CN107418401A - Sealing wax suit, lampshade and preparation method thereof - Google Patents

Sealing wax suit, lampshade and preparation method thereof Download PDF

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Publication number
CN107418401A
CN107418401A CN201710547763.1A CN201710547763A CN107418401A CN 107418401 A CN107418401 A CN 107418401A CN 201710547763 A CN201710547763 A CN 201710547763A CN 107418401 A CN107418401 A CN 107418401A
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CN
China
Prior art keywords
sealing wax
weight
paint
parts
strong
Prior art date
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Pending
Application number
CN201710547763.1A
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Chinese (zh)
Inventor
张戈辉
董立志
荆旺
李幕英
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Hebei Chenyang Industry and Trade Group Co Ltd
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Hebei Chenyang Industry and Trade Group Co Ltd
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Priority to CN201710547763.1A priority Critical patent/CN107418401A/en
Publication of CN107418401A publication Critical patent/CN107418401A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/02Polyureas
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16Antifouling paints; Underwater paints
    • C09D5/1656Antifouling paints; Underwater paints characterised by the film-forming substance
    • C09D5/1662Synthetic film-forming substance
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/16Antifouling paints; Underwater paints
    • C09D5/1687Use of special additives
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F21LIGHTING
    • F21VFUNCTIONAL FEATURES OR DETAILS OF LIGHTING DEVICES OR SYSTEMS THEREOF; STRUCTURAL COMBINATIONS OF LIGHTING DEVICES WITH OTHER ARTICLES, NOT OTHERWISE PROVIDED FOR
    • F21V3/00Globes; Bowls; Cover glasses
    • F21V3/04Globes; Bowls; Cover glasses characterised by materials, surface treatments or coatings
    • F21V3/10Globes; Bowls; Cover glasses characterised by materials, surface treatments or coatings characterised by coatings
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F21LIGHTING
    • F21WINDEXING SCHEME ASSOCIATED WITH SUBCLASSES F21K, F21L, F21S and F21V, RELATING TO USES OR APPLICATIONS OF LIGHTING DEVICES OR SYSTEMS
    • F21W2131/00Use or application of lighting devices or systems not provided for in codes F21W2102/00-F21W2121/00
    • F21W2131/10Outdoor lighting
    • F21W2131/103Outdoor lighting of streets or roads

Abstract

The present invention proposes sealing wax suit, lampshade and preparation method thereof.The sealing wax suit includes:Paint vehicle;And solidifying substance, wherein, the paint vehicle contains Nano silica sol.The sealing wax of the present invention, which is set with the paint film to be formed, has at least one of following advantages:Hardness is strong, richness is high, water resistance is strong, anti-corrosive properties are strong, resistance to ag(e)ing is strong, anti-soil power is high and good visual effect.

