CN102772336B - Washing agent composition for colored hairs and preparation method for washing agent composition - Google Patents
Washing agent composition for colored hairs and preparation method for washing agent composition Download PDFInfo
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/60—Sugars; Derivatives thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/87—Polyurethanes
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/896—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate
- A61K8/897—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate containing halogen, e.g. fluorosilicones
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/896—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate
- A61K8/898—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate containing nitrogen, e.g. amodimethicone, trimethyl silyl amodimethicone or dimethicone propyl PG-betaine
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/92—Oils, fats or waxes; Derivatives thereof, e.g. hydrogenation products thereof
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
- A61K8/9783—Angiosperms [Magnoliophyta]
- A61K8/9789—Magnoliopsida [dicotyledons]
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
- A61K8/9783—Angiosperms [Magnoliophyta]
- A61K8/9794—Liliopsida [monocotyledons]
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/10—Preparations for permanently dyeing the hair
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
Abstract
The invention provides a washing agent composition for colored hairs. The washing agent composition comprises the following components in parts by weight: 5 to 95 parts of washing agent for hairs, 2 to 98 parts of darkening agent and 3 to 96 parts of color fixing agent, wherein the darkening agent is one or more of chitin, chitosan, silicone oil compound, rare earth and resin. The washing agent composition for the colored hairs is obtained by adding various auxiliary materials such as the darkening agent and the color fixing agent into the washing agent for hairs and used for doubly darkening the color of the original hairs after being washed, namely the original color of the colored hairs after being washed is fixed and darkened, so that various types of hairs achieve effects of washing and darkening as well as washing and refreshing. The invention also provides a method for preparing the washing agent composition for the colored hairs.
Description
Technical field
The present invention relates to hair washing technology field, particularly hyperchromic hair composition of detergent of one and preparation method thereof.
Background technology
In general, the hair detergent of existing washing hair primarily of detergent with additive as conditioner, suds booster, antidandruff agent, antiseptic become to be grouped into essence etc., the Chinese patent literature being CN1121203C as Authorization Notice No. discloses a kind of hair care detergent comsetic compositions, it comprises the washing base, the conditioner system containing at least one cation guar gum polysiloxanes insoluble with at least one that are made up of anion surfactant and C10 ~ C14 alkyl beet alkali ampholytic surface active agent, can be used for washing and the nursing of hair.When adopting existing hair detergent washing hair, it has certain decontamination, de-sludging, grease removal, the function such as anti-dandruff to hair, and make hair comparatively clean after washing, its color is still original degree of depth.
At present, increasing decorative effect or the object such as attractive in appearance to reach, adopting hair dye to dye one of way of becoming common to hair.But when adopting the hair after the dyeing of existing hair detergent washing, the color of the hair after dyeing after washing generally can shoal.Although in the good situation of the color fastness of hair dye, for fading of single hair washing, usually can ignore during range estimation, but when the frequency of having one's hair wash is higher or the number of times of hair washing is accumulated to a threshold quantity, the color of hair after dyeing after washing then can show as entirety and shoal, even become the original color of hair before dyeing again, thus cause weakening the effect even cannot played and increase decorative effect or the aspect such as attractive in appearance.Meanwhile, the more shallow and hair that Color is not good for congenital color, after adopting existing hair detergent washing, the color of hair is still unsaturated, affects attractive in appearance.
Therefore, need a kind of make washing after original hair color by the original color of hair that become after the dark or dyeing of multiplication by fixation, and each washing all has the detergent of darkening effect to the color of hair.
Summary of the invention
In order to solve above technical problem, the invention provides a kind of hyperchromic hair composition of detergent and preparation method thereof, hyperchromic hair composition of detergent provided by the invention can make original hair color dark by increasing after washing, the original color of hair after dyeing after washing is by fixation, and its color is increased deeply.
The invention provides a kind of hyperchromic hair composition of detergent, comprise:
The hair detergent of 5 ~ 95 weight portions;
The deep-dyeing agent of 2 ~ 98 weight portions, described deep-dyeing agent is one or more in chitin, chitosan, silicone oil compound, rare earth and resin;
The color-fixing agent of 3 ~ 96 weight portions.
