Summary of the invention
In order to solve above technical problem; The present invention provides a kind of hyperchromic hair with composition of detergent and preparation method thereof; It is dark that hyperchromic hair provided by the invention can make original hair color after washing, increased with composition of detergent; The original color of hair after the dyeing after washing is by fixation, and its color is increased deeply.
The present invention provides a kind of hyperchromic hair to use composition of detergent, comprises:
The hair of 5 ~ 95 weight portions is used detergent;
The deep-dyeing agent of 2 ~ 98 weight portions, said deep-dyeing agent are one or more in chitin, chitosan, silicone oil chemical compound, rare earth and the resin;
The color-fixing agent of 3 ~ 96 weight portions.
Preferably, said resin is one or more in organic fluorine, organic siliconresin, polyamine resinoid and the polyurethane resin.
Preferably, said silicone oil chemical compound is one or more in hydroxy silicon oil, alkyl-silicone oil, amido silicon oil, dimethicone, fluorine containing silicone oil and the polyether modified silicon oil.
Preferably, said color-fixing agent is cationic resin color-fixing agent, response type color-fixing agent, quaternary ammonium salt color-fixing agent or silicone based color-fixing agent.
Preferably, said hair is made up of detergent and additive with detergent.
Preferably, said detergent is anion surfactant detergent and/or nonionic surfactant detergent.
Preferably, said additive is one or more in oil material, aminosal, alcohol, inorganic salt, antiseptic, suds booster, antidandruff agent, surface activity conditioner, nonionic conditioner, cation opsonizing agent, essence and the pigment.
Preferably, also comprise 5 ~ 95 parts by weight of Chinese traditional medicine hair blackening agent.
Preferably, said Chinese medicine hair blackening agent is one or more in Radix Polygoni Multiflori extract, Radix Ginseng extract, Radix Astragali extract, Aloe extract, Radix Angelicae Sinensis extract and the wolfberry fruit extract.
The present invention also provides the method for preparing of a kind of hyperchromic hair with composition of detergent, may further comprise the steps:
Take by weighing the raw material of following weight portion:
The hair of 5 ~ 95 weight portions is used detergent;
The deep-dyeing agent of 2 ~ 98 weight portions, said deep-dyeing agent are one or more in chitin, chitosan, silicone oil chemical compound, rare earth and the resin;
The color-fixing agent of 3 ~ 96 weight portions;
Be to mix under 0 ~ 550 ℃ the condition said raw material, obtain hyperchromic hair and use composition of detergent in temperature.
Compared with prior art; Hyperchromic hair provided by the invention comprises the deep-dyeing agent of the hair of 5 ~ 95 weight portions with detergent, 2 ~ 98 weight portions with composition of detergent; Said deep-dyeing agent is one or more in chitin, chitosan, silicone oil chemical compound, rare earth and the resin, and the color-fixing agent of 3 ~ 96 weight portions.The present invention adds various adjuvants such as deep-dyeing agent, color-fixing agent at hair in detergent, obtains hyperchromic hair and uses composition of detergent.When adopting hyperchromic hair provided by the invention with composition of detergent washing hair; Said resin, said chitin, said chitosan or said silicone oil chemical compound can form the layer of even low refractive index film in hair surface; This tough and tensile clear films has tint retention to original color of hair; Simultaneously can weaken hair to reflection of light and scattering power, it is inner to make more visible light get into hair, produces bathochromic effect thereby make hair absorb the back to light generation selectivity; Said chitin, said chitosan or said rare earth can combine with the hair dye in the hair dyeing simultaneously, and the molecular weight of hair dye is increased, and color and luster is deepened, thereby hair dyeing original color after washing is increased deeply.Experiment shows, through the hair that hyperchromic hair provided by the invention is handled with composition of detergent, its original color by fixation, increase dark.
The specific embodiment
In order further to understand the present invention, below in conjunction with embodiment the preferred embodiment of the invention is described, describe just to further specifying feature and advantage of the present invention but should be appreciated that these, rather than to the restriction of claim of the present invention.
The invention provides a kind of hyperchromic hair and use composition of detergent, comprise:
The hair of 5 ~ 95 weight portions is used detergent;
The deep-dyeing agent of 2 ~ 98 weight portions, said deep-dyeing agent are one or more in chitin, chitosan, silicone oil chemical compound, rare earth and the resin;
The color-fixing agent of 3 ~ 96 weight portions.
Hyperchromic hair provided by the invention mainly is made up of with raw materials such as detergent, deep-dyeing agent and color-fixing agent hair with composition of detergent; Behind the hair after adopting it to wash original hair or dyeing; The color of hair by fixation, increase dark, thereby make the hair after original hair or the dyeing reach the effect of often washing Chang Xin.