Description

Sealing wax suit, lampshade and preparation method thereof
Technical field
The present invention relates to chemical field.In particular it relates to sealing wax suit, lampshade and preparation method thereof.
Background technology
Along with the sustained and rapid development of China's economic for many years, many cities, small towns evening still brilliantly illuminated, street lamp As the necessity in streets and lanes.
Sealing wax refers to the coating using water as diluent.At present, required study suitable for the sealing wax of street lampshade.
The content of the invention
It is contemplated that at least solves at least one technical problem present in prior art to a certain extent.Therefore, The present invention proposes sealing wax suit, lampshade and preparation method thereof.The sealing wax of the present invention, which is set with the paint film to be formed, has following advantages At least one of:Hardness is strong, richness is high, water resistance is strong, anti-corrosive properties are strong, resistance to ag(e)ing is strong, anti-soil power is high and visual effect It is good.
It should be noted that the present invention is the following discovery based on inventor and completed:
Street lampshade is chronically exposed to external environment condition, is subjected to wind, Exposure to Sunlight, drenches with rain, causes its cracky, it is often necessary to return Repair, cause the excessive waste of human and material resources.
In view of this, inventor has found, using Nano silica sol as raw material so that the paint film of formation is with higher soft Toughness and hardness, so as to enhance the resistance to ag(e)ing of paint film, scrub resistance and contamination resistance.Thus, according to of the invention real The sealing wax for applying example is set with the paint film to be formed and has at least one of following advantages:Hardness is strong, richness is high, water resistance is strong, anti-corrosion Property strong, resistance to ag(e)ing it is strong and anti-soil power is high.
Therefore, in one aspect of the invention, the present invention proposes a kind of sealing wax suit.According to an embodiment of the invention, The sealing wax suit includes:Paint vehicle;And solidifying substance, wherein, the paint vehicle contains Nano silica sol.Inventor has found, uses Nano silica sol is as raw material so that the paint film of formation has higher pliability and hardness, so as to enhance the resistance to old of paint film The property changed, scrub resistance and contamination resistance., it is necessary to be used in the short time after being mixed due to paint vehicle with solidifying substance.For convenience Storage and use, paint vehicle and solidifying substance are separated, when to be used, paint vehicle mixed with solidifying substance, you can obtain sealing wax.By This, sealing wax according to embodiments of the present invention, which is set with the paint film to be formed, has at least one of following advantages:Hardness is strong, richness Height, water resistance is strong, anti-corrosive properties are strong, resistance to ag(e)ing is strong and anti-soil power is high.
According to an embodiment of the invention, above-mentioned sealing wax suit can also have following additional technical feature:
According to an embodiment of the invention, the mass ratio of the paint vehicle and solidifying substance is 14~16:1.Thus, according to the present invention The sealing wax of embodiment, which is set with the paint film to be formed, further has at least one of following advantages:Hardness is strong, richness is high, water resistance By force, anti-corrosive properties are strong, resistance to ag(e)ing is strong and anti-soil power is high.
According to an embodiment of the invention, the gross mass based on the paint vehicle, the content of the Nano silica sol is 15~20 Quality %.Thus, sealing wax according to embodiments of the present invention, which is set with the paint film to be formed, further has at least one of following advantages: Hardness is strong, richness is high, water resistance is strong, anti-corrosive properties are strong, resistance to ag(e)ing is strong and anti-soil power is high.
According to an embodiment of the invention, the gross mass based on the paint vehicle, the paint vehicle contain 10~15 mass % change Color pigment.Thus, sealing wax according to embodiments of the present invention, which is set with the paint film to be formed, further has preferable visual effect.
According to an embodiment of the invention, the paint vehicle includes:The base-material of 60~65 parts by weight;The nanometer of 15~20 parts by weight Ludox;The auxiliary agent of 5~10 parts by weight;The substrate wetting agents of 0.2~0.5 parts by weight;The wetting dispersing agent of 0.5~1 parts by weight; The defoamer of 0.1~0.5 parts by weight;The insect prevention auxiliary agent of 0.1~0.5 parts by weight;The camouflage paint of 10~15 parts by weight;And 1 The titanium dioxide of~3 parts by weight.Thus, sealing wax according to embodiments of the present invention, which is set with the paint film to be formed, further has following advantages At least one of:Hardness is strong, richness is high, water resistance is strong, anti-corrosive properties are strong, resistance to ag(e)ing is strong, anti-soil power is high and visual effect It is good.
According to an embodiment of the invention, the base-material is Aqueous acrylic urethane's emulsion.Thus, implemented according to the present invention The sealing wax of example, which is set with the paint film to be formed, further has at least one of following advantages:Hardness is strong, richness is high, water resistance is strong, Anti-corrosive properties are strong, resistance to ag(e)ing is strong, anti-soil power is high and good visual effect.
According to an embodiment of the invention, the camouflage paint is colors changing hue pearl essence.Thus, according to embodiments of the present invention Sealing wax be set with the paint film to be formed further there is preferable visual effect.