Preferably, described resin is one or more in organic fluorine, organic siliconresin, polyamine resinoid and polyurethane resin.
Preferably, described silicone oil compound is one or more in hydroxy silicon oil, alkyl-silicone oil, amido silicon oil, dimethicone, fluorine containing silicone oil and polyether modified silicon oil.
Preferably, described color-fixing agent is cationic resin color-fixing agent, response type color-fixing agent, quaternary ammonium salt color-fixing agent or silicone based color-fixing agent.
Preferably, described hair detergent is made up of detergent and additive.
Preferably, described detergent is anion surfactant detergent and/or nonionic surfactant detergent.
Preferably, described additive is one or more in oil material, aminosal, alcohol, inorganic salt, antiseptic, suds booster, antidandruff agent, surface activity conditioner, non-ionic conditioning agents, cation opsonizing agent, essence and pigment.
Preferably, the Chinese medicine hair blackening agent of 5 ~ 95 weight portions is also comprised.
Preferably, described Chinese medicine hair blackening agent is one or more in Radix Polygoni Multiflori extract, Radix Ginseng extract, Radix Astragali extract, Aloe extract, Radix Angelicae Sinensis extract and wolfberry fruit extract.
The present invention also provides a kind of preparation method of hyperchromic hair composition of detergent, comprises the following steps:
Take the raw material of following weight portion:
The hair detergent of 5 ~ 95 weight portions;
The deep-dyeing agent of 2 ~ 98 weight portions, described deep-dyeing agent is one or more in chitin, chitosan, silicone oil compound, rare earth and resin;
The color-fixing agent of 3 ~ 96 weight portions;
Be mix under the condition of 0 ~ 550 DEG C in temperature by described raw material, obtain hyperchromic hair composition of detergent.
Compared with prior art, hyperchromic hair composition of detergent provided by the invention comprises the hair detergent of 5 ~ 95 weight portions, the deep-dyeing agent of 2 ~ 98 weight portions, described deep-dyeing agent is one or more in chitin, chitosan, silicone oil compound, rare earth and resin, and the color-fixing agent of 3 ~ 96 weight portions.The present invention adds the various adjuvant such as deep-dyeing agent, color-fixing agent in hair detergent, obtains hyperchromic hair composition of detergent.When adopting hyperchromic hair composition of detergent washing hair provided by the invention, described resin, described chitin, described chitosan or described silicone oil compound can form the uniform low refractive index film of one deck in hair surface, the original color of this tough and tensile transparent thin film to hair has tint retention, hair can be weakened to the reflection of light and scattering power simultaneously, make more visible ray enter hair inside, thus make hair produce bathochromic effect to after light generation selective absorbing; Described chitin, described chitosan or described rare earth can be combined by the hair dye in hair dyeing simultaneously, and the molecular weight of hair dye is increased, and color and luster is deepened, thus hair dyeing original color after washing is increased deeply.Experiment shows, through the hair of hyperchromic hair composition of detergent provided by the invention process, its original color is dark by fixation, increasing.
Detailed description of the invention
In order to understand the present invention further, below in conjunction with embodiment, the preferred embodiment of the invention is described, but should be appreciated that these describe just for further illustrating the features and advantages of the present invention, instead of limiting to the claimed invention.
The invention provides a kind of hyperchromic hair composition of detergent, comprise:
The hair detergent of 5 ~ 95 weight portions;
The deep-dyeing agent of 2 ~ 98 weight portions, described deep-dyeing agent is one or more in chitin, chitosan, silicone oil compound, rare earth and resin;
The color-fixing agent of 3 ~ 96 weight portions.
Hyperchromic hair composition of detergent provided by the invention is primarily of raw material compositions such as hair detergent, deep-dyeing agent and color-fixing agent, after hair after adopting it to wash original hair or dyeing, the color of hair is dark by fixation, increasing, thus makes the hair after original hair or dyeing reach the effect of often washing Chang Xin.