In the present invention, said hyperchromic hair is used detergent with the hair that composition of detergent comprises 5 ~ 95 weight portions, and the hair that preferably comprises 10 ~ 90 weight portions is used detergent, and the hair that more preferably comprises 50 ~ 80 weight portions is used detergent.Said hair preferably is made up of detergent and additive with detergent, and the present invention does not have particular restriction to the ratio of said detergent and said additive, adopts hair commonly used can play decontamination preferably etc. with detergent and acts on and getting final product.
In the present invention; Said detergent can be anion surfactant detergent, cationic surfactant detergent, zwitterionic surfactant detergent or nonionic surfactant detergent; It also can be the cleaning composition of above-mentioned ability compounded surfactant; Be preferably anion surfactant detergent and/or nonionic surfactant detergent; Wherein, said anion surfactant detergent includes but not limited to dodecylbenzene sodium sulfonate detergent, ethyl oleate sodium sulfonate detergent, oleoyl aminoacid sodium detergent and N, N-oleoyl N-methyltaurine sodium detergent; Said non-ionic surface active agent such as NPE detergent, alkyl polyglucoside detergent etc.
Said additive is preferably one or more in oil material, aminosal, alcohol, inorganic salt, antiseptic, suds booster, antidandruff agent, surface activity conditioner, nonionic conditioner, cation opsonizing agent, essence and the pigment.
Wherein, Said oil material is preferably one or more in ethoxyquin Oleum Cocois MEA, almond oil, olive oil, water solublity lanoline, sunflower oil, Radix Glycyrrhizae quintessence oil, chamomile oil, turtle oil, zamene, Nyctereutes procyonoides oil, liquid paraffin, myristic acid octyl group lauryl, isopropyl palmitate and the liquid isoalkane, can play steady bubble effect, short bubble effect and lubricated, nourish opsonic action such as hair.Said aminosal is preferably hydrolysis of keratin or hydrolysis of animal glue, can play the good nursing care effect to hair.Said alcohol is preferably ethanol or isopropyl alcohol, and it belongs to excellent solvent.Said inorganic salt is preferably one or more in sodium chloride, ammonium chloride, potassium chloride, metaphosphate, orthophosphate and the sulfate, can play thickening power.Said antiseptic is preferably P-hydroxybenzoic acid, can not work the mischief to health.Said suds booster is preferably the Oleum Cocois diethanolamine, is convenient to use.Said antidandruff agent is preferably one or more in mercaptopyridine zinc oxide, selenium sulfide, sulfur, salicylic acid and the undecylenic acid derivant, can antipruritic anti-dandruff.Said surface activity conditioner is preferably the wheat germ oil derivant, has thickening power and opsonic actions such as hair caring, hair care.Said nonionic conditioner is preferably fatty alcohol-polyoxyethylene ether or polysorbate, has effects such as emulsifying, foaming and decontamination.Said cation opsonizing agent is preferably polyquaternary ammonium salt, acrylamide polymer or cation guar gum, can play thickening power and increase opsonic actions such as hair luster, the easy combing of maintenance hair.Said essence and said pigment adopt commonly used the getting final product in this area respectively, and the present invention does not all have particular restriction to it.
In the present invention, said hyperchromic hair comprises the deep-dyeing agent of 2 ~ 98 weight portions with composition of detergent, preferably comprises the deep-dyeing agent of 10 ~ 80 weight portions, more preferably comprises the deep-dyeing agent of 20 ~ 50 weight portions.
Said deep-dyeing agent is one or more in chitin, chitosan, silicone oil chemical compound, rare earth and the resin, is preferably rare earth and/or resin, and tint retention is with to increase dark effect better.
Because the color of hair is by form and aspect, purity and lightness (gloss) decision, under different form and aspect, gloss,, contain deep or light with to receive the light path degree different and show the visual effect of the shade of grey if the reflectance of light wave, absorbance are different.The gloss of hair is positive and negative coloured light, surface reflection and from the coefficient result of the scattered light of inside, and reflected light wherein is a main part.The main path that improves the hair color degree of depth is to weaken it to reflection of light and scattering power, and it is inner to make more visible light get into hair, makes hair generation selectivity absorb the back and produces bathochromic effect.
