fig. 3, it is clearly observed that the hair damage in fig. 3 is higher than that in fig. 2, further illustrating that example 9 of the present invention has negligible damage to human hair.

Claims (3)

1. A green mordant for dyeing hair is characterized by containing C-O bond, including mordant I, mordant II and mordant III;
the mordant I is chitosan-acid water solution; the mordant II is water solution of konjac glucomannan-acid; the mordant III is an aqueous solution of sodium carboxymethylcellulose-acid;
the total concentration of chitosan and acid in the water solution of the mordant I chitosan-acid is 0.03-0.07g/mL, the mass ratio of chitosan to acid is 1:1, and the acid is citric acid or malic acid;
the total concentration of konjac glucomannan and acid in the aqueous solution of the mordant No. II konjac glucomannan-acid is 0.03-0.07g/mL, the mass ratio of the konjac glucomannan to the acid is 1:1, and the acid is citric acid or malic acid;
the total concentration of the sodium carboxymethyl cellulose and the acid in the aqueous solution of the mordant No. III sodium carboxymethyl cellulose-acid is 0.03-0.07g/mL, the mass ratio of the sodium carboxymethyl cellulose to the acid is 1:1, and the acid is citric acid or malic acid.
2. A green hair dyeing method is characterized in that the green mordant of claim 1 is used firstly, and then the green hair dye is used, wherein the color source material of the green hair dye is one or more of coffee powder, black sesame, black bean, purple rice, pomegranate, red bean, dragon fruit peel, amaranth, purple cabbage, walnut peel, isatis root, tea and gallnut which are mixed according to any proportion.
3. The green dyeing method according to claim 2, wherein the green dyeing agent is prepared by the following steps: wrapping 3-7g of the color source material with gauze, putting into 50mL of purified water, and boiling to 20mL at 100 ℃ to obtain the green hair dye.
CN202010655840.7A 2020-07-09 2020-07-09 Green mordant, hair dye and hair dyeing method Active CN111643397B (en)

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Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1018560B (en) * 1989-08-22 1992-10-07 金福姬 Dye compositions for dyeing denim cotton yarn and dyeing process and dyed articles using same
CN102772336B (en) * 2012-08-13 2015-03-18 宋子奎 Washing agent composition for colored hairs and preparation method for washing agent composition
CN104721069B (en) * 2015-04-09 2018-08-21 宋子奎 A kind of deep composition for hair dying of increasing
CN107254253B (en) * 2017-07-04 2019-05-21 南京博物院 A kind of painting and calligraphy fixing material and its preparation method and application
CN109403078A (en) * 2018-10-12 2019-03-01 江苏阳光毛纺服装技术开发有限公司 A kind of wool fabric dyeing of dye yam extracting solution
CN109440503A (en) * 2018-10-31 2019-03-08 嘉兴珠韵服装有限公司 Coconut shell extract/modified konjac glucomannan compound color fixing agent preparation method

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