In the present invention, described hyperchromic hair composition of detergent comprises the hair detergent of 5 ~ 95 weight portions, preferably comprises the hair detergent of 10 ~ 90 weight portions, more preferably comprises the hair detergent of 50 ~ 80 weight portions.Described hair detergent is preferably made up of detergent and additive, and the ratio of the present invention to described detergent and described additive is not particularly limited, and adopts conventional hair detergent can play good decontamination etc. and acts on.
In the present invention, described detergent can be anion surfactant detergent, cationic surfactant detergent, zwitterionic surfactant detergent or nonionic surfactant detergent, also can be the cleaning composition of the composite surfactant of above-mentioned energy, be preferably anion surfactant detergent and/or nonionic surfactant detergent, wherein, described anion surfactant detergent includes but not limited to dodecylbenzene sodium sulfonate detergent, ethyl oleate sodium sulfonate detergent, oleoyl amino acid sodium detergent and N, N-oleoyl N-methyltaurine sodium detergent, described non-ionic surface active agent is as NPE detergent, alkyl polyglucoside detergent etc.
Described additive be preferably in oil material, aminosal, alcohol, inorganic salt, antiseptic, suds booster, antidandruff agent, surface activity conditioner, non-ionic conditioning agents, cation opsonizing agent, essence and pigment one or more.
Wherein, described oil material be preferably in ethoxyquin Oleum Cocois monoethanolamine, almond oil, olive oil, water solublity lanoline, sunflower oil, Radix Glycyrrhizae quintessence oil, chamomile oil, turtle oil, zamene, Nyctereutes procyonoides oil, liquid paraffin, myristic acid octyl group lauryl, isopropyl palmitate and liquid isoalkane one or more, steady bubble effect, short bubble effect and the opsonic action such as lubrication, nourishing hair can be played.Described aminosal is preferably hydrolysis of keratin or hydrolysis of animal glue, can play good nursing role to hair.Described alcohol is preferably ethanol or isopropyl alcohol, and it belongs to excellent solvent.Described inorganic salt be preferably in sodium chloride, ammonium chloride, potassium chloride, metaphosphate, orthophosphate and sulfate one or more, can thickening power be played.Described antiseptic is preferably P-hydroxybenzoic acid, can not work the mischief to health.Described suds booster is preferably Oleum Cocois diethanolamine, is convenient to application.Described antidandruff agent be preferably in mercaptopyridine zinc oxide, selenium sulfide, sulfur, salicylic acid and undecenoic acid derivatives one or more, can antipruritic anti-dandruff.Described surface activity conditioner is preferably wheat germ oil derivant, has thickening power and the opsonic action such as hair caring, hair care.Described non-ionic conditioning agents is preferably fatty alcohol-polyoxyethylene ether or polysorbate, has the effects such as emulsifying, foaming and decontamination.Described cation opsonizing agent is preferably polyquaternary ammonium salt, acrylamide polymer or cation guar gum, can play thickening power and increase the opsonic action such as hair luster, the easy combing of maintenance hair.Described essence and described pigment adopt this area to commonly use respectively, and the present invention is all not particularly limited it.
In the present invention, described hyperchromic hair composition of detergent comprises the deep-dyeing agent of 2 ~ 98 weight portions, preferably comprises the deep-dyeing agent of 10 ~ 80 weight portions, more preferably comprises the deep-dyeing agent of 20 ~ 50 weight portions.
Described deep-dyeing agent is one or more in chitin, chitosan, silicone oil compound, rare earth and resin, is preferably rare earth and/or resin, tint retention and to increase dark effect better.
Because the color of hair is determined by form and aspect, purity and lightness (gloss), under different form and aspect, gloss, if the reflectance of light wave, absorbance are different, containing deep or light different with light degree and show the visual effect of shade.The gloss of hair is positive and negative coloured light, surface reflection and the coefficient result of scattered light from inside, and reflected light is wherein main part.The main path improving the hair color degree of depth weakens it to the reflection of light and scattering power, makes more visible ray enter hair inside, produce bathochromic effect after making hair generation selective absorbing.