Said resin, said silicone oil chemical compound, said chitin or said chitosan have extremely strong adsorptivity to hair; Can closely combine with the active group in the wool fibre; Can form the layer of even low refractive index film in hair surface; Weaken hair to reflection of light and scattering power, it is inner to make more visible light get into hair, produces bathochromic effect thereby make hair absorb the back to light generation selectivity; Because the film in that hair surface forms is different with absorption to reflection of light, the lightness of hair descends to some extent, and color looks and deepens; Though formed film is very thin; Be about 0.5 μ m, but hair is the aggregation of wool fibre, this effect of a large amount of wool fibres combines; It is just comparatively outstanding to increase dark effect, therefore on the higher hair of the degree of depth to increase dark effect more obvious.Said resin, said silicone oil chemical compound, said chitin or said chitosan have simultaneously fixation function, make maintenance actions such as hair is smooth, straight and kill that demodicid mite is antibacterial, the health-care effect of anti-inflammatory analgetic, promotion hair wound healing.
In the present invention, said resin is preferably one or more in organic fluorine, organic siliconresin, polyamine resinoid and the polyurethane resin.The refractive index of said resin is low more, and it is just good more that it increases dark effect, and said resin is preferably refractive index at the resin below 1.5.
Said silicone oil chemical compound is preferably one or more in hydroxy silicon oil, alkyl-silicone oil, amido silicon oil, dimethicone, fluorine containing silicone oil and the polyether modified silicon oil; Wherein, dimethicone is claimed organic silicone oil, silicone oil etc. again, is a kind of polysiloxane of different polymerization degree chain structure; Its preparation method comprises: dimethyldichlorosilane adds the water hydrolysis and makes polycondensation ring body just; Ring body makes low ring body through cracking, rectification, telomerizes ring body, closure agent, catalyst mix then, obtains the different mixture of the degree of polymerization; Remove low-boiling-point substance through distilling under reduced pressure, promptly get dimethicone.Said dimethicone such as SILANOL SF9188, SILANOLSF9103, refractive index is generally 1.40 ~ 1.45; The refractive index of said fluorine containing silicone oil is generally below 1.38.
Said chitin is claimed chitin, chitin again, and chemical name is (1-4)-2-acetamido-2-deoxidation-β-D-glucose, or is called for short policapram base glucose.Said chitosan is claimed chitosan, chitosan again; It is a kind of by the chitin hydrolysis under alkali condition that is mainly derived from aquatic shell animal shells such as shrimp, Eriocheir sinensis; The soluble chitin of taking off acetyl group and forming; Chemical name is (1-4)-2-amino-2-deoxidation-B-D-glucose, or is called for short polyamine base glucose.Said chitin and said chitosan have unsaturated cation group; The hair that has negative charge is had powerful adsorption, form the thin layer of molecular thickness, it has utmost point antiradar reflectivity; Make the light of injecting hair surface produce refraction, diffuse-reflectance in hair surface; Thereby hair is increased the absorption of incident light amount greatly, and reflected light reduces, and reaches to increase dark effect.Simultaneously, said chitin and said chitosan can also combine with the hair dye on the hair after the dyeing, the color fastness of hair dye is improved, and the molecular weight of hair dye is increased, and the chroma of hair intensification after causing dyeing increases dark effect thereby have.In addition, the source of said chitin and said chitosan is abundant, and is cheap, comparatively is suitable for applying.
There is complexing between hydroxyl oxygen atom, azo group nitrogen-atoms, sulfonic group oxygen atom in the hair dye molecule on the hair after said rare earth at first can and dye; Intermolecular force between the nonpolar part of hair after hair dye and the dyeing is increased; Color fastness improves; And the molecular weight of hair dye is increased, color and luster is deepened, thereby makes the hair dyeing after washing keep the degree of depth of original color, colour brightness to improve; Secondly, said rare earth can make the coloring matter activation of dirt on the wool fibre, reduces the activation energy of washing reaction, and the reaction of dirt and detergent is carried out more easily, that is, the washing reaction of hair is had the active catalytic effect, thereby make hair more clean; Once more, the maximum absorption wavelength of said rare earth itself is 580nm, and the gold-tinted with hair that graying, yellowing or color are shoaled carries out the ability that selectivity absorbs, and the color of the hair that yellowing shoals is increased deeply.Therefore, said rare earth can make the color of original hair after washing increase deeply, makes the color after washing of the hair after the dyeing dark and gorgeous, coloured light is pure, color fastness is high.In addition, said rare earth has than strong complexing, can form complex by coordinate bond, covalent bond during the amorphous region of its entering wool fibre, plays a kind of effect of cross-linking agent, thereby the brute force of hair is improved.The present invention does not have particular restriction to the kind of said rare earth; Can adopt purity at the mixed chlorinated rare earth more than 46%, also can adopt with purity the single rare earth lanthana (La203) more than 99.9999%, single rare earth oxidation admire (NdZO) be the products such as CR-1, CR-2, CR-3 of raw material production.