According to an embodiment of the invention, the auxiliary agent is water;The substrate wetting agents soak for twin structure silicone-type Agent;The wetting dispersing agent is the macromolecule dispersing agent without VOC and solvent;The defoamer is poly- containing aerosil Ether silicone copolymers type defoamer.Thus, sealing wax according to embodiments of the present invention is set with the paint film to be formed further has At least one of row advantage:Hardness is strong, richness is high, water resistance is strong, anti-corrosive properties are strong, resistance to ag(e)ing is strong and anti-soil power is high.
According to an embodiment of the invention, the solidifying substance includes:The polyureas curing agent of 70~80 parts by weight;And 20~30 The propylene-glycol diacetate of parts by weight.Thereby, it is possible to accelerate to paint body solidification, paint film is formed.
In another aspect of this invention, the present invention proposes a kind of lampshade.According to an embodiment of the invention, the lampshade bag Include:Lampshade matrix;And enamelled coating, the enamelled coating are formed at least part surface of the lampshade matrix, wherein, the enamelled coating is It is made up of sealing wax noted earlier suit.Thus, lampshade according to embodiments of the present invention has at least one of following advantages:Firmly Degree is strong, water resistance is strong, anti-corrosive properties are strong, resistance to ag(e)ing is strong, anti-soil power is high and good visual effect.
According to an embodiment of the invention, the lampshade is street lampshade.Thus, street lampshade according to embodiments of the present invention With at least one of following advantages:Hardness is strong, water resistance is strong, anti-corrosive properties are strong, resistance to ag(e)ing is strong, anti-soil power is high and vision effect Fruit is good.
In still another aspect of the invention, the present invention proposes a kind of method for preparing lampshade.According to an embodiment of the invention, Methods described includes:The paint vehicle and the solidifying substance are subjected to mixed processing, obtain mixed paint;And the mixed paint is applied At least part surface of the lampshade matrix is added on, to form the enamelled coating.Thus, method according to embodiments of the present invention institute Obtained street lampshade has at least one of following advantages:Hardness is strong, water resistance is strong, anti-corrosive properties are strong, resistance to ag(e)ing is strong, anti-soil Power height and good visual effect.
The additional aspect and advantage of the present invention will be set forth in part in the description, and will partly become from the following description Obtain substantially, or recognized by the practice of the present invention.
Embodiment
Embodiments of the invention are described below in detail.The embodiments described below is exemplary, is only used for explaining this hair It is bright, and be not considered as limiting the invention.
The present invention proposes sealing wax suit, lampshade and preparation method thereof, will be described in greater detail respectively below.
Sealing wax is set with
In one aspect of the invention, the present invention proposes a kind of sealing wax suit.According to an embodiment of the invention, sealing wax set Dress includes:Paint vehicle;And solidifying substance, wherein, paint vehicle contains Nano silica sol.After being mixed due to paint vehicle with solidifying substance, it is necessary to Used in short time.In order to facilitate storing and using, paint vehicle is set to be individually present with solidifying substance, when to be used, by paint vehicle and solidification Material is mixed, you can obtains sealing wax.
Nano silica sol is hydrolytic resistance silane, and such a silane can be stabilized more than 1 year in aqueous phase, and it has phase When the hydroxy functional group of high activity, such a silane belongs to more grafted products, and racemosus structure provides for very strong position every effect in itself Should, along with water position every, so the hydroxyl of silane can't to resin produce harmful effect, also will not auto polymerization, but spray Moisture evaporation afterwards, silane is close to each other, and racemosus structure also can be overlapping, so the paint film formed will be very fine and close flexible, has Higher hardness.Thereby, it is possible to strengthen paint film ageing-resistant performance, hardness reaches 2H after 8 hours hardness of construction reaches H, drying, resistance to Clean > 20000 times, improve film contamination resistance, persistently cleaning, extend paint film service life.Thus, according to of the invention real The sealing wax for applying example is set with the paint film to be formed and has at least one of following advantages:Hardness is strong, richness is high, water resistance is strong, anti-corrosion Property strong, resistance to ag(e)ing it is strong and anti-soil power is high.
According to an embodiment of the invention, the mass ratio of paint vehicle and solidifying substance is 14~16:1.Inventor has found that paint vehicle is with consolidating The mixed proportion of material can influence hardness, film forming and water resistance of paint film etc..And then inventor obtains by many experiments Above-mentioned preferable mixed proportion, if solidifying substance is very few, impact resistance is poor, film forming sexual deviation, water resistance are relatively low;If solidifying substance mistake More, the water resistance of paint film is poor, and slow drying speed, hardness are low.Thus, sealing wax according to embodiments of the present invention is set with the paint to be formed Film further has at least one of following advantages:Hardness is strong, richness is high, water resistance is strong, anti-corrosive properties are strong, resistance to ag(e)ing by force with And anti-soil power is high.
According to an embodiment of the invention, the gross mass based on paint vehicle, the content of Nano silica sol is 15~20 mass %.Hair A person of good sense has found that Nano silica sol content can influence hardness, pliability and resistance to ag(e)ing of paint film etc..And then inventor passes through Many experiments obtain above-mentioned preferable content, and thus, sealing wax according to embodiments of the present invention, which is set with the paint film to be formed, further to be had There are at least one of following advantages:Hardness is strong, richness is high, water resistance is strong, anti-corrosive properties are strong, resistance to ag(e)ing is strong and anti-soil power It is high.Specifically, Nano silica sol is purchased from Yantai Heng Xin chemical industry or Guangdong favour and silicon product company.