Described resin, described silicone oil compound, described chitin or described chitosan have extremely strong adsorptivity to hair, can closely be combined by the active group in wool fibre, the uniform low refractive index film of one deck can be formed in hair surface, weaken hair to the reflection of light and scattering power, make more visible ray enter hair inside, thus make hair produce bathochromic effect to after light generation selective absorbing; Because the film formed in hair surface is different from absorption to the reflection of light, the lightness of hair declines to some extent, color looks and deepens, although the film formed is very thin, be about 0.5 μm, but hair is the aggregation of wool fibre, this effect of a large amount of wool fibre combines, increase dark effect just comparatively outstanding, the dark effect of the increasing therefore on the hair that the degree of depth is higher is more obvious.Described resin, described silicone oil compound, described chitin or described chitosan have function, the maintenance action such as make hair smooth, straight of fixation simultaneously and kill that demodicid mite is antibacterial, the health-care effect of anti-inflammatory analgetic, promotion hair wound healing.
In the present invention, described resin is preferably one or more in organic fluorine, organic siliconresin, polyamine resinoid and polyurethane resin.The refractive index of described resin is lower, and it is better that it increases dark effect, and described resin is preferably the resin of refractive index below 1.5.
Described silicone oil compound is preferably hydroxy silicon oil, alkyl-silicone oil, amido silicon oil, dimethicone, one or more in fluorine containing silicone oil and polyether modified silicon oil, wherein, dimethicone is also known as organic silicone oil, silicone oil etc., it is a kind of polysiloxane of different polymerization degree chain structure, its preparation method comprises: dimethyldichlorosilane adds water and is hydrolyzed obtained first minification polycyclic body, ring body is through cracking, rectification obtains low ring body, then ring body, closure agent, catalyst mix telomerizes, obtain the mixture that the degree of polymerization is different, through distilling under reduced pressure removing low-boiling-point substance, obtain dimethicone.Described dimethicone is as SILANOL SF9188, SILANOLSF9103, and refractive index is generally 1.40 ~ 1.45; The refractive index of described fluorine containing silicone oil is generally below 1.38.
Described chitin is also known as chitin, chitin, and chemical name is (1-4)-2-acetamido-2-deoxidation-β-D-Glucose, or is called for short policapram base glucose.Described chitosan is also known as chitosan, chitosan; it is that a kind of chitin by being mainly derived from the shellfish such as shrimp, Eriocheir sinensis shell is hydrolyzed in the basic conditions; take off acetyl group and the soluble chitin formed; chemical name is (1-4)-2-amino-2-deoxidation-B-D-glucose, or is called for short Chitin.Described chitin and described chitosan are with unsaturated cation group, to the hair with negative charge, there is powerful adsorption, form the thin layer of molecular thickness, it has pole antiradar reflectivity, the light injecting hair surface is made to produce refraction, diffuse-reflectance in hair surface, thus the absorbtivity of hair to incident illumination is increased greatly, reflected light reduces, and reaches and increases dark effect.Meanwhile, described chitin can also be combined by the hair dye on the hair after dyeing with described chitosan, the color fastness of hair dye not only can be made to improve, and the molecular weight of hair dye can be made to increase, and causes the chroma of hair after dyeing to be deepened, thus has darkening effect.In addition, the abundance of described chitin and described chitosan, cheap, be comparatively suitable for applying.