In the present invention, said hyperchromic hair comprises the color-fixing agent of 3 ~ 96 weight portions with composition of detergent, preferably comprises the color-fixing agent of 10 ~ 90 weight portions, more preferably comprises the color-fixing agent of 20 ~ 40 weight portions.
Said color-fixing agent can improve the fastness of the hair color after the dyeing; Be preferably cationic resin color-fixing agent, response type color-fixing agent, quaternary ammonium salt color-fixing agent or silicone based color-fixing agent, more preferably cationic resin color-fixing agent, response type color-fixing agent or quaternary ammonium salt color-fixing agent.Wherein, said cationic resin color-fixing agent such as color fixing agent Y, color fixing agent M and color-fixing agent FLZOIL-810 etc.; Said response type color-fixing agent such as color-fixing agent NGC, color-fixing agent C and color-fixing agent DR-100 etc.; Said quaternary ammonium salt color-fixing agent such as color-fixing agent ECEOTIXFD-3, color-fixing agent ECEOTIXNF-50 and color-fixing agent TCD-R etc.; Said silicone based color-fixing agent comprises organosilicon, cationoid reaction type organosilicon and non-formaldehyde organosilicon etc.The fixation principle of said color-fixing agent can for: the cationic group contacts with alkaline aqueous solution; Separate out the formation aqueous gel; Adsorbable heavy metal ion of this aqueous gel and pigment; And can after drying, form thin film, thereby hair dye is played good fixing, protective effect on the wool fibre surface.
In the present invention, said hyperchromic hair preferably also comprises 5 ~ 95 parts by weight of Chinese traditional medicine hair blackening agent with composition of detergent, more preferably also comprises 10 ~ 50 parts by weight of Chinese traditional medicine hair blackening agent.
Said Chinese medicine hair blackening agent adopts this area Chinese medicine black hair extract commonly used to get final product; Be preferably in Radix Polygoni Multiflori extract, Radix Ginseng extract, Radix Astragali extract, Aloe extract, Radix Angelicae Sinensis extract and the wolfberry fruit extract one or more, more preferably one or more in Radix Polygoni Multiflori extract, Radix Ginseng extract, Radix Astragali extract, Radix Angelicae Sinensis extract and the wolfberry fruit extract.
The present invention also provides the method for preparing of a kind of hyperchromic hair with composition of detergent, may further comprise the steps:
Take by weighing the raw material of following weight portion:
The hair of 5 ~ 95 weight portions is used detergent;
The deep-dyeing agent of 2 ~ 98 weight portions, said deep-dyeing agent are one or more in chitin, chitosan, silicone oil chemical compound, rare earth and the resin;
The color-fixing agent of 3 ~ 96 weight portions;
Be to mix under 0 ~ 550 ℃ the condition said raw material, obtain hyperchromic hair and use composition of detergent in temperature.
After the present invention takes by weighing above-mentioned raw materials according to above-mentioned weight portion, it is mixed under 0 ~ 550 ℃, preferred 10 ℃ ~ 250 ℃, more preferably 30 ℃ ~ 160 ℃ temperature, obtain hyperchromic hair and use composition of detergent.In order further to reach the hair caring purpose, the present invention preferably also comprises and sneaks into 5 ~ 95 parts by weight of Chinese traditional medicine hair blackening agent.The present invention does not have particular restriction to other conditions such as said blended equipment.
Obtain hyperchromic hair with composition of detergent after, adopt its to versicolor hair or dyeing after hair repeatedly wash, said washing can be to embathe; Also can be spray, wherein, said embathing be specially: under 0 ~ 70 ℃ temperature; With the said hyperchromic hair of 0.1mL ~ 100mL with the water dissolution of composition of detergent, after stirring, under 0 ~ 100 ℃ temperature with 1mL ~ 100mL; The hair that 1g ~ 1000g is to be washed immerses wherein, and behind 1min ~ 100min, suction dries up or dries naturally.Said spray is specially: through vaporific generator, said hyperchromic hair is directly sprayed on the exsiccant hair to be washed with composition of detergent, behind 1min ~ 100min, the oven dry or dry naturally.
Experiment shows;, not only clean through hyperchromic hair provided by the invention with original hair of composition of detergent processing or the hair after the dyeing, and its color is increased deeply, is increased gorgeous; Reach and wash the effect of more deeply, often washing Chang Xin more; The problems such as pollution that can exempt dyeing repeatedly and form, thus make hair caring more simple and convenient, also practiced thrift a large amount of living funds simultaneously.