According to an embodiment of the invention, the gross mass based on paint vehicle, paint vehicle contain 10~15 mass % camouflage paint.Hair A person of good sense has found that the addition of camouflage paint enables to paint film to show different colours, enhancing vision effect under different illumination conditions Fruit.Thus, sealing wax according to embodiments of the present invention, which is set with the paint film to be formed, further has preferable visual effect.
According to an embodiment of the invention, paint vehicle includes:The base-material of 60~65 parts by weight;The nano silicasol of 15~20 parts by weight Glue;The auxiliary agent of 5~10 parts by weight;The substrate wetting agents of 0.2~0.5 parts by weight;The wetting dispersing agent of 0.5~1 parts by weight;0.1 The defoamer of~0.5 parts by weight;The insect prevention auxiliary agent of 0.1~0.5 parts by weight;The camouflage paint of 10~15 parts by weight;And 1~3 The titanium dioxide of parts by weight.Inventor obtains above-mentioned preferred component and its proportioning by many experiments, thus, is implemented according to the present invention The sealing wax of example, which is set with the paint film to be formed, further has at least one of following advantages:Hardness is strong, richness is high, water resistance is strong, Anti-corrosive properties are strong, resistance to ag(e)ing is strong, anti-soil power is high and good visual effect.
According to an embodiment of the invention, titanium dioxide is rutile class titanium dioxide.Thus, covered to play with improving hardness Effect.
According to an embodiment of the invention, base-material is Aqueous acrylic urethane's emulsion.Inventor has found in numerous base-materials, Aqueous acrylic urethane's emulsion causes the paint film to be formed to have a preferable hardness and wear resistance, and weatherability is also preferable.Thus, root Being set with the paint film to be formed according to the sealing wax of the embodiment of the present invention further has at least one of following advantages:Hardness is strong, richness Height, water resistance is strong, anti-corrosive properties are strong, resistance to ag(e)ing is strong, anti-soil power is high and good visual effect.Specifically, base-material is purchased from ten thousand Chinaization Learn, model 2033.
According to an embodiment of the invention, camouflage paint is colors changing hue pearl essence.Thus, water according to embodiments of the present invention The paint film that paint suit is formed further has preferable visual effect.Specifically, camouflage paint is limited purchased from color fine chemistry industry of singing The colors changing hue pearl essence of company.
According to an embodiment of the invention, auxiliary agent is water.
According to an embodiment of the invention, substrate wetting agents are twin structure silicone-type wetting agent.Inventor is in numerous bases Found in material wetting agent, twin structure silicone-type wetting agent can be effectively reduced the interfacial tension between liquid/solid, strengthen table The lyophily in face, and make it that the surface smoothness of paint film is preferable.Specifically, substrate wetting agents are purchased from TEGO companies, model TEGO4100。
According to an embodiment of the invention, wetting dispersing agent is the macromolecule dispersing agent without VOC and solvent.Invention human hair Existing, the macromolecule dispersing agent without VOC and solvent enables to each component to be dispersed in water, while can also prevent solid The sedimentation and cohesion of grain, form stabilising system.Specifically, wetting dispersing agent is purchased from BYK companies, model BYK192.
According to an embodiment of the invention, defoamer is the polyether siloxane copolymer type defoamer containing aerosil. Inventor has found that above-mentioned defoamer can effectively eliminate bubble, prevent paint film from bubble be present in numerous defoamers.Thus, Sealing wax according to embodiments of the present invention, which is set with the paint film to be formed, further has at least one of following advantages:Hardness is strong, plentiful Degree is high, water resistance is strong, anti-corrosive properties are strong, resistance to ag(e)ing is strong and anti-soil power is high.Specifically, defoamer is purchased from TEGO, model Foamex 810。
According to an embodiment of the invention, solidifying substance includes:The polyureas curing agent of 70~80 parts by weight;And 20~30 weight The propylene-glycol diacetate of part.Thereby, it is possible to accelerate to paint body solidification, paint film is formed.Specifically, polyureas curing agent is purchased from Wuxi ancient cooking vessel Safe Chemical Co., Ltd., model 4200.
According to an embodiment of the invention, insect prevention auxiliary agent is natural insect prevention auxiliary agent, such as Ke Shiwei natural insect prevention auxiliary agent.
Lampshade
In another aspect of this invention, the present invention proposes a kind of lampshade.According to an embodiment of the invention, the lampshade bag Include:Lampshade matrix;And enamelled coating, enamelled coating are formed at least part surface of the lampshade matrix, wherein, enamelled coating is by above water Paint suit is formed.The enamelled coating that paint vehicle and solidifying substance in sealing wax suit are formed, has at least one of following advantages:Hardness By force, water resistance is strong, anti-corrosive properties are strong, resistance to ag(e)ing is strong, anti-soil power is high and good visual effect.
According to an embodiment of the invention, lampshade is street lampshade.Thus, shape on street lampshade according to embodiments of the present invention Into enamelled coating there are at least one of following advantages:Hardness is strong, water resistance is strong, anti-corrosive properties are strong, resistance to ag(e)ing is strong, anti-soil power height with And good visual effect.
The method for preparing lampshade