Described rare earth first can and dyeing after hair on hair dye molecule in hydroxyl oxygen atom, azo group nitrogen-atoms, there is complexing between sulfonic group oxygen atom, the intermolecular force between the nonpolar moiety of the hair after hair dye and dyeing not only can be made to increase, color fastness improves, and the molecular weight of hair dye can be made to increase, color and luster is deepened, thus makes the hair dyeing after washing keep the former coloured degree of depth, colour brightness to improve; Secondly, described rare earth can make the coloring matter of dirt on wool fibre activate, and reduces the activation energy of washing reaction, the reaction of dirt and detergent is more easily carried out, that is, has active catalytic effect to the washing reaction of hair, thus make hair more clean; Again, the maximum absorption wavelength of described rare earth itself is 580nm, has the ability of the gold-tinted of the hair of graying, yellowing or lighter being carried out to selective absorbing, and the color of the hair that yellowing is shoaled increases dark.Therefore, it is dark that described rare earth can make the color of original hair after washing increase, and makes that the color after washing of the hair after dyeing is dark and gorgeous, pure color light, color fastness are high.In addition, described rare earth has stronger complexing, can form complex, play a kind of effect of cross-linking agent, thus the brute force of hair is improved when it enters the amorphous region of wool fibre by coordinate bond, covalent bond.The kind of the present invention to described rare earth is not particularly limited, the mixed chlorinated rare earth of purity more than 46% can be adopted, also can adopt and be oxidized the products such as CR-1, CR-2, CR-3 that admire (NdZO) is raw material production with the single rare earth lanthana (La203) of purity more than 99.9999%, single rare earth.
In the present invention, described hyperchromic hair composition of detergent comprises the color-fixing agent of 3 ~ 96 weight portions, preferably comprises the color-fixing agent of 10 ~ 90 weight portions, more preferably comprises the color-fixing agent of 20 ~ 40 weight portions.
Described color-fixing agent can improve the fastness of the hair color after dyeing, be preferably cationic resin color-fixing agent, response type color-fixing agent, quaternary ammonium salt color-fixing agent or silicone based color-fixing agent, be more preferably cationic resin color-fixing agent, response type color-fixing agent or quaternary ammonium salt color-fixing agent.Wherein, described cationic resin color-fixing agent is as color fixing agent Y, color fixing agent M and color-fixing agent FLZOIL-810 etc.; Described response type color-fixing agent is as color-fixing agent NGC, color-fixing agent C and color-fixing agent DR-100 etc.; Described quaternary ammonium salt color-fixing agent is as color-fixing agent ECEOTIXFD-3, color-fixing agent ECEOTIXNF-50 and color-fixing agent TCD-R etc.; Described silicone based color-fixing agent comprises organosilicon, cationoid reaction type organosilicon and non-formaldehyde organosilicon etc.The fixation principle of described color-fixing agent can be: cationic groups contacts with alkaline aqueous solution; separate out and form aqueous gel; this aqueous gel adsorbing heavy metal ions and pigment; and thin film can be formed on wool fibre surface after the drying, thus good fixing, protective effect is played to hair dye.
In the present invention, described hyperchromic hair composition of detergent preferably also comprises the Chinese medicine hair blackening agent of 5 ~ 95 weight portions, more preferably also comprises the Chinese medicine hair blackening agent of 10 ~ 50 weight portions.
The Chinese medicine black hair extract that described Chinese medicine hair blackening agent adopts this area conventional, be preferably in Radix Polygoni Multiflori extract, Radix Ginseng extract, Radix Astragali extract, Aloe extract, Radix Angelicae Sinensis extract and wolfberry fruit extract one or more, be more preferably in Radix Polygoni Multiflori extract, Radix Ginseng extract, Radix Astragali extract, Radix Angelicae Sinensis extract and wolfberry fruit extract one or more.
Present invention also offers a kind of preparation method of hyperchromic hair composition of detergent, comprise the following steps:
Take the raw material of following weight portion:
The hair detergent of 5 ~ 95 weight portions;
The deep-dyeing agent of 2 ~ 98 weight portions, described deep-dyeing agent is one or more in chitin, chitosan, silicone oil compound, rare earth and resin;
The color-fixing agent of 3 ~ 96 weight portions;
Be mix under the condition of 0 ~ 550 DEG C in temperature by described raw material, obtain hyperchromic hair composition of detergent.