In order further to understand the present invention, hyperchromic hair provided by the invention is described in detail with composition of detergent and preparation method thereof below in conjunction with embodiment.
Embodiment 1
Take by weighing the dodecylbenzene sodium sulfonate detergent of 5 weight portions, the chitosan of 98 weight portions, the color fixing agent Y of 3 weight portions;
Be to mix under 30 ℃ the condition above-mentioned raw materials, obtain hyperchromic hair and use composition of detergent in temperature.
Adopt respectively that said hyperchromic hair is red, yellow, blue with composition of detergent spray, the hair after the dyeing to be washed of purple and black, handles 10 times after, be red, yellow, blueness, purple and black by the color of the hair after the dyeing of washing.
Comparative example 1
Taking by weighing the dodecylbenzene sodium sulfonate detergent of 5 weight portions and the water of 81 weight portions, is to mix under 30 ℃ the condition in temperature, obtains the hair composition of detergent.
Adopt respectively that said hair composition of detergent spray is red, yellow, blue, the hair after the dyeing to be washed of purple and black, handles 10 times after, the color of the hair after the quilt dyeing of washing is light red, light yellow, light blue, lilac and Lycoperdon polymorphum Vitt.
Embodiment 2
Take by weighing the NPE detergent of 94 weight portions, the sodium chloride of 0.1 weight portion, the ethoxyquin Oleum Cocois MEA of 0.1 weight portion, the ethanol of 0.1 weight portion, the hydrolysis of keratin of 0.1 weight portion, the P-hydroxybenzoic acid of 0.1 weight portion, the Oleum Cocois diethanolamine of 0.2 weight portion, the salicylic acid of 0.1 weight portion, the cation guar gum of 0.2 weight portion, the rare-earth products CR-1 of 2 weight portions and the color fixing agent Y of 96 weight portions;
Be to mix under 50 ℃ the condition above-mentioned raw materials, obtain hyperchromic hair and use composition of detergent in temperature.
Adopt the hair said hyperchromic hair embathes the dyeing to be washed of redness, yellow, blueness, purple and black with composition of detergent after respectively, handle 10 times after, be redness, gorgeous yellow, blueness, purple and black by the color of the hair after the dyeing of washing.
Embodiment 3
Take by weighing the alkyl polyglucoside detergent of 19 weight portions, the SILANOL SF9188 of 40 weight portions and the color fixing agent Y of 25 weight portions;
Be to mix under 30 ℃ the condition above-mentioned raw materials, obtain hyperchromic hair and use composition of detergent in temperature.
Adopt the hair said hyperchromic hair embathes the dyeing to be washed of redness, yellow, blueness, purple and black with composition of detergent after respectively, handle 10 times after, be red, yellow, blue, purple and black by the color of the hair after the dyeing of washing.
Embodiment 4
Take by weighing the ethyl oleate sodium sulfonate detergent of 77 weight portions, the polyurethane of 11 weight portions, the rare-earth products CR-2 of 3 weight portions and the color fixing agent Y of 16 weight portions;
Be to mix under 110 ℃ the condition above-mentioned raw materials, obtain hyperchromic hair and use composition of detergent in temperature.
Adopt respectively that said hyperchromic hair is red, yellow, blue with composition of detergent spray, the hair after the dyeing to be washed of purple and black, handles 10 times after, be red, yellow, blueness, purple and black by the color of the hair after the dyeing of washing.
Embodiment 5
Take by weighing the dodecylbenzene sodium sulfonate detergent of 20 weight portions, the alkyl polyglucoside detergent of 7 weight portions, the polyether modified silicon oil of 36 weight portions, the rare-earth products CR-3 of 5 weight portions, the color fixing agent Y of 51 weight portions and the wolfberry fruit extract of 5 weight portions;
Be to mix under 50 ℃ the condition above-mentioned raw materials, obtain hyperchromic hair and use composition of detergent in temperature.
Adopt the hair said hyperchromic hair embathes the dyeing to be washed of redness, yellow, blueness, purple and black with composition of detergent after respectively, wash 10 times after, be red, yellow, blue, purple and black by the color of the hair after the dyeing of washing.
Can know by above embodiment and comparative example; When adopting the hair after hyperchromic hair provided by the invention dyes with the composition of detergent washing; The color of hair had increase dark effect, thus original color that can make the hair dyeing after the washing time by fixation, and its color is increased deeply.
The explanation of above embodiment just is used for helping to understand method of the present invention and core concept thereof.Should be pointed out that for those skilled in the art, under the prerequisite that does not break away from the principle of the invention, can also carry out some improvement and modification to the present invention, these improvement and modification also fall in the protection domain of claim of the present invention.