In still another aspect of the invention, the present invention proposes a kind of method for preparing lampshade.According to an embodiment of the invention, This method includes:Paint vehicle and solidifying substance are subjected to mixed processing, obtain mixed paint;And mixed paint is put on into lampshade matrix At least part surface, to form enamelled coating.Thus, the street lampshade obtained by method according to embodiments of the present invention has following At least one of advantage:Hardness is strong, water resistance is strong, anti-corrosive properties are strong, resistance to ag(e)ing is strong, anti-soil power is high and good visual effect.
The solution of the present invention is explained below in conjunction with embodiment.It will be understood to those of skill in the art that following Embodiment is merely to illustrate the present invention, and should not be taken as limiting the scope of the invention.Unreceipted particular technique or bar in embodiment Part, carried out according to the technology described by document in the art or condition or according to product description.Agents useful for same or instrument The unreceipted production firm person of device, being can be by the conventional products of acquisition purchased in market.
Embodiment 1~4
In this embodiment, sealing wax suit is obtained in following manner:
1st, raw material
Table 1
2nd, preparation method
The preparation of paint vehicle:
Step a, according to the raw material proportioning, first by deionized water, the macromolecule dispersing agent without VOC and solvent, gassiness Polyether siloxane copolymer type defoamer, Nano silica sol, colors changing hue pearl essence, the rutile class titanium dioxide of aerosil Mixed, stirred 30 minutes with 1000r/min speed, to mill base fineness≤25 μm.
Step b, resulting mill base is added in stock pot, 600r/min speed stirring is lower to add water soluble acrylic acid Polyaminoester emulsion, stir 15 minutes.
Step c, insect prevention auxiliary agent is added in stock pot, 800r/min speed stirs 10 minutes, is eventually adding twin Structure silicone-type wetting agent, 800r/min speed stir 10 minutes, and paint vehicle is made.
The preparation of solidifying substance:
The speed of polyureas curing agent and propylene-glycol diacetate in 600r/min stirs 15 minutes.When to be used, by paint vehicle Mixed with solidifying substance, you can use.
The effect of the product of embodiment 1:With good wear-resisting quick-drying, hardness is higher, pencil hardness H, has certain Barrier propterty, drying time 30min, colors changing hue effect is worst in four formulation examples, has in general vermins-proof effect, Artificial ageing resistance > 1000 hours, scrubbing resistance > 15000 times.
The effect of the product of embodiment 2:With good wear-resisting quick-drying performance, pencil hardness 2H.With certain protection Property, can drying time 25min, colors changing hue effect is most strong in four formulation examples, has a best vermins-proof effect, and pencil is hard Spend for 3H, artificial ageing resistance > 1800 hours, scrubbing resistance > 30000 times.
The effect of the product of embodiment 3:With best quick-drying anti-wear performance, pencil hardness is up to 2H.In four formulas With best barrier propterty and higher water-fast solvent resistant, cost performance highest, drying time 15min.In four Formulation Examples Colors changing hue effect is moderate in son, has good vermins-proof effect, pencil hardness 2H.Artificial ageing resistance > 1300 hours, it is resistance to Clean > 18000 times.
The effect of the product of embodiment 4:With preferable anti-wear performance, pencil hardness is H drying time 26min, at four Colors changing hue effect is moderate in formulation examples, has good vermins-proof effect, pencil hardness 2H.Artificial ageing resistance > 1500 is small When, scrubbing resistance > 23000 times, cost is slightly higher.
Comparative example 1
Method according to embodiment 1 prepares sealing wax suit, and difference is, the mass ratio of paint vehicle and solidifying substance is 12:1.
As a result show, compared to embodiment 1, the slow drying speed and hardness of the sealing wax obtained by comparative example 1 are low.
Comparative example 2
Method according to embodiment 1 prepares sealing wax suit, and difference is, the mass ratio of paint vehicle and solidifying substance is 18:1.
As a result show, compared to embodiment 1, the impact resistance of the sealing wax obtained by comparative example 2 is poor.
Comparative example 3
Method according to embodiment 1 prepares sealing wax suit, and difference is, without Nano silica sol.
As a result show, compared to embodiment 1, the fine and close flexible and hardness of the sealing wax paint film obtained by comparative example 3 reduces, resistance to Ageing properties reduce, and contamination resistance reduces.
Comparative example 4
Method according to embodiment 1 prepares sealing wax suit, and difference is that the quality of Nano silica sol is 30kg.
As a result show, compared to embodiment 1, the excessive high hardness of the sealing wax obtained by comparative example 4, so as to cause its pliability It is deteriorated with impact.
In the description of this specification, reference term " one embodiment ", " some embodiments ", " example ", " specifically show The description of example " or " some examples " etc. means specific features, structure, material or the spy for combining the embodiment or example description Point is contained at least one embodiment or example of the present invention.In this manual, to the schematic representation of above-mentioned term not Identical embodiment or example must be directed to.Moreover, specific features, structure, material or the feature of description can be with office Combined in an appropriate manner in one or more embodiments or example.In addition, in the case of not conflicting, the skill of this area Art personnel can be tied the different embodiments or example and the feature of different embodiments or example described in this specification Close and combine.
Although embodiments of the invention have been shown and described above, it is to be understood that above-described embodiment is example Property, it is impossible to limitation of the present invention is interpreted as, one of ordinary skill in the art within the scope of the invention can be to above-mentioned Embodiment is changed, changed, replacing and modification.