After the present invention takes above-mentioned raw materials according to above-mentioned weight portion, it is mixed at the temperature of 0 ~ 550 DEG C, preferably 10 DEG C ~ 250 DEG C, more preferably 30 DEG C ~ 160 DEG C, obtains hyperchromic hair composition of detergent.In order to reach hair caring object further, the present invention preferably also comprises the Chinese medicine hair blackening agent being mixed into 5 ~ 95 weight portions.The present invention is not particularly limited other conditions such as the equipment of described mixing.
After obtaining hyperchromic hair composition of detergent, adopt it repeatedly to wash the hair after the hair of shades of colour or dyeing, described washing can be embathe, and also can be spray, wherein, described embathing is specially: at the temperature of 0 ~ 70 DEG C, by the water dissolution of hair composition of detergent 1mL ~ 100mL hyperchromic described in 0.1mL ~ 100mL, after stirring, at the temperature of 0 ~ 100 DEG C, be immersed by hair to be washed for 1g ~ 1000g, after 1min ~ 100min, water suction dries up or naturally dries.Described spray is specially: by vaporific generator, directly sprays on the hair to be washed of drying by described hyperchromic hair composition of detergent, after 1min ~ 100min, dries or naturally dries.
Experiment shows, hair after original hair or dyeing of hyperchromic hair composition of detergent provided by the invention process, not only clean, and its color increased deeply, increase gorgeous, reach the effect of more washing and more deeply, often washing Chang Xin, the problems such as the pollution of iterative staining and formation thereof can be exempted, thus make hair caring more simple and convenient, also save a large amount of living fund simultaneously.
In order to understand the present invention further, below in conjunction with embodiment, hyperchromic hair composition of detergent provided by the invention and preparation method thereof is described in detail.
Embodiment 1
Take the dodecylbenzene sodium sulfonate detergent of 5 weight portions, the chitosan of 98 weight portions, the color fixing agent Y of 3 weight portions;
Be mix under the condition of 30 DEG C in temperature by above-mentioned raw materials, obtain hyperchromic hair composition of detergent.
Adopt that described hyperchromic hair composition of detergent spray is red, yellow, blue respectively, hair after the dyeing to be washed of purple and black, after process 10 times, be red, yellow, blueness, purple and black by the color of the hair after the dyeing of washing.
Comparative example 1
Take the dodecylbenzene sodium sulfonate detergent of 5 weight portions and the water of 81 weight portions, be mix under the condition of 30 DEG C in temperature, obtain hair composition of detergent.
Hair after adopting described hair composition of detergent to spray the dyeing to be washed of red, yellow, blue, purple and black respectively, after processing 10 times, is light red, light yellow, light blue, lilac and Lycoperdon polymorphum Vitt by the color of the hair after the dyeing of washing.
Embodiment 2
Take the color fixing agent Y of the NPE detergent of 94 weight portions, the sodium chloride of 0.1 weight portion, the ethoxyquin Oleum Cocois monoethanolamine of 0.1 weight portion, the ethanol of 0.1 weight portion, the hydrolysis of keratin of 0.1 weight portion, the P-hydroxybenzoic acid of 0.1 weight portion, the Oleum Cocois diethanolamine of 0.2 weight portion, the salicylic acid of 0.1 weight portion, the cation guar gum of 0.2 weight portion, the rare-earth products CR-1 of 2 weight portions and 96 weight portions;
Be mix under the condition of 50 DEG C in temperature by above-mentioned raw materials, obtain hyperchromic hair composition of detergent.
Hair after adopting described hyperchromic hair composition of detergent to embathe the dyeing to be washed of redness, yellow, blueness, purple and black respectively, after processing 10 times, by the color of the hair after the dyeing of washing be redness, gorgeous yellow, blueness, purple and black.
Embodiment 3
Take the color fixing agent Y of the alkyl polyglucoside detergent of 19 weight portions, the SILANOL SF9188 of 40 weight portions and 25 weight portions;
Be mix under the condition of 30 DEG C in temperature by above-mentioned raw materials, obtain hyperchromic hair composition of detergent.
Hair after adopting described hyperchromic hair composition of detergent to embathe the dyeing to be washed of redness, yellow, blueness, purple and black respectively, after processing 10 times, is red, yellow, blue, purple and black by the color of the hair after the dyeing of washing.
Embodiment 4
Take the color fixing agent Y of the ethyl oleate sodium sulfonate detergent of 77 weight portions, the polyurethane of 11 weight portions, the rare-earth products CR-2 of 3 weight portions and 16 weight portions;
Be mix under the condition of 110 DEG C in temperature by above-mentioned raw materials, obtain hyperchromic hair composition of detergent.
Adopt that described hyperchromic hair composition of detergent spray is red, yellow, blue respectively, hair after the dyeing to be washed of purple and black, after process 10 times, be red, yellow, blueness, purple and black by the color of the hair after the dyeing of washing.
Embodiment 5
Take the wolfberry fruit extract of the dodecylbenzene sodium sulfonate detergent of 20 weight portions, the alkyl polyglucoside detergent of 7 weight portions, the polyether modified silicon oil of 36 weight portions, the rare-earth products CR-3 of 5 weight portions, the color fixing agent Y of 51 weight portions and 5 weight portions;
Be mix under the condition of 50 DEG C in temperature by above-mentioned raw materials, obtain hyperchromic hair composition of detergent.
Hair after adopting described hyperchromic hair composition of detergent to embathe the dyeing to be washed of redness, yellow, blueness, purple and black respectively, after washing 10 times, is red, yellow, blue, purple and black by the color of the hair after the dyeing of washing.
From above embodiment and comparative example, when adopting the hair after hyperchromic hair composition of detergent washing dyeing provided by the invention, have darkening effect to the color of hair, thus original color of the hair dyeing after washing can be made by while fixation, its color is increased deeply.
The explanation of above embodiment just understands method of the present invention and core concept thereof for helping.It should be pointed out that for those skilled in the art, under the premise without departing from the principles of the invention, can also carry out some improvement and modification to the present invention, these improve and modify and also fall in the protection domain of the claims in the present invention.
Claims (9)
1. a hyperchromic hair composition of detergent, is made up of following raw material:
The hair detergent of 5 ~ 95 weight portions;
The deep-dyeing agent of 2 ~ 98 weight portions, described deep-dyeing agent is: chitin or chitosan; With one or more the combination in silicone oil compound, rare earth and resin; Described silicone oil compound is one or more in hydroxy silicon oil, alkyl-silicone oil, amido silicon oil, fluorine containing silicone oil and polyether modified silicon oil; Described resin is one or more in organic fluorine, organic siliconresin, polyamine resinoid and polyurethane resin;
The color-fixing agent of 3 ~ 96 weight portions, described color-fixing agent is cationic resin color-fixing agent, response type color-fixing agent, quaternary ammonium salt color-fixing agent or silicone based color-fixing agent;
The Chinese medicine hair blackening agent of 5 ~ 95 weight portions.
2. hyperchromic hair composition of detergent according to claim 1, it is characterized in that, described alkyl-silicone oil comprises dimethicone.
3. hyperchromic hair composition of detergent according to claim 1, is characterized in that, described hair detergent is made up of detergent and additive.
4. hyperchromic hair composition of detergent according to claim 3, is characterized in that, described detergent is anion surfactant detergent and/or nonionic surfactant detergent.
5. hyperchromic hair composition of detergent according to claim 3, it is characterized in that, described additive is one or more in oil material, aminosal, alcohol, inorganic salt, antiseptic, suds booster, antidandruff agent, surface activity conditioner, essence and pigment.
6. hyperchromic hair composition of detergent according to claim 5, is characterized in that, described surface activity conditioner comprises at least one in non-ionic conditioning agents and cation opsonizing agent.
7. hyperchromic hair composition of detergent according to claim 1, is characterized in that, described Chinese medicine hair blackening agent is one or more in Radix Polygoni Multiflori extract, Radix Ginseng extract, Radix Astragali extract, Aloe extract, Radix Angelicae Sinensis extract and wolfberry fruit extract.