Claims (10)

  1. A kind of 1. sealing wax suit, it is characterised in that including:
    Paint vehicle;And
    Solidifying substance,
    Wherein, the paint vehicle contains Nano silica sol.
  2. 2. sealing wax according to claim 1 suit, it is characterised in that the mass ratio of the paint vehicle and solidifying substance is 14~ 16:1。
  3. 3. sealing wax suit according to claim 1, it is characterised in that the gross mass based on the paint vehicle, the nano-silicon The content of colloidal sol is 15~20 mass %,
    Optionally, the gross mass based on the paint vehicle, the paint vehicle contain 10~15 mass % camouflage paint.
  4. 4. sealing wax suit according to claim 1, it is characterised in that the paint vehicle includes:
    The base-material of 60~65 parts by weight;
    The Nano silica sol of 15~20 parts by weight;
    The auxiliary agent of 5~10 parts by weight;
    The substrate wetting agents of 0.2~0.5 parts by weight;
    The wetting dispersing agent of 0.5~1 parts by weight;
    The defoamer of 0.1~0.5 parts by weight;
    The insect prevention auxiliary agent of 0.1~0.5 parts by weight;
    The camouflage paint of 10~15 parts by weight;And
    The titanium dioxide of 1~3 parts by weight.
  5. 5. sealing wax suit according to claim 4, it is characterised in that the base-material is Aqueous acrylic urethane's emulsion.
  6. 6. sealing wax suit according to claim 3, it is characterised in that the camouflage paint is colors changing hue pearl essence.
  7. 7. sealing wax suit according to claim 4, it is characterised in that the auxiliary agent is water;
    The substrate wetting agents are twin structure silicone-type wetting agent;
    The wetting dispersing agent is the macromolecule dispersing agent without VOC and solvent;
    The defoamer is the polyether siloxane copolymer type defoamer containing aerosil.
  8. 8. sealing wax suit according to claim 1, it is characterised in that the solidifying substance includes:
    The polyureas curing agent of 70~80 parts by weight;And
    The propylene-glycol diacetate of 20~30 parts by weight.
  9. A kind of 9. lampshade, it is characterised in that including:
    Lampshade matrix;And
    Enamelled coating, the enamelled coating are formed at least part surface of the lampshade matrix,
    Wherein, the enamelled coating is made up of any one of the claim 1~8 sealing wax suit,
    Preferably, the lampshade is street lampshade.
  10. A kind of 10. method for preparing lampshade described in claim 9, it is characterised in that including:
    The paint vehicle and the solidifying substance are subjected to mixed processing, obtain mixed paint;And
    The mixed paint is put on at least part surface of the lampshade matrix, to form the enamelled coating.
CN201710547763.1A 2017-07-06 2017-07-06 Sealing wax suit, lampshade and preparation method thereof Pending CN107418401A (en)