8. a preparation method for hyperchromic hair composition of detergent, comprises the following steps:
Take the raw material of following weight portion:
The hair detergent of 5 ~ 95 weight portions;
The deep-dyeing agent of 2 ~ 98 weight portions, described deep-dyeing agent is: chitin or chitosan; With one or more the combination in silicone oil compound, rare earth and resin; Described silicone oil compound is one or more in hydroxy silicon oil, alkyl-silicone oil, amido silicon oil, fluorine containing silicone oil and polyether modified silicon oil; Described resin is one or more in organic fluorine, organic siliconresin, polyamine resinoid and polyurethane resin;
The color-fixing agent of 3 ~ 96 weight portions, described color-fixing agent is cationic resin color-fixing agent, response type color-fixing agent, quaternary ammonium salt color-fixing agent or silicone based color-fixing agent;
The Chinese medicine hair blackening agent of 5 ~ 95 weight portions;
Be mix under the condition of 0 ~ 550 DEG C in temperature by described raw material, obtain hyperchromic hair composition of detergent.
9. preparation method according to claim 8, is characterized in that, described alkyl-silicone oil comprises dimethicone.
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| CN201210287129.6A CN102772336B (en) | 2012-08-13 | 2012-08-13 | Washing agent composition for colored hairs and preparation method for washing agent composition |
| PCT/CN2013/071879 WO2014026476A1 (en) | 2012-08-13 | 2013-02-26 | Detergent composition for darkening hair and method for preparing same |
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| CN201210287129.6A CN102772336B (en) | 2012-08-13 | 2012-08-13 | Washing agent composition for colored hairs and preparation method for washing agent composition |
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| CN102772336B (en) * | 2012-08-13 | 2015-03-18 | 宋子奎 | Washing agent composition for colored hairs and preparation method for washing agent composition |
| CN103556464B (en) * | 2013-10-29 | 2015-06-10 | 宋子奎 | Fabric function repair agent composition and preparation method of fabric function repair agent composition |
| CN104721069B (en) | 2015-04-09 | 2018-08-21 | 宋子奎 | A kind of deep composition for hair dying of increasing |
| CN109939061B (en) * | 2019-05-14 | 2020-11-27 | 连云港诗碧曼生物科技有限公司 | Safe and non-irritant white hair blackening essence and preparation method thereof |
| CN111643397B (en) * | 2020-07-09 | 2021-07-02 | 昆明理工大学 | Green mordant, hair dye and hair dyeing method |
| CN113520947A (en) * | 2021-08-04 | 2021-10-22 | 广州葆妍生物科技有限公司 | Color-fixing hair-care composition and preparation and application thereof |
| CN115387140A (en) * | 2021-10-27 | 2022-11-25 | 青岛融美发制品集团有限公司 | Wig color fixation treatment mode and color fixing agent used by wig color fixation treatment mode |
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| DE4420880A1 (en) * | 1994-06-15 | 1995-12-21 | Wella Ag | Firming hair cleanser |
| GB0822823D0 (en) * | 2008-12-15 | 2009-01-21 | Dow Corning | Silicone oi-in-water emulsions |
| WO2011079187A1 (en) * | 2009-12-23 | 2011-06-30 | Momentive Performance Materials Inc. | Network copolymer crosslinked compositions and products comprising the same |
| FR2956975B1 (en) * | 2010-03-03 | 2012-05-11 | Rhodia Operations | NEW AGENT TO IMPROVE OIL DEPOSITION ON HAIR |
| CN102366382A (en) * | 2011-09-26 | 2012-03-07 | 谢建武 | Plant hair dye with isomerized C10 ethoxylate as penetrating agent and its preparation method |
| CN102772336B (en) * | 2012-08-13 | 2015-03-18 | 宋子奎 | Washing agent composition for colored hairs and preparation method for washing agent composition |
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| 吴国光.实验洗发香波的配制.《化学专业实验》.中国矿业大学出版社,2005,(第1版), * |
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