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Application Number Priority Date Filing Date Title
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CN107418401A true CN107418401A (en) 2017-12-01

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108285730A (en) * 2018-01-09 2018-07-17 河北晨阳工贸集团有限公司 Suitable for outdoor high performance polyurethane terrace sealing wax
CN108359322A (en) * 2018-01-17 2018-08-03 河北晨阳工贸集团有限公司 A kind of self-drying type lampshade environmental protection paint and preparation method thereof and application method

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CN102268208A (en) * 2011-06-02 2011-12-07 沈阳顺风新城建筑材料有限公司 Nanometer silica sol modified exterior wall emulsion paint and preparation method thereof
CN102796449A (en) * 2012-09-12 2012-11-28 沈阳飞机工业(集团)有限公司 Water-based polyurethane enamel paint
CN104371533A (en) * 2013-08-13 2015-02-25 陆伟明 Stainless steel surface paint
CN105542644A (en) * 2015-12-16 2016-05-04 华南理工大学 Nanometer silica-modified aqueous polyurethane waterproof paint and preparation method thereof
CN106380974A (en) * 2016-08-30 2017-02-08 河北晨阳工贸集团有限公司 Nano silica sol modified acrylic acid finishing varnish and preparation method thereof
CN106590382A (en) * 2016-11-24 2017-04-26 深圳市广田环保涂料有限公司 Dual-component aqueous nano modified UV carpentry paint, preparation method and use method thereof

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Publication number Priority date Publication date Assignee Title
CN102268208A (en) * 2011-06-02 2011-12-07 沈阳顺风新城建筑材料有限公司 Nanometer silica sol modified exterior wall emulsion paint and preparation method thereof
CN102796449A (en) * 2012-09-12 2012-11-28 沈阳飞机工业(集团)有限公司 Water-based polyurethane enamel paint
CN104371533A (en) * 2013-08-13 2015-02-25 陆伟明 Stainless steel surface paint
CN105542644A (en) * 2015-12-16 2016-05-04 华南理工大学 Nanometer silica-modified aqueous polyurethane waterproof paint and preparation method thereof
CN106380974A (en) * 2016-08-30 2017-02-08 河北晨阳工贸集团有限公司 Nano silica sol modified acrylic acid finishing varnish and preparation method thereof
CN106590382A (en) * 2016-11-24 2017-04-26 深圳市广田环保涂料有限公司 Dual-component aqueous nano modified UV carpentry paint, preparation method and use method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108285730A (en) * 2018-01-09 2018-07-17 河北晨阳工贸集团有限公司 Suitable for outdoor high performance polyurethane terrace sealing wax
CN108359322A (en) * 2018-01-17 2018-08-03 河北晨阳工贸集团有限公司 A kind of self-drying type lampshade environmental protection paint and preparation method thereof and application method

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